Flooding The Formation Patents (Class 507/936)
  • Patent number: 11920084
    Abstract: Compositions and methods for chemical enhanced hydrocarbon recovery that utilize a nonionic surfactant that is a mixture of isomerized C9-11 ethoxylated alcohols.
    Type: Grant
    Filed: August 30, 2022
    Date of Patent: March 5, 2024
    Assignee: Pioneer Natural Resources USA, Inc.
    Inventors: Dustin L. Walker, Joshua W. Brownlow, Kyle D. Scott
  • Patent number: 11708751
    Abstract: Provided are methods of recovering oil from a reservoir using carbon dioxide foam flooding in which a carbon dioxide foam of increased strength is used.
    Type: Grant
    Filed: August 13, 2021
    Date of Patent: July 25, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Kenneth Richard Kibodeaux, Huseyin Onur Balan, Anuj Gupta
  • Patent number: 8997862
    Abstract: A method includes introducing a treatment fluid including a first polymer gel into a subterranean formation to generate a production fluid having an aqueous portion and a hydrocarbon portion, treating the aqueous portion of the production fluid with chlorine dioxide to separate additional hydrocarbons from the aqueous portion, and adjusting the viscosity of the treated aqueous portion prior to introducing the treated aqueous portion back into the subterranean formation.
    Type: Grant
    Filed: June 27, 2014
    Date of Patent: April 7, 2015
    Assignee: Sabre Intellectual Property Holdings LLC
    Inventor: John Mason
  • Patent number: 8991500
    Abstract: A method includes introducing a treatment fluid into a wellbore penetrating a subterranean formation, the treatment fluid including a polymer gel having a water-soluble polymer, a proppant, and a polymer gel-preserving amount of chlorine dioxide, the placing step includes applying the treatment fluid at a sufficient pressure and at a sufficient rate to fracture the subterranean formation.
    Type: Grant
    Filed: September 19, 2013
    Date of Patent: March 31, 2015
    Assignee: Sabre Intellectual Property Holdings LLC
    Inventor: John Mason
  • Patent number: 8969262
    Abstract: The present invention includes the use of anhydride compositions, including alkyl and aryl anhydrides, for use as a demulsifier in resolving emulsions of water and oil. In particular, the anhydride composition can be used alone or in a blend with other demulsifiers. Suitable anhydrides suitable for the present invention include acetic and propionic, with acetic anhydride being preferred. The anhydride composition can be added directly to crude oil or other compositions to be resolved. As such, the demulsifier composition includes an anhydride, such as acetic anhydride, alone or in combination with other demulsifiers. The anhydride can be used in an amount ranging between trace and 100% by weight of the demulsifier composition.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: March 3, 2015
    Assignee: Nalco Company
    Inventors: Duncan E. Williams, Richard Mgla
  • Patent number: 8887804
    Abstract: The present invention relates to a method for the assisted recovery of crude oil from an underground formation, comprising: a) injecting, via at least one injection means in contact with the underground formation containing the crude oil, a liquid containing a mixture of at least: i) a salty aqueous medium, ii) a mixture of two zwitterionic viscosising surfactants or a mixture of two populations of said surfactants having a bimodal characteristic of the narrow distribution of Ri groups as defined below, in a weight content of between 1 and 0.05 wt %, preferably between 0.5 and 0.1 wt %, and more preferably between 0.4 and 0.15 wt %, such that the liquid has an oil/water interface tension of about 10 mN/m (milinewton per meter) or less as measured at room temperature (25° C.) and a viscosity of about 3 cPs or more as measured at a temperature of 80° C.
    Type: Grant
    Filed: February 10, 2010
    Date of Patent: November 18, 2014
    Assignee: Rhodia Operations
    Inventors: Guillaume Degre, Mikel Morvan
  • Patent number: 8789592
    Abstract: A method includes introducing a treatment fluid including a first polymer gel into a subterranean formation to generate a production fluid having an aqueous portion and a hydrocarbon portion, treating the aqueous portion of the production fluid with chlorine dioxide to separate additional hydrocarbons from the aqueous portion, and adjusting the viscosity of the treated aqueous portion prior to introducing the treated aqueous portion back into the subterranean formation.
