Preventing Contaminant Deposits In Petroleum Oil Conduits Patents (Class 507/90)
  • Patent number: 11898091
    Abstract: Disclosed is a gas hydrate inhibitor composition comprising an amphiphile by a linking moiety, the amphiphile having of the general formula (1) [R5-L-N(R1)(R2)(R3)]+X???(1) wherein each of R1 and R2 is an alkyl group having from 1 to 5 carbon atoms; or wherein the nitrogen atom and the R1 and R2 groups together form a heterocyclic group; R3 is present or not as hydrogen or an alkyl group having from 1 to 8 carbon atoms L is a linking moiety comprising a hydrocarbyl group having at least 2 adjacent carbon atoms, at least one heteroatom selected from nitrogen and oxygen, R5 is a hydrocarbyl group having from 6 to 22 carbon atoms; and X? is present as an anion when R3 is present; and a cationic surfactant which is selected from quaternary benzyl ammonium salts and a method of using the gas hydrate inhibitor composition.
    Type: Grant
    Filed: November 16, 2020
    Date of Patent: February 13, 2024
    Assignee: CLARIANT INTERNATIONAL LTD
    Inventors: Dirk Leinweber, Zachary Thomas Ward, Felix Hoevelmann, Jonathan James Wylde, Matthias Krull
  • Patent number: 11891567
    Abstract: The subject invention provides compositions comprising solvents and surfactants, as well as their use in improving oil and/or gas production. In some embodiments, the compositions comprise chemical or synthetic solvents and/or surfactants. In other embodiments, the compositions comprise biological components, such as microorganisms and/or their growth by-products. The subject invention can be used to dissolve, disperse and/or emulsify paraffin precipitates and/or deposits; prevent and/or inhibit paraffin deposition; remove rust deposits and prevent corrosion associated therewith; inhibit bacterial growth and/or biofilm formation; and to enhance oil recovery.
    Type: Grant
    Filed: July 30, 2022
    Date of Patent: February 6, 2024
    Assignee: Locus Solutions IPCo, LLC
    Inventors: Sean Farmer, Ken Alibek, Tyler Dixon, Karthik N. Karathur
  • Patent number: 11884891
    Abstract: A method of treating petroleum fluids may include adding a flow improver composition to the petroleum fluids, the flow improver composition, comprising: a solvent; and a dendrimer-based flow improver, wherein at least a portion of the surface sites of the dendrimer are chemically modified with saturated and unsaturated fatty acids.
    Type: Grant
    Filed: May 12, 2020
    Date of Patent: January 30, 2024
    Assignee: CAMERON INTERNATIONAL CORPORATION
    Inventors: Tore Nordvik, Rachael Anne Cole, Chandrashekhar Yeshwant Khandekar, Pradyumna Avinash Deshpande
  • Patent number: 11814588
    Abstract: Methods for preventing elemental sulfur deposition from a hydrocarbon fluid is disclosed. A mercaptan is added to a hydrocarbon fluid that has elemental sulfur and reacted with the elemental sulfur to produce a disulfide and hydrogen sulfide. Amines and/or surfactants can assist with the process. Secondary reactions between the disulfide and the elemental sulfur result in a polysulfide and a solvated sulfur-disulfide complex. The disulfide, hydrogen sulfide, polysulfide and solvated sulfur-disulfide complex do not deposit, and can optionally be removed.
    Type: Grant
    Filed: January 5, 2023
    Date of Patent: November 14, 2023
    Assignee: CONOCOPHILLIPS COMPANY
    Inventors: Jay Locklear, David P. Cope
  • Patent number: 11787996
    Abstract: A method may include providing a single-phase cleanout fluid comprising a first nonionic surfactant with a hydrophilic-lipophilic balance (HLB) greater than 10, a second nonionic surfactant with an HLB greater than 10, a third nonionic surfactant with an HLB of less than 10, and a solvent; preparing a cleanout pill by mixing the single-phase cleanout fluid with a brine; and displacing a fluid in a wellbore using the cleanout pill.
    Type: Grant
    Filed: June 7, 2022
    Date of Patent: October 17, 2023
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Emily Hart, Hui Zhou, Kay Ann Galindo
  • Patent number: 11624022
    Abstract: The present invention discloses a preparation method for the plant-based nano corrosion inhibition bactericide for oilfield, comprising the following steps: Step 1. Prepare the aloin liquid; Step 2. Stir the carbon nanotube, hydroxyethyl methacrylate and acrylic acid to react for 4 h at a constant temperature of 80° C. to get the carbon nanotube after fiber treatment, namely the modified carbon nanotube; Step 3. Mix the aloin liquid with imidazoline-ammonium-salt, add acetonitrile, and then add modified carbon nanotube, increase the temperature to 95° C. stir and react for 12 hours, and filter after naturally cooling down to room temperature and get the carbon nanotube loaded with bactericide; Step 4. Stir the carbon nanotube loaded with bactericide, diphenylmethane diisocyanate and polycaprolactone to react for 6 hours at a constant temperature of 95° C. and in the reaction process, continuously inject helium to get the target bactericide.
