Zsm Type Patents (Class 502/77)
  • Publication number: 20110263918
    Abstract: The invention concerns a xylenes isomerization process for the production of equilibrium or near-equilibrium xylenes. The process utilizes a catalyst comprising HZSM-5 or MCM-49 and process conditions including a temperature of less than 295° C. and a pressure sufficient to maintain the xylenes in liquid phase. In embodiments, the process can be operated in a continuous mode with ppm levels of dissolved H2 in the feed and in other embodiments in a cyclic mode without the H2 in feed but with periodic regenerations using a feed having low ppm levels of H2.
    Type: Application
    Filed: April 6, 2011
    Publication date: October 27, 2011
    Inventors: John Di-Yi Ou, April D. Ross, Doron Levin, Mohan Kalyanaraman, Wenyih Frank Lai
  • Publication number: 20110250127
    Abstract: A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir and Pt.
    Type: Application
    Filed: June 20, 2011
    Publication date: October 13, 2011
    Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: Joseph Michael Fedeyko, Rodney Kok Shin Foo, Paul Joseph Andersen, Jillian Elaine Gollier, John Leonello Casci, Hai-Ying Chen, Raj Rao Rajaram
  • Publication number: 20110236271
    Abstract: The zeolite structure includes a zeolite material containing a plurality of zeolite particles and an inorganic binding material which binds the zeolite particles to one another, the plurality of zeolite particles include fine zeolite particles having a small average particle diameter and coarse zeolite particles which have an average particle diameter of three or more times the average particle diameter of the fine zeolite particles and which are not an agglomerated material of primary particles, a ratio of volumes of the coarse zeolite particles with respect to the whole volume of the plurality of zeolite particles is from 40 to 90 vol %, in the zeolite material, a ratio of a volume of the inorganic binding material is from 5 to 50 vol %, and a zeolite raw material containing the plurality of zeolite particles and the inorganic binding material is extruded to form a zeolite structure.
    Type: Application
    Filed: March 17, 2011
    Publication date: September 29, 2011
    Applicant: NGK Insulators, Ltd.
    Inventors: Yoshio KIKUCHI, Haruo OTSUKA
  • Publication number: 20110192766
    Abstract: A supported catalyst comprises a zeolite having a silica to alumina molar ratio of 500 or less, a first metal oxide binder having a crystallite size greater than 200 ? and a second metal oxide binder having a crystallite size less than 100 ?, wherein the second metal oxide binder is present in an amount less than 15 wt % of the total weight of the catalyst.
    Type: Application
    Filed: February 7, 2011
    Publication date: August 11, 2011
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Stephen J. McCarthy, Wenyih F. Lai, Darryl Donald Lacy, Robert Ellis Kay
  • Patent number: 7982083
    Abstract: A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite having channels the opening to which is defined by a ring of 10 oxygen atoms (10 MR), at least one zeolite having channels the opening to which is defined by a ring of 12 oxygen atoms (12 MR) and at least one porous mineral matrix. Said catalyst optionally also contains at least one group VIII metal. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.
    Type: Grant
    Filed: December 1, 2006
    Date of Patent: July 19, 2011
    Assignee: IFP Energies Nouvelles
    Inventors: Emmanuelle Guillon, Eric Sanchez, Sylvie Lacombe
  • Publication number: 20110172478
    Abstract: [Object] To improve the yield of aromatic hydrocarbon and the stability of active life in a process for producing aromatic compound by using a lower hydrocarbon aromatization catalyst. [Solving Means] A lower hydrocarbon aromatization catalyst for producing aromatic compound under reaction of lower hydrocarbon has an average crystal diameter of not larger than 500 nm. A catalyst in which molybdenum is carried on ZSM-5 zeolite as metallosilicate is used as an example of the above-mentioned catalyst. Additionally, a process for producing aromatic compound upon contact of the above-mentioned catalyst with a reaction gas containing lower hydrocarbon is provided.
