Plural Oxygens Bonded Directly To The Same Saturated Carbon Atom Or Saturated Carbon Chain (e.g., Borated 1,2-glycols, Borated Alkoxylated Alcohols, Etc.) Patents (Class 508/199)
  • Patent number: 11897986
    Abstract: A comb copolymer A2 including at least two boronic ester functions, the copolymer including a main chain and side chains, and at least one portion of the side chains of the copolymer A2 made of oligomers. Also, a composition resulting from mixing at least one polydiol compound A1 and a copolymer A2. The compositions exhibit very varied rheological properties depending on the proportion of the compounds A1 and A2 used. Also, a lubricant composition including such a mixture and at least one lubricating oil. Also, use of this composition to lubricate a mechanical part.
    Type: Grant
    Filed: March 7, 2019
    Date of Patent: February 13, 2024
    Assignees: TOTAL MARKETING SERVICES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, ECOLE SUPERIEURE DE PHYSIQUE ET DE CHIMIE INDUSTRIELLES DE LA VILLE DE PARIS
    Inventors: Grégory Descroix, Fanny Briand, Renaud Nicolay, Thibault Derouineau
  • Patent number: 11840593
    Abstract: Compositions resulting from the mixing of at least: a comb polydiol copolymer A1 and a compound A2 including at least two boronic ester functional groups, the comb polydiol copolymer A1 including a main chain and side chains, at least a portion of the side chains of the copolymer A1 being composed of oligomers. They exhibit very varied rheological properties depending on the proportion of the compounds A1 and A2 used. Composition resulting from the mixing of at least one lubricating oil with such a composition of associative and exchangeable polymers and use of this composition for lubricating a mechanical part.
    Type: Grant
    Filed: March 7, 2019
    Date of Patent: December 12, 2023
    Assignees: TOTAL MARKETING SERVICES, CENTRE NATIONAL DE LA CHERCHE SCENTIFIQUE, ECOLE SUPERIEURE DE PHYSIQUE ET DE CHIMIE INDUSTRIELLES DE LA VILLE DE PARIS
    Inventors: Grégory Descroix, Fanny Briand, Renaud Nicolay, Thibault Derouineau
  • Patent number: 11702611
    Abstract: A composition is obtained by mixing at least one oligomer A1, which is obtained by copolymerizing at least two monomers functionalized by diol functions with at least one second monomer, with at least one compound A2 having at least two boron ester functions. The compositions exhibit very varied rheological properties depending on the proportion of the compounds A1 and A2 used. A composition is also obtained by mixing at least one lubricating oil with such a composition of associative and exchangeable polymers, and the use of this composition to lubricate a mechanical part.
    Type: Grant
    Filed: May 23, 2019
    Date of Patent: July 18, 2023
    Assignee: TOTAL MARKETING SERVICES
    Inventors: Gregory Descroix, Fanny Briand
  • Patent number: 10647939
    Abstract: Provided herein are compositions that include a thiadiazole component and a solubility enhancing component. The solubility enhancing component can include a dispersant, a detergent, or both a dispersant and a detergent. The thiadiazole component can include one or more species having a hydrocarbyl-disulfanyl moiety. The compositions may be used as a corrosion inhibitor. Also provided herein are methods for making a thiadiazole component and a composition.
    Type: Grant
    Filed: November 18, 2016
    Date of Patent: May 12, 2020
    Assignee: International Petroleum Products & Additives Company, Inc.
    Inventors: Xingguo R. Chen, Jeffrey A. Crow, Troy R. Haynes, Jonathan A. Crow, Brian J. Cereghino
  • Patent number: 10501701
    Abstract: The disclosed technology provides a lubricating composition comprising an oil of lubricating viscosity and 0.01 wt % to 10 wt % of an oxyalkylated aromatic polyol compound, wherein the aromatic compound has at least one alkoxy group represented by —OR1 group, R1 is hydroxyalkyl, or a (poly)ether group, and either: at least one hydroxyl group, or at least one alkoxy group represented by OR1 group, where R1 is alkyl, or a (poly)ether group, or at least one oxyalkyl group represented by —OR1, where R1 is hydroxyalkyl or a (poly)ether group. The disclosed technology further relates to a method of lubricating a mechanical device (such as an internal combustion engine) with the lubricating composition. The disclosed technology further relates to the use of the oxyalkylated aromatic polyol compound in the lubricating composition to a passenger car internal combustion engine at least one of (i) control of fuel economy, (ii) control of corrosion, (iii) cleanliness, and (iv) control of bore wear.