    Type: Grant
    Filed: July 13, 2022
    Date of Patent: April 11, 2023
    Assignee: Southwest Petroleum University
    Inventors: Xiankang Zhong, Haonan Li, Zhi Zhang, Junying Hu, Li Zhou, Xi Yuan, Lingjie Li
  • Patent number: 11572514
    Abstract: Methods for preventing elemental sulfur deposition from a hydrocarbon fluid is disclosed. A mercaptan is added to a hydrocarbon fluid that has elemental sulfur and reacted with the elemental sulfur to produce a disulfide and hydrogen sulfide. Amines and/or surfactants can assist with the process. Secondary reactions between the disulfide and the elemental sulfur result in a polysulfide and a solvated sulfur-disulfide complex. The disulfide, hydrogen sulfide, polysulfide and solvated sulfur-disulfide complex do not deposit, and can optionally be removed.
    Type: Grant
    Filed: October 5, 2021
    Date of Patent: February 7, 2023
    Assignee: CONOCOPHILLIPS COMPANY
    Inventors: Jay Locklear, David P. Cope
  • Patent number: 11332681
    Abstract: Fouling in a refinery vessel, such as heat transfer equipment, used in a petroleum refinery operation and in which a refineable petroleum feedstock is at an elevated temperature and in fluid communication with the refinery vessel during a petroleum refinery operation, is reduced by providing in the refineable petroleum feedstock an additive comprising (i) a poly(butylenyl)benzene sulphonic acid; or, (ii) a poly(propylenyl)benzene sulphonic acid; or, (iii) a combination of a poly(butylenyl)benzene sulphonic acid and a poly(propylenyl)benzene sulphonic acid.
    Type: Grant
    Filed: September 11, 2020
    Date of Patent: May 17, 2022
    Assignee: Infineum International Limited
    Inventors: Colin Morton, Paul D. Kerby, Andrew C. Sutkowski, Krzysztof J. Maranski
  • Patent number: 11299665
    Abstract: Compositions for stimulating hydrocarbon production from a subterranean formation are generally disclosed. In some embodiments, such compositions include olefinic ester compounds, such as alkyl esters of C10-18 unsaturated fatty acids. In some embodiments, the olefinic ester compounds are derived from a natural oil or a natural oil derivative, for example, by catalytic olefin metathesis. Uses of such compounds, such as in oil- and gas-production methods are also generally disclosed.
    Type: Grant
    Filed: August 22, 2018
    Date of Patent: April 12, 2022
    Assignee: Wilmar Trading Pte. Ltd.
    Inventors: Frederyk Ngantung, Robin Weitkamp
  • Patent number: 11236261
    Abstract: Methods involving anti-agglomerant hydrate inhibitors and polyaromatic hydrocarbons for hydrate inhibition are provided. In some embodiments, the methods include introducing a hydrate inhibitor composition including an anti-agglomerant hydrate inhibitor into a fluid including (i) water and (ii) one of gas, liquid hydrocarbon, and any combination thereof; and introducing a polyaromatic hydrocarbon into the fluid.
    Type: Grant
    Filed: August 23, 2019
    Date of Patent: February 1, 2022
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philippe Prince, Loan Vo, Deepak S. Monteiro, Tai Duc Bui, Alberto Striolo
  • Patent number: 11161804
    Abstract: The instant invention concerns a gas hydrate inhibitor comprising an N alkyl N? (N?,N?-dialkylammoniumalkyl)dicarboxylic acid diamide salt represented by the formula (I) wherein R is an alkyl or alkenyl group having from 8 to 22 carbon atoms, R1 is hydrogen, a C1- to C22 alkyl group or a C3- to C22 alkenyl group, R2 and R3 are each independently an alkyl group containing 1 to 10 carbon atoms or together form an optionally substituted ring having 5 to 10 ring atoms, wherein the ring may carry up to 3 substituents, R4 is hydrogen, A is an optionally substituted hydrocarbyl group containing from 1 to 18 carbon atoms, B is an alkylene group having from 2 to 6 carbon atoms, Y is NR5, R5 is hydrogen, a C1- to C22 alkyl group or a C3- to C22 alkenyl group, and M? is an anion, a process for producing a compound according to formula (I), the use of an N alkyl N?—(N?,N?-dialkylammoniumalkyl)dicarboxylic acid diamide salt of the formula (I) as an anti-agglomerant for gas hydrates, and a method for inhibiting the a
    Type: Grant
    Filed: October 9, 2018
    Date of Patent: November 2, 2021
    Assignee: Clariant International Ltd.
