Polymer Derived From Acrylic Acid Monomer Or Derivative Patents (Class 507/224)
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Publication number: 20120283149Abstract: Of the many compositions and methods provided herein, one example composition includes a treatment fluid comprising: an aqueous fluid; and a tar stabilizing polymer comprising at least one polymer selected from the group consisting of a styrene polymer, an acrylate polymer, a styrene-acrylate polymer, and any combination thereof.Type: ApplicationFiled: July 23, 2012Publication date: November 8, 2012Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Philip Wayne Livanec, Greg Paul Perez
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Publication number: 20120283152Abstract: A well treatment composition comprises: an aqueous liquid; a fluid loss additive, wherein the fluid loss additive comprises a high molecular weight, water-swellable polymer; and an amphiphilic dispersant, wherein the well treatment composition has an activity of at least 10%. A method of cementing in a subterranean formation comprises: introducing a cement composition into the subterranean formation, the cement composition comprising: (i) cement; (ii) water; and (iii) the well treatment composition; and allowing the cement composition to set.Type: ApplicationFiled: July 19, 2012Publication date: November 8, 2012Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Abhijit TARAFDAR, Remitha AK, Rahul Chandrakant PATIL, Vikrant WAGLE
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Publication number: 20120270758Abstract: A subterranean treatment fluid comprising a degradable gemini surfactant composition described by the following formula: A and A? are spacers that may be a hydrophobic group or a hydrophilic group. B is an ion and may contain a quaternary nitrogen, a sulfonate, or a phosphate. A, A?, B, B?, C, C, E and E? may be an alkyl, an aryl, a sugar, an ester, an ether, and any combination thereof. D and D? may be an aryl, a sugar, an ester, an ether, and any combination thereof. In some cases, A?, D?, and E? may be optional.Type: ApplicationFiled: June 26, 2012Publication date: October 25, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Rajesh K. Saini, Narongsak Tonmukayakul, Thomas D. Welton, Jason E. Bryant, Sherry G. Gaskins
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Publication number: 20120258895Abstract: An encapsulated composition for polymerization includes an initiator composition for initiating a polymerization reaction, and a capsule prepared from an elemental metal or fusible alloy having a melting temperature from about 20° C. to about 200° C. A fluid for polymerization includes the encapsulated composition and a monomer. When the capsule melts or breaks open, the initiator is released.Type: ApplicationFiled: April 7, 2011Publication date: October 11, 2012Applicant: Los Alamos National Security, LLCInventor: Robert E. Hermes
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Publication number: 20120258894Abstract: Methods and compositions are described for treating water- and hydrocarbon-producing subterranean formations with a relative permeability modifier at concentrations below those conventionally used in the art, while not substantially impacting the treatment fluid's performance. Treatment fluids described herein comprise a base fluid, a relative permeability modifier comprising a hydrophobically modified hydrophilic polymer, and a companion polymer interacting synergistically with the relative permeability modifier such that the treatment fluid is operable to reduce the water permeability or to increase an aqueous fluid injection pressure of at least a portion of a subterranean formation by more than the relative permeability modifier or the companion polymer acting alone at like concentration. The water permeability reduction and/or the aqueous fluid injection pressure increase can be more than additive.Type: ApplicationFiled: April 7, 2011Publication date: October 11, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, Jeff W. Loucks, B. Raghava Reddy
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Patent number: 8278250Abstract: Methods of using relative permeability modifiers for the diversion of aqueous fluids during subterranean operations are provided. An embodiment of the present invention provides a method of diverting fluids in a subterranean formation that may comprise providing a treatment fluid comprising an aqueous fluid and a relative permeability modifier that comprises water-soluble polymer with hydrophobic or hydrophilic modification; introducing the treatment fluid into a well bore that penetrates the subterranean formation; and at least a first portion of the treatment fluid to penetrate into a portion of the subterranean formation so as to substantially divert a second portion of the treatment fluid or another aqueous treatment fluid to another portion of the subterranean.Type: GrantFiled: May 5, 2005Date of Patent: October 2, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Eldon D. Dalrymple, Larry S. Eoff, B. Raghava Reddy