    Type: Grant
    Filed: September 19, 2013
    Date of Patent: July 29, 2014
    Assignee: Sabre Intellectual Property Holdings LLC
    Inventor: John Mason
  • Patent number: 8709982
    Abstract: The invention relates to the use of quaternary polyamines having formula (I) for the recovery of oil from reservoirs formula (I), wherein n>=1 R1 represents H, CH3, CH2CH3, CnH2n+1 R2 represents H2CHOHCH2, CH2, CH2CH?CH2 R3 represents CH3, CH2CH3, CnH2n+1 R4 represents CH2, CH2CH?CH2 when R2 and R4 are allyl group, they can jointly form aliphatic cyclic structures, the ratio between the carbon atoms and nitrogen atoms (C/N) ranges from 2 to 30.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: April 29, 2014
    Assignee: ENI S.p.A.
    Inventors: Lucilla Del Gaudio, Thomas Paul Lockhart, Emanuele Vignati
  • Patent number: 8691732
    Abstract: A water-based fluid, containing: a non-ionic surfactant, which is stable in a temperature range from 10 to 90° C. and soluble in water; and a salt, wherein the non-ionic surfactant contains an alkyl polyglucoside selected from the group consisting of a C8 alkyl polyglucoside, a C10 alkyl polyglucoside, and mixtures thereof, and the salt is present, and is present in an amount up to 60%. In addition, a process for preventing the formation of a W/O inverse emulsion or resolving a W/O inverse emulsion that has already formed in an oil well in which an oil-based mud has been employed by injecting the water-based fluid into the oil well.
    Type: Grant
    Filed: June 9, 2008
    Date of Patent: April 8, 2014
    Assignee: ENI S.p.A.
    Inventors: Lucilla Del Gaudio, Paola Albonico, Sandra Cobianco, Chiara Neva Emiliani, Giuseppe Ripa
  • Patent number: 8584750
    Abstract: A process for mineral oil production, especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one nonionic surfactant having 8 to 30 ethoxy units, which has a polydispersity of from 1.01 to 1.12, and at least one further surfactant is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: November 19, 2013
    Assignee: BASF SE
    Inventors: Christian Bittner, Oetter Günter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel
  • Patent number: 8584751
    Abstract: A process for mineral oil production especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one nonionic surfactant having 11 to 40 ethoxy units and a hydrophobic radical having 8 to 32 carbon atoms and at least one further surfactant differing therefrom is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: November 19, 2013
    Assignee: BASF SE
    Inventors: Christian Bittner, Günter Oetter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel
  • Patent number: 8573299
    Abstract: A method for enhancing oil recovery is disclosed. The method includes providing a subsurface reservoir containing hydrocarbons therewithin and a wellbore in fluid communication with the subsurface reservoir. A solution for injection into the reservoir is formed by mixing a composition with at least one non-ionic chemical, at least one polymer, and at least one alkali. The non-ionic chemical can be alcohol alkoxylates such as alkylaryl alkoxy alcohols or alkyl alkoxy alcohols. The solution is solution is clear and aqueous stable when mixed. The solution is injected through the wellbore into the subsurface reservoir.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: November 5, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Varadarajan Dwarakanath, Taimur Malik, Adam Christopher Jackson, Ping Zhao, Oya A. Karazincir, Sophany Thach
  • Patent number: 8524643
    Abstract: Use of a mixture comprising a surfactant and a cosurfactant in the form of an aqueous solution for flooding underground deposits of hydrocarbons for mobilizing and recovering the hydrocarbons from the underground deposits, the cosurfactant being a substance or a group of substances selected from the following list: an amphiphilic comb polymer having a backbone with two or more side chains attached to the backbone, the side chains differing from one another and/or the side chains differing from the backbone in their amphiphilic character, an amphiphilic polymer having one or more hydrophobic subunits [A2] based on a polyisobutene block, at least 50 mol % of whose polyisobutene macromolecules have terminally arranged double bonds, and one or more hydrophilic subunits [B2], or an amphiphilic polymer having the general structural formula
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: September 3, 2013
    Assignee: BASF SE
    Inventors: Juergen Huff, Guenter Oetter, Angelika Kuehnle, Susanne Petrovic, Marcus Guzmann, Ingo Muenster, Gregor Brodt
  • Patent number: 8465668
    Abstract: Surfactants with polyether sulfonate structure, which have a propanonylsulfonic acid group as a head group, a process for preparing such surfactants and their use for tertiary mineral oil extraction.
