Organic Component Is A Fat, Fatty Alcohol, Fatty Oil, Ester-type Wax, Fatty Still Residue, Or Higher Fatty Acid Or Salt Thereof Patents (Class 507/265)
  • Patent number: 7510005
    Abstract: A process is described for replacing at least a portion of the liquid within the annular volume of a casing system within a wellbore with a second liquid. The second liquid comprising at least one polymerizable monomer and at least one antistatic agent to control build up of static charge. The second fluid is preselected to provide a measure of control of the pressure within the annular volume as the fluid within the volume is being heated.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: March 31, 2009
    Assignees: Chevron U.S.A. Inc., Lucite International
    Inventors: Don M. Coates, John M. Daniel
  • Patent number: 7507693
    Abstract: Methods of improving shear recovery time of viscoelastic surfactant fluid systems are described, one method involving providing a viscoelastic surfactant fluid system comprising a major portion of a surfactant and a rheology enhancer in a concentration sufficient to shorten shear recovery time of the fluid system compared to shear recovery time of the fluid system absent the rheology enhancer, the rheology enhancer selected from aromatic sulfonates having a molecular weight of at least 500; and injecting the fluid system down a well. The rheology enhancer may be a lignosulfonate derived from wood pulping. Viscoelastic surfactant systems including the rheology enhancer are also described.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: March 24, 2009
    Assignee: Schlumberger Technology Corporation
    Inventors: Yiyan Chen, Jesse C. Lee, Eric Hanson
  • Patent number: 7507694
    Abstract: In one embodiment, the present invention provides a drilling fluid composition that comprises a surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles. In another embodiment, the present invention provides a method of treating a subterranean formation comprising providing a treatment fluid that comprises a surfactant-free emulsion, the surfactant-free emulsion comprising an oleaginous fluid, a fluid that is at least partially immiscible with the oleaginous fluid, and emulsion facilitating particles; and treating the subterranean formation.
    Type: Grant
    Filed: March 12, 2004
    Date of Patent: March 24, 2009
    Assignee: Halliburton Energy Services, Inc.
    Inventors: William W. Shumway, Kenneth W. Pober, Jeff Kirsner
  • Publication number: 20090054273
    Abstract: Improved gelled hydrocarbon fracturing fluids include a gelling agent and a crosslinking composition including a crosslinking agent and a catalytic agent. The catalytic agent is a fatty quaternized amine, which includes monoalkyl benzyl quaternized amines.
    Type: Application
    Filed: August 20, 2007
    Publication date: February 26, 2009
    Applicant: SANJEL CORPORATION
    Inventors: Sally Lawrence, Neil Warrender
  • Patent number: 7449431
    Abstract: A method of controlling the pressure of a casing annulus in a subterranean well that includes injecting into the casing annulus a composition including a base fluid and a polymer coated colloidal solid material. The polymer coated colloidal solid material includes: a solid particle having an weight average particle diameter (d50) of less than two microns, and a polymeric dispersing agent coated onto the surface of the solid particle during the comminution (i.e. grinding) process utilized to make the colloidal particles. The polymeric dispersing agent may be a water soluble polymer having a molecular weight of at least 2000 Daltons. The solid particulate material may be selected from materials having of specific gravity of at least 2.68 and preferably the solid particulate material may be selected from barium sulfate (barite), calcium carbonate, dolomite, ilmenite, hematite, olivine, siderite, strontium sulfate, combinations and mixtures of these-and other similar solids.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: November 11, 2008
    Assignee: M-I L.L.C.
    Inventors: Andrew J Bradbury, Christopher A. Sawdon, Sonny Clary, William M Reid, Tom Heinz
  • Patent number: 7435706
    Abstract: A method of reducing the viscosity of oil-based drilling fluids and well service fluids at low temperatures and a thinner compound for use in such drilling fluids and well service fluids is disclosed. The method comprises adding to said drilling fluids or well service fluids a thinner having the formula: R—(C2H4O)n(C3H6O)m(C4H8O)k-H where R is a saturated or unsaturated, linear or branched alkyl radical having about 8 to about 24 carbon atoms, n is a number ranging from about 1 to about 10, m is a number ranging form about 0 to about 10, and k is a number ranging from about 0 to about 10.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: October 14, 2008
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Heinz Mueller, Jeff Kirsner, Kimberly Burrows
  • Patent number: 7431087
    Abstract: Delayed breakers are given that break viscoelastic surfactant fluids inside the pores of formations into which the fluids have been injected. The breakers comprise proteins, proteins that contain breakers, or cells that contain breakers. Proteins become breakers, and proteins and cells release breakers, due to a triggering mechanism that may be, for example, a change in temperature, pH, or salinity.