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Publication number: 20120231977Abstract: Aqueous and substantially anhydrous fluids having particularly low thermal conductivities and variable densities are disclosed. The fluids include: one or more organic and/or inorganic salts and at least one aprotic polar organic solvent, a mixture of aprotic and erotic polar organic solvents, and/or a polar organic solvent having both prone and aprotic polar functional group linkages. The fluids optionally include one or more viscosifying agents and are free of cross-linking agents. Methods for formulating and using the fluids are also disclosed.Type: ApplicationFiled: March 8, 2011Publication date: September 13, 2012Applicant: TETRA Technologies, Inc.Inventors: Jeffrey McKennis, Marshall Chiasson, Mohammad Hossaini, Nam-Sook Bae
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Publication number: 20120225800Abstract: A method for improving hydraulic fracturing creates coated proppants containing one or more chemical constituents bonded to a substrate and introduced into the fracturing fluid itself. The substrate that eventually acts as a proppant may be sand, ceramic, resin coated sand, and other materials. Typically, the materials that are coated as powders adhered to the substrate may include friction reducers, biosides, oxygen scavengers, clay stabilizers, scale inhibitors, gelling agents, or the like. By adhering solid materials to a substrate 12 by a binder 14, a single, solid, granular material may be maintained onsite, requiring reduced footprint, reduced mixing and may introduce almost instantaneously into a fracturing flow stream all the necessary chemical constituents, which will eventually become mixed. The result is reduced time, energy, manpower, equipment, and space at the sight, while reducing the environmental impact of transportation, spills, hydrocarbon use, and the like.Type: ApplicationFiled: March 12, 2012Publication date: September 6, 2012Inventor: Calder Hendrickson
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Publication number: 20120214714Abstract: A process for achieving enhanced levels of friction reduction in high salinity conditions, particularly suited to slick-water hydraulic fracturing and coiled tubing applications, uses low charge and preferably uncharged water soluble high molecular weight polymers. A fracturing fluid is injected into a conduit. The fracturing fluid is an aqueous solution comprising at least one water soluble (co)polymer comprising less than 10 mol % ionic monomer(s), and the aqueous solution comprises total dissolved salts concentration ranging from 100,000 mg/L to up to the salt concentration at which the aqueous solution becomes saturated in salts.Type: ApplicationFiled: February 28, 2011Publication date: August 23, 2012Applicant: SNF HOLDING COMPANYInventors: Paul WHITWELL, Russell THORPE
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Patent number: 8240379Abstract: A well treatment composition is formed from a fluid mixture of a viscoelastic surfactant and a liquid carrier fluid. The fluid mixture has rheological properties wherein the mixture exhibits shear-thickening behavior when the shear rate is increased from a first shear rate to a second higher shear rate. The fluid mixture may further include a shear activation additive that interacts with the viscoelastic surfactant to facilitate the shear-thickening behavior. The method is accomplished by introducing the fluid mixture into a wellbore formed in a subterranean formation. In certain applications, the fluid mixture may be recycled by bringing the fluid mixture to the surface and reintroducing the fluid into the same or a different wellbore.Type: GrantFiled: October 28, 2009Date of Patent: August 14, 2012Assignee: Schlumberger Technology CorporationInventors: Yiyan Chen, Oscar Bustos, Philip F. Sullivan
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Publication number: 20120193092Abstract: In some embodiments, a method of determining the location of fracturing fluid in a subterranean formation includes providing purpose-designed additives (PDA) in the fracturing fluid. As the fracturing fluid moves through a fracture in the formation, the PDA solidifies and forms a barrier in the path of the fracturing fluid. In response to a pressure increase in the well contacting the barrier, at least one signal is generated and detected to provide information about the fracturing fluid and/or fracture.Type: ApplicationFiled: October 24, 2011Publication date: August 2, 2012Inventors: Qi Qu, C. Vipulanandan, Mark H. Houston
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Patent number: 8227381Abstract: Low molecular weight graft copolymer comprising a synthetic component formed from at least one or more olefinically unsaturated carboxylic acid monomers or salts thereof, and a natural component formed from a hydroxyl-containing natural moiety. The number average molecular weight of the graft copolymer is about 100,000 or less, and the weight percent of the natural component in the graft copolymer is about 50 wt % or greater based on total weight of the graft copolymer. Processes for preparing such graft copolymers are also disclosed.Type: GrantFiled: September 23, 2010Date of Patent: July 24, 2012Assignee: Akzo Nobel N.V.Inventors: Klin A. Rodrigues, Jannifer Sanders
