Corrosion Inhibitor Patents (Class 507/939)
  • Patent number: 11649393
    Abstract: Compositions inhibit corrosion in various commercial settings, such as in a refinery and/or in an oil and gas application. The compositions include at least one fatty acid and at least two amphipathic molecules selected from the group consisting of dodecenyl succinic acid, dimer fatty acid and benzalkonium chloride.
    Type: Grant
    Filed: March 22, 2022
    Date of Patent: May 16, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Muthukumar Nagu, Nayef M. Alanazi, Jothibasu Ramasamy, Md Amanullah
  • Patent number: 11345867
    Abstract: Corrosion inhibitor compositions and methods for inhibiting corrosion on a metal surface exposed to a hydrocarbon fluid are provided. The corrosion inhibition compositions can include a corrosion inhibitor, such as 3-dimethylamino benzoic acid, 4-dimethylamino benzoic acid, or 2,5-dihydroxyterephthalic acid. The corrosion inhibitor composition can further comprise dimethyl sulfoxide, and heavy aromatic naphtha. The corrosion inhibitor composition can be phosphate-free and can inhibit naphthenic acid corrosion. In the methods, a corrosion inhibitor composition is added to the hydrocarbon fluid exposed to the metal surface to prevent or inhibit corrosion on the metal surface, including naphthenic acid corrosion.
    Type: Grant
    Filed: June 25, 2021
    Date of Patent: May 31, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Muthukumar Nagu, Nayef M. Alanazi
  • Patent number: 8969263
    Abstract: A treatment fluid comprises: water; a carboxylate; and a corrosion inhibitor, wherein the corrosion inhibitor is a polymer, wherein the polymer comprises silicone, an ether monomer residue, and an amine functional group; wherein a test fluid consisting essentially of the water, the carboxylate, and the corrosion inhibitor, and in the same proportions as in the treatment fluid, is capable of providing a corrosion weight loss to a metal plate of less than 0.05 pounds per square feet (lb/ft2) under testing conditions of 200° F. (93.3° C.), a pressure of 500 psi (3.4 MPa), and a time of 24 hours whereas a substantially identical test fluid without the corrosion inhibitor provides a corrosion weight loss of greater than 0.05 lb/ft2 under the testing conditions. A method of treating a portion of a well comprises: forming the treatment fluid; and introducing the treatment fluid into the well.
    Type: Grant
    Filed: September 21, 2012
    Date of Patent: March 3, 2015
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Garima Misra, Arunesh Kumar
  • Patent number: 8933000
    Abstract: An oil well being subjected to an acid stimulation may be treated with a corrosion inhibitor including an Ammonium Iodide Ion Source, a first carbonyl containing compound having a general formula: and a second carbonyl containing compound having the general formula: wherein R1 is an alkyl or aromatic group, R2 is a hydrogen, alkyl or aromatic group, and R3 is a hydrogen or an alkyl group having from 1 to 6 carbons; and wherein the alkyl or aromatic groups of R1, R2, or R3 may further comprise a nitrogen, phosphorous, halogen or second oxygen moiety; and wherein the oil well being treated has zone being treated at a temperature of from about 90 to about 500° F.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: January 13, 2015
    Assignee: Baker Hughes Incorporated
    Inventor: Michael L. Walker
  • Patent number: 8865309
    Abstract: The present invention includes compositions and methods of supplying a corrosion inhibitor including placing a corrosion inhibitor attached to a nanostructure carrier, placing the nanostructure carrier containing the corrosion inhibitor at a location and the nanostructure carrier is capable of releasing the corrosion inhibitor.
    Type: Grant
    Filed: January 28, 2013
    Date of Patent: October 21, 2014
    Assignee: National Oilwell Varco, L.P.
    Inventors: Deepthi R. Setlur, Stefan M. Butuc
  • Patent number: 8585930
    Abstract: A quaternary nitrogen-containing corrosion inhibitor of formula wherein is an aromatic, nitrogen-containing ring of 5 to 14 ring atoms, optionally containing an additional N, O or S ring atom and optionally substituted with one or more alkyl, alkenyl, aryl, arylalkyl, cycloalkyl, amino, aminoalkyl, alkoxy, hydroxylalkyl, or cyano groups, or a mixture thereof; Y is a group of formula —OC(O)R1 or —C(O)R1; L is C1-C10 alkyl, C2-C10 alkenyl or a group of formula —CH2CH(OR2)CH2—; R1 is C8-C20 alkyl or C8-C20 alkenyl; R2 is H or —C(O)R1; R3 and R4 are independently selected from H, alkyl, alkenyl, amino, alkoxy, hydroxylalkyl and cyano; and X is Br, Cl or I is particularly useful for inhibiting corrosion in oil and gas field applications.
