Including Pelletizing Or Briquetting And Subsequently Comminuting Patents (Class 502/428)
  • Patent number: 9006137
    Abstract: In at least one embodiment, a compressed gaseous fuel storage pellet is provided comprising a gas adsorbent material and a thermally conductive material extending substantially an entire dimension of the pellet and having a thermal conductivity of at least 75 W/mK. The pellet may include at least two layers of gas adsorbent material spaced apart along a compression direction of the pellet and a substantially continuous layer of the thermally conductive material disposed between the at least two layers of gas adsorbent material. The pellet may further include thermally conductive projections which intersect the layer(s) of thermally conductive material.
    Type: Grant
    Filed: May 13, 2013
    Date of Patent: April 14, 2015
    Assignee: Ford Global Technologies, LLC
    Inventors: Rachel Blaser, Michael J. Veenstra, Chunchuan Xu
  • Patent number: 8927103
    Abstract: A method produces activated carbon, suitable in particular for use in double-layer condensers. The method includes a) producing a mixture of a preferably pulverulent carbon material, a base and a hydrophilic polymer chemically inert to the base, b) pressing the mixture produced in step a) to form a pressing and c) activating the pressed body produced in step b).
    Type: Grant
    Filed: September 7, 2012
    Date of Patent: January 6, 2015
    Assignee: SGL Carbon SE
    Inventors: Thomas Kirschbaum, Astrid Rota
  • Patent number: 8236275
    Abstract: Provided is a production process for a carbon material comprising an alkali activation reaction step in which a carbon precursor containing an activator selected from alkali metal compounds is heated under flow of inert gas. The above alkali activation reaction is carried out while allowing carbon dioxide gas to flow into a downstream part of an alkali activation reaction region on the condition that the carbon dioxide gas is not substantially brought into contact with the carbon precursor and the activator. This makes it possible to carry out alkali activation treatment safely and stably and obtain a carbon material useful for producing an electric double layer capacitor electrode having a high electrostatic capacity.
    Type: Grant
    Filed: April 27, 2006
    Date of Patent: August 7, 2012
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takuo Ohshida, Koichi Kanno
  • Patent number: 7759289
    Abstract: In activated carbon obtained by subjecting a carbonaceous material to an activation treatment, the overall content of alkali metals is set at 100 ppm or less, or the overall content of heavy metals is set at 20 ppm or less and the overall content of alkali metals is set at 200 ppm or less. In cases where such activated carbon is used as a raw material in electronic devices, the formation of dendrites by the reductive deposition of alkali metals or heavy metals tends not to occur, so that problems such as short-circuiting or the like tend not to arise, and a good rate of self-discharge retention is shown.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: July 20, 2010
    Assignees: Kuraray Chemical Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Hideharu Iwasaki, Nozomu Sugo, Mitsunori Hitomi, Shushi Nishimura, Takeshi Fujino, Shigeki Oyama, Yuji Kawabuchi
  • Patent number: 6962616
    Abstract: A method of making an adsorbent which includes: a) thermally drying dewatered sewage sludge to form granulated organic fertilizer; b) treating the fertilizer with mineral oil; and c) pyrolyzing the treated fertilizer at temperatures between about 600° C. and about 1000° C. The disclosure is also directed to adsorbents made by this method and to the processes of removing acidic gas or gases from wet gas streams by putting an adsorbent in contact with the wet gas stream and allowing the adsorbent to adsorb the acidic gas or gases.
    Type: Grant
    Filed: August 8, 2003
    Date of Patent: November 8, 2005
    Assignee: Research Foundation of The City University of New York
    Inventors: Teresa J. Bandosz, Andriy Bahryeyev
  • Patent number: 6914034
    Abstract: Adsorbents for removing anions of a heavy metals comprise a porous carbon in which at least one oxygen-containing compound of iron, copper, and/or aluminum is incorporated. The oxygen-containing compound may be incorporated into the porous carbon by impregnation or dispersion of a suitable precursor of such a compound. The precursor may be further treated to yield the oxygen-containing compound. Such adsorbents are particularly useful for removing arsenic and/or selenium from the environment and may be used in treating drinking water sources.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: July 5, 2005
    Assignee: Calgon Carbon Corporation
    Inventor: Toan Phan Vo
  • Patent number: 6902589
    Abstract: The invention relates to a method for producing shaped, activated charcoal. According to the method, after being ground, carbon-bearing material, or a mixture of several carbon-bearing materials are rendered homogenous with a binding agent which contains water, or a mixture of several binding agents, at least one of which contains water. The mixture of carbon-bearing material and binding agent is then formed into shaped bodies. According to the invention, in order to consolidate the grain formation, these are dried until they exhibit a maximum total water content of 3% by wt. in relation to the shaped body. The shaped bodies which have been formed and dried in this manner are then subjected to a carbonization and subsequently a gas activation process.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: June 7, 2005
    Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.