    Type: Application
    Filed: June 18, 2009
    Publication date: July 14, 2011
    Inventors: Hongtao Ma, Yuji Ogawa
  • Patent number: 7976697
    Abstract: A NOx reduction composition and process of using the composition to reduce the content of NOx emissions and gas phase reduced nitrogen species released from the regeneration zone during fluid catalytic cracking of a hydrocarbon feedstock into lower molecular weight components is disclosed. The process comprises contacting a hydrocarbon feedstock during a fluid catalytic cracking (FCC) process wherein a regeneration zone of an fluid catalytic cracking unit (FCCU) is operated in a partial or incomplete combustion mode under FCC conditions, with a circulating inventory of an FCC cracking catalyst and a particulate NOx reduction composition. The NOx reduction composition has a mean particle size of greater than 45 ?m and comprises (1) a zeolite component having (i) a pore size of form 2-7 A Angstroms and (ii) a SiO2 to Al2O3 molar ratio of less than 500, and (2) at least one noble metal selected from the group consisting of platinum, palladium, rhodium, iridium, osmium, ruthenium, rhenium and mixtures thereof.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: July 12, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: M. Sundaram Krishnamoorthy, Michael Scott Ziebarth, George Yaluris, Roger Jean Lussier, John Allen Rudesill
  • Publication number: 20110155641
    Abstract: The present invention concerns a catalyst comprising at least one crystalline material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said crystalline material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having microporous and crystalline walls with a thickness in the range 1.5 to 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
    Type: Application
    Filed: May 13, 2009
    Publication date: June 30, 2011
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Audrey Bonduelle, Alexandra Chaumonnot
  • Publication number: 20110144335
    Abstract: Zeolite material of the pentasil type has an alkali metal and alkaline earth metal content of not more than 100 ppm and a molar ratio of Si to Al of from 250 to 1500, at least 90% of the primary particles of the zeolite material being spherical and 95% by weight of the spherical primary particles having a diameter of less than or equal to 1 ?m.
    Type: Application
    Filed: February 18, 2011
    Publication date: June 16, 2011
    Applicant: BASF SE
    Inventors: Marco Bosch, Ulrich Müller, Matthias Frauenkron
  • Publication number: 20110136658
    Abstract: A catalyst used in the reaction of oxidative bromination of methane is provided. The catalyst is prepared by the following procedures: mixing at least one of the precursors selected from the compounds of Rh, Ru, Cu, Zn, Ag, Ce, V, W, Cd, Mo, Mn, Cr and La which can dissolve in water with the Si precursor, hydrolyzing, drying and sintering. In the catalysis system, methane reacts with HBr, H2O and oxygen source (O2, air or oxygen-rich air), finally CH3Br and CH2Br2 are produced. Another catalyst used in the reaction of condensation of methane bromide to C3-C13 hydrocarbons is also provided. This catalyst is prepared by supporting compounds of Zn or Mg on molecular sieves such as HZSM-5, HY, Hb, 3A, 4A, 5A or 13X et al. With this catalyst, CH3Br and CH2Br2 produced in the former process can react further to give C3 to C13 hydrocarbons and HBr, and HBr can be recycled as a medium.
    Type: Application
    Filed: April 14, 2008
    Publication date: June 9, 2011
    Inventors: Zhen Liu, Hongmin Zhang, Wensheng Li, Yanqun Ren, Xiaoping Zhou
  • Publication number: 20110120100
    Abstract: A catalyst system comprising a first catalytic composition comprising a homogeneous solid mixture containing at least one catalytic metal and at least one metal inorganic support. The pores of the solid mixture have an average diameter in a range of about 1 nanometer to about 15 nanometers. The catalytic metal comprises nanocrystals.
    Type: Application
    Filed: November 24, 2009
    Publication date: May 26, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Ming Yin, Larry Neil Lewis, Oltea Puica Siclovan, Dan Hancu, Benjamin Hale Winkler, Daniel George Norton, Ashish Balkrishna Mhadeshwar
  • Publication number: 20110118520
    Abstract: A porous, crystalline material is described having the framework structure of ZSM-12 and a composition involving the molar relationship: X2O3:(n)YO2 wherein X is a trivalent element, Y is a tetravalent element and n is less than about 45, e.g., less than about 40, wherein the average crystal size of the material is less than about 0.1 micron, which material is substantially free of impurities. The material is made by: (a) preparing a mixture capable of forming said material, said mixture comprising sources of alkali or alkaline earth metal (M), an oxide of trivalent element (X), an oxide of tetravalent element (Y), hydroxyl (OH?) ions, water, and an organic monoquaternary ammonium cation directing agent (R) and an organic diquaternary ammonium structure blocking agent (R?); (b) maintaining the mixture under sufficient conditions until crystals of said material are formed; and (c) recovering the crystalline material from step (ii). The material can be used as a hydrocarbon conversion process catalyst.
    Type: Application
    Filed: November 17, 2009
    Publication date: May 19, 2011
    Inventors: Frank Lai, Richard B. Saunders, Kathy Saunders
  • Publication number: 20110116982
    Abstract: A honeycomb structure includes at least one honeycomb unit. The at least one honeycomb unit has a plurality of through holes defined by partition walls along a longitudinal direction of the honeycomb unit. The honeycomb unit includes zeolite, an inorganic binder, and a noble metal catalyst. The noble metal catalyst is supported in a region of the honeycomb unit. The region extends from one end portion of the honeycomb unit in the longitudinal direction over approximately 1.5% or more to approximately 20% or less of an overall length of the honeycomb unit in the longitudinal direction.
