With Added Water Patents (Class 508/143)
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Patent number: 10814890Abstract: A friction control composition having high and positive frictional properties for sliding steel surfaces includes a water insoluble hydrocarbon that enables a reduced water content, a rheological additive, a freezing point depressant, a friction modifier, and a lubricant.Type: GrantFiled: February 19, 2019Date of Patent: October 27, 2020Assignee: Whitmore Manufacturing, LLCInventors: Kelvin Chiddick, Alejandro Medrano, Randall Krinker, Kyle Wilson, David Birdwell
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Patent number: 10213677Abstract: A mouthguard which has a unique shape and design which not only facilitates air passages so a player can breath while the mouthguard is in the player's mouth and protecting the player's teeth, but also has additionally has a flavoring embedded within the mouthguard, preferably on the base on which the player is placing his upper row of teeth so that in addition to protection, the mouthguard has an attractive flavor which can be tasted by the player as the player bites down on the mouthguard.Type: GrantFiled: November 6, 2015Date of Patent: February 26, 2019Inventor: Jonathan S. Hirshberg
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Patent number: 9951593Abstract: Organoclay is used as an alternative emulsifier and reinforcing agent to enhance the strength of emulsified polymeric gel aqueous solutions and form water in oil emulsions. The stability of the emulsion can be controlled by controlling salinity and the intensity of initial mixing. The new system can be used for water shut-off treatments as well as a relative permeability modifier in high water permeability zones. In addition, the system can tolerate salts much better than classical surfactants. This system will be appropriate for wellbores having high temperature (>85° C.) with harsh environmental conditions.Type: GrantFiled: April 22, 2014Date of Patent: April 24, 2018Assignees: King Fahd University of Petroleum and Minerals, King Abdulaziz City for Science and TechnologyInventors: Ibnelwaleed Ali Hussein, Ahmad Akanbi Adewunmi, Abdullah Saad Sultan, Khalid Saad Elkarsani, Ghaithan A. Al-Muntasheri
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Patent number: 9468959Abstract: A continuously cast slab with a rectangular cross section, and made of high alloy containing Cr of 20 to 30 mass %, Ni of 30 to 50 mass %, and at least one of Mo and W as Mo+0.5W of 1.5 mass % or more is subjected to blooming and billet-making to yield a round bar having a diameter of 150 to 400 mm as a starting material of the seamless tube. The blooming and billet-making process is performed under a condition satisfying a relation of 1.3?H/D?1.8 where a short side length of the cross section of the cast slab is defined as H (mm), and the diameter of the round bar is defined as D (mm). The round bar is pierced-rolled to make a hollow blank; the hollow blank tube is elongation-rolled, and then diameter-adjusting-rolled to make the seamless tube, thereby preventing end cracking during piercing-rolling, and increasing yield.Type: GrantFiled: December 20, 2011Date of Patent: October 18, 2016Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Naoya Hirase, Takanori Satou
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Patent number: 9382497Abstract: An oil-based graphite lubricant for a plunger includes graphite that is used as a solid lubricant, and an organic bentonite swollen by a mineral oil and a surfactant that are used as a graphite dispersant. The lubricant is prepared by a method which includes a first step of causing an organic bentonite to swell in the mineral oil, a second step of adding a surfactant, and a third step of adding and dispersing graphite.Type: GrantFiled: June 18, 2012Date of Patent: July 5, 2016Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Yuichi Furukawa, Hiroshi Kawai, Yasufumi Kondo
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Patent number: 8999900Abstract: The present invention provide a two-component anti-seizure agent for hot metal working process comprising the first aqueous solution and the second aqueous solution, wherein the first aqueous solution contains 10˜30 mass % of sodium silicate equivalent to anhydride to 100 mass % of total mass of the first aqueous solution, and the second aqueous solution contains at least one kind selected from a group consisting of: an organic acid and water-soluble amine salts thereof, an inorganic acid and water-soluble amine salts thereof, a water-soluble amine, a water-soluble alcohol, and a water-soluble metal chloride. When the two-component anti-seizure agent is applied onto disk-roll type guide shoes, it can be provided and maintained on the circumferential surface of the disk-roll type guide shoes without washed away by rolls' cooling water. Thereby, the anti-seizure agent does not adhere to rolls and the rolls and a pipe material do not cause slippage each other.Type: GrantFiled: February 9, 2006Date of Patent: April 7, 2015Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Sumio Iida, Masami Imamura, Yuuji Tanaka, Kazuhiro Shimoda, Hirofumi Hori, Akira Motoki, Shizuo Mori