    Type: Grant
    Filed: December 3, 2015
    Date of Patent: December 10, 2019
    Assignee: The Lubrizol Corporation
    Inventors: Kamalakumari Kunchithapatham Salem, David J. Moreton, Mohamed G. Fahmy, Gary M. Walker, James P. Roski, Yanshi Zhang, Adam Cox, W. Preston Barnes, Ewan E. Delbridge
  • Patent number: 8846588
    Abstract: Low viscosity functional fluids are described which comprises methoxy polyethylene glycol. The fluids are particularly well-suited for use as DOT 4 brake fluids and provide high ERBP, WERBP, low kinematic viscosity and low SBR volume % increase.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: September 30, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Pearl Crossen, Jin Zhao
  • Patent number: 8507417
    Abstract: Disclosed are sulfur and phosphorous free, borated organomolybdenum compositions containing borated alcohols. These compositions can be formulated with ashless antioxidants and low levels of phosphorous containing antiwear compounds to provide improved lubricating compositions.
    Type: Grant
    Filed: February 23, 2007
    Date of Patent: August 13, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: William H. Buck, Douglas E. Deckman, L. Oscar Farng, Andrew G. Horodsky, Marcia G. Rogers, Thomas J. Karol
  • Publication number: 20130143779
    Abstract: An ionic compound is represented by formula (1): AM(OY1)(OY2)(OY3)(OY4). A is a group 1 element. M is a group 13 element. Y1 is one selected from an oligoalkylene ether group, an oligoalkylene thioether group, and an oligoalkylene amino group and includes an electron donating group on carbon that is located in one of ?-? positions with respect to oxygen atom adjacent to M. Y2, Y3, and Y4 are the same each other or different from each other or cross-linked to each other. Y2, Y3, and Y4 are each any one of an alkyl group, an alkyl group with a fluorinated terminal, an aryl group, and one selected from the group consisting of an oligoalkylene ether group, an oligoalkylene thioether group, and an oligoalkylene amino group and including an electron donating group on carbon that is located in one of ?-? positions with respect to oxygen atom adjacent to M.
    Type: Application
    Filed: September 21, 2011
    Publication date: June 6, 2013
    Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO
    Inventor: Shin-ichi Ogata
  • Publication number: 20110207636
    Abstract: Low viscosity functional fluids are described which comprise glycols and an additive package that includes a fatty acid and a phosphate ester, such as a phosphate ester of an alkyl, alkenyl, or aryl alcohol. The fluids are particularly well-suit for use as DOT 3 or DOT 4 brake fluids and provide robust lubricity and corrosion inhibition.
    Type: Application
    Filed: October 1, 2009
    Publication date: August 25, 2011
    Inventor: Jin Zhao
  • Patent number: 7951757
    Abstract: The fluid compositions of the present invention include an alkoxy glycol component, where the composition includes no more than about 10 wt % of a borate ester based on the weight of the composition. The physical properties of the compositions of include a high dry equilibrium reflux boiling point (ERBP), a high wet equilibrium reflux boiling point (WERBP), and a low temperature viscosity. These compositions are particularly useful because their physical properties (e.g., WERBP, ERBP, and low temperature viscosity) meet or exceed the provisions for DOT 3 brake fluids under the Federal Motor Vehicle Standard No. 116.
