Phosphorus Or Silicon Containing Patents (Class 508/187)
  • Patent number: 11124732
    Abstract: Disclosed is a lubricating oil composition containing a base oil, a viscosity index improver, a molybdenum-based friction modifier, a boron-containing dispersant, and at least two extreme-pressure additives selected from a sulfur-based extreme-pressure additive, a phosphorous-based extreme-pressure additive and a sulfur/phosphorus-based extreme-pressure additive, or a sulfur/phosphorus-based extreme-pressure additive. The base oil is a synthetic oil having a kinematic viscosity at 100° C. of 3 mm2/s or more and 10 mm2/s or less, the viscosity index improver is a resin having a number average molecular weight (Mn) of 1,000 or more and 10,000 or less, the mass ratio of boron atoms (B) contained in the boron-containing dispersant to molybdenum atoms (Mo) contained in the molybdenum-based friction modifier, [(B)/(Mo)] is 1 or more and 5 or less, and the mass ratio of sulfur atoms (S) to phosphorus atoms (P) contained in the extreme-pressure additive(s), [(S)/(P)] is 10 or more and 20 or less.
    Type: Grant
    Filed: March 23, 2016
    Date of Patent: September 21, 2021
    Assignee: IDEMITSU KOSAN CO., LTD.
    Inventor: Yoji Sunagawa
  • Patent number: 11072758
    Abstract: The invention provides a lubricant composition comprising an oil of lubricating viscosity and a protic acid salt of an N-hydrocarbyl-substituted gamma-(?-) or delta-amino(thio)ester. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.
    Type: Grant
    Filed: November 4, 2016
    Date of Patent: July 27, 2021
    Assignee: Lubrizol Corporation
    Inventors: Daniel J. Saccomando, William R. S. Barton, Ewan E. Delbridge, Patrick E. Mosier
  • Patent number: 8703669
    Abstract: The present disclosure provides a fluid for lubricating the clutch-only portion of a wet clutch in a dual clutch transmission. The fluid provides high dynamic friction durability and comprises an oil of lubricating viscosity formulated with additive components comprising: i) at least one metal detergent; ii) at least one phosphorus-based wear preventative; iii) a phosphorylated and boronated dispersant different than the at least one phosphorus-based wear preventative; iv) a sulfurized extreme pressure agent; and a ratio between the content (ppm) of the sulfur based on the total weight of the fluid composition and a content (ppm) of phosphorus based on the total weight of the fluid composition ranging from about 2.0 to about 0.5 (ppm/ppm).
    Type: Grant
    Filed: February 17, 2009
    Date of Patent: April 22, 2014
    Assignee: Afton Chemical Corporation
    Inventor: Ramnath N. Iyer
  • Patent number: 8551927
    Abstract: The invention relates to a lubricating composition containing (a) an oil of lubricating viscosity, and (b) an oil soluble compound with a >N—R—N< group, wherein R may be a hydrocarbylene group. The invention further provides for the use of the lubricating composition for lubricating a limited slip differential.
    Type: Grant
    Filed: May 23, 2011
    Date of Patent: October 8, 2013
    Assignee: The Lubrizol Corporation
    Inventors: Daniel J. Saccomando, Stuart L. Bartley, Shubhamita Basu
  • Patent number: 8299003
    Abstract: There is disclosed herein an additive composition including a compound of formula (III): wherein R1, R2, R3, R4, R5, R6 , R7, R8, and R9are independently selected from the group consisting of hydrogen, cyano, and hydrocarbyl groups comprising from about 1 to about 30 carbon atoms.
    Type: Grant
    Filed: March 9, 2006
    Date of Patent: October 30, 2012
    Assignee: Afton Chemical Corporation
    Inventors: David J. DeGonia, Chip Hewette, Roger M. Sheets, Ronald L. Phillips, John T. Loper
  • Publication number: 20120208731
    Abstract: The invention relates to a method of lubricating a limited slip differential comprising supplying to the limited slip differential a lubricating composition containing (a) an oil of lubricating viscosity, and (b) a C4-30-diester of a dicarboxylic acid. The invention further provides for the use of the C4-30-diester of a dicarboxylic acid as a friction modifier, typically in a limited slip differential.
    Type: Application
    Filed: September 14, 2010
    Publication date: August 16, 2012
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Pamela Lann, William D. Abraham, Mark R. Baker
  • Publication number: 20110207635
    Abstract: The invention relates to a lubricating composition comprising (a) at least 0.05 wt % of a non-aromatic metal carboxylate, wherein the metal carboxylate is derived from a branched carboxylic acid, and (b) an oil of lubricating viscosity. The invention further provides for the use of the lubricating composition for lubricating a limited slip differential.
