And Group Viii (iron Group Or Platinum Group) Metal Containing Patents (Class 502/66)
  • Patent number: 11911747
    Abstract: Provided is an ammonia decomposition catalyst that exhibits high durability while maintaining high ammonia decomposition activity and low emissions of nitrogen oxides, for example, even under an atmosphere with a steam concentration of about 10% by volume. An ammonia decomposition catalyst capable of decomposing ammonia contained in an exhaust gas, the catalyst comprising an inorganic oxide loaded with an alloy containing Pt and Pd, and a zeolite.
    Type: Grant
    Filed: December 26, 2019
    Date of Patent: February 27, 2024
    Assignee: NIKKI-UNIVERSAL CO., LTD.
    Inventors: Tomoo Ikoma, Toshiya Nashida
  • Patent number: 11890600
    Abstract: The present disclosure provides Low Temperature NOx-Absorber (LT-NA) catalyst compositions, catalyst articles, and an emission treatment system for treating an exhaust gas, each including the LT-NA catalyst compositions. Further provided are methods for reducing a NOx level in an exhaust gas stream using the LT-NA catalyst articles. In particular, the LT-NA catalyst compositions include a first zeolite, a first palladium component, and a plurality of platinum nanoparticles. The LT-NA catalyst compositions exhibit enhanced regeneration efficiency with respect to NOx adsorption capacity, even after hydrothermal aging.
    Type: Grant
    Filed: October 19, 2020
    Date of Patent: February 6, 2024
    Assignee: BASF Corporation
    Inventors: Xinyi Wei, Evan Vincent Miu, Xiaoming Xu, Jia Cheng Liu, Stefan Maurer
  • Patent number: 11884616
    Abstract: Processes and apparatus for reforming hydrocarbons to reduce the impact of contaminants created by non-catalyst coking. The reaction zone receives sulfur to inhibit the impact, and a control index is used to control the determine conditions with generally lower pressures. Additionally, a compression zone, pressure control zone and combustion zone operation are provided for the operation of the reaction zone at the generally lower pressures.
    Type: Grant
    Filed: September 30, 2022
    Date of Patent: January 30, 2024
    Assignee: UOP LLC
    Inventors: Bryan J. Egolf, Christopher D. DiGiulio, William Yanez, Ka L. Lok, Elie J. Fayad, Haibo Yu, Kristen E. Allaire, Falaah Falih, Jeffrey R. Grott, Sujay R. Krishnamurthy, Hari S. Bajpai, Phillip F. Daly, Matthew R. Zuraski, Hosoo Lim, Joseph Peterson, Michael R. Van de Cotte, Steven A. Bradley
  • Patent number: 11872545
    Abstract: Catalytic compositions for depolymerizing polyolefin-based waste material into useful petrochemical products and methods of use are described. The compositions are a composite of at least one zeolite catalyst with one or more co-catalyst(s) that is a solid inorganic material. These composite catalysts, along with heat, are used to both increase the depolymerization reaction rate of the feed streams and suppress poisoning effects of non-polyolefin polymers that may be present. This results in a shorter residence time in the depolymerization unit and more efficient process.
    Type: Grant
    Filed: December 3, 2021
    Date of Patent: January 16, 2024
    Assignee: Basell Poliolefine Italia Srl
    Inventors: Sandor Nagy, Daniel F. White, Christopher D. Smith, David L. Ramage, Diego Brita, Noel C. Hallinan
  • Patent number: 11731119
    Abstract: Disclosed in the present invention is an integrated catalyst system for stoichiometric-burn natural gas vehicles, the catalyst system consisting of a three-way catalyst, a molecular sieve catalyst, and a base body, the three-way catalyst and the molecular sieve catalyst being coated on a surface of the base body. In the integrated three-way catalyst and molecular sieve catalyst system of the present invention, at the same time that pollutants such as CO, HC, and NOx in the exhaust of stoichiometric-burn natural gas vehicles are processed, the produced byproduct NH3 can also be processed, and the conversion rates of CO, HC, NOx, and NH3 are high.
    Type: Grant
    Filed: May 30, 2019
    Date of Patent: August 22, 2023
    Assignee: Sinocat Environmental Technology Co., Ltd.
    Inventors: Yongxiang Cheng, Yun Wang, Hongyi Du, Ganxue Wu, Xueqing Zhou, Guangfa Zu, Yi Yan, Dongdong Wu, Yun Li, Qizhang Chen
  • Patent number: 11660587
    Abstract: The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.