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Patent number: 8651745Abstract: In an electrical machine having a roller bearing, whose inner ring is seated on the rotor shaft of the electrical machine, whose outer ring is seated in a housing and which is located in a closed area, the roller bearing is intended to be protected against electrical breakdowns. For this purpose, the area contains a liquid on an aqueous basis, whose level overhangs the external contour of the inner ring at its lowest point. The inner ring and the outer ring are therefore conductively connected and the voltage can be equalized between the rotor and the housing of the electrical machine, without any impediment and without breakdowns. In an application as a geared motor, the lubricant for the gearbox is also a liquid on an aqueous basis.Type: GrantFiled: August 10, 2010Date of Patent: February 18, 2014Assignee: MAGNA STEYR Fahrzeugtechnik AG & Co. KGInventors: Franz Mayr, Ferdinand Tangl
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Publication number: 20120288649Abstract: An aqueous coating composition for reducing friction and/or blocking at a surface, said composition comprising a solid lubricant and a modified or synthetic clay mineral having thickening properties such that a 2% by weight aqueous dispersion of the modified or synthetic clay mineral thickener has a viscosity of at least 1000 mPa·s. Preferred clay minerals used as thickeners are preferably smectite clays such as saponite, hectorite, stevensite, sauconite, bentonite, beidellite, nontronite, or montmorillonite.Type: ApplicationFiled: December 27, 2010Publication date: November 15, 2012Inventors: William Blackwood, Seiji Hori, Kazuhiko Kojima, Tsugio Nozoe, Masaru Ozaki, Yuichi Tsuji
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Patent number: 8157876Abstract: A wiresaw cutting fluid composition of the present invention comprises about 25 to about 75% by weight of a particulate abrasive suspended in an aqueous carrier containing a polymeric viscosity modifier that comprises a polymer including a majority of non-ionic monomer units (preferably 100 mol % non-ionic monomer units), has a number average molecular weight (Mn) of at least about 5 kDa, and is present in the composition at a concentration sufficient to provide a Brookfield viscosity for the composition in the range of about 50 to about 1000 cP, e.g., 50 to about 700 cP, at about 25° C. at a spindle rotation rate of about 60 rpm. In one embodiment, the viscosity modifier comprises a polymer having a weight average molecular weight (Mw) of at least about 200 kDa. When a viscosity modifier of 200 kDa or greater Mw is utilized, a preferred wiresaw cutting method the cutting fluid is circulated and applied by pumps and nozzles operating at a relatively low shear rate of not more than about 104 s?1.Type: GrantFiled: December 19, 2008Date of Patent: April 17, 2012Assignee: Cabot Microelectronics CorporationInventors: Steven Grumbine, Chul Woo Nam, William Ward, Ramasubramanyam Nagarajan
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Patent number: 8024953Abstract: There is provided a lubricant for hot plastic working, which contains 20 to 40 mass % of iron oxide and 10 to 30 mass % of sodium silicate, wherein impurities are 3 mass % or less, and the lubricant contains 40 to 60 mass % of water. By virtue of combined action of these components, the lubricant exhibits excellent lubricity and suppliability and does not adversely affect the corrosion resistance of product. The lubricant is suitably used for lubricating a guide shoe in piercing-rolling, for example, a high-Cr steel and achieves a great effect of preventing a seizure flaw from occurring on the outer surface of product by being applied directly to the outer surface of a workpiece just before piercing rolling, preferably, within one second before starting piercing rolling.Type: GrantFiled: June 28, 2010Date of Patent: September 27, 2011Assignee: Sumitomo Metal Industries, Ltd.Inventors: Kenichi Saito, Sumio Iida