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Publication number: 20120178652Abstract: Pre-coated particulate for use in a subterranean operation comprising a particulate; and a film coated onto a surface of the particulate. The film is formed by allowing an anionic polymer and a cationic surfactant to contact the surface of the particulate, and allowing the anionic polymer and the cationic surfactant to interact with each other. In some cases, the anionic polymer is selected from the group consisting of a polyacrylamide; an alkylpolyacrylamide; a copolymer of polyacrylamide, with ethylene, propylene, and styrene; a copolymer of alkylpolyacrylamide with ethylene, propylene, and styrene; a polymaleic anhydride; and any derivatives thereof.Type: ApplicationFiled: March 16, 2012Publication date: July 12, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Thomas D. Welton, Philip D. Nguyen
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Patent number: 8215393Abstract: The invention discloses a method of creating a polymerized composition in a well bore: providing a polymerizable composition made of a polymerization initiator and a monomer polymerizable by frontal polymerization; introducing the polymerizable composition into the wellbore; exposing the polymerizable composition to a trigger to activate the frontal polymerization; and creating the polymerized composition.Type: GrantFiled: October 6, 2009Date of Patent: July 10, 2012Assignee: Schlumberger Technology CorporationInventors: Bruce A. MacKay, Philip F. Sullivan, Nicolas Droger, Ralph M. D'Angelo, Douglas E. Miller
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Publication number: 20120172263Abstract: Composition comprising a plurality of particulates wherein at least some particulates are at least partially covered with a coating that impedes the intrusion of water into the particulates; and, a silica scale control additive, wherein the silica scale control additive is capable of suppressing silica scale build-up proximate the plurality of particulates. Some compositions further include a treatment fluid wherein and the silica scale control additive are present in the treatment fluid.Type: ApplicationFiled: March 16, 2012Publication date: July 5, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Enrique A. Reyes, Jimmie D. Weaver, Matt E. Blauch, Corine L. McMechan
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Publication number: 20120152544Abstract: Disclosed herein is a well treatment fluid comprising an aqueous solution comprising greater than or equal to about 1 wt % boron, at least 5 wt % of a co-solvent, and greater than or equal to about 5 wt % sodium hydroxide, potassium hydroxide, or a combination thereof, wherein the co-solvent comprises glycerol, ethylene glycol, propylene glycol, or a combination thereof. Methods of using the well treatment fluid are also disclosed.Type: ApplicationFiled: December 7, 2011Publication date: June 21, 2012Inventors: Michael D. Parris, Li Jiang, Don Williamson
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Publication number: 20120157551Abstract: The present invention relates to the use of branched addition copolymers possessing melt or solution viscosities lower than the linear polymer analogues of equivalent or greater weight average molecular weight, compositions comprising said copolymers, methods for their preparation, and he use of novel polymers per se in for example but not limited to solution formulations or melt formulations.Type: ApplicationFiled: September 8, 2010Publication date: June 21, 2012Applicant: UNILEVER PLCInventors: Paul Hugh Findlay, Brodyck James Lachlan Royles, Roselyne Marie Andree Baudry, Neil John Simpson, Sharon Todd, Steven Paul Rannard
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Publication number: 20120157318Abstract: The present invention relates to the use of a branched addition copolymer in combination with a polymer in a solution or melt formulation to reduce the viscosity of the solution formulation and/or melt formulation compared to the viscosity of a solution and/or melt comprising the polymer alone wherein the branched addition copolymer is obtainable by an addition polymerisation process, methods for the preparation of the formulations, and novel branched addition copolymers for use as same.Type: ApplicationFiled: September 8, 2010Publication date: June 21, 2012Applicant: UNILEVER PLCInventors: Paul Hugh Findlay, Brodyck James Lachlan Royles, Roselyne Marie Andree Baudry, Neil John Simpson, Sharon Todd, Steven Paul Rannard
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Patent number: 8198220Abstract: The disclosed compositions and methods utilize hydrophilic polymers modified by the incorporation of one or more hydrophilic side groups. The polymers may exhibit physical association in solution at a specific temperature so as to provide a significant increase in viscosity at the specific temperature. The viscosity of such systems is substantially increased by the further inclusion of one or more hydrophilic components that may exhibit physical association in solution at one or more temperature trigger points and also associate with the one or more hydrophilic polymers modified by the incorporation of one or more hydrophilic side groups.Type: GrantFiled: November 3, 2011Date of Patent: June 12, 2012Assignee: BP Corporation North America Inc.Inventors: Philip S. Smith, Dale L. Handlin, Jr.
