Active Ingredient Contains A Ketone, Aldehyde, Ether, Or Hydroxy Group, Wherein The H Of The Hydroxy Group May Be Replaced By A Substituted Or Unsubstituted Ammonium Ion Or A Group Ia Or Iia Light Metal Patents (Class 504/161)
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Patent number: 9550720Abstract: Provided is a method for industrially producing a conjugated Z-alken-yn-yl acetate such as Z-13-hexadecen-11-yn-yl acetate which is a sex pheromone component of a pine processionary moth, and an intermediate for the conjugated Z-alken-yn-yl acetate under mild conditions at a high yield. More specifically, provided is a method for producing a conjugated Z-alken-yn-yl acetate (5) comprising the steps of: reacting an ?-halo-2-alkynal (1) with an alkylidene triphenylphosphorane (3) through a Wittig reaction to obtain a conjugated Z-alken-yn-yl halide (4), and acetoxylating the conjugated Z-alken-yn-yl halide (4) into a conjugated Z-alken-yn-yl acetate (5).Type: GrantFiled: December 30, 2015Date of Patent: January 24, 2017Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Miyoshi Yamashita, Takehiko Fukumoto, Takeshi Kinsho
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Publication number: 20140249029Abstract: Suggested are solid agricultural compositions, comprising: (a1) at least one alkoxylated alcohol according to general formula (I) R1O(AO)nH, wherein R1 stands for an unsaturated, linear hydrocarbon residue having 12 to 22 carbon atoms and 1, 2, or 3 double bonds, AO comprises an ethylene oxide, propylene oxide, and/or butylene oxide unit, and n comprises an integer of from 1 to 60; (a2) at least one alkoxylated alcohol according to general formula (II) R2O(AO)mH, wherein R2 comprises a saturated, branched hydrocarbon residue having 8 to 36 carbon atoms, AO comprises an ethylene oxide, propylene oxide, and/or butylene oxide unit, and m comprises an integer of from 1 to 60; (b) at least one biocide, and optionally (c) at least one inert Broenstedt base and/or (d) at least one solvent, emulsifier, polymer or filler, therein the compositions are granules with a water content of less than 10% b.w.Type: ApplicationFiled: September 27, 2011Publication date: September 4, 2014Applicant: Cognis IP Management GmbHInventors: Jianhua Mao, Anbao Zuo
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Patent number: 8318638Abstract: An object of the present invention is to determine novel means of activating plants; more particularly, means of controlling plant growth, such as means of promoting growth, means of controlling dormancy, means of imparting tolerance against stress for plants (dryness, high or low temperatures, osmotic pressure, etc.), and means of preventing aging. The present inventors have found that the above object can be achieved by providing plant activators containing, as an active ingredient, C4-C24 ketol fatty acids, in particular, 9-hydroxy-10-oxo-12(Z),15(Z)-octadecadienoic acid.Type: GrantFiled: December 6, 2010Date of Patent: November 27, 2012Assignee: Shiseido Company, Ltd.Inventors: Mineyuki Yokoyama, Shoko Yamaguchi, Toshii Iida, Kiyotaka Kojima, Koji Kobayashi, Osamu Tanaka
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Patent number: 7772156Abstract: Microbicidal compositions including (a) cyanodithiocarbimate and (b) an N-alkyl heterocyclic compound; a triazole compound or salt thereof or metal complex thereof; a microbicide with an activated halogen atom or a formaldehyde releasing compound; 1,4-bis(bromoacetoxy)-2-butene; 2-(thiocyanomethylthio)benzothiazole; a methylene-bis(thiocyanate); a halogenated acetophenone; a halopropynl compound; an iodosulfone; a phenol; a halocyanoacetamide compound and/or a quaternary ammonium compound are described. Components (a) and (b) can be present in a synergistically effective amount to control the growth of at least one microorganism. Methods for controlling the growth of microorganisms with the compositions are also disclosed.Type: GrantFiled: November 1, 2006Date of Patent: August 10, 2010Assignee: Buckman Laboratories International, Inc.Inventor: Stephen D. Bryant
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Publication number: 20100000457Abstract: A method of controlling target aquatic microorganism pest populations by exposing the target population to an effective amount of an aquacidal compound. The aquacidal compounds are selected from the group consisting of quinones, anthraquinones, naphthalenediones, quinine, warfarin, coumarins, amphotalide, cyclohexadiene-1,4-dione, phenidione, pirdone, sodium rhodizonate, apirulosin and thymoquinone. The method is particularly effective for treating ballast water of ships or other enclosed volumes of water subject to transport between or among geographic areas to control the relocation of plants, toxic bacteria, and animals contained in the water.Type: ApplicationFiled: September 8, 2009Publication date: January 7, 2010Inventors: Horace G. Cutler, Stephen J. Cutler, David Wright, Rodger Dawson
