Plural Carbons Bonded Directly To The Chalcogen Or To A Chain Of Chalcogens Patents (Class 508/431)
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Patent number: 9890462Abstract: The present invention relates to a corrosion-protection system suitable for producing aqueous metal treatment and metal processing fluids, particularly corrosion-protection, cleaning and cooling lubricant emulsions. The corrosion-protection system comprises carbonic and/or phosphonic acids, as well as at least one amine with at least one oxybis(alkylamine) unit. Such corrosion-protection systems effectively protect metal surfaces from corrosion and have a high level of water solubility, which is essential for formulating aqueous concentrates for metal treatment and metal processing fluids. The present invention further relates to an aqueous surface-active and corrosion-protecting preparation containing the corrosion protection system and an emulsifier system, as well as an oil-containing water-miscible emulsion concentrate, which supplies the ready-to-use corrosion-protection, cleaning and cooling lubricant emulsions by dilution with water.Type: GrantFiled: September 22, 2014Date of Patent: February 13, 2018Assignee: Henkel AG & Co. KGaAInventor: Andreas Temme
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Patent number: 8901052Abstract: A transmission oil composition for an automobile characterized in that it contains a base oil selected from the group consisting of a mineral oil, a synthetic oil and mixtures thereof; and a phosphate compound selected from the group consisting of (A) a zinc dithiophosphate having a hydrocarbon group, (B) a triaryl phosphate (C) a triaryl thiophosphate, and mixtures thereof at 0.1 to 15.0% by mass with respect to the total composition; wherein the composition has a volume resistivity of 1×107 ohm·m or more at 80° C.Type: GrantFiled: December 29, 2010Date of Patent: December 2, 2014Assignees: Nissan Motor Co., Ltd., Nippon Oil CorporationInventors: Takumaru Sagawa, Takafumi Ueno, Hisayuki Wada, Tooru Aoki
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Publication number: 20140154457Abstract: Described herein are low add-on fiber lubricant compositions useful in the production of synthetic fibers. The compositions and methods described herein impart or enhance one or more properties of the fibers such as, for example, dry soil resistance, liquid repellency, or a combination thereof. Fibers produced with the lubricant compositions with the compositions described herein and articles comprising the treated fibers are also described herein. These compositions are composed of (a) a lubricant component, (b) a friction modifier, and (c) water.Type: ApplicationFiled: December 4, 2013Publication date: June 5, 2014Applicant: ARROWSTAR LLCInventors: James R. BARTLEY, Vance W. BROWN
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Patent number: 8389450Abstract: The present invention relates to a lubricant concentrate containing the following components (i) at least one amine, (ii) at least one phosphate according to the general formula (I), (iii) at least one acid, (iv) optionally at least one ether carboxylic acid compounds with the general formula (II) R20—(O(CH2)m)nOCH2COO?M+??(II), (v) optionally at least one further aid or additive.Type: GrantFiled: September 22, 2011Date of Patent: March 5, 2013Assignee: Diversey, Inc.Inventors: Holger Theyssen, Mario Stanga, Franco Bruschi, Stefan Wiemer
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Publication number: 20120177915Abstract: Provided by the present invention is a lubricating oil composition showing a very low frictional coefficient when used as a lubricating oil for a low friction sliding material prepared by blending with an additive selected from a specific phosphorus-zinc-containing compound and a specific sulfur-containing compound, and a sliding mechanism having an excellent low frictional property in which a DLC film containing 5 to 50 atom % of hydrogen is formed or a sliding mechanism having an excellent low frictional property in which 1 to 30 atom % of tungsten (W) or molybdenum (Mo) is contained is provided by combining the above lubricating oil composition with a sliding member having a film of a specific low frictional sliding material on a sliding face.Type: ApplicationFiled: September 13, 2010Publication date: July 12, 2012Applicants: NIPPON ITF INC., IDEMITSU KOSAN CO., LTD.Inventors: Moritsugu Kasai, Ryou Yamada, Masanori Tsujioka, Koji Miyake
