Abstract: Bi-based superconducting ceramic films having high Tc's and high critical current densities are formed. The superconducting film is formed on a non-superconducting saubstrate of Bi.sub.2 Sr.sub.1-x Ca.sub.x O.sub.y. Due to crystalline similarity between the superconducting film and the underlying ceramic substrate, the crystalline structure of the film is improved. There are few impurities which contaminate the superconducting film since the constituent elements of the substrate are also the consitutents of the superconducting film.

Abstract: A superconducting composite comprising a compound oxide type superconductor and an outer metal pipe on which said superconductor is supported, characterized in that (i) said outer metal pipe is made of at least one of metals selected from a group comprising gold, silver and platinum metals and their alloys or (ii) an intermediate layer made of these precious metals is interposed between the compound oxide and the metal pipe.The composite may be in a form of a solid pipe or a hollow pipe having a superconducting thin layer deposited on an inner surface of the metal pipe.

Abstract: A ceramic superconductor comprises a substantially nonmagnetic preannealed nickel-based alloy substrate which supports a ceramic superconductor. The substrate may include aluminum to strengthen the substrate, make it less magnetic and enhance its chemical compatibility with the ceramic superconductor. The ceramic is formed on the substrate by sintering superconductor grains at temperatures above 1000.degree. C. to enhance densification of the ceramic.

Abstract: High T.sub.c superconducting devices are described in which controlled grain boundaries in a layer of the superconductors forms a weak link or barrier between superconducting grains of the layer. A method is described for reproducibly fabricating these devices, including first preparing a substrate to include at least one grain boundary therein. A high T.sub.c superconductor layer is then epitaxially deposited on the substrate in order to produce a corresponding grain boundary in the superconducting layer. This superconducting layer is then patterned to leave at least two regions on either side of the grain boundary, the two regions functioning as contact areas for a barrier device including the grain boundary as a current flow barrier. Electrical contacts can be made to the superconducting regions so that bias currents can be produced across the grain boundary which acts as a tunnel barrier or weak link connection.

Abstract: Grain boundary, weak-link junctions are formed at a predermined location of a uniform, planar substrate by depositing superconducting film on two sections of the substrate. The film is grown as a bicrystal having two distinct areas of superconducting film whose crystal lattices are rotated with respect to each other, either in-plane or out-of-plane, by more than 5.degree. and less than 90.degree.. The grain boundary acts as a weak link junction. The film can be induced to grow as a bicrystal by depositing intermediate strata such as seed layers or buffer layers or by modifying the growth conditions during deposition.

Abstract: A light detecting device includes a signal input portion which generates a current upon input of a light signal, a signal detecting portion including a superconductor which detects the light signal with injection of the generated current, and electrodes through which the generated current is injected into the superconductor.

Abstract: A superconductive device and method for the manufacture thereof is disclosed, having a tunneling Josephson element comprising a first oxide superconductor electrode, a blocking layer consisting of a metal substantially inert to oxygen formed on the surface of the oxide superconductor, an insulating thin film layer formed on the blocking layer, and a second superconductor electrode opposing said first electrode formed on the insulating thin film.

Abstract: A superconducting variable phase shifter providing improved performance in the microwave and millimeter wave frequency ranges. The superconducting variable phase shifter includes a transmission line and an array of superconducting quantum interference devices (SQUID's) connected in parallel with and distributed along the length of the transmission line. A DC control current I.sub.DC varies the inductance of the individual SQUID's and thereby the distributed inductance of the transmission line, thus controlling the propagation speed, or phase shift, of signals carried by the transmission line. The superconducting variable phase shifter provides a continuously variable time delay or phase shift over a wide signal bandwidth and over a wide range of frequencies, with an insertion loss of less than 1 dB. The phase shifter requires less than a milliwatt of power and, if one or more of the Josephson junctions fails, the whole device remains operational, since the SQUID's are connected in parallel.

Abstract: A laminated ceramic superconductor which comprises at least two layers of ceramic superconductor and a stabilizing metal layer interposed between said ceramic superconductor layers, which has improved flexibility and increased critical current density.

