Organic Component Contains An Alcohol Group Patents (Class 507/266)
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Publication number: 20130228333Abstract: A method of servicing a wellbore comprising identifying lost circulation zone within a wellbore; and placing in the wellbore a composition comprising a wax and a water-based mud wherein placement of the composition reduces or prevents a loss of fluids to the lost circulation zone. A wellbore servicing fluid comprising a water-based mud, a sized calcium carbonate particle and a wax.Type: ApplicationFiled: March 5, 2012Publication date: September 5, 2013Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventor: Matthew Lynn Miller
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Publication number: 20130213659Abstract: A breaker fluid for breaking a filtercake in a wellbore. The fluid including a hydrolysable ester of carboxylic acid, and a chelant, an alkyl glycoside, or a combination thereof. The breaker fluid may be pre-mixed and include an amount of water less than required to completely hydrolyze the ester.Type: ApplicationFiled: June 30, 2011Publication date: August 22, 2013Applicant: M-I L.L.C.Inventors: Mark Luyster, LaTosha Moore, Andrew Jones
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Publication number: 20130213657Abstract: Disclosed are aqueous-based compositions and methods for treating a subterranean formation for inhibiting formation damage after the treatment. Compositions include an aqueous-based fluid, gelling agents, sparingly-soluble crosslinking agents, and one or more formation damage prevention agents, such as scale inhibitors, iron control agents, non-emulsifiers, clay stabilizers, or polymer breakers. The methods include performing a well treating operation, such as a hydraulic fracturing operation, using the compositions described and inhibiting formation damage, such as scale, iron formation, emulsions, or clay swelling within the subterranean formation. The inclusion of the formation damage preventing agents allows for long-term formation damage inhibition after the treatment.Type: ApplicationFiled: February 22, 2013Publication date: August 22, 2013Applicant: TEXAS UNITED CHEMICAL COMPANY, LLCInventor: Texas United Chemical Company, LLC
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Patent number: 8499835Abstract: A method of agglomerating coal particles in a subterranean formation having a coal seam, comprising the steps of providing (a) a fluid having an aqueous medium and a first collector and/or a frother; (b) pumping the fluid into the formation and (c) contacting coal particles in the formation thereby agglomerating the contacted coal particles.Type: GrantFiled: June 13, 2008Date of Patent: August 6, 2013Assignee: Trican Well Services, Ltd.Inventors: Kewei Zhang, Chris Wiggins
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Publication number: 20130196885Abstract: A method for replacing glycol-based mutual solvents in an oil field application comprising: obtaining an alternative solvent and solvent blends and replacing all or a portion a glycol-based mutual solvent, which forms a component of an oil field formulation, with the alternative solvent or solvent blends, wherein the oil field formulation can be utilized in an oil field application.Type: ApplicationFiled: August 1, 2012Publication date: August 1, 2013Applicant: Rhodia OperationsInventors: Ruela Talingting PABALAN, Dominique LABARRE, Gary WOODWARD, Bruno LANGLOIS, Adedamola ADEDEJI
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Publication number: 20130178400Abstract: Emulsified acids have been used to increase production rates of oil and gas in carbonate reservoirs through acid fracturing and matrix acidizing operations. An emulsifier is used to emulsify the aqueous acid with an oil, usually diesel. Very small particles, such as colloidal clay particles and/or nanoparticles increase the stability of the emulsified acids over an elevated temperature range.Type: ApplicationFiled: February 28, 2013Publication date: July 11, 2013Applicant: Baker Hughes IncorporatedInventors: Tianping Huang, James B. Crews, John R. Willingham, Richard A. Mitchell, Kushal Seth
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Publication number: 20130175037Abstract: A method of reducing the presence of particles in a downhole environment, comprising contacting sediment particles contained in a downhole environment, with a composition comprising: a metallic composition, an inorganic oxide-based polymer, and a solvent; the contacting occurring in the presence of a fluid capable of decomposing the metallic compositionType: ApplicationFiled: January 8, 2013Publication date: July 11, 2013Applicant: Baker Hughes IncorporatedInventors: James Crews, Othon R. Monteiro
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Patent number: 8481463Abstract: A grouting composition for use in insulating a portion of a tubular located inside an enclosed conduit comprises: (A) an oil-swellable binding material comprising a organophilic clay; and (B) a hydrocarbon liquid, wherein the hydrocarbon liquid is the continuous phase of the grouting composition; and (C) an insulating material comprising a hollow microsphere, wherein after the grouting composition has set, the grouting composition has a thermal conductivity of less than 0.3 BTU/hr·ft·° F.Type: GrantFiled: June 22, 2012Date of Patent: July 9, 2013Assignee: Halliburton Energy Services, Inc.Inventor: Eric B. Frantz
