Nitrogen And Heavy Metal, Or Nitrogen And Aluminum, In The Same Compound Patents (Class 508/362)
  • Patent number: 6962896
    Abstract: Antioxidant additives for lubricating oils are prepared by reacting an acidic molybdenum compound or salt thereof and a basic nitrogen compound where the temperature of the process does not exceed 120° C., resulting in a product color that is light in intensity.
    Type: Grant
    Filed: May 31, 2002
    Date of Patent: November 8, 2005
    Assignee: Chevron Oronite Company LLC
    Inventors: William R. Ruhe, Jr., Anatoli Onopchenko
  • Patent number: 6919300
    Abstract: A protective lubricating composition is provided which will penetrate readily to closely fitting frictional parts and form a protective non-migrating lubricating film improving lubrication between the moving parts reducing friction and wear and preventing corrosion. The lubricant composition may be combined with solvents and propellants to make a sprayable lubricant composition.
    Type: Grant
    Filed: July 2, 2002
    Date of Patent: July 19, 2005
    Assignee: Ashland Inc.
    Inventors: Michael A. Dituro, Richard J. Baumgart, Mandeep S. Saini, Christopher J. Nonevski
  • Patent number: 6914037
    Abstract: The invention relates to an improved process for producing organomolybdenum compositions with high molybdenum content that are highly useful as lubricant additives, in which the process involves reacting a fatty oil with a diamine, followed by reaction with a molybdenum source. The process of the present invention does not require a volatile organic solvent to promote molybdenum incorporation and produces an organomolybdenum composition having a high molybdenum content. In addition, the process can be conducted in the absence of sulfur and phosphorus-containing reactants.
    Type: Grant
    Filed: October 21, 2003
    Date of Patent: July 5, 2005
    Assignee: Ethyl Corporation
    Inventor: Vincent J. Gatto
  • Patent number: 6878676
    Abstract: A lubricant composition is disclosed that comprises: (a) a lubricant and (b) at least one molybdenum-containing compound in the form of surface-capped nanosized particles of the general formula: (Z)n(X—R)m wherein Z is an inorganic moiety comprising molybdenum and sulfur in the form of particles having dimensions in the range of from about 1 to about 100 nm; (X—R) is a surface-capping reagent wherein R is a C4 to C20 straight or branched-chain alkyl or alkylated cycloalkyl radical or radicals and X is a functional group capable of specific sorption and/or chemical interaction with molybdenum/sulfur moiety; n is the number of molecules of Z in the particles; m is an integer representing the amount of surface-capping reagents relative to a single particle; and the ratio of m to n is in the range of from about 1:1 to about 10:1.
    Type: Grant
    Filed: May 8, 2001
    Date of Patent: April 12, 2005
    Assignee: Crompton Corporation
    Inventors: Cyril A. Migdal, Paul E. Stott, Victor N. Bakunin, Oleg P. Parenago, Galina N. Kuz'mina, Ludmila M. Vedeneeva, Andrei Yu Suslov
  • Patent number: 6841521
    Abstract: Disclosed are methods and lubricant compositions for reducing wear in heavy-duty diesel engines. The lubricant compositions disclosed herein comprise a combination of an anti-wear effective amount of a dispersed, hydrated alkali metal borate, a neutral sulfonate and an overbased detergent composition.
    Type: Grant
    Filed: March 7, 2003
    Date of Patent: January 11, 2005
    Assignee: Chevron Oronite Company LLC
    Inventors: Alexander B. Boffa, William M. Kleiser
  • Publication number: 20040224859
    Abstract: A urea grease composition is provided containing a lubricating base oil and from 2 to 30 wt.
    Type: Application
    Filed: December 4, 2003
    Publication date: November 11, 2004
    Inventors: Kouichi Numazawa, Kazushige Ohmura, Takahiro Ozaki, Keiji Tanaka
  • Publication number: 20040214731
    Abstract: Novel organoammonium compounds are provided, which are useful as additives for improving the antiwear and friction-reducing properties of lubricating compositions. The compound is formed by reacting a metal acid hydrate with one or more alkyl amines. Particular examples are the preparation of ditridecylammonium tungstate, di-n-octylammonium tungstate and ditridecylammonium molybdate.