Abstract: A pre-existing superconductor ceramic which is bonded to a substrate is passed through a relatively short heating zone to melt the ceramic superconductor. As the superconductor is subsequently cooled after it has passed through the heating zone, a temperature gradient is established along the superconductor which causes the melted crystals to renucleate and grow along and parallel to the temperature gradient. The resulting crystalline structure exhibits improved superconducting properties when the superconductor is placed in the presence of a magnetic field. For appropriate applications, the substrate can be formed as a wire.

Abstract: A superconducting thick film circuit board or thick film superconductor obtained by forming a rod-like crystal superconducting composite layer comprising a superconductor made of a compound of M-Ba-Cu-O, M being Y and/or a lanthanide element, and a composite of Ag and Pt on a stabilized zirconia substrate has a high Jc value and good superconducting properties.

Abstract: A flexible superconducting wire element comprising a flexible tape of partially stabilized (.about.3 mole % yttria) yttria-stabilized zirconia (YSZ), a buffer layer of fully stabilized (between 8 and 18 mole % yttria, preferably 9 mole %) YSZ deposited on the flexible tape, and a high-temperature, perovskite superconductor such as YBaCuO deposited on the buffer layer. The tape provides the strength while remaining flexible. The buffer layer is flexible because of its thinness (.about.100 nm), but provides a good crystallographic template for the growth of oriented perovskite superconductors. Thereby, the superconducting properties of the wire element approach those of a superconducting film deposited on a rigid substrate.

Abstract: A manufacturing method for the thin film superconductor is disclosed in which photons having energies larger than ultraviolet rays are irradiated to the thin film superconductor on or after formation of the thin film. Further, manufacturing methods for superconductive magnetic memory, Josephson device and superconductive transistor are disclosed.

Abstract: A superconducting wire comprises a flexible base material having average surface roughness of not more than 0.05 .mu.m and an oxide superconducting layer formed on the base material.A superconducting wire comprises a flexible base material of yttria stabilized zirconia containing less than 0.1 percent by weight of an Al impurity and an oxide superconducting layer formed on the base material.

Abstract: The superconducting device according to the present invention is provided with a superconducting thin film of the Tl-Ba-Ca-Cu oxide deposited on a substrate thereof. Consequently, the device can be produced at a low cost because no rare earth elements are required.The superconducting thin film according to the present invention is formed by sputtering on substrate from a Tl-Ba-Ca-Cu oxide target by means of the sputtering method, followed by annealing in an oxidizing atmosphere. In this way, according to the present invention, it is possible to produce a superconducting thin film of the Tl-Ba-Ca-Cu oxide in a simple way by using an ordinary sputtering apparatus.

Abstract: A method for manufacturing a superconducting device comprises the steps of forming a blocking film by means of an optical vapor deposit reaction on the surface of an oxide superconducting material; and then adding oxygen into the oxide superconducting material by the implementation of a heat treatment.

Abstract: A superconducting thin film of Bi-containing compound oxide deposited on a substrate, a buffer layer made of Bi.sub.2 O.sub.3 being interposed between the superconducting thin film and the substrate.

Abstract: A thin film superconductor assembly is disclosed along with a method of fabricating same. The assembly comprises a self-supporting substrate defining at least a portion of a containment for a flow of cryogenic fluid, a dielectric layer adherent to a surface of the substrate, a thin film superconductor adherent to the dielectric layer and a moisture and oxygen impervious electrically insulating coating covering the thin film superconductor. A method of forming such thin film superconductor assembly, wherein the dielectric layer consists essentially of aluminum nitride, comprises growing the aluminum nitride dielectric layer integrally on the surface of the substrate.

Abstract: A HTSC layered structure comprising a substrate such as sapphire, a strontium titanate buffer layer and a HTSC film such as YBa.sub.2 Cu.sub.3 O.sub.7 provides a superconductor having lower surface resistance and a narrower transition temperature.

