With Organic Nitrogen Compound Patents (Class 508/375)
  • Patent number: 11485927
    Abstract: A lubricating oil composition includes at least one base oil selected from the group consisting of a mineral oil-based lubricating oil, a synthetic oil-based lubricating oil, and a mixed oil thereof, zinc dialkyldithiophosphate X represented by Formula (1), and an acid phosphate ester amine salt Y represented by Formula (2), in which a content PX of the X is from 0.06% by mass to 0.08% by mass in terms of phosphorus concentration with respect to a total mass of the lubricating oil composition, and a content PY of the Y is from 0.015% by mass to 0.025% by mass in terms of phosphorus concentration with respect to the total mass of the lubricating oil composition.
    Type: Grant
    Filed: November 28, 2018
    Date of Patent: November 1, 2022
    Assignee: Cosmo Oil Lubricants Co., Ltd.
    Inventors: Takuma Saito, Koichi Sakamoto, Naoki Asami, Atsushi Akamatsu
  • Patent number: 9783756
    Abstract: A lubricant composition comprising an oil of lubricating viscosity and an N-hydrocarbyl-substituted ?-aminoester or ?-aminothioester, wherein the N-hydrocarbyl substituent comprises a hydrocarbyl group of at least 3 carbons atoms, with a branch at the 1 or 2 position of the hydrocarbyl chain, provides exhibits basicity and good seal performance.
    Type: Grant
    Filed: October 28, 2013
    Date of Patent: October 10, 2017
    Assignee: The Lubrizol Corporation
    Inventors: Daniel J. Saccomando, Ewan E. Delbridge, Alexandre Roumaneix
  • Publication number: 20150024986
    Abstract: A lubricating oil comprises a major amount of a base oil and a minor amount of an additive package, wherein the additive package comprises one or more friction modifiers including a reaction product of a hydroxy acid represented by HOCH2CO2H and an amine represented by the formula II: wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms; X is oxygen or —NH; and m is an integer from about 1 to about 4. The friction modifiers may include one or more compounds of the Formula I: wherein X is selected from oxygen, —NR1, and a glycolic amide moiety; and R and each R1 are independently selected from linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl having about 8 to about 22 carbon atoms and one but not both of R and R1 can be hydrogen; and m is an integer from about 1 to about 4. Methods of improving thin film and/or boundary layer friction are also provided.
    Type: Application
    Filed: July 18, 2013
    Publication date: January 22, 2015
    Inventor: John T. Loper
  • Publication number: 20140038870
    Abstract: A sump-lubricated, spark-ignited engine is lubricated by supplying thereto a lubricant which comprises (a) an oil of lubricating viscosity; (b) a polyether; and (c) a metal-containing detergent. The lubricant has a total phosphorus content of less than 0.075 percent by weight.
    Type: Application
    Filed: January 11, 2012
    Publication date: February 6, 2014
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Patrick E. Mosier, Jonathan S. Vilardo
  • Publication number: 20130281336
    Abstract: This invention relates to N-alkylated anthranilic acid derivative and their use in lubricants, such as engine oils, as TBN boosters. The invention particularly relates to compositions that deliver an ash-free base to a lubricant in the form of a basic amine additive, without adversely impacting seal compatibility and/or degradation, and methods thereof.
    Type: Application
    Filed: September 15, 2011
    Publication date: October 24, 2013
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Danielle N. Ivancic, Patrick E. Mosier, Ewan E. Delbridge, Christopher L. Friend
  • Patent number: 8367591
    Abstract: Provided is a lubricating oil composition of an environmental regulation compliant type, comprising (A) a base oil for a lubricating oil, (B) sulfated oxymolybdenum dithiocarbamate, (C) an acid amide compound, (D) (d1) a fatty acid partial ester compound and/or (d2) an aliphatic amine compound and (E) a specific benzotriazole derivative, wherein a content of the component (B) is 0.02 to 0.1% by mass in terms of molybdenum; a content of the component (C) is 0.2 to 1.0 % by mass; a content of the component (D) is 0.2 to 1.0% by mass; and a content of the component (E) is 0.02 to 0.1% by mass each based on the whole amount of the composition, and it has an excellent friction reducing effect in combination with a high corrosion preventing effect to copper and lead.
