Mordenite Type Patents (Class 502/78)
  • Patent number: 11123719
    Abstract: A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.
    Type: Grant
    Filed: November 27, 2019
    Date of Patent: September 21, 2021
    Assignee: Enerkem, Inc.
    Inventors: Allen Artur Carl Reule, Natalia Semagina, Esteban Chornet
  • Patent number: 10801384
    Abstract: The present invention relates to a diesel oxidation catalyst, which comprises a carrier body having a length L extending between a first end face a and a second end face b and a catalytically active material zone A arranged on the carrier body, wherein the material zone A contains palladium and platinum on a manganese-containing carrier oxide, wherein the carrier oxide consists of a carrier oxide component A and a carrier oxide component B and the carrier oxide component B consists of manganese and/or a manganese compound and is present in an amount of 5 to 15 wt. %, calculated as MnO2 and based on the total weight of the manganese-containing carrier oxide.
    Type: Grant
    Filed: March 6, 2018
    Date of Patent: October 13, 2020
    Assignee: UMICORE AG & CO. KG
    Inventors: Christoph Hengst, Naohiro Kato
  • Patent number: 10767528
    Abstract: The invention relates to a diesel oxidation catalyst which has a support body with a length L extending between a first end face a and a second end face b and catalytically active material zones A, B, and C arranged on the support body, wherein—material zone A contains palladium or platinum and palladium in a weight ratio of Pt:Pd of ?1 and an alkaline earth metal and extends over 20 to 80% of the length L starting from the end face a, material zone B contains ceroxide, is free of platinum, and extends over 20 to 80% of the length L starting from the end face b, material zone C contains platinum or platinum and palladium in a weight ratio of Pt:Pd of ?5, and neither material zone A nor material zone C is arranged over material zone B.
    Type: Grant
    Filed: May 2, 2017
    Date of Patent: September 8, 2020
    Assignee: UMICORE AG & CO. KG
    Inventors: Christoph Hengst, Franz Dornhaus, Michael Schiffer
  • Patent number: 10213767
    Abstract: The present invention relates to a catalyst that comprises a carrier body with a length L, which extends between a first end face ‘a’ and a second end face ‘b’, and differently composed, catalytically-active material zones A, B, and C arranged on the carrier body, wherein material zone A contains platinum or platinum and palladium with a weight ratio Pt:Pd of ?1 and, starting from end face ‘a’ or starting from end face ‘b’, extends along 70 to 100% of the length L, and material zone B contains palladium or platinum and palladium and, starting from end face ‘b’, extends along a portion of the length L, and material zone C contains SCR-active material and, starting from end face ‘a’, extends along a portion of the length L, wherein material zone C is arranged above material zone A.
    Type: Grant
    Filed: February 1, 2018
    Date of Patent: February 26, 2019
    Assignee: UMICORE AG & CO. KG
    Inventors: Christoph Reith, Birgit Friedrich, Christoph Hengst
  • Patent number: 9034780
    Abstract: This disclosure relates to a catalyst system adapted for transalkylation a C9+ aromatic feedstock with a C6-C7 aromatic feedstock, comprising: (a) a first catalyst comprising a first molecular sieve having a Constraint Index in the range of 3-12 and 0.01 to 5 wt. % of at least one source of a first metal element of Groups 6-10; and (b) a second catalyst comprising a second molecular sieve having a Constraint Index less than 3 and 0 to 5 wt. % of at least one source of a second metal element of Groups 6-10, wherein the weight ratio of the first catalyst over the second catalyst is in the range of 5:95 to 75:25 and wherein the first catalyst is located in front of the second catalyst when they are brought into contacting with the C9+ aromatic feedstock and the C6-C7 aromatic feedstock in the present of hydrogen.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: May 19, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Doron Levin
  • Publication number: 20150126357
    Abstract: The present invention is related to a nano-structured composite material and process of making for air detoxing and deodoring in enclosed spaces to prevent harmful chemicals in the air from damaging human health. The nano-structured composite material consists of nano-porous carbon, zeolites with sub nano-size pores and at least 1 other component chosen from nano-porous rare earth oxides and nano-sized catalysts, and is made into highly efficient configurations with high geometric surface and low resistance air flow channels. The synergetic action of those nano-structured components can effectively remove toxic chemicals including, but not limited to formaldehyde, benzene, toluene, xylene, propene, butadiene, acetone, carbon monoxide, nitric oxide, nitrogen dioxide, sulfur dioxide, hydrogen sulfide, ammonia, alcohols, chlorine, mercaptans, as well as bad odors, such cigarette smoke and bathroom/toilet smells.
