Hydrogen Bonded Directly To The Phosphorus Patents (Class 508/434)
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Publication number: 20130170777Abstract: The present invention provides a grease composition having an excellent fretting wear resistance in a wide temperature region from low to high temperatures and particularly even at low temperatures and a rolling bearing in which the grease composition is packed. A grease composition (7) is packed inside a grease-packed bearing (1). The grease composition (7) contains base oil, a thickener, and an additive. The additive contains at least, one kind selected from among a phosphite ester shown by a chemical formula (1) or a phosphite ester shown by a chemical formula (2). The content of the phosphite ester is 0.5 to 4 parts by weight for 100 parts by weight which is the total of the amount of the base oil and that of the thickener. (In the chemical formulas (1) and (2), R1, R2, R3, R4, and R5 denote a methyl group or an ethyl group respectively. R1 and R2 are the same group or different groups. R3, R4, and R5 are the same group or different groups).Type: ApplicationFiled: September 9, 2011Publication date: July 4, 2013Applicant: NTN CORPORATIONInventors: Motohiro Ito, Yoji Sato, Hidenobu Mikami
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Publication number: 20120196778Abstract: The invention provides a lubricating composition containing (a) an oil of lubricating viscosity, (b) a phosphite having at least one hydrocarbyl group that has 4 or more carbon atoms, and (c) a compound derived from a hydroxy-carboxylic acid. The invention further relates to the use of the lubricating composition in an internal combustion engine.Type: ApplicationFiled: August 11, 2010Publication date: August 2, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Matthew D. Gieselman, Patrick E. Mosier, Michael R. Sutton, Mark C. Davies, William R.S. Barton
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Patent number: 7786059Abstract: An anti-wear additive composition comprising at least one acid phosphite compound and at least one neutral phosphite compound, wherein the ratio of the acid phosphite to the neutral phosphite is from about 1.0:10.7 to about 2.0:1.0, and lubricating oil compositions containing the same.Type: GrantFiled: December 21, 2004Date of Patent: August 31, 2010Assignee: Chevron Oronite Company LLCInventor: Juan Alberto Buitrago
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Patent number: 6706670Abstract: This invention relates to novel water soluble metal working fluid compositions, their use to work metal, a process for working metal using such compositions and the metal worked article of manufacture. More particularly, this invention relates to fluid compositions useful in cutting, grinding, shaping and other metal working operations which require a lubricant. The terms “first Group A” and “second Group B” are used herein to denote different groups and not to indicate any sequence of use or selection as any possible combination or sequence of use of a component(s) is envisioned without limit of any kind. The disclosed fluid compositions are also anticorrosive and environmentally more acceptable than current oil based fluids.Type: GrantFiled: February 24, 1999Date of Patent: March 16, 2004Assignee: Solutia, Inc.Inventors: Dennis J. Kalota, Yueting Chou, Timothy K. Hirzel, David C. Silverman, Jacob S. Tou, Winsor R. Cho
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Publication number: 20040023819Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorus content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a complex of a molybdenum/nitrogen containing compound and at least one phosphorus-containing compound wherein the total phosphorus employed in the composition is no more than about 0.06 weight percent based on the total weight of the composition.Type: ApplicationFiled: August 1, 2002Publication date: February 5, 2004Inventor: Alexander B. Boffa
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Patent number: 6613722Abstract: A lubricating composition for lubricating a continuously variable transmission, the lubricating composition comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) at least one organic phosphite; (b) at least one amine salt of an organic phosphate; and (c) one or more friction modifiers selected from the group consisting of selected (1) amides, (2) succinimides, and (3) ethoxylated amines.Type: GrantFiled: March 7, 1997Date of Patent: September 2, 2003Assignee: Exxon Chemical Patents Inc.Inventors: Raymond F. Watts, Philip Reeve
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Publication number: 20030144157Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals.Type: ApplicationFiled: February 14, 2003Publication date: July 31, 2003Applicant: Idemitsu Kosan Co., Ltd.Inventor: Eiichi Nakamura