    Type: Grant
    Filed: June 29, 2006
    Date of Patent: May 31, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Gregory A. Carpenter, Pearl L. Crossen
  • Patent number: 7875576
    Abstract: Disclosed herein is a lubricating oil composition comprising a) major amount of a base oil of lubricating viscosity; b) from about 0.1 to 10 wt % of an overbased alkaline earth metal alkyl aryl sulfonate detergent having a total base number (TBN) of about 25 to 500; c) from about 0.02 to 10 wt % of a oxymolybdenum-containing complex of a nitrogen-containing compound; d) from about 0.1 to 5 wt % of a friction modifier; and e) from about 0.2 to 10 wt % of an antioxidant selected from the group consisting of a diphenylamine type, a sulfurized ester-containing compound and mixtures thereof; wherein the total concentration of the oxymolybdenum-containing complex and antioxidant must be at least 1.3 wt %, based on the total weight of the lubricating oil composition and wherein the phosphorus content of the total lubricating oil composition is 0.08 wt % or less, based on the total weight of the lubricating oil composition.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: January 25, 2011
    Assignee: Chevron Oronite Company LLC
    Inventor: Alexander B. Boffa
  • Patent number: 7838472
    Abstract: An oil composition for cutting and grinding by minimal quantity lubrication system and for sliding surface according to the present invention comprises an ester and a sulfur compound and/or a phosphorus compound.
    Type: Grant
    Filed: March 26, 2008
    Date of Patent: November 23, 2010
    Assignee: Nippon Oil Corporation
    Inventors: Hideo Yokota, Masanori Ibi, Satoshi Suda
  • Patent number: 7691793
    Abstract: A composition is disclosed that comprises the reaction product of an acidic organic compound and a boron compound. The composition is useful as a detergent additive for lubricants and hydrocarbon fuels.
    Type: Grant
    Filed: May 9, 2005
    Date of Patent: April 6, 2010
    Assignee: Chemtura Corporation
    Inventor: Ronald J. Muir
  • Patent number: 7595286
    Abstract: An oil composition for cutting and grinding by minimal quantity lubrication system and for sliding surface according to the present invention comprises an ester and a sulfur compound and/or a phosphorus compound.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: September 29, 2009
    Assignee: Nippon Oil Corporation
    Inventors: Hideo Yokota, Masanori Ibi, Satoshi Suda
  • Patent number: 7329772
    Abstract: A method of making a hindered phenolic antioxidant is disclosed wherein the method comprises: reacting an ester of the formula: wherein R1, R2, and R3 are independently selected alkyl groups and n is 0, 1, or 2, with an aliphatic polyhydroxyl alcohol of the general formula R(OH)n wherein R is an aliphatic group of from 2 to about 12 carbon atoms and n is an integer of from 2 to 7, provided that one hydroxyl is primary and the others are secondary or tertiary, in the presence of a strong acid catalyst; then, neutralizing the strong acid catalyst with an overbased detergent; and isolating the hindered phenolic antioxidant after the neutralization step.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: February 12, 2008
    Assignee: Crompton Corporation
    Inventor: John R. Baranski
  • Patent number: 6903055
    Abstract: A composition is disclosed which comprises a lubricating oil and a refrigerant, wherein the lubricating oil comprises a polyalkyleneglycol derivative of the formula (I): RX(RaO)x(RbO)y(RcO)zRd, wherein: X?O or S, R is a C3 to C15 substituent comprising a heterocyclic ring, in which the heteroatom(s) in said ring is (are) oxygen and/or sulphur, Ra is a C2 alkylene group, Rb is a C3 alkylene group, Rc is a C4 alkylene group, Rd is the same as R, or is H, a C1-C20 alkyl or a C1-C20 acyl, x, y, z are each independently 0 or an integer of 100 or less, and x+y+z=4 to 100, but excluding compositions where the refrigerant is halogen-free and R contains a carbonate group. The use of borate esters as dehydrogenating agents in conjunction with the above lubricating oils is also disclosed.