    Type: Application
    Filed: October 27, 2014
    Publication date: May 7, 2015
    Inventors: Xiwang Qi, Mei Jiang
  • Patent number: 9018120
    Abstract: The present invention provides a process for the preparation of metal-doped zeolites comprising the steps of i) provision of a dry mixture of a) a zeolite, b) a compound of a catalytically active metal, ii) intimate grinding of the mixture, iii) heating of the mixture in a reactor, iv) cooling to room temperature and obtaining the metal-doped zeolite, wherein the internal pressure in the reactor during the heating is kept in a pressure range from 0 to ?200 millibar. The invention further relates to the use of a metal-doped zeolite prepared by means of the process according to the invention for the conversion of NOx and N2O into harmless products.
    Type: Grant
    Filed: July 19, 2007
    Date of Patent: April 28, 2015
    Assignee: Süd-Chemie IP GmbH & Co KG
    Inventors: Soovi Hurgobin, Arno Tissler, Ashveer Raghunandan, Attila Jambor, Rainer Rakoczy, Roderik Althoff
  • Patent number: 9006125
    Abstract: In a process for producing xylene by transalkylation of a C9+ aromatic hydrocarbon feedstock with a C6 and/or C7 aromatic hydrocarbon, the C9+ aromatic hydrocarbon feedstock, at least one C6 and/or C7 aromatic hydrocarbon and hydrogen are contacted with a first catalyst comprising (i) a first molecular sieve having a Constraint Index in the range of about 3 to about 12 and (ii) at least first and second different metals or compounds thereof of Groups 6 to 12 of the Periodic Table of the Elements. Contacting with the first catalyst is conducted under conditions effective to dealkylate aromatic hydrocarbons in the feedstock containing C2+ alkyl groups and to saturate C2+ olefins formed so as to produce a first effluent.
    Type: Grant
    Filed: May 22, 2013
    Date of Patent: April 14, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Doron Levin, April D. Ross, James H. Beech, Jr.
  • Patent number: 8993468
    Abstract: This invention is for a catalyst for conversion of hydrocarbons. The catalyst is a medium pore germanium zeolite, a germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). At least one metal selected from Group 10 is deposited on the medium pore zeolite and, optionally on the germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO). The catalyst is prepared by synthesizing a medium pore zeolite, an aluminophosphate (AlPO) or a silicoaluminophosphate (SAPO) with germanium incorporated into the framework and calcining the medium pore germanium zeolite, germanium aluminophosphate (AlPO) or germanium silicoaluminophosphate (SAPO). At least one metal may be deposited on the germanium zeolite, germanium aluminophosphate (AlPO) or a germanium silicoaluminophosphate (SAPO).
    Type: Grant
    Filed: May 22, 2008
    Date of Patent: March 31, 2015
    Assignee: Saudi Basic Industries Corporation
    Inventors: Scott A. Stevenson, Alla K. Khanmamedova, Dustin B. Farmer, Scott F. Mitchell, Jim Vartuli
  • Publication number: 20150071841
    Abstract: In order to improve the lifetime of an SCR catalyst in the waste gas purification by means of the SCR process of waste gas of a biomass combustion plant, the catalyst comprises a sacrificial component selected from a zeolite and/or a clay mineral, in particular halloysite. During operation, catalyst poisons contained in the waste gas, in particular alkali metals, are absorbed by the sacrificial component so that catalytically active centres of the catalyst are not blocked by the catalyst poisons.
    Type: Application
    Filed: September 10, 2014
    Publication date: March 12, 2015
    Inventor: Maria Theresia Brandmair
  • Publication number: 20150064102
    Abstract: A hydrogen oxidation catalyst is provided, comprising a zeolite that contains at least one catalytically active noble metal or a compound thereof, wherein said zeolite is a hydrophobic zeolite. A use of the catalyst and a method for hydrogen recombination in nuclear power plants, reprocessing plants or fuel element repositories is also specified.
