The Heavy Metal Is Molybdenum, A Rare Earth Metal, Gold, Silver, Or Mercury Patents (Class 508/379)
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Patent number: 11753599Abstract: The present disclosure relates to methods for improving phosphorus retention and improving antiwear performance in an internal combustion engine of a hybrid vehicle, comprising lubricating the internal combustion engine of the hybrid vehicle with a lubricating oil composition comprising: greater than 50 wt. % of a base oil of lubricating viscosity; and an amount of one or more zinc dialkyl dithiophosphate compound(s) sufficient to provide: from about 100 ppmw phosphorus to about 1000 ppmw phosphorus, based on a total weight of the lubricating oil composition; and from about 10 ppmw zinc to about 1200 ppmw zinc, based on the total weight of the lubricating oil composition.Type: GrantFiled: May 6, 2022Date of Patent: September 12, 2023Assignee: AFTON CHEMICAL CORPORATIONInventors: Huifang Shao, Mark Devlin, Paul Ransom, Guillaume Carpentier
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Patent number: 11155766Abstract: A grease composition comprises a thickener, a base oil, and a friction modifier. The friction modifier comprises: at least one selected from the group consisting of fatty acids, fatty acid metal salts, phosphate esters, thiophosphate esters, and zinc dithiophosphates; and a polyhydric alcohol ester.Type: GrantFiled: July 26, 2017Date of Patent: October 26, 2021Assignee: KYODO YUSHI CO., LTD.Inventors: Ryosuke Saito, Yuta Sato, Iwaki Hirooka
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Publication number: 20140309150Abstract: A lubricant composition and a method of lubricating off-road vehicles and/or machinery. The lubricant composition includes (i) a base oil, (ii) at least one ashless component (A) having the structure P(?S)(SR1)(OR2)(OR3), wherein R1, R2 and R3 are independently selected form the group consisting of alkyl, aryl, alkylaryl, cycloalkyl, alcohol, carboxylic acid and ester having 1 to 24 carbon atoms; and (iii) at least one component (B) being a metal dialkyl dithio phosphate salt. The total of ashless components (A) provides to the lubricant composition from 0.010 to 0.080 wt. % phosphorus based on the total weight of the lubricant composition and the total of components (B) provides to the lubricant composition from 0.010 to 0.080 wt. % phosphorus based on the total weight of the lubricant composition.Type: ApplicationFiled: April 11, 2013Publication date: October 16, 2014Applicant: Afton Chemical CorporationInventor: Jonathan W. BENDER
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Patent number: 8664442Abstract: A dialkylanilino-cyclohexane compound useful as an antioxidant has the following formula I or formula II: wherein Ar1 and Ar2 can be the same or different and each is an alkylaromatic group; each of R1, R2, R3, and R4 is independently selected from hydrogen or CR7R8; each of R5, R6, and R7 is independently selected from hydrogen and a substituted or unsubstituted C1 to C32 hydrocarbyl group; and each R8 is independently selected from hydrogen and a C1 to C2 alkyl group, provided that when, each of R1 and R2 is CR7R8 and each such R8 is other than hydrogen, R1 and R2 may be joined to form a five or six-membered ring, and provided further that when, each of R3 and R4 is an adjacent CR7R8 and each such R8 is other than hydrogen, R3 and R4 may be joined to form a five or six-membered ring.Type: GrantFiled: September 9, 2008Date of Patent: March 4, 2014Assignee: Chemtura CorporationInventor: Theodore E. Nalesnik
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Publication number: 20140045733Abstract: The grease composition for a clean environment includes, a base oil, a thickener and a extreme-pressure agent, in which a kinetic viscosity of the base oil at 40° C. is 100˜300 mm2/s, the thickener comprising a lithium complex soap, a content of the thickener is 10˜40 mass % with respect to the total amount of the grease composition.Type: ApplicationFiled: April 11, 2012Publication date: February 13, 2014Applicants: IDEMITSU KOSAN CO., LTD., THK CO., LTD.Inventors: Akira Nogami, Terumoto Hayami, Hiroshi Sampei, Yukitoshi Fujinami, Kouji Takane
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Publication number: 20130244915Abstract: Combining a metal based friction modifier, such as a molybdenum dialkyldithiocarbamate, and certain esters of hydroxy carboxylic acids, such as short chain alkyl esters of citric or tartaric acid, e.g., tributyl citrate, has a synergistic effect on lowering the friction coefficient of lubricating oils allowing one to reduce the amount of metal based friction modifier needed to adequately formulate a lubricant with low friction characteristics.Type: ApplicationFiled: February 28, 2013Publication date: September 19, 2013Applicant: Chemtura CorporationInventors: Frank J. DeBlase, Venkatramanan K. Madabusi, Susan Ferrarotti, Faith Gaenzler, Cyril A. Migdal, Gerard Mulqueen