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Publication number: 20130172218Abstract: Compounds of biodegradable surfactants useful for optimizing the separation of impurities typical of hydrocarbons, and designed to intervene and stabilize the molecular structure of crude oil, with no significant alterations of the crude's intrinsec composition are disclosed. The biodegradable surfactants compounds coexist with a non-ionic surfactant and an organic mix in emulsion form with the purpose of isolating crude from the pipeline, reduce friction to improve crude flow and to enter the crude macromolecule to modify the hydrocarbon chain to reduce its density and thus its viscosity; including compounds of biodegradable surfactants that comprise sodium hydroxide 1N, potasium chloride, sulphonic acid, dodecanoic acid, nonylphenol, terpene-1 and water, preferably hard water.Type: ApplicationFiled: May 18, 2012Publication date: July 4, 2013Applicant: ENVIROMENTAL DEVELOPMENT PRODUCTS (ENDEVPRO), LIMITEDInventors: Osmerio Enrique Labarca Finol, Rixio Egardo Reyes Lopéz
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Publication number: 20130157906Abstract: A fracturing fluid, gravel pack fluid and/or frac pack fluid containing particles such as proppants, gravel and/.or sand, may contain an effective amount of a nano-sized particulate additive to fixate or reduce fines migration, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides piezoelectric crystals and pyroelectric crystals. The nano-sized particulate additive is optionally bound to the particles with a coating agent such as an oil, alcohol, glycol, glycol ethers, ketones, terpenes, etc. The particle size of the magnesium oxide or other agent may be nanometer scale but may be a larger scale than nanometer but still relatively small, which scale may provide unique particle charges that help fixate the formation fines.Type: ApplicationFiled: February 20, 2013Publication date: June 20, 2013Applicant: Baker Hughes IncorporatedInventors: Tianping Huang, James B. Crews, John R. Willingham, James R. Pace, Christopher K. Belcher
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Publication number: 20130146295Abstract: Disclosed is a filter cake removal composition, and method of use thereof, for use in a wellbore for controlled removal of a filter cake present in a target production zone. The filter cake removal composition includes hydrochloric acid and an organic acid. The filter cake removal composition, when a mixture of the hydrochloric acid and the organic acid is applied to the filter cake in the target production zone, is operable to dissolve the filter cake in the target production zone over an extended reaction time. The mixture includes the hydrochloric acid present in an amount of between about 0.1% and 5% by weight and the organic acid present in an amount of between about 0.1% and 10% by weight.Type: ApplicationFiled: December 7, 2012Publication date: June 13, 2013Applicant: SAUDI ARABIAN OIL COMPANYInventor: Saudi Arabian Oil Company
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Publication number: 20130123151Abstract: A method for breaking the viscosity of an aqueous fluid gelled with a viscoelastic surfactant (VES) is disclosed. The method includes providing an aqueous fluid and adding to the aqueous fluid, in any order: at least one VES comprising a non-ionic surfactant, cationic surfactant, amphoteric surfactant or zwitterionic surfactant, or a combination thereof, in an amount sufficient to form a gelled aqueous fluid comprising a plurality of elongated micelles and having a viscosity, and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles dispersed within the gelled aqueous fluid. The method also includes dissolving the metallic particles in the gelled aqueous fluid to provide a source of at least one transition metal ion in an amount effective to reduce the viscosity.Type: ApplicationFiled: November 14, 2011Publication date: May 16, 2013Applicant: BAKER HUGHES INCORPORATEDInventor: James B. Crews
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Publication number: 20130112417Abstract: Guard bed compositions for protecting metal surfaces in a wellbore from corrosion may comprise a variety of constituent components. Exemplary guard bed compositions may include: one or more surfactants selected from the group comprising amine surfactants; one or more co-surfactants selected from the group comprising C3 to C15 alcohols; and one or more non-surfactant amines. Other exemplary guard bed compositions may comprise: a hydrocarbon fluid and an overbased detergent. Still other exemplary guard bed compositions may comprise: a hydrocarbon fluid; one or more surfactants; one or more co-surfactants; and one or more non-surfactant amines. The one or more surfactants may be selected from the group comprising alkyl alkoxylated surfactants. Still further, exemplary guard bed compositions may comprise: a hydrocarbon fluid and one or more associating surface active polymers selected from the group comprising amphiphilic polymers.Type: ApplicationFiled: May 9, 2011Publication date: May 9, 2013Inventors: Ramesh Varadaraj, Sabine C. Zeilinger, Catalin Dragos Ivan