    Type: Grant
    Filed: October 25, 2007
    Date of Patent: October 7, 2008
    Assignee: Schlumberger Technology Corporation
    Inventors: Philip F. Sullivan, Belgin Baser, Carlos Abad, Yiyan Chen, Mehmet Parlar, Gregory Kubala
  • Publication number: 20080220995
    Abstract: The handling, transport and delivery of particulate materials, particularly fine particles, may be difficult. Alkaline earth metal oxide particles such as magnesium oxide (MgO) may be suspended in glycerin and/or alkylene glycols such as propylene glycol up to loadings of 51 wt %. Such suspensions or slurries make it easier to deliver MgO and similar agents into fluids, such as aqueous fluids gelled with viscoelastic surfactants (VES). These concentrated suspensions or slurries may be improved in their stability by the inclusion of minor amounts of a vegetable oil and/or a fish oil. The MgO serves as stabilizers and/or fluid loss control agents for VES-gelled fluids used to treat subterranean formations, e.g. for well completion or stimulation in hydrocarbon recovery operations. The particle size of the magnesium oxide or other agent may be between 1 nanometer to 0.4 millimeter.
    Type: Application
    Filed: May 19, 2008
    Publication date: September 11, 2008
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Tianping Huang, James B. Crews
  • Patent number: 7410934
    Abstract: The invention concerns an aqueous viscoelastic fluid for use in the recovery of hydrocarbons. According to the invention, the aqueous viscoelastic fluid comprises a monomer, a dimer or an oligomer of a viscoelastic surfactant able to form a viscoelastic gel under downhole conditions, said surfactant comprising a hydrophobic tail and a hydrophilic head, and being of the following formulae: R—X—Y-Z where R is the hydrophobic tail of the surfactant, Z is the hydrophilic head of the surfactant, said hydrophilic head being charged, X is a stabilising group and Y chain is a linear, saturated or unsaturated, hydrocarbon chain of 1, 2 or 3 carbon atoms or a branched, saturated or unsaturated hydrocarbon chain wherein the main chain is of 1, 2 or 3 carbon atoms, possibly incorporating an aromatic ring.
    Type: Grant
    Filed: February 13, 2002
    Date of Patent: August 12, 2008
    Assignee: Schlumberger Technology Corporation
    Inventors: Trevor Hughes, Timothy Gareth John Jones, Gary John Tustin, Jian Zhou
  • Patent number: 7409994
    Abstract: An additive that increases the density of fluids used in a wellbore during the construction or repair of oil, gas, injection, water, or geothermal wells comprises In one illustrative embodiment the additive comprises a weighting agent, and more preferably an ultra-fine weighting agent. Another embodiment includes a wellbore fluid containing an ultra-fine weighting agent that has an increased density with improved suspension stability without a significant viscosity increase. The wellbore fluid as described herein has rheological properties comparable to a conventional wellbore fluid. An illustrative embodiment of the claimed subject matter is further directed to a method for making the ultra-fine weighting agent and a method for using such ultra-fine weighting agent in a wellbore fluid. In one preferred embodiment the additive has a particle diameter between 4 ?m to 15 ?m. In another preferred embodiment, the additive has a D50 of approximately 3 ?m (1 ?m to 6 ?m).
    Type: Grant
    Filed: December 28, 2006
    Date of Patent: August 12, 2008
    Assignee: M-I L.L.C.
    Inventors: Jarrod Massam, Neale Browne, Mukesh Kapila
  • Publication number: 20080182763
    Abstract: Pumpable multiple phase vesicle compositions carry agents and components downhole or through a conduit, and controllably releasing them at a different place and time by breaking the compositions. In one non-limiting embodiment the pumpable multiple phase vesicles have a third phase containing a first phase which bears the agent to be controllably released. The first and third phases of the vesicles are separated by a surface active material bilayer that forms the second phase. The pumpable multiple phase vesicles may have internal and external phases that are both oil miscible, both aqueous miscible, or both alcohol miscible. The surface active material bilayer may be composed of compounds such as phospholipids, alkyl polyglycosides, gemini surfactants, sorbitan monooleate, sorbitan trioleate, and many others. The agent may be released by one or more of a variety of mechanisms.
    Type: Application
    Filed: April 3, 2008
    Publication date: July 31, 2008
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Ronald G. BLAND, Lirio QUINTERO
  • Publication number: 20080171673
    Abstract: A wellbore servicing composition comprising a metal oxide, a soluble salt, a surfactant and an oleaginous fluid. A wellbore servicing composition comprising magnesium oxide, a chloride or phosphate salt, an organophilic surfactant and an oleaginous fluid. A wellbore servicing composition comprising magnesium oxide, magnesium chloride, an organophilic surfactant, water and an oleaginous fluid wherein the organophilic surfactant is present in an amount of from about 0.25% to about 5% base on the combined weight of the magnesium oxide and magnesium chloride, and the oleaginous fluid is present ratio of from about 95:5 cement:oleaginous fluid to about 50:50 cement:oleaginous fluid.