    Type: Grant
    Filed: September 15, 2010
    Date of Patent: November 19, 2013
    Assignee: Nalco Company
    Inventor: Laxmikant Tiwari
  • Patent number: 8580154
    Abstract: Disclosed are quaternary ammonium salts containing non-halogen anions such as carbonates, bicarbonates, phosphates, glycolates and mixtures thereof as conversion coatings or additives imparting anti-corrosive properties to paints. The invention relates to a method for inhibiting the corrosion of metal surfaces by applying a composition containing one or more quaternary ammonium carbonate or bicarbonate. The disclosure is also directed to anti-corrosive coatings for metal substrates containing these compounds and to metal substrates having these anticorrosive coatings.
    Type: Grant
    Filed: December 24, 2012
    Date of Patent: November 12, 2013
    Assignee: Lonza, Inc.
    Inventors: Thomas C. Bedard, Thomas David Burleigh, Larry K. Hall, Joseph Kimler, Joseph W. Scheblein, Michael Y. Chiang
  • Patent number: 8383559
    Abstract: The present invention includes compositions and methods of supplying a corrosion inhibitor including placing a corrosion inhibitor attached to a nanostructure carrier, placing the nanostructure carrier containing the corrosion inhibitor at a location and the nanostructure carrier is capable of releasing the corrosion inhibitor.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: February 26, 2013
    Assignee: National Oilwell Varco, L.P.
    Inventors: Deepthi R. Setlur, Stefan M. Butuc
  • Patent number: 8349215
    Abstract: The invention relates to the use of salts of compound of the formula (1) and amines of the formula (2), where R1 means C8- to C30-Alkyl or C8- to C30-Alkenyl, R2 means hydrogen or a group of the formula -(A-O)x—H, R3, R4 mean hydrogen, C1- to C4-Alkyl or a group of the formula -(A-O)x—H, A means C2- to C4-Alkylene, and x means a number from 1 to 10, as water-soluble or water-dispersible corrosion inhibitors.
    Type: Grant
    Filed: December 10, 2008
    Date of Patent: January 8, 2013
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Dirk Leinweber, Alexander Roesch, Michael Feustel
  • Patent number: 8337640
    Abstract: Disclosed are quaternary ammonium salts containing non-halogen anions such as carbonates, bicarbonates, phosphates, glycolates and mixtures thereof as conversion coatings or additives imparting anti-corrosive properties to paints. The invention relates to a method for inhibiting the corrosion of metal surfaces by applying a composition containing one or more quaternary ammonium carbonate or bicarbonate. The disclosure is also directed to anti-corrosive coatings for metal substrates containing these compounds and to metal substrates having these anticorrosive coatings.
    Type: Grant
    Filed: November 23, 2010
    Date of Patent: December 25, 2012
    Assignee: Lonza, Inc.
    Inventors: Thomas C. Bedard, Thomas David Burleigh, Larry K. Hall, Joseph Kimler, Joseph W. Scheblein, Michael Y. Chiang
  • Patent number: 8246857
    Abstract: The present invention relates to a chemical composition comprising (a) a glycoside component A comprising at least one glycoside of the formula R(OG)x wherein R is an aliphatic hydrocarbon radical having 1 to 25 carbon atoms or is a radical of formula R1(OR2)m which does not have more than 25 carbon atoms and wherein n=0 to 24 and R1 and R2 are aliphatic hydrocarbon radicals; G is the residue of a saccharide moiety selected from the group consisting of fructose, glucose, mannose, galactose, talose, gulose, allose, altrose, idose, arabinose, xylose, lyxose, ribose and alkoxylated derivatives thereof; and x is 1 to 30; (b) an aspartate component B comprising at least one polymerisation product of aspartic acid, optionally in form of a copolymerisate with fatty acids, polybasic carboxylic acids, anhydrides of polybasic carboxylic acids, polybasic hydroxycarboxylic acids, monobasic polyhydroxycarboxylic acids, alkoxylated alcohols, alkoxylated amines, amino sugars, carbohydrates, sugar carboxylic acids and polyme
    Type: Grant
    Filed: November 29, 2006
    Date of Patent: August 21, 2012
    Assignee: BASF Aktiengesellschaft
    Inventors: Marcus Guzmann, Uwe Ossmer, Henry Craddock
  • Patent number: 8158561
    Abstract: The present invention relates to a method for inhibiting scale and corrosion in aqueous systems, for example, under high temperature and pressure conditions such as temperatures up to 250° C. and/or pressures up to 10000 psi (i.e., about 68.9 MPa). The method involves providing polymer compositions comprising 1% to 100% by weight of a phosphorus-containing amide monomer to such aqueous systems, which arise, for example, in connection with oilfield operations and some water treatment applications.