    Inventors: Nirupam Purkayastha, Zachary Thomas Ward, Fabian Schneider, Dirk Leinweber, Matthias Krull, Jonathan James Wylde
  • Patent number: 11130901
    Abstract: The present invention relates to a method to inhibit gas hydrate formation in the field of crude oil and natural gas extraction, transportation and processing.
    Type: Grant
    Filed: December 20, 2017
    Date of Patent: September 28, 2021
    Assignee: Lamberti SPA
    Inventors: Mauro Parini, Andrea Balestrini, Lorenzo Giardini, Giovanni Floridi, Giuseppe Li Bassi
  • Patent number: 11130902
    Abstract: The present invention relates to a method to inhibit gas hydrate formation in the field of crude oil and natural gas extraction, transportation and processing.
    Type: Grant
    Filed: December 20, 2017
    Date of Patent: September 28, 2021
    Assignee: Lamberti SPA
    Inventors: Mauro Parini, Andrea Balestrini, Lorenzo Giardini, Giovanni Floridi, Giuseppe Li Bassi
  • Patent number: 11060012
    Abstract: A solvent mixture comprising a solvent and a polar additive and associated methods.
    Type: Grant
    Filed: April 12, 2017
    Date of Patent: July 13, 2021
    Assignee: SHELL OIL COMPANY
    Inventors: Nirmal Tatavalli-Mittadar, Sunil Ashtekar, Shekhar Jain, Jian Lu, Sujatha Degaleesan, Kamran Akbar Zadeh
  • Patent number: 10626318
    Abstract: Disclosed herein are paraffin suppressant compositions, and methods of making and using them. The compositions comprise a paraffin inhibitor, a hydrocarbon-soluble hydrotrope equivalent, and optionally one or more additional paraffin dispersants. When added to hydrocarbon media such as crude oils to form crude oil compositions, the suppressant compositions inhibit the precipitation of paraffin waxes in the crude oil compositions. The suppressant compositions, added to hydrocarbon media such as hydrocarbon solvents or crude oils, exhibit reduced precipitation, gelling, and/or crystallization of paraffin inhibitor from the hydrocarbon media, when the media are subjected to sustained temperatures between 4° C. and ?60° C.
    Type: Grant
    Filed: September 28, 2017
    Date of Patent: April 21, 2020
    Assignee: Ecolab USA Inc.
    Inventors: Kousik Kundu, Susan Amy Garner
  • Patent number: 10584276
    Abstract: A CO2-sensitive fracturing and displacement fluid contains a surfactant, an auxiliary agent, water, and CO2, wherein CO2 is liquid and/or supercritical CO2. The CO2-sensitive fracturing and displacement fluid provided by the invention does not flow back after completion of fracturing construction, and the gel breaking fluid displacement is carried out after soak for a period of time to improve the tight oil recovery ratio. The CO2-sensitive fracturing and displacement fluid exerts the “one-agent multi-purpose” function of sand carrying, CO2 energization and oil displacement, surfactant imbibition and oil discharge of a fracturing-displacement system in different development and production stages, and achieves the dual goals of expanding the utilization degree of tight oil and improving the displacement efficiency of the tight oil, which can effectively reduce costs and achieve the goal of unified, highly efficient and green development of oil and gas fields.
    Type: Grant
    Filed: April 23, 2019
    Date of Patent: March 10, 2020
    Assignees: CHINA UNIVERSITY OF PETROLEUM (EAST CHINA), CHINA UNIVERSITY OF GEOSCIENCES (BEIJING), SCIENCE AND TECHNOLOGY RESEARCH INSTITUTE LTD., PETRO CHINA
    Inventors: Caili Dai, Mingwei Gao, Mingwei Zhao, Qing You, Guang Zhao, Yining Wu, Yongpeng Sun, Lin Li, Yifei Liu, He Liu, Xin Wang, Baoshan Guan
  • Patent number: 10550215
    Abstract: Copolymers having General Formula (I): in which R1 and R3 are chosen from divalent C4-C7 aliphatic groups and divalent C4-C7 heteroaliphatic groups, optionally substituted with one or more C1-C6 aliphatic groups, heteroatoms independently chosen from O, N, and S, or combination thereof, where the divalent C4-C7 heteroaliphatic groups of R1 and R3 include one or two heteroatoms independently chosen from O, N, and S, and the maximum number of heteroatoms in R1 or R3 is two, R2 is chosen from Q1 and Q2, x is a molar fraction range chosen from 0.1 to 0.9, y is a molar fraction range chosen from 0.1 to 0.9, and z is a molar fraction range chosen from 0 to 0.8, where the summation of x, y, and z equals 1. Methods for inhibiting formation of clathrate hydrates include contacting a fluid with at least one copolymer of General Formula (I).