    Type: Application
    Filed: January 11, 2007
    Publication date: July 17, 2008
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Sam Lewis, Chris Gordon, Mike Szymanski
  • Patent number: 7392844
    Abstract: A method of treating a well consists of introducing into the wellbore a biodegradable fluid system containing a fatty acid ester, such as methyl soyate. The fluid system may further contain a lactic acid ester, such as ethyl lactate, and/or a nonionic surfactant. The fluid system may be used in displacement, well remediation and stimulation as well as additional, alternative applications such as the cleaning of surface and/or downhole equipment.
    Type: Grant
    Filed: November 2, 2005
    Date of Patent: July 1, 2008
    Assignee: BJ Services Company
    Inventors: Sandra L. Berry, Kay E. Cawiezel
  • Publication number: 20080153719
    Abstract: Fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of a breaker composition that contains at least one mineral oil, at least one polyalphaolefin oil, and/or at least one saturated fatty acid. The breaker may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the breaker, e.g. mineral oil is added to the fluid after it has been substantially gelled. The breaking composition is believed to act possibly by rearranging, disaggregating or otherwise attacking the micellar structure of the VES-gelled fluid in a non-spontaneous, rate controlled manner at elevated fluid temperatures. In a specific, non-limiting instance, a brine fluid gelled with an amine oxide surfactant can have its viscosity broken with a light, low viscosity paraffinic mineral oil.
    Type: Application
    Filed: February 28, 2008
    Publication date: June 26, 2008
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: James B. CREWS, John R. WILLINGHAM
  • Publication number: 20080146466
    Abstract: A substantially liquid gellant formed as one or more reaction products of a metal carboxylate or metal carboxylate amine salt, one or more organic acids, an ester which drives the reaction so that the reaction products are asymmetrical in structure, and a rheology modifier which preferentially interacts between the reaction products for prevent solidifying of the gellant reaction products until such time as the gellant is mixed with the fracturing fluid containing an activator after which the reaction products preferentially interact with the activator to gel the fracturing fluid. The resulting gellant is capable of gelling a hydrocarbon base fluid in less than about 30 seconds.
    Type: Application
    Filed: December 14, 2007
    Publication date: June 19, 2008
    Applicant: INNOVATIVE CHEMICAL TECHNOLOGIES CANADA LTD.
    Inventors: Clayton SMITH, Simon John Michael LEVEY
  • Patent number: 7380606
    Abstract: Disclosed is a microemulsion well treatment microemulsion that is formed by combining a solvent-surfactant blend with a carrier fluid. In preferred embodiments, the solvent-surfactant blend includes a surfactant and a solvent selected from the group consisting of terpenes and alkyl or aryl esters of short chain alcohols. The disclosed well treatment microemulsion can be used in well remediation, stimulation and hydrogen sulfide mitigation operations. Additionally, the well treatment microemulsion can be used in the production of benzothiophenes through interaction with hydrogen sulfide.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: June 3, 2008
    Assignee: CESI Chemical, a Flotek Company
    Inventors: John T. Pursley, David L. Holcomb, Glenn S. Penny
  • Patent number: 7373977
    Abstract: A process for recovering oil by injecting into a subterranean oil-bearing reservoir through one or more injection wells, an aqueous solution containing one or more amphoteric alkyl amido betaine surfactants that form a viscoelastic gel reducing interfacial tension and increasing the viscosity of the injection fluid simultaneously, displacing the solution into the reservoir, and recovering the oil from one or more production wells. These viscoelastic gels are tolerant to electrolytes and multivalent cations. They are shear reversible and adsorbed little onto the reservoir. Their viscosity is reduced when contacting certain hydrocarbons but remains high when contacting water or brine. This allows the fluid to preferentially penetrate the oil-bearing portions of the formation and resulting additional oil recovery.
    Type: Grant
    Filed: March 16, 2005
    Date of Patent: May 20, 2008
    Assignee: Oil Chem Technologies
    Inventors: Paul Daniel Berger, Christie Huimin Berger
  • Patent number: 7360593
    Abstract: Coatings for well screens that protect the screens from damage as they are inserted into the wellbore and once in the well, release reactive materials to react with and degrade potentially plugging materials such as drill solids, fluid filtercakes, fluid loss additives, and drilling fluids. The coatings can be specifically designed for individual well conditions and are comprised of a binder that either melts or dissolves within the wellbore and one or more reactive materials such as acids, enzymes, surfactants, chelants, oxidizers or free radical generators and the like which are released into the screen and the near wellbore area and which are effective in degrading or dissolving materials which could potentially plug the screen.