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Patent number: 6949250Abstract: We have now discovered that certain 9,10-anthraquinone derivatives we developed possess potent activity against O. perornata while possessing a sufficiently high level of solubility in water to make their activity against O. perornata viable. These compounds possess a high level of activity against O. perornata yet are relatively non-toxic to green algae and fishes. The compounds also possess a relatively short half-life. The compounds represent a new means to providing compounds possessing a high degree of selective activity against blue-green algae while being physiologically tolerated by catfish and green algae. The compounds provide a means for controlling blue-green algae in managed bodies of water that are destined for public use or consumption.Type: GrantFiled: December 16, 2002Date of Patent: September 27, 2005Assignees: The United States of America as represented by the Secretary of Agriculture, The University of MississippiInventors: Kevin K. Schrader, N. P. Dhammika Nanayakkara
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Patent number: 6649567Abstract: Algal defacement of coated and non-coated porous masonry and wood construction materials is prevented by pre-treatment of the construction material with an aqueous composition of a copolymer that releases 2-propenal (acrolein) over time.Type: GrantFiled: October 11, 2001Date of Patent: November 18, 2003Assignee: ISP Investments Inc.Inventor: William B. Woods
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Publication number: 20030092575Abstract: Algal defacement of coated and non-coated porous masonry and wood construction materials is prevented by pre-treatment of the construction material with an aqueous composition of a copolymer that releases 2-propenal (acrolein) over time.Type: ApplicationFiled: October 11, 2001Publication date: May 15, 2003Inventor: William B. Woods
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Patent number: 6515184Abstract: The present invention relates to novel bicyclic cyclopentane-1,3-dione derivatives of the formula (I) to a process for their preparation and to their use as pesticides and herbicides.Type: GrantFiled: April 6, 1998Date of Patent: February 4, 2003Assignee: Bayer AktiengesellschaftInventors: Reiner Fischer, Michael Ruther, Alan Graff, Arno Widdig, Jacques Dumas, Christoph Erdelen, Peter Dahmen, Markus Dollinger, Ulrike Wachendorff-Neumann
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Publication number: 20020098979Abstract: A method of controlling target aquatic microorganism pest populations by exposing the target population to an effective amount of an aquacidal compound. The aquacidal compounds are selected from the group consisting of quinones, anthraquinones, naphthalenediones, quinine, warfarin, coumarins, amphotalide, cyclohexadiene-1,4-dione, phenidione, pirdone, sodium rhodizonate, apirulosin and thymoquinone. The method is particularly effective for treating ballast water of ships or other enclosed volumes of water subject to transport between or among geographic areas to control the relocation of plants, toxic bacteria, and animals contained in the water.Type: ApplicationFiled: December 6, 2001Publication date: July 25, 2002Inventors: Stephen J. Cutler, Horace G. Cutler, David Wright, Rodger Dawson
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Publication number: 20020098978Abstract: A method of controlling target aquatic microorganism pest populations by exposing the target population to a toxic amount of an aquacidal compound comprising an anthraquinone. The method is particularly effective for treating ballast water of ships or other enclosed volumes of water subject to transport between or among geographic areas to control the relocation of plants, toxic bacteria, and animals contained in the water.Type: ApplicationFiled: December 6, 2001Publication date: July 25, 2002Inventors: Stephen J. Cutler, Horace G. Cutler, David Wright, Rodger Dawson
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Patent number: 6391925Abstract: A liquid composition of phenolic compounds can be formed in the substantial absence of a solvent and a surfactant. This composition includes at least one substituted phenol and a halo-substituted phenol. In one embodiment, the composition includes benzylchlorophenol and at least one of phenylphenol and tert-pentylphenol. In another embodiment, the composition includes benzylchlorophenol, phenylphenol, and tert-pentylphenol. The composition may be useful for preparing an antimicrobial material. A liquid phenolic composition can be prepared by forming a composition having at least one substituted phenol and a halo-substituted phenol in the substantial absence of a solvent and surfactant and mixing the composition until a liquid phenolic composition is formed.Type: GrantFiled: January 13, 2000Date of Patent: May 21, 2002Assignee: Ecolab Inc.Inventor: Kim R. Smith