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Patent number: 8293689Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and polymer with pendant groups. The invention further provides for a method of controlling viscosity index by supplying to an oil of lubricating viscosity the polymer with pendant groups.Type: GrantFiled: May 7, 2007Date of Patent: October 23, 2012Assignee: The Lubrizol CorporationInventors: Bryan A. Grisso, Mark R. Baker, Daniel C. Visger, Marina Baum, Barton J. Schober, Calvin A. James
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Publication number: 20120258897Abstract: The present invention provides a cylinder lubricating oil composition for a crosshead-type diesel engine, which is improved in oxidation stability and anti-scuffing properties besides the properties of the conventional cylinder lubricating oil composition and comprises a base oil having an aromatic content of 8.5 percent by mass or more and on the basis of the total mass of the composition (A) an alkaline earth metal phenate in an amount of 0.005 mole/kg or more on the basis of phenate soap content, (B) an aminic antioxidant in an amount of 0.1 to 5 percent by mass and (C) an oil-soluble molybdenum compound in an amount of 30 to 500 ppm by mass on the basis of molybdenum and having a base number of 20 to 100 mgKOH/g and a 100° C. kinematic viscosity of 12.6 mm2/s or higher.Type: ApplicationFiled: October 8, 2010Publication date: October 11, 2012Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Shigeki Takeshima, Naozumi Arimoto
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Patent number: 8178478Abstract: An internal combustion engine crankcase lubricating oil composition is disclosed. The crankcase lubricating oil composition has a TBN no greater than 6 and contains the following additives: (B1) a metal detergent system having a metal ratio no greater than 3, as the sole detergent system; (B2) an organic ashless friction modifier; (B3) an oil-soluble molybdenum friction modifier; and (B4) a metal dihydrocarbyl dithiophosphate.Type: GrantFiled: February 23, 2006Date of Patent: May 15, 2012Assignee: Infineum International LimitedInventors: Brian Lawrence, Christopher Locke
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Publication number: 20120021956Abstract: The invention provides a lubricating composition containing a ?-amino compound. The invention further relates to a method of lubricating an internal combustion engine by lubricating the engine with the lubricating composition. The invention further relates to the use of the ?-amino carbonyl compound as copper corrosion inhibitors, friction control agents, antiwear and/or extreme pressure agents.Type: ApplicationFiled: February 5, 2010Publication date: January 26, 2012Applicant: The Lubrizol CorporationInventors: Matthew D. Gieselman, Jody A. Kocsis
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Patent number: 8101558Abstract: A composition containing an oil of lubricating viscosity in a concentrate-forming or major amount; and, as an additive component, an oil-soluble or oil dispersible mononuclear molybdenum compound having a molybdenum atom having bonded thereto one or more diazenide ligands and one or more hydrocarbyl group-carrying ligands, other than diazenide ligands, the hydrocarbyl groups conferring oil-solubility or oil-dispersibility on the molybdenum compound.Type: GrantFiled: December 1, 2009Date of Patent: January 24, 2012Assignee: Infineum International LimitedInventors: Benjamin R. Elvidge, Aleka Hinni, Jonathan Dilworth
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Patent number: 8093190Abstract: An antioxidant lubricant composition has at least 50 wt % of a lubricating base oil and an oil-soluble metal compound providing between 1 and 2,000 parts per million of metal to the lubricant composition, the metal compound being chosen from the group consisting of molybdenum, tungsten titanium and boron compounds, and an oil-soluble hindered amine providing between about 0.001 and about 2 wt % of oil-soluble hindered amine to the lubricant composition, and optionally, an oil-soluble diarylamine providing between 0.001 and about 2 wt % of oil-soluble diarylamine to the lubricant composition.Type: GrantFiled: December 10, 2010Date of Patent: January 10, 2012Assignee: R.T. Vanderbilt Company, Inc.Inventors: Kevin J. Chase, John M DeMassa, Brian Stunkel, Glenn A. Mazzamaro, Steven G. Donnelly
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Patent number: 8071801Abstract: Provided is a phosphorus molybdenum amine compound, represented by the following general formula (I). where R1 to R6 each independently represent a hydrogen atom or a hydrocarbon group and p represents a number of 1 to 5, provided that all of R1 to R6 are can not all be hydrogen atoms at the same time and the phosphorus molybdenum compound is obtained by reducing a hexavalent molybdenum compound with a reducing agent, and then reacting the resulting with an acidic phosphate after neutralization with a mineral acid.Type: GrantFiled: July 3, 2007Date of Patent: December 6, 2011Assignee: Adeka CorporationInventors: Yukio Tatsumi, Kazuhiro Umehara, Kenji Yamamoto