    Type: Grant
    Filed: November 2, 2004
    Date of Patent: April 22, 2008
    Inventor: Vernon George Constien
  • Patent number: 7354886
    Abstract: Pumpable multiple phase vesicle compositions carry agents and components downhole or through a conduit, and controllably releasing them at a different place and time by breaking the compositions. In one non-limiting embodiment the pumpable multiple phase vesicles have a third phase containing a first phase which bears the agent to be controllably released. The first and third phases of the vesicles are separated by a surface active material bilayer that forms the second phase. The pumpable multiple phase vesicles may have internal and external phases that are both oil miscible, both aqueous miscible, or both alcohol miscible. The surface active material bilayer may be composed of compounds such as phospholipids, alkyl polyglycosides, gemini surfactants, sorbitan monooleate, sorbitan trioleate, and many others. The agent may be released by one or more of a variety of mechanisms.
    Type: Grant
    Filed: October 13, 2004
    Date of Patent: April 8, 2008
    Assignee: Baker Hughes Incorporated
    Inventors: Ronald G. Bland, Lirio Quintero
  • Publication number: 20070298978
    Abstract: Alkaline earth metal compounds may be fluid loss control (FLC) agents for viscoelastic surfactant (VES) fluids used for fluid loss control pills, lost circulation material pills and kill pills in hydrocarbon recovery operations. The FLC agents may include, but not be limited to oxides and hydroxides of alkaline earth metal, and in one case magnesium oxide where the particle size of the magnesium oxide is between 1 nanometer to 0.4 millimeter. The FLC agent may alternatively be transition metal oxides and/or transition metal hydroxides. The FLC agent appears to associate with the VES micelles and together form a novel pseudo-filter cake quasi-crosslinked viscous fluid layer that limits further VES fluid flow into the porous media. The FLC agent solid particles may be added along with VES fluids. The pills may also contain internal breakers to reduce the viscosity thereof so that the components of the pill may be recovered.
    Type: Application
    Filed: May 29, 2007
    Publication date: December 27, 2007
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: James B. Crews, Tianping Huang
  • Patent number: 7287590
    Abstract: Delayed breakers are given that break viscoelastic surfactant fluids inside the pores of formations into which the fluids have been injected. The breakers comprise proteins, proteins that contain breakers, or cells that contain breakers. Proteins become breakers, and proteins and cells release breakers, due to a triggering mechanism that may be, for example, a change in temperature, pH, or salinity.
    Type: Grant
    Filed: September 18, 2006
    Date of Patent: October 30, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Philip F. Sullivan, Belgin Baser, Carlos Abad, Yiyan Chen, Mehmet Parlar, Gregory Kubala
  • Patent number: 7259130
    Abstract: Methods of servicing a wellbore in contact with a subterranean formation include passing an ester-based fluid into the wellbore and reducing a temperature of the ester-based fluid by an amount effective to cause the ester-based fluid to set, e.g., by from about 10° F. to about 20° F. The ester-based fluid includes a water in ester-based oil emulsion, a pH controlling additive, e.g., hydrated lime, in the water-phase, and an emulsifier to stabilize the pH controlling additive. Cooling the ester-based fluid causes the emulsion to destabilize, resulting in the release of the pH controlling additive. This release raises pH of the ester-based fluid by an effective amount to cause it to set. Wellbore servicing fluids comprising the foregoing ester-based fluid may be employed as environmentally friendly sealants or spotting fluids in wellbores.
    Type: Grant
    Filed: August 3, 2004
    Date of Patent: August 21, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: James E. Griffith, Ron D. Nida, John L. Dennis, Jr.
  • Patent number: 7238647
    Abstract: The present invention relates to a method and to a fluid for drilling or workover in a well running through a porous permeable formation, wherein a water-based well fluid circulates in said well. In the method, at most 3% by weight of a composition obtained from fat, or an oil, and an alcohol, is added to the fluid in addition to the conventional constituents for such a fluid, the chain lengths of the acid and alcohol parts being chosen such that the ester thus obtained has sufficient dispersion in water, compatibility with said constituents, does not form an emulsion with the reservoir oil and adsorbs sufficiently on the porous formation.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: July 3, 2007
    Assignees: Institut Francais du Petrole, Oleon N.V.
    Inventors: Annie Audibert Hayet, Jean-Francois Argillier, Daniel Longeron, Carine Dewattines, Michel Janssen
  • Patent number: 7231976
    Abstract: A method of treating a well consists of introducing into the wellbore a biodegradable fluid system containing a blend of lactic acid ester, such as ethyl lactate, and a fatty acid ester, such as methyl soyate. The fluid system may be further in the form of a microemulsion that is formed by combining a blend with one or more emulsifiers, an alcohol, and water. The fluid system may be used in displacement, well remediation and stimulation as well as additional, alternative applications such as the cleaning of surface and/or downhole equipment.