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Patent number: 8193124Abstract: A wellbore fluid that includes an oleaginous base fluid; and a silanated weighting agent is disclosed. In particular, the silanated weighting agents may be produced by reaction between an alkyl alkoxy silane and a weighting agent Methods of formulating such fluids and methods of drilling using such fluids are also disclosed.Type: GrantFiled: January 22, 2009Date of Patent: June 5, 2012Assignee: M-I L.L.C.Inventors: Sashikumar Mettath, Steven Young
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Publication number: 20120135894Abstract: Disclosed herein is a method comprising disposing in a formation fracture, a proppant and/or a fracturing fluid that comprises a radiation susceptible material that comprises indium and/or vanadium; irradiating the radiation susceptible material with neutrons; measuring gamma-radiation emitted from the radiation susceptible material in a single pass; wherein the single pass does not involve measuring of background radiation from previous or subsequent logging passes; and determining formation fracture height from the measured gamma-radiation.Type: ApplicationFiled: February 2, 2012Publication date: May 31, 2012Inventors: Robert R. McDaniel, Scott M. Mccarthy, Michael Smith
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Publication number: 20120132423Abstract: Of the many compositions and methods provided herein, one method includes a method comprising: contacting tar resident in a well bore with a tar stabilizing polymer comprising at least one polymer selected from the group consisting of a styrene polymer, an acrylate polymer, a styrene-acrylate polymer, and any combination thereof; and allowing the tar stabilizing polymer to interact with the tar to at least partially reduce the tendency of the tar to adhere to a surface.Type: ApplicationFiled: February 8, 2012Publication date: May 31, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Philip Wayne Livanec, Greg Paul Perez
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Patent number: 8183184Abstract: A polyelectrolyte complex for the controlled release of an oil and gas field chemical selected from the group consisting of (a) a gel-forming or cross-linking agent, (b) a scale inhibitor, (c) a corrosion inhibitor, (d) an inhibitor of asphaltene or wax deposition, (e) a hydrogen sulfide scavenger, (f) a hydrate inhibitor, (g) a breaking agent, and a surfactant.Type: GrantFiled: September 5, 2006Date of Patent: May 22, 2012Assignee: University of KansasInventors: Cory Berkland, Mary Cordova, Jenn-Tai Liang, G. Paul Willhite
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Publication number: 20120121523Abstract: A monomer compound that contains at least one polymerizable functional group per molecule, and at least one bicycloheptyl-, bicycloheptenyl-, or branched (C5-C42)alkyl-polyether radical per molecule, wherein the bicycloheptyl- or bicycloheptenyl-polyether radical may optionally be substituted on one or more of the ring carbon atoms by one or two (C1-C6)alkyl groups per ring carbon atom is useful in making polymers, particularly pH responsive polymers.Type: ApplicationFiled: November 7, 2011Publication date: May 17, 2012Applicant: RHODIA OPERATIONSInventors: Hui Shirley Yang, Derek Pakenham, Herve Adam, Pierre Hennaux, Brian Chung, Subramanian Kesavan, Seren Frantz
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Publication number: 20120111567Abstract: Methods and apparatus for using a fluid within a subterranean formation, including forming a fluid comprising an acrylamide copolymer and a formate salt, and introducing the fluid to the subterranean formation, wherein a temperature of the formation is about 149° C. or warmer. Also, methods and apparatus for a fluid for use within a subterranean formation, including an acrylamide copolymer comprising polyacrylamide, a formate salt comprising potassium, and a crosslinker comprising zirconium. Additionally, methods and apparatus for using a fluid within in a subterranean formation, including forming a fluid comprising an acrylamide copolymer and a formate salt, and introducing proppant into the fluid to form a mixture, introducing the mixture to the subterranean formation, wherein a temperature of the formation is about 149° C. or warmer.Type: ApplicationFiled: November 9, 2010Publication date: May 10, 2012Inventors: Lijun Lin, Alhad Phatak, Leiming Li, Carlos Abad
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Patent number: 8148304Abstract: A copolymer containing, as monomer components, a) at least one sulfonic acid-containing compound, b) at least one nitrogen-containing N-vinylamide, one acrylamide or methacrylamide and c) at least one bifunctional or higher-functional vinyl ether is proposed. These copolymers are suitable in particular as thixotropic agents, antisegregation agents and water retention agents and overall as an additive in cement-containing but also gypsum-based systems. Such copolymers having a molecular weight of >40 000 g/mol can be used in particular as admixtures in the exploration of mineral oil and natural gas deposits.Type: GrantFiled: November 24, 2008Date of Patent: April 3, 2012Assignee: BASF SEInventors: Christian Spindler, Andrea Assmann, Uwe Huber