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Patent number: 6346262Abstract: Controlled release compositions of matter are disclosed comprising complexes for treating a population of one or more aquatic organisms in a column of water. The complexes comprise at least one system wherein the system comprises at least one bioactive agent as a component selected for treating a population of aquatic organisms, at least one carrier component, and at least one coating component for regulating the controlled release rate and release profile of the bioactive agent in water or at least one bioactive agent and one joint-function component that can serve as both a carrier and coating to regulate the controlled release rate and release profile of the bioactive agent in water, with or without optional binder components and/or additional formulation materials. The components are selected to sink or float so that the complexes will permeate and/or remain in any planar or volumetric segment of a water column for a period of time that is sufficient to effectively treat a population of aquatic organisms.Type: GrantFiled: November 29, 1999Date of Patent: February 12, 2002Assignee: Lee County Mosquito Control DistrictInventor: Richard Levy
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Patent number: 6340468Abstract: A method of controlling or inhibiting the growth of aquatic plants and animals applies an effective amount of an active compound. The active compounds are selected from the group consisting of quinones, anthraquinones, naphthalenediones, quinine, warfarin, coumarins, amphotalide, cyclohexadiene-1,4-dione, phenidione, pirdone, sodium rhodizonate, apirulosin and thymoquinone. The compounds are particularly effective for treating ballast water of ships to control the relocation of plants and animals contained in the ballast water.Type: GrantFiled: February 17, 2000Date of Patent: January 22, 2002Assignee: Garnett, Inc.Inventors: Horace G. Cutler, Stephen J. Cutler, David Wright, Rodger Dawson
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Patent number: 6337078Abstract: Controlled release compositions of matter are disclosed comprising complexes for treating a population of one or more aquatic organisms in a column of water. The complexes comprise at least one system wherein the system comprises at least one bioactive agent as a component selected for treating a population of aquatic organisms, at least one carrier component, and at least one coating component for regulating the controlled release rate and release profile of the bioactive agent in water or at least one bioactive agent and one joint-function component that can serve as both a carrier and coating to regulate the controlled release rate and release profile of the bioactive agent in water, with or without optional binder components and/or additional formulation materials. The components are selected to sink or float so that the complexes will permeate and/or remain in any planar or volumetric segment of a water column for a period of time that is sufficient to effectively treat a population of aquatic organisms.Type: GrantFiled: December 10, 1999Date of Patent: January 8, 2002Assignee: Lee County Mosquito Control DistrictInventor: Richard Levy
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Patent number: 6294584Abstract: The present invention provides for methods for fumigating soil containing deleterious organisms such as nematodes. The methods utilize an effective amount of acrolein over sole demand for acrolein which when added to the soil will control the organisms but will not exhibit phytotoxicity towards the existing or future plant life.Type: GrantFiled: January 29, 1999Date of Patent: September 25, 2001Assignee: Betzdearborn Inc.Inventors: Edmund J. Bockowski, Dwight P. Davis
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Patent number: 6235300Abstract: An plant protecting composition comprising a biocide component and an adjuvant component wherein the adjuvant component includes at least one surfactant selected from the group consisting of topped alcohol alkoxylates and peaked alcohol alkoxylates and combinations thereof in combination with a conventional alcohol alkoxylate.Type: GrantFiled: January 19, 1999Date of Patent: May 22, 2001Assignee: Amway CorporationInventor: Ernest H. Brumbaugh
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Patent number: 6149929Abstract: A composition for effective algae control comprising bacteria and humic acid made by extracting the liquid from barley straw soaked in water for a period of time.Type: GrantFiled: January 19, 1999Date of Patent: November 21, 2000Inventor: Robert S. Friedman
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Patent number: 5998330Abstract: A method of treating vegetation by application of a microbial insecticide in which a quinone has been covalently bonded to the viral occlusion body surface of the microbial insecticide in order to improve the UV stability of the microbial insecticide by forming a protective shield around the pathogen.Type: GrantFiled: February 21, 1997Date of Patent: December 7, 1999Assignee: The Board of Trustees of the University of ArkansasInventor: Gary W. Felton