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Patent number: 8178004Abstract: A composition and method for forming a hydrophobic coating on a metallic substrate are disclosed. The composition comprises: (a) a perfluorinated acid, (b) a surfactant, (c) an organic solvent, and (d) water. The composition is applied to the metal surface, the organic solvent and water permitted to evaporate and coalesce to form a substantially continuous film that preferably is in the form of a self-assembled monolayer covalently bonded to the surface of the substrate.Type: GrantFiled: June 17, 2009Date of Patent: May 15, 2012Assignee: Aculon, Inc.Inventor: Eric L. Hanson
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Patent number: 8119580Abstract: The present invention relates to a lubricant concentrate containing the following components (i) at least one amine, (ii) at least one phosphate according to the general formula (I), (iii) at least one acid, (iv) optionally at least one ether carboxylic acid compounds with the general formula (II) R20—(O(CH2)m)nOCH2COO?M+??(II), (v) optionally at least one further aid or additive.Type: GrantFiled: February 2, 2006Date of Patent: February 21, 2012Assignee: Diversey, Inc.Inventors: Holger Theyssen, Mario Stanga, Franco Bruschi, Stefan Wiemer
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Publication number: 20100286009Abstract: The invention refers to lubricant compositions, said lubricant compositions being particularly preferred for conveyor systems, especially in the foodstuff industry, which are suitable for lubricating, cleaning and disinfecting of the transport chains. More specifically, the invention refers to lubricant compositions for conveyor systems comprising: a) one or more phosphoric acid esters; and b) one or more ether carboxylates; and e) water; and c) one or more C6-C22 fatty acids, optionally ethoxylated with to 20 moles of ethylene oxide; and/or d) one or more C6-C22 fatty alcohols, optionally ethoxylated with 1 to 20 moles of ethylene oxide wherein the weight ratio of component (a) to component (b) is in the range of 9:1 to 1:3. Said lubricant compositions can be used in conveyor systems for glass and/or plastic bottles, such as polyethylen terepthalate (PET) or polycarbonate (PC); cans, glass containers, drums, cardboard containers and similar items.Type: ApplicationFiled: March 28, 2007Publication date: November 11, 2010Applicant: KAO CHEMICALS GMBHInventors: Melanie Vierbaum, Ben De Rijk, Hamke Meijer
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Patent number: 7759294Abstract: Lubricant compositions having improved load carrying capacity comprising an extreme pressure compound comprising a sulfur-containing compound, a load carrying capacity enhancing combination comprising a hydrocarbylamine compound and an alkylphosphorothioate compound, a friction modifier compound, and a diluent or base oil as applicable. These lubricant compositions can be used as industrial oils well-suited for the demands of geared device applications, such as in wind turbine gear-boxes and automotive gears and axles.Type: GrantFiled: October 24, 2003Date of Patent: July 20, 2010Assignee: Afton Chemical CorporationInventors: Mark T. Devlin, Helen T. Ryan
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Publication number: 20100130392Abstract: The present invention relates to a lubricant concentrate containing the following components (i) at least one amine, (ii) at least one phosphate according to the general formula (I), (iii) at least one acid, (iv) optionally at least one ether carboxylic acid compounds with the general formula (II) R20—(O(CH2)m)nOCH2COO?M+??(II), (v) optionally at least one further aid or additive.Type: ApplicationFiled: February 2, 2006Publication date: May 27, 2010Applicant: JOHNSONDIVERSEY, INC.Inventors: Holger Theyssen, Mario Stanga, Franco Bruschi, Stephan Wiemer
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Patent number: 7718587Abstract: A lubricant composition is provided for use in lubricating a conveyor track for bottles, cans, kegs and other containers for beverages and foodstuffs. The composition comprises a phosphate ester of the formula R1—(OCH2CH2)n—O—P(O)(OH)2 where n is in the range of from 0 to 10, and R1 is a C9 to C20 saturated or unsaturated alkyl group or a mixture of such alkyl groups; and water. The composition has a pH of from about 1 to about 3.5. The composition optionally further comprises a biocidal agent, an acid, and a synthetic surfactant. Also disclosed is a method for lubricating a conveyor track by applying an effective amount of such a lubricating composition.Type: GrantFiled: April 26, 2004Date of Patent: May 18, 2010Assignee: Lynx Enterprises, Inc.Inventor: William Charles Schmidt, IV