    Type: Grant
    Filed: November 10, 2004
    Date of Patent: June 19, 2007
    Assignee: BJ Services Company
    Inventors: Sandra L. Berry, Kay E. Cawiezel
  • Patent number: 7226896
    Abstract: An organic based emulsion-breaking formulation for use in treating well bores drilled in oil-bearing mud that is not eco-toxic and is optimally compatible with formation fluids comprises: as the emulsion-breaking agent, at least one constituent selected from non-ionic amphiphilic compositions obtained by reacting at least one polymerized vegetable oil with at least one aminoalcohol and alkyl esters (for example C1 to C8) of fatty acids derived from natural, vegetable or animal oils; optionally, at least one wetting agent selected from anionic surfactants; and optionally at least one solvent; the assembly being as a mixture in an organic base. Such a formulation can be weighted by mineral fillers.
    Type: Grant
    Filed: November 21, 2001
    Date of Patent: June 5, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Annie Audibert-Hayet, Claire Giard-Blanchard, Christine Dalmazzone
  • Patent number: 7219735
    Abstract: A packer fluid is provided for use with a wellbore fluid in an annulus or casing bore, having an aqueous portion which contains additives for preventing corrosion, microbiological activity, salt and scale deposition, and an environmentally-acceptable capping fluid which resides at a top of the wellbore to act as freeze protection and as thermal insulation in a the frost penetration layer. The additives in the packer fluid are particularly selected to exist in the aqueous additive fluid and in the wellbore fluid and to be substantially immiscible with the capping fluid and thereby prevent significant migration of the additives into the capping fluid which would compromise its environmental acceptability.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: May 22, 2007
    Assignee: Innovative Chemical Technologies Canada Ltd.
    Inventors: Clayton Smith, Dan Skibinski
  • Patent number: 7219731
    Abstract: A method is given for treating a subterranean formation penetrated by a wellbore with a viscosified fluid. The fluid contains a solid hydrolysable polyacid that upon dissolution and hydrolysis releases an acid that is a breaker for the viscosifying system. Suitable solid hydrolysable polyacids include polylactic acid and polyglycolic acid. The fluid also contains a pH control agent, present in an amount sufficient to neutralize any acid present in the solid hydrolysable polyacid before the injection and to neutralize any acid generated by the solid hydrolysable polyacid during the injection, so that the acid breaker is not available to break the fluid during the injection. In one embodiment the viscosifier is a viscoelastic surfactant fluid system and the solid hydrolysable polyacid is of a size selected to be a fluid loss additive, for example in fracturing or gravel packing.
    Type: Grant
    Filed: June 22, 2005
    Date of Patent: May 22, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Philip F. Sullivan, J Ernest Brown, Jesse C. Lee, Golchehreh Salamat
  • Patent number: 7216709
    Abstract: The present invention generally relates to a method for treating a subterranean formation with an aqueous viscoelastic treating fluid that an aqueous base fluid and one or more non-ionic amido amine oxide surfactant gelling agents. The treatment method comprises injecting the aqueous viscoelastic surfactant treating fluid through a wellbore and into the subterranean formation under conditions effective to control fluid loss, and breaking the gel of the aqueous viscoelastic treating fluid subsequent to treating said formation.
    Type: Grant
    Filed: October 28, 2004
    Date of Patent: May 15, 2007
    Assignee: Akzo Nobel N.V.
    Inventors: Paul M. McElfresh, Chad F. Williams
  • Patent number: 7199084
    Abstract: Suspensions are provided of water-soluble materials in non-aqueous carrier fluids using suspension agents that include thixotropic agents and, optionally, organophilic clays. Methods of forming such suspensions are provided. Methods are also provided for using such suspensions to prepare aqueous solutions, in particular thickened aqueous solutions, in particular for use in oilfield treatments.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: April 3, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Michael Parris, Geoff Robinson
  • Patent number: 7196041
    Abstract: A surfactant has the formula (R1—X)nZ, where R1 is an aliphatic group comprising a C10–C25 principal straight chain bonded at a terminal carbon atom thereof to X, and comprising at least one C1–C6 side chain. X is a charged head group, Z is a counterion, and n is an integer which ensures that the surfactant is charge neutral.
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: March 27, 2007
    Assignee: Schlumberger Technology Corporation
    Inventors: Timothy Gareth John Jones, Gary John Tustin
  • Patent number: 7195068
    Abstract: The present invention relates to methods and compositions for degrading filter cakes in subterranean formations, and more specifically, to improved methods and compositions for degrading filter cakes that comprise acid-soluble portions and polymeric portions.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: March 27, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Bradley L. Todd
  • Patent number: 7084096
    Abstract: A non-aqueous suspension including boron-containing particulates, a low molecular weight polyalkylene glycol and a suspension stabilizer is provided. Methods of crosslinking water soluble polymers and of fracturing a subterranean formation are also provided.