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Patent number: 8030257Abstract: The present invention is directed to lubricating oils of improved antioxidancy comprising a base oil selected from the group consisting of mineral oils, synthetic oils and mixtures thereof containing an effective amount of one or more organometallic compound and/or coordination complex selected from the group consisting of (a) a metal or metal cation with more than one oxidation state, above the ground state, and two or more anions, (b) a metal or metal cation with more than one oxidation state above the ground state and one or more bidentate or tridentate ligands, (c) a metal or metal cation with more than one oxidation state above the ground slate, and one or more amines and one or more ligands, and (d) mixtures thereof, to a method for improving the antioxidancy of formulated lubricating oil compositions by the addition thereto of an effective amount of the aforementioned organometallic compound, and/or coordination complex, and to an additive concentrate containing the aforementioned organometallic compouType: GrantFiled: May 5, 2006Date of Patent: October 4, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Jacob Joseph Habeeb, Steven Paul Rucker
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Patent number: 8012916Abstract: A lubricating oil additive capable of providing an antioxidant which enables a lubricating oil composition to have long drain intervals, while reducing specific components such as metals and phosphorus atoms, and a lubricating oil composition containing the lubricating oil additive are provided. A phosphorus molybdenum compound represented by the following general formula (1) where R1, R2, and R3 each independently represent a hydrocarbon group having 1 to 20 carbon atoms is also provided.Type: GrantFiled: October 26, 2007Date of Patent: September 6, 2011Assignee: Adeka CorporationInventors: Yukiya Moriizumi, Kazuhiro Umehara, Yukio Tatsumi
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Patent number: 7989406Abstract: An additive to a fuel oil for a Diesel engine having a Diesel particulate filter (DPF), which comprises a molybdenum compound and having the function of improving the combustion property of a particulate matter (PM) trapped with DPF; a fuel oil comprising the additive; a lubricating oil composition for a Diesel engine having DPF, which has a sulfated ash content of 1.0% by weight or smaller, a sulfur content of 0.3% by weight or smaller and a molybdenum content of 100 ppm or greater; and DPF for removing PM in combustion gas discharged from a Diesel engine vehicle by trapping and burning PM, DPF comprising a filter supporting a molybdenum compound. The combustion property of PM trapped with the filter of DPF is improved, PM is burned at a low temperature with stability, the efficiency of removal of PM is improved and the life of DPF is increased.Type: GrantFiled: September 22, 2004Date of Patent: August 2, 2011Assignee: Idemitsu Kosan Co., Ltd.Inventor: Tadashi Katafuchi
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Patent number: 7989407Abstract: The present invention is directed to lubricating oils exhibiting improved resistance to oxidation and deposit/sludge formation comprising a lubricant base oil and an effective amount of a catalytic antioxidant comprising one or more polymetal organometallic compound, to a method for improving the antioxidancy and the resistance to deposit/sludge formation of formulated lubricating oil compositions by the addition thereto of an effective amount of the aforementioned polymetal organometallic compound, and to an additive concentrate containing the aforementioned polymetal organometallic compound.Type: GrantFiled: September 18, 2007Date of Patent: August 2, 2011Assignee: ExxonMobil Research and Engineering CompanyInventors: Jacob J. Habeeb, Steven P. Rucker, Michael E. Landis, Abhimanyu O. Patil
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Patent number: 7875579Abstract: An antioxidant lubricant composition has at least 50 wt % of a lubricating base oil and an oil-soluble metal compound providing between 1 and 2,000 parts per million of metal to the lubricant composition, the metal compound being chosen from the group consisting of molybdenum, tungsten titanium and boron compounds, and an oil-soluble hindered amine providing between about 0.001 and about 2 wt % of oil-soluble hindered amine to the lubricant composition, and optionally, an oil-soluble diarylamine providing between 0.001 and about 2 wt % of oil-soluble diarylamine to the lubricant composition.Type: GrantFiled: March 3, 2008Date of Patent: January 25, 2011Assignee: R.T. Vanderbilt Company, Inc.Inventors: Kevin J. Chase, John M. DeMassa, Brian W. Stunkel, Glenn A. Mazzamaro, Steven G. Donnelly