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: April 17, 2012
    Assignee: Rohm and Haas Company
    Inventors: Eric Greyson, Joseph Manna, Somil Chandrakant Mehta
  • Patent number: 8058211
    Abstract: Of the many methods and compositions provided herein, one method includes a method comprising contacting a metal surface with an acidic fluid comprising an aqueous base-fluid, an acid, a corrosion inhibitor, and a corrosion inhibitor intensifier composition comprising a compound that corresponds to a formula R1R2XCCOOH, wherein X is a halogen, R1 comprises at least one group selected from the group consisting of a C1-C20 alkyl group, a C3-C20 cycloalkyl group, a C1-C20 oxyalkyl, and a C6-C20 aryl group, and R2 comprises at least one group selected from the group consisting of a C1-C20 alkyl group, a C3-C20 cycloalkyl group, a C1-C20 oxyalkyl, and a C6-C20 aryl group.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: November 15, 2011
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Juanita M. Cassidy, Chad E. Kiser, J. Michael Wilson
  • Patent number: 7951754
    Abstract: Environmentally friendly compounds for corrosion inhibition and hydrocarbonaceous deposit removal and methods using such compounds are disclosed and claimed. The compounds are derivatives of heterocyclic bis-quaternary molecules having an amido moiety and are applicable to a variety of oil and gas operations.
    Type: Grant
    Filed: December 7, 2007
    Date of Patent: May 31, 2011
    Assignee: Nalco Company
    Inventors: Laxmikant Tiwari, G. Richard Meyer, David Horsup
  • Patent number: 7915205
    Abstract: An acidizing formulation for use in the stimulation of hydrocarbon production is stable when packaged and stored as a single fluid for periods exceeding one year. The formulation contains a miscibility solvent which substantially prevents any phase separation between the constituents and lack of dispersion of the additives in the fluid.
    Type: Grant
    Filed: June 9, 2006
    Date of Patent: March 29, 2011
    Assignee: Weatherford Engineered Chemistry Canada Ltd.
    Inventors: Clayton Smith, Darin Oswald, Dan Skibinski, Nicole Sylvestre
  • Patent number: 7833948
    Abstract: A composition and a method for treating a subterranean formation with an injection liquid containing liquid carbon dioxide, a treating liquid and optionally a foaming agent and/or methanol. The treating liquid may be an acid, a corrosion inhibitor, a solvent or a scale inhibitor.
    Type: Grant
    Filed: May 1, 2007
    Date of Patent: November 16, 2010
    Assignee: Team CO2, Inc
    Inventors: Randal L. Decker, Michael D. Hyman, John J. Ridge
  • Patent number: 7807609
    Abstract: The invention provides a method for the treatment of a hydrocarbon well which method comprises administering, down said well, polymeric particles having covalently bound to a polymeric component thereof a well treatment chemical or a precursor thereof, wherein the particles contain covalent bonds scissile in an aqueous environment to release or expose said chemical or precursor.
    Type: Grant
    Filed: November 21, 2008
    Date of Patent: October 5, 2010
    Assignee: Statoil ASA
    Inventors: Hans Kristian Kotlar, Olav Martin Selle, Oddvar Arnfinn Aune, Lars Kilaas, Anne Dalager Dyrli
  • Patent number: 7624805
    Abstract: Corrosive effects arising during oilfield treatment applications are inhibited and/or prevented by introducing into an oil or gas well at least one compound of formula I: wherein: R1 is independently H, —[—CnH2nO—]a—H, or an alkyl group having from 1 to about 24 carbon atoms; R2 is independently H or —[—CnH2nO—]b—H, R3 is independently —[—CH2]c—, or —CdH2d—[—OCnH2n—]e—, R4 is independently H or —[—CnH2nO—]f—H, R5 is independently H or —[—CnH2nO—]g—H, a is from about 1 to about 8; b+f+g is between 0 to about 30; c is from about 1 to 6; d is from about 1 to 6; e is from about 1 to about 8; and n is 2 or 3. Such corrosive effects are especially inhibited in the treatment of sour wells where H2S corrosion is a potential problem as well as conduits used during the treatment of subterranean formations.