    Type: Application
    Filed: April 2, 2013
    Publication date: March 5, 2015
    Applicant: Clariant Produkte (Deutschland) GmbH
    Inventors: Patrick Mueller, Arno Tissler, Frank Klose, RoderikPeter Althoff, Olaf Buettner
  • Patent number: 8969232
    Abstract: This invention is for a catalyst for conversion of hydrocarbons. The catalyst contains a zeolite with one element from Group 13, Group 14, or the first series transition metals and, optionally, germanium and/or aluminum in the zeolite framework. At least one Group 10 metal, such as platinum, is deposited on the zeolite. Examples of the elements in the framework are tin, boron, iron or titanium. The catalyst is prepared by synthesizing a zeolite with one element from Group 13, Group 14, or the first series transition metals and, optionally, germanium and/or aluminum in the zeolite framework; depositing the metal; and calcining after preparation of the zeolite and before or after depositing the metal. The catalyst may be used in a process for the conversion of hydrocarbons, such as propane to aromatics, by contacting the catalyst with alkanes having 2 to 12 carbon atoms per molecule and recovering the product.
    Type: Grant
    Filed: May 22, 2008
    Date of Patent: March 3, 2015
    Assignee: Saudi Basic Industries Corporation
    Inventors: Scott F. Mitchell, Alla K. Khanmamedova, Scott A. Stevenson, Jim Vartuli
  • Patent number: 8956993
    Abstract: Oxychlorination catalyst compositions which include a catalytically effective amount of an oxychlorination catalyst and a diluent having certain chemical composition and/or physical properties are disclosed. Processes using such oxychlorination catalyst compositions are also described. Some oxychlorination catalyst compositions and processes disclosed herein can increase the optimal operating temperature, and thereby increase the production capacity of an existing reactor, such as a fluid-bed reactor, compared to other oxychlorination catalyst compositions.
    Type: Grant
    Filed: August 10, 2009
    Date of Patent: February 17, 2015
    Assignee: Oxy Vinyls LP
    Inventors: Keith S. Kramer, Joseph A. Cowfer
  • Patent number: 8957271
    Abstract: The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a h
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: February 17, 2015
    Assignee: Total Research & Technology Feluy
    Inventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
  • Patent number: 8957274
    Abstract: The present invention relates to a process to make light olefins and aromatics, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-cont
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: February 17, 2015
    Assignee: Total Research & Technology Feluy
    Inventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
  • Patent number: 8957272
    Abstract: The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containing organic
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: February 17, 2015
    Assignee: Total Research & Technology Feluy
    Inventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
  • Patent number: 8957273
    Abstract: The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, optionally at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-contain
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: February 17, 2015
    Assignee: Total Research & Technology Feluy
    Inventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
  • Patent number: 8932974
    Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.
    Type: Grant
    Filed: July 17, 2013
    Date of Patent: January 13, 2015
    Assignee: Massachusetts Institute of Technology
    Inventor: Javier Garcia-Martinez
  • Patent number: 8932712
    Abstract: The present invention relates a metal passivator additive comprising: a rare earth component; alumina; clay; colloidal silica; and a zeolite having high silica to alumina ratio.
    Type: Grant
    Filed: June 1, 2011
    Date of Patent: January 13, 2015
    Assignee: Indian Oil Corporation Limited
    Inventors: Mohan Prabhu Kuvettu, Manish Agarwal, Arumugam Velayutham Karthikeyani, Balaiah Swamy, Biswanath Sarkar, Mitra Bhanu Patel, Santanam Rajagopal
  • Patent number: 8889587
    Abstract: A catalyst system comprising a first catalytic composition comprising a first catalytic material disposed on a metal inorganic support; wherein the metal inorganic support has pores; and at least one promoting metal. The catalyst system further comprises a second catalytic composition comprising, (i) a zeolite, or (ii) a first catalytic material disposed on a first substrate, the first catalytic material comprising an element selected from the group consisting of tungsten, titanium, and vanadium. The catalyst system may further comprise a third catalytic composition. The catalyst system may further comprise a delivery system configured to deliver a reductant and optionally a co-reductant. A catalyst system comprising a first catalytic composition, the second catalytic composition, and the third catalytic composition is also provided. An exhaust system comprising the catalyst systems described herein is also provided.