    Type: Grant
    Filed: May 3, 2017
    Date of Patent: February 4, 2020
    Assignees: Saudi Arabian Oil Company, King Fahd University of Petroleum & Minerals
    Inventors: Mohamed Elanany, Abdullah Al-Malki, Manal Al-Eid, Mohammed Al-Daous, Shaikh Asrof Ali, Khalid Majnouni
  • Patent number: 10351757
    Abstract: The present invention relates to a method for removing organic deposits from oil and gas wells and other subsystem systems comprising cumene and biodiesel. The invention also relates to a method for removing organic deposits, including the steps for pumping said remover composition through a riser and/or through peripheral pipes of the umbilical and/or production pipe, leaving the composition in contact with the deposit for a sufficient time for removal of at least 50% of such.
    Type: Grant
    Filed: June 12, 2015
    Date of Patent: July 16, 2019
    Assignee: PETRÓLEO BRASILEIRO S.A.-PETROBRAS
    Inventors: Wendel Rodrigues Cezario, Rodrigo Pio Borges Menezes, Pedro Aledi Portugal, Rosana Serfaty De Campos, Guilherme dos Santos Vieira Lima, Plinio Martins Dias Da Silva
  • Patent number: 9845434
    Abstract: Biological source oils, including, but not limited to, algae oil, stabilize the presence of asphaltenes in petroleum feedstocks, such as crude oil, to help avoid or prevent fouling and/or corrosion in the production, transferring and processing of the petroleum feedstocks. Chemical additives such as phenol-based resins, and reaction products or combinations of long chain alpha-olefins and/or small chain aldehydes and/or long chain alkyl phenate sulfides and/or metal oxide-based colloidal hydrocarbon-based nanodispersions, may also stabilize the presence of asphaltenes in petroleum feedstocks. By “stabilizing” is meant keeping the asphaltenes in solution in the petroleum feedstocks.
    Type: Grant
    Filed: December 19, 2016
    Date of Patent: December 19, 2017
    Assignee: Baker Hughes, a GE company, LLC
    Inventors: Sai Reddy Pinappu, Lawrence N. Kremer, Corina L. Sandu
  • Patent number: 9670399
    Abstract: Acidizing fluids may be formulated to minimize the detrimental effects of precipitation during an acidizing operation by promoting production of precipitates from a subterranean formation. Methods for acidizing a subterranean formation can comprise: providing an acidizing fluid comprising a stabilized microemulsion carrier fluid, a chelating agent, and an acid source; introducing the acidizing fluid into a subterranean formation; at least partially dissolving a surface in the subterranean formation with the acidizing fluid, thereby forming a spent fluid; and producing the spent fluid from the subterranean formation.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: June 6, 2017
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Enrique A. Reyes, Alyssa L. Smith
  • Patent number: 9671972
    Abstract: A method for data storage includes storing data in a group of analog memory cells by writing respective input storage values to the memory cells in the group. After storing the data, respective output storage values are read from the analog memory cells in the group. Respective confidence levels of the output storage values are estimated, and the confidence levels are compressed. The output storage values and the compressed confidence levels are transferred from the memory cells over an interface to a memory controller.
    Type: Grant
    Filed: January 4, 2016
    Date of Patent: June 6, 2017
    Assignee: Apple Inc.
    Inventors: Uri Perlmutter, Dotan Sokolov, Ofir Shalvi, Oren Golov
  • Patent number: 9523054
    Abstract: Biological source oils, including, but not limited to, algae oil, stabilize the presence of asphaltenes in petroleum feedstocks, such as crude oil, to help avoid or prevent problematic issues caused by the asphaltenes, such as sludges, plugging, deposits, fouling and/or corrosion in the production, transferring and processing of the petroleum feedstocks. Chemical additives such as phenol-based resins, and reaction products or combinations of long chain alpha-olefins and/or small chain aldehydes and/or long chain alkyl phenate sulfides and/or metal oxide-based colloidal hydrocarbon-based nanodispersions, may also stabilize the presence of asphaltenes in petroleum feedstocks. By “stabilizing” is meant keeping the asphaltenes in solution in the petroleum feedstocks.