    Type: Grant
    Filed: December 29, 2008
    Date of Patent: December 1, 2009
    Assignee: BJ Services Company
    Inventors: Ronald L. Hoppe, Richard L. Martin, Marek K. Pakulski, Thane D. Schaffer
  • Patent number: 7615102
    Abstract: The invention relates to the use of compounds of formula (1) as corrosion and gas hydrate inhibitors. In said formula: R1 and R2 independently of one another represent C1 to C22 alkyl, C2 to C22 alkenyl, C6 to C30 aryl or C7 to C30 alkyl aryl; R3 represents M, hydrogen or an organic group with between 1 and 100 carbon atoms that optionally contains heteroatoms; A represents a C2 to C4 alkene group; B represents an optionally substituted C1 to C10 alkene group; D represents an ethylene group that is substituted with an organic group comprising between 1 and 600 carbon atoms; X and Y independently of one another represent O or NR4; R4 represents hydrogen, C1 to C22 alkyl, C2 to C22 alkenyl, C6 to C30 aryl or C7 to C30 alkyl aryl; M represents a cation; and n represents a number between 0 and 30.
    Type: Grant
    Filed: September 28, 2005
    Date of Patent: November 10, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Dirk Leinweber, Michael Feustel
  • Patent number: 7566687
    Abstract: Improved desulfurization compositions are provided for removing substantial fractions of sulfur, sulfur complexes, and sulfur compounds from liquid hydrocarbons such as crude oil and fuels. The preferred compositions comprise respective quantities of an alkylphenol ethoxylate, an amine, and an alkali metal nitrite. The compositions may be contacted with liquid hydrocarbons to achieve high levels of desulfurization.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: July 28, 2009
    Assignee: Jacam Chemical, LLC
    Inventors: Gene H. Zaid, Beth Ann Wolf, Gary W. Zorn
  • Patent number: 7481276
    Abstract: Corrosive effects arising during oilfield treatment applications are inhibited and/or prevented by introducing into an oil or gas well at least one compound of formula I: wherein: R1 is independently H, —[—CnH2nO—]a—H, or an alkyl group having from 1 to about 24 carbon atoms; R2 is independently H or —[—CnH2nO—]b—H, R3 is independently —[—CH2]c—, or —Cd2d—[—OCnH2n—]e—, R4 is independently H or —[—CnH2nO—]f—H, R5 is independently H or —[—CnH2nO—]g—H, a is from about 1 to about 8; b+f+g is between 0 to about 30; c is from about 1 to 6; d is from about 1 to 6; e is from about 1 to about 8; and n is 2 or 3. Such corrosive effects are especially inhibited in the treatment of sour wells where H2S corrosion is a potential problem as well as conduits used during the treatment of subterranean formations.
    Type: Grant
    Filed: May 12, 2006
    Date of Patent: January 27, 2009
    Assignee: BJ Services Company
    Inventors: Ronald L. Hoppe, Richard L. Martin, Marek K. Pakulski, Thame D. Schaffer
  • Patent number: 7473672
    Abstract: The invention provides a method for the treatment of a hydrocarbon well which method comprises administering, down said well, polymeric particles having covalently bound to a polymeric component thereof a well treatment chemical or a precursor thereof, wherein the particles contain covalent bonds scissile in an aqueous environment to release or expose said chemical or precursor.
    Type: Grant
    Filed: November 19, 2001
    Date of Patent: January 6, 2009
    Assignee: Statoilhydro ASA
    Inventors: Hans Kristian Kotlar, Olav Martin Selle, Oddvar Arnfinn Aune, Lars Kilaas, Anne Dalager Dyrli
  • Patent number: 7381689
    Abstract: A method and an amide composition used therein for inhibiting, retarding, mitigating, reducing, controlling and/or delaying formation of hydrocarbon hydrates or agglomerates of hydrates. The method may be applied to prevent or reduce or mitigate plugging of conduits, pipes, transfer lines, valves, and other places or equipment where hydrocarbon hydrate solids may form under the conditions. At least one amide compound is added into the process stream, where the compound may be mixed with another compound selected from amino alcohols, esters, quaternary ammonium, phosphonium or sulphonium salts, betaines, amine oxides, other amides, simple amine salts, and combinations thereof.