    Type: Grant
    Filed: October 19, 2007
    Date of Patent: February 5, 2013
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Hideki Kamano
  • Patent number: 8227389
    Abstract: A lubricant additive produced by various processes, including mixing an organophosphate and an organofluorine compound, reacting an organophosphate and an organofluorine compound, reacting a fluorinated organophosphate and an organofluorine compound (with or without molybendum disulfide), or reacting an organophosphate, a metal halide and an organofluorine compound (with or without molybendum disulfide), to produce a reaction mixture comprising the lubricant additive. Also, a lubricant produced by various processes, including mixing an organophosphate and an organofluorine compound, reacting an organophosphate and an organofluorine compound, reacting a fluorinated organophosphate and an organofluorine compound (with or without molybendum disulfide), or reacting an organophosphate, a metal halide and an organofluorine compound (with or without molybendum disulfide), and adding at least a portion of the reaction mixture to a lubricant base.
    Type: Grant
    Filed: October 11, 2007
    Date of Patent: July 24, 2012
    Inventors: Pranesh B. Aswath, Harold Shaub, Ramoun Mourhatch, Krupal Patel, David P. Owen, Ronald L. Elsenbaumer
  • Patent number: 8222191
    Abstract: The present invention relates to a lubricating composition containing an oil of lubricating viscosity, a metal containing antiwear agent and a metal containing dispersant. The invention further provides for a method for lubricating a hydraulic system.
    Type: Grant
    Filed: November 18, 2010
    Date of Patent: July 17, 2012
    Assignee: The Lubrizol Corporation
    Inventor: Allan Barber
  • Patent number: 7960319
    Abstract: A lubricating oil composition favorably employable for trunk piston diesel engines contains an overbased sulfurized alkylphenol calcium salt, at least two (preferably three) overbased alkylsalicylic acid calcium salts having different base ratios and hydrocarbyl groups of different carbon atom numbers, a borated ashless dispersant, and a zinc dihydrocarbyldithiophosphate.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: June 14, 2011
    Assignee: Chevron Japan Ltd.
    Inventor: Hiroyuki Nagamatsu
  • Patent number: 7956021
    Abstract: A lubricating oil composition comprising a base oil of lubricating viscosity having a kinematic viscosity of 22 to 300 mm2/s at 40° C. and dissolved or dispersed therein the following additives in the following amounts based on a total amount of the lubricating oil composition: (1) an overbased sulfurized alkylphenol calcium salt detergent in an amount of 0.5 to 1.0 wt. % in terms of calcium content, (2) an overbased calcium alkylbenzenesulfonate detergent in an amount of 1.5 to 2.1 wt. % in terms of calcium content, (3) a nitrogen-containing ashless dispersant in an amount of 0.005 to 0.1 wt. % in terms of nitrogen content, and (4) a zinc dihydrocarbyldithiophosphate in an amount of 0.007 to 0.1 wt.
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: June 7, 2011
    Assignee: Chevron Japan Ltd.
    Inventor: Hiroyuki Nagamatsu
  • Patent number: 7906470
    Abstract: A quaternary ammonium salt detergent made from the reaction product of the reaction of: (a) Mannich reaction product having a tertiary amino group, said Mannich reaction product being prepared from the reaction of a hydrocarbyl-substituted phenol, an aldehyde, and amine; and (b) a quaternizing agent suitable for converting the tertiary amino group to a quaternary nitrogen and the use of such quaternary ammonium salt detergents in a fuel composition to reduce intake valve deposits.
    Type: Grant
    Filed: September 1, 2006
    Date of Patent: March 15, 2011
    Assignee: The Lubrizol Corporation
    Inventors: Paul R. Stevenson, Dean Thetford, Jonathan S. Vilardo
  • Patent number: 7897549
    Abstract: An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.