Abstract: A HTSC layered structure comprising a substrate such as calcium titanate and a HTSC film such as YBa.sub.2 Cu.sub.3 O.sub.7. Use of a thin buffer layer of calcium titanate on sapphire provides a YBa.sub.2 Cu.sub.3 O.sub.7-x film with higher critical current.

Abstract: The superconducting material YBa.sub.2 Cu.sub.3 O.sub.7, which loses its superconducting qualities when exposed to water, is passivated against such water damage by a thin film on its surface comprised of a mixed phase which includes YBa.sub.2 Cu.sub.3 O.sub.(7-x) F.sub.2x, where 0<X.ltoreq.1/2.

Abstract: A cubic perovskite crystal structure is disclosed satisfying the unit cell formula:R.sub.0.33+z A.sub.0.67 C.sub.1-y O.sub.3-xwhereR, A and C represent rare earth, alkaline earth and copper atoms, respectively, capable of forming a superconductive R.sub.1 A.sub.2 C.sub.3 orthorhombic perovskite crystal structure;x is 0.67 to 1.0;y is up to 0.2; andz is up to 0.1.The crystal structure can be used to form superconductive superlattices and weak links for Josephson junction devices. The crystal structure can be produced by laser ablation deposition at a temperature below that required for the formation of a superconductive R.sub.1 A.sub.2 C.sub.3 orthorhombic perovskite crystal structure. The crystal structure can be used as a substrate for the subsequent deposition of an R.sub.1 A.sub.2 C.sub.3 orthorhombic perovskite crystal structure.

Abstract: A superconducting fiber bundle includes carrier material formed by fibers of carbon, silicon carbide, steel, boron or glass. The fibers have a superconducting coating formed of a superconducting, non-metallic, inorganic material. The coating of the fibers is carried out from the liquid phase or the gas phase.

Abstract: Superconducting device include a type having a structure of a superconductor--a normal-conductor (or a semiconductor)--a superconductor, and a type having a superconducting weak-link portion between superconductors.The superconductors constituting the superconducting device are made of an oxide of either of perovskite type and K.sub.2 NiF.sub.4 type crystalline structures, containing at least one element selected from the group consisting of Ba, Sr, Ca, Mg, and Ra; at least one element selected from the group consisting of La, Y, Ce, Sc, Sm, Eu, Er, Gd, Ho, Yb, Nd, Pr, Lu, and Tb; Cu; and O. In addition, the c-axis of the crystal of the superconductor is substantially perpendicular to the direction of current flowing through this superconductor.

Abstract: A super conducting material is disclosed which exhibits super conducting properties at higher temperature than known so far. The super conducting by the invented materials is exhibited at temperatures of over 110.degree. K. Various combinations of the components exhibits superconductivities even at temperatures of around 273.degree. K. or even around 300.degree. K. Contrary to known art superconducting materials, which require super cooled conditions and are suited only to sophisticated applications, and thereby have limited applications, the materials of this inventions do not always require super cooled conditions are suited for limitless applications and can work even at room temperature conditions. While a large range of choice of materials are suggested a few important combinations are made of oxides of Bismuth, Barium and Copper. Replacement of Barium by Thantalium gives additional advantages.

Abstract: An apparatus for magnetic measurement using superconductive magneto-resistive film which is disposed in a magnetic field with the surface of the superconductive magneto-resistive film directed in parallel with the direction of the magnetic field so that the magnetic hysterisis property of the film can be avoided and the accuracy of the measurement can be much improved.

Abstract: There is disclosed the structure of a superconductive wiring fabricated on an insulating substrate comprising a conductive pattern having at least one wiring strip of a superconductive ceramic formed on the insulating substrate and a protective film covering the wiring pattern and formed of a basic oxide, the basic oxide hardly reacts with the superconductive ceramic because of the fact that most of the superconductive ceramics are bases, then the wiring strip is allowed to stay in the superconductive state for a prolonged period of time.

