Oxygen And Nitrogen Bonded Directly To The Same Carbon Atom Or Carbon Chain (e.g., Borated Alkanolamines, Etc.) Patents (Class 508/195)
  • Patent number: 11674106
    Abstract: The disclosed technology relates to lubricants for compression ignition internal combustion engines, particularly those demonstrating at least one of improved seals performance, reduced deposit formation, and excellent durability. The present invention provides a low zinc lubricating composition comprising (a) an oil of lubricating viscosity, (b) a borated dispersant, and (c) a metal-free organo-phosphorus anti-wear additive, wherein the lubricating composition is substantially free of a metal containing sulfur coupled alkyl phenol compound. Further, the low zinc lubricating composition contains zinc in an amount less than 600 ppm by weight of the composition.
    Type: Grant
    Filed: July 17, 2018
    Date of Patent: June 13, 2023
    Assignee: The Lubrizol Corporation
    Inventors: Joanne L. Jones, Mark C. Davies, Michael R. Sutton, Patrick E. Mosier
  • Patent number: 11111457
    Abstract: Disclosed is a lubricating oil composition capable of inhibiting vibrations or noises generated between a pulley and a chain or between a pulley and a belt in a CVT or the like, while increasing an intermetallic friction coefficient, the composition containing a base oil, an alkaline earth metal-based detergent (A), a phosphite ester (B1), a phosphate ester amine salt (B2), an acidic phosphate ester (B3), an aliphatic monoamine (C1), and an aromatic monoamine (C2).
    Type: Grant
    Filed: March 2, 2020
    Date of Patent: September 7, 2021
    Assignee: IDEMITSU KOSAN CO., LTD.
    Inventor: Toshiaki Iwai
  • Publication number: 20140121141
    Abstract: A lubricating oil additive composition comprising the reaction product of a (a) nitrogen-containing reactant, wherein the nitrogen-containing reactant comprises an alkyl alkanolamide, an alkyl alkoxylated alkanolamide, an alkyl alkanolamine, an alkyl alkoxylated alkanolamine or mixtures thereof, and wherein the nitrogen-containing reactant contains less than 10 mass percent of glycerol alkyl ester; (b) a source of boron; and (c) a hydrocarbyl polyol, having at least three hydroxyl groups.
    Type: Application
    Filed: October 30, 2012
    Publication date: May 1, 2014
    Applicant: Chevron Oronite Company LLC
    Inventor: Yat Fan Suen
  • Publication number: 20130150271
    Abstract: Compositions and methods for reducing toolwear during iron-machining, including applying a composition comprising water; a lubricant ester; and a sulfur-containing lubricant additive.
    Type: Application
    Filed: December 10, 2012
    Publication date: June 13, 2013
    Applicant: QUAKER CHEMICAL CORPORATION
    Inventor: Quaker Chemical Corporation
  • Patent number: 7897549
    Abstract: An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.
    Type: Grant
    Filed: March 24, 2008
    Date of Patent: March 1, 2011
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventors: Thomas J. Karol, Steven G. Donnelly
  • Patent number: 7888299
    Abstract: In its broadest concept, the present invention relates to an improved gear oil comprising: a) a base oil having a viscosity range of 4 to 32 cSt at 100° C.; b) a maximum level of hydrocarbyl polysulfide with a minimum level of active S species; c) a dihydrocarbyl dithiophosphate ester or salt; and d) a dihydrocarbyl (mono)thiophosphate amine salt, essentially free of phosphite.
    Type: Grant
    Filed: January 13, 2004
    Date of Patent: February 15, 2011
    Assignee: Afton Chemical Japan Corp.
    Inventors: Jeffrey L. Milner, Masao Seki, Roger M. Sheets, Kenji Yatsunami
  • Patent number: 7851418
    Abstract: The present invention is directed to ashless detergents comprising the products resulting from the reaction of a salicylic acid, organic group substituted salicylic acid, sulfonic acid or organic groups substituted sulfur acid with thiadiazole or organic group substituted thiadiazole or an alkyl primary or secondary amine, and to formulated lubricating oils containing said ashless detergents.
    Type: Grant
    Filed: June 1, 2006
    Date of Patent: December 14, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Jacob Joseph Habeeb, William H. Buck, Douglas Edward Deckman, William L. Maxwell
  • Publication number: 20090291867
    Abstract: Aqueous alkaline metal working fluids and concentrates thereof and processes for their use are disclosed. Processes to reduce the presence of Mycobacteria in a metal working environment are also disclosed.