    Type: Grant
    Filed: January 11, 2013
    Date of Patent: November 18, 2014
    Assignee: General Electric Company
    Inventors: Larry Neil Lewis, Benjamin Hale Winkler, Dan Hancu, Daniel George Norton, Ashish Balkrishna Mhadeshwar
  • Patent number: 8889940
    Abstract: The subject invention comprises a hydrocarbon-conversion process using a zeolitic catalyst comprising very low concentrations of non-zeolitic material and featuring a gradient in crystallinity decreasing from the outer portion to the center and an intrusion pore volume of at least 0.6 cc/gram. The catalyst is particularly effective in a xylene-isomerization process comprising ethylbenzene conversion.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: November 18, 2014
    Assignee: UOP LLC
    Inventors: Paula L. Bogdan, Hui Wang, Richard R. Willis
  • Patent number: 8883668
    Abstract: The present invention is a phosphorous modified zeolite (A) made by a process comprising in that order: selecting a zeolite with low Si/Al ratio (advantageously lower than 30) among H+ or NH4+-form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870° C. for 0.01-200 h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.3 wt % of P; separation of the solid from the liquid; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step.
    Type: Grant
    Filed: July 28, 2008
    Date of Patent: November 11, 2014
    Assignee: Total Research & Technology Feluy
    Inventors: Nikolai Nesterenko, Walter Vermeiren, Delphine Minoux, Sander Van Donk
  • Patent number: 8883667
    Abstract: A purification catalyst which prevents contamination within a reflow furnace, including flux components, while suppressing the generation of CO is provided. A purification catalyst for a reflow furnace gas, having one or two of zeolite and silica-alumina as an active ingredient.
    Type: Grant
    Filed: October 10, 2007
    Date of Patent: November 11, 2014
    Assignee: Nikki-Universal Co., Ltd.
    Inventors: Yoshiki Nakano, Takanobu Sakurai, Shinichi Ueno
  • Patent number: 8877670
    Abstract: Catalysts are disclosed comprising fibrous substrates having silica-containing fibers with diameters generally from about 1 to about 50 microns, which act effectively as “micro cylinders.” Such catalysts can dramatically improve physical surface area, for example per unit length of a reactor or reaction zone. At least a portion of the silica, originally present in the silica-containing fibers of a fibrous material used to form the fibrous substrate, is converted to a zeolite (e.g., having a SiO2/Al2O3 ratio of at least about 150) that remains deposited on these fibers. The fibrous substrates possess important properties, for example in terms of acidity, which are useful in hydroprocessing (e.g., hydrotreating or hydrocracking) applications.
    Type: Grant
    Filed: August 7, 2013
    Date of Patent: November 4, 2014
    Assignee: UOP LLC
    Inventors: Antoine Negiz, Hui Wang
  • Patent number: 8871667
    Abstract: The zeolite structure includes a zeolite material containing a plurality of zeolite particles and an inorganic binding material which binds the zeolite particles to one another, the plurality of zeolite particles include fine zeolite particles having a small average particle diameter and coarse zeolite particles which have an average particle diameter of three or more times the average particle diameter of the fine zeolite particles and which are not an agglomerated material of primary particles, a ratio of volumes of the coarse zeolite particles with respect to the whole volume of the plurality of zeolite particles is from 40 to 90 vol %, in the zeolite material, a ratio of a volume of the inorganic binding material is from 5 to 50 vol %, and a zeolite raw material containing the plurality of zeolite particles and the inorganic binding material is extruded to form a zeolite structure.
    Type: Grant
    Filed: March 17, 2011
    Date of Patent: October 28, 2014
    Assignee: NGK Insulators, Ltd.
    Inventors: Yoshio Kikuchi, Haruo Otsuka
  • Patent number: 8841227
    Abstract: A catalyst for the conversion of methane to higher hydrocarbons including aromatic hydrocarbons comprises a support and molybdenum or a compound thereof dispersed on the support. The support comprises an aluminosilicate zeolite combined with a binder selected from silica, titania, zirconia and mixtures thereof. The catalyst is substantially free of aluminum external to the framework of the aluminosilicate zeolite.