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Publication number: 20020165102Abstract: There is disclosed a lubricating oil composition for cellulose base wet friction material which comprises a base oil blended with (A) a boron-containing imide base dispersant (e.g. boron treated polyalkenyl succinimide) having a weight-average molecular weight in the range of 500 to 3000 and having a ratio by weight of boron to nitrogen (B/N) in the range of 0.1 to 1.5 in such a blending amount that the boron content and the nitrogen content each derived from the component (A) are made to be at least 60 ppm by weight and at least 100 ppm by weight, respectively based on the base oil. The above lubricating oil composition enhances peeling resistant durability for a friction material, especially a cellulose base friction material without impairing the wear resistance or scoring resistance of a steel material element, and is well suited for use in a cellulose base friction material for a starting and running device and a transmission clutch that are used in an automatic transmission of an automobile.Type: ApplicationFiled: May 7, 2002Publication date: November 7, 2002Applicant: Idemitsu Kosan Co., Ltd.Inventors: Hitoshi Hata, Hisashi Machida
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Publication number: 20020010102Abstract: New sulfur-containing organophosphorus compounds of general formulae (I) and (II) and processes for producing the same; additives for lubricating oils, which contain the sulfur-containing organophosphorus compounds; and lubricating oil compositions satisfying requirements of extreme-pressure lubrication and abrasion resistance under severe conditions of high loads imposed, on automatic or continuously variable transmissions or the like. In said formulae, R1 is a hydrocarbon group having 6 to 20 carbon atoms; R2 is a divalent hydrocarbon group having 1 to 6 carbon atoms; n is an integer of 1 to 3; p is an integer of 0 to 2; and q is an integer of 0 or 1, with the proviso that p and q cannot be 0 at the same time.Type: ApplicationFiled: April 4, 2000Publication date: January 24, 2002Inventors: HIROAKI KOSHIMA, HITOSHI HATA, NOBORU SONODA, IZUMI TERADA
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Patent number: 6303546Abstract: There is disclosed a traction drive fluid which comprises a base oil blended with (A) an active phosphate ester base compound, (B) a boron-containing imide base dispersant (e.g. polyalkenyl succinimide treated with a boron compound) and (C) a boron-free imide base dispersant (e.g. polyalkenyl succinimide) in such blending amounts that the phosphorus content derived from the component (A) and the boron content derived from the component (B) are each 100 to 600 ppm, preferably 60 to 300 ppm by weight, and at least 60 ppm by weight, respectively based on the base oil, and the boron-free imide base dispersant (C) is blended so that the ratio by weight of the nitrogen in the component(C) to the boron in the component (B) is at least 1, preferably 1 to 6.Type: GrantFiled: June 2, 2000Date of Patent: October 16, 2001Assignees: Idemitsu Kosan Co., Ltd., NSK Co., Ltd., Nissan Motor Co., Ltd.Inventors: Hitoshi Hata, Tomomi Miyaji, Nobuo Goto, Yoshie Arakawa, Yasuhiro Murakami
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Patent number: 6225266Abstract: A zinc-free lubricating composition for lubricating a continuously variable transmission, the lubricating composition comprising a mixture of a major amount of a lubricating oil and an effective amount of a performance enhancing additive combination comprising: (a) an ashless dispersant; (b) at least one organic phosphite; (c) a calcium detergent; (d) one or more friction modifiers selected from the group consisting of: succinimides and ethoxylated amines; and (e) a primary amide of a long chain carboxylic acid.Type: GrantFiled: May 28, 1999Date of Patent: May 1, 2001Assignee: Infineum USA L.P.Inventors: Raymond F. Watts, Katherine M. Richard
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Patent number: 6100226Abstract: Improved grease compositions comprise a major amount of an oil based metal soap thickened base grease selected from the group consisting of simple metal soap thickened base grease, complex grease and failed complex grease, at least one sulfur and phosphorus containing composition, an overbased metal salt of an organic acid, a hydrocarbyl phosphite, and an aliphatic group substituted carboxylic acid or anhydride thereof, wherein the aliphatic group contains at least about 12 carbon atoms in amounts sufficient to increase the dropping point of the base grease, as measured by ASTM Procedure D-2265 by at least 15.degree. C., the phosphorus and sulfur compound being described in detail herein.Type: GrantFiled: May 20, 1998Date of Patent: August 8, 2000Assignee: The Lubrizol CorporationInventors: Edward J. Konzman, Gary W. Wiggins