Abstract: A superconducting composite comprising a compound oxide type superconductor and an outer metal pipe on which said superconductor is supported, characterized in that (i) said outer metal pipe is made of at least one of metals selected from a group comprising gold, silver and platinum metals and their alloys or (ii) an intermidiate layer made of these precious metals is interposed between the compound oxide and the metal pipe.The composite may be in a form of a solid pipe or a hollow pipe having a superconducting thin layer deposited on an inner surface of the metal pipe.

Abstract: A multilayer superconducting thin film composite article, comprising a carbon-containing substrate, and an interlayer comprising a material selected from the group consisting of zirconium, yttrium, niobium, and carbides and oxides thereof, platinum, iridium, gold, palladium, and silver, and an overlayer comprising an HTSC material. The carbon-containing substrate preferably comprises diamond and the interlayer preferably comprises a zirconium carbide sub-layer at the interface with the substrate, an intermediate sub-layer of zirconium metal, and an outer sub-layer of zirconium oxide at the interface with the HTSC material overlayer. The superconducting thin film material may comprise a copper oxide HTSC material, with YBaCuO, TlBaCaCuO, and BiSrCaCuO HTSC materials being preferred.

Abstract: A VLWIR proximity effect detector 10 includes a substrate 12, a bulk superconducting material 14, a proximity layer 16 which overlies a portion of the bulk superconducting material 14, an insulator layer 17 and a transparent tunnelling electrode 18. Detector electrical contacts 19 are provided on the proximity layer 16 and on the electrode 18. VLWIR, indicated by the arrows, is absorbed in proximity layer 16 and causes a detectable modulation of tunnelling characteristics (current or voltage) between the proximity layer 16 and the electrode 18. The proximity layer has a thickness on the order of a coherence length for the material which comprises the proximity layer. In accordance with the invention it has been determined that a spatially varying energy gap (E.sub.gap) induced in the proximity layer by the adjacent superconducting material results in the proximity layer having a longer cut off wavelength than that of the adjacent bulk superconducting material. The lower value of the induced E.sub.

Abstract: An excellent oxide series superconductive sintered body can be provided which can be joined to a metallic member easily and economically at low temperatures without causing peeling-off and deformation of the metallic member, cracks in the sintered body, and deterioration of the sintered body, by coating the surface of the sintered body with a coating metal. A method of producing the sintered body having the coating metal is also provided.

Abstract: The invention relates to a process for making a superconducting connection between a pair of superconducting ceramic oxide pieces, each of the pieces having been formed by combining the metallic elements of the superconducting oxide in substantially the stoichiometric proportions needed to form the superconducting oxide into a precursor and forming the precursor into a shaped piece. The process comprises the steps of: contacting each of the shaped pieces with the other; connecting each of the shaped pieces to the other by means for forming a metallurgical bond between the shaped pieces; and oxidizing the connected shaped pieces under conditions sufficient to oxidize the metallic elements to the superconducting oxide.In other embodiments of the invention, the process is for forming a superconducting connection between a pair of pieces having a superconducting ceramic oxide/noble metal composition; or for forming a joint between a superconducting ceramic oxide and a normal conductor.

Abstract: A tape based on a superconducting oxide containing Cu-O, the tape being characterized by the fact that it comprises a substrate of flexible metal or composite material having a rectangular cross-section and provided on at least one of its faces with a cavity-free film of perovskite type superconducting oxide having congruent or quasi-congruent melting or peritectic decomposition close to a eutectic point, the thickness of said film lying in the range 1 .mu.m to 100 .mu.m, the orientation of the C axis of the superconducting crystals being perpendicular to said face of said substrate.

Abstract: A two-dimensional array of Josephson junctions is used as a high-frequency oscillator capable of emitting coherent power of predetermined frequencies since the geometry of the two-dimensional array allows the individual Josephson junctions to phase lock at predetermined frequencies. The array is controlled at a given voltage and excited by the application of DC current through the array, in effect providing a rapidly tunable DC-to-AC converter at GHz and THz frequencies. The oscillator operates without the application of external high frequency signals or a connection to a cavity resonator. Load matching and other adjustments can be made by selecting the appropriate number of Josephson junctions in the array, selecting a damping factor which determines non-hysteretic operation, adding resistive shunts or a superconducting ground plane.