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Patent number: 7867330Abstract: The present invention relates to a metal treatment composition including Tin (II) Chloride and processed montmorillonite clay. The addition of Tin (II) Chloride to the composition provides Tin for forming a ceramic-metal layer on the surfaces of the friction pair. Tin (II) Chloride provides Chlorine ions for forming Chloric films for protecting juvenile surfaces which form in the friction zone. The clay is heated and pulverized to produce a powder comprising both particles having crystalline layer structure and salts and oxides. The layered crystalline structure of the clay contains slip planes that transversely shift when tangential pressure from the friction pair is applied thereby lubricating the friction pair. The salts and oxides contribute to the formation of the ceramic-metal layer.Type: GrantFiled: September 24, 2007Date of Patent: January 11, 2011Inventors: Dmitry Tananko, Olena Lyubchenko, Oleksandr Oliinik, Oleksandr Umanskiy, Svitlana Aksyonova
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Patent number: 7727941Abstract: The passage of a container along a conveyor is lubricated by applying to the container or conveyor a composition comprising a water-miscible silicone material wherein the composition comprises a stoichiometric amount of an organic acid. The compatibility of the lubricating composition with polyethylene terephthalate is increased because of the presence of a stoichiometric amount of acid.Type: GrantFiled: September 22, 2005Date of Patent: June 1, 2010Assignee: Ecolab Inc.Inventors: Eric D. Morrison, Richard D. Johnson, Robert D. Hei
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Patent number: 7462582Abstract: A waterborne composition for forming protective coatings to provide, by a simple method comprising coating and drying onto a metal surface, a coating that is uniform with little unevenness and that has an excellent galling resistance and workability that are at least as good as the corresponding properties afforded by conversion treatment methodologies, contains water-soluble inorganic salt and smectite-type clay mineral. The lubrication performance of the coating can also be improved when said composition additionally contains a lubricating component.Type: GrantFiled: February 11, 2003Date of Patent: December 9, 2008Assignee: Henkel AG & Co. KGaAInventors: Shinobu Komiyama, Hidehiro Yamaguchi, Akihiro Seo
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Patent number: 7414012Abstract: A waterborne lubricant, useful in the plastic working of metals, which imparts a lubricating behavior to the surface of metals in the absence of a conversion coating contains (A) water-soluble inorganic salt and (B) wax, wherein these components are dissolved or dispersed in water and the (B)/(A) solids weight ratio is 0.3 to 1.5. The (C) metal salt of a fatty acid can also be present at a (C)/(A) solids weight ratio of 0.01 to 0.4. The water-soluble inorganic salt (A) can be selected from the sulfates, silicates, borates, molybdates, and tungstates. The wax (B) can be a synthetic wax having a melting point of 70 to 150° C. A lubricating coating is formed by application to give a post-drying add-on of 0.5 to 40 g/m2. A method for using said lubricant is also provided.Type: GrantFiled: February 7, 2003Date of Patent: August 19, 2008Assignee: Henkel KGaAInventors: Yasuo Imai, Syuji Nagata, Masayuki Yoshida
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Patent number: 7244695Abstract: According to the invention there is provided a method of reducing wear of one or both of two steel elements having surfaces in sliding or sliding-rolling contact. The method involves applying an HPF friction control composition to one, or more than one contacting surface of one or both of the two steel elements. In a particular example, the HPF friction control composition comprises a rheological control agent, a lubricant, a friction modifier, and one, or more than one of a retentivity agent, an antioxidant, a consistency modifier, and a freezing point depressant.Type: GrantFiled: May 2, 2003Date of Patent: July 17, 2007Assignee: Kelsan Technologies Corp.Inventor: Don T. Eadie
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Patent number: 7141535Abstract: In a particular embodiment, the invention concerns a lubricating grease having 70 to 95 percent by weight of a mixture that includes at least a first ester of fatty acid and of sorbitan, and at least a second ester of fatty acid and of polyoxyalkylated sorbitan. The esters are present in quantities by weight, relative to the weight of the mixture, of 10 to 90 percent and 90 to 10 percent respectively. The grease also includes from 5 to 30 percent by weight of at least one thickening agent.Type: GrantFiled: May 3, 2002Date of Patent: November 28, 2006Inventors: Pierre Belot, Jean-Marie Pinoche