    Type: Grant
    Filed: December 1, 2020
    Date of Patent: May 30, 2023
    Assignee: Mississippi State University
    Inventors: Mark G. White, Shetian Liu
  • Patent number: 11633695
    Abstract: A device and method of simultaneously removing flammable gases and nitrous oxide are provided. The device includes a thermal oxidation chamber, a high-temperature resistant dust filter, and a catalyst chamber. The thermal oxidation chamber is configured to receive an exhaust gas from a process tool. The exhaust gas includes flammable gases and nitrous oxide. The thermal oxidation chamber has a first exhaust pipe to emit nitrous oxide and dust generated after the exhaust gas is thermally oxidized. The high-temperature resistant dust filter receives dust and nitrous oxide from the first exhaust pipe, wherein the high-temperature resistant dust filter has a filter fiber net and a second exhaust pipe, and the second exhaust pipe is configured to emit nitrous oxide. The catalyst chamber receives nitrous oxide from the second exhaust pipe, wherein the catalyst chamber has a nitrous oxide decomposition catalyst to decompose nitrous oxide into nitrogen and oxygen.
    Type: Grant
    Filed: December 29, 2021
    Date of Patent: April 25, 2023
    Assignee: Industrial Technology Research Institute
    Inventors: Chuan-Lin Chang, Hong-Ping Lin, Shou-Nan Li, Jui-Hsiang Cheng, Hui-Ya Shih, I-Ling Nien
  • Patent number: 11618858
    Abstract: In accordance with one or more embodiments of the present disclosure, a method for hydrodearylating aromatic bottoms oil includes contacting at least one aromatic bottoms oil stream with at least one catalyst composition and hydrogen in a reactor in order to hydrodearylate the aromatic bottoms oil stream. The catalyst composition includes a catalyst support comprising framework-substituted ultra-stable Y-type (USY) zeolite substituted with at least zirconium atoms. The catalyst composition does not include a hydrogenative metal component disposed on the support.
    Type: Grant
    Filed: December 6, 2021
    Date of Patent: April 4, 2023
    Assignees: Saudi Arabian Oil Company, JGC Catalysts and Chemicals Ltd., Japan Cooperation Center Petroleum
    Inventors: Omer Refa Koseoglu, Robert Peter Hodgkins, Koji Uchida
  • Patent number: 11511228
    Abstract: The present invention relates generally to the field of exhaust treatment systems for purifying exhaust gas discharged from a lean burn engine. The exhaust treatment system comprises a Diesel Oxidation Catalyst (DOC), a Catalyzed Soot Filter (CSF), a reductant injector, an AEI zeolite based Selective Catalyzed Reduction (SCR) catalyst and an Ammonia Oxidation Catalyst (AMOX) downstream to the AEI zeolite based SCR catalyst.
    Type: Grant
    Filed: October 24, 2019
    Date of Patent: November 29, 2022
    Assignee: BASF Corporation
    Inventors: Stefan Maurer, Jia Di Zhang, Yu Dai, Yu Fen Hao, Ming Ming Wei, Teng Shen
  • Patent number: 11461755
    Abstract: Technologies for closed-looped testing of integrated circuit card payment terminals include loading a test profile onto an integrated circuit payment card. Authorization request and response messages are locally generated and translated to simulate acquirer processor processing and payment network processing. An outcome report indicative of the outcome of the test transaction is generated and transmitted to a remote certification server. Other embodiments are described and claimed.
    Type: Grant
    Filed: September 30, 2020
    Date of Patent: October 4, 2022
    Assignee: Worldpay, LLC
    Inventors: Patricia Lynn Walters, Steven Scott Cole
  • Patent number: 11311863
    Abstract: A process of making an aromatization catalyst comprising: (a) mixing a zeolite, a binder, and water to form a mixture; (b) extruding the mixture to form a green extrudate; (c) drying the green extrudate to form a dried green extrudate; (d) calcining the dried green extrudate to form a support, wherein calcining the dried green extrudate is the only calcination step in the process; (e) washing the support to form a washed support; (f) drying the washed support to form a dried washed support; (g) impregnating the dried washed support with a Group 8-10 transition metal compound and at least one halide-containing compound to form a metalized-halided material; and (h) vacuum drying the metalized-halided material to form a dried metalized-halided material which is the aromatization catalyst.
    Type: Grant
    Filed: July 8, 2020
    Date of Patent: April 26, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Ryan W. Snell, Gabriela Alvez-Manoli
  • Patent number: 11260376
    Abstract: Catalysts and method of preparing the catalysts are disclosed. One of the catalysts includes a zeolite support, a Group VIII metal on the zeolite support, and at least two halides bound to the zeolite support, to the Group VIII metal, or to both, and can have an average crush strength greater than 11.25 lb based on at least two samples of pellets of the catalyst measured in accordance with ASTM D4179.
    Type: Grant
    Filed: October 22, 2019
    Date of Patent: March 1, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: An-Hsiang Wu, Joseph Bergmeister, III
  • Patent number: 11149610
    Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.