Abstract: An oxide superconductor having a high critical temperature is provided with a passivation coating comprising a first layer of a Group II oxide, such as magnesium oxide, and a second layer of a polymer, such as polyimide. The Group II oxide is formed under conditions to be substantially amorphous. After depositing the Group II layer, the encapsulated superconductor is heated to an elevated temperature for a period of time in an oxidizing atmosphere. This restores the high critical temperature to its original value. The polymer is then coated on top of the Group II oxide and cured. The passivation coating is resistant to strong acids, strong bases, and water, is robust, hard, and resilient against scratching.

Abstract: A superconducting ceramics elongated body comprising a flexible ceramics elongated substrate and an oxide ceramics superconducting layer formed at least on a part of the surface of the ceramics elongated substrate to longitudinally extend along the ceramics elongated substrate. The superconducting ceramics elongated body further comprises a protective layer of ceramics containing a nitride, which is provided to at least cover the surface of the superconducting layer exposed on the ceramics elongated substrate. A method of manufacturing a superconducting ceramics elongated body by forming a longitudinally continuous superconducting layer on at least a part of the surface of a flexible ceramics elongated substrate. The superconducting layer is formed on the elongated substrate by a sol-gel method, a coating/sintering method, evaporation under oxygen ions, deposition from a fluoride solution or oxidation after application of corresponding fluorides.

Abstract: An optical modulation method and apparatus uses superconductive oxide material for the optical modulation element. The current, magnetic field, temperature or pressure applied to the superconductive oxide material is varied so as to induce a superconduction-normalconduction transition, and the resulting variation in optical characteristics such as the reflectivity, transmissivity or refractive index of the superconductive oxide material modulate the input light. The method and apparatus are fast in operation and simple in structure. The method and apparatus also detect the variation in the current, magnetic field, temperature or pressure as a change in the reflectivity, transmissivity or refractive index of the superconductive oxide material on the basis of a superconduction-normalconduction transition.

Abstract: A superconductive system for the lossless transmission of electrical current comprising a thin film of superconducting material Y.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x epitaxially deposited upon a KTaO.sub.3 substrate. The KTaO.sub.3 is an improved substrate over those of the prior art since the it exhibits small lattice constant mismatch and does not chemically react with the superconducting film.

Abstract: A superconducting weak link device includes a plurality of interconnected small superconducting regions and a plurality of conductive bridges which connect adjacent the small superconducting regions in which the length of the bridges is in the range from 1 to 5.31 times the coherence length.

Abstract: Superconducting ceramic material is woven into an interconnected structure and embedded in a polymer to produce a flexible, superconducting ceramic material. The polymer also provides protection from moisture. The ceramic polymer composite is fabricated by soaking a carbon fabric in a solution of metal nitrates, ethylene glycol and citric acid to yield a nominal composition of, for example, YBa.sub.2 Cu.sub.3 O.sub.7-x. Heat treatment results in the decomposition of the nitrates, organics and carbon fabric to produce an interconnected structure of the superconducting ceramic material which takes the shape of the original carbon fabric on a reduced scale. In addition, the processing conditions yield significant grain orientation. The superconducting grains of the ceramic material align along the direction of the original fabric weave which provides an improvement of the critical current densities.

Abstract: Disclosed is an oxide superconductor, wherein at least the surface layer has a chemical composition represented by the following formula:La.sub.x Sr.sub.y NbO.sub.zwherein0<x<1,0<y<1, and1<z<4,and has a critical temperature (Tc) higher than 100.degree. K.This superconducotr has a high critical temperature and is rendered superconducting by cooling with cheap liquefied nitrogen.This superconductor is prepared by a process comprising carrying out sputtering in an argon atmosphere by using one of NB and an La--Sr--Cu--O oxide as the substrate and the other as the target under such a temperature condition that substitution of Cu by Nb is caused, an quencing the formed film.