    Inventors: Joachim Guderian, Volker Heil, Christian Horn, Michael Feseker, Jens Sohnemann
  • Patent number: 6391429
    Abstract: A fluid permeable composite structure having active particulate bonded together using a pressure-sensitive adhesive (PSA) polymer microparticulate. Use of the PSA polymer microparticulate to bond the active particulate together produces a bonded structure that, unlike previously-developed active bonded structures, is flexible and therefore can be conformed into a variety of shapes. The shaped structures may be used as gaseous filters in a wide variety of respirators.
    Type: Grant
    Filed: January 9, 1997
    Date of Patent: May 21, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Raymond Senkus, Chung I. Young, Leonard W. Barrett, Ying-Yuh Lu
  • Patent number: 6113673
    Abstract: This invention is directed to the synthesis of high bulk density high gas absorption capacity adsorbents for gas storage applications. Specifically, this invention is concerned with novel gas absorbents with high gravimetric and volumetric gas adsorption capacities which are made from fullerene-based materials. By pressing fullerene powder into pellet form using a conventional press, then polymerizing it by subjecting the fullerene to high temperature and high inert gas pressure, the resulting fullerene-based materials have high bulk densities and high gas adsorption capacities. By pre-chemical modification or post-polymerization activation processes, the gas adsorption capacities of the fullerene-based adsorbents can be further enhanced. These materials are suitable for low pressure gas storage applications, such as oxygen storage for home oxygen therapy uses or on-board vehicle natural gas storage.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: September 5, 2000
    Assignee: Materials and Electrochemical Research (MER) Corporation
    Inventors: Raouf O. Loutfy, Xiao-Chun Lu, Weijiong Li, Michael G. Mikhael
  • Patent number: 6060424
    Abstract: The present invention relates to carbon and methods for preparing same. In particular, this invention relates to the preparation of novel carbons derived from lignocellulosic materials (particularly wood-based lignocellulosic materials) which are useful for producing high energy density double layer energy storage devices.
    Type: Grant
    Filed: January 26, 1999
    Date of Patent: May 9, 2000
    Assignee: Westvaco Corporation
    Inventor: John A. Alford
  • Patent number: 6043183
    Abstract: The present invention relates to carbon and methods for preparing same. In particular, this invention relates to the preparation of novel carbons derived from lignocellulosic materials (particularly wood-based lignocellulosic materials) which are useful for producing high power density double layer energy storage devices.
    Type: Grant
    Filed: June 23, 1997
    Date of Patent: March 28, 2000
    Assignee: Westvaco Corporation
    Inventor: John A. Alford
  • Patent number: 6033573
    Abstract: Activated carbons derived from nutshells, and for use in adsorption of metallic cations, are prepared utilizing phosphoric acid activation with concurrent oxidation under air. The acid activation is carried out utilizing a one or two-step heating regime subsequent to the infusion of the phosphoric acid into the nutshell material during which concurrent oxidation is achieved by exposure to atmospheric oxygen. Further oxidation is optionally achieved by equilibration of the nutshell carbons to room temperature under air. Prior to utilization, a washing step is employed to remove unwanted acid from the carbon product.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: March 7, 2000
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: Christopher A. Toles, Wayne E. Marshall, Mitchell M. Johns
  • Patent number: 6030922
    Abstract: The synthesis of carbon, particularly in an activated form, from sludge materials such as composed of biosolids and the like is described wherein the treated material is subjected to processing including chemical activation, light and humidity treatment, pyrolysis and physical activation to result in an activated carbon of high surface area and microporosity.
    Type: Grant
    Filed: July 10, 1998
    Date of Patent: February 29, 2000
    Assignee: Illinois Institute of Technology
    Inventors: Nasrin R. Khalili, Hamid Arastoopour, Laura K. Walhof
  • Patent number: 5880061
    Abstract: Active carbon having a pore size distribution obtained from a nitrogen adsorption isothermal line such that the volume of pores having a pore diameter of less than 15 .ANG. is at least 0.25 ml/g and constitutes at least 40% of the total volume of pores having a pore diameter of at most 300 .ANG., and the volume of pores having a pore diameter of from 100 to 300 .ANG. constitutes at least 10% of the total volume of pores having a pore diameter of at most 300 .ANG..