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Publication number: 20130105163Abstract: A method of opening productive formations by slot-perforating includes providing a working fluid including water, an abrasive component, and an additive, supplying the working fluid at a high pressure towards a formation so as to cut slots and to provide an inflow of oil, gas and hydrogeological liquid from the formation into a borehole, and using the additive, so as to reduce density of the working fluid and therefore to increase a speed of jet of the working fluid due to increase of kinetic energy of particles of the abrasive component.Type: ApplicationFiled: November 2, 2011Publication date: May 2, 2013Inventors: Anatoli Nikouline, Nikolai Korvet
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Patent number: 8424600Abstract: The present invention is directed to a method and system for treating a well having a wellbore extending from a ground surface or subsea surface downhole to an oil producing formation. Oil producing formations are capable of generating formation fluids into a wellbore. Formation fluids are comprised of at least an oil fraction and an aqueous fraction. Emulsions may form during oil production, and such emulsions may be comprised of oil and water. Inhibitor compositions may be employed to break such emulsions.Type: GrantFiled: May 24, 2010Date of Patent: April 23, 2013Assignee: Chevron U.S.A. Inc.Inventor: Darrell L. Gallup
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Publication number: 20130092376Abstract: A spacer fluid made of a viscosity thinner, a weighting agent, an antifoaming agent, and a non-ionic surfactant in a base aqueous fluid. In some instances, the viscosity thinner is a sulfomethylated tannin, the weighting agent is barium sulfate, the antifoaming agent is a silicone, and the non-ionic surfactant is an ethoxylated alcohol. A method of treating a well bore annulus in preparation of introducing water-based cement slurry into a well bore using the spacer fluid. A method of using the spacer fluid to position a first fluid into a well bore annulus of a well bore containing a second fluid. A method for fluidly isolating at least a portion of a well bore annulus in a well bore containing an oil-based drilling fluid using water-based cement slurry and the spacer fluid.Type: ApplicationFiled: October 12, 2012Publication date: April 18, 2013Applicant: Saudi Arabian Oil CompanyInventor: Saudi Arabian Oil Company
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Patent number: 8418759Abstract: Fluorinated polymers having first divalent units represented by formula, and a plurality of groups of formula —CH2—CH2—O—. Compositions containing the fluorinated polymer and solvent, and methods of treating hydrocarbon-bearing formations using these compositions are disclosed. A method of making a composition containing the fluorinated polymer is also disclosed.Type: GrantFiled: December 18, 2008Date of Patent: April 16, 2013Assignee: 3M Innovative Properties CompanyInventors: George G. I. Moore, Rudolf J. Dams, Jimmie R. Baran, Jr.
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Patent number: 8404623Abstract: According to one aspect of the inventions, emulsion compositions are provided. Emulsions according to this aspect include: (a) a water-insoluble resinous material; (b) water; and (c) an emulsifier, wherein the emulsifier comprises a non-ionic, a cationic, or a zwitterionic emulsifier; wherein the continuous phase of the emulsion comprises the water; wherein a dispersed phase of the emulsion comprises the resinous material; wherein the dispersed phase is in the form of droplets having a size distribution range such that at least 50% of the droplets have a size of 0.5 micrometers-500 micrometers; wherein the resinous material of the droplets is in a concentration of at least 5% by weight of the water; and wherein the composition of the droplets has a viscosity of less than 2,000 Poise measured at 20° F. According to another aspect of the inventions, methods are provided for treating a portion of a subterranean formation.Type: GrantFiled: July 17, 2009Date of Patent: March 26, 2013Assignee: Halliburton Energy Services, Inc.Inventors: Ian D. Robb, Sherry G. Gaskins, Jimmie D. Weaver, Phillip D. Nguyen
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Publication number: 20130056204Abstract: Proppants for use in fractured or gravel packed/frac packed oil and gas wells are provided with a contaminant removal component to remove one or more of the contaminants found in subterranean water/hydrocarbon from a production well. The water/hydrocarbon cleaning proppant solids may be used as discrete particles in a proppant formulation, as a coating on proppant solids in pores of a porous proppant solid or as part of the proppant's internal structure. The contaminant removal component removes contaminants, especially dissolved contaminants, in the subterranean water or hydrocarbon before the water/hydrocarbon leaves the well. For those contaminant removal components that can be regenerated, such as ion exchange resins, a measured quantity of an acidic regeneration solution can be injected into the fractured stratum for regeneration and recovered when the well resumes production.Type: ApplicationFiled: September 2, 2011Publication date: March 7, 2013Applicant: PREFERRED TECHNOLOGY, LLCInventors: Robert Ray McDaniel, Avis Lloyd McCrary