    Type: Application
    Filed: October 21, 2009
    Publication date: August 25, 2011
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Stuart L. Bartley, Mark R. Baker
  • Publication number: 20100279901
    Abstract: An additive composition may comprise at least one phosphorus- and boron-containing dispersant, at least one boron-containing dispersant, and at least one detergent. Such composition may be useful in power transmissions to provide improved anti-shudder performance and/or improved friction durability.
    Type: Application
    Filed: May 21, 2010
    Publication date: November 4, 2010
    Inventors: Ramnath N. Iyer, Samuel H. Tersigni
  • Publication number: 20100147238
    Abstract: The invention provides lubricant compositions for diesel engines having a regenerative DPF, which prolong life of the DPF by inhibiting accumulation of components depositable on DPF inner walls, diesel engine systems having a regenerative DPF with prolonged life, and a method for inhibiting accumulation of components depositing on the DPF in the system. The present composition is for diesel engines having a regenerative DPF and running on diesel fuel with <10 mass ppm sulfur, contains a base oil and additives including (A) metal detergent, (B) ashless dispersant, and (C) phosphorus-based anti-wear agent, and satisfies the conditions of a sulfated ash content of 0.4-2 mass %, an atomic ratio of metal from component (A) to the total phosphorus of 0.2-3, an atomic ratio of the total boron to metal from component (A) of 0.2-2, and an atomic ratio of the total sulfur to metal from component (A) of 0-4.
    Type: Application
    Filed: February 19, 2010
    Publication date: June 17, 2010
    Applicants: NIPPON OIL CORPORATION, JAPAN PETROLEUM ENERGY CENTER
    Inventors: Isao KURIHARA, Mineo Kagaya
  • Publication number: 20090233822
    Abstract: The present disclosure provides a fluid for lubricating the clutch-only portion of a wet clutch in a dual clutch transmission. The fluid provides high dynamic friction durability and comprises an oil of lubricating viscosity formulated with additive components comprising: i) at least one metal detergent; ii) at least one phosphorus-based wear preventative; iii) a phosphorylated and boronated dispersant different than the at least one phosphorus-based wear preventative; iv) a sulfurized extreme pressure agent; and a ratio between the content (ppm) of the sulfur based on the total weight of the fluid composition and a content (ppm) of phosphorus based on the total weight of the fluid composition ranging from about 2.0 to about 0.5 (ppm/ppm).
    Type: Application
    Filed: February 17, 2009
    Publication date: September 17, 2009
    Applicant: AFTON CHEMICAL CORPORATION
    Inventor: Ramnath N. Iyer
  • Patent number: 6444622
    Abstract: Mixtures of the reaction product of at least one C5-C60 carboxylic acid and at least one amine selected from the group consisting of guanidine, aminoguanidine, urea, thioruea and salts thereof and a phosphorus-containing dispersant are useful as gear oil additives. Lubricant formulations containing said mixtures exhibit excellent low and high temperature rheology and are particularly suited for use in automotive and industrial gear applications. Lubricants of the present invention exhibit improved performance properties such as increased axle efficiencies and lower axle temperatures compared to lubricant formulations that do not contain said mixtures.
    Type: Grant
    Filed: September 11, 2001
    Date of Patent: September 3, 2002
    Assignee: Ethyl Corporation
    Inventor: Vasudevan Balasubramaniam
  • Publication number: 20020119895
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) an antiwear improving amount of at least one molybdenum containing composition, and (B) at least one member selected from the group consisting of (i) at least one borated overbased metal salt of an acidic organic compound, provided that (A) and (Bi) are not the same, (ii) a combination of (a) at least one organic polysulfide or at least one ashless dithiocarbamate containing composition and (b) at least one component selected from the group consisting of a metal thiophosphate, a phosphoric acid ester or salt thereof, a phosphorus-containing carboxylic acid, ester, ether, or amide, a borated dispersant, an alkali metal borate, a borated fatty amine, a borated phospholipid, a borate ester, and mixtures thereof, and (iii) a combination of (i) and (ii).
    Type: Application
    Filed: May 26, 1995
    Publication date: August 29, 2002
    Inventors: SUSAN P. COOK, JAMES J. SCHWIND, BERNARD CONSTANS, HENRI BOURGOGNON
  • Publication number: 20020055440
    Abstract: Mixtures of the reaction product of at least one C5-C60 carboxylic acid and at least one amine selected from the group consisting of guanidine, aminoguanidine, urea, thioruea and salts thereof and a phosphorus-containing dispersant are useful as gear oil additives. Lubricant formulations containing said mixtures exhibit excellent low and high temperature rheology and are particularly suited for use in automotive and industrial gear applications. Lubricants of the present invention exhibit improved performance properties such as increased axle efficiencies and lower axle temperatures compared to lubricant formulations that do not contain said mixtures.