    Type: Grant
    Filed: March 24, 2008
    Date of Patent: March 1, 2011
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventors: Thomas J. Karol, Steven G. Donnelly
  • Patent number: 7875577
    Abstract: A lubricating oil composition comprising a base oil of lubricating viscosity having a kinematic viscosity of 22 to 300 mm2/s at 40° C. and dissolved or dispersed therein the following additives in the following amounts based on a total amount of the lubricating oil composition: (1) an overbased sulfurized alkylphenol calcium salt detergent in an amount of 0.1 to 1.6 wt. % in terms of calcium content, (2) an overbased calcium alkylbenzenesulfonate detergent in an amount of 0.6 to 2.1 wt. % in terms of calcium content, (3) a nitrogen-containing ashless dispersant in an amount of 0.005 to 0.1 wt. % in terms of nitrogen content, and (4) a zinc dihydrocarbyldithiophosphate in an amount of 0.01 to 0.1 wt.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: January 25, 2011
    Assignee: Chevron Japan Ltd.
    Inventor: Hiroyuki Nagamatsu
  • Patent number: 7790659
    Abstract: Disclosed are lubricating oil compositions excellent in friction reducing effect and long drain properties and particularly suitable for internal combustion engines, which comprise a lubricating base oil, a specific phosphorus compound in an amount of 0.005 to 0.5 percent by mass in terms of phosphorus based on the total mass of the composition, and at least one additive selected from the group consisting of (C) metallic detergents, (D) ashless dispersants, and (E) anti-oxidants, and further contains (F) a sulfur-containing organic molybdenum complex and (G) an ashless friction modifier and which satisfy prescribed requirements and have a sulfated ash content not exceeding a specified level.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: September 7, 2010
    Assignee: Nippon Oil Corporation
    Inventors: Kazuhiro Yagishita, Akira Yaguchi
  • Patent number: 7732385
    Abstract: Disclosed are lubricating oil additives obtained by dissolving or reacting (A) a metal salt of a specific phosphorus compound which is insoluble or less soluble in lubricating oils in or with (B) an amine compound so as to be solved in the lubricating oils; a lubricating oil composition containing such an additive; a method of producing the additive and composition.
    Type: Grant
    Filed: December 22, 2004
    Date of Patent: June 8, 2010
    Assignee: Nippon Oil Corporation
    Inventor: Kazuhiro Yagishita
  • Patent number: 7683017
    Abstract: Disclosed is a lubricating oil composition containing an oil of lubricating viscosity and a particularly effective mixture of a nitro-substituted diphenylamine and a diarylamine which together provide superior oxidation inhibition.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: March 23, 2010
    Assignee: Chevron Oronite Company LLC
    Inventors: Richard E. Cherpeck, Carrie Y. Chan
  • Patent number: 7543445
    Abstract: Methods for regenerating or improving the regeneration of a particulate filter and for improving the performance of a particulate filter during the operation of an internal combustion engine comprise lubricating the engine with a lubricant composition comprising additives that when combusted can form an ash deposit in the filter. The methods are particularly useful for diesel particulate filters on diesel engines that are equipped with an exhaust gas recirculation system.
    Type: Grant
    Filed: October 19, 2004
    Date of Patent: June 9, 2009
    Assignee: The Lubrizol Corporation
    Inventor: Ewa Bardasz
  • Publication number: 20080052985
    Abstract: A quaternary ammonium salt detergent made from the reaction product of the reaction of: (a) Mannich reaction product having a tertiary amino group, said Mannich reaction product being prepared from the reaction of a hydrocarbyl-substituted phenol, an aldehyde, and amine; and (b) a quaternizing agent suitable for converting the tertiary amino group to a quaternary nitrogen and the use of such quaternary ammonium salt detergents in a fuel composition to reduce intake valve deposits.
    Type: Application
    Filed: September 1, 2006
    Publication date: March 6, 2008
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Paul R. Stevenson, Dean Thetford, Jonathan S. Vilardo
  • Patent number: 7183241
    Abstract: A lubricating oil with very low phosphorus content, and having long life as evidenced by a reduction in viscosity increase, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents, at least a zinc dialkyldithiocarbamate and a zinc dialkyldithiophosphate antiwear additive and at least a dihydrocarbylthiocarbamoyl.