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Patent number: 7838472Abstract: An oil composition for cutting and grinding by minimal quantity lubrication system and for sliding surface according to the present invention comprises an ester and a sulfur compound and/or a phosphorus compound.Type: GrantFiled: March 26, 2008Date of Patent: November 23, 2010Assignee: Nippon Oil CorporationInventors: Hideo Yokota, Masanori Ibi, Satoshi Suda
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Patent number: 7790659Abstract: Disclosed are lubricating oil compositions excellent in friction reducing effect and long drain properties and particularly suitable for internal combustion engines, which comprise a lubricating base oil, a specific phosphorus compound in an amount of 0.005 to 0.5 percent by mass in terms of phosphorus based on the total mass of the composition, and at least one additive selected from the group consisting of (C) metallic detergents, (D) ashless dispersants, and (E) anti-oxidants, and further contains (F) a sulfur-containing organic molybdenum complex and (G) an ashless friction modifier and which satisfy prescribed requirements and have a sulfated ash content not exceeding a specified level.Type: GrantFiled: December 22, 2004Date of Patent: September 7, 2010Assignee: Nippon Oil CorporationInventors: Kazuhiro Yagishita, Akira Yaguchi
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Publication number: 20100062955Abstract: A dialkylanilino-cyclohexane compound useful as an antioxidant has the following formula I or formula II: wherein Ar1 and Ar2 can be the same or different and each is an alkylaromatic group; each of R1, R2, R3, and R4 is independently selected from hydrogen or CR7R8; each of R5, R6, and R7 is independently selected from hydrogen and a substituted or unsubstituted C1 to C32 hydrocarbyl group; and each R8 is independently selected from hydrogen and a C1 to C2 alkyl group, provided that when, each of R1 and R2 is CR7R8 and each such R8 is other than hydrogen, R1 and R2 may be joined to form a five or six-membered ring, and provided further that when, each of R3 and R4 is an adjacent CR7R8 and each such R8 is other than hydrogen, R3 and R4 may be joined to form a five or six-membered ring.Type: ApplicationFiled: September 9, 2008Publication date: March 11, 2010Inventor: Theodore E. Nalesnik
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Publication number: 20090312210Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and polymer with pendant groups. The invention further provides for a method of controlling viscosity index by supplying to an oil of lubricating viscosity the polymer with pendant groups.Type: ApplicationFiled: May 7, 2007Publication date: December 17, 2009Applicant: The Lubrizol CorporationInventors: Bryan A. Grisso, Mark R. Baker, Daniel C. Visger, Marina Baum, Barton J. Schober, Calvin A. James
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Publication number: 20090247437Abstract: In order to provide for a grease composition reducing or preventing noise, vibration and harshness (NVH) in the driveline, a grease composition for use in constant velocity joints is suggested, comprising a) a base oil composition; b) at least one tri-nuclear molybdenum compound of the formula MO3SkLnQZ, wherein L are independently selected ligands having organo groups with a sufficient number of carbon atoms to render the compound soluble or dispersible in the oil, n is from 1 to 4, k varies from 4 though 7, Q is selected from the group of neutral electron donating compounds such as amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5 and includes non-stoichiometric values. c) at least one further molybdenum containing compound; and d) at least one simple and/or complex soap thickener.Type: ApplicationFiled: April 7, 2009Publication date: October 1, 2009Inventors: Jisheng E., Frank Resher, Leandro Muntada, Stefanie Rosenkranz
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Publication number: 20090247435Abstract: To solve the problem to provide for a new grease composition giving low wear and low friction primarily to constant velocity joints, a grease composition is suggested comprising a) a base oil composition; and b) 0.25% by weight to 5% by weight of at least one tri-nuclear molybdenum corn pound of the formula Mo3SkLnQz wherein L are independently selected ligands having organo groups with a sufficient number of carbon atoms to render the compound soluble or dispersible in the oil, n is from 1 to 4, k varies from 4 though 7, Q is selected from the group of neutral electron donating compounds such as amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5 and includes non-stoichiometric values.Type: ApplicationFiled: April 7, 2009Publication date: October 1, 2009Inventors: Jisheng E, Frank Reher, Stefanie Rosenkranz
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Patent number: 7595286Abstract: An oil composition for cutting and grinding by minimal quantity lubrication system and for sliding surface according to the present invention comprises an ester and a sulfur compound and/or a phosphorus compound.Type: GrantFiled: April 5, 2002Date of Patent: September 29, 2009Assignee: Nippon Oil CorporationInventors: Hideo Yokota, Masanori Ibi, Satoshi Suda
