Abstract: A method of selecting an appropriate resin bonded sorbent composition which may be used at least for in part making an enclosure to protect contents from external humidity including the steps of: a) selecting a plurality of resins, a plurality of sorbents and a plurality of ratios therebetween to form a plurality of composites; b) calculating a plurality of failure times for the plurality of composites, wherein each failure time of the plurality of failure times is based on when an internal relative humidity of each composite of the plurality of composites is equal to the maximum internal relative humidity; c) determining which of the plurality of failure times is greater; and, d) selecting one composite of the plurality of composites based on the result of step (c).

Abstract: A pyrolyzed monolith carbon physical adsorbent that is characterized by at least one of the following characteristics: (a) a fill density measured for arsine gas at 25° C. and pressure of 650 torr that is greater than 400 grams arsine per liter of adsorbent; (b) at least 30% of overall porosity of the adsorbent including slit-shaped pores having a size in a range of from about 0.3 to about 0.72 nanometer, and at least 20% of the overall porosity including micropores of diameter<2 nanometers; and (c) having a bulk density of from about 0.80 to about 2.0 grams per cubic centimeter, preferably from 0.9 to 2.0 grams per cubic centimeter.

Abstract: A hydrogen storage system for storing hydrogen gas at elevated pressures and cryogenic temperatures is disclosed. The hydrogen gas is fed to a storage container which contains a physisorption type material and a volatile liquid container for liquid nitrogen. Cryogenic conditions are maintained within the storage container during the periods of storage and the periods where the hydrogen gas is removed from the storage system.

Abstract: Disclosed herein is a hydrogen storage material comprising a metal hydride and an organic hydrogen carrier. Also disclosed herein is a hydrogen storage/fuel cell system which employs the hydrogen storage material.

Abstract: Disclosed herein are metal-organic frameworks of metals and boron rich ligands, such as carboranes and icosahedral boranes. Methods of synthesizing and using these materials in gas uptake are disclosed.

Abstract: The present invention relates to zeolitic compositions of at least one A, X, Y zeolite and/or chabazite and at least one clinoptilolite type of zeolite. These zeolitic compositions can be used in adsorption methods for removing H2O and/or CO2 and/or H2S present in gas or liquid mixtures, particularly for purifying natural gas, acid gases, alcohols and mercaptans.

Abstract: Method and apparatus for storing hydrogen. One embodiment of such a method comprises providing a storage apparatus having a substrate and a nanostructure mat on at least a portion of a side of the substrate. The nanostructure mat comprises a plurality of nanostructures having a surface ionization state which causes more than one layer of hydrogen to adsorb onto the nanostructures. The method can also include exposing the nanostructure mat to hydrogen such that more than one layer of hydrogen adsorbs onto the nanostructures.

Abstract: A composition and method of storing and releasing fuel gas such as hydrogen, methane or natural gas is provided which utilizes lightly crosslinked high density polyethylene pellets. Fuel gas is stored by placing the pellets in a reaction chamber which is heated to a temperature slightly above the crystalline melting point of the pellets, followed by the introduction of fuel gas into the chamber. The fuel gas permeates the pellets and becomes contained therein upon cooling of the pellets under pressure. The fuel gas may be stored indefinitely in the pellets at ambient temperature. When release of the fuel gas is desired, the pellets are incrementally metered into a discharge chamber and are heated to a temperature above the crystalline melting point of the pellets under a pressure from about 5 to 200 psi such that the fuel gas is released from the pellets for use. The expended pellets may then be recycled for further fuel gas storage.

Abstract: Disclosed herein is a transition metal-substituted hydrotalcite catalyst for removing nitrogen oxides using a storage-reduction method, in which a molar ratio of transition metal to magnesium is 0.2 or less, and a method of manufacturing a transition metal-substituted hydrotalcite catalyst for removing nitrogen oxides using a storage-reduction method, including the steps of preparing a hydrotalcite synthesis solution including transition metal precursors such that the molar ratio of transition metal to magnesium is 0.2 or less, and preferably 0.001 to 0.2; aging the synthesis solution; and hydrothermally treating the synthesis solution.