    Type: Grant
    Filed: October 15, 2008
    Date of Patent: June 18, 2013
    Assignee: BASF SE
    Inventors: Christian Bittner, Oetter Günter, Ulrich Steinbrenner, Jürgen Huff, Marcus Guzmann
  • Patent number: 8256511
    Abstract: A process is disclosed for using heavy petroleum fraction as a drive fluid in the recovery of hydrocarbons from a subterranean formation. The hydrocarbons may be in the form of bitumen or heavy oil. The heavy petroleum fraction may be injected into at least one injection well and hydrocarbons produced out of at least one distinct production well. The heavy petroleum fraction may be co-injected together with steam and/or hot water and/or solvent. The heavy petroleum fraction may be a heavy fraction of a process used to upgrade crude oil, such as a heavy asphaltene fraction produced from solvent deasphalting crude oil produced by this recovery process.
    Type: Grant
    Filed: June 18, 2008
    Date of Patent: September 4, 2012
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Thomas J. Boone, Mori Y. Kwan, J. Pierre Lebel, Brad C. Harker
  • Patent number: 8240380
    Abstract: Compositions having shear-gelling and shear-thickening properties are based on an amphiphilic polymer combined with hydrophilic particles and polyethyleneoxide. The hydrophilic particles preferably consist of a hydrous sodium lithium magnesium silicate. The amphiphilic polymer may be a synthetic polymer, a hydrophobically modified biopolymer, or both. The compositions may be employed in enhanced oil recovery operations.
    Type: Grant
    Filed: September 13, 2007
    Date of Patent: August 14, 2012
    Assignee: Schlumberger Technology Corporation
    Inventors: Jean-Philippe Caritey, Mélanie Cady
  • Patent number: 8076272
    Abstract: A process for preparing an alkylaryl sulfonate comprising (a) reacting at least one meta-xylene compound with olefin or a mixture of olefins having from about 10 to about 20 carbon atoms, in the presence of an acid catalyst, wherein the resulting product comprises no more than 40 weight percent of 1-alkyl-2,4 dimethylsubstituted aromatic compound and at least about 60 weight percent of 1-alkyl-3,5 dimethyl substituted aromatic compound; (b) sulfonating the product of (a); and (c) neutralizing the product of (b) with a source of alkali or alkaline earth metal or ammonia.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: December 13, 2011
    Assignee: Chevron Oronite Company LLC
    Inventors: Andrew J. Howes, Curtis Bay Campbell, Sophany Thach
  • Patent number: 8053396
    Abstract: Use of a mixture comprising a surfactant and a cosurfactant in the form of an aqueous solution for flooding underground deposits of hydrocarbons for mobilizing and recovering the hydrocarbons from the underground deposits, the cosurfactant being a substance or a group of substances selected from the following list: an amphiphilic comb polymer having a backbone with two or more side chains attached to the backbone, the side chains differing from one another and/or the side chains differing from the backbone in their amphiphilic character, an amphiphilic polymer having one or more hydrophobic subunits [A2] based on a polyisobutene block, at least 50 mol % of whose polyisobutene macromolecules have terminally arranged double bonds, and one or more hydrophilic subunits [B2], or an amphiphilic polymer having the general structural formula
    Type: Grant
    Filed: June 8, 2006
    Date of Patent: November 8, 2011
    Assignee: BASF SE
    Inventors: Jürgen Huff, Günter Oetter, Angelika Kühnle, Susanne Petrovic, Marcus Guzmann, Ingo Münster, Gregor Brodt
  • Patent number: 7987907
    Abstract: Method for increasing the recovery of crude oil from a reservoir containing at least one porous and permeable subterranean formation wherein the formation includes sandstone rock and at least one mineral that has a negative zeta potential under the reservoir conditions and wherein crude oil and connate water are present within the pores of the formation. The method is carried out by (A) injecting into the formation a slug of an aqueous displacement fluid that displaces crude oil from the surface of the pores of the formation wherein the pore volume (PV) of the slug of the aqueous displacement fluid is at least 0.