    Type: Grant
    Filed: April 2, 2020
    Date of Patent: October 19, 2021
    Assignee: BASF Corporation
    Inventors: Yuejin Li, Xiaolai Zheng, Stanley Roth, Olga Gerlach, Andreas Sundermann
  • Patent number: 11103856
    Abstract: A process of making an aromatization catalyst comprising: (a) mixing a zeolite, a binder, and water to form a mixture; (b) extruding the mixture to form a green extrudate; (c) drying the green extrudate to form a dried green extrudate; (d) calcining the dried green extrudate to form a support, wherein calcining the dried green extrudate is the only calcination step in the process; (e) washing the support to form a washed support; (f) drying the washed support to form a dried washed support; (g) impregnating the dried washed support with a Group 8-10 transition metal compound and at least one halide-containing compound to form a metalized-halided material; and (h) vacuum drying the metalized-halided material to form a dried metalized-halided material which is the aromatization catalyst.
    Type: Grant
    Filed: May 7, 2018
    Date of Patent: August 31, 2021
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: Ryan W. Snell, Gabriela Alvez-Manoli
  • Patent number: 11014073
    Abstract: An improved cluster-supporting catalyst has heteroatom-removed zeolite particles, and catalyst metal clusters supported within the pores of the heteroatom-removed zeolite particles. A method for producing a cluster-supporting catalyst includes the following steps: providing a dispersion liquid containing a dispersion medium and the heteroatom-removed zeolite particles dispersed in the dispersion medium; and in the dispersion liquid, forming catalyst metal clusters having a positive charge, and supporting the catalyst metal clusters within the pores of the heteroatom-removed zeolite particles through an electrostatic interaction.
    Type: Grant
    Filed: June 26, 2018
    Date of Patent: May 25, 2021
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, GENESIS RESEARCH INSTITUTE, INC.
    Inventors: Kazuhiro Egashira, Yoshihiro Takeda, Namiki Toyama, Toshiaki Tanaka, Seitoku Ito, Masahiko Ichihashi
  • Patent number: 10850264
    Abstract: The present invention relates to a catalyst comprising a carrier substrate of the length L extending between substrate ends a and b and a first washcoat zone, which comprises a) a zeolite, b) a redox active base metal compound and c) palladium in oxidic or metallic state which is fixed to the surface of a support oxide.
    Type: Grant
    Filed: May 18, 2018
    Date of Patent: December 1, 2020
    Assignee: UMICORE AG & CO. KG
    Inventors: John Nunan, David Moser, Chad Alltizer
  • Patent number: 10774018
    Abstract: A method of preparing a bound zeolite support comprising: contacting a zeolite powder with a binder and water to form a paste; shaping the paste to form an wet extruded base; removing excess water from the wet extruded base to form an extruded base; contacting the extruded base with a fluorine-containing compound to form a fluorinated extruded base; calcining the extruded base to form a calcined fluorinated extruded base; washing the calcined fluorinated extruded base to form a washed calcined fluorinated extruded base; drying the washed calcined fluorinated extruded base to form a dried washed calcined fluorinated extruded base; and calcining the dried washed calcined fluorinated extruded base to form a bound zeolite support.
    Type: Grant
    Filed: September 16, 2019
    Date of Patent: September 15, 2020
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: An-Hsiang Wu
  • Patent number: 10738246
    Abstract: The present invention relates to a process for producing monoaromatic hydrocarbons from a hydrocarbon feed comprising polyaromatics, the process comprising contacting said feed in the presence of hydrogen with a M/zeolite catalyst under hydrocracking process conditions.
    Type: Grant
    Filed: September 15, 2016
    Date of Patent: August 11, 2020
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Luis Aramburo, Emiel van Kimmenade, Dustin Farmer, Scott A. Stevenson
  • Patent number: 10723959
    Abstract: The present invention relates to a process for producing monoaromatic hydrocarbons from a hydrocarbon feed comprising polyaromatics, the process comprising contacting said feed in the presence of hydrogen with a M/A/zeolite catalyst under hydrocracking process conditions.
    Type: Grant
    Filed: September 15, 2016
    Date of Patent: July 28, 2020
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Luis Aramburo, Dustin Farmer, Scott A. Stevenson
  • Patent number: 10639617
    Abstract: A process comprising contacting said feed in the presence of hydrogen with a M/zeolite catalyst under hydrocracking process conditions.
    Type: Grant
    Filed: September 15, 2016
    Date of Patent: May 5, 2020
    Assignee: SABIC Global Technologies B.V.
    Inventors: Luis Aramburo, Maikel van Iersel, Dustin Farmer, Scott A. Stevenson, Emiel van Kimmenade
  • Patent number: 10611705
    Abstract: Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, including cyclopentadiene, and formulated catalyst compositions for use in such process. The process comprises contacting the feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form the product. The catalyst composition comprises a microporous crystalline metallosilicate, a Group 10 metal or compound thereof, a binder, optionally, a metal selected from the group consisting of rare earth metals, metals of Groups 8, 9, or 11, mixtures or combinations thereof, or a compound thereof, in combination with a Group 1 alkali metal or a compound thereof and/or a Group 2 alkaline earth metal or a compound thereof.