    Type: Grant
    Filed: May 20, 2003
    Date of Patent: August 1, 2006
    Assignee: Benchmark Research & Technology, LLC
    Inventors: William Franklin Harris, Jr., David Nigel Harry, Xiaoping Qiu
  • Patent number: 7084095
    Abstract: It was found that the addition of polymers to viscoelastic surfactant base system allows to adjust the rheological properties of the base fluid. Depending in particular on one side of the ratio of the concentration of added polymer and the concentration of viscoelastic surfactant and on the other side of the molecular weight of the added polymer, the same polymer—or the same type of polymer—may perform different functions such as viscosity enhancer, viscosity breaker or viscosity-recovery enhancer.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: August 1, 2006
    Assignee: Schlumberger Technology Corporation
    Inventors: Jesse Lee, Erik Nelson, Kevin England, Philip Sullivan
  • Patent number: 7066260
    Abstract: Methods are presented to induce a screenout during a subterranean formation fracturing or combined fracturing and gravel packing treatment having a viscoelastic surfactant-based carrier fluid by laying down a filter cake at least a portion of which is a base-soluble material, injecting proppant slurry, and causing hydrolysis and dissolution of the solid base-soluble material by adding base so that leak-off increases, the concentration of proppant in the fracture increases, and the proppant screens out. A method of gravel packing with a viscoelastic surfactant-based carrier fluid by laying down a filter cake at least a portion of which is a base-soluble material, injecting gravel, and causing hydrolysis and dissolution of the solid base-soluble material by adding base. Methods of slowing or accelerating the hydrolysis and dissolution are given, and addition of bridging-promoting materials is included.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: June 27, 2006
    Assignee: Schlumberger Technology Corporation
    Inventors: Philip F. Sullivan, Curtis L. Boney
  • Patent number: 6994166
    Abstract: It has been discovered that solid, particulate dicarboxylic acids are useful as diverting agents in methods for acidizing subterranean formations to improve the uniformity of the acid treatments (acid displacement) by diverting acid to intervals of relatively less permeability. Particularly suitable solid, particulate dicarboxylic acids include, but are not necessarily limited to, those insoluble in both aqueous and hydrocarbon liquids, but which are soluble in mutual solvents or alcohol blends. These acids may have melting points of from about 180 to about 300° F. (about 82 to about 149° C.), formula molecular weights of from 146 to 400, and mesh sizes of from about 20 mesh to about 400 mesh (about 841 to about 38 microns). Particular dicarboxylic acids that fit this description include, but are not necessarily limited to, dodecanedioic acid, undecanedioic acid, decanedioic acid, azelaic acid, suberic acid, and mixtures thereof.
    Type: Grant
    Filed: June 24, 2003
    Date of Patent: February 7, 2006
    Assignee: Baker Hughes Incorporated
    Inventors: Tianping Huang, Paul M. McElfresh
  • Patent number: 6984610
    Abstract: Acid based micro-emulsions are disclosed comprising water, an acid blend, an anionic surfactant, a nonionic surfactant, a co-solvent, a solvent and an oxidizer. The micro-emulsions have particular utility in cleaning oil sludges and drilling mud residues from well cuttings, well formations and down hole and surface oil well drilling and production equipment.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: January 10, 2006
    Assignee: Integrity Industries, Inc.
    Inventors: James R. VonKrosigk, William M. Duncan
  • Patent number: 6849581
    Abstract: Gelled organic compositions and methods for using same. The gelled compositions may be liquid organic fluids, such as gelled liquid hydrocarbons, formed from a mixture of an organic-base fluid, a carboxylic acid, and one or more metal source compounds, such as a metal salt of carboxylic acid. The gelled compositions may be used in variety of applications including, but not limited to, oil field, pipeline and processing facility applications.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: February 1, 2005
    Assignee: BJ Services Company
    Inventors: Joseph E. Thompson, Joel L. Boles
  • Patent number: 6849582
    Abstract: Stimulation, particularly fracturing or acidising, of hydrocarbon wells having bores leading to hydrocarbon bearing uses a fluid including a continuous phase of or including a compound of the formula (1): (R2)p—Ph—(CH2)m—COO—(AO)n—R1 where R1, AO, n, m, Ph, R2 and p having defined meanings and particularly where the esters are alkyl or alkenyl benzoate esters. These esters are beneficial by having a range of viscosities, especially extending to low viscosities, and attractive toxicological and environmental profiles for use in well stimulation.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: February 1, 2005
    Assignee: Imperial Chemical Industries PLC
    Inventors: Neil Grainger, Terence Cox, Edward George Scovell
  • Publication number: 20040262002
    Abstract: It has been discovered that solid, particulate dicarboxylic acids are useful as diverting agents in methods for acidizing subterranean formations to improve the uniformity of the acid treatments (acid displacement) by diverting acid to intervals of relatively less permeability. Particularly suitable solid, particulate dicarboxylic acids include, but are not necessarily limited to, those insoluble in both aqueous and hydrocarbon liquids, but which are soluble in mutual solvents or alcohol blends. These acids may have melting points of from about 180 to about 300° F. (about 82 to about 149° C.), formula molecular weights of from 146 to 400, and mesh sizes of from about 20 mesh to about 400 mesh (about 841 to about 38 microns). Particular dicarboxylic acids that fit this description include, but are not necessarily limited to, dodecanedioic acid, undecanedioic acid, decanedioic acid, azelaic acid, suberic acid, and mixtures thereof.