    Type: Application
    Filed: April 8, 2004
    Publication date: October 28, 2004
    Applicant: R.T. Vanderbilt Company, Inc.
    Inventor: Robert J. Tynik
  • Patent number: 6797677
    Abstract: The invention relates to a lubricating oil composition having improved antioxidant properties, and which contains a molybdenum compound and an alkylated phenothiazine. Further, it may also include a secondary diarylamine, preferably an alkylated diphenylamine. This combination of additives provides improved oxidation control and friction modifier performance to the lubricating oil. The composition is particularly suited for use as a crankcase lubricant, or a transmission lubricant, including low levels and zero levels of phosphorus.
    Type: Grant
    Filed: May 30, 2002
    Date of Patent: September 28, 2004
    Assignee: Afton Chemical Corporation
    Inventors: Carl K. Esche, Jr., Vincent J. Gatto
  • Patent number: 6734147
    Abstract: A process is disclosed for manufacturing a lubricant composition comprising combining a superabsorbent polymer with a material for decreasing friction between moving surfaces. The superabsorbent polymer absorbs from about 25 to greater than 100 times its weight in water and may comprise a polymer of acrylic acid, an acrylic ester, acrylonitrile or acrylamide, including co-polymers thereof or starch graft co-polymers thereof or mixtures thereof. A product produced by the process includes the material for decreasing friction comprising a petroleum lubricant containing an additive, water containing an additive, synthetic lubricant, grease, solid lubricant or metal working lubricant, wherein the synthetic lubricant, grease, solid lubricant or metal working lubricant optionally contain an additive. A process comprising controlling the delivery of a lubricant to at least one of two moving surfaces in order to decrease friction between said moving surfaces, is also disclosed.
    Type: Grant
    Filed: October 3, 1997
    Date of Patent: May 11, 2004
    Assignee: LCC County Mosquito Control
    Inventor: Richard Levy
  • Patent number: 6734148
    Abstract: A boron-containing dispersant composition containing one or more dispersants that are the reaction product of a polyalkenyl-substituted mono- or dicarboxylic acid, anhydride or ester; and a polyamine, in which at least one of the dispersants has a polyalkenyl moiety with a number average molecular weight of at least about 1800, and from greater than about 1.3 to about 1.7 mono- or di-carboxylic acid producing moieties per polyalkenyl moiety; and in which a ratio of wt. % of boron to wt. % of nitrogen (B/N) for the dispersant composition is from about 0.05 to about 0.24.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: May 11, 2004
    Assignee: Infineum International Ltd.
    Inventors: Ian A. W. Bell, Jacob Emert, Raymond Fellows, Antonio Gutierrez, Robert Robson
  • Publication number: 20040082486
    Abstract: The invention relates to an improved process for producing organomolybdenum compositions with high molybdenum content that are highly useful as lubricant additives, in which the process involves reacting a fatty oil with a diamine, followed by reaction with a molybdenum source. The process of the present invention does not require a volatile organic solvent to promote molybdenum incorporation and produces an organomolybdenum composition having a high molybdenum content. In addition, the process can be conducted in the absence of sulfur and phosphorus-containing reactants.
    Type: Application
    Filed: October 21, 2003
    Publication date: April 29, 2004
    Applicant: Ethyl Corporation
    Inventor: Vincent J. Gatto
  • Publication number: 20040023819
    Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorus content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a complex of a molybdenum/nitrogen containing compound and at least one phosphorus-containing compound wherein the total phosphorus employed in the composition is no more than about 0.06 weight percent based on the total weight of the composition.
    Type: Application
    Filed: August 1, 2002
    Publication date: February 5, 2004
    Inventor: Alexander B. Boffa
  • Publication number: 20030224949
    Abstract: Antioxidant additives for lubricating oils are prepared by reacting an acidic molybdenum compound or salt thereof and a basic nitrogen compound where the temperature of the process does not exceed 120° C., resulting in a product color that is light in intensity.