    Type: Grant
    Filed: August 20, 2014
    Date of Patent: December 20, 2016
    Assignee: Baker Hughes Incorporated
    Inventors: Sai Reddy Pinappu, Lawrence N. Kremer, Corina L. Sandu
  • Patent number: 9493598
    Abstract: Polymers are described that are polymerized from at least one reactive vinyl monomer having acid functionality or a salt thereof, and at least one reactive vinyl monomer having amide functionality. These polymers have a molecular weight from about 500 Da to about 15,000 Da; and may additionally comprise one or more solvent adducts. These polymers may be included in compositions that find use in oilfield applications, such as for inhibition and/or prevention of gas hydrates and/or corrosion.
    Type: Grant
    Filed: April 13, 2011
    Date of Patent: November 15, 2016
    Assignee: ISP INVESTMENTS LLC
    Inventors: Osama M. Musa, Cuiyue C. Lei
  • Patent number: 9452981
    Abstract: A pyroglutamic acid ester of formula (1) in which A represents a C2 to C4 alkylene group; x represents a number from 1 to 100; R? represents an aliphatic, cycloaliphatic or aromatic radical that contains at least one structural unit of formula 2, and; y represents a number from 1 to 100. The use of these pyroglutamic acid esters in quantities of 0.01 to 2% by weight for preventing the formation of gas hydrates in aqueous phases that are connected to a gaseous, liquid or solid organic phase.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: September 27, 2016
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Michael Feustel, Dirk Leinweber
  • Patent number: 9291051
    Abstract: The present invention relates to a method and system for identifying one or more characteristics within a subterranean reservoir of natural gas.
    Type: Grant
    Filed: October 20, 2011
    Date of Patent: March 22, 2016
    Assignee: ConocoPhillips Company
    Inventors: Keith C. Hester, James J. Howard
  • Patent number: 9260649
    Abstract: Disclosed are methods and systems for reducing the risk of oxidation of hydrate inhibitors such as monoethylene glycol used to prevent the formation of hydrates in fluid handling systems including flow lines and pipelines. A hydrate inhibitor storage tank in fluid communication with the fluid handling system is used to hold a volume of liquid hydrate inhibitor and a volume of high purity argon as a blanket gas.
    Type: Grant
    Filed: July 18, 2014
    Date of Patent: February 16, 2016
    Assignee: Chevron U.S.A. Inc.
    Inventor: Andrew Mark Titley
  • Patent number: 9228075
    Abstract: Disclosed herein is a composition for inhibiting a gas hydrate formation, the composition including an ionic liquid compound and polyvinylcaprolactam. The composition can reduce the formation rate of a gas hydrate under the same environment in small quantity, thus remarkably extending the induction time of a gas hydrate formation.
    Type: Grant
    Filed: May 3, 2012
    Date of Patent: January 5, 2016
    Assignee: Korea Institute of Energy Research
    Inventors: Seong-Pil Kang, Dongwook Lee, Howon Ra, Kisub Kim
  • Patent number: 9193671
    Abstract: A method of inhibiting gas hydrate formation in petroleum and natural gas production systems through the use of low dosage hydrate inhibitors which include reaction products of non-halide-containing inorganic acids, organic acids, and organic amines. The use of these non-halide-containing reaction products rather than chloride containing acids or alkylating agents avoids corrosion and stress cracking caused by residual inorganic chloride and other inorganic, halide-containing acids. The anti-agglomerate compositions can be administered continuously to effectively inhibit gas hydrate formation. In preferred embodiments, the anti-agglomerate compositions are mixtures of reaction products of non-halide-containing organic acids and organic amines.
    Type: Grant
    Filed: September 26, 2011
    Date of Patent: November 24, 2015
    Assignee: Multi-Chem Group, LLC
    Inventors: Danny Durham, Curtis Conkle, James Russum
  • Patent number: 9045676
    Abstract: This invention refers to the production and use of a petroleum asphaltene handler additive compound which when applied in heavy oil, causes asphaltenes to remain in suspension or dissolve, producing a viscosity reduction effect that prevents formation of precipitation of asphaltenic conglomerates in oil wells and storage tanks, as well as prevents pipelines from being obstructed. The molecular binding of the components of this new additive compound is such that the final liquid may be miscible in all types of oil. There are currently solubility models using different methods for handling asphaltenes; some of which use solvents which generate other problems to the physical and chemical stability of the oil, while others, as for example with the use of steam or heat, provide a temporary solution because the oil ultimately returns to the initial conditions thereof owing to the use of reversible processes.