    Type: Application
    Filed: September 27, 2010
    Publication date: May 19, 2011
    Applicant: IBIDEN CO., LTD.
    Inventors: Masafumi Kunieda, Ken Yoshimura, Toshiyuki Miyashita
  • Publication number: 20110108462
    Abstract: A catalyst composition prepared based on high solids formulation containing a zeolite, a binder precursor, a matrix and a slurring agent and a process for preparing a shaped catalyst product to be used in fluid catalytic cracking process for converting a heavier hydrocarbon fraction into a lighter hydrocarbons, particularly gasoline and light olefins.
    Type: Application
    Filed: November 10, 2009
    Publication date: May 12, 2011
    Inventor: Yun-Feng Chang
  • Publication number: 20110098519
    Abstract: A catalyst composition for dehydration of an alcohol to prepare an alkene is provided. The catalyst composition comprises a catalyst and a modifying agent which is phosphoric acid, sulfuric acid or tungsten trioxide, or a derivative thereof. A process for preparing an alkene by dehydration of an alcohol is also provided. The process comprises mixing one or more alcohols and optionally water and the catalyst composition.
    Type: Application
    Filed: August 12, 2008
    Publication date: April 28, 2011
    Inventors: Kanaparthi Ramesh, Armando Borgna
  • Publication number: 20110092356
    Abstract: Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures.
    Type: Application
    Filed: December 16, 2010
    Publication date: April 21, 2011
    Applicant: BATTELLE ENERGY ALLIANCE, LLC
    Inventors: Harry W. Rollins, Lucia Petkovic, Daniel M. Ginosar
  • Publication number: 20110085940
    Abstract: A honeycomb filter includes a honeycomb structure and a zeolite. The honeycomb structure has cell walls to define cells between the cell walls. The zeolite is supported on the cell walls. An amount of the zeolite is from about 80 g/L to about 150 g/L. The cells include a large volume cell and a small volume cell. A porosity of the cell walls is from about 55% to about 65%. A proportion of a sum of a pore volume A and a pore volume B relative to a total pore volume C is about 20% or less. The pore volume A indicates a pore volume of pores having a pore diameter of one half or less of the average pore diameter. The pore volume B indicates a pore volume of pores having a pore diameter of twice or more the average pore diameter.
    Type: Application
    Filed: April 9, 2010
    Publication date: April 14, 2011
    Applicant: IBIDEN CO., LTD.
    Inventors: Kazutake Ogyu, Toyoki Ogasawara
  • Publication number: 20110082025
    Abstract: A zeolite catalyst that may be used in aromatic alkylation is prepared by treating a zeolite with a phosphorus compound. The phosphorus-treated zeolite is calcined and contacted with liquid water, whereby an amount of phosphorus is removed from the phosphorus-treated zeolite. The phosphorus-treated zeolite is then heated. A method of preparing an aromatic product may also be carried out by contacting the prepared zeolite catalyst with an aromatic alkylation feed of an aromatic compound and an alkylating agent under reaction conditions suitable for aromatic alkylation.
    Type: Application
    Filed: October 5, 2009
    Publication date: April 7, 2011
    Inventors: Ashim Kumar Ghosh, Neeta Kulkarni, Pamela Harvey
  • Publication number: 20110071264
    Abstract: The invention covers a process for obtaining an alkaline earth or rare earth metal-P-modified molecular sieve (M-P-modified molecular sieve) comprising the following steps: a). selecting at least one molecular sieve selected from one of: a P-modified molecular sieve which contains at least 0.3 wt % of P obtained by dealuminating a molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P a molecular sieve which is modified with P during step b) by dealuminating the molecular sieve in a steaming step, followed by a leaching step using an acid solution containing a source of P thereby introducing at least 0.3 wt % of P b). contacting said molecular sieve with an alkaline earth or rare earth metal-containing compound (M-containing compound) to introduce at least 0.05 wt % of the alkaline earth or rare earth metal to the molecular sieve. The invention also covers a catalyst composite comprising: a).
    Type: Application
    Filed: January 23, 2009
    Publication date: March 24, 2011
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventors: Nikolai Nesterenko, Walter Vermeiren, Sander Van Donk, Delphine Minoux
  • Patent number: 7906091
    Abstract: A method and device for removal of N2O in nitric acid production are disclosed. The device is arranged after a heat exchanger, post ammonia burning, before the absorption tower and contains a catalyst, which essentially comprises one or several iron loaded zeolites.