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Publication number: 20080234153Abstract: The present invention provides a lubricating oil composition, which is capable to maintain sufficient low-friction (i.e. fuel saving performance) even when the lubricating oil is contaminated with soot and metal abrasion powder, which is excellent in durability with regard to anti-wear property and detergency, as well as oxidation stability, and which is capable to lower the ash content and to sufficiently maintain the performance of exhaust-gas after-treatment device for a long term. The lubricating oil composition comprises a lubricant base oil containing a base oil (X) of which % CP is 70 or more, % CA is 1 or less, viscosity index is 115 or more, and CCS viscosity at ?35° C. is 3000 mPa·s or less, wherein the lubricant base oil, to total mass of the composition, contains following components (A)˜(D): (A) 0.01˜10 mass % of ashless friction modifier; (B) 0.01˜0.2 mass % of phosphorus-containing anti-wear agent as phosphorous content; (C) 0.01˜1 mass % of metallic detergent as metal content; and (D) 0.01˜0.Type: ApplicationFiled: March 18, 2008Publication date: September 25, 2008Inventor: Shigeki MATSUI
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Publication number: 20080221000Abstract: An antioxidant lubricant composition has at least 50 wt % of a lubricating base oil and an oil-soluble metal compound providing between 1 and 2,000 parts per million of metal to the lubricant composition, the metal compound being chosen from the group consisting of molybdenum, tungsten titanium and boron compounds, and an oil-soluble hindered amine providing between about 0.001 and about 2 wt % of oil-soluble hindered amine to the lubricant composition, and optionally, an oil-soluble diarylamine providing between 0.001 and about 2 wt % of oil-soluble diarylamine to the lubricant composition.Type: ApplicationFiled: March 3, 2008Publication date: September 11, 2008Applicant: R.T. VANDERBILT COMPANY, INC.Inventors: KEVIN J. CHASE, JOHN M. DeMASSA, BRIAN W. STUNKEL, GLENN A. MAZZAMARO, STEVEN G. DONNELLY
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Publication number: 20080176776Abstract: In order to provide for a grease composition which has a good compatibility with boots made of rubber or thermoplastic elastomer, and which also gives low wear and low friction, a grease composition for use in constant velocity joints is suggested, comprising a) a base oil composition; b) at least one tri-nuclear molybdenum compound of the formula Mo3SkLnQz, wherein L are independently selected ligands having organo groups with a sufficient number of carbon atoms to render the compound soluble or dispersible in the oil, n is from 1 to 4, k varies from 4 though 7, Q is selected from the group of neutral electron donating compounds such as amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5 and includes non-stoichiometric values; c) at least one urea derivative thickener.Type: ApplicationFiled: October 8, 2007Publication date: July 24, 2008Applicants: GKN Driveline International GmbH, Kyodo Yushi Co., Ltd.Inventors: Jisheng E., Shinya Kondo, Frank Reher, Akira Taniguchi
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Publication number: 20080119377Abstract: The lubricant compositions of the present disclosure comprises a base oil and an additive composition comprising, for example, a detergent and an additive chosen from a phosphorus-containing compound, a friction modifier, and a dispersant, wherein the additive composition exhibits at least one of reduced thin-film friction and increased fuel efficiency as compared to an additive composition that is devoid of the detergent and the additive. As a further example, the additive composition can comprise a friction modifier and a dispersant, wherein the additive composition exhibits at least one of reduced thin-film friction and increased fuel efficiency as compared to an additive composition that is devoid of the friction modifier and the dispersant. Methods of using the additive and lubricant compositions are also disclosed.Type: ApplicationFiled: November 22, 2006Publication date: May 22, 2008Inventors: Mark T. DEVLIN, Tze-chi Jao
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Publication number: 20080015128Abstract: There is disclosed a lubricating composition comprising a friction modifier and a base oil comprising less than about 3% by weight of tetracycloparaffins. Methods of making and using the composition are also disclosed.Type: ApplicationFiled: July 14, 2006Publication date: January 17, 2008Inventors: Mark T. Devlin, Tze-chi Jao, John T. Loper, Helen T. Ryan, Carl K. Esche