    Type: Grant
    Filed: August 13, 2004
    Date of Patent: June 3, 2008
    Assignee: Champion Technologies, Inc.
    Inventors: Vaithilingam Panchalingam, Michael Gregory Rudel, Scot Harris Bodnar
  • Patent number: 7341617
    Abstract: The invention provides the use of compounds of the formula (1) where R1, R2 are each independently C1- to C22-alkyl, C2- to C22-alkenyl, C6- to C30-aryl or C7- to C30-alkylaryl, R3 is C1- to C22-alkyl, C2- to C22-alkenyl, C6- to C30-aryl or C7- to C30-alkylaryl, —CHR5—COO? or —O?, R4 is M, hydrogen or an organic radical which optionally contains heteroatoms and has from 1 to 100 carbon atoms, A is a C2- to C4-alkylene group, B is a C1- to C10-alkylene group, D is an organic radical which optionally contains heteroatoms and has from 1 to 600 carbon atoms, X, Y are each independently O or NR6, R5, R6 are each independently hydrogen, C1- to C22-alkyl, C2- to C22-alkenyl, C6- to C30-aryl or C7- to C30-alkylaryl, and M is a cation n is a number from 1 to 30 as corrosion inhibitors and gas hydrate inhibitors, and also the compounds of formula 1.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: March 11, 2008
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Uwe Dahlmann, Michael Feustel
  • Patent number: 7244693
    Abstract: A method for the treatment of a hydrocarbon well comprising administering down the well polymeric particles impregnated with a well treatment chemical or precursor or generator thereof. The particles have a pore volume of at least 20%, and are prepared by a process which comprises preparing an aqueous dispersion of polymer particles containing from 0.05 to 10 times by volume, based on the polymer, of one or more specific first material(s) adding a partly water-soluble second material having a water-solubility of at least ten times that of first material(s) under conditions which prevent or hinder transport of first material(s) through the aqueous phase, whereby second material diffuses into the polymer particles swelled with first material(s) and increases the volume of said particles by from 20 to 1000 times, based on the polymer.
    Type: Grant
    Filed: November 19, 2001
    Date of Patent: July 17, 2007
    Assignee: Statoil ASA
    Inventors: Hans Kristian Kotlar, Olav Martin Selle, Oddvar Arnfinn Aune, Lars Kilaas, Anne Dalager Dyrli
  • Patent number: 7216710
    Abstract: Methods of inhibiting corrosion comprising providing a corrosive environment; adding a corrosion inhibitor comprising a reaction product of a thiol compound and an aldehyde compound. Methods of acidizing a near well bore region of a subterranean formation comprising isolating a zone of interest along a well bore; and placing an acidizing solution in the zone of interest wherein the acidizing solution comprises an acid and a corrosion inhibiting compound comprising the reaction product of a thiol compound and an aldehyde compound.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: May 15, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Thomas D. Welton, Juanita M. Cassidy
  • Patent number: 7196040
    Abstract: A material and a device for releasing chemicals in a fluid environment is disclosed, and a method for releasing substances into downhole fluid environments. The invention also relates to materials for sand control and hydraulic fracturing. The substance release device typically comprises a polymeric material for releasing a substance into a downhole fluid environment in a well, and in preferred embodiments the material comprises a spherical, plastic chemical release capsule which is hard, permeable and may encapsulate a range of solids and/or liquids for subsequent release. These solids or liquids can include inhibitors such as scale inhibitors and other oilfield production chemicals for release into the wellbore of an oil or gas producing well or a water injection well.
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: March 27, 2007
    Assignee: T R Oil Services Limited
    Inventors: Stephen Mark Heath, Hugh Malcolm Bourne
  • Patent number: 7022652
    Abstract: A solution containing a compound having the general formula XF.nH2O2, wherein X is K+, Na+ or NH4+ and n is an integer from 1 to 3 (e.g., a peroxysolvate of potassium fluoride compound such as potassium fluoride hydroperoxide (KF.H2O2)) is injected into a subterranean formation in order to increase its permeability, especially with respect to hydrocarbon flow. These compounds serve to dissolve a wide variety of subterranean formation minerals (e.g., siliceous materials as well as carbonaceous materials). Potassium hydrofluoride (KHF2), can be employed with these compounds to produce particularly efficacious subterranean formation treatment solutions.