Abstract: A superconducting transistor comprises: a superconducting collector layer for drawing out quasiparticles from a superconducting base layer while a carrier concentration thereof is maintained at a level lower than in metal and at a high level where the superconducting property, is exhibited said superconducting collector layer being formed of predetermined component elements which are formed by a predetermined composition rate, a first barrier layer provided on the superconducting collector layer, formed of a substance having the same component elements as that of the collector layer and having different composition rate from that of the collector layer, and said first barrier layer having a low carrier concentration where the superconducting property is not exhibited, a superconducting base layer provided on the first barrier layer, formed of a substance having the same component elements as that of the superconducting collector layer, a second barrier layer provided on the superconducting base layer formed o

Abstract: An oxide superconductor having oxide superconductor layers and metal material layers, which are alternately laminated on each other by a desired number of times, and a method of manufacturing the same.

Abstract: A device comprising semiconductor elements and conductor tracks of an oxidic superconducting material, electrically conductive connections being formed between semiconductor elements and conductor tracks, is provided with an electrically conductive antidiffusion layer between the semiconductor elements and the conductor tracks. The antidiffusion layer is composed of an amorphous alloy having the composition A.sub.x E.sub.1-x, wherein A is selected from one or more of the elements Zr, Nb, Mo, Ru, Rh, Pd, Hf, Ta, W, Re, Os, Ir and Pt, wherein E is selected from one or more of the elements B, Si, Al, Ga and Ge, and wherein x has a value of from 0.7 to 0.95.

Abstract: A superconductive device and method for the manufacture thereof is disclosed, having a tunneling Josephson element comprising a first oxide superconductor electrode, a blocking layer consisting of a metal substantially inert to oxygen formed on the surface of the oxide superconductor, an insulating thin film layer formed on the blocking layer, and a second superconductor electrode opposing said first electrode formed on the insulating thin film.

Abstract: A substrate for supporting a ceramic superconductor comprises a metallic base member precoated with an yttrium oxide, rare earth oxide, or zirconium oxide layer and having a constituent oxide former which establishes an oxide layer with the yttrium oxide, rear earth oxide, or zirconium oxide on the surface of the substrate. A layer of ceramic superconducting material covers the substrate with the oxide layer between the metallic base member and the ceramic superconductor layer to inhibit the interdiffusion of respective constituent elements between the metallic base member and the ceramic layer. For applications requiring the transmission of electrical current through the ceramic layer over relatively extensive distances, the substrate can be formed as a wire or ribbon.

Abstract: A high T.sub.c oxide superconductive switching device [10] formed on a substantially planar substrate [18] includes a base electrode [12] comprised of a layer or film of anisotropic superconducting material. The layer has a first crystalline axis [c] along which a magnitude of an energy gap of the material is less than an energy gap of the material along other crystalline axes. The superconductive switching device further includes at least one injector electrode [14] forming a planar [16] or an edge tunneling junction with the base electrode for injecting, under the influence of a bias potential eV, quasiparticles into the base electrode. The first crystalline axis is aligned in a predetermined manner with the tunneling junction for optimizing a quasiparticle injection efficiency of the tunneling junction.

Abstract: A superconducting oxide wire and a method of manufacturing the same are disclosed. The wire comprises a pipe made of a metal and a superconducting oxide material filling the interior of the pipe and comprising superconducting oxide grains which are bonded to each other and which have a perovskite crystal structure having a C face and a C axis. The superconducting oxide grains contain more than 50 vol % of plate-shaped grains of which the length in the direction of the C face is greater than the length in the direction of the C axis. The C faces of most the plate-shaped grains are arranged to be directed toward longitudinal axis of the pipe.

Abstract: An oxide superconductor cable and a method of producing the same. The oxide superconductor cable includes a ceramic fiber and an oxide superconductor layer coated over the ceramic fiber. Such a structure of the cable provides flexibility to it to some extent and enables it to become relatively thin.

Abstract: Superconductive structures and a method of forming the same wherein an assembled mass (12) of superconductive particles, or of a mixture of superconductive particles and particles having other properties, are formed into a desired confined configuration and consolidated into a rigid useful unitized body through shock-wave treatment performed at relatively lower temperatures.