    Type: Grant
    Filed: January 23, 2001
    Date of Patent: June 7, 2005
    Assignee: Cognis Performance Chemicals UK Limited
    Inventors: Simon Lawford, John Robert Moxey, Andrew Small
  • Patent number: 6790813
    Abstract: Oil compositions and formulated crankcase engine oils demonstrate improved fuel economy performance when comprising an overbased sulfonate detergent having a total base number greater than about 450 and which contain at least one other additive which includes a succinimide type dispersant. Methods for improving fuel economy employing such high TBN sulfonates and engine oil formulations and concentrates containing such are disclosed.
    Type: Grant
    Filed: November 21, 2002
    Date of Patent: September 14, 2004
    Assignee: Chevron Oronite Company LLC
    Inventor: Alexander B. Boffa
  • Publication number: 20040102336
    Abstract: Oil compositions and formulated crankcase engine oils demonstrate improved fuel economy performance when comprising an overbased sulfonate detergent having a total base number greater than about 450 and which contain at least one other additive which includes a succinimide type dispersant. Methods for improving fuel economy employing such high TBN sulfonates and engine oil formulations and concentrates containing such are disclosed.
    Type: Application
    Filed: November 21, 2002
    Publication date: May 27, 2004
    Applicant: Chevron Oronite Company LLC
    Inventor: Alexander B. Boffa
  • Publication number: 20040077507
    Abstract: Alkoxylated alkylphenols which have at least one long-chain alkyl radical having at least one tertiary or quaternary carbon atom are prepared and are used as fuel or lubricant additives in fuel and lubricant compositions.
    Type: Application
    Filed: July 16, 2003
    Publication date: April 22, 2004
    Inventors: Arno Lange, Hans Peter Rath, Marc Walter
  • Patent number: 6689723
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, at least one organic polysulfide comprising less than about 88% dihydrocarbyl trisulfide, from up to about 5% dihydrocarbyl disulfide, and more than about 7 wt. % dihydrocarbyl higher polysulfides, and at least one phosphorus or boron compound, or mixtures of two or more thereof. The invention also relates to concentrates and greases containing the above combination. The invention also relates to methods of making the organic polysulfide.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: February 10, 2004
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: William T. Sullivan, Percy Rohinton Kanga, Thomas Smith Coolbaugh
  • Publication number: 20030171222
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, at least one organic polysulfide comprising less than about 88% dihydrocarbyl trisulfide, from up to about 5% dihydrocarbyl disulfide, and more than about 7 wt. % dihydrocarbyl higher polysulfides, and at least one phosphorus or boron compound, or mixtures of two or more thereof. The invention also relates to concentrates and greases containing the above combination. The invention also relates to methods of making the organic polysulfide.
    Type: Application
    Filed: March 5, 2002
    Publication date: September 11, 2003
    Inventors: William T. Sullivan, Percy Rohinton Kanga, Thomas Smith Coolbaugh
  • Publication number: 20030166477
    Abstract: This invention relates to a lubricating oil composition, comprising:
    Type: Application
    Filed: February 15, 2002
    Publication date: September 4, 2003
    Applicant: The Lubrizol Corporation
    Inventors: William D. Abraham, Jack C. Kelley, Jonathan S. Vilardo
  • Publication number: 20030153470
    Abstract: A composition is disclosed which comprises a lubricating oil and a refrigerant, wherein the lubricating oil comprises a polyalkyleneglycol derivative of the formula (I): RX(RaO)x(RbO)y(RcO)zRd, wherein: X=O or S, R is a C3 to C15 substituent comprising a heterocyclic ring, in which the heteroatom(s) in said ring is (are) oxygen and/or sulphur, Ra is a C2 alkylene group, Rb is a C3 alkylene group, Rc is a C4 alkylene group, Rd is the same as R, or is H, a C1-C20 alkyl or a C1-C20 acyl, x, y, z are each independently 0 or an integer of 100 or less, and x+y+z=4 to 100, but excluding compositions where the refrigerant is halogen-free and R contains a carbonate group. The use of borate esters as dehydrogenating agents in conjunction with the above lubricating oils is also disclosed.