    Type: Grant
    Filed: January 9, 2001
    Date of Patent: March 15, 2011
    Assignee: Uhde GmbH
    Inventors: Meinhard Schwefer, Rainer Maurer, Thomas Turek
  • Patent number: 7902102
    Abstract: Zeolite material of the pentasil type has an alkali metal and alkaline earth metal content of not more than 100 ppm and a molar ratio of Si to Al of from 250 to 1500, at least 90% of the primary particles of the zeolite material being spherical and 95% by weight of the spherical primary particles having a diameter of less than or equal to 1 ?m.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: March 8, 2011
    Assignee: BASF SE
    Inventors: Marco Bosch, Ulrich Müller, Matthias Frauenkron
  • Patent number: 7902107
    Abstract: Provided is an emission treatment system and method for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The emission treatment system has an oxidation catalyst upstream of a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia. Also provided is a method for disposing an SCR catalyst composition on a wall flow monolith that provides adequate catalyst loading, but does not result in unsuitable back pressures in the exhaust.
    Type: Grant
    Filed: February 8, 2008
    Date of Patent: March 8, 2011
    Assignee: BASF Corporation
    Inventors: Joseph A. Patchett, Joseph C. Dettling, Elizabeth A. Przybylski
  • Publication number: 20110054232
    Abstract: A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises molybdenum or a compound thereof dispersed on an aluminosilicate zeolite, wherein the amount of aluminum present as aluminum molybdate in the catalyst is less than 2700 ppm by weight.
    Type: Application
    Filed: February 5, 2009
    Publication date: March 3, 2011
    Inventors: Neeraj Sangar, Teng Xu, Larry L. Iaccino, Mobae Afeworki
  • Publication number: 20110047995
    Abstract: A catalyst system comprising a first catalytic composition comprising, (i) a first component comprising a zeolite, and (ii) a second component comprising a homogeneous solid mixture containing at least one catalytic metal and at least one metal inorganic network; wherein the pores of the solid mixture have an average diameter in a range of about 1 nanometer to about 15 nanometers; wherein the first component and the second component form an intimate mixture. The catalyst system may further comprise a second catalytic composition and a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. An exhaust system comprising the catalyst systems described herein is also provided.
    Type: Application
    Filed: August 31, 2009
    Publication date: March 3, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Larry Neil Lewis, Donald Wayne Whisenhunt, Jr., Dan Hancu, Ashish Balkrishna Mhadeshwar, Benjamin Hale Winkler, Daniel George Norton, Oltea Puica Siclovan
  • Publication number: 20110047988
    Abstract: A catalyst system comprising a first catalytic composition comprising a first catalytic material disposed on a metal inorganic support; wherein the metal inorganic support has pores; and at least one promoting metal. The catalyst system further comprises a second catalytic composition comprising, (i) a zeolite, or (ii) a first catalytic material disposed on a first substrate, the first catalytic material comprising an element selected from the group consisting of tungsten, titanium, and vanadium. The catalyst system may further comprise a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. A catalyst system comprising a first catalytic composition, the second catalytic composition, and the third catalytic composition is also provided. An exhaust system comprising the catalyst systems described herein is also provided.
    Type: Application
    Filed: August 31, 2009
    Publication date: March 3, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Larry Neil Lewis, Benjamin Hale Winkler, Dan Hancu, Daniel George Norton, Ashish Balkrishna Mhadeshwar
  • Publication number: 20110039954
    Abstract: Multi-functional catalyst and processes utilizing the catalyst in single-stage conversion of syngas into hydrocarbon compounds are provided. The multi-functional catalyst, which comprises two or more catalytic materials situated within molecular distances of each other, facilitates conversion of syngas into one or more intermediate compounds and then into desired hydrocarbon compounds, such as high octane gasoline, diesel, jet fuel, olefins, and xylenes.
    Type: Application
    Filed: August 13, 2010
    Publication date: February 17, 2011
    Applicant: BLACK & VEATCH CORPORATION
    Inventors: Jianli Hu, Jon C. Erickson
  • Publication number: 20110034321
    Abstract: [Task] To provide a catalyst in which granules of the catalyst are improved in crash strength with no use of the caking agent, while increasing the effective area of the crystal surface part of the catalyst. [Solving Means] A catalyst powder-containing slurry obtained by milling a metallosilicate-containing raw material by a bead mill is dried by a spray drying method to obtain granules of a catalyst. The raw material may be one containing a metallosilicate having micropores of a size that is substantially 4.5 to 6.5 angstroms. It is better to mill the raw material by a bead mill such that the particle size of the metallosilicate becomes 1.0 ?m or less at a cumulative frequency of 50%. It is better that as a metal component at least one metal component selected from rhenium, vanadium, molybdenum, tungsten, chromium, and their compounds is supported on the metallosilicate. It is better to subject the slurry to the drying process after aging. It is better to add polyvinyl alcohol to the slurry.