Abstract: A process for producing borazane from boron-nitrogen and boron-nitrogen-hydrogen containing BNH-waste products. The process includes reacting the BNH-waste products with a hydrogen halide, having the formula HX, wherein X is selected from the group consisting of F, Cl, Br, I, and combinations thereof, to form any of the following: a boron trihalide, having the formula BX3, an ammonium halide, having the formula NH4X, and hydrogen. The boron trihalide is then reacted with the hydrogen to form diborane, having the formula B2H6, and hydrogen halide. The ammonium halide is then converted to ammonia, having the formula NH3, and hydrogen halide. The diborane is then reacted with the ammonia to form borazane, having the formula BH3NH3.

Abstract: A composition for decontaminating a highly toxic material, wherein the composition includes a modified reactive sorbent comprising a reactive sorbent in combination with a sufficient amount of an organic solvent to saturate the pores of the reactive sorbent to yield a non-slurry, free flowing mixture. The present invention is further directed to a method for making such compositions and method for decontaminating surfaces using such compositions.

Abstract: There is disclosed a multi-metal-nitrogen compound for use in hydrogen storage materials. The compound comprising two dissimilar metal atoms and a nitrogen atom. The multi-metal-nitrogen compound being capable of absorbing hydrogen at an absorption temperature and pressure, and of desorbing 60% or more by weight of said absorbed hydrogen at a desorption temperature and pressure.

Abstract: A hydrogen accumulation and storage material and a method of forming thereof are provided. The material comprises a plurality of various-sized and at least partially permeable to hydrogen microspheres bound together to form a rigid structure in which a diameter of the microspheres is reduced from a center of the structure towards edges of the structure. An outer surface of the rigid structure can be enveloped by a sealing layer, thereby closing interspherical spaces.

Abstract: A gas storage system that stores a gas by cryo-adsorption on high surface materials. The gas storage system includes an outer container having insulated walls and a plurality of pressure vessels disposed therein. Each of the pressure vessels includes a high surface material. A manifold assembly distributes the gas under pressure to the pressure vessels where the gas is adsorbed by cryo-adsorption using the high surface materials. A cooling fluid is provided within voids between the pressure vessels to remove heat as the pressure vessels are being filled with the gas.

Abstract: The present invention relates to a method of absorbing and/or storing gases, in which the gas to be stored is brought into contact with an electrochemically prepared metal-organic framework under conditions suitable for absorption of the gas, with absorption of the gas into the metal-organic framework occurring, and, if appropriate, the conditions are subsequently changed so that release of the stored gas occurs.

Abstract: The present invention relates to a gas storage and dispensing system, which comprising a carrier material for a target gas and multiple microtubular elements in contact with such carrier material. Each microtubular element comprises a tubular wall that defines a bore side and a shell side that are sealed from each other, preferably by one or more potting members. The carrier material is either at the bore sides or at the shell sides of the microtubular elements, and it can be either a solid sorbent material for the target gas, or a liquid carrier therefor. Such gas storage and dispensing system is particular useful for hydrogen storage, when the carrier material can be a hydrogen-sorbent that contains hydrogen gas, or liquefied hydrogen, or an organic hydrogen solution, or a metal hydride solution capable of generating hydrogen gas. Such microtubular elements can further be designed as microfibrous fuel cells, while each microfibrous fuel cell comprises a carrier material at its bore side.

Abstract: A fluid storage and dispensing apparatus, including a cylindrical fluid storage and dispensing vessel having an interior volume, in which the interior volume contains a physical adsorbent for sorptively retaining a fluid thereon and from which the fluid is desorbable for dispensing from the vessel, and a valve head coupled to the vessel for dispensing desorbed fluid from the vessel. The physical adsorbent includes a monolithic carbon physical adsorbent that is characterized by at least one of the following characteristics: (a) a fill density measured for arsine gas at 25° C. and pressure of 650 torr that is greater than 400 grams arsine per liter of adsorbent; (b) at least 30% of overall porosity of the adsorbent including slit-shaped pores having a size in a range of from about 0.3 to about 0.72 nanometer, and at least 20% of the overall porosity including micropores of diameter <2 nanometers; and (c) having a bulk density of from about 0.80 to about 2.0 grams per cubic centimeter.

Abstract: A gas storage assembly that has an enclosure within which are disposed at least about 100 inorganic tubules are present for each cubic micron of volume of the enclosure. The assembly has a storage capacity of at least 20 grams of hydrogen per liter of volume of the enclosure.

Abstract: A hydrogen storage tank comprises a hydrogen adsorbent accommodated in a pressure-resistant container. The hydrogen adsorbent is capable of adsorbing and retaining hydrogen gas of a volume exceeding an occupation volume occupied by the hydrogen adsorbent itself. As for the hydrogen adsorbent, the amount of endothermic heat, which is generated when the adsorbed hydrogen gas is released, is not more than 16 kJ per mol of hydrogen molecules. The hydrogen adsorbent is prevented from leaking outside of the pressure-resistant container by a filter.