    Type: Application
    Filed: May 31, 2002
    Publication date: December 4, 2003
    Inventors: William R. Ruhe, Anatoli Onopchenko
  • Publication number: 20030224950
    Abstract: The invention relates to a lubricating oil composition having improved antioxidant properties, and which contains a molybdenum compound and an alkylated phenothiazine. Further, it may also include a secondary diarylamine, preferably an alkylated diphenylamine. This combination of additives provides improved oxidation control and friction modifier performance to the lubricating oil. The composition is particularly suited for use as a crankcase lubricant, or a transmission lubricant, including low levels and zero levels of phosphorus.
    Type: Application
    Filed: May 30, 2002
    Publication date: December 4, 2003
    Inventors: Carl K. Esche, Vincent J. Gatto
  • Patent number: 6645921
    Abstract: The invention relates to an improved process for producing organomolybdenum compositions with high molybdenum content that are highly useful as lubricant additives, in which the process involves reacting a fatty oil with a diamine, followed by reaction with a molybdenum source. The process of the present invention does not require a volatile organic solvent to promote molybdenum incorporation and produces an organomolybdenum composition having a high molybdenum content. In addition, the process can be conducted in the absence of sulfur and phosphorus-containing reactants.
    Type: Grant
    Filed: February 8, 2002
    Date of Patent: November 11, 2003
    Assignee: Ethyl Corporation
    Inventor: Vincent J. Gatto
  • Publication number: 20030171226
    Abstract: The invention relates to an improved process for producing organomolybdenum compositions with high molybdenum content that are highly useful as lubricant additives, in which the process involves reacting a fatty oil with a diamine, followed by reaction with a molybdenum source. The process of the present invention does not require a volatile organic solvent to promote molybdenum incorporation and produces an organomolybdenum composition having a high molybdenum content. In addition, the process can be conducted in the absence of sulfur and phosphorus-containing reactants.
    Type: Application
    Filed: February 8, 2002
    Publication date: September 11, 2003
    Applicant: Ethyl Corporation
    Inventor: Vincent J. Gatto
  • Publication number: 20030166477
    Abstract: This invention relates to a lubricating oil composition, comprising:
    Type: Application
    Filed: February 15, 2002
    Publication date: September 4, 2003
    Applicant: The Lubrizol Corporation
    Inventors: William D. Abraham, Jack C. Kelley, Jonathan S. Vilardo
  • Publication number: 20030148897
    Abstract: A boron-containing dispersant composition containing one or more dispersants that are the reaction product of a polyalkenyl-substituted mono- or dicarboxylic acid, anhydride or ester; and a polyamine, in which at least one of the dispersants has a polyalkenyl moiety with a number average molecular weight of at least about 1800, and from greater than about 1.3 to about 1.7 mono- or di-carboxylic acid producing moieties per polyalkenyl moiety; and in which a ratio of wt. % of boron to wt. % of nitrogen (B/N) for the dispersant composition is from about 0.05 to about 0.24.
    Type: Application
    Filed: December 6, 2001
    Publication date: August 7, 2003
    Inventors: Ian A. W. Bell, Jacob Emert, Raymond Fellows, Antonio Gutierrez, Robert Robson
  • Publication number: 20030148898
    Abstract: A dispersant that is a reaction product of a polyalkenyl-substituted mono- or dicarboxylic acid, anhydride or ester; and a polyamine, wherein the reaction product has from greater than about 1.3 to less than about 1.7 mono- or di-carboxylic acid producing moieties per polyalkenyl moiety, and the polyalkenyl moiety has a number average molecular weight of at least about 1800, and a molecular weight distribution (Mw/Mn) of from about 1.5 to about 2.0.
    Type: Application
    Filed: December 6, 2001
    Publication date: August 7, 2003
    Inventors: Ian A. W. Bell, Jacob Emert, Raymond Fellows, Antonio Gutierrez, Robert Robson
  • Patent number: 6528463
    Abstract: Organic molybdenum complexes comprising the reaction products of a long-chain mono carboxylic acid, a mono-alkylated alkylene diamine, glycerides, and a molybdenum source and their use as multifunctional additives for lubricating compositions.