    Type: Application
    Filed: April 13, 2009
    Publication date: February 10, 2011
    Inventors: Takuya Hatagishi, Tomohiro Yamada
  • Patent number: 7879749
    Abstract: Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures.
    Type: Grant
    Filed: August 15, 2006
    Date of Patent: February 1, 2011
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Harry W. Rollins, Lucia M. Petkovic, Daniel M. Ginosar
  • Publication number: 20110015057
    Abstract: The present invention provides modified molecular sieve membranes with improved CO2/CH4 separation selectivity and methods for making such membranes. The molecular sieve membranes are modified by adsorption of a modifying agent, such as ammonia, within and/or on the membrane.
    Type: Application
    Filed: September 30, 2010
    Publication date: January 20, 2011
    Applicant: The Regents of the University of Colorado, a body corporate
    Inventors: Shiguang LI, Sara A. ARVIDSON, John L. FALCONER, Richard D. NOBLE
  • Publication number: 20100331592
    Abstract: A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises a support and molybdenum or a compound thereof dispersed on the support. The support comprises an aluminosilicate zeolite combined with a binder selected from silica, titania, zirconia and mixtures thereof. The catalyst is substantially free of aluminum external to the framework of the aluminosilicate zeolite.
    Type: Application
    Filed: December 22, 2008
    Publication date: December 30, 2010
    Inventors: Neeraj Sangar, Jocelyn A. Kowalski, Larry L. Iaccino, Kenneth R. Clem
  • Publication number: 20100319332
    Abstract: To equip a diesel particle filter with a zeolite-containing coating uniformly over the entire length of the particle filter and with a further zeolite-free coating which is applied, from the entry side of the filter, solely up to a specific length of the filter, it is proposed, first, to apply the zeolite-free coating from the entry side of the filter and only thereafter to apply the zeolite-containing coating over the entire length of the filter from the exit side of the filter. As a result of this sequence of coatings, a better adhesive strength of the coatings than when both coatings are applied from the entry side is ensured.
    Type: Application
    Filed: February 17, 2009
    Publication date: December 23, 2010
    Inventors: Gerald Jeske, Marcus Pfeifer, Wolfgang Schneider, Franz Dornhaus, Ralf Mueller, Michael Schiffer
  • Publication number: 20100316547
    Abstract: Embodiments of the present disclosure include a catalyst for the conversion of CO and/or hydrocarbons in an exhaust stream including a Sn compound selected from the group consisting of a binary composition comprising Sn and Ti, a ternary composition comprising Sn, Ti and Zr, and mixtures of any thereof. In those embodiments, the binary composition may include Sn(X)Ti(y)O2, wherein x+y=1, 0.85>y>0. In other embodiments of the present disclosure, the Sn compound includes a ternary composition including Sn(a)Ti(b)Zr(c)O2, wherein a is 0.25, b is 0.25 and c is 0.5. Certain embodiments of this disclosure include a method for the conversion of CO in an exhaust stream, including contacting an exhaust stream containing CO with the catalyst described above containing a Sn compound. In other embodiments, the exhaust stream includes hydrocarbons.
    Type: Application
    Filed: May 20, 2010
    Publication date: December 16, 2010
    Inventors: Rachelle Justice, Rajashekharam V. Malyala, Svetlana Iretskaya, Dylan Trandal, Dien To, Jason Pless, Stephen Golden, Jiho Yoo
  • Publication number: 20100304957
    Abstract: Zeolite-based honeycomb bodies and methods of manufacturing same. Zeolite-based honeycomb bodies especially suited for engine exhaust treatment applications include a primary phase comprising a zeolite having a SiO2 to Al2O3 molar ratio in the range from 5 to 300. The zeolite-based composites are porous with an open porosity of at least 25% and a median pore diameter of at least 1 micron. The zeolite-based honeycomb bodies can be manufactured by an extrusion method.
    Type: Application
    Filed: June 3, 2010
    Publication date: December 2, 2010
    Inventors: Steven Bolaji Ogunwumi, Patrick David Tepesch, Raja Rao Wusirika
  • Publication number: 20100296992
    Abstract: Honeycomb catalyst structures and methods of using them, where the structures have honeycomb channel walls of selective catalytic reduction catalyst, the channel walls occupy at least 20% of the volume of the structure, the structure exhibits a pressure drop for flowing air not exceeding about 110 Pa at a space velocity of 20,000 hr?1, and the channel walls are of a thickness insuring high degree of catalyst utilization and NOx conversion efficiency.