    Type: Grant
    Filed: April 10, 2018
    Date of Patent: April 7, 2020
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Larry L. Iaccino, Xiaoying Bao, Chuansheng Bai, Jeremy W. Bedard, Jocelyn A. Gilcrest, Wenyih F. Lai
  • Patent number: 10557287
    Abstract: A casement/leaf arrangement having a casement/leaf of a window or door, with a frame profile of the casement/leaf. The frame profile having a C-shaped casement/leaf groove in the rebate, and with at least one fitting part, in particular a drive rod of a fitting, provided to be inserted into the casement/leaf groove. The casement/leaf groove has a first groove limb and a first groove portion and, located opposite, a second groove limb and a second groove portion. The fitting part has an elongate main body having a front side and a rear side. The main body has, on opposite longitudinal sides, a first peripheral region for engaging behind the first groove limb of the casement/leaf groove and a second peripheral region for engaging behind the second groove limb of the casement/leaf groove. The fitting part is pivotable into the casement/leaf groove with a peripheral region inserted into the groove portion.
    Type: Grant
    Filed: June 15, 2017
    Date of Patent: February 11, 2020
    Assignees: WILH. SCHLECHTENDAHL & SÖHNE GMBH & CO. KG (WSS), SAPA AS
    Inventor: Giovanni Zaccaria
  • Patent number: 10556228
    Abstract: Methods for producing supported catalysts containing a transition metal and a bound zeolite base are disclosed. These methods employ a step of impregnating the bound zeolite base with the transition metal, fluorine, and high loadings of chlorine. The resultant high chlorine content supported catalysts have improved catalyst activity in aromatization reactions.
    Type: Grant
    Filed: September 7, 2017
    Date of Patent: February 11, 2020
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: Gabriela D. Alvez-Manoli
  • Patent number: 10519387
    Abstract: Accordingly, the present invention provides a catalyst composition suitable for converting light naphtha comprising one or more of C5 to C8 carbon atoms to aromatic compounds ranging from C6 to C10 carbon atoms, said catalyst composition comprising: (a) a medium pore size zeolite; (b) 0.1 to 5.0 wt % of zinc; and (c) 0.1 to 5 wt % of gallium. Also, the present invention provides a process for converting light naphtha comprising one or more of C5 to C8 carbon atoms to aromatic compounds ranging from C6 to C10 carbon atoms, said process comprising the step of contacting a feedstock comprising the light naphtha with a catalyst composition comprising (a) a medium pore size zeolite; (b) 0.1 to 5.0 wt % of zinc; and (c) 0.1 to 5 wt % of gallium in presence of carrier gas at temperatures ranging from 400° to 600° C.
    Type: Grant
    Filed: August 25, 2014
    Date of Patent: December 31, 2019
    Assignee: HINDUSTAN PETROLEUM CORPORATION LTD.
    Inventors: Raman Ravishankar, Peddy Venkat Chalapathi Rao, Nettem Venkateswarlu Choudary, Ganapati V. Shanbhag, Hodala Lakshminarayan Janardhan, Anand B. Halgeri, Sriganesh Gandham
  • Patent number: 10301192
    Abstract: Techniques for reduction of copper from aqueous streams using an iron promoted activated alumina are disclosed. An adsorbent media composition that reduces copper levels in an aqueous feed stream includes an iron containing activated alumina. A process for reducing copper levels in an aqueous fluid using an iron promoted activated alumina sorption media includes contacting the aqueous fluid containing a copper contaminant with the iron promoted activated alumina to achieve reductions in copper from the aqueous fluid.
    Type: Grant
    Filed: August 7, 2017
    Date of Patent: May 28, 2019
    Assignee: The Frazer and Cruickshank Living Trust
    Inventors: Nancy S. Sherwood, Duane R. Steelman
  • Patent number: 10293332
    Abstract: The present invention relates to a hydrocracking catalyst for hydrocarbon oil comprising a support containing a framework-substituted zeolite-1 in which zirconium atoms and/or hafnium atoms form a part of a framework of an ultrastable y-type zeolite and a hydrogenative metal component carried thereon and a method for producing the same. The hydrocracking catalyst of the present invention makes it easy to diffuse heavy hydrocarbon oils such as VGO, DAO and the like into mesopores, is improved in a cracking activity and makes it possible to obtain a middle distillate at a high yield as compared with catalysts prepared by using zeolite comprising titanium and/or zirconium carried thereon.
    Type: Grant
    Filed: September 25, 2018
    Date of Patent: May 21, 2019
    Assignees: Saudi Arabian Oil Company, JGC Catalyst and Chemicals Ltd., Japan Cooperation Center, Petroleum
    Inventors: Omer Refa Koseoglu, Adnan Al-Hajji, Ali Mahmoud Al-Somali, Ali H. Al-Abdul'Al, Mishaal Al-Thukair, Masaru Ushio, Ryuzo Kuroda, Takashi Kameoka, Koji Nakano, Yuichi Takamori
  • Patent number: 10265689
    Abstract: The present invention relates to a zeolite comprising platinum. The invention furthermore relates to a method for producing said zeolite comprising platinum according to the invention, to the use of said zeolite as an oxidation catalyst and hydrocarbon reservoir and to a catalyst component comprising the zeolite according to the invention.