    Type: Grant
    Filed: July 26, 2004
    Date of Patent: April 4, 2006
    Assignee: GeoStim Group LLC
    Inventor: Vladimir Marakov
  • Patent number: 7008561
    Abstract: The present invention relates to compounds of formula (1) and the salts thereof which correspond to formula (2). In the formulae, A is C2- to C4-alkylene, x is a number from 1 to 100, y is a number from 1 to 4, and R is a cation. The compound of formula (1) and/or formula (2) forms a persistent film on metal surfaces, particularly on metal surfaces under stress in metal working and in the operation of crude oil and natural gas processing.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: March 7, 2006
    Assignee: Clariant GmbH
    Inventors: Uwe Dahlmann, Michael Feustel, Rainer Kupfer
  • Patent number: 6995120
    Abstract: Barium sulfate and/or calcium carbonate scale inhibitor composition composed of a water-soluble polymer having incorporated phosphate functionality, the polymer being formed from at least one ethylenically unsaturated carboxylic acid monomer, at least one ethylenically unsaturated vinyl sulfonate monomer, or a mixture thereof. The scale inhibitor composition can be used as a means of detecting inhibitor composition in downhole and topside oilfield treatments by means that are faster and more accurate than turbidometric measurement.
    Type: Grant
    Filed: August 25, 2005
    Date of Patent: February 7, 2006
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Martin Crossman, Stuart Peter Robert Holt
  • Patent number: 6939483
    Abstract: It has been discovered that ammonia and amines are useful to increase the pH and corrosion resistance of high density brines, such as zinc bromide brines, without significantly reducing their densities. The ammonia or amine additive is preferably incorporated by contacting the brine with the additive which is in the vapor phase. Optionally, a substituted carboxylic acid, such as hydroxy carboxylic acid, may be used to increase the amount of ammonia or amine that can be included in the high density brine without precipitation of salts.
    Type: Grant
    Filed: October 11, 2001
    Date of Patent: September 6, 2005
    Assignee: PABU Services, Inc.
    Inventor: Michael L. Walker
  • Patent number: 6894008
    Abstract: It has been discovered that carbonate powders and bicarbonate powders are useful to increase the pH and corrosion resistance of high-density brines, such as zinc bromide brines, without significantly reducing their densities. The carbonates and/or bicarbonates should be water-soluble and may be sodium, potassium, magnesium and/or ammonium carbonates and/or bicarbonates and the like. The carbonates and/or bicarbonates are easily added in powder or other finely divided solid form.
    Type: Grant
    Filed: December 3, 2003
    Date of Patent: May 17, 2005
    Assignee: Baker Hughes Incorporated
    Inventor: Michael L. Walker
  • Patent number: 6887840
    Abstract: An iron sulfide cleaning composition is described, along with a process for using the iron sulfide cleaning composition. The iron sulfide cleaning composition is simple to use and effective in removing deposits of iron sulfide from hydrocarbon wells. The iron sulfide cleaning composition consists of formaldehyde or glutaraldehyde, methanol, 2-butoxyethanol, isopropyl alcohol, hydrochloric acid, Surfactant Intermediate, Surfactant/Corrosion Inhibitor, glacial acetic acid and water.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: May 3, 2005
    Assignee: Milborn Enterprises LLC
    Inventor: Andy R. Miller
  • Patent number: 6866797
    Abstract: A class of quaternary ammonium compounds are found to be effective as corrosion inhibitors. These quaternary ammonium compounds may be used alone or in combination with additional components. For example, phosphate esters can be used with the quaternary ammonium compounds. Moreover, thiocarbonyl compounds can also be added to the corrosion inhibitor compositions. These corrosion inhibitors are effective against ferrous metal corrosion, especially under downhole conditions.