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Publication number: 20100009879Abstract: The present invention relates to a method of lubricating a conveyor belt, wherein a lubricant concentrate containing at least 0.1 wt-% of at least one free fatty acid and at least one corrosion inhibitor is employed as a dry lubricant in a dry lubrication process.Type: ApplicationFiled: December 12, 2007Publication date: January 14, 2010Applicant: JOHNSONDIVERSEY, INC.Inventors: Holger Theyssen, Stefan Grober, Harry Kany, Mark V. Clifton
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Patent number: 7592297Abstract: The present disclosure is directed to compounds and methods of making the compounds (3, 5) having the formula: where X is a functional group chosen from: and wherein R is chosen from hydrogen, n-alkyl, iso-alkyl, aryl, heterocyclic ring, and nitrogen or a sulfur containing group, and n ranges from 0 to 4.Type: GrantFiled: October 31, 2006Date of Patent: September 22, 2009Assignee: Caterpillar Inc.Inventor: Atanu Adhvaryu
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Patent number: 6995121Abstract: A data/information storage and retrieval medium comprises: (a) a substrate having a layer stack thereon, the layer stack including an outer surface and comprising at least one magnetic or magneto-optical (“MO”) recording layer; and (b) a thin film or layer of a lubricant on the outer surface of the layer stack and comprised of a derivatized perfluoropolyether-based material including at least one generally linear perfluoropolyether chain and at least one phosphite antioxidant/stabilizer moiety attached to at least one end of at least one the chain.Type: GrantFiled: December 23, 2002Date of Patent: February 7, 2006Assignee: Seagate Technology LLCInventors: Jianwei Liu, Michael Joseph Stirniman, Jing Gui
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Patent number: 6989107Abstract: A method for the mechanical working of metals and alloys which comprises conducting the mechanical working in the presence of an aqueous cooling lubricant having a pH of 6-10 and containing a phosphate ester of the formula R1(oxyalkylene)nOP(O)(X)(OH)??(I), or (HO)2(O)P-(oxyalkylene)mOP(O)(OH)2??(II), where R1 is an alkyl group with 1-12 carbon atoms, oxyalkylene is a group containing 2-4 carbon atoms, n is a number from 1-20, X is hydroxyl, R1O or R1(oxyalkylene)nO, where R1, oxyalkylene and n have the meanings mentioned above, and m is a number from 4-40, or a salt thereof, and an alkenyl substituted succinic acid of the formula HOOCCH(R2)CH2COOH??(III), where R2 is an alkenyl group with 4-10 carbon atoms, or a salt thereof, or a mixture of any of the compounds I, II and III.Type: GrantFiled: January 13, 2000Date of Patent: January 24, 2006Assignee: AB Chem DimensionInventor: Rolf Skold
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Patent number: 6828284Abstract: A composition that is or comprises a phosphorus-, perfluoropolyether-, and perfluoroalkyl-containing compound is provided. The compound comprises either (i) mono- or polyalkylene oxide linking groups between the phosphorus and the fluorocarbon group, or (ii) no linking group between the phosphorus and fluorocarbon group, or (iii) individual mixtures of (i) and (ii); and the fluorocarbon group can be the perfluoropolyether or perfluoroalkyl group. The compound can also be a partially esterified phosphate, a partially esterified phosphonate, a salt of a partially esterified phosphate, a salt of a partially esterified phosphonate, or mixtures of two or more thereof.Type: GrantFiled: August 6, 2001Date of Patent: December 7, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Jon Lee Howell, Erik William Perez
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Patent number: 6806238Abstract: The invention concerns the use as extreme pressure additive in aqueous lubricants used for deforming or transforming metals, lamellar crystallites having a length (L) ranging between 0.1 and 100 &mgr;m, a width (I) ranging between 0.Type: GrantFiled: July 24, 2002Date of Patent: October 19, 2004Assignee: Rhodia ChimieInventors: Gilles Lorentz, Jean-Marie Georgees