    Type: Application
    Filed: June 24, 2003
    Publication date: December 30, 2004
    Inventors: Tianping Huang, Paul M. McElfresh
  • Patent number: 6831044
    Abstract: Coatings for well screens that protect the screens from damage as they are inserted into the wellbore and once in the well, release reactive materials to react with and degrade potentially plugging materials such as drill solids, fluid filtercakes, fluid loss additives, and drilling fluids. The coatings can be specifically designed for individual well conditions and are comprised of a binder that either melts or dissolves within the wellbore and one or more reactive materials such as acids, enzymes, surfactants, chelants, oxidizers or free radical generators and the like which are released into the screen and the near wellbore area and which are effective in degrading or dissolving materials which could potentially plug the screen.
    Type: Grant
    Filed: January 31, 2002
    Date of Patent: December 14, 2004
    Inventor: Vernon George Constien
  • Patent number: 6818597
    Abstract: Liquid water soluble polymer suspensions in non-aqueous solvents are extremely stable over long periods of time with minimum separation of the solvent and no hard packing of the dispersed water soluble polymer. The suspensions enable a user to rapidly add the suspension to water, being mixed at low speeds, without the formation of lumps or fisheyes and without generating fugitive dust in the process. The suspensions are environmentally safe and biodegradable. Unlike many other liquid polymer suspensions, the suspensions exhibit minimal oil or grease upon dilution. They contain no surfactants that can add to the oil and grease determination. The suspensions and the fluids produced by diluting the fluids to a working concentration of the water soluble polymer exhibit low toxicity to marine organisms and to humans. The suspensions can be manufactured from ingredients suitable for use in personal care applications such as cosmetics, shampoos and the like.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: November 16, 2004
    Assignee: Benchmark Research & Technology, Inc.
    Inventor: William Franklin Harris
  • Patent number: 6800593
    Abstract: Disclosed is a hydrophilic, water soluble polymer concentrate for addition to aqueous liquids to enhance the properties thereof, particularly to increase the viscosity or decrease the fluid loss of well drilling and servicing fluids, the concentrate comprising a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, the water soluble polymer, and a stabilizing agent comprising one or more acids in an amount from about 0.001% to about 1.5%, one or more anionic surfactants in an amount from about 0.001% to about 1.0%, one or more nonionic surfactants in an amount from 0.001% to about 0.625% and, from about 0% to about 0.75% of one or more water soluble organic liquids, wherein the total concentration of the stabilizing agent is from about 0.1% to about 2.5%, these percentages being based on the weight of the concentrate.
    Type: Grant
    Filed: June 19, 2002
    Date of Patent: October 5, 2004
    Assignee: Texas United Chemical Company, LLC.
    Inventors: James W. Dobson, Jr., Shauna Leigh Hayden, Carolina Trejo Rangel
  • Patent number: 6787505
    Abstract: A wellbore fluid having a non-aqueous continuous liquid phase that exhibits an electrical conductivity of not less than 10 &mgr;S m−1 at 1 kHz comprises a polar organic liquid (POL) which exhibits a dielectric constant of at least about 5.0 and a Hildebrand Solubility Parameter of at least about 17 (J cm−3)1/2. Oils or other organic liquids (OL) known to be suitable as the continuous liquid phase of wellbore fluids, may be used in admixture with POL component. Certain inorganic salts, organic bases, quaternary ammonium salts or hydroxides (the dissolved component, DC), display sufficient solubility (and current carrying abilities) in POL, OL or in mixtures of liquid (POL) and liquid (OL) to further improve the electrical conductivity of the mixture. The wellbore fluid can be used for providing enhanced information from electrical logging tools, measurement while drilling, logging while drilling, geosteering and the like.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: September 7, 2004
    Assignee: M-I LLC
    Inventors: Geoffrey Maitland, Christopher Sawdon, Mostafa Tehrani
  • Patent number: 6770603
    Abstract: A wellbore fluid having a non-aqueous continuous liquid phase that exhibits an electrical conductivity increased by a factor in order of 104 to 107 compared to conventional invert emulsion comprises from about 0.2% to about 10% by volume of carbon black particles and one or more emulsifying surfactant(s) selected from the class including nonionic emulsifiers of Hydrophilic-Lipophilic Balance (HLB) less than about 12, and anionic surfactants wherein the counter-ion (cation) is any of alkali metal, ammonium, or hydrogen ions. This wellbore fluid can be used for drilling or completing a well and can be used for providing enhanced information from electrical logging tools, measurement while drilling, logging while drilling, geosteering and the like.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: August 3, 2004
    Assignee: M-I L.L.C.