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Publication number: 20080015127Abstract: There is disclosed a lubricating composition having a base oil, a friction modifier, and a dispersant, wherein the lubricating composition has less than about 325 ppm of boron. Methods of making and using the disclosed lubricating composition are also disclosed.Type: ApplicationFiled: July 14, 2006Publication date: January 17, 2008Inventors: John T. Loper, William Y. Lam, Mark T. Devlin
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Publication number: 20080015125Abstract: A lubricant composition comprising a phosphorus-containing compound and a base oil comprising less than about 3% by weight of tetracycloparaffins is disclosed. Methods of making and using the lubricant composition are also disclosed.Type: ApplicationFiled: July 14, 2006Publication date: January 17, 2008Inventors: Mark T. Devlin, Tze-chi Jao, John T. Loper, Roger M. Sheets, Gregory H. Guinther
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Patent number: 7309680Abstract: A process for making an additive comprising one or more oil-soluble or oil-dispersible molybdenum-sulfur compounds, said process comprising the steps of: (I) reacting in a polar medium a reactant molybdenum compound (A) and a source of a ligand (B), which ligand (B) is capable of rendering the or each molybdenum-sulfur compound oil-soluble or oil-dispersible; and (II) reacting a compound (C), which is capable of reacting with labile sulfur, either with (a) the reaction mixture of step (I) after the reaction of (A) and (B) has begun or (b) the product of step (I). The additive has improved color characteristics and a lubricating oil composition comprising said additive is more benign to corrosion of metals.Type: GrantFiled: July 1, 2003Date of Patent: December 18, 2007Assignee: Infineum International LimitedInventors: Joby V. John, Ronald P. Wangner, Antonio Gutierrez, Gregory C. Giffin
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Patent number: 7214648Abstract: An engine lubricant formulated as a complete crankcase motor oil or additive concentrate composed of a combination of chemical constituents including a base oil selected from a synthetic oil, a mineral oil or semi-synthetic base oil (hydrogenated oil) or combination thereof, an oil soluble molybdenum additive, a dispersant inhibitor containing zinc dithiophosphate, and viscosity index improvers and one or more seal swelling agents to lubricate the engine and recondition the seals of new and/or high mileage engines. Addition of a polyalphaolefin and/or one or more esters such as a diester or polyolester may also be utilized therein. The lubricant may be formulated as a complete engine oil crankcase lubricant, or concentrated into an additive for addition to conventional mineral oil based engine oil, synthetic engine oils, or blends thereof in an effective amount of up to 30 percent volume percent, typically from 20 to 25 percent by volume.Type: GrantFiled: July 29, 2002Date of Patent: May 8, 2007Assignee: Ashland Licensing and Intellectual Property, LLCInventors: Mandeep S. Saini, Thomas R. Smith, Michael A. Dituro, Richard J. Baumgart, Frances E. Lockwood
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Patent number: 7176167Abstract: According to the invention, a self contained vibration resistant bearing is provided. The bearing is coated with a film formed from a rust preventive oil having an extreme-pressure additive content of 0.5 to 10% by weight. Desirably the extreme-pressure additive is an organometallic compound, an organofatty acid compound, organofatty acid derivative, an organophosphoric acid compound or a combination of two(2) or more of such compounds. When a rust preventive film that contains an extreme-pressure additive is formed all over bearing components during the assembling process, the bearing components are fully protected even from sudden vibrations from transportation.Type: GrantFiled: May 16, 2003Date of Patent: February 13, 2007Inventors: Motoharu Akiyama, Noriyuki Yoshimura
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Patent number: 7067463Abstract: A pivot assembly bearing used in an information storage device maintains its capabilities for a longer period of time under frequent quick starting and stopping by containing a grease composition made up of a base oil, a thickener and an extreme-pressure agent.Type: GrantFiled: February 12, 2003Date of Patent: June 27, 2006Assignee: Minebea Co., Ltd.Inventor: Motoharu Akiyama
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Patent number: 6958409Abstract: A process for the manufacture of a low sediment overbased metal dithiophosphate composition is disclosed. The process uses delayed addition of a C1 to C5 mono-carboxylic acid promoter during the neutralization of a primary dialkyl dithiophosphoric acid. The process results in reducing crude sediment whereby the resulting overbased metal dithiophosphate may need not undergo additional filtration steps prior to its intended use.Type: GrantFiled: June 15, 2004Date of Patent: October 25, 2005Assignee: Chevron Oronite Company LLCInventor: William R. Ruhe, Jr.