    Type: Grant
    Filed: March 23, 2011
    Date of Patent: June 2, 2015
    Assignee: Geo Estratos, S.A. de C.V.
    Inventor: Vicente Gonzalez Davila
  • Publication number: 20150148266
    Abstract: The present invention generally relates to one or more compositions and methods for inhibiting the formation of gas hydrate agglomerates in a fluid. The fluid may be contained, for example, in an oil or gas pipeline or refinery.
    Type: Application
    Filed: November 26, 2013
    Publication date: May 28, 2015
    Applicant: Ecolab USA Inc.
    Inventors: Peter A. Webber, Sahana Nagappayya
  • Patent number: 9034804
    Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one friction reducing agent selected from the group consisting of guar gums, polyacrylamides, hydratable cellulosic materials, viscoelastic surfactants, and mixtures thereof. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for use in fracturing subterranean formations. Methods for inhibiting formation and/or precipitation of metal oxides in an aqueous composition using the fluid treatment systems or compositions also are provided.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: May 19, 2015
    Assignees: KROFF CHEMICAL COMPANY, NABORS COMPLETION & PRODUCTION SERVICES CO.
    Inventors: Paul Rey, Susan Rey, Michael John Seyman, Matthew E. Blauch
  • Patent number: 9034805
    Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one scale control agent. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for treating aqueous compositions found in subterranean formations. Methods for inhibiting formation and/or precipitation of calcium salts in an aqueous composition using the fluid treatment systems or compositions also are provided.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: May 19, 2015
    Assignees: KROFF CHEMICAL COMPANY, NABORS COMPLETION & PRODUCTION SERVICES CO.
    Inventors: Paul Rey, Susan Rey, Michael John Seyman, David Grottenthaler, Matthew E. Blauch
  • Publication number: 20150126413
    Abstract: A method for inhibiting the plugging of a conduit containing a flowable mixture comprising at least an amount of hydrocarbons capable of forming hydrates in the presence of water and an amount of water, which method comprises adding to the mixture an amount of a functionalized dendrimer effective to inhibit formation and/or accumulation of hydrates in the mixture at conduit temperatures and pressures; and flowing the mixture containing the functionalized dendrimer and any hydrates through the conduit wherein the functionalized dendrimer comprises two or more functional end groups selected from the group consisting of non-cyclic tertiary amine functional end groups, quaternary ammonium functional end groups, polyalkylene glycol functional end groups, quaternary ammonium zwitterionic end groups and phosphate or sulfate end groups.
    Type: Application
    Filed: December 17, 2012
    Publication date: May 7, 2015
    Inventor: Ulfert Cornelis Klomp
  • Publication number: 20150119299
    Abstract: A method of inhibiting hydrates in a fluid comprising water and gas comprising adding to the fluid an effective hydrate-inhibiting amount of a composition comprising one or more co-polymers of N-alkyl (alkyl)acrylamide monomers and one or more cationic monomers selected from acid and alkyl chloride quaternary salts of N,N-dialkylaminoalkyl (meth)acrylates and N,N-dialkylaminoalkyl (meth)acrylamides.
    Type: Application
    Filed: December 24, 2014
    Publication date: April 30, 2015
    Inventors: Peter G. Conrad, Erick J. Acosta, Kevin P. McNamee, Brian Bennett, Olga E.S. Lindeman, Joseph R. Carlise
  • Patent number: 9010430
    Abstract: Shaped particulates which have been compressed from a composite of a well treatment agent and adsorbent in a matrix may be introduced into horizontal or deviated oil or gas wells. The well treatment agent of the shaped pellets may be used to prevent and/or control the formation of deposits in a production well.
    Type: Grant
    Filed: July 19, 2010
    Date of Patent: April 21, 2015
    Assignee: Baker Hughes Incorporated
    Inventors: John Gregory Darby, D. V. Satyanarayana Gupta, Dong Shen
  • Patent number: 9012376
    Abstract: Methods of inhibiting corrosion of a metal surface in a well or pipeline are provided. The methods include the steps of: (a) forming a fluid of: (i) an aqueous acid solution; and (ii) inulin; and (b) introducing the fluid into the well or pipeline. The methods have wide application in various kinds of operations involved in the production or transportation of oil and gas, such as acid stimulation or remedial treatment in a pipeline.