    Type: Grant
    Filed: September 19, 2003
    Date of Patent: February 27, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: Stanley James Cartwright
  • Publication number: 20040259742
    Abstract: The use in a cooled exhaust gas recirculation (EGR) engine of an olefin copolymer dispersant viscosity index improver to reduce or eliminate oil thickening and sludge formation is provided. Also provided are lubricated cooled EGR engines with ability to pass rigorous oil viscosity and emission standards.
    Type: Application
    Filed: June 18, 2003
    Publication date: December 23, 2004
    Inventors: Munmaya K. Mishra, David A. Venhaus, Charles A. Passut
  • Publication number: 20040242435
    Abstract: A machine tool is used for machining a workpiece in the presence of a cutting oil composition. The machine tool includes a tool base and a hard carbon coating formed on the tool base. The hard carbon coating has 1 atomic % or less of hydrogen. The cutting oil composition contains a base oil and at least one of an ashless fatty-ester friction modifier and an ashless aliphatic-amine friction modifier.
    Type: Application
    Filed: May 28, 2004
    Publication date: December 2, 2004
    Applicant: NISSAN MOTOR CO., LTD.
    Inventors: Kimio Nishimura, Yutaka Mabuchi, Tomohiro Kondo
  • Publication number: 20040198615
    Abstract: A lubricating composition containing the reaction product (a) of an aldehyde, amine and a di-secondary alkyl hindered phenol and at least one additive selected from the group consisting of hydrocarbyl diphenylamines, sterically hindered phenols other than component (a), metal hydrocarbyl dithiophosphates, sulphurised olefins and mixtures thereof. The composition has antioxidant properties for internal combustion engines without the bioaccumulation of tris-tert-butyl phenol.
    Type: Application
    Filed: April 4, 2003
    Publication date: October 7, 2004
    Applicant: The Lubrizol Corporation
    Inventors: Christopher L. Friend, Douglas M. Barr, Jolanta Z. Adamczewska
  • Patent number: 6777378
    Abstract: This invention relates to a lubricating oil composition, comprising: (A) a base oil; (B) a molybdenum and sulfur containing composition derived from a basic nitrogen containing compound, a molybdenum compound and carbon disulfide; (C) a boron-containing compound; and (D) optionally a phosphorus containing compound, provided the phosphorus content of the lubricating oil composition does not exceed about 0.10% by weight.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: August 17, 2004
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, Jack C. Kelley, Jonathan S. Vilardo
  • Patent number: 6774092
    Abstract: Disclosed is an additive composition that can be mixed with various types of basic oils to produce a lubricant that can meet the international standards of manual truck gearbox oils. A preferred embodiment includes various quantities of an isobutylene sulfide, zinc dialklydithiophosate and other components. Component properties of the additive composition are selected to produce a lubricant that has good thermal stability, rust-resisting and endurance qualities and that has a low cost of use and production.
    Type: Grant
    Filed: August 16, 2002
    Date of Patent: August 10, 2004
    Assignee: PetroChina Company, Ltd.
    Inventors: Xisheng Fu, Xiuling Hua
  • Patent number: 6767871
    Abstract: The lubricating oil of the present invention has a viscosity suitable for use in a diesel engine and includes at least one functionalized olefin polymer, and at least one zinc dialkyl dithiophosphate (ZDDP). The ZDDP is made from a mixture of primary alcohols or a mixture of primary and secondary alcohols, wherein the lubricant has a high boundary film value greater than or equal to 15, and preferably greater than 60, as measured by using a High Frequency Reciprocating Rig (HFRR).
    Type: Grant
    Filed: August 21, 2002
    Date of Patent: July 27, 2004
    Assignee: Ethyl Corporation
    Inventors: Mark Thomas Devlin, Charles A. Passut, Carl K. Esche, Jr., John T. Loper
  • Patent number: 6750184
    Abstract: The present invention relates to improved lubricant compositions highly resistant to oxidative degradation comprising selected 5-tert.-butyl-4hydroxy-3-methylphenyl substituted fatty acid esters, diphenylamines and zinc dithiophosphates. The compositions as defined above are characterized by superior antioxidative properties. This can be demonstrated in various standard tests such as Deposit and Oxidation Panel Test (DOPT) and Pressurized Differential Scanning Calorimetry (PDSC).
