Abstract: A superabsorbent having surfaces complexed with polyvalent metal ions and which contains at least one phosphonic acid derivative, and the molar ratio between polyvalent metal and phosphonic acid derivative is at most 1.2/n, where n is the number of phosphonic acid groups in the phosphonic acid derivative. The superabsorbent exhibits good stability against discoloration and a surprisingly low caking tendency without any significant impairment of its performance properties.

Abstract: A denitrification method is disclosed for removing nitrogen compounds from a hydrocarbon feed in which the feed is contacted with an adsorbent including an organic heterocyclic salt deposited on a porous support. Additionally, a method for hydrotreating a hydrocarbon feed which includes a hydroprocessing step is disclosed, wherein prior to hydroprocessing, the feed is contacted with an adsorbent including an organic heterocyclic salt deposited on a support. Additionally, a method for producing a lube oil which includes isomerization dewaxing of a base oil fraction is disclosed, wherein prior to the isomerization dewaxing step, the base oil fraction is contacted with an adsorbent including an organic heterocyclic salt deposited on a support.

Abstract: An object of the invention is to provide a protein-adsorbing material having both adsorption capacity and high-speed treatment performance applicable to not only analysis use but also industrial use, in balance, and to provide a method for producing the same. The present invention provides a protein-adsorbing material comprising a polymer base-material, a polymer side-chain immobilized to the surface of the polymer base-material and a functional group having protein adsorption ability and immobilized to the polymer side-chain, in which the mass of the polymer side-chain is 5 to 30% relative to the mass of the polymer base-material.

Abstract: A method for the treatment of solvent-containing MOF material to increase its internal surface area involves introducing a liquid into the MOF in which liquid the solvent is miscible, subjecting the MOF to supercritical conditions for a time to form supercritical fluid, and releasing the supercritical conditions to remove the supercritcal fluid from the MOF. Prior to introducing the liquid into the MOF, occluded reaction solvent, such as DEF or DMF, in the MOF can be exchanged for the miscible solvent.

Abstract: A linking ligand compound includes three bidentate chemical moieties distributed about a central chemical moiety. Another linking ligand compound includes a bidentate linking ligand and a monodentate chemical moiety. Coordination polymers include a plurality of metal clusters linked together by residues of the linking ligand compounds.

Abstract: An electric deionized water production apparatus in which a direct current field is applied to a deionizing chamber packed with an ion-exchange material such that ions to be discharged are allowed to migrate in the direction identical or opposite to the direction of the water flow in the ion-exchange material, whereby ionic impurities adsorbed in the ion-exchange material are discharged from the system, the ion-exchange material being a mixture of a monolith-shaped organic porous ion-exchange material and ion-exchange resin particles. The electric deionized water production apparatus has a simple structure that can reduce material cost, process cost, and assembly cost, capable of accelerating migration of the adsorbed ionic impurities to facilitate discharge of the adsorbed ions and free from a deflected flow due to swelling or shrinkage accompanying an ion-exchanging reaction, and from poor contact with an ion-exchange membrane.

Abstract: Two new classes of amine-based sorbents are disclosed. The first class comprises new polymer-immobilized tertiary amine sorbents; the second class new polymer-bound amine sorbents. Both classes are tailored to facilitate removal of acid anhydrides, especially carbon dioxide (CO2), from effluent gases. The amines adsorb acid anhydrides in a 1:1 molar ratio. Both classes of amine sorbents adsorb in the temperature range from about 20° C. upwards to 90° C. and can be regenerated by heating upwards to 100° C.

Abstract: A process for the industrial isolation of propene from a gas stream comprising at least propene and propane, which involves contacting of the gas stream with an adsorbent having a porous metal organic framework having at least one at least bidentate organic compound coordinated to at least one metal ion, with the adsorbent becoming laden with propane and the gas stream therefore having an increased proportion of propene, wherein the W least bidentate organic compound is an imidazolate which is unsubstituted or has one or more substituents selected independently from of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, O-phenyl and O—C1-6-alkyl.

Abstract: The present invention is directed to a separation medium comprising rotary dried or spray dried precipitated silica. The silica has a pore surface area P wherein log10 P>2.2, and the ratio of BET to CTAB is at least 1.0 measured prior to any surface modification of the silica. The present invention is further directed to a method of separating suspended or dissolved materials from a fluid stream, comprising contacting the stream with the separation medium described above.