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Publication number: 20120077717Abstract: The invention relates to polymers derived at least from one: (A) one N-vinyl amide unit, and (B) one hydroxyl-containing acrylate unit, and to polymers derived at least from: (A) N-vinyl-2-caprolactam, and (B) one non-acrylate unit having: (i) at least one hydroxyl group, and/or (ii) at least one functional group convertible to a hydroxyl group wherein at least one group is converted to hydroxyl functionality in the final polymer product. Such polymers may exhibit degradability, e.g., in seawater or soil environments. In preferred embodiments, these polymers and compositions thereof are used in oilfield applications, such as an inhibitor of gas hydrates and/or a kinetic inhibitor of gas hydrates. The polymer can assume alternating, block, and/or random configurations of the repeating units, with at least one ester group. The chemical structure subscripts m, and n may be any integer equal to or greater than 1.Type: ApplicationFiled: March 25, 2010Publication date: March 29, 2012Applicant: ISP INVESTMENTS INC.Inventors: Osama M. Musa, Cuiyue Lei
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Publication number: 20120073817Abstract: Of the methods provided in this invention, one method includes: providing a treatment fluid comprising: an aqueous fluid, a microemulsion surfactant, and an amphiphilic polymer, wherein the amphiphilic polymer comprises a hydrophobic component, and a hydrophilic component; and introducing the treatment fluid into a subterranean formation, wherein the microemulsion surfactant forms a microemulsion that comprises the amphiphilic polymer within the subterranean formation.Type: ApplicationFiled: September 23, 2010Publication date: March 29, 2012Inventor: Ryan van Zanten
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Publication number: 20120067581Abstract: The subject disclosure discloses mechanisms for embedding and controlling multifunctional additives within a polymer matrix for use in oilfield applications. More particularly, the subject disclosure discloses methods of treating a subterranean formation with a polymer matrix comprising one or a plurality of polymers and one or a plurality of functional additives embedded into this polymer matrix.Type: ApplicationFiled: September 17, 2010Publication date: March 22, 2012Applicant: Schlumberger Technology CorporationInventors: Francois Auzerais, Huilin Tu, Sudeep Maheshwari, Partha Ganguly, Vadim Khiestkin, Bruno Lecerf
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Patent number: 8138127Abstract: The present invention includes a method of treating a hydrocarbon-bearing clastic formation having non-connate water by contacting the hydrocarbon-bearing clastic formation with a composition that includes a solvent and a nonionic fluorinated polymeric surfactant wherein the solvent at least partially displaces or solubilizes the water in the formation.Type: GrantFiled: December 30, 2007Date of Patent: March 20, 2012Assignees: Board of Regents, The University of Texas, 3M Innovative Properties CompanyInventors: Gary A. Pope, Jimmie R. Baran, Jr., Vishal Bang, John D. Skildum, Mukul M. Sharma
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Publication number: 20120037364Abstract: The invention is directed to delayed gelation agents comprising a degradable polymeric cage containing therein one or more gelation agents. The cage degrades in situ, e.g, in an oil reservoir, thus releasing the gelation agent(s), which can then crosslink second polymers in situ to form a gel.Type: ApplicationFiled: June 9, 2011Publication date: February 16, 2012Applicants: University of Kansas, ConocoPhillips Company-IP Services GroupInventors: Huili Guan, Cory Berkland, Ahmad Moradi-Araghi, Jenn-Tai Liang, David R. Zornes, Riley B. Needham, Min Cheng, James H. Hedges, James P. Johnson, Faye L. Scully
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Patent number: 8114819Abstract: This invention provides polymers having side chain groups selected from at least one of the following: a) a group comprising an ester of a polycarboxylic acid or polycarboxylate salt, an aminoalkylphosphate ester, or an ammoniumalkylphosphate ester; b) a group comprising (1) an alkanolamino group, (2) a fatty quaternary ammonium moiety, (3) a heterocyclic ring moiety having at least five members, which ring has at least one nitrogen atom, said ring further comprising either unsaturation or at least one additional heteroatom, or (4) both (2) and (3) c) a group comprising an alkylamino ethoxylate or an alkylamino propoxylate; d) a group comprising a trialkylhexahydrotriazine moiety; e) a group comprising a fatty alkyl ester; and f) a group comprising (i) a group as in a), and (ii) a group as in b). Also provided are processes for preparing polymers having such side chain groups.Type: GrantFiled: September 17, 2009Date of Patent: February 14, 2012Assignee: Baker Hughes IncorporatedInventor: Harold L. Becker