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Publication number: 20130048281Abstract: A method of servicing a wellbore comprising placing a composition comprising a microemulsion surfactant and a completion fluid into a wellbore, wherein the composition is substantially free of an organic solvent. A method of servicing a wellbore having a permeable zone comprising introducing a composition comprising a brine and a microemulsion surfactant to the wellbore proximate to the permeable zone wherein at least a portion of the composition enters the permeable zone and wherein the composition excludes an organic solvent. A wellbore servicing fluid comprising a microemulsion surfactant and a completion fluid.Type: ApplicationFiled: August 25, 2011Publication date: February 28, 2013Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Ryan VAN ZANTEN, Per-Bjarte TANCHE-LARSEN
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Patent number: 8383557Abstract: Incorporating water-based polymer breakers, such as oxidizers, enzymes and/or acids, into a mixture of an oil and oil-soluble surfactants creates an emulsion that can then perform as a dual-functional breaker for reducing the viscosity of hybrid fluids gelled with both a viscoelastic surfactant (VES) and a polymer. The outer phase of the dual-functional breaker emulsion is oil, e.g. a mineral oil, containing an oil-soluble surfactant that will, over time and with heat, break the VES portion of the gel. As it does so, the polymer breaker in the internal aqueous phase will be released to then break the polymer portion of the gel. The polymer breaker will not start to break the polymer gel before the oil-soluble surfactant starts to break the VES gel. The overall breaking using the emulsion is slower as compared to introducing the polymer breaker and the oil-soluble surfactant in a non-emulsified form.Type: GrantFiled: June 15, 2010Date of Patent: February 26, 2013Assignee: Baker Hughes IncorporatedInventors: Tianping Huang, James B. Crews
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Publication number: 20130029884Abstract: Biocide compositions comprising biocide, surfactant, and solubilizing agent. The preferred biocide is parachlorometaxylenol. The biocide composition is useful in oil and gas drilling operations, such as hydraulic fracturing, as well as treating aqueous slurries in ore mining operations. The biocide compositions are effective in controlling microorganisms even in the presence of high salt content water and at high temperatures.Type: ApplicationFiled: July 23, 2012Publication date: January 31, 2013Applicant: ENVIROSYSTEMS, INC.Inventors: Paul S. Malchesky, George E. Grignol, J. Lloyd Breedlove
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Publication number: 20120322694Abstract: A base fluid may contain nanoparticles where the base fluid may include a non-aqueous fluid, an aqueous fluid, and combinations thereof. The fluid may have a resistivity range of from about 0.02 ohm-m to about 1,000,000 ohm-m. The non-aqueous fluid may be a brine-in-oil emulsion, or a water-in-oil emulsion; and the aqueous fluid may be an oil-in-water emulsion, or an oil-in-brine emulsion; and combinations thereof. The addition of nanoparticles to the base fluid may improve or increase the electrical conductivity and other electrical properties of the fluid. The fluid may be a drilling fluid, a completion fluid, a production fluid, and/or a stimulation fluid.Type: ApplicationFiled: July 10, 2012Publication date: December 20, 2012Applicant: BAKER HUGHES INCORPORATEDInventors: Othon Rego Monteiro, Jonathan J. Brege, Lirio Quintero, Soma Chakroborty, Ashley D. Leonard, Chad F. Christian
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Publication number: 20120312533Abstract: Processes for recovering hydrocarbons from subterranean formations are disclosed. The hydrocarbon can be contacted with water or steam and one or more additives, and subsequently recovered. The hydrocarbon can be selected from heavy or light crude oil, bitumen, an oil sand ore, a tar sand ore, and combinations thereof. The additive can be, for example, an aromatic hydrocarbon. Compositions or mixtures including hydrocarbons, water or steam, and additives are also disclosed.Type: ApplicationFiled: June 13, 2011Publication date: December 13, 2012Inventor: Kimberly Jantunen Cross
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Publication number: 20120302470Abstract: The present invention provides compositions, methods, apparatus, and systems to minimize environmental impact, water use, and overall cost of drilling and hydraulic fracturing for crude oil and natural gas. Some variations of the invention provide a fracturing-fluid additive composition comprising a water-soluble portion of a biomass-pyrolysis liquid. In some embodiments, the fracturing-fluid additive composition is substantially biodegradable and is not toxic. Some variations provide improved proppants for oil or gas well fracturing. Other variations of this invention relate to drilling-fluid additive compositions, and methods of using these compositions. This invention can significantly improve the environmental, economic, and social sustainability associated with drilling and fracturing for production of oil and gas.Type: ApplicationFiled: May 24, 2012Publication date: November 29, 2012Applicant: AVELLO BIOENERGY, INC.Inventors: Anthony J. S. POLLARD, Dennis S. BANASIAK, Cody J. ELLENS, Jared N. BROWN