    Type: Grant
    Filed: December 22, 2008
    Date of Patent: September 23, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Neeraj Sangar, Jocelyn A. Kowalski, Larry L. Iaccino, Kenneth R. Clem
  • Patent number: 8815763
    Abstract: A method of manufacturing a catalyst body which includes: soaking at least part of a fired zeolite-based body in a transition metal oxide solution; removing the body from the transition metal oxide solution; exposing the body to a humidified atmosphere at one or more temperatures above 20° C.; then drying the body; and calcining the body.
    Type: Grant
    Filed: May 26, 2011
    Date of Patent: August 26, 2014
    Assignee: Corning Incorporated
    Inventors: Steven Bruce Dawes, Steven Bolaji Ogunwumi
  • Patent number: 8809573
    Abstract: A process for the production of acetic acid and/or methyl acetate by the carbonylation of methanol, methyl acetate and/or dimethyl ether with carbon monoxide in the presence of a desilicated mordenite catalyst.
    Type: Grant
    Filed: May 6, 2010
    Date of Patent: August 19, 2014
    Assignee: BP Chemicals Limited
    Inventors: Gareth Gerald Armitage, Bogdan Costin Gagea, David John Law, John Glenn Sunley
  • Patent number: 8809216
    Abstract: The present invention relates to a catalyst for converting inferior acid-containing crude oil. Based on the total amount of the catalyst, said catalyst comprises from 1 to 50 wt % of a mesopore material, from 1 to 60 wt % of molecular sieves and from 5 to 98 wt % of thermotolerant inorganic oxides and from 0 to 70 wt % of clays. Said mesopore material is an amorphous material containing alkaline earth oxide, silica and alumina, and has an anhydrous chemical formula of (0-0.3)Na2O.(1-50)MO.(6-58)Al2O3.(40-92)SiO2, based on the weight percent of the oxides, wherein M is one or more selected from Mg, Ca and Ba. Said mesopore material has a specific surface area of 200-400 m2/g, a pore volume of 0.5-2.0 ml/g, an average pore diameter of 8-20 nm, and a most probable pore size of 5-15 nm. The catalyst provided in the present invention is suitable for the catalytic conversion of crude oil having a total acid number of greater than 0.
    Type: Grant
    Filed: January 9, 2009
    Date of Patent: August 19, 2014
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Jun Long, Jiushun Zhang, Huiping Tian, Yuxia Zhu
  • Patent number: 8785707
    Abstract: A catalyst that comprises at least one binder and at least one crystallized material with hierarchized and organized porosity in the fields of microporosity and mesoporosity is described, whereby said crystallized material consists of at least two elementary spherical particles, each of said particles comprising a mesostructured silicon-oxide-based matrix that has a mesopore diameter of between 1.5 and 30 nm and that has microporous and crystallized walls with a thickness of between 1 and 60 nm, whereby said elementary spherical particles have a maximum diameter of 200 microns. Said catalyst is used in a process for oligomerization of an olefinic feedstock that contains hydrocarbon molecules that have 2 to 12 carbon atoms per molecule.
    Type: Grant
    Filed: April 28, 2009
    Date of Patent: July 22, 2014
    Assignee: IFP Energies Nouvelles
    Inventors: Amandine Cabiac, Alexandra Chaumonnot, Laurent Simon
  • Patent number: 8765095
    Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.
    Type: Grant
    Filed: September 23, 2009
    Date of Patent: July 1, 2014
    Assignee: Massachusetts Institute of Technology
    Inventors: Jackie Y. Ying, Javier Garcia-Martinez
  • Patent number: 8747652
    Abstract: The present invention concerns a catalyst comprising at least one crystalline material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said crystalline material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having microporous and crystalline walls with a thickness in the range 1.5 to 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
    Type: Grant
    Filed: May 13, 2009
    Date of Patent: June 10, 2014
    Assignee: IFP Energies Nouvelles
    Inventors: Audrey Bonduelle, Alexandra Chaumonnot
  • Publication number: 20140141963
    Abstract: According to the invention there is provided a zeolite having a porous structure produced by forming the zeolite on a porous carbon substrate which has been substantially or completely removed, wherein (i) the zeolite was formed on the substrate at a loading of at least 8% by weight and/or (ii) the zeolite has a reinforcing layer.