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Patent number: 6780824Abstract: Emulsifier system containing a) ethoxylates/propoxylates of fatty alcohols with 8 to 18 C atoms in the alcohol with 2 to 6 ethylene oxide units and 4 to 8 propylene oxide units, b) fatty alcohols and/or fatty alcohol propoxylates with 12 to 24 C atoms in the alcohol and 0 to 3 propylene oxide units and/or distillation residue of these fatty alcohols and c) phosphates, selected from: c1) mono- and/or diesters of phosphoric acid with alkanols with 10-20 C atoms, c2) mono- and/or diesters of phosphoric acid with ethoxylated and/or propoxylated alkanols with 10-20 C atoms and/or c3) phosphates of polyethylene glycol ethers and/or polypropylene glycol ethers, and the water-soluble salts of each of these, in a weight ratio a:b:c=1:0.3:0.1 to 1:4:1; anti-corrosive and emulsifier system with these components, emulsion concentrate with these components, oil-in-water emulsion obtainable therefrom and use thereof as a cleaning, anti-corrosive and low-temperature lubricant emulsion.Type: GrantFiled: October 31, 2002Date of Patent: August 24, 2004Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)Inventors: Hans-Peter Oelscher, Juergen Geke
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Patent number: 6764984Abstract: Fluorinated dialkyl dithiophosphoric acids according to formula (I) and metallic salts thereof: the compounds are useful, for example, as additives for lubricant compositions.Type: GrantFiled: December 4, 2002Date of Patent: July 20, 2004Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard P. Beatty
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Publication number: 20040038834Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, (A) an antiwear improving amount of at least one molybdenum containing composition, (B) at least one phosphorus antiwear or extreme pressure agent, and (C) at least one dispersant, provided that the lubricating composition is free of polysulfurized olefins. The lubricating compositions have improved antiwear properties. When the lubricating composition is used in a manual transmission, the amount of brass wear is reduced.Type: ApplicationFiled: August 21, 2003Publication date: February 26, 2004Inventor: Michael P. Gahagan
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Patent number: 6617288Abstract: This invention relates to an aqueous composition comprising water, a surfactant or thickener, and at least one metal-free thiophosphorus acid ester, at least one amine salt of the thiophosphorus acid ester, or a mixture thereof, wherein the thiophosphorus acid ester contains at least one hydrocarbyl terminated oxyalkylene group, at least one hydrocarbyl terminated polyoxyalkylene group, or a mixture thereof. The aqueous compositions have improved antiwear/extreme pressure properties and improved antioxidation properties. In these compositions, the thiophosphorus acid esters and their salts act as antiwear agents and rust inhibitors.Type: GrantFiled: May 8, 1998Date of Patent: September 9, 2003Assignee: The Lubrizol CorporationInventors: Naresh Chand Mathur, Edward J. Konzman
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Patent number: 6602833Abstract: The present invention is directed to a method for mechanical working of a metal containing copper, aluminum or an alloy thereof. The method is carried out in the presence of an aqueous cooling lubricant containing an alkanol amine. The lubricant is capable of preventing and reducing the corrosion of both metals and iron.Type: GrantFiled: April 30, 2001Date of Patent: August 5, 2003Assignee: AB Chem DimensionInventor: Rolf Skold
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Publication number: 20030139300Abstract: Fluorinated dialkyl dithiophosphoric acids according to formula (I) and metallic salts thereof: 1Type: ApplicationFiled: December 4, 2002Publication date: July 24, 2003Inventor: Richard P. Beatty
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Patent number: 6592775Abstract: The present invention relates to an aqueous metalworking liquid, which has the form of a clear solution at 20 ° C., is precipitated at a temperature higher than 20 ° C. and contains: (a) a polypropylene glycol compound containing 6-100 propyleneoxy groups and lacking the presence of hydrocarbons groups having more than 12 carbon atoms, and (b) at least one water-soluble anionic compound, selected from the group consisting of a phosphate ester or an ether carboxylate, the anionic compound containing 1-40 oxyalkylene groups having 2-4 carbon atoms and lacking presence of hydrocarbon groups with more than 12 carbon atoms. The metalworking liquid has excellent lubricating properties and can easily be worked up and reused without leaving troublesome coatings on the metal surfaces.Type: GrantFiled: July 18, 2001Date of Patent: July 15, 2003Assignee: AB Chem DimensionInventor: Rolf Skold