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Publication number: 20120283155Abstract: The migration of coal fines within a bed is reduced, inhibited or constrained by contacting the fines with nanoparticles, such as magnesium oxide crystals having an average particle size of about 30 nm. These nanoparticles may coat a proppant during the fracturing of a subterranean formation to produce methane from a coal bed therein. The nanoparticles may also treat a proppant pack in a fractured coal bed. The nanoparticles cause the coal fines to thus bind to or associate with the proppants. Thus, most of the coal fines entering fractures away from the near-wellbore region will be restrained or controlled near their origin or source and the production of methane at a desired level will be maintained much longer than a similar situation than where the nanoparticles are not used.Type: ApplicationFiled: July 18, 2012Publication date: November 8, 2012Applicant: Baker Hughes IncorporatedInventors: Tianping Huang, James B. Crews, Allen D. Gabrysch, Rick M. Jeffrey
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Patent number: 8298996Abstract: A low toxicity composition and method of reducing the swelling of clay in well comprising circulating in the well a water-based fluid comprising a functionally effective concentration of the additive formed from the following reaction of a tertiary amine of the following general formula: wherein R1 and R2 are alkyl or hydroxyalkyl groups with one to three carbon atoms or combinations thereof, and R3 is a hydroxyalkyl group with one to three carbon atoms, with an alkylating agent of the following general formula: R-A wherein R is an alkyl radical with one to three carbon atoms, and A is an organic or inorganic anion selected from the group consisting of sulfate, phosphate, carbonate, and combinations thereof.Type: GrantFiled: April 8, 2011Date of Patent: October 30, 2012Assignee: M-I L.L.C.Inventor: Arvind D. Patel
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Publication number: 20120255728Abstract: The present invention relates to methods and compositions that can be used to delay crystallization of a treatment solution so that thief zones or fractures are plugged in subterranean formations at a substantial distance from a wellbore. A supersaturated sodium aluminate solution, or other solutions, are introduced into the reservoir. The solution is relatively stable in the supersaturated state. Crystallization, or de-stabilizing the solution, can be controlled, which in turn plugs the thief zone or fracture at a designed point of time. By controlling the time that crystallization starts, i.e., the induction period, thief zones that are located at a substantial distant from the wellbore can be plugged.Type: ApplicationFiled: April 11, 2011Publication date: October 11, 2012Applicant: Saudi Arabian Oil CompanyInventors: Xianmin Joe Zhou, Yun Chang
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Publication number: 20120241158Abstract: A method for using a fracture fluid in forming subterranean fractures includes delaying degradation of a polymer in a fracture fluid when the fracture fluid comprises a breaker by combining at least one radical scavenger with the fracture fluid. The mixture for use in a fracture fluid comprises a radical scavenger and a breaker. A method of fracturing a subterranean formation may include providing a fracture fluid comprising a proppant, a polymer, and a breaker and adding a radical scavenger to the fracture fluid. The fracture fluid is supplied to a desired location in the subterranean formation to form at least one fracture where the viscosity of the fracture fluid is maintained. The breaker is then allowed to degrade the polymer and reduce the viscosity of the fracture fluid at a specific time or temperature.Type: ApplicationFiled: December 6, 2010Publication date: September 27, 2012Applicant: Arkema Inc.Inventors: Sri R. Seshadri, Leonard H. Palys, James J. Feorino, JR.
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Patent number: 8273693Abstract: Coacervate gels having excellent shear viscosities and other properties are made with anionic or cationic polymers, a smaller amount of a surfactant having a charge opposite that of the polymer, and a hydrophobic alcohol and an effective amount of a phosphorus-containing compound sufficient to increase the viscosity of coacervate gels up to 3 times as compared to the gels in the absence of the phosphorus-containing compound. The Zeta Potential of the gel is maintained at an absolute value of at least 20. Optional gel promoting additives include betaines and amine oxides. A preferred gel comprises poly diallyl dimethyl ammonium chloride, a lesser amount of sodium lauryl sulfonate, and lauryl alcohol. The gels are particularly useful in well drilling fluids and well fracturing fluids.Type: GrantFiled: June 8, 2007Date of Patent: September 25, 2012Assignee: Clearwater International LLCInventor: Kevin M. Schwartz