    Type: Grant
    Filed: August 3, 2001
    Date of Patent: March 15, 2005
    Assignee: BJ Services Company
    Inventors: Richard L. Martin, Gene F. Brock, James B. Dobbs
  • Patent number: 6764980
    Abstract: An oil field production chemical, especially a scale inhibitor, is in the form of particles thereof carrying a coating e.g. of a dispersing agent. The coating may be polymeric such as an oligomeric polyacid polyester, a polymeric alkoxylated alcohol or a fatty acid polyamine condensate or it may also be a surfactant and may be used in the form of a suspension in an inert oil, such as diesel oil or kerosene which may be injected into a subterranean formation to inhibit the formation of deposits, e.g. scale in oil wells over a longer period than compounds free of the coating.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: July 20, 2004
    Assignee: BP Exploration Operating Company Limited
    Inventors: Christopher Ian Bates, Ian Ralph Collins, Paul Derek Ravenscroft
  • Patent number: 6743756
    Abstract: Liquid suspensions of particles in non-aqueous solvents are extremely stable over long periods of time with minimum separation of the solvent and no hard packing of the dispersed particles. The suspensions enable a user to rapidly add the suspension to water and to mix at low speeds without generating fugitive dust in the process. In addition, a liquid dispersion can provide an easy to use liquid containing higher concentrations of the active dispersed phase than can be accomplished by simply preparing an aqueous solution of the dispersed phase. Alternatively, highly water-soluble particles may also be suspended which have poor storage, freeze/thaw, or heat/cool stability. In some cases, liquid dispersions can yield controlled release of the dispersed phase because the dispersed phase is not in aqueous solution. The suspensions are environmentally safe and biodegradable and may be used in environmentally sensitive applications, such as for oil well treating fluids for offshore areas.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: June 1, 2004
    Assignee: Benchmark Research and Technology, Inc.
    Inventor: William Franklin Harris, Jr.
  • Patent number: 6723683
    Abstract: The present invention relates to biodegradable chemical compositions wherein core substrates, particularly oil well chemicals, are adsorbed onto particulate starch, particularly granular starch, providing a stable, controlled release formulation suitable for use in oil field applications. The invention further relates to the process of preparing obtaining these compositions.
    Type: Grant
    Filed: August 7, 2001
    Date of Patent: April 20, 2004
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Martin C. Crossman, James A. Rosie, Daniel B Solarek
  • Patent number: 6706669
    Abstract: The present invention relates to a method for inhibiting high temperature of corrosion-prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of phosphorous acid, typically up to 1000 wppm, to the metal surface.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: March 16, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Guido Sartori, David Craig Dalrymple, Saul Charles Blum, Liza Marie Monette, Mohsen S. Yeganeh, Andreas Vogel
  • Patent number: 6695897
    Abstract: A corrosion inhibited formulation for drilling compositions consisting essentially of an environmentally friendly corrosion inhibitor blended with an alkali metal formate. The corrosion inhibitor is prepared pursuant to a process including the steps of: (1) preparing a reactant mixture comprising a fatty acid such as soya fatty acid or tall oil fatty acid with polyfunctional amines; (2) subjecting the reactant mixture to a temperature of between about 130 and 170 for a period sufficient to substantially complete the reaction to obtain a fatty acid amido amine product; (3) solubilizing the reactant product with an organic acid such as acetic to produce a product that is substantially completely soluble in aqueous solutions; and (4) blending the water soluble inhibitor salts into the buffered formate media.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: February 24, 2004
    Assignee: Cortec Corporation
    Inventors: Boris A. Miksic, Alla Furman, Margarita Kharshan, Jostein Braaten, Håkon Leth-Olsen
  • Patent number: 6620341
    Abstract: Anti-corrosion additives and processes useful for oil drilling and similar applications. Heteropoly complex anions of transitional metal elements can be added to an oil well drilling solution which includes a metallic salt, optionally in combination with transition metal compounds or compounds of the metallic elements of Groups IIIa to VIa of the Periodic Table of Elements, to minimize corrosion of systems within which the solution is used.
    Type: Grant
    Filed: November 15, 2000
    Date of Patent: September 16, 2003
    Assignee: FMC Corporation
    Inventors: Shyam Kumar Verma, George Robert Sandor
  • Patent number: 6613720
    Abstract: The effect of various chemical or biological agents in well treatment fluids can be delayed by sequestering the agents in the discontinuous phase of an emulsion for a period of time, before the emulsion is destabilized by exposure to at least one of: (1) a change in temperature, (2) a change in pH, (3) a change in salinity, (4) a change in alcohol concentration, (5) a change in stabilizing surfactant concentration, (6) a change in organic ion concentration, (7) a change in destabilizing surfactant concentration, (8) a change in surfactant adsorbent material concentration, (9) an ultrasonic pulse, and (10) an electrical field. Upon exposure to the emulsion destabilizing condition, the agent sequestered in the discontinuous phase of the emulsion is released into the continuous phase of the fluid composition, where it can have its intended effect.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: September 2, 2003
    Assignee: Schlumberger Technology Corporation
    Inventors: Jean Pierre Feraud, Michael D. Parris, Richard D. Hutchins, Stanley Bruce McConnell, Erik B. Nelson, Keith Dismuke
  • Patent number: 6593278
    Abstract: The present invention relates to a method for inhibiting corrosion of corrosion-prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of certain sulfur and phosphorus-free aromatic compounds substituted with nitrogen, containing functional groups at the 5- or 3, 5-position, typically up to 1000 wppm, to the metal surface.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: July 15, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Mohsen S. Yeganeh, Shawn Michael Dougal, Guido Sartori, David Craig Dalrymple, Cheayao Zhang, Saul Charles Blum, Liza Marie Monette
  • Patent number: 6583091
    Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of 4-sulfophthalic acid, typically up to 1000 wppm, to the metal surface.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: June 24, 2003
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Guido Sartori, David Craig Dalrymple, Saul Charles Blum, Liza Marie Monette, Mohsen S. Yeganeh, Andreas Vogel
  • Patent number: 6559104
    Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of an additive aromatic compound tri-substituted with acidic functionalities selected from 5-hydroxyisophthalic acid and 1,3,5-benzenetricarboxylic acid, typically up to 1000 wppm, to the metal surface.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: May 6, 2003
    Assignee: ExxonMobil Research and Engineering Co.