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Publication number: 20030087770Abstract: Emulsifier system containing a) ethoxylates/propoxylates of fatty alcohols with 8 to 18 C atoms in the alcohol with 2 to 6 ethylene oxide units and 4 to 8 propylene oxide units, b) fatty alcohols and/or fatty alcohol propoxylates with 12 to 24 C atoms in the alcohol and 0 to 3 propylene oxide units and/or distillation residue of these fatty alcohols and c) phosphates, selected from: c1) mono- and/or diesters of phosphoric acid with alkanols with 10-20 C atoms, c2) mono- and/or diesters of phosphoric acid with ethoxylated and/or propoxylated alkanols with 10-20 C atoms and/or c3) phosphates of polyethylene glycol ethers and/or polypropylene glycol ethers, and the water-soluble salts of each of these, in a weight ratio a:b:c=1:0.3:0.1 to 1:4:1; anti-corrosive and emulsifier system with these components, emulsion concentrate with these components, oil-in-water emulsion obtainable therefrom and use thereof as a cleaning, anti-corrosive and low-temperature lubricant emulsion.Type: ApplicationFiled: October 31, 2002Publication date: May 8, 2003Inventors: Hans-Peter Oelscher, Juergen Geke
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Publication number: 20030073588Abstract: A composition that is or comprises a phosphorus-, perfluoropolyether-, and perfluoroalkyl-containing compound is provided. The compound comprises either (i) mono- or polyalkylene oxide linking groups between the phosphorus and the fluorocarbon group, or (ii) no linking group between the phosphorus and fluorocarbon group, or (iii) individual mixtures of (i) and (ii); and the fluorocarbon group can be the perfluoropolyether or perfluoroalkyl group. The compound can also be a partially esterified phosphate, a partially esterified phosphonate, a salt of a partially esterified phosphate, a salt of a partially esterified phosphonate, or mixtures of two or more thereof.Type: ApplicationFiled: August 6, 2001Publication date: April 17, 2003Inventors: Jon Lee Howell, Erik Williams Perez
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Patent number: 6548455Abstract: The invention relates to a chain lubricant for conveyor and transport systems which is comprised of water, surfactants, disinfecting agents as well as conventional auxiliary agents and additives. According to the invention, an anionic surfactant is used as the surfactant and chlorine dioxide is used as the disinfecting agent.Type: GrantFiled: June 26, 2001Date of Patent: April 15, 2003Assignee: Bactria Industriehygiene-Service GmbH & Co. KGInventors: Michael Sperling, Guenter Stroh, Heinrich Hix, Juergen Gutknecht
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Patent number: 6486102Abstract: An emulsion used to lubricate the surface of a steel sheet, comprising an additive corresponding to one of the following formulae: (R1-2—O—)1-2—PSS—(CH2)n—COO—(CH2)m—CH3, (R1-2—O—)1,2—PSS—CH2-&phgr;-O—H, (R1,2—O—)1,2—PSS—CH2-&phgr;-O—(CH2)n, —COO—(CH2)m, —CH3, where PSS designates a dithiophosphate function. The naked sheets of steel that are treated with said emulsion have very good tribological properties even when the density of the emulsion thus applied is less than or equal to 1 g/m2 when dry. The invention enables dry-looking oiled sheets to be obtained, whereby no re-oiling is required before forming even by die stamping.Type: GrantFiled: September 28, 2001Date of Patent: November 26, 2002Assignee: UnisorInventors: Hervé Derule, Hubert Jacobs, Amadou Dicko, Peggy Guinet
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Patent number: 6432890Abstract: The present invention relates to a method for mechanically working of cobalt-containing metals or performing metalworking with a tool made of a metal containing cobalt. The method is carried out in the presence of an aqueous cooling lubricant containing a combination of an alkanolamine, a mono- or diphosphate ester and a mono- or dicarboxylic acid. The combination is capable of reducing both the release of cobalt ions and the corrosion of iron. In addition it also contributes essentially to the lubrication.Type: GrantFiled: April 26, 2001Date of Patent: August 13, 2002Assignee: AB Chem DimensionInventor: Rolf Skold