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Patent number: 8273692Abstract: Methods of reducing the permeability of a subterranean formation to aqueous-based fluids using a water-soluble relative permeability modifier that comprises a hydrophobically modified polymer, wherein the hydrophobically modified polymer is a reaction product of: a hydrophilic polymer that comprises a polymer selected from the group consisting of a polyvinylamine, a poly(vinylamine/vinyl alcohol), and an alkyl acrylate polymer; and, a hydrophobic compound comprising at least one alkyl chain having a carbon chain length between about 4 and about 22 carbons. The water-soluble relative permeability modifier may be placed within a subterranean drilling operation such that the water-soluble relative permeability modifier attaches onto surfaces within the subterranean formation to effect permeability of aqueous fluids.Type: GrantFiled: August 10, 2011Date of Patent: September 25, 2012Assignee: Halliburton Energy Services, Inc.Inventors: Larry S. Eoff, Eldon D. Dalrymple, B. Raghava Reddy
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Publication number: 20120234540Abstract: Methods comprising providing a dry, solid particulate material comprising a cementitious material, a non-cementitious material, or a combination thereof and having a flow enhancing additive absorbed thereon. The flow enhancing additive comprises a flow inducing chemical, ethylene glycol, and water. The coated, dry, solid material is then mixed with a sufficient amount of water to form a pumpable slurry and then the slurry may be placed in a subterranean formation. In some cases the dry, solid particulate material comprising a cementitious material, a non-cementitious material, or a combination thereof and having a flow enhancing additive absorbed thereon may be stored for a period of time before the slurry is formed.Type: ApplicationFiled: June 1, 2012Publication date: September 20, 2012Applicant: Halliburton Energy Services, Inc.Inventors: Sam Lewis, Rita McKinley, Russell Fitzgerald
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Publication number: 20120220503Abstract: The concentrate solution for the crosslinking of polymers comprises water, polyol, a viscosifying agent, a first borate ion in solution, and a crosslinking agent able to release a second borate ion, wherein the second borate ion is not in solution.Type: ApplicationFiled: February 24, 2011Publication date: August 30, 2012Inventors: Javier Sanchez Reyes, Michael D. Parris
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Patent number: 8220546Abstract: Methods for using a microemulsion system are disclosed which comprises a solvent subsystem, a co-solvent subsystem and a surfactant subsystem comprises at least one monoalkyl branched propoxy sulfate anionic surfactant, where the microemulsion system are useful in drilling, producing, remediation, and fracturing application to reduce water blocks and water blocking in formation of a producing formation.Type: GrantFiled: April 4, 2011Date of Patent: July 17, 2012Inventors: Sarkis R. Kakadjian, Frank Zamora, Tina Garza
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Publication number: 20120152536Abstract: The instant invention pertains to a composition which may be useful for enhancing oil recovery. The composition typically comprises the reaction mixture of at least (a) two or more compounds capable of generating at least about 20 kcal to about 150 kcal per mole when contacted; (b) one or more suitable surfactants or one or more suitable polymers or a mixture thereof; and (c) oil. The invention also pertains to a method for enhancing oil recovery wherein a suitable system is injected through a wellbore into a reservoir to enhance mobility of oil.Type: ApplicationFiled: December 17, 2010Publication date: June 21, 2012Applicant: Chevron U.S.A. Inc.Inventors: Gregory Winslow, Gabriel Prukop, Varadarajan Dwarakanath
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Publication number: 20120152544Abstract: Disclosed herein is a well treatment fluid comprising an aqueous solution comprising greater than or equal to about 1 wt % boron, at least 5 wt % of a co-solvent, and greater than or equal to about 5 wt % sodium hydroxide, potassium hydroxide, or a combination thereof, wherein the co-solvent comprises glycerol, ethylene glycol, propylene glycol, or a combination thereof. Methods of using the well treatment fluid are also disclosed.Type: ApplicationFiled: December 7, 2011Publication date: June 21, 2012Inventors: Michael D. Parris, Li Jiang, Don Williamson
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Patent number: 8193127Abstract: A fluid system for hydraulic fracturing operations which comprises a low residue fluid that facilitates the clean up of the wellbore following the treatment is disclosed. The system includes a surfactant compound that forms micelles above a critical concentration. Under certain conditions the addition of an associative thickener compound yields a network based on hydrophobic interactions. The resulting viscous fluid can transport proppants, be applied neat or as a foamed or energized system, or used in an acidizing treatment. The fluid system may further include a breaker additive.Type: GrantFiled: February 4, 2009Date of Patent: June 5, 2012Assignee: Sanjel CorporationInventors: Karena Thieme, Sally Lawrence
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Patent number: 8183182Abstract: A composition of a microemulsion including a mixture of a combination of surfactants and co-surfactants, an oil phase and an aqueous phase is described. In addition, a method for the advanced recovery of heavy oils is described which includes the steps of injecting a bank containing a microemulsion composition, injecting a bank of a polymer solution, and injecting water. The microemulsion composition can be applied in arenitic and carbonatic reservoirs, containing oils with API below 22.3° API, in both onshore and offshore fields.Type: GrantFiled: June 18, 2009Date of Patent: May 22, 2012Assignee: Petroleo Brasileiro S.A.—PetrobrasInventors: Marcia Cristina Khalil Oliveira, Gaspar Gonzalez Maldonado