    Type: Application
    Filed: May 22, 2009
    Publication date: November 25, 2010
    Inventors: Yi Jiang, Ameya Joshi, Steven Bolaji Ogunwumi, Jianhua Weng
  • Publication number: 20100285948
    Abstract: A process for the pre-treatment of Mo/ZSM-5 and Mo/MCM-22 catalysts is provided, which process comprises heating the catalyst at 500° C. in the presence of propane. The treated catalyst, when used in the non-oxidative dehydrogenation of methane demonstrates improved benzene yield and catalyst stability as compared to catalysts pre-treated with He, methane or H2.
    Type: Application
    Filed: January 16, 2008
    Publication date: November 11, 2010
    Applicants: AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH, MITSUI CHEMICALS INC.
    Inventors: Yan Liu, Toru Nishimura
  • Patent number: 7807132
    Abstract: A quantity of solution sufficient to dissolve a pH controlling substance and/or substantially dissolve a surfactant without substantial excess solution is controlled under a set of time and temperature conditions to transform an inorganic material having long-range crystallinity to a mesostructure having long-range crystallinity. The method employs concentrated conditions that have a consistency similar to a thick slurry. The economic viability of scaling up such thick slurry methods is improved relative to prior more dilute methods of transforming an inorganic material to a mesostructure.
    Type: Grant
    Filed: March 13, 2007
    Date of Patent: October 5, 2010
    Assignee: Rive Technology, Inc.
    Inventor: Javier Garcia-Martinez
  • Patent number: 7758847
    Abstract: A MFI-structured molecular sieve containing phosphorus and metal components has a formula expressed in anhydrous form and on the basis of oxide weight, as follows: (0˜0.3) Na2O (0.5˜5.5) Al2O3 (1.3˜10) P2O5 (0.7˜15) M1xOy (0.01˜5) M2mOn (70˜97) SiO2, wherein M1 is one of transition metals selected from the group consisting of Fe, Co and Ni, and M2 is any one of metals selected from the group consisting of Zn, Mn, Ga and Sn. Preparation processes and uses of the instant molecular sieve are also provided. The molecular sieve has an excellent performance for increasing the yield of lower olefins and increasing the aromatics content in gasoline, and can be used as a shape-selective active component for the catalytic cracking catalyst of petroleum hydrocarbons or its additives.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: July 20, 2010
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Yibin Luo, Ying Ouyang, Xingtian Shu, Mingyuan He, Dianzhong Wang, Baoning Zong, Minggang Li
  • Publication number: 20100179359
    Abstract: A catalyst useful for the alkylation or transalkylation of aromatic compounds is disclosed. The catalyst is an acid-treated zeolitic catalyst produced by a process including contacting an acidic zeolitic catalyst comprising surface non-framework aluminum and framework aluminum with an organic dibasic acid at a catalyst to acid weight ratio in the range from about 2:1 to about 20:1 and at a temperature in the range from about 50° C. to about 100° C. to selectively remove at least a portion of the surface non-framework aluminum. The resulting catalyst may have a measured first-order rate constant, kcum, for the alkylation of benzene with propylene to form cumene, of at least 2.0 cm3/s g.
    Type: Application
    Filed: January 14, 2009
    Publication date: July 15, 2010
    Applicant: LUMMUS TECHNOLOGY INC.
    Inventors: Chuen Yuan Yeh, Ruozhi Song, Anne Mae Gaffney, Tadeusz Langner, Marshall J. Margolis
  • Patent number: 7745367
    Abstract: An emission control catalyst that exhibits improved CO and HC reduction performance includes a supported platinum-based catalyst, and a supported palladium-gold catalyst. The two catalysts are coated onto different layers, zones, or monoliths of the substrate for the emission control catalyst such that the platinum-based catalyst encounters the exhaust stream before the palladium-gold catalyst. Zeolite may be added to the emission control catalyst as a hydrocarbon absorbing component to boost the oxidation activity of the palladium-gold catalyst.
    Type: Grant
    Filed: May 5, 2009
    Date of Patent: June 29, 2010
    Assignee: Nanostellar, Inc.