    Type: Grant
    Filed: March 14, 2011
    Date of Patent: April 21, 2015
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Yogesh Kumar Choudhary, Anupom Sabhapondit, Deepak Ranganathan
  • Patent number: 9012377
    Abstract: Removing an asphaltene particle from a substrate includes contacting a silicate nanoparticle with a chemical group to form a functionalized silicate nanoparticle, the chemical group includes a first portion; and a second portion comprising an aromatic moiety, the first portion being bonded to the silicate nanoparticle; contacting the asphaltene particle with the functionalized silicate nanoparticle, the asphaltene particle being disposed on the substrate; interposing the functionalized silicate nanoparticle between the asphaltene particle and the substrate; and separating the asphaltene particle from the substrate with the functionalized silicate nanoparticle to remove the asphaltene particle. A composition includes a functionalized silicate nanoparticle comprising a reaction product of a silicate nanoparticle and an aromatic compound; and a fluid.
    Type: Grant
    Filed: December 31, 2012
    Date of Patent: April 21, 2015
    Assignee: Baker Hughes Incorporated
    Inventors: Valery Khabashesku, Oleg Mazyar, Soma Chakraborty, Gaurav Agrawal, Toby D. Hain
  • Patent number: 8980798
    Abstract: The precipitation of polymeric kinetic hydrate inhibitors (KHIs) in stored produced water is prevented or inhibited by incorporating a water immiscible solvent therein having a polarity index greater than about 3. The polymeric KHIs whose precipitation is inhibited or prevented include, but are not limited to, hyperbranched molecules, polyvinylcaprolactam, polyvinylpyrrolidone, and the like. Suitable water immiscible solvents include, but are not necessarily limited to, xylene, toluene, kerosene, mineral spirits, trimethylbenzene, cumene, heavy aromatic naphtha, ethylbenzene, polyethylbenzene, naphthalene, and mixtures thereof.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: March 17, 2015
    Assignee: Baker Hughes Incorporated
    Inventors: Jun Tian, Cheryl R. Bailey
  • Patent number: 8940667
    Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; (b) at least one friction reducing agent selected from the group consisting of guar gums, polyacrylamides, hydratable cellulosic materials, viscoelastic surfactants, and mixtures thereof; and (c) at least one scale control agent. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for treating aqueous compositions found in subterranean formations. Methods for inhibiting formation and/or precipitation of metal oxides in an aqueous composition using the fluid treatment systems or compositions also are provided.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: January 27, 2015
    Assignees: Kroff Chemical Company, Nabors Completion & Production Services Co.
    Inventors: Paul Rey, Susan Rey, Michael John Seyman, Matthew E. Blauch
  • Patent number: 8927467
    Abstract: Methods of preventing precipitation of calcium citrate and iron-based scale during acidizing treatments and related compositions are provided as embodiments of the present invention. The acidizing treatment fluid includes citric acid and tetra-salts of EDTA.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: January 6, 2015
    Assignee: Saudi Arabian Oil Company
    Inventor: Mohammed H. Al-Khaldi
  • Publication number: 20140367101
    Abstract: Treatment fluids suitable for use in subterranean operations may include a base fluid; a protected scale inhibitor; and at least one selected from the group consisting of (1) a metal crosslinker and a gelling agent, (2) an amine-based resin curing agent and an epoxy-based composition, and (3) any combination thereof, wherein the protected scale inhibitor is a scale inhibitor with at least one chelating group functionalized with a protecting group.
    Type: Application
    Filed: June 14, 2013
    Publication date: December 18, 2014
    Inventor: Thomas Donovan Welton
  • Publication number: 20140357532
    Abstract: A composition can be used for inhibiting the precipitation of asphaltene or paraffin or for dissolving asphaltene or paraffin. The composition includes: (A) one or more aliphatic compounds having 6 to 21 carbon atoms; (B) one or more alpha-olefins, wherein the alpha-olefins are acyclic and have 16 to 26 carbon atoms; and (C) camphor or a source of camphor. In addition, a method for removing at least some of an organic material in a portion of a wellbore, wellbore tubular, fracture system, matrix of a subterranean formation, or pipeline, the method comprising the steps of: (A) forming or providing such a composition; and (B) contacting the composition with the portion.
    Type: Application
    Filed: June 3, 2013
    Publication date: December 4, 2014
    Inventors: Anjali Ramesh Sarda, Prajakta Ratnakar Patil
  • Patent number: 8895478
    Abstract: The invention relates to novel polymers derived from: (A) at least one N-vinyl amide-based unit and/or at least one acrylamide-based unit, and (B) at least one unit comprising: (i) at least one hydroxyl group, and/or (ii) at least one functional group convertible to a hydroxyl group wherein at least one group is converted to hydroxyl functionality in the final polymer product, wherein the polymer comprises at least one ester group. The polymers and compositions are used in oilfield applications, such as an inhibitor of gas hydrates and/or a kinetic inhibitor of gas hydrates. The polymer can assume alternating, block, and/or random configurations of the repeating units, with at least one ester group.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: November 25, 2014
    Assignee: ISP Investments Inc.