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Publication number: 20120028856Abstract: The invention relates to a copolymer having: A) at least one monomer unit a) derived from at least one ethylenically unsaturated aliphatic monocarboxylic or polycarboxylic acid, a corresponding anhydride, or a corresponding water-soluble salt; B) at least one monomer unit b) derived from a particular sulfonated or sulfated ethylenically unsaturated ether or at least one monomer unit (b?) derived from a sulfonated ethylenically unsaturated monomer other than (b), C) at least one monomer unit (c) derived from a monomer with the average general formula [CH2?CH—CH2—R6—O—]xP(?O)(OM)3-x. The invention also relates to a method for preparing such a copolymer, an inhibitor composition including such a copolymer, and a method for inhibiting inorganic deposits in a petroleum reservoir by means of said inhibitor composition.Type: ApplicationFiled: December 23, 2009Publication date: February 2, 2012Inventors: Hervé Adam, Dominique Labarre, James Wilson, Jean-Francois Argillier, Brigitte Bazin, Patrick Gateau, Benjamin Herzhaft
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Publication number: 20120012311Abstract: Use of a mixture comprising a surfactant and a cosurfactant in the form of an aqueous solution for flooding underground deposits of hydrocarbons for mobilizing and recovering the hydrocarbons from the underground deposits, the cosurfactant being a substance or a group of substances selected from the following list: an amphiphilic comb polymer having a backbone with two or more side chains attached to the backbone, the side chains differing from one another and/or the side chains differing from the backbone in their amphiphilic character, an amphiphilic polymer having one or more hydrophobic subunits [A2] based on a polyisobutene block, at least 50 mol % of whose polyisobutene macromolecules have terminally arranged double bonds, and one or more hydrophilic subunits [B2], or an amphiphilic polymer having the general structural formulaType: ApplicationFiled: September 23, 2011Publication date: January 19, 2012Applicant: BASF SEInventors: Jüergen Huff, Günter Oetter, Angelika Kühnle, Susanne Petrovic, Marcus Guzmann, Ingo Münster, Gregor Brodt
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Patent number: 8097567Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid including a choline compound together with an formation control additive.Type: GrantFiled: January 9, 2006Date of Patent: January 17, 2012Assignee: Clearwater International, LLCInventor: Thomas P Wilson, Jr.
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Patent number: 8076270Abstract: The disclosed compositions and methods utilize hydrophilic polymers modified by the incorporation of one or more hydrophilic side groups. The polymers may exhibit physical association in solution at a specific temperature so as to provide a significant increase in viscosity at the specific temperature. The viscosity of such systems is substantially increased by the further inclusion of one or more hydrophilic components that may exhibit physical association in solution at one or more temperature trigger points and also associate with the one or more hydrophilic polymers modified by the incorporation of one or more hydrophilic side groups.Type: GrantFiled: September 23, 2009Date of Patent: December 13, 2011Assignee: BP CORPORATION NORTH AMERICA Inc.Inventors: Philip S. Smith, Dale L. Handlin, Jr.
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Patent number: 8076271Abstract: The present invention relates to aqueous tackifiers and methods of controlling particulates in subterranean formations using aqueous tackifiers. Some embodiments of the present invention provide methods of controlling particulates, comprising placing an aqueous tackifier compound into a portion of a subterranean formation comprising unconsolidated particulates; and, activating the aqueous tackifier compound. Other embodiments of the present invention provide methods of coating a portion of a surface in a subterranean formation comprising substantially coating an aqueous tackifier compound onto a portion of a subterranean formation; and, activating the aqueous tackifier compound. Other embodiments of the present invention provide treatment fluids for controlling fine particulates, comprising a servicing fluid and an aqueous tackifier compound.Type: GrantFiled: June 9, 2004Date of Patent: December 13, 2011Assignee: Halliburton Energy Services, Inc.Inventors: Matthew E. Blauch, Thomas D. Welton, Philip D. Nguyen
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Publication number: 20110297375Abstract: The invention is a composition, for use in treating oil wells, comprising fibres, hot melt adhesives and particulate solids. This composition has a wide range of applications including preventing or lessening lost circulation, wellbore strengthening or consolidation, controlling fluid loss, producing a “stress cage” effect, gravel packing, acting as an aid to cementing, and for proppant backflow control.Type: ApplicationFiled: August 13, 2009Publication date: December 8, 2011Applicant: Schlumberger Technology CorporationInventors: Nikhil Shindgikar, Jesse Lee