    Type: Application
    Filed: September 11, 2001
    Publication date: May 9, 2002
    Inventor: Vasudevan Balasubramaniam
  • Publication number: 20010044387
    Abstract: An engine oil composition characterized by containing a major amount of lubricating base oil and (a) 0.01 to 30% by weight of an overbasic oil-soluble metal salt prepared by use of an alkaline-earth metal borate, (b) 0.01 to 5% by weight of a molybdenum dithiocarbamate, and (c) 0.01 to 5% by weight of an antioxidant as essential components, on the basis of the total amount of the composition.
    Type: Application
    Filed: January 30, 2001
    Publication date: November 22, 2001
    Applicant: Nippon Mitsubishi Oil Corporation
    Inventors: Kiyoshi Inoue, Jinichi Igarashi, Mituaki Ishimaru, Mineo Kagaya, Masakuni Hirata
  • Patent number: 6228818
    Abstract: A borate ester represented by one of the following formulae: wherein each R1 is independently hydrocarbyl, a hydrocarbyloxy or a hydrocarbylthio group or both R1 on the same phosphorus atom taken together form a heterocyclic group; each X1 and X2 is independently an oxygen or sulfur; and each R2 is independently a hydrocarbylene group. These reaction products are useful as lubricant additives for oil-based and water-based functional fluids. These materials act as anti-wear, extreme pressure and friction modifying agents.
    Type: Grant
    Filed: June 3, 1993
    Date of Patent: May 8, 2001
    Assignee: The Lubrizol Corporation
    Inventors: James J. Schwind, S. Q. Abbas Rizvi, Stephen A. DiBiase
  • Patent number: 5843873
    Abstract: Lubricants containing a compound of the structureR.sub.1 R.sub.2 N--C(X')S--(CR.sub.3 R.sub.4).sub.a Ywhere X' is an oxygen or sulfur atom and Y is, e.g., an activating group; also containing a phosphorus acid or ester of the formula (R.sub.6 X)(R.sub.7 X)P(X).sub.n X.sub.m R.sub.8 or an amine salt thereof; and also a surfactant, exhibit good antiwear properties. They are particularly useful in pressure transmitting applications such as tractor hydraulic fluids.
    Type: Grant
    Filed: June 24, 1997
    Date of Patent: December 1, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Betsy J. Butke, Craig D. Tipton, Reed H. Walsh
  • Patent number: 5817605
    Abstract: Oil-based functional fluid compositions formulated for use as automatic transmission fluid, fluid for a wet brake system, or a friction-depending lubricant are improved by including in the composition a minor amount of at least one alcohol or polyol having less than 12 carbon atoms in the molecule. This results in a desirable increase in the dynamic and/or static coefficients of friction of automatic transmission or other frictional surfaces contacted by the composition. Preferred for this use is a composition formed by heating at least one ashless dispersant containing basic nitrogen and/or at least one hydroxyl group with a combination of at least (i) an inorganic acid of phosphorus, (ii) a boron compound, and (iii) a polyol having less than 12 carbon atoms, so that a liquid composition is formed. The boron compound and the inorganic phosphorus acid are preferably co-present during the heating.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: October 6, 1998
    Assignee: Ethyl Petroleum Additives, Inc.
    Inventor: Andrew G. Papay
  • Patent number: 5698498
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) a minor amount of at least one hydroxyalkyl dithiocarbamate or at least one borate thereof, wherein the dithiocarbamate is derived from an amine other than an alkyl or alkenylsuccinimide. In another aspect the invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, a hydroxyalkyl dithiocarbamate or a borate thereof, and (B) at least one sulfur compound or (C) at least one phosphorus or boron antiwear or extreme pressure agent. The invention also relates to greases, functional fluids and aqueous fluids containing the hydroxyalkyl dithiocarbamates and borates thereof. The lubricants and fluids have improved antiwear and extreme pressure properties including providing improved antiscuff protection.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: December 16, 1997
    Assignee: The Lubrizol Corporation
    Inventors: Carmen V. Luciani, Syed Q. A. Rizvi, Bernard C. Roell, Jr.
  • Patent number: 5595961
    Abstract: Grease compositions, wherein the grease is thickened with a metal hydroxy-containing soap grease thickener are provided. Other essential ingredients of the compositions include borated hydroxyhydrocarbyl esters and phosphorus and/or sulfur compounds.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 21, 1997
    Assignee: Mobil Oil Corporation
    Inventors: John P. Doner, Andrew G. Horodysky, John A. Keller, Jr.