    Type: Application
    Filed: October 28, 2002
    Publication date: August 14, 2003
    Inventors: Simon Lawford, John Robert Moxey, Andrew Small
  • Patent number: 6593281
    Abstract: To provide a lubricating oil composition for automatic transmission which ensures both a high torque capacity of a wet clutch and a good &mgr;(coefficient of friction)-V (sliding velocity) characteristic in an automatic transmission along with excellent storage stability in a high humidity environment. A lubricating oil composition for automatic transmission is provided, which comprises a lubricating base oil made of a mineral oil and/or a synthetic oil formulated with a friction modifier, a metal detergent and an ashless dispersant, characterized in that said ashless dispersant consists of an succinimide having boron at a rate of three or less atoms in one molecule of the ashless dispersant.
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: July 15, 2003
    Assignee: TonenGeneral Sekiyu K.K.
    Inventors: Takehisa Sato, Takanori Kugimiya
  • Patent number: 6583092
    Abstract: This invention relates to a lubricating oil composition, comprising: (A) a base oil; (B) an alkali or alkaline earth metal salt of a saligenin derivative; (C) an alkali or alkaline earth metal salt of a hydrocarbon-substituted salicylic acid, and (D) a metal salt of a phosphorus-containing compound.
    Type: Grant
    Filed: September 12, 2001
    Date of Patent: June 24, 2003
    Assignee: The Lubrizol Corporation
    Inventors: Virginia A. Carrick, Gordon D. Lamb, Ewa A. Bardasz, William D. Abraham
  • Publication number: 20020187903
    Abstract: To provide a lubricating oil composition for automatic transmission which ensures both a high torque capacity of a wet clutch and a good &mgr;(coefficient of friction)-V (sliding velocity) characteristic in an automatic transmission along with excellent storage stability in a high humidity environment.
    Type: Application
    Filed: June 5, 2001
    Publication date: December 12, 2002
    Inventors: Takehisa Sato, Takanori Kugimiya
  • Patent number: 6277794
    Abstract: A marine diesel engine lubricant composition having a TBN of at least 10 and preferably a VI of at least 90, comprises a major amount of oil of lubricating viscosity, and admixed therewith, minor amounts of an ashless antiwear additive and a metal detergent in the form of (i) an overbased metal detergent having a TBN at least 300, preferably at least 330, more preferably at least 400, and comprising a surfactant system derived from at least two surfactants, and/or (ii) a metal detergent other than (i); provided that, if detergent (ii) is present, the composition does not contain a minor amount of an extreme pressure additive, being up to 5.0 mass % based on the total mass of the composition.
    Type: Grant
    Filed: December 28, 1998
    Date of Patent: August 21, 2001
    Assignee: Infineum USA L.P.
    Inventor: Adrian Dunn
  • Patent number: 6103673
    Abstract: A composition comprising of an oil of lubricating viscosity; a shear stable viscosity modifier; at least 0.1 percent by weight of an overbased metal salt; at least 0.1 percent by weight of at least one phosphorus compound; and 0.1 to 0.25 percent by weight of a combination of at least two friction modifiers provides an improved fluid for continuously variable transmissions. At least one of the friction modifiers is selected from the group consisting of zinc salts of fatty acids having at least 10 carbon atoms, hydrocarbyl imidazolines containing at least 12 carbon atoms in the hydrocarbyl group, and borated epoxides. The total amount of the friction modifiers is limited to those amounts which provide a metal-to-metal coefficient of friction of at least about 0.120 as measured at 110.degree. C. by ASTM-G-77.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: August 15, 2000
    Assignee: The Lubrizol Corporation
    Inventors: James L. Sumiejski, William C. Ward, Jr.