    Type: Grant
    Filed: September 19, 2001
    Date of Patent: June 15, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Marc Ribeaud, Paul Dubs, Serge Laemlin
  • Publication number: 20040106527
    Abstract: This invention relates to a lubricating oil composition used in conjunction with a gasoline fuel having a sulphur content of less than 10 ppm by weight, characterised in that said oil composition has a phosphorus content of no more than 0.05% by weight. The feature of the invention is that the use of a low sulphur fuel enables the amount of anti-wear agents containing phosphorus such as eg ZDDP to be halved without any adverse effect on the anti-wear performance of the lubricating oil.
    Type: Application
    Filed: July 25, 2003
    Publication date: June 3, 2004
    Inventors: Stuart Pace, Medi Mostafa Hafez, Maria-Laura Kosidowski, Robert Barbour, Alan Mark Schilowitz
  • Patent number: 6734149
    Abstract: A composition comprising a compound of formula I: wherein W represents O, S—A2, or two groups, R3 and R4; bonds a and b are single or double bonds, provided that one of a and b is a single bond and the other is a double bond; c is a single or double bond, and d is a single bond, double bond, or two single bonds, provided that d is a single bond when c is a double bond, d is not a single bond when c is a single bond, and W is R3 and R4 when d is two single bonds; A1, A2, B1 and B2 are independently hydrogen, alkyl, alkenyl, aralkyl or one of the groups depicted in Scheme 1: and a dithiophosphate.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: May 11, 2004
    Assignee: Rohm and Haas Company
    Inventor: Ravindranath Mukkamala
  • Patent number: 6720293
    Abstract: A low viscosity lubricating oil composition having a CCS viscosity less than 3500 mPa.s at −25° C. and having no more than 0.16 mass % of phosphorus which comprises a dispersant, and a detergent of calcium or magnesium or both; and optionally a zinc dihydrocarbyldithiophosphate, a viscosity modifier, a pour point depressant and an antioxidant. The oil satisfies the Cummins M11 cross-head wear engine test specification in a low phosphorus and low viscosity formulation.
    Type: Grant
    Filed: September 24, 2001
    Date of Patent: April 13, 2004
    Assignee: Infineum International Ltd.
    Inventors: Charles H. Bovington, Christopher J. Locke, Terence Kelly
  • Publication number: 20040038836
    Abstract: The lubricating oil of the present invention has a viscosity suitable for use in a diesel engine and includes at least one functionalized olefin polymer, and at least one zinc dialkyl dithiophosphate (ZDDP). The ZDDP is made from a mixture of primary alcohols or a mixture of primary and secondary alcohols, wherein the lubricant has a high boundary film value greater than or equal to 15, and preferably greater than 60, as measured by using a High Frequency Reciprocating Rig (HFRR).
    Type: Application
    Filed: August 21, 2002
    Publication date: February 26, 2004
    Inventors: Mark Thomas Devlin, Charles A. Passut, Carl K. Esche, John T. Loper
  • Patent number: 6696393
    Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorus content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a complex of a molybdenum/nitrogen containing compound and at least one phosphorus-containing compound wherein the total phosphorus employed in the composition is no more than about 0.06 weight percent based on the total weight of the composition.
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: February 24, 2004
    Assignee: Chevron Oronite Company LLC
    Inventor: Alexander B. Boffa
  • Publication number: 20030216266
    Abstract: A lubricating oil composition employable in combination with a low sulfur content fuel oil is preferably composed of a base oil having a sulfur content of at most 0.2 wt. %, an ashless dispersant comprising an alkenyl- or alkyl-succinimide or a derivative thereof, a metal-containing detergent containing an organic acid metal salt, a zinc dialkyldithiophosphate, a zinc dialkylaryldithiophosphate, and an oxidation inhibitor selected from the group consisting of a phenol compound, an amine compound, and a molybdenum-containing compound, wherein a ratio of the phosphorus content of the zinc dialkyldithiophosphate to the phosphorus content of the zinc dialkylaryldithiophosphate is in the range of 20:1 to 2:1.