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Patent number: 6953771Abstract: A lubricating oil composition comprising, or made by mixing, a major amount of an oil of lubricating viscosity and a minor amount of at least one compound comprising a polynuclear molybdenum core having bonded thereto one or more monoanionic ligands capable of rendering the compound oil-soluble or oil-dispersible, and further comprising at least one ionic species that is not required to confer oil-solubility or oil-dispersibility to the compound, wherein the combination of said one or more monoanionic ligands and said at least one ionic species confers electrical neutrality to the compound and wherein the ratio of the number of molybdenum atoms in the core to the number of said ligands is greater than 1:1.Type: GrantFiled: January 27, 2003Date of Patent: October 11, 2005Assignee: Infineon International LimitedInventors: Jonathan M. McConnachie, Ian A. W. Bell, Alisdair J. Brown, Edward I. Stiefel, Ernestine W. Hill
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Patent number: 6919300Abstract: A protective lubricating composition is provided which will penetrate readily to closely fitting frictional parts and form a protective non-migrating lubricating film improving lubrication between the moving parts reducing friction and wear and preventing corrosion. The lubricant composition may be combined with solvents and propellants to make a sprayable lubricant composition.Type: GrantFiled: July 2, 2002Date of Patent: July 19, 2005Assignee: Ashland Inc.Inventors: Michael A. Dituro, Richard J. Baumgart, Mandeep S. Saini, Christopher J. Nonevski
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Patent number: 6894009Abstract: A grease composition for constant velocity joints, having a base oil and a urea-based thickener, which grease additionally contains, (A) molybdenum sulphide dialkyldithiocarbamate and (B) 5,5-dithiobis (1,3,4-thiadiazole-2-thiol); a method of lubricating a constant velocity joint including packing it with grease and a constant velocity joint packed with said grease.Type: GrantFiled: February 28, 2001Date of Patent: May 17, 2005Assignee: Shell Oil CompanyInventors: Yasushi Kawamura, Kouichi Nakazawa, Noriaki Shinoda, Keiji Tanaka, Tetsuo Nimura, Kouji Saitou, Tomoyasu Wada
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Patent number: 6890890Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, (A) an antiwear improving amount of at least one molybdenum containing composition, (B) at least one phosphorus antiwear or extreme pressure agent, and (C) at least one dispersant, provided that the lubricating composition is free of polysulfurized olefins. The lubricating compositions have improved antiwear properties. When the lubricating composition is used in a manual transmission, the amount of brass wear is reduced.Type: GrantFiled: August 21, 2003Date of Patent: May 10, 2005Assignee: The Lubrizol CorporationInventor: Michael P. Gahagan
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Patent number: 6852678Abstract: An aqueous lubricant is provided which by simple application onto metal surfaces forms lubricating films required for heavy working of metals, and which contains no oil. The aqueous lubricant is prepared by suspending or dispersing a metal chelate compound in water with a surfactant or the like. The metal chelate compound has a polydentate or multidentate chelate ligand, in which at least one of the coordinating atoms is sulfur, coordinated to the coordination site of at least one metal species selected from among zinc, manganese, iron, molybdenum, tin and antimony. When applied onto metal surfaces, the aqueous lubricant forms effective lubricating films on the metal surfaces. The lubricating films contain sulfur as coordinating atoms and therefore, extreme pressure produces sulfur radicals through decomposition by tribo-chemical reactions. The sulfur radicals are highly reactive and react rapidly with the metal surface to produce metal sulfides with a lubricating effect.Type: GrantFiled: November 19, 2001Date of Patent: February 8, 2005Assignees: MEC International Corporation, Toyota Jidosha Kabushiki KaishaInventors: Heijiro Ojima, Masahiko Takeuchi, Fumio Ikesue, Noritoshi Kaskimura, Fumio Kawahara, Mitsuru Tomono
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Publication number: 20040224859Abstract: A urea grease composition is provided containing a lubricating base oil and from 2 to 30 wt.Type: ApplicationFiled: December 4, 2003Publication date: November 11, 2004Inventors: Kouichi Numazawa, Kazushige Ohmura, Takahiro Ozaki, Keiji Tanaka