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: March 9, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yoshio Yoshino, Atsushi Matsumoto, Kimitoshi Ohishi, Akihide Yoshida
  • Patent number: 5736481
    Abstract: Extruded pellets comprising a majority of activated carbon particles and an organic binder provide improved performance when processed through tumbling equipment while the pellets are in their "green" state, i.e., pellets which are fresh off the extruder and contain activated carbon, binder, and water and have not been subjected to any thermal processing (drying). The tumbling action both smoothes the pellets (by closing any cracks and greatly improving appearance) and increases the density of the pellets, e.g., by increasing particle density and reducing voids between the pellets. Improved performance results from an ability to increase the weight of carbon pellets which can be packed into a fixed volume and thereby increase the volumetric working capacity of the bed for adsorbing/desorbing vapors. Another benefit is to greatly reduce the levels of dust associated with the carbon, both the initial dust and the dust of attrition.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: April 7, 1998
    Assignee: Westvaco Corporation
    Inventor: James R. Miller
  • Patent number: 5736485
    Abstract: Extruded pellets comprising a majority of activated carbon particles and an organic binder provide improved performance when processed through tumbling equipment while the pellets are in their "green" state, i.e., pellets which are fresh off the extruder and contain activated carbon, binder, and water and have not been subjected to any thermal processing (drying). The tumbling action both smoothes the pellets (by closing any cracks and greatly improving appearance) and increases the density of the packed bed, e.g., by increasing particle density and reducing voids between the pellets. Improved performance results from an ability to increase the weight of carbon pellets which can be packed into a fixed volume and thereby increase the volumetric working capacity of the bed for adsorbing/desorbing vapors. Another benefit is to greatly reduce the levels of dust associated with the carbon, both the initial dust and the dust attrition.
    Type: Grant
    Filed: September 19, 1996
    Date of Patent: April 7, 1998
    Assignee: Westvaco Corporation
    Inventor: James R. Miller
  • Patent number: 5703003
    Abstract: Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.
    Type: Grant
    Filed: November 1, 1995
    Date of Patent: December 30, 1997
    Assignee: United States Department of Energy
    Inventor: Ranjani V. Siriwardane
  • Patent number: 5691270
    Abstract: Extruded pellets comprising a majority of activated carbon particles and a minority of a binder material are disclosed to provide improved performance when processed through tumbling equipment while the pellets are in their "green" state (i.e., pellets which are fresh off the extruder and contain activated carbon), binder material, and water and have not been subjected to any thermal processing (drying or calcining). The tumbling action both smooths and densifies (i.e., reduces void volume within) the pellet, thereby closing any cracks and greatly improving appearance. Improved performance results from an ability to increase the weight of carbon pellets which can be packed into a fixed volume and thereby increase the volumetric working capacity of the bed for adsorbing/desorbing vapors. Another benefit is to greatly reduce the levels of dust associated with the carbon, both the initial dust and the dust attrition.
    Type: Grant
    Filed: March 8, 1996
    Date of Patent: November 25, 1997
    Assignee: Westvaco Corporation
    Inventor: James R. Miller
  • Patent number: 5494880
    Abstract: Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.
    Type: Grant
    Filed: March 23, 1994
    Date of Patent: February 27, 1996
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Ranjani V. Siriwardane
  • Patent number: 5276000
    Abstract: Lignocellulosic carbonaceous material is activated to produce a high activity, high density gas-phase activated carbon under conditions which effectively alter the particle pore volume size distribution to optimize the carbon's mesoporosity. An improved process is disclosed for producing the carbon, as are its application in emission control for vehicles.
    Type: Grant
    Filed: October 28, 1992
    Date of Patent: January 4, 1994
    Assignee: Westvaco Corporation
    Inventors: Charles C. Matthews, Edward D. Tolles
  • Patent number: 5272126
    Abstract: An adsorption type packing for gas chromatography composed of finely divided carbon particles in whole, and having a ratio of nitrogen gas adsorption at a relative pressure of 0.3 (V.sub.0.3) to nitrogen gas adsorption at a relative pressure of about 1.0 (V.sub.1.0) each in the adsorption isotherm of said packing, V.sub.0.3 /V.sub.1.0, of 0.9 or more and a BET specific surface area of 1,000 to 2,000 m.sup.2 /g; and a process for producing said packing.
    Type: Grant
    Filed: April 8, 1992
    Date of Patent: December 21, 1993
    Assignees: Nippon Carbon Co., Ltd., Shinwa Chemical Industries, Ltd.
    Inventors: Hiroshi Ichikawa, Akira Yokoyama, Keiichi Hirata