    Type: Grant
    Filed: December 21, 2015
    Date of Patent: April 23, 2019
    Assignee: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH
    Inventors: Olga Manoylova, Markus Hutt, Klaus Wanninger, Arno Tiβler
  • Patent number: 10232358
    Abstract: [Problem] The purpose of the present invention is to provide: a pentasil-type zeolite that combines a higher BET specific surface area and a higher acid amount than previously; and a method for manufacturing said pentasil-type zeolite. [Solution] A pentasil-type zeolite characterized in that the BET specific surface area thereof is 450 m2/g or more, and furthermore the acid amount thereof, measured by the ammonia-TPD method, is 0.38 mmol/g or more. This pentasil-type zeolite can be obtained by a manufacturing method which has a crystallization step for crystallizing a mixture containing tetrabutylphosphonium cations, a silica source, an alumina source, an alkali metal source, and water, and which is characterized in that the molar ratio of the alkali metal relative to the silica in the mixture is greater than 0.04 and less than 0.10.
    Type: Grant
    Filed: August 12, 2014
    Date of Patent: March 19, 2019
    Assignee: TOSOH CORPORATION
    Inventors: Satoshi Yoshida, Yukio Ito, Hidenori Yamada
  • Patent number: 10179321
    Abstract: The present invention provides a method (100) for removal of metals from aqueous solutions comprising the steps of treating (102) the aqueous solutions with an adsorbent, allowing (104) the aqueous solutions and the adsorbent to be in contact for a predetermined time to obtain treated aqueous solutions, collecting (106) the treated aqueous solutions, filtering (108) the treated aqueous solutions and discharging (110) the filtered aqueous solutions. The adsorbent comprising plurality of natural biomaterials. Further, the plurality of natural biomaterials are capable of adsorbing the metals from the aqueous solutions.
    Type: Grant
    Filed: January 25, 2016
    Date of Patent: January 15, 2019
    Assignee: DR. D. Y. PATIL VIDYAPEETH
    Inventors: Neelu Nawani, Prithviraj Desale, Balasaheb Kapadnis, Aminur Rahman, Noor Nahar, Abul Mandal
  • Patent number: 10155218
    Abstract: A TiO2-based catalyst precursor material in powder form includes TiO2 particles with the formula TiO(2-x)(OH)2x (x=0-1). The particles are coated with one or more auxiliary shaping agents and after coating and drying have a specific surface area of at least 150 m2/g. The material has a content of 1) 50-99.5% by weight of the titanium-oxygen compound with the general formula TiO(2-x)(OH)2x, wherein x=0 to 1, or mixtures thereof, wherein the crystalline phases of the titanium-oxygen compound are in the anatase form, and 2) 0.5-50% by weight of an auxiliary shaping agent or mixtures thereof, which evaporates, sublimates and/or decomposes upon heating to temperatures below the transformation temperature from anatase to rutile, wherein the % by weight are relative to the total weight of the dried catalyst precursor material.
    Type: Grant
    Filed: February 20, 2015
    Date of Patent: December 18, 2018
    Assignee: Huntsman P&A Germany GmbH
    Inventors: Sonja Grothe, Christian Spitzwieser
  • Patent number: 10125650
    Abstract: An engine exhaust gas purification apparatus includes a three way catalyst disposed on an exhaust line, and which transforms harmful materials in exhaust gas to harmless materials by an oxidation-reduction reaction. The three way catalyst includes a first catalyst layer, a second catalyst layer, and a third catalyst layer laminated from an upper portion on a cordierite carrier, and the first catalyst layer comprises at least one platinum group metal and an oxygen non-storage material.
    Type: Grant
    Filed: December 8, 2017
    Date of Patent: November 13, 2018
    Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATION
    Inventor: Jin Woo Choung
  • Patent number: 10086356
    Abstract: The present disclosure relates to a substrate containing passive NOx adsorption (PNA) materials for treatment of gases, and washcoats for use in preparing such a substrate. Also provided are methods of preparation of the PNA materials, as well as methods of preparation of the substrate containing the PNA materials. More specifically, the present disclosure relates to a coated substrate containing PNA materials for PNA systems, useful in the treatment of exhaust gases. Also disclosed are exhaust treatment systems, and vehicles, such as diesel or gasoline vehicles, particularly light-duty diesel or gasoline vehicles, using catalytic converters and exhaust treatment systems using the coated substrates.