    Inventors: Kyle L. Fujdala, Timothy J. Truex, Jifei Jia
  • Publication number: 20100143227
    Abstract: Disclosed herein is a catalyst comprising a binder; and a catalytic composition, the catalytic composition comprising a first catalyst composition that comprises a zeolite; and a second catalyst composition that comprises a catalytic metal disposed upon a porous inorganic material, wherein the porous inorganic material is a metal oxide, an inorganic oxide, an inorganic carbide, an inorganic nitride, an inorganic hydroxide, an inorganic oxide having a hydroxide coating, an inorganic carbonitride, an inorganic oxynitride, an inorganic boride, an inorganic borocarbide, or a combination comprising at least one of the foregoing inorganic materials; wherein the catalyst is in the form of an extrudate or foam.
    Type: Application
    Filed: December 5, 2008
    Publication date: June 10, 2010
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Hrishikesh Keshavan, Benjamin Hale Winkler, Dan Hancu
  • Publication number: 20100137666
    Abstract: A catalyst for aromatizing a lower hydrocarbon, in order to increase the amount of production of useful aromatic compounds, such as benzene and toluene, by improving the methane conversion rate, the benzene formation rate, the naphthalene formation rate and the BTX formation rate (or a total formation rate of benzene, toluene and xylene) is such that molybdenum and silver are loaded on a metallosilicate as a substrate. It is more preferable to obtain the aromatizing catalyst by loading molybdenum and silver after modifying a zeolite formed of the metallosilicate with a silane compound that has a molecular diameter larger than a pore diameter of the zeolite and that has an amino group, which selectively reacts at a Bronsted acid point of the zeolite, and a straight-chain hydrocarbon group.
    Type: Application
    Filed: March 28, 2008
    Publication date: June 3, 2010
    Inventors: Shinichi Yamada, Tomohiro Yamada, Yuji Ogawa, Takuya Hatagishi, Yo Yamamoto, Yoshio Sugiyama
  • Publication number: 20100135864
    Abstract: Provided are a photocatalytic material that improves a decomposition performance and a decomposition rate, as well as a photocatalytic member and a purification device in which the photocatalytic material is used. The photocatalytic member is a photocatalytic member (1) that includes a substrate (10) and a photocatalyst layer (11) formed on a surface of the substrate (10), wherein the photocatalyst layer (11) contains a titanium oxide photocatalyst and zeolite, the titanium oxide photocatalyst containing at least an anatase-type titanium oxide and fluorine, in which a content of the fluorine in the titanium oxide photocatalyst is 2.5 wt % to 3.5 wt %, and 90 wt % or more of the fluorine is chemically bonded to the anatase-type titanium oxide.
    Type: Application
    Filed: April 18, 2008
    Publication date: June 3, 2010
    Applicant: PANASONIC CORPORATION
    Inventors: Noboru Taniguchi, Tomohiro Kuroha, Shuzo Tokumitsu, Kenichi Tokuhiro
  • Patent number: 7723252
    Abstract: There is disclosed in embodiments catalysts produced by a two-stage loading of a zeolite carrier with an aqueous solution of a cobalt compound, with drying in an air current after each loading. Methods using the catalysts to produce synfuel are disclosed.
    Type: Grant
    Filed: April 11, 2007
    Date of Patent: May 25, 2010
    Assignee: Wesco
    Inventors: Lapidus Albert Lvovich, Budtsov Vladimir Sergeevich
  • Patent number: 7718840
    Abstract: Disclosed is a process for producing light olefins from hydrocarbon feedstock. The process is characterized in that a porous molecular sieve catalyst consisting of a product obtained by evaporating water from a raw material mixture comprising a molecular sieve with a framework of Si—OH—Al— groups, a water-insoluble metal salt, and a phosphate compound, is used to produce light olefins, particularly ethylene and propylene, from hydrocarbon, while maintaining excellent selectivity to light olefins. According to the process, by the use of a specific catalyst with hydrothermal stability, light olefins can be selectively produced in high yield with high selectivity from hydrocarbon feedstock, particularly full-range naphtha. In particular, the process can maintain higher cracking activity than the reaction temperature required in the prior thermal cracking process for the production of light olefins, and thus, can produce light olefins with high selectivity and conversion from hydrocarbon feedstock.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: May 18, 2010
    Assignees: SK Energy Co., Ltd., Korea Research Institute of Chemical Technology
    Inventors: Sun Choi, Yong Seung Kim, Deuk Soo Park, Suk Joon Kim, Il Mo Yang, Hee Young Kim, Yong Ki Park, Chul Wee Lee, Won Choon Choi, Kwang An Ko, Na Young Kang
  • Publication number: 20100115994
    Abstract: The adsorbent for carbon monoxide of the present invention is obtained by activating a Cu-ZSM5 type zeolite prepared as a catalyst for removal of NOX through heating at 450 to 600° C. in an inert gas atmosphere containing no moisture. The gas purification method of the present invention includes removing carbon monoxide as a trace amount of impurities contained in a gas by a temperature swing adsorption method, wherein the adsorbent for carbon monoxide according to claim 1 is used, and a regeneration operation of the adsorbent for carbon monoxide is carried out at 200 to 350° C.