    Type: Grant
    Filed: September 5, 2007
    Date of Patent: August 2, 2011
    Assignees: BP Exploration Operating Company Limited, BP Corporation North America Inc.
    Inventors: Ian Ralph Collins, Gary Russell Jerauld
  • Patent number: 7798219
    Abstract: Process and a method for enhancing recovery of petroleum from an underground source including injecting into the source, a petroleum displacement agent including fluids and modified liposomes. The liposomes and fluids merge the discrete oil droplets after waterflood into a continuous layer of oil (oil phase) eliminating b-pass of water through oil and employ mobility control through transition of gel phase to liquid crystalline phase.
    Type: Grant
    Filed: March 25, 2009
    Date of Patent: September 21, 2010
    Inventor: Gideon N. Harnoy
  • Patent number: 7691790
    Abstract: The present invention includes a cost effective custom-designed blend of organic chemicals to stimulate oil production. The invention includes a chemical composition for use in drilling operations for oil recovery and the method of using the chemical composition. The chemical composition includes an ammonia compound, an alcohol, and aqueous carrier solution. The aqueous carrier solution is of sufficient volume such that it is operable to fully dissolve the ammonia compound and alcohol in the aqueous carrier solution.
    Type: Grant
    Filed: October 16, 2008
    Date of Patent: April 6, 2010
    Assignee: Coriba Technologies, L.L.C.
    Inventor: Harvey G. Cobb
  • Patent number: 7373977
    Abstract: A process for recovering oil by injecting into a subterranean oil-bearing reservoir through one or more injection wells, an aqueous solution containing one or more amphoteric alkyl amido betaine surfactants that form a viscoelastic gel reducing interfacial tension and increasing the viscosity of the injection fluid simultaneously, displacing the solution into the reservoir, and recovering the oil from one or more production wells. These viscoelastic gels are tolerant to electrolytes and multivalent cations. They are shear reversible and adsorbed little onto the reservoir. Their viscosity is reduced when contacting certain hydrocarbons but remains high when contacting water or brine. This allows the fluid to preferentially penetrate the oil-bearing portions of the formation and resulting additional oil recovery.
    Type: Grant
    Filed: March 16, 2005
    Date of Patent: May 20, 2008
    Assignee: Oil Chem Technologies
    Inventors: Paul Daniel Berger, Christie Huimin Berger
  • Publication number: 20080011475
    Abstract: An oil recovery method employing amphoteric surfactants with the steps of: a) Injecting into one or more injection wells an aqueous solution containing a mixture of amphoteric surfactants containing mixture of amphoteric surfactants having a hydrocarbyl chain length between 8 and 26 and certain degree of unsaturation, and b) recovering the oil from one or more producing wells. The aqueous injection fluid may also contain one or more of the following: a thickening agent, an alkali, a co-solvent.
    Type: Application
    Filed: July 14, 2007
    Publication date: January 17, 2008
    Inventors: Paul Daniel Berger, Christie Huimin Berger
  • Publication number: 20040011526
    Abstract: A method of recovering oil or contaminants from subterranean reservoirs using a surfactant system where an adsorption reducing agent is injected before, after, and/or with the surfactant system. The adsorption reducing agent is formed by the reaction of an olefin sulfonic acid and phenol/aldehyde resin, the structure which is shown below where M may be Hydrogen or any cation, R is hydrogen, alkyl, alkenyl, etc., X is methylene or other aldehyde derived bridge, Y is hydrogen, ethylene oxide, propylene oxide, butylene oxide or mixtures of two or more of these, x+y is greater than 2 and n is equal or greater than 1.