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Patent number: 8062999Abstract: Sealant compositions comprising a colloidally stabilized latex and methods of using the same to service a wellbore are provided. The sealant compositions may include: an aliphatic conjugated diene monomer; an additional monomer comprising a non-aromatic unsaturated mono- or di- carboxylic ester monomer, an aromatic unsaturated monomer, a nitrogen-containing monomer, or combinations thereof; and a protective colloid. The foregoing sealant composition may be displaced into the wellbore to isolate the subterranean formation from a portion of the wellbore, to support a conduit in the wellbore, to plug a void or crack in the conduit, to plug a void or crack in a cement sheath disposed in an annulus of the wellbore, to plug an opening between the cement sheath and the conduit, or combinations thereof. The colloidally stabilized latex remains substantially stable when exposed to salt, which may be present in the wellbore and/or in the sealant composition itself.Type: GrantFiled: May 4, 2007Date of Patent: November 22, 2011Assignee: Halliburton Energy Services Inc.Inventors: B. Raghava Reddy, Anthony V. Palmer
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Publication number: 20110278006Abstract: A slurry for treating a wellbore that includes a base fluid; at least one fibrous structure; and a plurality of calcium silicate particles is disclosed. Methods of reducing loss of wellbore fluid in a wellbore to a formation using an LCM pill having calcium silicate particles therein is also disclosed.Type: ApplicationFiled: January 29, 2010Publication date: November 17, 2011Applicant: M-I L.L.C.Inventors: Mark W. Sanders, Jason T. Scorsone, Arvind D. Patel
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Publication number: 20110272142Abstract: The present invention includes methods and compositions relating to the setting of fluids or slurries in a wellbore. In one embodiment, a method of isolating a portion a wellbore includes preparing a sealant composition having a fluid component, a polymeric additive constituent, and a set modifier component. The sealant composition is placed into a wellbore and subjected to ionizing radiation. The ionizing radiation can cause bonding between polymeric additive constituents and create a polymer matrix within the sealant composition that increases the mechanical strength of the sealant composition. The ionizing radiation also alters the set modifier component, triggering the thickening of the sealant composition.Type: ApplicationFiled: March 2, 2011Publication date: November 10, 2011Applicant: Halliburton Law DepartmentInventors: Samuel J. Lewis, Gary Funkhouser, Anthony Badalamenti, Vikram Rao, David F. Myers, Vijay Gupta, James Lynn Davis, Michael Lamvik, Paul Hoertz, Lynn Margaret Soby, Andrew K. Dummer
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Publication number: 20110272141Abstract: The present invention relates to methods useful for isolating a portion of a wellbore. In one embodiment, a method includes preparing a sealant composition containing a set modifier component. The sealant composition is placed into the wellbore and is subjected to ionizing radiation that alters the set modifier component, triggering the thickening of the sealant composition.Type: ApplicationFiled: March 2, 2011Publication date: November 10, 2011Applicant: Halliburton Law DepartmentInventors: Samuel J. Lewis, Anthony Badalamenti, James Lynn Davis, Vijay Gupta, Michele Ostraat, David F. Myers, Michael Lamvik, Andrew K. Dummer, Vikram Rao, Lawrence R. Roberts, Paul Hoertz
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Publication number: 20110275546Abstract: The present invention relates to the preparation of foaming formulations for high temperature, salinity and concentration of divalent ions, such as Calcium and Magnesium, that apply the synergistic effect of sodium alpha olefin sulfonates and alkyl amido propyl betaines; said inventions may use, as solvent, water, sea water, connate water, alcohols or mixtures all thereof. Said formulations control the piping of gas in reservoirs of the naturally fractured carbonate type.Type: ApplicationFiled: October 5, 2009Publication date: November 10, 2011Applicant: INSTITUTO MEXICANO DEL PETROLEOInventors: Luis Silvestre Zamudio Rivera, Simon López Ramírez, Cecilia de loss Ángele Durán Valencia, Raúl Hernández Altamirano, Violeta Yasmín Mena Cervantes, Norma Araceli García Muñoz, Alfredo Ríos Reyes, Alejandro Ortega Rodríguez, José Luis Mendoza De La Cruz, Marcelo Lozada Ycassou, Eduardo Buenrostro González
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Patent number: 8043997Abstract: A lost circulation material and method for well treatment employing the material that is effective at sealing or plugging small fissures and large fractures and has utility over a wide range of temperatures, including high temperatures. The material has an optimized bimodal particle distribution and optionally has a polymer flocculent or water swellable polymer.Type: GrantFiled: February 29, 2008Date of Patent: October 25, 2011Assignee: Halliburton Energy Services Inc.Inventors: Donald L. Whitfill, Cindy C. Fang, Matthew Miller