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Patent number: 6355604Abstract: The multifunctional aqueous lubricant according to the invention comprises at least one water-soluble salt of dithiodiglycolic acid and at least one water-soluble compound chosen from the group consisting of: a) phosphoric esters of general formula: in which R represents an alkyl, alkenyl or alkylaryl radical having from 6 to 20 carbon atoms, k is equal to 2 or 3, m is a number ranging from 0 to 20 and x is equal to 1 or 2, and their salts, and b) water-soluble salts of alkylthio acids of general formula: R′—S—(CH2)n—COOH (II) in which n is a number ranging from 1 to 10 and R′ represents an alkyl, alkenyl or aryl radical having from 6 to 20 carbon atoms, the ratio by mass of dithiodiglycolic acid to compound(s) I and/or II being between 1/1 and 50/1.Type: GrantFiled: May 17, 2001Date of Patent: March 12, 2002Assignee: AtofinaInventor: François Guillemet
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Publication number: 20020006880Abstract: The multifunctional aqueous lubricant according to the invention comprises at least one water-soluble salt of dithiodiglycolic acid and at least one water-soluble compound chosen from the group consisting of:Type: ApplicationFiled: May 17, 2001Publication date: January 17, 2002Inventor: Francois Guillement
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Patent number: 6316394Abstract: A synthetic aqueous machining fluid admixture, that is free of sulfur containing and chlorine containing lubricants, and usable in heavy duty machining (e.g. stamping, punching and drawing) operations comprises a) water, b) a water soluble or dispersible fatty acid or water soluble or dispersible fatty acid salt, c) a water soluble or dispersible ethylene oxide propylene oxide copolymer having at least one terminal hydroxyl group or water soluble or dispersible derivative of an ethylene oxide propylene oxide copolymer and d) a water soluble or dispersible organic phosphate ester. Methods for heavy duty machining comprise the steps of applying a force to a workpiece by a tool contacting the workpiece and applying the synthetic aqueous fluid admixture to the interface between the tool and workpiece. The fluid exhibits safety and environmental advantages in use compared to prior art fluids comprising vanishing oils while providing equal or superior lubricity.Type: GrantFiled: January 29, 2001Date of Patent: November 13, 2001Assignee: Milacron Inc.Inventors: Myrna J. Morgan, Deli Gong
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Patent number: 6303546Abstract: There is disclosed a traction drive fluid which comprises a base oil blended with (A) an active phosphate ester base compound, (B) a boron-containing imide base dispersant (e.g. polyalkenyl succinimide treated with a boron compound) and (C) a boron-free imide base dispersant (e.g. polyalkenyl succinimide) in such blending amounts that the phosphorus content derived from the component (A) and the boron content derived from the component (B) are each 100 to 600 ppm, preferably 60 to 300 ppm by weight, and at least 60 ppm by weight, respectively based on the base oil, and the boron-free imide base dispersant (C) is blended so that the ratio by weight of the nitrogen in the component(C) to the boron in the component (B) is at least 1, preferably 1 to 6.Type: GrantFiled: June 2, 2000Date of Patent: October 16, 2001Assignees: Idemitsu Kosan Co., Ltd., NSK Co., Ltd., Nissan Motor Co., Ltd.Inventors: Hitoshi Hata, Tomomi Miyaji, Nobuo Goto, Yoshie Arakawa, Yasuhiro Murakami
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Patent number: 6235689Abstract: The degree of bonding of a perfluoro polyether lubricant topcoat to a magnetic recording medium is improved by forming a polymeric phosphate derivative thereof. In an embodiment of the present invention, a perfluoro polyether phosphate polymer is formed with a molecular weight of about 1000 to about 5000, and applied to a magnetic recording medium to achieve a bonded lube ratio in excess of 0.9.Type: GrantFiled: October 5, 1998Date of Patent: May 22, 2001Assignee: Seagate Technology LLCInventor: Samuel J. Falcone
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Patent number: 6218344Abstract: Lubricants for satellite applications consist essentially of a base fluid having low volatility and a minor amount, i.e., about 0.1 to 10 weight percent, of a chlorinated tris(phenoxyphenyl)phosphate.Type: GrantFiled: January 21, 2000Date of Patent: April 17, 2001Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Lois J. Gschwender, Carl E. Snyder, Jr.