Abstract: A method of selecting an appropriate resin bonded sorbent composition which may be used at least for in part making an enclosure to protect contents from external humidity including the steps of: a) selecting a plurality of resins, a plurality of sorbents and a plurality of ratios therebetween to form a plurality of composites; b) calculating a plurality of failure times for the plurality of composites, wherein each failure time of the plurality of failure times is based on when an internal relative humidity of each composite of the plurality of composites is equal to the maximum internal relative humidity; c) determining which of the plurality of failure times is greater; and, d) selecting one composite of the plurality of composites based on the result of step (c).

Abstract: Metal-organic framework (MOF) materials are provided and are selectively adsorbent to xenon (Xe) over another noble gas such as krypton (Kr) and/or argon (Ar) as a result of having framework voids (pores) sized to this end. MOF materials having pores that are capable of accommodating a Xe atom but have a small enough pore size to receive no more than one Xe atom are desired to preferentially adsorb Xe over Kr in a multi-component (Xe—Kr mixture) adsorption method. The MOF material has 20% or more, preferably 40% or more, of the total pore volume in a pore size range of 0.45-0.75 nm which can selectively adsorb Xe over Kr in a multi-component Xe—Kr mixture over a pressure range of 0.01 to 1.0 MPa.

Abstract: Porous metal organic frameworks formed by AlIII ions to which fumarate ions are coordinated to produce a framework structure; shaped bodies comprising such porous metal organic frameworks, and also the preparation and use thereof for the uptake of a substance for the purposes of its storage, controlled release, separation, chemical reaction or as support.

Abstract: The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for its preparation and separations devices containing the chromatographic material; separations devices, chromatographic columns and kits comprising the same; and methods for the preparation thereof. The chromatographic materials of the invention are chromatographic materials comprising having a narrow particle size distribution.

Abstract: This invention provides a multi-aperture carbon granule air purificant and production method thereof, and belongs to the technical field of air purification. The air purificant is made from carbon powder, attapulgite, sepiolite, zeolite, cationic surfactant, pore-forming agent, and bamboo vinegar. The rational design that carbon powder (including plant carbon and activated carbon) of the air purificant mentioned above is treated with nano minerals, attapulgite, sepiolite, zeolite and so on, improves plant carbon adsorption capacity (over 5 folds) and activated carbon adsorption capacity (over 2 folds). Moreover it has additional bactericidal and antibacterial actions besides for the effects of cationic surfactant and bamboo vinegar. Compared with other adsorbents under current techniques, this air purificant still holds high adsorption capacity even at high temperature and low partical pressure of adsorbates, and maintains the function of plant carbon's releasing anion and far infrared at the meantime.

Abstract: Disclosed herein are rod-packing robust microporous metal-organic frameworks having the repeat unit Zn4(OH)2(1,2,4-BTC)2, useful for applications such as selective gas storage, selective gas sorption and/or separation, selective sensing of chemicals, and catalysis.

Abstract: Porous organic-inorganic hybrid materials with crystallinity and a method for preparing the same are provided. The method comprises preparing a reaction solution containing a mixture of at least one inorganic metal precursor, at least one organic compound which may act as a ligand, and a solvent (step 1); and forming porous organic-inorganic hybrid materials with crystallinity by reacting the reaction solution (step 2), wherein the reaction is carried out under the pressure of about 3 atm or less.

Abstract: Methods for solubilizing carbon nanohorns and applications thereof, including the manufacture of composites, hydrogen storage, catalyst supports and drug delivery. In certain embodiments, the method can include: a) Reduction of pristine carbon nanohorns by an alkali metal to lead to a carbon nanohorn alkali salt; and b) Exposure of said carbon nanohorn alkali salt to a polar aprotic solvent to lead to a solution of reduced carbon nanohorns. In certain other embodiments, solutions of carbon nanohorns, and individual carbon nanohorns are obtainable by the methods, as well as uses of such individual carbon nanohorns and solutions of carbon nanohorns.

Abstract: A gas adsorption material comprising: a porous metal-organic framework and a plurality of functionalized fullerenes or fullerides provided in the pores of the metal-organic framework. The metal-organic framework includes a plurality of metal clusters, each metal cluster including one or more metal ions, and a plurality of charged multidentate linking ligands connecting adjacent metal clusters.

Abstract: The present application provides a protected solid adsorbent that includes a solid adsorbent substrate and a surface layer at least partially coating the solid adsorbent substrate, the surface layer being generally permeable to an active agent. Additionally, a process for protecting a solid adsorbent and an adsorption system that includes a vessel containing the protected solid adsorbent is provided.

Abstract: The present invention relates to a process for the production of a surface-treated calcium carbonate, the use of this surface-treated calcium carbonate in a process for the control of organic material in an aqueous medium, as well as to a composite of surface-treated calcium carbonate and organic material, such as a composite of surface-treated calcium carbonate and to the use of such a composite.