    Type: Application
    Filed: July 22, 2002
    Publication date: January 22, 2004
    Inventors: Paul D. Berger, Christie H. Berger
  • Patent number: 6043391
    Abstract: New anionic surfactants and methods of preparation which are derived from aromatic or substituted aromatic molecules and alkenesulfonic acid. Wherein the aryl compound is alkylated and sulfonated in one-step with an alkene sulfonic acid prior to sulfonic acid neutralization. The methods allow the functional sulfonate group to be attached to the end of the alkyl chain rather than to the aromatic ring thus allowing for selective substituted groups, either branched, linear or alkoxylated or combinations thereof to be placed on the aryl compound prior to sulfonation and alkylation.
    Type: Grant
    Filed: January 20, 1998
    Date of Patent: March 28, 2000
    Inventors: Paul D. Berger, Christie H. Berger, Iris K. Hsu
  • Patent number: 6022834
    Abstract: An improved concentrated surfactant formulation and process for the recovery of residual oil from subterranean petroleum reservoirs, and more particularly an improved alkali surfactant flooding process which results in ultra-low interfacial tensions between the injected material and the residual oil, wherein the concentrated surfactant formulation is supplied at a concentration above, at, or, below its CMC, also providing in situ formation of surface active material formed from the reaction of naturally occurring organic acidic components with the injected alkali material which serves to increase the efficiency of oil recovery.
    Type: Grant
    Filed: April 4, 1997
    Date of Patent: February 8, 2000
    Assignee: Oil Chem Technologies, Inc.
    Inventors: Oliver YeSung Hsu, Nelson SungNan Hsu
  • Patent number: 5911276
    Abstract: A method for the enhanced recovery of oil comprises injecting into an oil-containing formation an aqueous surfactant system having at least (1) a blend containing an unmodified Kraft lignin, an oil-soluble amine and a water-soluble sulfonate, and (2) water; driving the surfactant system through the formation and producing the oil mobilized by the surfactant system. A surfactant composition useful for enhanced oil recovery methods is also provided having at least an unmodified Kraft lignin, an oil-soluble amine and a water-soluble sulfonate.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: June 15, 1999
    Assignee: Texaco Inc
    Inventor: Dan Edward Kieke
  • Patent number: 5780395
    Abstract: A foam is provided having utility for improving sweep efficiency in subterranean oil-bearing formations and having specific utility for conformance improvement treatments and mobility control in such formations. The foam is a gel medium having a gas dispersed therein. The gel medium is made up of a crosslinkable polymer, a crosslinking agent, a surfactant and a liquid solvent.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: July 14, 1998
    Assignee: Marathon Oil Company
    Inventor: Robert D. Sydansk
  • Patent number: 5725771
    Abstract: Process for the treatment of drilling muds recovered at the surface of the ground, especially synthetic muds, characterized in that it comprises at least one stage of hydrolysis of said mud by means of a lipase.
    Type: Grant
    Filed: April 15, 1996
    Date of Patent: March 10, 1998
    Assignee: Elf Aquitaine Production
    Inventors: Sophie Aliphat, Frederic Perie, Christian Zurdo, Alain Martignon
  • Patent number: 5478802
    Abstract: A gelling composition and a process for wellbore treatment comprising injecting the composition into reservoirs are disclosed wherein the composition comprise a produced brine; a water-soluble polymer such as, for example, polyacrylamide; a crosslinker such as, for example, a complexed zirconium compound; and optionally a complexing ligand such as, for example, lactic acid.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: December 26, 1995
    Assignee: Phillips Petroleum Company
    Inventor: Ahmad Moradi-Araghi
  • Patent number: 5401425
    Abstract: A method for recovering surfactants from produced fluids by mixing with produced fluids about 0.1% to about 5% of a nonionic surfactant having a phase inversion temperature above the temperature of the produced fluids, heating the mixture above the phase inversion temperature, mixing the phase containing oil and the surfactants with water, and cooling the mixture below the phase inversion temperature to extract the surfactants into an aqueous phase, provided that if a sufficient concentration of the nonionic surfactant is already in the produced fluids, it need not be added.
    Type: Grant
    Filed: May 16, 1994
    Date of Patent: March 28, 1995
    Assignee: Texaco Inc.
    Inventor: Gabriel Prukop