Abstract: Disclosed in this specification is an apparatus for storing hydrogen which is comprised of molecular hydrogen, halloysite rods, and a supporting substrate wherein hydrogen is stored within the lumen of the halloysite rods.

Abstract: An appliance that uses a substantially carbon-free hydrogen is disclosed. The appliance includes a converter, a hydrogen storage container including a carbon-based nanostructured material, a charger, a discharger and, optionally, a controller is disclosed. The hydrogen storage container is capable of storing the substantially carbon-free hydrogen in a condensed state. In addition to the carbon-based nanostructured material, the container may include a metal capable of acting as both a seed for the formation of the nanostructured material and a facilitator for promoting the storage in the condensed state of the substantially carbon-free gaseous hydrogen provided to the storage container.

Abstract: A hydrogen storage and release material is provided in the form of a supportive host component that carries or contains a hydrogen absorbing guest material. Metal compounds, such as oxides, carbides, nitrides, or the like, are prepared to carry polyaromatic molecules that absorb hydrogen in conjugated double bonds. Examples of suitable guest-host materials include layers of vanadium oxide with interacted layers of polyaniline or polythiophene. Dopant elements, like nickel, in the host oxide can enhance hydrogen absorption and de-sorption in the host material.

Abstract: A hybrid hydrogen storage composition includes a first phase and a second phase adsorbed on the first phase, the first phase including BN for storing hydrogen by physisorption and the second phase including a borazane-borazine system for storing hydrogen in combined form as a hydride.

Abstract: The present invention relates to new crystalline molecular sieve SSZ-74 prepared using a hexamethylene-1,6-bis-(N-methyl-N-pyrrolidinium) dication as a structure-directing agent, and its use in gas separations.

Abstract: A container for uptaking, or storing, or releasing, or uptaking and storing, or uptaking and releasing, or storing and releasing, or uptaking, storing and releasing at least one gas, comprising a metal-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound which is bound to said metal ion, as well as to a fuel cell comprising said container, and to a method of using said container or said fuel cell for supplying power to power plants, cars, trucks, busses, cell phones, and laptops.

Abstract: A system for hydrogen storage comprising a porous nano-structured material with hydrogen absorbed on the surfaces of the porous nano-structured material. The system of hydrogen storage comprises absorbing hydrogen on the surfaces of a porous nano-structured semiconductor material.

Abstract: An organic compound capable of forming a hydrogen molecular compound such as a hydrogen clathrate is brought in contact with hydrogen gas in a pressurized state. It enables relatively light-weight and stable storage of hydrogen at or near the ordinary temperature and the ambient pressure and easy takeoff of the stored hydrogen.

Abstract: Polymer particles are irradiated with radiation from a high energy source to increase the water or other fluid absorbency of the particles. Products manufactured using the activated particles include protective undergarments, bandages, kitty litter, and spill clean up materials.

Abstract: A storage medium for gas molecules has a nanowire core and a number of organic molecules attached to the exterior surface of the nanowire. The organic molecules attached to the exterior of the nanowire are adapted to releasably hold gas molecules. Methods for making and using the invention, including the use of a silicon nanowire, are disclosed.

Abstract: The present invention involves a carbon-based hydrogen storage material which includes a carbon material, exhibiting a specific surface area, being 1,000 m2/g or more, and a bulk density, being from 0.4 g/cm3 or more to 1 g/cm3 or less. The carbon-based hydrogen storage material is such that the hydrogen storage capacity per unit volume is large. The invention also provides for a hydrogen storage apparatus whose hydrogen storage capacity per unit volume is large. The hydrogen storage apparatus is constituted so as to include a container and a hydrogen absorbing material accommodated in the container, and the hydrogen absorbing material is arranged to include a porous carbon material whose specific surface area is 1,000 m2/g or more, and a hydrogen absorbing alloy.

Abstract: A fluid storage and delivery system utilizing a porous metal matrix that comprises at least one Group VIIIB metal therein. In one embodiment, the porous metal matrix forms a solid-phase metal adsorbent medium, with an average pore diameter of from about 0.5 nm to about 2 nm and a porosity of from about 10% to about 30%, which is particularly useful for sorptively storing and desorptively dispensing a low vapor pressure fluid, e.g., ClF3, HF, GeF4, Br2, etc. In another aspect, the porous metal matrix forms a solid-phase metal sorbent with an average pore diameter of from about 0.25 ?m to about 500 ?m and a porosity of from about 15% to about 95%, which can effectively immobilize low vapor pressure liquefied gas.