    Inventors: Osama M. Musa, Cuiyue Lei
  • Patent number: 8887815
    Abstract: Inhibiting gas hydrate formation while transporting hydrocarbon fluids may include providing a kinetic gas hydrate inhibitor, adding the kinetic gas hydrate inhibitor to a fluid capable of producing gas hydrates, and transporting the fluid that comprises the kinetic gas hydrate inhibitor. Generally a kinetic gas hydrate inhibitor may include a heterocyclic compound comprising nitrogen, e.g., poly(vinyl pyrrolidone).
    Type: Grant
    Filed: January 5, 2012
    Date of Patent: November 18, 2014
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Alexandra Clare Morrison
  • Patent number: 8889598
    Abstract: The subject-matter of the present invention is multifunctional corrosion inhibitors for protecting from top of line corrosion and bottom line corrosion for pipes used in particular in the petroleum industry. The corrosion-inhibiting compositions comprise, as inhibitors, at least one amine with a boiling point of between 105 and 130° C.
    Type: Grant
    Filed: June 2, 2011
    Date of Patent: November 18, 2014
    Assignee: CECA S.A.
    Inventors: Jean-Phillippe Gillet, Frédéric Moser, Tong Eak Pou
  • Patent number: 8877689
    Abstract: Of the many compositions and methods provided herein, one example composition includes a treatment fluid comprising: an aqueous fluid; and a tar stabilizing polymer comprising at least one polymer selected from the group consisting of a styrene polymer, an acrylate polymer, a styrene-acrylate polymer, and any combination thereof.
    Type: Grant
    Filed: July 23, 2012
    Date of Patent: November 4, 2014
    Assignee: Haliburton Energy Services, Inc.
    Inventors: Philip Wayne Livanec, Greg Paul Perez
  • Publication number: 20140303044
    Abstract: The subject-matter of the present invention is multifunctional corrosion inhibitors for protecting from top of line corrosion and bottom line corrosion for pipes used in particular in the petroleum industry. The corrosion-inhibiting compositions comprise, as inhibitors, at least one amine with a boiling point of between 105 and 130° C.
    Type: Application
    Filed: June 2, 2011
    Publication date: October 9, 2014
    Inventors: Jean-Phillippe Gillet, Frédéric Moser, Tong Eak Pou
  • Publication number: 20140271757
    Abstract: Compositions having antimicrobial activity contain surface functionalized particles comprising an inorganic copper salt which has low water solubility. These types of inorganic salts may also be introduced in porous particles to yield antimicrobial compositions. The compositions may optionally comprise additional antimicrobial agents, salts with high water solubility, organic acids, salts of organic acids and their esters. The compositions may be added to various fluids used in the petroleum extraction industry, or used as coatings on components used in this industry. These antimicrobial materials may be used for reducing both anaerobic and aerobic bacteria and are also useful for reducing corrosion of ferrous components caused by anaerobic bacteria. Although such compositions may be used for any antimicrobial application, and some of the other important uses of these compositions are in wound care, personal care and waste processing.
    Type: Application
    Filed: November 25, 2013
    Publication date: September 18, 2014
    Applicant: AGIENIC, INC.,
    Inventors: Anoop Agrawal, Nicholas R. Krasnow, John P. Cronin, Lori L. Adams, Murat Akarsu, Ryan J. Reeser, Juan Carlos Lopez-Tonazzi, Donald R. Uhlmann
  • Publication number: 20140256599
    Abstract: The present invention relates to methods of inhibiting the formation or agglomeration of gas hydrates using amidines or guanidines. The invention further relates to compositions comprising amidines or guanidines that find use as gas hydrate inhibitors, as well as processes for preparing alkylated amidinium or guanidinium salts.
    Type: Application
    Filed: October 10, 2012
    Publication date: September 11, 2014
    Applicant: ECO INHIBITORS AS
    Inventor: Malcolm Andrew Kelland
  • Patent number: 8821754
    Abstract: The present invention relates to the use of a specific group of alkoxylated and/or acylated non-quaternary nitrogen-containing compounds as anti-agglomerants for gas hydrates. The invention also relates to a method for inhibiting the agglomeration of gas hydrates in a conduit, and compositions comprising the gas hydrate anti-agglomerant, a corrosion inhibitor and/or a paraffin deposition inhibitor.
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: September 2, 2014
    Assignee: Akzo Nobel N.V.
    Inventors: Martin Hellsten, Hans Oskarsson