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Patent number: 6774092Abstract: Disclosed is an additive composition that can be mixed with various types of basic oils to produce a lubricant that can meet the international standards of manual truck gearbox oils. A preferred embodiment includes various quantities of an isobutylene sulfide, zinc dialklydithiophosate and other components. Component properties of the additive composition are selected to produce a lubricant that has good thermal stability, rust-resisting and endurance qualities and that has a low cost of use and production.Type: GrantFiled: August 16, 2002Date of Patent: August 10, 2004Assignee: PetroChina Company, Ltd.Inventors: Xisheng Fu, Xiuling Hua
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Patent number: 6774091Abstract: A lubricant additive formulation for increasing the performance of conventional engine lubricants for use as an engine treatment oil additive formulated for addition to conventional motor oil to improve the lubricating properties of the engine oil and enhance the performance of the engine. A preferred embodiment of the engine treatment oil additive comprises a blend of chemical constituents including a base stock selected from a synthetic base stock, a mineral oil base stock, and a severely hydrocracked base stock or combinations thereof, an oil soluble molybdenum additive, dispersant inhibitor, and selected additives such as polytetrafluoroethylene, viscosity index improvers, and extreme pressure wear agent used in combination with a conventional crankcase lubricant at about a 20 to about a 25% volume/percent or as a complete motor oil. Additional components may be added to the engine treatment oil additive formulation to enhance specific properties for special applications.Type: GrantFiled: July 26, 2002Date of Patent: August 10, 2004Assignee: Ashland Inc.Inventors: Michael A. Dituro, Richard J. Baumgart, Frances E. Lockwood
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Publication number: 20040138073Abstract: An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.Type: ApplicationFiled: October 2, 2003Publication date: July 15, 2004Applicant: R.T. Vanderbilt Company, Inc.Inventors: Thomas J. Karol, Steven G. Donnelly
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Publication number: 20040132627Abstract: A process for making an additive comprising one or more oil-soluble or oil-dispersible molybdenum-sulfur compounds, said process comprising the steps of:Type: ApplicationFiled: July 1, 2003Publication date: July 8, 2004Inventors: Joby V. John, Ronald P. Wangner, Antonio Gutierrez, Gregory C. Giffin
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Publication number: 20040116309Abstract: An oil composition for cutting and grinding by minimal quantity lubrication system and for sliding surface according to the present invention comprises an ester and a sulfur compound and/or a phosphorus compound.Type: ApplicationFiled: October 3, 2003Publication date: June 17, 2004Inventors: Hideo Yokota, Masanori Ibi, Satoshi Suda
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Patent number: 6730638Abstract: A lubricating composition for internal combustion engines especially useful with fuels having less than 350 ppm sulfur comprises a lubricating oil basestock, a boron containing ashless dispersant, a molybdenum containing friction reducing agent, a metal type detergent and zinc dithiophosphate.Type: GrantFiled: January 24, 2003Date of Patent: May 4, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Liehpao O. Farng, Andrew Jackson, Willie A. Givens, Jr., Douglas E. Deckman, William H. Buck
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Patent number: 6727208Abstract: A lubricating oil composition comprising a major amount of an oil of lubricating viscosity and an additive system comprising (A) from about 0.1 to about 5% by weight of a detergent composition comprising at least two metal overbased compositions wherein said detergent composition consists essentially of (A-1) at least one alkali metal overbased detergent and (A-2) at least one calcium overbased detergent, wherein the ratio of total base number on a per 100 TBN and diluent-free basis contributed by the alkali metal detergent to the total base number contributed by the calcium detergent ranges from about 99.5-20 to about 0.5-80; (B) from about 1 to about 10% by weight of a succinimide dispersant; and (C) from about 0.1 to about 5 % by weight of a metal dihydrocarbyl dithiophosphate of the formula (I) wherein R1 and R2 are each, independently, hydrocarbyl groups containing from 3 to 13 carbon atoms, M is a metal and n is an integer equal to the valence of M.Type: GrantFiled: May 23, 2002Date of Patent: April 27, 2004Assignee: The Lubrizol CorporationInventor: Melody A. Wilk