Abstract: The present invention is directed to a process for the preparation of crystalline anionic clay-containing bodies from sources comprising a trivalent metal source and a divalent metal source comprising the steps of: a) preparing a precursor mixture containing a liquid, a divalent metal source and/or a trivalent metal source, at least one of them being insoluble in the liquid; b) shaping the precursor mixture to obtain shaped bodies; c) optionally thermally treating the shaped bodies; and d) aging the shaped bodies to obtain crystalline anionic clay-containing bodies; with the proviso that if no divalent or trivalent metal source is present in the precursor mixture of step a), such source is added to the shaped bodies after shaping step b) and before aging step d); and with the further proviso that the combined use of an aluminium source as the trivalent metal source and a magnesium source as the divalent metal source is excluded.

Abstract: The present invention relates to the technical field of storing gas including methane and hydrogen, in particular to the fuel cell technology. In particulars it relates to a method of using a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound.

Abstract: A system and method for sorption and desorption of molecular gas contained by storage sites of graphite nano-filaments randomly disposed in three-dimensional reticulated aerogel.

Abstract: A personal care absorbent article, such as a sanitary pad or napkin, wound dressing, and the like having one or more layers of absorbent material treated with a red blood cell lysing agent and a gelling agent. The effect of combining a lysing agent that thins menses or other blood-containing bodily fluids with a gelling agent that thickens menses or other blood-containing bodily fluids is enhanced agglomeration and increased viscosity of the blood-containing bodily fluids that come in contact with the treated material.

Abstract: Carbon fiber including graphitized fiber is processed electrochemically in an acidic solution for a time sufficient to run a layer reaction such that the reaction extends to the inside of the fiber and thereafter, as required, heat-treated accurately at 100° C. or more to expand layer spacing to form multifibrous carbon fiber, with which hydrogen is brought into contact, adsorbing hydrogen in the inside of the multifibrous carbon fiber.

Abstract: A method for producing high capacity gas-storage microporous sorbents involves precursor carbonization under relatively severe heat-treatment conditions, normally followed by activation using a cyclic chemisorption-desorption process.

Abstract: The invention relates to a fluid storage and delivery system utilizing a porous metal matrix that comprises at least one Group VIII metal or Group IB metal therein. In one aspect of the invention, such porous metal matrix forms a solid-phase metal adsorbent medium, characterized by an average pore diameter of from about 0.5 nm to about 2.0 nm and a porosity of from about 10% to about 30%. Such solid-phase metal adsorbent medium is particularly useful for sorptively storing and desoprotively dispensing a low vapor pressure fluid, e.g., ClF3, HF, GeF4, Br2, etc. In another aspect of the invention, such porous metal matrix forms a solid-phase metal sorbent, characterized by an average pore diameter of from about 0.25 &mgr;m to about 500 &mgr;m and a porosity of from about 15% to about 95%, which can effectively immobilize low vapor pressure liquefied gas.

Abstract: A method for storing natural gas by adsorption which comprises separating an available natural gas in an infrastructure side (10) into a low carbon number component mainly containing methane and ethane and a high carbon number component mainly containing propane, butane and the like, and storing the low carbon number component by adsorption in a first adsorption tank (16) and storing the high carbon number component by adsorption in a second adsorption tank (18). The method can solve the problem that the high carbon number component condenses within a pore of an adsorbing agent and hence the adsorption of the carbon number component, the main component of natural gas, is inhibited, and thus improves the storage density. Accordingly, the method can be used for ensuring a high storage density also for an available natural gas. An adsorbing agent for use in the method is also disclosed.

Abstract: Herein is disclosed an oxygen scavenging composition, comprising (i) an oxygen scavenging polymer comprising units having structure I: 1

Abstract: A personal care absorbent article, such as a sanitary pad or napkin, wound dressing, and the like having one or more layers of absorbent material treated with a red blood cell lysing agent and a gelling agent. The effect of combining a lysing agent that thins menses or other blood-containing bodily fluids with a gelling agent that thickens menses or other blood-containing bodily fluids is enhanced agglomeration and increased viscosity of the blood-containing bodily fluids that come in contact with the treated material.