  • Patent number: 5858929
    Abstract: A composition for use in lubricants and function fluids to provide improved anti-shudder and shudder durability properties to an automatic transmission. The composition comprises alkoxylated fatty amines as well as a mixture of other friction modifiers.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: January 12, 1999
    Assignee: The Lubrizol Corporation
    Inventors: James L. Sumiejski, William C. Ward, Mitsuo Higashi, Craig D. Tipton
  • Patent number: 5849675
    Abstract: A hydraulic system containing a piston-type pump having wear surfaces containing copper or a copper alloy, and, optionally, a vane-type pump having wear surfaces containing steel, uses an antiwear hydraulic fluid having an oil of lubricating viscosity and minor amounts of zinc dithiophosphate and a wear moderating agent. The wear moderating agent can be aliphatic polyol esters, boric acid derivatives of aliphatic polyol esters, aliphatic amines, aliphatic polyamines, aliphatic imidazolines, or mixtures of any combination thereof. The aliphatic groups of the wear moderating agent are substantially straight-chained, and the wear moderating agent contains at least ten carbon atoms.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: December 15, 1998
    Assignee: Chevron Chemical Company
    Inventors: Stuart H. Brown, Todd Brookhart
  • Patent number: 5827805
    Abstract: Compositions represented by the structures ##STR1## where Ar represents an aromatic group, each R is independently a hydrocarbyl group, at least one R having more than 12 carbon atoms, a is 1 to 4, and R' is hydrogen or alkyl, are useful as lubricant and fuel additives and as intermediates for the preparation of derivatives useful as such additives.
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: October 27, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Paul E. Adams, Bryan A. Grisso, Mark R. Baker
  • Patent number: 5759965
    Abstract: This invention relates to a composition, comprising: (A) a boron-containing overbased material; (B) a phosphorus acid, ester or derivative thereof; and (C) a borated epoxide or borated fatty acid ester of glycerol. In one embodiment the inventive composition further comprises (D) a thiocarbamate. These compositions are useful in providing lubricants and functional fluids, particularly automatic transmission fluids, with enhanced antiwear properties. In one embodiment these compositions also provide such lubricants and functional fluids with enhanced extreme-pressure and/or friction-modifying.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: June 2, 1998
    Assignee: The Lubrizol Corporation
    Inventor: James L. Sumiejski
  • Patent number: 5629272
    Abstract: An engine oil composition which comprises a metal-containing detergent, zinc dithiophosphate, and a boron-containing ashless dispersant dissolved or dispersed in a base oil; characterized by further containing an antiwear agent having an aliphatic amide compound and either a dithiocarbamate compound or an ester derived from a fatty acid and boric acid.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: May 13, 1997
    Assignee: Oronite Japan Limited
    Inventors: Morikuni Nakazato, Jiro Magarifuchi, Yoshifumi Isozaki
  • Patent number: 5595964
    Abstract: A composition of an oil of lubricating viscosity, an antioxidant, an anti-nitration agent, and optionally a borated product of an epoxide or the reactive equivalent of an epoxide, provides a desirable lubricant for diesel or natural gas-fueled engines. The composition is substantially free from metals and preferably substantially free from phosphorus. The amount of the antioxidant the anti-initration agent are sufficient to reduce the amount of varnish formation in a natural gas engine.
    Type: Grant
    Filed: September 1, 1995
    Date of Patent: January 21, 1997
    Assignee: The Lubrizol Corporation
    Inventor: Ewa A. Bardasz
  • Patent number: 5584945
    Abstract: Disclosed is a lubricant carrier salt for facilitating the cold forming of a workpiece of iron or steel, based on boric acid and/or alkali borate. The salt has an additional content of aliphatic di- or tricarboxylic acid, which either is unsubstituted or substituted by at least one hydroxyl group, and/or of alkali salts thereof, the weight ratio of boric acid/alkali borate to the acid is (5 to 15):1. Especially appropriate carboxylic acids are malonic acid, maleic acid, succinic acid, tartaric acid and/or citric acid.Inorganic or organic thickening agents, such as bentonite and/or polysaccharide, aluminate and/or silicate, dispersants, lubricants and/or antioxidants as well as titanium salt can be contained as additional components in the lubricant carrier salt of the invention.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: December 17, 1996
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Klaus-Dieter Nittel, Norbert Schwinke-Kruse