    Type: Application
    Filed: August 3, 2009
    Publication date: November 26, 2009
    Inventors: Mark J. Fretz, Paul Kutzko
  • Patent number: 7598211
    Abstract: An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: October 6, 2009
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventors: Thomas J. Karol, Steven G. Donnelly
  • Patent number: 7544644
    Abstract: A novel hydroxyalkyldithiocarbamate borate ester compound is presented according to the formula: where R=alkyl C1 to C25; R?=H or CO2R; R?=(CH2)mOH where m=1 to 8, or alkyl C1 to C25; n=1 to 8. The borate ester compound is prepared by reacting boric acid with a novel hydroxyalkyldithiocarbamate ester compound according to the formula, and optionally with an alcohol: where R, R?, R? and n are as above. The hydroxyalkyldithiocarbamate ester is prepared by reacting a hydroxyalkylamine with CS2, and an acrylate or maleate compound. A lubricating composition is based on a major amount of lubricating oil and a minor amount of the hydroxyalkyldithiocarbamate borate ester.
    Type: Grant
    Filed: October 21, 2005
    Date of Patent: June 9, 2009
    Assignee: R.T. Vanderbilt, Inc.
    Inventors: Kevin J. Chase, Ronald Tepper
  • Publication number: 20040147410
    Abstract: In its broadest concept, the present invention relates to an improved gear oil comprising:
    Type: Application
    Filed: January 13, 2004
    Publication date: July 29, 2004
    Inventors: Jeffrey L. Milner, Masao Seki, Roger M. Sheets, Kenji Yatsunami
  • Publication number: 20040138073
    Abstract: An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.
    Type: Application
    Filed: October 2, 2003
    Publication date: July 15, 2004
    Applicant: R.T. Vanderbilt Company, Inc.
    Inventors: Thomas J. Karol, Steven G. Donnelly
  • Patent number: 6660695
    Abstract: A power transmission fluid comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) at least one organic phosphate having the structure R1—X2—P(:X1)(R2X3)—X—R5 where R1, and R2 may independently be substituted or unsubstituted alkyl, aryl, alkylaryl or cycloalkyl having 1 to 24 carbon atoms and X, X1, X2 and X3 may independently be sulfur or oxygen. R1 and R2 may also contain substituent hetero atoms, in addition to carbon and hydrogen, such as chlorine, sulfur, oxygen or nitrogen; wherein R5 is derived from a reactive olefin and can be either CH2—CHR—C(:O)O—R6; —CH2—CR7HR8; or R9—OC(:O)CH2—CH—C(:O)O—R10 where R is H or the same as R1, R6, R7, R9 and R10 are the same as R1 and R8 is a phenyl or alkyl or alkenyl substituted phenyl moiety, the moiety having from 6 to 30 carbon atoms, (b) a calcium detergent, and (c) a friction modifier.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: December 9, 2003
    Assignee: Infineum International Ltd.
    Inventors: Raymond F. Watts, Katherine M. Richard
  • Publication number: 20030181339
    Abstract: An power transmission fluid comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) at least one organic phosphate having the structure: R1—X2—P(:X1)(R2X3)—X—R5 where R1, R2, R3, and R4 may independently be substituted or unsubstituted alkyl, aryl, alkylaryl or cycloalkyl having 1 to 24 carbon atoms and X, X1, X2 and X3 may independently be sulfur or oxygen.
    Type: Application
    Filed: March 15, 2002
    Publication date: September 25, 2003
    Inventors: Raymond F. Watts, Katherine M. Richard
  • Patent number: 6613722
    Abstract: A lubricating composition for lubricating a continuously variable transmission, the lubricating composition comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) at least one organic phosphite; (b) at least one amine salt of an organic phosphate; and (c) one or more friction modifiers selected from the group consisting of selected (1) amides, (2) succinimides, and (3) ethoxylated amines.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: September 2, 2003
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Raymond F. Watts, Philip Reeve
  • Patent number: 6511946
    Abstract: Described is a water-miscible cooling lubricant concentrate which comprises natural or synthetic mineral oils, emulsifying agents, corrosion protection additives, solubilizers, means of preservation, metal inhibitors and other conventional additives, and, after dilution to form a 2 to 25% by weight aqueous solution, has a pH value between 7.0 and 7.5 as well as additionally as means of preservation and/or anticorrosive additive comprises a mixture of a) a conversion product of boric acid and a primary or tertiary alkanolamine and/or b) an ethoxylated and/or propoxylated fatty acid or a fatty acid alkanolamide as well as at least one further compound selected from the group comprised of c) a carboxylic acid imide, a phosphoric acid ester, a triazole, a thiadiazole, an isothiazolinone, an imidazole, a guanidine, an aromatic carboxylic acid and the 3-iodo-2-propinyl-carbamate and/or d) a methylol urea derivative.