    Type: Application
    Filed: March 4, 2008
    Publication date: May 13, 2010
    Inventors: Masayoshi Hayashida, Akihiro Nakamura, Tatsuya Hidano, Kazuhiko Fujie, Masato Kawai
  • Patent number: 7713898
    Abstract: A catalyst is formed from a phosphorus-containing ZSM-5-type zeolite. The ZSM-5-type zeolite has a silica/alumina molar ratio of at least 200. The phosphorus-containing ZSM-5-type zeolite also has a phosphorus content of at least 8% by weight of zeolite and has multiple phosphorus species exhibited by at least two 31P MAS NMR peaks with maxima at from about 0 to about ?50 ppm. The catalyst may be used in aromatic alkylation by contacting the catalyst with a feed of an aromatic hydrocarbon and an alkylating agent under reaction conditions suitable for aromatic alkylation.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: May 11, 2010
    Assignee: Saudi Basic Industries Corporation
    Inventors: Ashim Kumar Ghosh, Neeta Kulkarni, Pamela Harvey
  • Patent number: 7713904
    Abstract: This invention relates to a composition with desulfurization property, in which the desulfurization component is a kind of molecular sieves with incorporation of vanadium into the skeleton. The composition has high hydrothermal stability and the vanadium is hard to lose.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: May 11, 2010
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SINOPEC
    Inventors: Baoning Zong, Jinyu Zheng, Wenhua Xie, Yong Xu, Xuhong Mu, Yibin Luo, Minggang Li, Xingtian Shu
  • Publication number: 20100112095
    Abstract: The present invention relates to a bifunctional material which comprises copper and which is capable of storing nitric oxide (NO), as well as catalytically producing nitric oxide from a suitable precursor. The material typically includes a zeolite and the copper may be part of or separate from the zeolite. In this manner the material may include a single bifunctional material; that is, a material which is capable of both storing NO and catalytically producing NO, such as Cu-MFI or Cu—X. Alternatively the material may include at least two components, a first component to store NO, such as a zeolite Zn-LTA, and a further component including Cu(I), such as Cu2O, to catalytically produce NO from a suitable precursor. The bifunctional material may be used in a pharmaceutical, neutraceutical or cosmetic preparation, or comprised in a medical article, a cosmetic and/or personal hygiene product.
    Type: Application
    Filed: November 19, 2007
    Publication date: May 6, 2010
    Inventors: Russel Edward Morris, Ian L. Megson
  • Publication number: 20100113850
    Abstract: A catalyst and method of forming a catalyst for use in aromatic alkylation involves treating a zeolite, which may be a ZSM-5 zeolite, with a phosphorus-containing compound. The phosphorus-treated zeolite is combined with a binder material. The bound phosphorus-treated zeolite is treated with an aqueous solution of a hydrogenating metal compound by contacting the bound phosphorus-treated zeolite with the aqueous solution and separating the aqueous solution from the bound phosphorus-treated zeolite to form a hydrogenating-metal-containing zeolite catalyst. The catalyst may be used in preparing an alkyl aromatic product by contacting a hydrogenating-metal-containing zeolite catalyst with an aromatic alkylation feed of an aromatic compound and an alkylating agent under reaction conditions suitable for aromatic alkylation.
    Type: Application
    Filed: November 3, 2008
    Publication date: May 6, 2010
    Inventors: Ashim Kumar Ghosh, Neeta Kulkarni
  • Patent number: RE41314
    Abstract: A gas adsorbing element is formed into a honeycomb-shaped laminate having many small channels penetrating from one end surface to the other and in which hydrophobic high silica zeolite powder is exposed on the walls of the small channels. The hydrophobic high silica zeolite is, for example, a zeolite which is produced by removing most of the aluminum component from an ordinary zeolite. In forming the honeycomb-shaped laminate, it is favorable that non-flammable sheets are laminated and the laminate is impregnated with a dispersion of high silica zeolite powder and with an inorganic binder, and that the high silica zeolite powder is fixed in fiber gaps and on the surface of the non-flammable paper. It is desirable that the non-flammable sheet is a low density inorganic fiber paper and is baked either before or after forming the honeycomb-shaped laminate.
    Type: Grant
    Filed: April 30, 1991
    Date of Patent: May 4, 2010
    Assignee: Kabushiki Kaisha Seibu Giken
    Inventors: Toshimi Kuma, Chieko Kuma