    Type: Grant
    Filed: May 25, 2017
    Date of Patent: October 2, 2018
    Assignee: Umicore AG & Co. KG
    Inventors: Maximilian A. Biberger, Bryant Kearl, Qinghua Yin, Xiwang Qi
  • Patent number: 10081009
    Abstract: The present invention relates to a hydrocracking catalyst for hydrocarbon oil comprising a support containing a framework-substituted zeolite-1 in which zirconium atoms and/or hafnium atoms form a part of a framework of an ultrastable y-type zeolite and a hydrogenative metal component carried thereon and a method for producing the same. The hydrocracking catalyst of the present invention makes it easy to diffuse heavy hydrocarbon oils such as VGO, DAO and the like into mesopores, is improved in a cracking activity and makes it possible to obtain a middle distillate at a high yield as compared with catalysts prepared by using zeolite comprising titanium and/or zirconium carried thereon.
    Type: Grant
    Filed: November 3, 2015
    Date of Patent: September 25, 2018
    Assignees: Saudi Arabian Oil Company, JGC Catalyst and Chemical Ltd., Japan Cooperation Center Petroleum
    Inventors: Omer Refa Koseoglu, Adnan Al-Hajji, Ali Mahmoud Al-Somali, Ali H. Al-Abdul'al, Mishaal Al-Thukair, Masaru Ushio, Ryuzo Kuroda, Takashi Kameoka, Koji Nakano, Yuichi Takamori
  • Patent number: 9682369
    Abstract: Shaped articles and methods for forming shaped articles are provided. In one embodiment, a method for forming a shaped article includes providing a hydroxy metal oxide binder precursor in a solution of hydroxy metal oxide binder precursor. The method mixes a primary ion exchange composition with the solution of hydroxy metal oxide binder precursor. Further, the method mixes a solid with the solution of hydroxy metal oxide binder precursor. The method includes converting the hydroxy metal oxide binder precursor to a hydroxy metal oxide binder. Also, the method includes forming the shaped article from the primary ion exchange composition, the hydroxy metal oxide binder, and the solid.
    Type: Grant
    Filed: May 30, 2014
    Date of Patent: June 20, 2017
    Assignee: UOP LLC
    Inventor: Evgeny Todorov Kolev
  • Patent number: 9669396
    Abstract: This invention is directed to hydrocracking catalysts and hydrocracking processes employing a magnesium aluminosilicate clay and a zeolite. The magnesium aluminosilicate clay has a characteristic 29Si NMR spectrum. The magnesium aluminosilicate clay is the product of a series of specific reaction steps. The resulting magnesium aluminosilicate clay combines high surface area and activity for use in hydrocracking catalysts and processes.
    Type: Grant
    Filed: November 4, 2013
    Date of Patent: June 6, 2017
    Assignee: Chevron U.S.A. Inc.
    Inventors: Theodorus Maesen, Alexander E. Kuperman, Darren P. Fong
  • Patent number: 9643166
    Abstract: A process for preparing a catalyst is disclosed. The process generally comprises the steps of: (a) preparing a slurry comprising clay, zeolite, a sodium-free silica source, quasi-crystalline boehmite, and micro-crystalline boehmite, provided that the slurry does not comprise peptized quasi-crystalline boehmite; (b) adding a monovalent acid to the slurry; (c) adjusting the pH of the slurry to a value above about 3, and (d) shaping the slurry to form particles. This process results in attrition resistant catalysts with a good accessibility.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: May 9, 2017
    Assignee: Albemarle Netherlands B.V.
    Inventors: Dennis Stamires, Paul O'Connor, Erik Jeroen Laheij, Charles Vadovic
  • Patent number: 9637389
    Abstract: An activated carbon monolith catalyst comprising a finished self-supporting activated carbon monolith having at least one passage therethrough, and comprising a supporting matrix and substantially discontinuous activated carbon particles dispersed throughout the supporting matrix and at least one catalyst precursor on the finished self-supporting activated carbon monolith. A method for making, and a method for use, of such an activated carbon monolith catalyst in catalytic chemical reactions are also disclosed.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: May 2, 2017
    Assignee: Applied Technology Limited Partnership
    Inventors: Robert L. Mitchell, Sr., Lee M. Mitchell, Joseph H. Keller, Jack H. L'Amoreaux
  • Patent number: 9604203
    Abstract: Process for the preparation of a catalyst suitable for use in a naphtha reforming process, the process including providing a Y zeolite with an initial SiO2:Al2O3 molar ratio of at least 150, introducing the Y zeolite to a binder to form an intermediate composition, extruding the intermediate composition, reducing the alpha acidity of the extruded composition to provide a low acid composition, and introducing a noble metal to the low acid composition. Processes and systems of converting naphtha to a higher-octane hydrocarbon supply using catalysts, as prepared herein, are also disclosed.