Abstract: Porous inorganic oxide particles, such as porous silica particles, and compositions containing porous inorganic oxide particles are disclosed. Methods of making porous inorganic oxide particles and methods of using porous inorganic oxide particles are also disclosed.

Abstract: A sorbent structure comprising a continuous activated carbon body in the form of a flow-through substrate; and an additive provided on the flow-through substrate, wherein the additive is capable of enhancing the sorption of CO2 on the sorbent structure. Methods of making the sorbent structure, its use for CO2 capture, and methods for regenerating the structure for further use.

Abstract: A process for producing a polysaccharide superabsorbent particulate including the process steps of bringing into contact a polysaccharide with a polyphosphate or a polyphosphoric acid as crosslinking agent in the presence of water to form a polysaccharide gel drying the polysaccharide gel, comminuting the dried polysaccharide gel to form polysaccharide superabsorbent polymer particles, coating the particles with a polyphosphate or polyphosphoric acid, crosslinking the coated particles, and surface treating the particulate with a metal multivalent salt or an acid. The invention further relates to a polysaccharide superabsorbent polymer particulate obtainable by this process, a water-absorbent polysaccharide, a composite, a process for producing a composite, a composite produced by this process, the use of the polysaccharide superabsorbent particulates or of the composites as well as the use of polyphosphates.

Abstract: A treatment medium has a particulate natural substrate saturated, suffused and/or coated with hydrous iron oxide. The particulate substrate can be wood based, such as wood chips, bark, sawdust, wood waste or other plant material (such as straw, lucerne, hay, coconut husk or other bulk particulate plant material). The hydrous iron oxide is provided in aqueous suspension form. The substrate may be tumbled in aqueous hydrous iron suspension to achieve saturation/coating. The resulting hydrous iron oxide bearing medium is either placed loose directly into the target treatment site or contained in bags 18 before placing into the target site.

Abstract: A heavy metal absorbent, and a filter device including the same, include heavy metal absorbing particles each having a surface with a —NOx (1?x?2) functional group. The heavy metal absorbing particles are one selected from inorganic oxide particles, graphite-based carbon particles, and a combination thereof.

Abstract: Various embodiments relate to an impregnated nonwoven for degreasing food, to a process for degreasing food and to a process for manufacturing the impregnated nonwoven.

Abstract: A method of making absorbent core systems for the construction of absorbent articles such as baby care, feminine hygiene or adult incontinence products. The method essentially replaces the traditional synthetic acrylic acid polymer-based hydrophilic material mixed with wood pulp fiber in the absorbent core with a safer, green, biodegradable plant-based material.

Abstract: Activated carbon is rendered more thermally stable by exposure to a non-halogenated additive, and optionally to a halogen and/or a halogen-containing compound. Such treated carbon is suitable for use in mitigating the content of hazardous substances in flue gases, especially flue gases having a temperature within the range of from about 100° C. to about 420° C.

Abstract: A hybrid composite of Metal Organic Frameworks (MOF) encapsulated in nanocarbon material, wherein the MOFs are grown inside or outside or both side of nano carbon morphologies of the hybrid composite. Such composites may be prepared by a. dissolving and mixing a salt of the metal and a ligand in the ratio ranging between 1:1 to 1:4 (by w/w ratio) by sonicating them to form a precursor mixture; b. adding non-functionalized or functionalized nano-carbon material to the precursor mixture of step (a); c. sonicating the mixture of step (b) followed by heating; d. keeping the slurry obtained at elevated temperature followed by centrifugation.

Abstract: This disclosure describes a method and apparatus for agglomerating stover to produce a liquid absorbing particle. The method comprises providing stover particles coated with a first binder component and then rolling the stover particles coated with the first binder component on a rotating surface. The rotating surface is inclined sufficiently to aid in the rolling of the stover particles. A second liquid binder component that readily chemically crosslinks with the first binder component is applied to the first binder component to produce a web that the stover particles adhere to. The web in combination with the inclined rotating surface rolls the stover particles thereby forming an agglomerated stover particle that will be suitable for absorbing liquids. Agglomerated stover particles are also described.

Abstract: Provided are a low-molecular-weight organic gas absorbent material including a porous material having an average pore size of 10 to 200 nm impregnated with one or more organic compounds having 10 or more carbon atoms in a proportion of 10 wt % or more based on the porous material, and a fuel vapor treatment apparatus for an internal combustion engine using this low-molecular-weight organic gas absorbent material. This low-molecular-weight organic gas absorbent material sufficiently absorbs and removes low-molecular-weight organic gases even for a porous material having large pores which cannot adsorb low-molecular-weight organic gases such as butane and the like.