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Publication number: 20120118569Abstract: An oxygen scavenger for completion brines effective and stable in high temperature subterranean formations. In one embodiment, the scavenger contains erythorbate and alkylhydroxlyamine.Type: ApplicationFiled: November 16, 2010Publication date: May 17, 2012Inventor: Jay Paul Deville
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Patent number: 8173581Abstract: Solid, particulate dicarboxylic acids may be fluid loss control agents and/or viscosifying agents for viscoelastic surfactant (VES) fluids in treatments such as well completion or stimulation in hydrocarbon recovery operations. The fluid loss control agents may include, but not be limited to, dodecanedioic acid, undecanedioic acid, decanedioic acid, azelaic acid, suberic acid, and mixtures thereof having a mesh size of from about 20 mesh to about 400 mesh (about 841 to about 38 microns). A mutual solvent or a blend of at least two alcohols subsequently added to the aqueous viscoelastic surfactant treating fluid will at least partially dissolve the solid, particulate dicarboxylic acid fluid loss control agents, and optionally also “break” or reduce the viscosity of the aqueous viscoelastic surfactant treating fluid.Type: GrantFiled: May 19, 2008Date of Patent: May 8, 2012Assignee: Baker Hughes IncorporatedInventor: Tianping Huang
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Patent number: 8163676Abstract: An oil-in-water emulsion that includes a brine continuous phase; and an oleaginous discontinuous phase stabilized by an emulsifier blend, the emulsifier blend comprising: an emulsifier having an HLB greater than 11; and an amphoteric chemotrope is disclosed. Emulsifier blends comprising an emulsifier having an HLB greater than 11 and an amphoteric chemotrope and methods of using emulsifier blends are also disclosed.Type: GrantFiled: November 21, 2008Date of Patent: April 24, 2012Assignee: M-I L.L.C.Inventors: Eugene Dakin, Hui Zhang, Bethicia B. Prasek
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Publication number: 20120088700Abstract: An asphaltene and resin precipitation inhibiting solution formed of an asphaltene and resin precipitation inhibiting compound and a solvent miscible in a carbon dioxide liquid or supercritical fluid. The inhibiting compound includes a head region with an affinity for asphaltene and resin components of a hydrocarbon mixture that is greater than its affinity for water, carbon dioxide, and aliphatic components of the hydrocarbon mixture. The head region includes one or more unsaturated hydrocarbon groups or one or more nonionic dipolar groups. The inhibiting compound also includes a tail region with an affinity for carbon dioxide that is greater than its affinity for substantially all components of the hydrocarbon mixture and water. The tail region includes one or more nonionic quadrupolar groups. An effective amount of solution is added to a hydrocarbon mixture in an underground reservoir when employing a carbon dioxide fluid to flush the hydrocarbon mixture from the reservoir.Type: ApplicationFiled: October 12, 2011Publication date: April 12, 2012Applicant: CHAMPION TECHNOLOGIES, INC.Inventor: Paul R. Hart
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Patent number: 8129316Abstract: A method of creating a carbon dioxide hydrate is disclosed. The preferred steps include supplying liquid carbon dioxide and a dissociation agent to a hydrocarbon hydrate, decomposing the hydrocarbon hydrate by the dissociation agent into a hydrocarbon gas and liquid water, and forming the carbon dioxide hydrate from the liquid carbon dioxide and the liquid water. The dissociation agent preferably is at least one of an inorganic salt, a surface active agent, a hydrate inhibitor, and an absorption solution. Furthermore, a substance composition of liquid carbon dioxide and the dissociation agent is described, which is provided for depositing carbon dioxide hydrate in a subterranean geological formation. Furthermore, a deposition device is described, which is configured for depositing carbon dioxide hydrate in a subterranean geological formation.Type: GrantFiled: June 19, 2009Date of Patent: March 6, 2012Assignee: Bergen Teknologioverforing ASInventor: Bjorn Kvamme
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Patent number: 8105989Abstract: A method of cleaning a wellbore prior to the production of oil or gas is disclosed, wherein the wellbore has been drilled with an invert emulsion drilling mud that forms an invert emulsion filter cake. The method may include the steps of circulating a breaker fluid into the wellbore, where the breaker fluid includes an aqueous fluid, a water soluble polar organic solvent, a hydrolysable ester of a carboxylic acid, and a weighting age, and where the hydrolysable ester is selected so that upon hydrolysis an organic acid is released and the invert emulsion of the filter cake breaks.Type: GrantFiled: January 20, 2006Date of Patent: January 31, 2012Assignee: M-I L.L.C.Inventors: Charles Svoboda, Raymond D. Ravitz, Mark Luyster