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Patent number: 8043998Abstract: The present invention includes compositions and methods of treating a hydrocarbon-bearing formation, the formation having at least one fracture, by contacting the fracture with a composition that includes a solvent and a nonionic fluorinated polymeric surfactant, wherein the composition interacts with at least a portion of the proppants in the fracture.Type: GrantFiled: December 30, 2007Date of Patent: October 25, 2011Assignees: Board of Regents, The University of Texas System, 3M Innovative Properties CompanyInventors: Gary A. Pope, Jimmie R. Baran, Jr., John Skildum, Vishal Bang, Mukul M. Sharma
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Publication number: 20110256085Abstract: A composition for enhancing fluid viscosity including a mixture of at least one cationic or cationizable polymer and at least one anionic or anionizable (hydrolysable) polymer. The composition has a zeta potential at 25° C. in the range of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV, or is a precursor convertible at a temperature of 100 to 250° C. to the composition having a zeta potential at 25° C. of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV. Typically the compositions exhibit salt tolerance and interaction of both polymers at very high temperatures (>300° F.) such that the system exhibits an increase of viscosity at extreme temperatures. The compositions are useful for hydraulic fracturing, enhanced oil recovery, subterranean acidization, personal care as well as home and industrial cleaners.Type: ApplicationFiled: February 14, 2011Publication date: October 20, 2011Applicant: RHODIA OPERATIONSInventors: Ruela TALINGTING PABALAN, Nemesio Martinez-Castro, Subramanian Kesavan, Marie Pierre Labeau, Bruno Langlois
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Publication number: 20110253366Abstract: Fibers comprising a first thermoplastic composition having a softening temperature up to 120° C and a curable resin. Also disclosed are compositions comprising a plurality of fibers, with some of the fibers comprising a first thermoplastic composition having a softening temperature up to 120° C and some of the fibers comprising a curable resin. The fibers have an aspect ratio of at least 2:1 and a maximum cross-sectional dimension up to 60 micrometers. Fluid compositions containing the fibers and methods of contacting a subterranean formation using the fibers are also disclosed.Type: ApplicationFiled: December 21, 2009Publication date: October 20, 2011Inventors: Michael R. Berrigan, James G. Carlson, Michael D. Crandall, Clayton A. George, Ignatius A. Kadoma, Yong K. Wu
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Publication number: 20110245114Abstract: A well servicing fluid formulated with components comprising a friction reducer having at least one polymer unit chosen from acrylamide groups, acrylate groups, sulfo groups, and maleic acid groups; and an anionic surfactant, a cationic surfactant and an aqueous base capable of forming a viscoelastic gel. Methods of making the well servicing fluid and methods of employing the well servicing fluid in a well are also disclosed.Type: ApplicationFiled: March 31, 2010Publication date: October 6, 2011Inventors: D. V. Satyanarayana Gupta, Justyna Ferraro, Kay Cawiezel
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Patent number: 8030253Abstract: Of the many compositions provided herein, an embodiment includes a foamed cement composition comprising a cementitious component, an oil-swellable particle comprising at least one swellable elastomer selected from the group consisting of acrylate butadiene rubber, polyacrylate rubber, isoprene rubber, choloroprene rubber, butyl rubber, brominated butyl rubber, chlorinated butyl rubber, chlorinated polyethylene, neoprene rubber, styrene butadiene block copolymer, sulphonated polyethylene, ethylene acrylate rubber, epichlorohydrin ethylene oxide copolymer, ethylene-propylene rubber, ethylene vinyl acetate copolymer, fluorosilicone rubber, silicone rubber, and combinations thereof, a foaming and stabilizing surfactant, gas, and water. Another embodiment includes a foamed cement composition comprising a cementitious component, an oil-swellable particle comprising a block copolymer of styrene butadiene rubber, a foaming and stabilizing surfactant, and gas.Type: GrantFiled: August 20, 2009Date of Patent: October 4, 2011Assignee: Halliburton Energy Services, Inc.Inventors: Craig W. Roddy, Jiten Chatterji, Bobby J. King, D. Chad Brenneis
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Patent number: 8030252Abstract: In one embodiment, the present invention provides a drilling fluid composition that comprises a surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and a non-surfactant polymeric emulsifier. In another embodiment, the present invention provides a method of treating a subterranean formation comprising providing a treatment fluid that comprises a surfactant-free emulsion, the surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and a non-surfactant polymeric emulsifier; and treating the subterranean formation.Type: GrantFiled: April 22, 2004Date of Patent: October 4, 2011Assignee: Halliburton Energy Services Inc.Inventor: William W. Shumway