    Type: Application
    Filed: May 6, 2003
    Publication date: November 20, 2003
    Inventors: Satoshi Hirano, Shigeru Iwamoto, Morikuni Nakazato
  • Patent number: 6649575
    Abstract: A low-phosphorus lubricant comprises: an oil of lubricating viscosity; a nitrogen-containing and a nitrogen-free dispersant; a metal dihydrocarbyl dithiophosphate; and a hydrocarbyl-substituted carboxylic acid derivative, the ratio of the dispersants being such as to provide suitable fluoroelastomer seal compatibility.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: November 18, 2003
    Assignee: Infineum International Ltd.
    Inventor: Robert Robson
  • Publication number: 20030166477
    Abstract: This invention relates to a lubricating oil composition, comprising:
    Type: Application
    Filed: February 15, 2002
    Publication date: September 4, 2003
    Applicant: The Lubrizol Corporation
    Inventors: William D. Abraham, Jack C. Kelley, Jonathan S. Vilardo
  • Patent number: 6605571
    Abstract: Concentrates for lubricating oil compositions are prepared by blending at elevated temperature: (A) at least one high molecular weight ashless dispersant; and (B) at least one oil-soluble metal detergent; in the presence of (C) at least one metal salt of a dihydrocarbylphosphorodithoic acid wherein the metal of the metal salt is an alkali metal, an alkaline earth metal, or zinc, aluminium, lead, tin, molybdenum, manganese, nickel or copper.
    Type: Grant
    Filed: April 2, 1999
    Date of Patent: August 12, 2003
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Gary Higton, Roger Glyde, Robert A. Wilkinson
  • Publication number: 20030134754
    Abstract: A composition comprising: a high-sulfur API Group I mineral oil base stock; a molybdenum dithiocarbamate in an amount suitable to provide 50 to about 600 ppm molybdenum to the composition; a succinimide dispersant based on a polyolefin-substituted succinic structure, where the polyolefin has a number average molecular weight of at least 1500; a zinc dialkyldithiophosphate derived from at least one secondary alcohol; and a hindered phenol, alkylated aromatic amine, or sulfurized olefin oxidation inhibitor, is capable of passing a Sequence III test.
    Type: Application
    Filed: March 6, 2002
    Publication date: July 17, 2003
    Applicant: The Lubrizol Corporation
    Inventor: Jack C. Kelley
  • Patent number: 6569818
    Abstract: A lubricating oil composition having a low P content of 0.01 to 0.1 wt. %, and a sulfated ash of 0.1 to 1 wt. %, which is composed of a) a major amount of mineral base oil having a low S content of at most 0.1 wt. %; b) an ashless alkenyl or alkyl-succinimide dispersant; c) a metal-containing detergent (non-sulfurized alkali metal or alkaline earth metal salt of an alkylsalicylic acid and/or non-sulfurized alkali metal or alkaline earth metal salt of an alkylphenol derivative having a Mannich base structure); d) Zn-DTP; e) an oxidation inhibitor (phenol compound and/or amine compound) and wherein the sulfur content is 0.01 to 0.3 wt %. The lubricating oil composition shows good high temperature detergency notwithstanding its low S, P, and sulfated ash content, and is favorably employable in diesel engines using fuel of an extremely low sulfur content.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: May 27, 2003
    Assignee: Chevron Oronite Company, LLC
    Inventors: Morikuni Nakazato, Shigeru Iwamoto, Satoshi Hirano
  • Patent number: 6559105
    Abstract: A composition of an antioxidant of the formula where R3 is an alkyl group of 2 to 6 carbon atoms, and a dispersant or a detergent, is a useful additive package for lubricant compositions.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: May 6, 2003
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, Paul E. Adams, Gordon D. Lamb, Thomas J. Wolak, Richard A. Denis, Jody A. Kocsis, James P. Roski, Virginia A. Carrick, Susan V. Cowling
  • Patent number: 6551965
    Abstract: A lubricating oil composition containing a base oil of lubricating viscosity, overbased sulfurized alkylphenate detergent or its calcium salt, an overbased alkylsulfonate detergent or its calcium salt, an ashless dispersant, and a zinc dialkyldithiophosphate and/or zinc diaryidithiophosphate is described. The lubricating oil composition provides improved heat stability and anti-wear performance in marine diesel engines operated under severe conditions where the cylinder liner temperature may reach 200 to 260° C.