    Type: Grant
    Filed: March 23, 2000
    Date of Patent: March 4, 2003
    Assignee: Ethyl Corporation
    Inventors: Vincent James Gatto, Carl A. Mike, John T. Loper
  • Patent number: 6509303
    Abstract: Organic molybdenum complexes comprising the reaction products of fatty oils, a mono-alkylated alkylene diamine, and a molybdenum source and their use as multifunctional additives for lubricating compositions.
    Type: Grant
    Filed: March 23, 2000
    Date of Patent: January 21, 2003
    Assignee: Ethyl Corporation
    Inventor: Vincent James Gatto
  • Publication number: 20020123435
    Abstract: Lubricants are taught that can quickly and easily form a lubricating layer on a metal surface of a metal before plastic processing. Such lubricants preferably include a primary lubricating agent or component having a bridge complex that satisfies the following conditions: (1) the complex contains at least two central metal atoms; (2) at least one first multidentate ligand forms a bridge between two central metal atoms; and (3) at least one second multidentate ligand is bound to at least one central metal atom and has at least one coordinating atom that can coordinate with metal atoms, but which is not coordinated with any of the central metal atoms or is only partially coordinated with at least one of those central metal atoms. A third multidentate ligand is preferably also bound to one of the central metal atoms and may preferably include at least two sulfur atoms that are coordinated to the central metal atom.
    Type: Application
    Filed: November 15, 2001
    Publication date: September 5, 2002
    Applicant: MEC International Corporation
    Inventors: Heijiro Ojima, Fumio Kawahara, Mitsuru Tomono
  • Publication number: 20020119895
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) an antiwear improving amount of at least one molybdenum containing composition, and (B) at least one member selected from the group consisting of (i) at least one borated overbased metal salt of an acidic organic compound, provided that (A) and (Bi) are not the same, (ii) a combination of (a) at least one organic polysulfide or at least one ashless dithiocarbamate containing composition and (b) at least one component selected from the group consisting of a metal thiophosphate, a phosphoric acid ester or salt thereof, a phosphorus-containing carboxylic acid, ester, ether, or amide, a borated dispersant, an alkali metal borate, a borated fatty amine, a borated phospholipid, a borate ester, and mixtures thereof, and (iii) a combination of (i) and (ii).
    Type: Application
    Filed: May 26, 1995
    Publication date: August 29, 2002
    Inventors: SUSAN P. COOK, JAMES J. SCHWIND, BERNARD CONSTANS, HENRI BOURGOGNON
  • Patent number: 6403538
    Abstract: Grease composition for constant velocity joints comprising a base oil and urea-based thickener, which grease further comprises, (A) from 0.1 to 10% by weight of an optionally substituted molybdenum-organocyclic compound containing at least 5 ring atoms, wherein each ring atom attached directly to the molybdenum atom is a hetero atom, (B) from 0.1 to 5% by weight of at least one sulphur-containing additive chosen from the group consisting of sulphur olefins, sulphur-phosphorus extreme-pressure agents, ashless dithiocarbamates, polysulphides, thiadiazoles and zinc dithiocarbamate, and (C) from 0.1 to 5% by weight of at least one phosphorous-containing additive chosen from the group consisting of molybdenum dithiophosphate, zinc dithiophosphate and triphenylphosphorothionate; a method of lubricating a constant velocity joint comprising packing it with said grease and a constant velocity joint packed with said grease.
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: June 11, 2002
    Assignee: Shell Oil Company
    Inventors: Takahiro Ozaki, Tsutomu Yoshida, Ryuichi Masumori
  • Patent number: 6329327
    Abstract: A lubricating composition containing an organic molybdenum compound having excellent oxidation stability that provides lubricity for long periods of time is provided. The lubricant comprises a molybdenum amine compound obtained by reacting a compound containing a hexavalent molybdenum atom with an amine represented by the following formula (1): wherein each of R1 to R3 represents a hydrogen atom and/or a hydrocarbon group, and at least one of R1 to R3 is a chain hydrocarbon group having 14 or more carbon atoms; or the following formula (2) wherein R4 represents a chain hydrocarbon group having 10 or more carbon atoms, s represents 0 or 1, X and/or Y represents a hydrogen atom, a hydrocarbon group, an alkanol group or an alkyl amino group having 2 to 4 carbon atoms, and X and Y are not hydrogen atoms or hydrocarbon groups at the same time when s is 0. A lubricating composition containing the lubricant is also provided.