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Patent number: 5990043Abstract: An anti-fouling composition comprising a carrier, and a binder, the improvement which comprises an effective amount of at least one insecticide. The composition is applied to the surfaces of articles which come into contact with seawater or brackish water, especially wood. Other conventional anti-fouling agents may also be present.Type: GrantFiled: June 17, 1996Date of Patent: November 23, 1999Assignee: Bayer AktiengesellschaftInventors: Martin Kugler, Michael Londershausen, Heinrich Schrage, Hermann Uhr, Franz Kunisch
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Patent number: 5866614Abstract: The present invention provides for methods for fumigating soil containing deleterious organisms such as nematodes. The methods utilize an effective amount of acrolein which when added to the soil will control the organisms but will not exhibit phytotoxicity towards the existing or future plant life and an effective amount of a detoxification compound such as for example: sulfites, bisulfites, ammonia or ammonium compounds.Type: GrantFiled: August 6, 1997Date of Patent: February 2, 1999Assignee: BetzDearborn Inc.Inventors: Edmund J. Bockowski, Dwight P. Davis
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Patent number: 5753593Abstract: An environmentally compatible aquatic herbicidal composition comprising at least one surfactant and at least one high terepene containing natural oil to effectively control target aquatic vegetation including Red Azolla, Salvinia Molesta and Lemna.Type: GrantFiled: December 20, 1995Date of Patent: May 19, 1998Inventors: Erroll M. Pullen, Melvin D. Pullen
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Patent number: 5723498Abstract: A composition which is capable of releasing acrolein and is easy to handle contains (i) an acetal of acrolein with a C.sub.1-6 alcohol with 1 to 4 hydroxyl groups and (ii) an acid soluble therein and chemically compatible with a pK.sub.s value of less than 4 and (iii) is anhydrous. A preferred composition contains 2-vinyl-1,3-dioxolane as acetal, anhydrous oxalic acid, fumaric acid or maleic acid or a mixture of mono- and di(C.sub.1 - to C.sub.3 -)alkyl phosphate as acid and, in addition, a non-ionic surfactant. The acrolein is released at the site of use upon contact with for example water for the purpose of combatting microbial, vegetable and animal pests.Type: GrantFiled: September 13, 1995Date of Patent: March 3, 1998Assignee: Degussa AktiengellschaftInventors: Peter Werle, Martin Trageser, Oswald Helmling, Harold Jakob
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Patent number: 5696052Abstract: The direct handling of acrolein for the purpose of combatting microbial, vegetable and animal pests in water and soil is problematic on account of the potential for danger of acrolein. According to the invention a composition which releases acrolein upon contact with water at the site of use and is easy to handle is used.The composition in accordance with the invention contains an acrolein acetal, preferably 2-vinyl-1,3-dioxolane, and a compound hydrolyzable to an acid with a pK.sub.s value of less than 4, especially one from the series of organic acid anhydrides, organic acid halides and inorganic halogen compounds forming hydrogen halide upon hydrolysis.Type: GrantFiled: June 7, 1995Date of Patent: December 9, 1997Assignee: Degussa AktiengesellschaftInventors: Peter Werle, Martin Trageser, Oswald Helmling, Harald Jakob
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Patent number: 5656670Abstract: Synergistic antimicrobial combinations comprising N-decyl-N-isononyl-N,N-dimethyl ammonium chloride and 2-bromo-2-nitropropane-1,3,-diol, are disclosed. Methods for inhibiting microbial growth using these synergistic antimicrobial combinations are also disclosed.Type: GrantFiled: May 2, 1996Date of Patent: August 12, 1997Assignee: Calgon CorporationInventors: Kevin I. Ajoku, Nancy J. Kapp
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Patent number: 5529700Abstract: A composition comprising a water-dispersible ionene polymer and a water-dispersible di-lower-alkyl ammonium halide polymer (for example, a polymer of dimethyl diallyl ammonium chloride) is disclosed. These polymers are present in the composition in a ratio effective to function synergistically as an algistatic or algicidal agent when an effective amount of the composition is dispersed in a body of water. Examples of suitable bodies of water are swimming pools, spas, lakes, rivers, or water in an industrial water system, such as a cooling water system. Also, a method of treating water which is susceptible to the growth of algae is disclosed. The method is carried out by incorporating in the water an at least algistatic amount of the composition.Type: GrantFiled: September 27, 1995Date of Patent: June 25, 1996Assignee: Laporte Water Technologies & Biochem, Inc.Inventors: David J. Kierzkowski, Pamela A. Kuske
