With Control Of Oxygen Content In Oxidation Gas Patents (Class 502/52)
  • Patent number: 4542114
    Abstract: A unique process arrangement is disclosed wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by combustion in a mixture of pure oxygen diluted with carbon dioxide is processed to provide a carbon dioxide-rich recycle gas stream to be mixed with oxygen as regenerator feed gas; and a net combustion product stream from which are recovered SO.sub.x and NO.sub.x to eliminate atmospheric emissions, and a pure CO.sub.2 product for export. An alternate embodiment also produces hydrogen or synthesis gas for export.
    Type: Grant
    Filed: April 13, 1984
    Date of Patent: September 17, 1985
    Assignee: Air Products and Chemicals, Inc.
    Inventor: William P. Hegarty
  • Patent number: 4507397
    Abstract: The process of oxidatively regenerating in situ a fixed bed hydrocarbon catalyst which is sensitive to reactive sulfur compounds in a conversion system having sulfur-contaminated vessels and/or conduits in the flow path upstream from said catalyst is improved by passing regenerating oxygen-containing gas first through the sulfur-contaminated vessels and/or conduits and then through the fixed catalyst bed while limiting the water content of the regenerating gas to a concentration of not more than 0.1 mol percent throughout the flow path and at a temperature in the range of 750.degree.-1100.degree. F. to oxidize the sulfur contaminants in the vessels and/or conduits upstream from the catalyst. Thereby the evolved sulfur oxides flow through the fixed bed catalyst in the absence of sufficient water which would promote reaction of sulfur oxides with the catalyst.
    Type: Grant
    Filed: July 28, 1983
    Date of Patent: March 26, 1985
    Assignee: Chevron Research Company
    Inventor: Waldeen C. Buss
  • Patent number: 4482637
    Abstract: A method is disclosed for regenerating reforming catalysts containing a platinum group component and/or rhenium component in association with a halogen component on a porous inorganic oxide, such as one containing alumina without significant displacement of the rhenium components by sulfur oxides generated during the regeneration process. The method is particularly characterized in that carbon is removed from the catalyst by in situ oxidation at temperatures not in excess of about 750.degree. F. and without modification of the catalytic reforming process flow circuit, as by disconnecting or isolating the heat exchangers and furnace tubes.Sulfide scale is converted in a separate oxidation step to sulfur dioxide, SO.sub.2, without substantial oxidation to sulfur trioxide, SO.sub.3, by maintaining the inner walls of the heat exchangers and furnace tubes, where such iron sulfides are present, at a temperature not in excess of about 900.degree. F. and not less than about 750.degree. F.
    Type: Grant
    Filed: August 4, 1982
    Date of Patent: November 13, 1984
    Assignee: Chevron Research Company
    Inventors: Waldeen C. Buss, Thomas R. Hughes
  • Patent number: 4480144
    Abstract: Regeneration of an aromatics processing catalyst is effected in the absence of a gas cooler and a gas-liquid separator with a continuous loop flow of an oxidizing gas stream by removing a portion of said continuous closed loop flow and introducing therein a quantity of a low moisture content molecular oxygen containing gas effective to maintain a molecular oxygen content no greater than 1.0 mole percent and a water partial pressure no greater than about 1.0 psi.
    Type: Grant
    Filed: August 6, 1981
    Date of Patent: October 30, 1984
    Assignee: Mobil Oil Corporation
    Inventor: Fritz A. Smith
  • Patent number: 4465788
    Abstract: An olefin oligomerization catalyst containing nickel sulfate on a porous support, activated by calcining in an oxidizing atmosphere, followed by inert gas treatment at a lower but elevated temperature, is useful for oligomerizing propylene and butenes.
    Type: Grant
    Filed: September 10, 1982
    Date of Patent: August 14, 1984
    Assignee: Chevron Research Company
    Inventor: Stephen J. Miller
  • Patent number: 4442078
    Abstract: A spent solid sorbent resulting from the removal of hydrogen sulfide from a fuel gas flow is regenerated with a steam-air mixture. The mixture of steam and air may also include additional nitrogen or carbon dioxide. The gas mixture contacts the spent sorbent containing metal sulfide at a temperature above 500.degree. C. to regenerate the sulfide to metal oxide or carbonate. Various metal species including the period four transition metals and the lanthanides are suitable sorbents that may be regenerated by this method. In addition, the introduction of carbon dioxide gas permits carbonates such as those of strontium, barium and calcium to be regenerated. The steam permits regeneration of spent sorbent without formation of metal sulfate. Moreover, the regeneration will proceed with low oxygen concentrations and will occur without the increase in temperature to minimize the risk of sintering and densification of the sorbent.
    Type: Grant
    Filed: July 7, 1982
    Date of Patent: April 10, 1984
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Vinod M. Jalan, David G. Frost
  • Patent number: 4440725
    Abstract: A regenerator control system is disclosed which is particularly useful in connection with combustion promoted cracking catalysts. The air flow is controlled responsive to the temperature in the dilute phase, first in a direct mode when the amount of combustibles on the catalyst is at or above a set point and second in accordance with a reverse mode when the amount of combustibles is below such a set point. This versatile control system allows a safe operation of a regenerator under a variety of conditions.
    Type: Grant
    Filed: July 22, 1982
    Date of Patent: April 3, 1984
    Assignee: Phillips Petroleum Company
    Inventors: Harold J. Swindell, Randall G. Thompson
  • Patent number: 4435281
    Abstract: Emissions of sulfur oxides from the regenerator of a catalytic cracking unit are reduced by selectively removing a portion of the sulfur from sulfur-containing coke deposits on deactivated cracking catalyst. This is accomplished by reaction of these deposits with limited amounts of molecular oxygen in a stripping zone at a temperature in the range from about 550.degree. to about 700.degree. C. Hot regenerated catalyst and/or hot effluent gas from the catalyst regeneration zone is passed to the stripping zone in an amount which is effective to maintain the temperature in said stripping zone within the range from about 550.degree. to about 700.degree. C.
    Type: Grant
    Filed: September 15, 1980
    Date of Patent: March 6, 1984
    Assignee: Standard Oil Company (Indiana)
    Inventor: Iacovos A. Vasalos
  • Patent number: 4412914
    Abstract: A process is disclosed for decarbonization-demetallization of a poor quality residual oil feed boiling above about 650.degree. F. and comprising substantial Conradson carbon components to provide a higher grade of oil feed by contacting the poor quality oil feed with sorbent particle material containing one or more metal additives selected to catalyze the endothermic removal of coke with CO.sub.2. Sorbent decarbonization conditions are selected so that substantial quantities of carbonaceous material and metals are deposited on the sorbent in the decarbonizing zone. Sorbent material with metals and hydrocarbonaceous deposits is regenerated in the presence of an oxygen and carbon dioxide containing gas streams in separate sorbent regeneration zones at a temperature sufficiently elevated to remove residual coke to a desired low level. Regenerated sorbent particle material at an elevated temperature below about 1500.degree. F.
    Type: Grant
    Filed: August 10, 1981
    Date of Patent: November 1, 1983
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., James F. Hoffman, Stephen M. Kovach
  • Patent number: 4409123
    Abstract: A process for regenerating a spent copper-porous refractory metal oxide carrier composite for sorbing sulfur compounds from hydrocarbons in which the spent sorbent is optionally stripped of hydrocarbons, oxidized to convert absorbed sulfur to a sulfate form, and then purged with an inert gas at temperatures that decompose the sulfate form to sulfur dioxide, thereby reducing the sulfur content of the sorbent substantially.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: October 11, 1983
    Assignee: Chevron Research Company
    Inventor: William C. Hecker