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Patent number: 7045489Abstract: According to the invention there is provided a liquid friction control composition characterized as either having a high and positive friction characteristic or a low and neutral friction characteristic, comprising a retentivity agent. The liquid friction control composition may also comprise other components such as a solid lubricant, a wetting agent, a consistency modifier, and a preservative. The liquid friction control compositions may be used to modify the interfacial friction characteristics in sliding and rolling-sliding contact such as steel wheel-rail systems including mass transit and freight systems.Type: GrantFiled: September 28, 2001Date of Patent: May 16, 2006Assignee: Kelsan Technologies Corp.Inventors: John Cotter, Donald T. Eadie, Kelvin Spencer Chiddick
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Patent number: 6855673Abstract: According to the invention there is provided a liquid friction control composition for use in low temperature conditions, which comprises a rheological control agent, a consistency modifier and a freezing point depressant. The liquid friction control composition may also comprise other components such as a retentivity agent, an antioxidant, a friction modifier, a lubricant, a wetting agent, and a preservative.Type: GrantFiled: November 8, 2002Date of Patent: February 15, 2005Assignee: Kelsan Technologies CorporationInventors: John Cotter, Don Eadie
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Patent number: 6759372Abstract: According to the invention there is provided a liquid friction control composition with enhanced retentivity comprising an anti-oxidant. The liquid friction control composition may also comprise other components such as a retentivity agent, a rheological control agent, a friction modifier, a lubricant, a wetting agent, a consistency modifier, and a preservative.Type: GrantFiled: April 12, 2002Date of Patent: July 6, 2004Assignee: Kelsan Technologies Corp.Inventor: John Cotter
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Publication number: 20040092407Abstract: According to the invention there is provided a liquid friction control composition for use in low temperature conditions, which comprises a rheological control agent, a consistency modifier and a freezing point depressant. The liquid friction control composition may also comprise other components such as a retentivity agent, an antioxidant, a friction modifier, a lubricant, a wetting agent, and a preservative.Type: ApplicationFiled: November 8, 2002Publication date: May 13, 2004Applicant: Kelsan Technologies CORP.Inventors: John Cotter, Don Eadie
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Publication number: 20040053790Abstract: According to the invention there is provided a liquid friction control composition characterized as either having a high and positive friction characteristic or a low and neutral friction characteristic, comprising a retentivity agent. The liquid friction control composition may also comprise other components such as a solid lubricant, a wetting agent, a consistency modifier, and a preservative. The liquid friction control compositions may be used to modify the interfacial friction characteristics in sliding and rolling-sliding contact such as steel wheel-rail systems including mass transit and freight systems.Type: ApplicationFiled: October 9, 2003Publication date: March 18, 2004Inventors: John Cotter, Donald T. Eadie, Kelvin Spencer Chiddick
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Publication number: 20040033909Abstract: A surface-lubricated metal product, with excellent shapability, comprising a metal having coated on both surfaces, or one surface, thereof an alkali-soluble lubricating film mainly comprising an alkali-soluble polyurethane aqueous composition containing a carboxyl group or a sulfonic acid group within the molecule, and a lubricating function-imparting agent in an amount of 1 to 30 mass % based on the alkali-soluble polyurethane aqueous composition, the film being coated to have a film thickness of 0.5 to 10 &mgr;m and the elastic modulus of the film after coating being 0.5 to 20 GPa at 25° C.Type: ApplicationFiled: May 15, 2003Publication date: February 19, 2004Inventors: Ikuro Yamaoka, Hiroshi Kanai, Akihiro Miyasaka, Yoichiro Mori, Tsutomu Tawa, Mitsuhiro Nishimura, Chikako Kouda
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Patent number: 6673754Abstract: The present invention provides a nonflammable water-based cutting fluid composition which affords excellent dispersion property of abrasives, which does not cause problems involving in flammability upon the use for cutting process of a hard and brittle materials, which can be readily washed, and which can achieve sufficient rust preventive property even if it is used in an equipment for oil use. Provided by the present invention is a nonflammable water-based cutting fluid composition containing a polycarboxylic acid-based polymer compound and/or a salt thereof having a weight-average molecular weight of 1,000-200,000, and additionally a carboxylic acid and/or a salt thereof upon needs for a rust preventive property.Type: GrantFiled: September 6, 2002Date of Patent: January 6, 2004Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Toshikazu Nabeshima, Kaori Sugiyama, Hitoshi Shinike