    Type: Grant
    Filed: September 19, 2011
    Date of Patent: March 28, 2017
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Jean W. Beeckman, Stephen J. McCarthy, Jane C. Cheng
  • Patent number: 9587540
    Abstract: The invention relates to a method for reactivating a system composed of an oxidation catalytic converter (5) followed by a possibly catalytically coated particle filter (6), and to a correspondingly adapted exhaust-gas purification system for lean-burn engines (1) with low pressure EGR (14). The present invention relates in particular to the reactivation of such a system during overrun operation of the engine.
    Type: Grant
    Filed: June 22, 2012
    Date of Patent: March 7, 2017
    Assignee: UMICORE AG & CO. KG
    Inventors: Stephan Eckhoff, Stefan Franoschek
  • Patent number: 9428695
    Abstract: A method of producing olefins and aromatic compounds from a feedstock is accomplished by introducing a hydrocarbon feedstock and a catalyst composition within a reactor. At least a portion of the reactor is at a reactor temperature of from 470° C. to 730° C. The catalyst composition is comprised of a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from greater than 0 wt. % of the total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. At least a portion of the feedstock is converted to products of at least one of olefins and aromatic compounds within the reactor, with at least some of the products being contained in a liquid product stream. At least a portion of the liquid product stream is directed to different downstream processes to increase production of at least one of olefins and aromatic compounds.
    Type: Grant
    Filed: February 12, 2013
    Date of Patent: August 30, 2016
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Ravichander Narayanaswamy, Krishna Kumar Ramamurthy, P. S. Sreenivasan
  • Patent number: 9409785
    Abstract: The purpose of/problem addressed by the present invention is to provide: an Fe(II)-substituted MEL-type zeolite useful for the catalytic removal of a variety of gases; and a production method therefor. The SiO2/Al2O3 ratio in this Fe(II)-substituted MEL-type zeolite is in the range of 10-30 inclusive. This Fe(II)-substituted MEL-type zeolite is obtained by being subjected to ionic exchange with Fe(II) ions. It is preferable that the Fe(II) loading amount be in the range of 0.001-0.4 mmol/g of the Fe(II)-substituted MEL-type zeolite. It is preferable that the Fe(II)-substituted MEL-type zeolite be produced using a method in which an MEL-type zeolite having an SiO2/Al2O3 ratio in the range of 10-30 inclusive is dispersed in an Fe(II) water-soluble-compound aqueous solution, and then mixed and agitated to cause the MEL-type zeolite to carry Fe(II) ions.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: August 9, 2016
    Assignees: UniZeo Co., Ltd., THE UNIVERSITY OF TOKYO
    Inventors: Masaru Ogura, Keiji Itabashi, Tatsuya Okubo, Shanmugam Palani Elangovan
  • Patent number: 9387466
    Abstract: This invention reveals a method for synthesizing a hydrotreating catalyst wherein the support is prepared by mixing of peptized alumina with an amorphous silica or crystalline aluminum silicate as one component of the catalyst. The catalyst comprises a group VI metal and/or a group VIII metal of the periodic table. The catalyst exhibits improved hydrocracking, hydrodesulfurization and hydrodemetallization activities and has a relatively stable life with time on stream. Thus, the invention concerns a method for developing a catalyst for hydroprocessing of heavy hydrocarbon feedstocks which is characterized by two steps: the first step consists of the optimization of a catalyst formulation with respect to the textural properties, number of acid sites, active metal incorporation. The second step consists of the evaluation with real feedstock and catalyst stability with time-on-stream.
    Type: Grant
    Filed: November 27, 2008
    Date of Patent: July 12, 2016
    Assignee: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Mohan Singh Rana, Jorge Ancheyta Juarez, Zenaida Carolina Leyva Inzunza, Samir Kumar Maity, Léon Pablo Torres Mancera
  • Patent number: 9364818
    Abstract: A zeolite structure is provided which has partition walls composed of a zeolite ion-exchanged with a metal ion and forming a plurality of cells extending from one end face of the zeolite structure to its other end face and functioning as a passage of fluid and which has a honeycomb shape. The content per unit zeolite amount of the metal ion in the surface portion of the partition wall is larger than the content per unit zeolite amount of the metal ion in the inner portion of the partition wall and is preferably 1.1 to 5.0 times the content per unit zeolite amount of the metal ion in the inner portion of the partition wall.
    Type: Grant
    Filed: October 25, 2010
    Date of Patent: June 14, 2016
    Assignee: NGK Insulators, Ltd.
    Inventors: Akira Takahashi, Shogo Hirose, Eriko Kodama
  • Patent number: 9347006
    Abstract: The invention relates to a method for optimizing layered catalytic processes. This is accomplished by testing various catalysts with a compound found in a feedstock to be tested, to determine the facility of the catalyst in hydrogenating, hydrosulfurizing, or hydrodenitrogenating the molecule, and hence the feedstock. In a preferred embodiment, the Double Bond Equivalence of the feedstock and molecule are determined, and catalysts are pre-selected based upon their known ability to work with materials of this DBE value.