    Type: Grant
    Filed: November 14, 2001
    Date of Patent: April 22, 2003
    Assignee: Chevron Oronite Company LLC
    Inventors: Hiroyuki Nagamatsu, Shigeru Iwamoto, Hirokazu Fujita
  • Patent number: 6531428
    Abstract: A low phosphorous lubricating oil composition for internal combustion engines comprising an alkylthiocarbamate compound of the formula: wherein each of R1, R2, R3, and R4 independently represents an alkyl group of 1-18 carbon atoms, and (X) represents S, S—S, S—CH2—S, S—CH2CH2—S, S—CH2CH2CH2—S, or S—CH2CH(CH3)—S, and additive compositions and additive packages utilizing the above compound.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: March 11, 2003
    Assignee: Chevron Oronite Company LLC
    Inventors: Morikuni Nakazato, Jiro Magarifuchi, Akihiro Mochizuki, Hiroshi Tanabe
  • Publication number: 20030045436
    Abstract: Disclosed is an additive composition that can be mixed with various types of basic oils to produce a lubricant that can meet the international standards of manual truck gearbox oils. A preferred embodiment includes various quantities of an isobutylene sulfide, zinc dialklydithiophosate and other components. Component properties of the additive composition are selected to produce a lubricant that has good thermal stability, rust-resisting and endurance qualities and that has a low cost of use and production.
    Type: Application
    Filed: August 16, 2002
    Publication date: March 6, 2003
    Inventors: Xisheng Fu, Xiuling Hua
  • Patent number: 6500786
    Abstract: Lubricating oil compositions exhibititing improved low temperature valve train wear performance with a lowered phosphorus content, which contain a reduced amount of a metal hydrocarbyl dithiophosphate, a molybdenum compound, a metal-free friction modifier and a phosphorus-free antioxidant.
    Type: Grant
    Filed: November 26, 2001
    Date of Patent: December 31, 2002
    Assignee: Infineum International Ltd.
    Inventors: Rolfe J. Hartley, Malcolm Waddoups
  • Patent number: 6482777
    Abstract: This invention relates to a lubricating composition comprising a blend of a major amount of an oil of lubricating viscosity, gear or transmission oil package and a top treatment which comprises at least one saturated fatty phosphate ester or salt, wherein the lubricating composition is free of saturated fatty phosphites. Tin another embodiment, the invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, at least one saturated fatty phosphate ester or salt, at least one polysulfide and at least one phosphorus antiwear or extreme pressure agent, wherein the lubricating composition is free of saturated fatty phosphites. The invention relates to additive combinations which when added to a lubricant can provide and improve frictional and, optionally, thermal stability properties. The additives include a phosphate ester or salt wherein the hydrocarbyl group of the phosphate is a fatty-saturated group.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: November 19, 2002
    Assignee: The Lubrizol Corporation
    Inventor: Robert W. Cain
  • Publication number: 20020137639
    Abstract: Disclosed is a grease sealed bearing for automobile that has the high temperature resistance as well as shear stability, and prevents the noise at low temperature as well as the brittle flaking under high speed rotation and high load. The grease comprises a base oil containing a synthesized hydrocarbon oil and one or more ester oils at a weight ratio of 0.1 to 0.49:0.9 to 0.51; 5 to 30% by weight of a urea based thickener, and 0.1 to 10% by weight of dithiozinc phosphate based on the whole grease. The grease sealed bearing for automobile is obtained by sealing a bearing used in a device driven by an automobile engine with the grease.