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Patent number: 6191079Abstract: A lubricant additive suitable for combination with an aqueous-based paper or paper board coating mixture wherein the lubricant additive is selected from the group consisting of a polyoxyalkylene mono- and di-ester of phosphoric acid, a polyoxyalkylene mono- and di-ester of a phosphoric acid salt, and a mixture thereof.Type: GrantFiled: March 2, 1994Date of Patent: February 20, 2001Assignee: GEO Specialty Chemicals, Inc.Inventors: Rudolph Klima, John Krasniewski, Jose Maria Rodriguez
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Patent number: 6103675Abstract: The invention relates to the use of mixtures of one or more phosphoric esters of the formula (I) with one or more amines of the formula (II) as extreme pressure additives in water-immiscible cooling lubricants ##STR1## in which the substituents have the meaning defined in the description.Type: GrantFiled: March 11, 1998Date of Patent: August 15, 2000Assignee: Clariant GmbHInventors: Peter Pyka, Barbara Vollnhals, Bernd Pomrehn
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Patent number: 6017858Abstract: This invention relates to synergistic antiwear compositions comprising an organomolybdenum complex and an organic sulfuir compound selected from 2,5-dimercapto-1, 3,4-thiadiazole derivatives, bisdithiocarbamate esters, metal dithiocarbamates, metal phosphorodithioates and phosphorodithioate esters. The organomolybdenum complex is a reaction product prepared by reacting 1 mole fatty oil, 1.0 to 2.5 moles diethanolamine and a molybdenum source.Lubricating compositions containing the synergistic compositions possess good antiwear properties and improved oxidation stability.Type: GrantFiled: March 24, 1998Date of Patent: January 25, 2000Assignee: R.T. Vanderbilt Co., Inc.Inventors: Thomas J. Karol, Steven G. Donnelly
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Patent number: 5968880Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and at least one metal-free thiophosphorus acid ester, at least one amine salt of the thiophosphorus acid ester, or a mixture thereof, wherein the thiophosphorus acid ester contains at least one hydrocarbyl terminated oxyalkylene group, at least one hydrocarbyl terminated polyoxyalkylene group, or a mixture thereof. In one embodiment, the thiophosphorus acid ester is a thiophosphorus acid ester represented by the following formula ##STR1## wherein X.sub.1, X.sub.2, and X.sub.3 are oxygen or sulfur, provided that at least one of X.sub.1, X.sub.2, and X.sub.3 is sulfur; R.sub.1 is a hydrocarbyl group; R.sub.2 is an alkylene group; R.sub.3 is hydrogen or a hydrocarbyl group; x is a number from 1 to about 40; and a is 0, 1, or 2, or at least one salt of the thiophosphorus acid ester.Type: GrantFiled: October 23, 1997Date of Patent: October 19, 1999Assignee: The Lubrizol CorporationInventors: Naresh Chand Mathur, Mary Galic Raguz
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Patent number: 5863871Abstract: Lubricating solutions are used on conveying systems in the beverage industry during the filling of containers with beverages. Lubricating compositions of the present invention, especially those designed for use in beverage conveying systems for contained beverages, comprise at least the following components:a) an alkyl alkoxylated (e.g., ethoxylated or propoxylated, preferably ethoxylated) phosphate ester,b) aryl (e.g., aromatic, such as phenol) alkoxylated (e.g., ethoxylated or propoxylated) phosphate ester,c) an aromatic or linear quaternary ammonium antimicrobial agent, andd) a liquid carrier, such as water.These lubricating solutions are capable of providing good lubricity and antimicrobial activity over a prolonged time.Type: GrantFiled: January 5, 1998Date of Patent: January 26, 1999Assignee: Ecolab IncInventors: Michael E. Besse, Joy G. Dressel, Kimberly L. Person Hei
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Patent number: 5750046Abstract: A method of maintaining and servicing air conditioning systems and compositions therefor are provided whereby newer, more environmentally friendly R-134a refrigerant gas is substituted for the older R-12 and R-22 types. In addition, a method of flushing and internal lubrication of the system is presented, along with a new flush solvent and a new lubricant composition for use with an R-134a refrigerant gas.Type: GrantFiled: May 27, 1997Date of Patent: May 12, 1998Inventor: William B. Wheeler