    Type: Grant
    Filed: March 12, 2001
    Date of Patent: January 28, 2003
    Assignee: Fuchs Petrolub AG
    Inventors: Heinz Gerhard Theis, Rüdiger Schwab
  • Patent number: 6225266
    Abstract: A zinc-free lubricating composition for lubricating a continuously variable transmission, the lubricating composition comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) an ashless dispersant; (b) at least one organic phosphite; (c) a calcium detergent; (d) one or more friction modifiers selected from the group consisting of: succinimides and ethoxylated amines; and (e) a primary amide of a long chain carboxylic acid.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: May 1, 2001
    Assignee: Infineum USA L.P.
    Inventors: Raymond F. Watts, Katherine M. Richard
  • Patent number: 6103673
    Abstract: A composition comprising of an oil of lubricating viscosity; a shear stable viscosity modifier; at least 0.1 percent by weight of an overbased metal salt; at least 0.1 percent by weight of at least one phosphorus compound; and 0.1 to 0.25 percent by weight of a combination of at least two friction modifiers provides an improved fluid for continuously variable transmissions. At least one of the friction modifiers is selected from the group consisting of zinc salts of fatty acids having at least 10 carbon atoms, hydrocarbyl imidazolines containing at least 12 carbon atoms in the hydrocarbyl group, and borated epoxides. The total amount of the friction modifiers is limited to those amounts which provide a metal-to-metal coefficient of friction of at least about 0.120 as measured at 110.degree. C. by ASTM-G-77.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: August 15, 2000
    Assignee: The Lubrizol Corporation
    Inventors: James L. Sumiejski, William C. Ward, Jr.
  • Patent number: 5759965
    Abstract: This invention relates to a composition, comprising: (A) a boron-containing overbased material; (B) a phosphorus acid, ester or derivative thereof; and (C) a borated epoxide or borated fatty acid ester of glycerol. In one embodiment the inventive composition further comprises (D) a thiocarbamate. These compositions are useful in providing lubricants and functional fluids, particularly automatic transmission fluids, with enhanced antiwear properties. In one embodiment these compositions also provide such lubricants and functional fluids with enhanced extreme-pressure and/or friction-modifying.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: June 2, 1998
    Assignee: The Lubrizol Corporation
    Inventor: James L. Sumiejski
  • Patent number: 5628804
    Abstract: A polyether esteramide reaction product effective as a fuel additive for reducing intake valve deposits and octane requirement increase, as well as controlling combustion chamber deposits, in gasoline engines is disclosed together with fuel compositions and methods of making and using the same. The polyether esteramide reaction product contains two carbonyl groups. Preferably, the polyether esteramide contains an oxalyl group. Also disclosed are compositions and methods for dispersing deposits in lubricating oil products.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: May 13, 1997
    Assignee: Ethyl Corporation
    Inventor: John T. Loper
  • Patent number: 5571445
    Abstract: A "cold-clash" gear problem associated with vehicular manual transmissions exposed to the cold is overcome by use of a special all-synthetic gear oil composition. The composition is composed of base oil and specified additive components. The base oil is a blend of dialkyl ester of an aliphatic dicarboxylic acid having a maximum pour point of about -55.degree. C. and a maximum kinematic viscosity at 100.degree. C. of about 4 cSt, and three hydrogenated poly-.alpha.-olefin oligomers having kinematic viscosities at 100.degree. C. of about 40, about 4-8 cSt and about 2 cSt in specified proportions. The additive components comprise an organic sulfur-containing antiwear and/or extreme pressure agent, an organic phosphorus-containing antiwear and/or extreme pressure agent, a copper corrosion inhibitor, a rust inhibitor, a foam inhibitor, and an ashless dispersant. The gear oil has a boron content of about 0.0025 to about 0.07 wt %.
    Type: Grant
    Filed: September 21, 1995
    Date of Patent: November 5, 1996
    Assignee: Ethyl Corporation
    Inventors: Sanjay Srinivasan, Rolfe J. Hartley
  • Patent number: 5561103
    Abstract: Compositions of matter containing self condensation reaction products of alkylthio alkanols and dispersants which are found to have utility in lubricating/functional fluids.
    Type: Grant
    Filed: September 25, 1995
    Date of Patent: October 1, 1996
    Assignee: The Lubrizol Corporation
    Inventor: Craig D. Tipton
  • Patent number: 5534170
    Abstract: A phosphorous- and sulfur-containing additive and its use to impart anti-wear properties to oleaginous compositions such as fuels and lubricating oils, particularly power transmission compositions, such as automatic transmission fluids, is disclosed. The additive comprises a mixture of products formed, for example, by simultaneously reacting (1) a beta-hydroxy thioether, such as thiobisethanol, (2) a phosphorous-containing reactant, such as triethyl phosphite and (3) optionally, a nucleophilic reactant capable of reacting with the ion ##STR1## to form thioether species. The resulting one or two phase reaction products are supplemented with inorganic phosphorous acids and/or anhydrides to increase the products' total acid number and correspondingly adjust the products' antiwear properties.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: July 9, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Raymond F. Watts