    Inventors: Guido Sartori, David Craig Dalrymple, Saul Charles Blum, Liza Marie Monette, Mohsen S. Yeganeh, Andreas Vogel
  • Patent number: 6555506
    Abstract: A method of preventing corrosion in pipelines comprising draining pipeline of all residual compounds, blowing through with nitrogen and rinsing with a corrosion inhibiting rinsing agent.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: April 29, 2003
    Assignee: Illinois Tool Works Inc.
    Inventors: William Hopkins, Christopher Nettleship
  • Patent number: 6540943
    Abstract: The corrosion of metal equipment which is cleaned with an inorganic acid is inhibited by treating the equipment with a corrosion inhibitor composition containing at least one quaternary ammonium compound, a sulfur-containing compound and a nonionic surfactant in a solvent.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: April 1, 2003
    Assignee: Ondeo Nadco Company
    Inventors: Duane S. Treybig, Dennis A. Williams
  • Patent number: 6537950
    Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of triphenylstibine, typically up to 1000 wppm, to the metal surface.
    Type: Grant
    Filed: July 13, 2001
    Date of Patent: March 25, 2003
    Assignee: ExxonMobil Research and Engineering Co.
    Inventors: Guido Sartori, David Craig Dalrymple, Saul Charles Blum, Liza Marie Monette, Mohsen S. Yeganeh
  • Patent number: 6475431
    Abstract: A low toxic, biodegradable, water soluble and dispersant series of corrosion inhibitors are described. The method of inhibiting corrosion in aqueous medium by incorporating the inhibitor in PPM is provided. The corrosion inhibitor compromises an acrylic acid and chloroacetic acid adduct of 2-substituted imidazolines or primary, secondary or tertiary amines with carbon chain of twelve to twenty-two saturated or unsaturated carbon atoms. The molar ratio of acrylic acid to chloroacetic acid was methodically changed while keeping the concentration of imidazoline or the amine a constant. The product is made water soluble by raising the pH to 8-9 at the end of the synthesis by adding aqueous sodium hydroxide.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: November 5, 2002
    Assignee: Champion Technologies, Inc.
    Inventors: Ali Naraghi, Nihal U. Obeyesekere
  • Patent number: 6467492
    Abstract: A method of preventing corrosion in pipelines comprising draining pipeline of all residual compounds, blowing through with nitrogen and rinsing with a corrosion inhibiting rinsing agent.
    Type: Grant
    Filed: February 23, 2001
    Date of Patent: October 22, 2002
    Assignee: Illinois Tool Works, Inc.
    Inventors: William Hopkins, Christopher Nettleship
  • Patent number: 6436880
    Abstract: An acidic fluid that is useful in stimulation and workover operations, and in particular, for the control of iron in acidizing operations, the removal of alkaline earth carbonate scale in scale removal operations, and matrix or fracture acidizing operations, comprises an acid, such as hydrochloric acid; water; and a hydroxyethylaminocarboxylic acid. Preferred hydroxyethylaminocarboxylic acids are hydroxyethylethylenediaminetriacetic acid (HEDTA) and hydroxyethyliminodiacetic acid (HEIDA). Also disclosed herein are methods of controlling iron, removing alkaline earth carbonate scale, or matrix or fracture acidizing, involving the use of the acidic fluid.
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: August 20, 2002
    Assignee: Schlumberger Technology Corporation
    Inventor: Wayne W. Frenier