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Patent number: 5744432Abstract: Water-based stamping lubricants are comprised of: (1) water; (2) a polyester that is water-soluble or readily emulsifiable made by reacting one or more dicarboxylic acids and a polyalkylene glycol; (3) one or more ethoxylated alkylalcohols; (4) the salt of a phosphate ester of an ethoxylated alkyl alcohol; (5) an alkanolamine.Type: GrantFiled: October 28, 1996Date of Patent: April 28, 1998Assignee: Henkel CorporationInventors: Jeff A. Barnhorst, Roger H. Garst, Ronald H. Gordon, Eugene R. Zehler
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Patent number: 5667349Abstract: An improved process for making metallic pull tabs is provided. In accordance with the improved pull tab making process comprising the steps of feeding a strip of metal into a pull tab forming die and forming the metallic pull tab the step of forming the pull tab is carried out in the presence of an aqueous based lubricant composition comprising water, an alkaline pH producing substance selected from the group consisting of alkali metal hydroxides, water soluble or dispersible aliphatic amines and water soluble or dispersible hydroxyl substituted aliphatic amines, an emulsifier, a water soluble or dispersible alpha (p-nonylphenyl) omega hydroxypoly (oxyethylene) phosphate ester and a water soluble or dispersible aliphatic diol.Type: GrantFiled: April 26, 1995Date of Patent: September 16, 1997Assignee: Cincinnati Milacron Inc.Inventors: Henry Turchin, Cindy S. Dinevski, Kevin H. Tucker
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Patent number: 5622923Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and at least one metal-free thiophosphorus acid ester, at least one amine salt of the thiophosphorus acid ester, or a mixture thereof, wherein the thiophosphorus acid ester contains at least one hydrocarbyl terminated oxyalkylene group, at least one hydrocarbyl terminated polyoxyalkylene group, or a mixture thereof. In one embodiment, the thiophosphorus acid ester is a thiophosphorus acid ester represented by the following formula ##STR1## wherein X.sub.1, X.sub.2, and X.sub.3 are oxygen or sulfur, provided that at least one of X.sub.1, X.sub.2, and X.sub.3 is sulfur; R.sub.1 is a hydrocarbyl group; R.sub.2 is an alkylene group; R.sub.3 is hydrogen or a hydrocarbyl group; x is a number from 1 to about 40; and a is 0, 1, or 2, or at least one salt of the thiophosphorus acid ester.Type: GrantFiled: June 16, 1995Date of Patent: April 22, 1997Assignee: The Lubrizol CorporationInventors: Naresh C. Mathur, Mary G. Raguz
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Patent number: 5618778Abstract: The present invention relates to a composition containing a lubricant or hydraulic fluid and in an effective amount to improve extreme pressure and anti-wear properties of said lubricant or hydraulic fluid of at least one compound of the formula II ##STR1## R.sup.1, R.sup.2, and R.sup.3 together with the C atom to which they are bound are tert-C.sub.4 -C.sub.14 -alkyl. R.sup.4 is phenyl, --CH.sub.2 --CH.sub.2 --NH.sub.2, --CH.sub.2 CH.sub.2 OH, --CH.sub.2 CH(OH)--CH.sub.2 --OH, tert-C.sub.4 -C.sub.14 alkyl, --(CH.sub.2).sub.2 --S--CH(OH)--CH.sub.2 --S-(tert-C.sub.8 -C.sub.12 alkyl), --CH.sub.2 --COOH, --CH.sub.2 --COO--(i-C.sub.8 H.sub.17), --CH.sub.2 --CO--OH.H.sub.2 N-(tert-C.sub.10 -C.sub.16 -alkyl), --P(S)--[O--(i-C.sub.3 H.sub.7)].sub.2, --P(S)--[O--(i-C.sub.8 H.sub.17)].sub.2, .alpha.-naphthyl, benzothiazolyl, benzimidazolyl, thiazolyl, --CH.sub.2 --CH--(OH)--CH.sub.2 --S--R.sup.10 wherein R.sup.10 is tertiary C.sub.4 -C.sub.14 -alkyl, or R.sup.4 is radical ##STR2## R.sup.1, R.sup.2 and R.sup.Type: GrantFiled: April 12, 1995Date of Patent: April 8, 1997Assignee: Ciba-Geigy CorporationInventors: Hermann O. Wirth, Hans-Helmut Friedrich
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Patent number: 5569406Abstract: Stamping lubricant compositions which exhibit improved lubricity and methods for reducing friction and wear utilizing said stamping lubricant compositions.Type: GrantFiled: March 15, 1995Date of Patent: October 29, 1996Assignee: Henkel CorporationInventors: Jeff A. Barnhorst, Roger H. Garst, Ronald H. Gordon, Eugene R. Zehler