    Type: Application
    Filed: June 27, 2012
    Publication date: May 22, 2014
    Inventors: Susan Jones, Paul Sermon
  • Patent number: 8716163
    Abstract: A hydrocarbon conversion catalyst, which comprises, based on the total weight of the catalyst, 1-60 wt % of a zeolite mixture, 5-99 wt % of a thermotolerant inorganic oxide and 0-70 wt % of clay, wherein said zeolite mixture comprises, based on the total weight of said zeolite mixture, 1-75 wt % of a zeolite beta modified with phosphorus and a transition metal M, 25-99 wt % of a zeolite having a MFI structure and 0-74 wt % of a large pore zeolite, wherein the anhydrous chemical formula of the zeolite beta modified with phosphorus and the transition metal M is represented in the mass percent of the oxides as (0-0.3)Na2O.(0.5-10)Al2O3.(1.3-10)P2O5.(0.7-15)MxOy.(64-97)SiO2, in which the transition metal M is one or more selected from the group consisting of Fe, Co, Ni, Cu, Mn, Zn and Sn; x represents the atom number of the transition metal M, and y represents a number needed for satisfying the oxidation state of the transition metal M.
    Type: Grant
    Filed: September 28, 2006
    Date of Patent: May 6, 2014
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SINOPEC
    Inventors: Yujian Liu, Huiping Tian, Xingtian Shu, Jun Long, Yibin Luo, Chaogang Xie, Zhenyu Chen, Liuzhou Zhao, Yuxia Zhu, Youbao Lu
  • Patent number: 8703636
    Abstract: A method of manufacturing a catalyst body which includes: combining one or more inorganic components with an inorganic binder, and optionally with an organic binder, to form a mixture, the one or more inorganic components comprising a primary phase material being zeolite, or CeO2—ZrO2, or a combination; forming the mixture into a shaped body; firing the shaped body to allow the inorganic binder to bind the one or more inorganic components; impregnating the shaped body with a source of a reducing or oxidizing element; and heating the impregnated shaped body to form a redox oxide from the source, the redox oxide being supported by the shaped body.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: April 22, 2014
    Assignee: Corning Incorporated
    Inventors: Steven Bolaji Ogunwumi, Mallanagouda Dyamanagouda Patil
  • Patent number: 8703635
    Abstract: This disclosure relates to a catalyst composition comprising (a) MCM-22 family material; and (b) a binder comprising at least 1 wt. % of a titanium compound based on the weight of said catalyst composition, wherein said titanium compound was anatase and rutile phases.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: April 22, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Christine N. Elia, Frederick Y. Lo, Jeffrey T. Elks, Darryl D. Lacy, Mohan Kalyanaraman
  • Patent number: 8685875
    Abstract: Methods for enhancing the mesoporosity of a zeolite-containing material. Such methods may comprise contacting a composite shaped article containing at least one zeolite and at least one non-zeolitic material with at least one pH controlling agent and at least one surfactant. Such methods may be performed under conditions sufficient to increase the pore volume of at least one 10 angstrom subset of mesoporosity.
    Type: Grant
    Filed: October 19, 2010
    Date of Patent: April 1, 2014
    Assignee: Rive Technology, Inc.
    Inventors: Javier Garcia-Martinez, Lawrence B. Dight, Barry K. Speronello
  • Patent number: 8673802
    Abstract: Disclosed are a molecular sieve catalyst and a preparation method thereof to produce light olefins from cracking naphtha catalytically in severe environments of high temperature and high moisture. In detail, the catalyst is prepared by spray-drying and calcining the mixed slurry, in which 0.01˜5.0 wt % of MnO2 and 1˜15 wt % of P2O5 are simultaneously imbedded in catalyst which consists of zeolite, clay and inorganic complex. According to the present invention, the method that manganese and phosphate are imbedded simultaneously in zeolite and inorganic complex is used to increases thermal-stability of obtained spherical catalyst, and increase olefin yield of cracking hydrocarbon such as naphtha by protecting acid-site of zeolite. To synthesize the required catalyst, the important procedures are mixing ratio and mixing sequence of Mn, P, zeolite, and inorganic complex.