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Patent number: 5470586Abstract: A method of controlling the attachment of organisms to an underwater surface is disclosed. The method comprises contacting the organisms with a compound of Formula I ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently hydrogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, halogen, or hydroxyl. Antifouling coatings and cementitious compositions containing a compound of Formula I are also disclosed.Type: GrantFiled: April 11, 1994Date of Patent: November 28, 1995Assignee: Duke UniversityInventor: Donald J. Gerhart
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Patent number: 5466717Abstract: Halogenated 4'-methoxyacetophenones of formula I: ##STR1## wherein X is a halogen; Y is a halogen; and n is 1 or 2 as microbicides for inhibiting the growth of microorganisms in aqueous systems and on surfaces, as well as for inhibiting slime formation in aqueous systems and biocidal compositions containing effective amounts of the halogenated 4'-methoxyacetophenones.Type: GrantFiled: December 15, 1993Date of Patent: November 14, 1995Assignee: Buckman Laboratories Int'l, Inc.Inventors: S. Rao Rayudu, Joseph G. Fenyes, Thomas E. McNeel
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Patent number: 5322834Abstract: This invention relates to synergistic antimicrobial and biocidal compositions comprising 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one and one or more commercial biocides for more effective, and broader control of microorganisms in various industrial systems.Type: GrantFiled: October 21, 1993Date of Patent: June 21, 1994Assignee: Rohm and Haas CompanyInventor: Jemin C. Hsu
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Patent number: 5246913Abstract: This invention relates to synergistic antimicrobial and biocidal compositions comprising 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one and one or more commercial biocides for more effective, and broader control of microorganisms in various industrial systems.Type: GrantFiled: October 30, 1992Date of Patent: September 21, 1993Assignee: Rohm and Haas CompanyInventor: Jemin C. Hsu
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Patent number: 5236888Abstract: Synergistic microbicidal compositions are disclosed, comprising 4,5-dichloro-2-cyclohexyl-3-isothiazolone and one or more known microbicides for more effective, and broader control of microorganisms in various systems.Type: GrantFiled: October 21, 1992Date of Patent: August 17, 1993Assignee: Rohm and Haas CompanyInventor: Jemin C. Hsu
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Patent number: 5227360Abstract: Synergistic antialgal compositions comprising substituted fluoroalkyl diphenylethers and a material selected from the group consisting of sodium hypochlorite, halodialkylhydantoin, n-alkyl dimethyl benzylammonium chloride, 2,2-dibromo-3-nitrilopropionamide, 2-bromo-2-nitro-1,3-propanediol, poly[oxyethylene(dimethylimino)ethylene(dimethylimino)ethylene dichloride], 3-iodo-2-propynylbutylcarbamate, sodium N-methyldithiocarbamate, 3-(3,4-dichlorophenyl)-1,1-dimethylurea, N-(phosphonomethyl)glycine and salts thereof, zinc bis(dimethyldithiocarbamate), p-tolydiiodomethylsulfone and fatty acid salt in ratios to each other which exhibit synergism are disclosed. Particularly effective combinations are based on oxyfluorfen as the diphenylether for use in protecting aqueous systems, such as latices and cooling water systems, from algal growth.Type: GrantFiled: August 5, 1992Date of Patent: July 13, 1993Assignee: Rohm and Haas CompanyInventors: Samuel E. Sherba, Terry M. Williams, Gary L. Willingham
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Patent number: RE35320Abstract: A process for increasing the rate of plant growth. Plants are treated with one or more acids, which are condensation products of glycolic and/or L-lactic acid. These acids also increase the concentration of chlorophyll, increase the rate of new plant formation when plants are propagated by tissue culture, decrease the amount of added nutrients required for plant growth, and protect plants against the toxic effects of salts. Certain of the acids are useful for increasing the rate of root formation in the plant.The questions raised in reexamination request Nos. 90/002,306, filed Mar. 26, 1991 and 90/003,035 filed Apr. 27, 1993, have been considered and the results thereof are reflected in this reissue patent which constitutes the reexamination certificate required by 35 U.S.C. 307 as provided in 37 CFR 1.570(e).Type: GrantFiled: January 6, 1995Date of Patent: August 27, 1996Assignee: CPC International Inc.Inventors: Alan M. Kinnersley, Taylor C. Scott, III, John H. Yopp, George H. Whitten