Abstract: A system and method for systematically generating potential metal-organic framework (MOFs) structures given an input library of building blocks is provided herein. One or more material properties of the potential MOFs are evaluated using computational simulations. A range of material properties (surface area, pore volume, pore size distribution, powder x-ray diffraction pattern, methane adsorption capability, and the like) can be estimated, and in doing so, illuminate unidentified structure-property relationships that may only have been recognized by taking a global view of MOF structures. In addition to identifying structure-property relationships, this systematic approach to identify the MOFs of interest is used to identify one or more MOFs that may be useful for high pressure methane storage.

Abstract: An ionic compound is represented by formula (1): AM(OY1)(OY2)(OY3)(OY4). A is a group 1 element. M is a group 13 element. Y1 is one selected from an oligoalkylene ether group, an oligoalkylene thioether group, and an oligoalkylene amino group and includes an electron donating group on carbon that is located in one of ?-? positions with respect to oxygen atom adjacent to M. Y2, Y3, and Y4 are the same each other or different from each other or cross-linked to each other. Y2, Y3, and Y4 are each any one of an alkyl group, an alkyl group with a fluorinated terminal, an aryl group, and one selected from the group consisting of an oligoalkylene ether group, an oligoalkylene thioether group, and an oligoalkylene amino group and including an electron donating group on carbon that is located in one of ?-? positions with respect to oxygen atom adjacent to M.

Abstract: Disclosed herein is an radioisotope adsorbent including a bifunctional organosilane compound, including an organosiloxane functional group and a phosphate group, bonded on the surface of silica which is a bone structure of the adsorbent, and a method of preparing the radioisotope adsorbent, and a strontium/yttrium generator using the radioisotope adsorbent. Since the radioisotope adsorbent has a high adsorption capacity for 90Y such as 95% extraction efficiency or more from ICi 90Sr/90Y by using a column packed with 0.4 g of the adsorbent with a high-purity of 90Y, it can be usefully to be employed in the fields requiring 90Y.

Abstract: Superabsorbents comprising pyrogenic aluminum oxide exhibit a low caking tendency coupled with good absorption properties and rapid water absorption.

Abstract: A method of forming a zirconium-loaded fibrous adsorbent material having phosphoryl groups, the method including: grafting a reactive monomer having phosphoryl groups onto a polymeric substrate; and loading zirconium such that the zirconium-loaded fibrous adsorbent material has a zirconium content in an amount of 4.0 or 4.2 mmol/g.

Abstract: Novel chromatographic materials for chromatographic separations, columns, kits, and methods for preparation and separations with a superficially porous material comprising a substantially nonporous core and one or more layers of a porous shell material surrounding the core. The material of the invention is comprised of superficially porous particles and a narrow particle size distrution.

Abstract: A supported and sulphur-containing catalyst is described, comprising; a porous support constituted by an organic-inorganic hybrid material for which the covalent bond between the organic and inorganic phases conforms to the formula M-O—Z—R where M represents at least one metal constituting the inorganic phase, Z at least one heteroelement from among phosphorus and silicon and R an organic fragment, at least one metal of group VIB and/or of group VB and/or of group VIII. The invention also relates to the use of this catalyst for the hydrorefining and the hydroconversion of hydrocarbon-containing feedstocks such as petroleum fractions, fractions from coal or biomass or hydrocarbons produced from natural gas.

Abstract: By fibrillated cellulose fibrillated in fiber form and humidified as a water permeable polymeric substance of botanical origin and a radioactive-substance-absorbent obtained by mixing with zeolite as a granulated inorganic porous crystal, radioactive substances released and spilled in a accident etc. in a nuclear facility etc. may be efficiently and easily collected and removed at a low cost.

Abstract: The present invention is a process for making an inorganic/organic hybrid totally porous spherical silica particles by self assembly of surfactants that serve as organic templates via pseudomorphic transformation.

Abstract: The method of making an acid-absorbing biosolid composition provides a method for the use of recycled materials to produce an acid-absorbing composition that may then be recycled as a fertilizer after absorbing the acid. The method includes the steps of: collecting sewage sludge; drying the sewage sludge to remove water therefrom to form dried sludge; adding hydrochloric acid to the dried sludge to form a liquid intermediary product; heating the liquid intermediary product to produce a dried porous biomass; and mixing inorganic waste material with the dried porous biomass to produce the acid-absorbing biosolid composition. Thereafter, the acid-absorbing biosolid composition may be placed in a gas flow to absorb an acidic component therefrom; and then recycled for use as fertilizer following absorption of the acidic component from the gas flow.