    Type: Grant
    Filed: February 5, 2009
    Date of Patent: March 18, 2014
    Assignees: SK Innovation Co., Ltd., Korea Research Institute of Chemical Technology
    Inventors: Dae Hyun Choo, Hong Chan Kim, Suk Joon Kim, Ji Min Kim, Tae Jin Kim, Sun Choi, Seung Hoon Oh, Yong Seung Kim, Deuk Soo Park, Yong Ki Park, Chul Wee Lee, Hee Young Kim, Won Choon Choi, Na Young Kang, Bu Sub Song
  • Patent number: 8598397
    Abstract: Described is a process for the treatment of at least one zeolite having a pore size of less than or equal to 7 ? comprising at least a) a step for dealumination of said zeolite, b) a cationic exchange step using at least one cation other than H+, c) a step for treatment of said zeolite obtained in step b) in the presence of at least one molecular compound containing at least one silicon atom, and d) at least one heat treatment step. The present invention also concerns the preparation of a catalyst containing the zeolite treated in accordance with the treatment process the subject-matter of the invention and the use of said catalyst in a process for the oligomerization of an olefinic charge containing hydrocarbon molecules having from 2 to 12 carbon atoms per molecule.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: December 3, 2013
    Assignee: IFP Energies nouvelles
    Inventors: Laurent Simon, Sylvie Lacombe
  • Publication number: 20130299389
    Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.
    Type: Application
    Filed: July 17, 2013
    Publication date: November 14, 2013
    Inventor: Javier Garcia-Martinez
  • Patent number: 8546287
    Abstract: A group V metal/rhenium-modified molecular sieve catalyst can be used in hydrocarbon conversion reactions. Embodiments can provide a toluene conversion of at least 30 wt % with selectivity to benzene above 40 wt % and to xylenes above 40 wt % and non-aromatics selectivity of less than 2.0 wt %.
    Type: Grant
    Filed: May 31, 2010
    Date of Patent: October 1, 2013
    Assignee: Fina Technology, Inc.
    Inventors: James Butler, Olga Khabashesku, Darek Wachowicz, Callum Bailey
  • Publication number: 20130236382
    Abstract: Cu/mordenite catalysts were found to be highly active for the SCR of NO with NH3 and exhibited high resistance to alkali poisoning. Redox and acidic properties of Cu/mordenite were well preserved after poisoning with potassium unlike that of vanadium catalysts. Fe-mordenite catalysts also revealed much higher alkali resistivity than that of commercial V2O5/WO3—TiO2 (VWT) SCR catalyst which is currently used for NOx abatement in stationary installations. Unique support properties like high surface area and surface acidity, which are not available in the commercial VWT catalyst, seem to be essential requirements for the high alkali resistance. Mordenite-type zeolite based catalysts could therefore be attractive alternatives to conventional SCR catalysts for biomass fired power plant flue gas treatment.
    Type: Application
    Filed: August 26, 2011
    Publication date: September 12, 2013
    Applicant: TECHNICAL UNIVERSITY OF DENMARK
    Inventors: Putluru Siva Sankar Reddy, Anders Riisager, Rasmus Fehrmann
  • Patent number: 8524624
    Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.
    Type: Grant
    Filed: August 8, 2011
    Date of Patent: September 3, 2013
    Assignee: Massachusetts Institute of Technology
    Inventor: Javier Garcia-Martinez
  • Publication number: 20130225397
    Abstract: The present invention relate to a binderless molecular sieve catalyst and a process for preparing the same, which are mainly useful for solving the problems of the current catalysts, such as lower activity, less pore volume and worse diffusivity. The present invention relates to a novel binderless molecular sieve catalyst, comprising, based on the weight of the catalyst, 90-100 wt. % of a molecular sieve, 0-10 wt. % of a binder, and 0-10 wt. % of an anti-wear agent, wherein said catalyst has a pore volume of 0.1-0.5 ml/g, an average pore diameter of 50-100 nm, and a porosity of 20-40%; the anti-wear agent is selected from the rod or needle-like inorganic materials having a length/diameter ratio of 2-20. Said catalyst has the advantages of higher activity, greater pore volume, larger average pore diameter and porosity, and better diffusivity, and well solves said problems and can be used for the industrial preparation of binderless molecular sieve catalysts.