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Publication number: 20030195123Abstract: According to the invention there is provided a liquid friction control composition with enhanced retentivity comprising an anti-oxidant. The liquid friction control composition may also comprise other components such as a retentivity agent, a rheological control agent, a friction modifier, a lubricant, a wetting agent, a consistency modifier, and a preservative.Type: ApplicationFiled: April 12, 2002Publication date: October 16, 2003Applicant: Kelsan Technologies Corp.Inventor: John Cotter
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Publication number: 20030100455Abstract: An aqueous grinding fluid has compositions mainly consisting of 40.0-95.0 wt. % a polyalcohol and/or a polyalcohol derivative, 5.0-50.0 wt. % water, 0.1-3.5 wt. % bentonite, 0.1-5.0 wt. % cellulose and weight %, 0.5-10.0 wt. % mica and optionally a small amount of a surfactant or polar solvent. Bentonite, cellulose and mica are preferably added with such combination to adjust a viscosity of a slurry to 150-300 mPa.second as a value measured by a rotating cylinder type viscometer. The aqueous suspension is nonflammable and stabilized in dispersiveness and settleability-proof of abrasive grits as well as a viscosity for a long time, and facilitates washing and cleaning of sliced wafers and a grinding machine without radiation of stinks.Type: ApplicationFiled: May 12, 2000Publication date: May 29, 2003Inventors: Hiroshi Oishi, Keiichiro Asakawa, Junichi Matsuzaki
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Patent number: 6258759Abstract: A metal-working water or a metal-working composition which has excellent cooling and lubricating properties and does not exert a harmful influence on the environment. A metal-working water containing sodium ion and one or more kinds selected from the group consisting of fluoride ion, hydrogencarbonate ion and silicon and being adjusted to pH 6.0 to pH 10 can be used as a substitute for a conventional cutting oil. A metal-working composition including a metal-working water with such additive as a rust-preventive agent and being adjusted to pH 6.0 to pH 10 can also be used.Type: GrantFiled: April 19, 2000Date of Patent: July 10, 2001Inventors: Sadao Futahashi, Yasuo Fukutani, Yukio Wada, Eiichiro Nakayama
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Patent number: 6228816Abstract: An aqueous cutting liquid comprises a cationic water-soluble resin having an amine value of 20 to 200 mgKOH/g, and at least one rheology control agent selected from the group consisting of an inorganic bentonite, an organic bentonite and an aqueous silica sol, wherein the content of a nonvolatile matter of the rheology control agent is 0.1 to 30 percent by weight of the amount of the nonvolatile matter of the cationic water-soluble resin. An aqueous cutting agent comprises the aqueous cutting liquid, and an abrasive grain, wherein the content of the abrasive grain is 100 to 1000 percent by weight of the amount of the nonvolatile matter of the aqueous cutting liquid. A hard and brittle material is cut by a cutting device using the aqueous cutting agent.Type: GrantFiled: October 6, 1999Date of Patent: May 8, 2001Assignees: NOF Corporation, Fujimi IncorporatedInventors: Kenji Ito, Shunji Maemichi, Hutoshi Nakanishi, Masahiro Ishidoya, Takashi Tanaka, Toshihiko Nakamichi, Kazuyuki Mori, Shigehiro Hayashi, Hideki Yokoyama
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Patent number: 6221814Abstract: An aqueous cutting fluid which can reduce the impact on working environment and the global environment, and can achieve both preventing precipitates from becoming a hard cake and keeping high dispersibility for abrasive grains is provided. Such an aqueous cutting fluid is obtained by a method comprising dispersing abrasive grains (G) in an aqueous composition comprising a dispersion medium (M) containing a hydrophilic alcohol compound such as ethylene glycol, a lipophilic alcohol compound such as propylene glycol and water, and silica colloid particles dispersed stably in the medium. The dispersion medium (M) is odorless and not flammable. The abrasive grains (G) may settle out after a time, but they do not closely contact with one another, and therefore the resulting precipitates do not become a hard cake, which allows the re-dispersion and reuse of precipitated grains.Type: GrantFiled: November 12, 1999Date of Patent: April 24, 2001Assignees: Shin-Etsu Handotai Co., Ltd., Ohtomo Chemical Ind., Corp.Inventors: Shingo Kaburagi, Akio Ashida, Etsuo Kiuchi