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: December 11, 2001
    Assignee: Asahi Denka Kogyo, K.K.
    Inventors: Noriyoshi Tanaka, Aritoshi Fukushima, Kazuhisa Morita, Atsuo Miyashita, Kazuhiro Umehara, Yoko Saito
  • Patent number: 6103674
    Abstract: A lubricating oil additive is disclosed that comprises the reaction product of:(a) an unsaturated or saturated ester or acid,(b) a diamine of the formula: ##STR1## (c) carbon disulfide, and (d) a molybdenum compound,wherein R.sub.8 is an alkyl group of 1 to 40 carbon atoms, R.sub.9 and R.sub.10 are independently selected aliphatic or aromatic moieties, W is oxygen, sulfur, or --CH.sub.2 --. The additive imparts friction modification and beneficial antiwear, extreme pressure, and oxidation stability properties to the lubricating oil.
    Type: Grant
    Filed: March 15, 1999
    Date of Patent: August 15, 2000
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Theodore E. Nalesnik, Cyril A. Migdal
  • Patent number: 5837657
    Abstract: The present invention is directed to a method for improving the performance of a sooted diesel oil and controlling soot induced viscosity increase by adding to a major amount of a diesel oil a minor amount of a composition comprising at least one compound having the formula Mo.sub.3 S.sub.k L.sub.n Q.sub.z and mixtures thereof wherein the L are independently selected ligands having organo groups with a sufficient number of carbon atoms to render the compound soluble or dispersible in the oil, n is from 1 to 4, k varies from 4 through 10, Q is selected from the group of neutral electron donating compounds such as water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5 and includes nonstoichiometric values.
    Type: Grant
    Filed: December 2, 1997
    Date of Patent: November 17, 1998
    Inventors: Howard L. Fang, Jonathan M. McConnachie, Edward Ira Stiefel
  • Patent number: 5830577
    Abstract: The lubricant layer according to the present invention is used in a thin film magnetic recording medium in which a solid surface sliding at a high speed is required to retain its lubricating performance and abrasion resistance for a long period of time, comprising a host-guest complex composed of a lubricant molecule as a guest molecule and a multidentate ligand as a host compound to form the complex with the guest molecule.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: November 3, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Hideki Murayama, Keiichiro Sano, Kazuhiko Sawada, Fumiaki Yokoyama, Haruhiko Ikeuchi, Yutaka Teranishi
  • Patent number: 5821374
    Abstract: A process for oxidizing primary and secondary alcohols to the corresponding aldehydes and ketones is disclosed. The oxidation is carried out by reacting the primary or secondary alcohol with an organic N-chloro compound oxidizing agent in the presence of a catalyst of the formula: ##STR1## wherein the substituent groups are as defined in the specification.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: October 13, 1998
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Christian-Johannes Jenny, Bruno Lohri, Markus Schlageter
  • Patent number: 5811378
    Abstract: A composition of matter suitable for use as a dispersant-viscosity improver for lubricating oil compositions comprises the reaction product of reactants comprising(a) a hydrocarbon polymer grafted with an .alpha.,.beta.-ethylenically unsaturated carboxylic acid or functional derivative thereof, and(b) at least one nitrogen and metal containing derivative of a hydrocarbon substituted polycarboxylic acid or functional derivative thereof; and optionally(c) at least one hydroxyl-containing polyester containing at least one condensable free hydroxyl group.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: September 22, 1998
    Assignee: The Lubrizol Corporation
    Inventor: Richard M. Lange
  • Patent number: 5628804
    Abstract: A polyether esteramide reaction product effective as a fuel additive for reducing intake valve deposits and octane requirement increase, as well as controlling combustion chamber deposits, in gasoline engines is disclosed together with fuel compositions and methods of making and using the same. The polyether esteramide reaction product contains two carbonyl groups. Preferably, the polyether esteramide contains an oxalyl group. Also disclosed are compositions and methods for dispersing deposits in lubricating oil products.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: May 13, 1997
    Assignee: Ethyl Corporation
    Inventor: John T. Loper