    Type: Application
    Filed: August 23, 2011
    Publication date: August 29, 2013
    Applicants: SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Guangwei Ma, Huiming Zhang, Jingxian Xiao, Liang Chen, Xiqiang Chen
  • Patent number: 8505285
    Abstract: A catalyst system includes a first catalytic composition and a second catalytic composition. The first catalytic composition includes a homogeneous solid mixture, which includes a first catalytic material disposed on a first substrate. The pores of the solid mixture have an average diameter of greater than about 45 nanometers. The second catalytic composition includes at least one of a zeolite or a second catalytic material disposed on a second substrate. The second catalytic material includes an element selected from the group that includes tungsten, titanium, and vanadium.
    Type: Grant
    Filed: October 6, 2010
    Date of Patent: August 13, 2013
    Assignee: General Electric Company
    Inventors: Benjamin Hale Winkler, Dan Hancu, Daniel George Norton, Ashish Balkrishna Mhadeshwar
  • Publication number: 20130190166
    Abstract: To provide a catalyst having excellent performance and durability by improving a NOx reduction ratio at 350° C. or higher without deteriorating excellent durability of a Ti—V—Mo—P catalyst in view of problems of conventional art.
    Type: Application
    Filed: September 5, 2011
    Publication date: July 25, 2013
    Applicant: BABCOCK-HITACHI KABUSHIKI KAISHA
    Inventors: Yasuyoshi Kato, Seiji Ikemoto
  • Patent number: 8481443
    Abstract: In a process for producing xylene by transalkylation of a C9+aromatic hydrocarbon feedstock with a C6 and/or C7 aromatic hydrocarbon, the C9+aromatic hydrocarbon feedstock, at least one C6 and/or C7 aromatic hydrocarbon and hydrogen are contacted with a first catalyst under conditions effective to dealkylate aromatic hydrocarbons in the feedstock containing C2+alkyl groups and to saturate C2+olefins formed so as to produce a first effluent. At least a portion of the first effluent is then contacted with a second catalyst under conditions effective to transalkylate C9+aromatic hydrocarbons with said at least one C6-C7 aromatic hydrocarbon to form a second effluent comprising xylene.
    Type: Grant
    Filed: April 18, 2012
    Date of Patent: July 9, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Doron Levin, April D. Ross, James H. Beech, Jr.
  • Patent number: 8475649
    Abstract: Methods and apparatus relate to processing of petroleum with a bed having a sorbent based diluent that the petroleum contacts upon passing through the bed. Magnetic properties of the sorbent and any other material, such as zeolite, used in the bed enable separation of such bed constituents based on a sulfided form of the sorbent being magnetic in contrast to a non-sulfided form of the sorbent being non-magnetic. Dividing the bed constituents into first and second portions by magnetic separation facilitates in selective replacing and/or regenerating the first portion independent of the second portion.
    Type: Grant
    Filed: August 8, 2012
    Date of Patent: July 2, 2013
    Assignee: Phillips 66 Company
    Inventors: Sundararajan Uppili, Donald R. Engelbert
  • Patent number: 8466080
    Abstract: A catalyst comprising an aluminosilicate zeolite having an MOR framework type, an acidic MFI molecular sieve component having a Si/Al2 molar ratio of less than 80, a metal component comprising one or more elements selected from groups VIB, VIIB, VIII, and IVA, an inorganic oxide binder, and a fluoride component.
    Type: Grant
    Filed: September 15, 2010
    Date of Patent: June 18, 2013
    Assignee: UOP LLC
    Inventor: Edwin P. Boldingh
  • Patent number: 8435909
    Abstract: The dual-zeolite catalyst for production of ethylbenzene is formed by mixing at least two different zeolites selected from mordenite, beta, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, SAPO-5, SAPO-34, SAPO-11 and MAPO-36 zeolites and an inactive alumina binder. The two zeolites have different topology and possess dissimilar and unique physical and chemical characteristics, including particle size, surface area, pore size and acidity. The preferred amount of the two zeolites may range from 10 to 90 wt % of the total catalyst amount in the final dried and calcined form, preferably the zeolites are in equal parts by weight.
    Type: Grant
    Filed: February 18, 2010
    Date of Patent: May 7, 2013
    Assignee: King Fahd University of Petroleum and Minerals
    Inventors: Sulaiman S. Al-Khattaf, Taiwo Odedairo