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Patent number: 6194357Abstract: Waterborne lubricants comprising: (A) water-soluble inorganic salt; (B) homogeneously dispersed solid lubricant; (C) at least one homogeneously emulsified substance selected from mineral oils, animal and plant oils and fats, and synthetic oils; (D) surfactant; and (E) water, in which the weight ratio (B)/(A) is from 0.05:1 to 2:1 and the weight ratio {C/(A+B)} is from 0.05:1 to 1:1, provide a one-step, highly lubricating waterborne lubricant for use in the cold plastic working of metals. This waterborne lubricant can replace the conversion coating treatment (phosphate, oxalate, etc.)+reactive soap treatment combined lubrication system now in general use and is free of the environmental issues associated with the combined lubrication system, provides for facile coating removal, and is not subject to the decline in seizure resistance caused by nonuniform add-on when large numbers of workpieces are treated together by immersion.Type: GrantFiled: December 21, 1998Date of Patent: February 27, 2001Assignee: Henkel CorporationInventors: Motoharu Murata, Yoshio Matsumura, Yoshihiko Nishizawa, Takashi Koyama
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Patent number: 5859124Abstract: A lubricant is provided for use in hot working such as cross-roll rolling of a seamless steel pipe. It effectively reduces the friction coefficient between the working tools and the material under the hot work, thus extending the lives of the tools. The lubricant contains: (A) from about 10 to about 60 wt % of alkali silicate; (B) from about 1 to about 20 wt % of silane coupling agent; (C) from about 0.1 to about 5.0 wt % of at least one kind of alkali compound selected from a group consisting of an alkali hydroxide, an alkali carbonate, an alkali borate and an alkali salt of mineral acid; and (D) from about 30 to about 70 wt % of water. Alternatively, the lubricant contains: (A) from about 10 to about 60 wt % of alkali silicate; (B) from about 1 to about 20 wt % of silane coupling agent; (C) from about 0.1 to about 5.Type: GrantFiled: April 22, 1997Date of Patent: January 12, 1999Assignee: Kawasaki Steel CorporationInventors: Akira Yorifuji, Takaaki Toyooka, Ken Shimamoto, Masaharu Kita, Taro Kanayama
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Patent number: 5792727Abstract: Lubricant composition containing spherical particles of a ceramic material dispersed in a supporting vehicle. The composition is used as a lubricant, metalworking cooling fluid, drilling fluid or drilling mud.Type: GrantFiled: February 15, 1996Date of Patent: August 11, 1998Inventor: Norman Laurie Jacobs
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Patent number: 5738813Abstract: A release agent composition for tire molding applications that, when applied on the inner liner surface of an unvulcanized green tire, has a white color prior to vulcanization and a black to blackish-gray color after vulcanization. The release agent composition contains a diorganopolysiloxane that has a viscosity at 25.degree. C. of at least 100 centistokes, an emulsifying dispersant, mica powder or talc powder, a powder having a melting point not exceeding 200.degree. C., and water.Type: GrantFiled: July 19, 1995Date of Patent: April 14, 1998Assignee: Dow Corning Toray Silicone Co., LTD.Inventors: Tsutomu Naganawa, Isao Ona
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Patent number: 5693596Abstract: A water-soluble cutting fluid is produced by dissolving a polymer fatty acid triglyceride imidazole, 2-methyl-1-stearate, and boric acid imidazole in the dispersion of inorganic bentonite in water thereby preparing a main component and adding oleic acid (agent for enhancing the lubricity), Na salt of ethylenediamine tetraacetic acid (metallic ion adsorbent), benzotriazole (rust-preventing auxiliary agent), and a silicone type defoaming agent to the main component.Type: GrantFiled: October 23, 1995Date of Patent: December 2, 1997Assignee: Shin-Etsu Handotai Co., Ltd.Inventors: Shingo Kaburagi, Akio Ashida, Etsuo Kiuchi, Kazuo Hayakawa, Kohei Toyama
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Patent number: 5560853Abstract: A borate ester having the formula ##STR1## wherein Y is N, S or O, X is O or S, R.sup.1 and R.sup.2 are, independent of one another, selected from the group consisting of H, (C.sub.1 -C.sub.40)hydrocarbon residues and (C.sub.3 -C.sub.50)cycloalkyl, aryl and aralkyl, each of which may further contain N, O or S, R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are independent of one another, selected from the group consisting of H and (C.sub.1 -C.sub.8)hydrocarbon residues, n is 0 to 4. An anti-wear/anti-oxidant/anti-friction/anti-rust additive comprises the borate ester of the invention when added to a lubricating oil.Type: GrantFiled: March 13, 1992Date of Patent: October 1, 1996Assignee: Pennzoil Products CompanyInventor: I-Ching Chiu