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Patent number: 8093187Abstract: Composition and method for shortening the shear recovery time of cationic, zwitterionic, and amphoteric viscoelastic surfactant fluid systems by adding an effective amount of a co-gelling agent selected from triblock oligomeric compounds having hydrophilic (for example polyether) and hydrophobic (for example alkyl) portions. The co-gelling agent also increases fluid viscosity and very low co-gelling agent concentration is needed. Preferred surfactants are betaines and quaternary amines. The fluids are useful in oilfield treatments, for example fracturing and gravel packing.Type: GrantFiled: January 17, 2008Date of Patent: January 10, 2012Assignee: Schlumberger Technology CorporationInventors: Yiyan Chen, Jesse C. Lee
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Patent number: 8084401Abstract: New fluids are disclosed for use in servicing subterranean formations containing oil and gas. In particular, an improved chemical gelling additive for hydrocarbon based fracturing fluids is disclosed having reduce, negligible or no volatile phosphorus at temperatures below about 250° C.Type: GrantFiled: January 25, 2006Date of Patent: December 27, 2011Assignee: Clearwater International, LLCInventors: Brent Lukocs, Shaun Mesher, Thomas P Wilson, Jr., Tina Garza, Wayne Mueller, Frank Zamora, Larry W. Gatlin
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Patent number: 8071512Abstract: An annular fluid or packer fluid, and methods of making the same, that includes a water-miscible solvent, a viscosifying additive, a crosslinking agent, a crosslinking inhibitor having the facility to inhibit crosslinking between the viscosifying additive and the crosslinking agent, and an initiating agent having the facility to overcome an action of the crosslinking inhibitor and to initiate crosslinking between the viscosifying additive and the crosslinking agent, is shown and described. The fluid has a thermal conductivity of no more than about 0.25 btu/(hr·ft·° F.) and a potential to substantially increase its viscosity upon sitting for a selected period of time.Type: GrantFiled: October 12, 2010Date of Patent: December 6, 2011Assignee: M-I L.L.C.Inventors: Andrew G. K. Jones, Bethicia B. Prasek, Robert L. Horton
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Publication number: 20110287985Abstract: The present invention is directed to a method and system for treating a well having a wellbore extending from a ground surface or subsea surface downhole to an oil producing formation. Oil producing formations are capable of generating formation fluids into a wellbore. Formation fluids are comprised of at least an oil fraction and an aqueous fraction. Emulsions may form during oil production, and such emulsions may be comprised of oil and water. Inhibitor compositions may be employed to break such emulsions.Type: ApplicationFiled: May 24, 2010Publication date: November 24, 2011Applicant: Chevron U.S.A. Inc.Inventor: Darrell L. Gallup
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Publication number: 20110284228Abstract: In hydrocarbon recovery applications, viscoelastic surfactant (VES) gelled fluids may be preheated to a temperature that will increase viscosity of the VES gelled fluid. The preheated VES gelled fluid retains at least a portion of its preheated viscosity when cooled such as by introduction into a low temperature condition. In an embodiment, the VES gelled fluid may be a drilling fluid, completion fluid, or fracturing fluid, and the low temperature condition may be an offshore operation, an operation in a locality having a cold climate, and/or a shallow oil, gas, or both land-based operation where the formation temperature is 120° F. or less. The surfactant in the VES gelled fluid may be one or more of an amine, amine salt, quaternary ammonium salt, betaine, amidoamine oxide, amine oxide, and combinations thereof.Type: ApplicationFiled: May 19, 2010Publication date: November 24, 2011Applicant: BAKER HUGHES INCORPORATEDInventors: Tianping Huang, James B. Crews, Guarav Agrawal
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Patent number: 8062999Abstract: Sealant compositions comprising a colloidally stabilized latex and methods of using the same to service a wellbore are provided. The sealant compositions may include: an aliphatic conjugated diene monomer; an additional monomer comprising a non-aromatic unsaturated mono- or di- carboxylic ester monomer, an aromatic unsaturated monomer, a nitrogen-containing monomer, or combinations thereof; and a protective colloid. The foregoing sealant composition may be displaced into the wellbore to isolate the subterranean formation from a portion of the wellbore, to support a conduit in the wellbore, to plug a void or crack in the conduit, to plug a void or crack in a cement sheath disposed in an annulus of the wellbore, to plug an opening between the cement sheath and the conduit, or combinations thereof. The colloidally stabilized latex remains substantially stable when exposed to salt, which may be present in the wellbore and/or in the sealant composition itself.Type: GrantFiled: May 4, 2007Date of Patent: November 22, 2011Assignee: Halliburton Energy Services Inc.Inventors: B. Raghava Reddy, Anthony V. Palmer