Abstract: A channelized sorbent material comprises porous sorbent particles characterized by an average pore diameter. Each sorbent particle has at least one interior channel of an average transverse dimension (i.e. transverse diameter) that is at least ten times larger than the average pore diameter of the porous sorbent particle. The interior channel may constitute a single cylindrical through-bore in the sorbent particle, or alternatively, an array of intersecting or non-intersecting channels. The porous sorbent particles preferably comprise bead activated carbon particles. Such channelized sorbent material is particular useful as sorbent media in an adsorption-desorption apparatus for storage and dispensing of a sorbable fluid.

Abstract: In a method for storing hydrogen in a carbon material containing microstructures in the form of cones with cone angles being multiples of 60°, the carbon material is introduced in a reaction vessel which is evacuated while the carbon material is kept at a temperature of 295-800 K, after which pure hydrogen gas is introduced in the reaction vessel, the carbon material being exposed to a hydrogen gas pressure in the range of 300-7600 torr such that the hydrogen gas is absorbed in the carbon material, and after which the reaction vessel is left at the ambient temperature with the carbon material under a fixed hydrogen gas pressure. For use the hydrogen is released in the form of a gas from the carbon material either at ambient temperature or by heating the carbon material in the reaction vessel.

Abstract: A gas separator includes a porous substrate having fine pores opened on its surface and a metal for separating a gas, the porous substrate having fine pores having an average diameter of 0.1-3.0 .mu.m and a porosity of 25-45%, and the metal for separating a gas being filled into the pores in the porous substrate to close them. A gas separation film seldom exfoliates from the porous substrate, and the gas separator is excellent in durability in comparison with a conventional gas separator.

Abstract: The present invention is a hydrogen getter and method for formulating and using the getter. This getter effectively removes hydrogen gas typically present in many hermetically-sealed electronic applications where the presence of such gas would otherwise be harmful to the electronics. The getter is a non-organic composition, usable in a wide range of temperatures as compared to organic getters. Moreover, the getter is formulated to be used without the need for the presence of oxygen. The getter is comprised of effective amounts of an oxide of a platinum group metal, a desiccant, and a gas permeable binder which preferably is cured after composition in an oxygen-bearing environment at about 150 to about 205 degrees centigrade.

Abstract: A method of making a microporous carbon material which includes providing a precursor selected from the group consisting of crystalline salts of aromatic sulfonates and nonporous polymeric salts. Prior to carbonization, the precursor is treated by ion exchange or other conventional processes to introduce a metal such as iron, nickel and cobalt into the precursor. Heat treatment of such composite precursors in the temperature range of 350.degree. to 850.degree. C. in an inert oxygen free atmosphere for a sufficient time promotes thermally induced hydrogen abstraction and rearrangement of BSUs which result in the formation of a composite, carbonaceous microporous material which contains a metal component, and has a pore size distribution in the range of about 4-15 .ANG. A. The structural and storage characteristics of the microporous carbon materials are also disclosed.

Abstract: A highly microporous adsorbent material is formed as a composite of a natural or synthetic clay or clay-like mineral matrix intercalated with an active carbon. The mineral is prepared and selected to have a selected interlayer spacing between microcrystalline sheets. An organic polymeric precursor is contacted therewith to fill the matrix interstices. Then the precursor is polymerized and carbonized to yield the adsorbent material in which the carbon is intercalated into the mineral matrix. The mineral can be naturally occurring smectite or synthetic hydrotalcite.

Abstract: A halogenated or sulfonated active carbon which has a high storage capacity for methane is provided from selected halogens in elemental form or solutions of such halogens or from solutions of sulfuric acid, fuming sulfuric acid, sulfur trioxide.

Abstract: Natural gas is stored in a closed vessel under a pressure of about 1400 to 4500 kPa using a carbon molecular sieve adsorbent. The deliverable volume of natural gas from a vessel packed with carbon molecular sieve particles is increased by raising the density of the polymer precursor of the carbon molecular sieve through adjustment of the conditions for suspension polymerization of vinylidene chloride.

Abstract: Natural gas is stored in a closed vessel under a pressure of about 1400 to 4500 kPa using a carbon molecular sieve adsorbent. The deliverable volume of natural gas from a vessel packed with carbon molecular sieve particles is increased by impregnating a polymer precursor of the carbon molecular sieve with additional monomers and polymerizing the monomers before carbonizing the precursor.