    Inventors: Christopher Sawdon, Mostafa Tehrani, Paul Craddock, Anthony Lawson
  • Patent number: 6750180
    Abstract: The present invention relates to a borehole fluid comprising a lubricating compound containing at least one amphiphilic non-ionic compound obtained by reacting at least one vegetable oil or fatty acid as such or in a polymerized state on at least one amino alcohol. In one variant, the compound can be mixed with a solvent. The invention also relates to a method for verifying the lubrication power of a water-based fluid. The invention further relates to the application of said method to borehole fluids with a high pH.
    Type: Grant
    Filed: December 12, 2000
    Date of Patent: June 15, 2004
    Assignees: Institut Francais du Petrole, Oleon NV
    Inventors: Jean-François Argillier, André Demoulin, Annie Audibert-Hayet, Michel Janssen
  • Patent number: 6743756
    Abstract: Liquid suspensions of particles in non-aqueous solvents are extremely stable over long periods of time with minimum separation of the solvent and no hard packing of the dispersed particles. The suspensions enable a user to rapidly add the suspension to water and to mix at low speeds without generating fugitive dust in the process. In addition, a liquid dispersion can provide an easy to use liquid containing higher concentrations of the active dispersed phase than can be accomplished by simply preparing an aqueous solution of the dispersed phase. Alternatively, highly water-soluble particles may also be suspended which have poor storage, freeze/thaw, or heat/cool stability. In some cases, liquid dispersions can yield controlled release of the dispersed phase because the dispersed phase is not in aqueous solution. The suspensions are environmentally safe and biodegradable and may be used in environmentally sensitive applications, such as for oil well treating fluids for offshore areas.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: June 1, 2004
    Assignee: Benchmark Research and Technology, Inc.
    Inventor: William Franklin Harris, Jr.
  • Patent number: 6740625
    Abstract: The present invention relates to a method and a fluid for drilling or intervening in a well passing through a porous, permeable formation, wherein a water-based well fluid is circulating in said well. In this method, there is added to the fluid not only the conventional ingredients for such a fluid but also a maximum of 10 wt. % of a composition obtained from a grease or oil and an alcohol, with the chain lengths of the acid and alcohol parts being chosen such that the ester thus obtained has sufficient dispersion in water, compatibility with said ingredients, does not form an emulsion with the reservoir oil, and adsorbs sufficiently on the porous formation.
    Type: Grant
    Filed: July 28, 2000
    Date of Patent: May 25, 2004
    Assignees: Institut Francais du Petrole, Oleon NV
    Inventors: Annie Audibert, Jean-François Argillier, Daniel Longeron, Carine Dewattines, Michel Janssen
  • Publication number: 20040045710
    Abstract: A method of treating a hydrocarbon-containing formation is disclosed.
    Type: Application
    Filed: August 30, 2002
    Publication date: March 11, 2004
    Inventors: Diankui Fu, Marieliz Garcia-Lopez de Victoria
  • Patent number: 6667280
    Abstract: This Invention relates to a novel reversible thickener, i.e., a fluid whose viscosity can be carefully modulated—from very low viscosity to sufficient viscosity to act as a barrier to further flow; particularly preferred embodiments are directed to fluids and methods for stimulating hydrocarbon low viscosity to sufficient viscosity to act as a barrier to further flow; particularly preferred—bearing formations—i.e., to increase the production of oil/gas from the formation. In particular, the Present Invention is directed to a family of fluids (and methods incorporating those fluids) intended to be pumped through a wellbore and into the hydrocarbon-bearing formation.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: December 23, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Frank F. Chang, Qi Qu, Matthew J. Miller
  • Patent number: 6662871
    Abstract: A new composition for a spotting fluid and a method of using such spotting fluid for freeing differential stuck pipe in a subterranean well drilling operation is disclosed. The composition comprises an invert water-in-oil emulsion comprising iso-butyl oleate as its external phase and glycerin as the internal phase. In an alternative embodiment, calcium chloride and water may be substituted for glycerin.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: December 16, 2003
    Assignee: Halliburton Energy Services, Inc.
    Inventors: James D. Kercheville, Kenneth W. Pober