    Type: Grant
    Filed: January 7, 2014
    Date of Patent: May 24, 2016
    Assignees: Saudi Arabian Oil Company, JGC Catalysts and Chemicals Ltd., Japan Cooperation Center, Petroleum
    Inventors: Omer Refa Koseoglu, Adnan Al-Hajji, Hendrik Muller, Masaru Ushio, Koji Nakano
  • Patent number: 9334211
    Abstract: The present invention provides a hydrocracking catalyst obtainable by mixing a metal compound (A) including any one metal of Groups 3 to 11 of the Periodic Table, a compound (B) including at least one compound selected from the group consisting of a ruthenium oxide compound (B1) and a high-valence compound (B2) including any metal of Groups 8 to 11 of the Periodic Table, and a metal oxide (C) including a metal of Group 5, Group 6 or Group 7 of the Periodic Table, and conducting reduction treatment.
    Type: Grant
    Filed: August 22, 2012
    Date of Patent: May 10, 2016
    Assignee: UBE INDUSTRIES, LTD.
    Inventors: Kiyotaka Yoshii, Atsushi Yamada
  • Patent number: 9303369
    Abstract: Methods for embedding photocatalytic titanium dioxide in asphalt surfaces to reduce pollutants via photocatalytic reactions include applying an amount of an asphalt surface treatment compound to an upper surface of the asphalt surface, the asphalt surface treatment compound including a mixture of a liquid carrier compound with a titanium dioxide (TiO2) photocatalyst.
    Type: Grant
    Filed: December 2, 2014
    Date of Patent: April 5, 2016
    Assignee: D&D Emulsions, Inc.
    Inventors: Colin Durante, Delbert L. Dawson
  • Patent number: 9272919
    Abstract: This invention relates to a process for producing aluminum silicates in the form of zeolite L, as well as the intermediate and end products of this process. The invention further relates to the use of these aluminum silicates for the conversion or adsorption of hydrocarbons.
    Type: Grant
    Filed: July 28, 2011
    Date of Patent: March 1, 2016
    Assignee: SUED-CHEMIE IP GMBH & CO. KG
    Inventors: Olivier Larlus, Martin Claus, Rainer Albert Rakoczy
  • Patent number: 9221036
    Abstract: The present invention relates to a hydrocracking catalyst for hydrocarbon oil comprising a support containing a framework-substituted zeolite-1 in which zirconium atoms and/or hafnium atoms form a part of a framework of an ultrastable y-type zeolite and a hydrogenative metal component carried thereon and a method for producing the same. The hydrocracking catalyst of the present invention makes it easy to diffuse heavy hydrocarbon oils such as VGO, DAO and the like into mesopores, is improved in a cracking activity and makes it possible to obtain a middle distillate at a high yield as compared with catalysts prepared by using zeolite comprising titanium and/or zirconium carried thereon.
    Type: Grant
    Filed: August 2, 2011
    Date of Patent: December 29, 2015
    Assignees: Saudi Arabian Oil Company, Japan Cooperation Center, Petroleum, JGC Catalysts and Chemicals Ltd.
    Inventors: Omer Refa Koseoglu, Adnan Al-Hajji, Ali Mahmood Al-Somali, Ali H. Al-Abdul'Al, Mishaal Al-Thukair, Masaru Ushio, Ryuzo Kuroda, Takashi Kameoka, Koji Nakano, Yuichi Takamori
  • Patent number: 9212105
    Abstract: A process for producing at least one light olefin comprising: (a) contacting a first raw material comprising methanol with a least one catalyst in a first reaction zone to produce at least one light olefin and at least one inactivated catalyst; (b) transporting the at least one inactivated catalyst to a first regeneration zone to produce at least one first regenerated catalyst, and transporting a portion of the at least one first regenerated catalyst to the first reaction zone; (c) transporting another portion of the at least one first regenerated catalyst to a second regeneration zone to obtain at least one second regenerated catalyst; and (d) transporting the at least one second regenerated catalyst to a second reaction zone, and contacting the at least one second regenerated catalyst with a second raw material comprising C4 olefins to produce a product stream II comprising at least one light olefin.
    Type: Grant
    Filed: March 3, 2011
    Date of Patent: December 15, 2015
    Assignees: Shanghai Research Institute of Petrochemical Technology, Sinopec, China Petroleum & Chemical Corporation
    Inventors: Guozhen Qi, Siqing Zhong, Hongtao Wang, Yongming Jin
  • Patent number: RE48220
    Abstract: Methods for embedding photocatalytic titanium dioxide in asphalt surfaces to reduce pollutants via photocatalytic reactions include applying an amount of an asphalt surface treatment compound to an upper surface of the asphalt surface, the asphalt surface treatment compound including a mixture of a liquid carrier compound with a titanium dioxide (TiO2) photocatalyst.
    Type: Grant
    Filed: October 24, 2018
    Date of Patent: September 22, 2020
    Assignee: D&D Emulsions, Inc.
    Inventors: Colin Durante, Delbert L. Dawson