Abstract: A method for removing at least one contaminant from a fluid stream includes filtering the fluid stream with a filtration medium. The filtration medium includes an impregnate. The impregnate includes an organic amine and an inorganic metal salt. The inorganic metal salt includes magnesium oxide, calcium oxide or combinations thereof. The medium has from about 0.1 to about 25% by weight of impregnate. The impregnate contains from about 0.1 to about 5% by weight organic amine, and the organic amine includes aqueous urea, solid urea, melamine or mixtures thereof. The impregnate contains from about 0.1 to about 5% by weight metal salt. The impregnate optionally further includes a surfactant such as polyacrylic acid. In some embodiments, the method includes removing at least two contaminants from the fluid stream.

Abstract: The present invention further relates to a process to make a superabsorbent polymer comprising the steps of a) preparing a neutralized monomer solution comprising a polymerizable monomer selected from unsaturated acid groups-containing monomers, ethylenically unsaturated carboxylic acid anhydride, salts, or derivatives thereof and a caustic agent selection from an alkali agent, wherein the polymerizable monomer is neutralized to from about 50 mol % to about 85 mol %; b) forming a crosslinker monomer mixture by adding an internal crosslinker composition to the neutralized monomer solution wherein the internal crosslinking composition is the reaction product of a stoichiometric excess of amine with a glycidyl compound, wherein the internal crosslinker composition has a residual amount of glycidyl compounds of less than about 500 ppm based on the mass of the internal crosslinker composition; and c) polymerizing the crosslinker monomer mixture to make a superabsorbent polymer.

Abstract: The subject invention pertains to metal organic frameworks (MOF) having zeolite-net-like topology, their methods of use, and their modes of synthesis. The ZMOFs are produced by combining predesigned tetrahedral building, generated in situ using heterochelation, with polyfunctional ligands that have the commensurate angle and the required donor groups for the chelation. Each molecular building block is contrasted of a single metal ion and ligands with both heterochelation functionality and bridging functionality. Advantageously, zeolite-net-like MOFs of the subject invention are porous and contain large functional cavities, which is useful for encapsulating large molecules.

Abstract: A porous polymer, poly-9,9?-spirobifluorene and its derivatives for storage of H2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO2/steam oxidation and supercritical water treatment.

Abstract: A porous structured organic film for storing gaseous a gaseous entity and method for storing gaseous entities in a porous structured organic film, the porous structured organic film including a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein at a macroscopic level the covalent organic framework is a film and contains a plurality of sites accessible to one or more gaseous entity.

Abstract: The invention relates to a monolithic porous material made of amorphous silica or activated alumina, comprising substantially rectilinear capillary channels that are parallel to one another, wherein: the channels have a substantially uniform cross-section relative to each other, the cross-section of each channel is regular over its entire length, the channels pass through the material from end to end, the length of the channels is equal to or more than 10 mm. The invention also relates to an annular, radial or axial chromatographic apparatus, the packing of which consists of at least one said monolithic material. The invention also relates to processes for manufacturing such a monolithic material.

Abstract: A method of forming functionalized fly ash particles includes contacting a plurality of fly ash particles with a hydroxide compound under conditions to directly bond oxygen (O) onto a surface portion of the plurality of fly ash particles. The plurality of fly ash particles having O directly bound to their surface portion are reacted with an organic alcohol or an organic acid to covalently bond hydrophobic groups in the form of condensation residue from the organic alcohol or organic acid to the O to form the plurality of functionalized fly ash particles.

Abstract: A radioactive iodine removal apparatus applying a radioactive iodine adsorbent according to an embodiment of the present invention includes an iodine filter that is provided in a chamber of a duct to which flue gas containing radioactive iodine is fed, and includes a radioactive iodine adsorbent that adsorbs radioactive iodine contained in the flue gas. The radioactive iodine adsorbent includes a carrier constituting a matrix and an impregnated substance with which the carrier is impregnated. The impregnated substance contains at least TEDA, and an impregnated amount of the TEDA is from 3.0% by mass to less than 10.0% by mass.

Abstract: Described herein is a low back-pressure, solid phase extraction media for removing dissolved metals in a liquid. The solid phase extraction media comprises particles entrapped in a porous polymeric fiber matrix. The particles comprise at least one of a thiol-containing moiety or a thiourea-containing moiety, and the porous polymeric fiber matrix comprises a plurality of fibers and a polymeric binder.