    Type: Application
    Filed: January 16, 2002
    Publication date: September 26, 2002
    Inventors: Mitsunari Asao, Hidenobu Mikami, Takayuki Kawamura, Takahiro Koremoto, Kunio Takemura
  • Publication number: 20020107152
    Abstract: A low-phosphorus lubricant comprises:
    Type: Application
    Filed: December 5, 2001
    Publication date: August 8, 2002
    Inventor: Robert Robson
  • Publication number: 20020086802
    Abstract: This invention relates to a lubricating composition comprising a blend of a major amount of an oil of lubricating viscosity, gear or transmission oil package and a top treatment which comprises at least one saturated fatty phosphate ester or salt, wherein the lubricating composition is free of saturated fatty phosphites. Tin another embodiment, the invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, at least one saturated fatty phosphate ester or salt, at least one polysulfide and at least one phosphorus antiwear or extreme pressure agent, wherein the lubricating composition is free of saturated fatty phosphites. The invention relates to additive combinations which when added to a lubricant can provide and improve frictional and, optionally, thermal stability properties. The additives include a phosphate ester or salt wherein the hydrocarbyl group of the phosphate is a fatty-saturated group.
    Type: Application
    Filed: October 19, 1999
    Publication date: July 4, 2002
    Inventor: ROBERT W. CAIN
  • Patent number: 6403538
    Abstract: Grease composition for constant velocity joints comprising a base oil and urea-based thickener, which grease further comprises, (A) from 0.1 to 10% by weight of an optionally substituted molybdenum-organocyclic compound containing at least 5 ring atoms, wherein each ring atom attached directly to the molybdenum atom is a hetero atom, (B) from 0.1 to 5% by weight of at least one sulphur-containing additive chosen from the group consisting of sulphur olefins, sulphur-phosphorus extreme-pressure agents, ashless dithiocarbamates, polysulphides, thiadiazoles and zinc dithiocarbamate, and (C) from 0.1 to 5% by weight of at least one phosphorous-containing additive chosen from the group consisting of molybdenum dithiophosphate, zinc dithiophosphate and triphenylphosphorothionate; a method of lubricating a constant velocity joint comprising packing it with said grease and a constant velocity joint packed with said grease.
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: June 11, 2002
    Assignee: Shell Oil Company
    Inventors: Takahiro Ozaki, Tsutomu Yoshida, Ryuichi Masumori
  • Publication number: 20020065201
    Abstract: The present invention relates to improved lubricant compositions highly resistant to oxidative degradation comprising selected 5-tert. -butyl-4hydroxy-3-methylphenyl substituted fatty acid esters, diphenylamines and zinc dithiophosphates. The compositions as defined above are characterized by superior antioxidative properties. This can be demonstrated in various standard tests such as Deposit and Oxidation Panel Test (DOPT) and Pressurized Differential Scanning Calorimetry (PDSC).
    Type: Application
    Filed: September 19, 2001
    Publication date: May 30, 2002
    Inventors: Marc Ribeaud, Paul Dubs, Serge Laemlin
  • Publication number: 20020058593
    Abstract: A low viscosity lubricating oil composition having a CCS viscosity less than 3500 mPa.s at −25° C. and having no more than 0.16 mass % of phosphorus which comprises a dispersant, and a detergent of calcium or magnesium or both; and optionally a zinc dihydrocarbyldithiophosphate, a viscosity modifier, a pour point depressant and an antioxidant. The oil satisfies the Cummins M11 cross-head wear engine test specification in a low phosphorus and low viscosity formulation.
    Type: Application
    Filed: September 24, 2001
    Publication date: May 16, 2002
    Inventors: Charles H. Bovington, Christopher J. Locke, Terence Kelly
  • Publication number: 20020006878
    Abstract: A composition of an antioxidant of the formula 1
    Type: Application
    Filed: January 16, 2001
    Publication date: January 17, 2002
    Applicant: Lubrizol Corporation
    Inventors: William D. Abraham, Paul E. Adams, Gordon D. Lamb, Thomas J. Wolak, Richard A. Denis, Jody A. Kocsis, James P. Roski, Virginia A. Carrick, Susan V. Cowling