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Patent number: 6063742Abstract: Improved grease compositions comprise a major amount of an oil based metal soap thickened base grease selected from the group consisting of simple metal soap thickened base grease, complex grease and failed complex grease, at least one metal salt of a sulfur and phosphorus containing acid, an overbased metal salt of an organic acid, a hydrocarbyl phosphite, and optionally, an aliphatic group substituted carboxylic acid, anhydride thereof and aliphatic group substituted lactone, wherein the aliphatic group contains at least about 8 carbon atoms in amounts sufficient to increase the dropping point of the base grease, as measured by ASTM Procedure D-2265 by at least 15.degree. C.Type: GrantFiled: March 1, 1999Date of Patent: May 16, 2000Assignee: The Lubrizol CorporationInventor: Edward J. Konzman
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Patent number: 5922656Abstract: The lubricant composition of the present invention can be used in automatic transmissions and contains 0.05 to 2% of a metallic salt of organic acid (component (A)), such as calcium sulfonate, 0.15 to 4% of a specific polyamide compound (component (B)) and 0.05 to 1.5% of acid phosphate or acid phosphite ester (component (C)) which are added to a lubricant base oil, wherein all percentages are by weight in the total lubricant composition. The lubricant composition for automatic transmissions can show high anti-shudder property, high anti-shudder durability for an extended period, high property of preventing clogging of the friction material, and sufficient transmission torque capacity, while retaining the lubricant characteristic requirements for use in automatic transmissions.Type: GrantFiled: March 23, 1998Date of Patent: July 13, 1999Assignees: Tonen Corporation, Toyota Jidosha Kabushiki KaishaInventors: Narihiko Yoshimura, Takanori Kugimiya, Takanori Nakada, Fumio Ueda, Yasushi Ando
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Patent number: 5916852Abstract: The present invention generally pertains to a power transmission fluid composition comprising: (a) a major amount of lubricating oil; (b) an oil soluble phosphorus compound; (c) an ashless dispersant; and (d) an amine (i.e., alkyl primary amine) having the following Structure I:R--NH.sub.2wherein R is about a C.sub.8 to C.sub.30 alkyl. Optionally, the power transmission fluid composition may include an amine containing friction modifier.Type: GrantFiled: September 2, 1997Date of Patent: June 29, 1999Assignee: Exxon Chemical Patents Inc.Inventors: Roger Keith Nibert, Raymond F. Watts
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Patent number: 5854183Abstract: A grease composition for constant-velocity joints which is prepared by blending a lube base oil with (A) a urea-urethane thickening agent comprising a mixture of(a) 20 to 95 mole % of a diurea compound of the formula (1): ##STR1## (b) 4 to 50 mole % of a urea-urethane compound of the formula (2): ##STR2## and (c) 1 to 50 mole % of a diurethane compound of the formula (3): ##STR3## with each mole percentage being based on the total amount of the components (a) to (c), wherein a ratio of the total number of R.sup.2 --NH--, R.sup.3 --NH-- and R.sup.5 --NH-- groups contained in the mixture to the total number of R.sup.6 --O--, R.sup.8 --O-- and R.sup.9 --O-- groups contained therein lies between 40:60 and 95:5,(B) at least one compound selected from oxidized paraffins, diphenyl hydrogenphosphite and hexamethylphosphoric triamide, and(C) at least one organomolybdenum compound selected from molybdenum dithiophosphate and molybdenum dithiocarbamate.Type: GrantFiled: April 23, 1997Date of Patent: December 29, 1998Assignees: Nippon Oil Co., Ltd., NTN CorporationInventors: Yukio Hasegawa, Shinichi Takabe, Hirotsugu Kinoshita, Souichi Nomura, Fumihiro Itano
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Patent number: 5807811Abstract: An oil-in-water emulsion composition is disclosed which comprises a mixture of water and(A) at least one oil comprising(1) a natural oil or synthetic triglyceride of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently saturated or unsaturated aliphatic groups that contain from about 7 to about 23 carbon atoms;(2) a synthetic ester base oil comprising the reaction of a monocarboxylic acid or a dicarboxylic acid or an aryl carboxylic acid;(3) an olefin;(4) a polyolefin;(B) at least one phosphite ester of the formula ##STR2## wherein R.sup.11 and R.sup.12 are independently aliphatic, aryl or aliphatic substituted aryl groups that independently contain from 6 to 30 carbon atoms; and(C) at least one emulsifier.Type: GrantFiled: August 23, 1996Date of Patent: September 15, 1998Assignee: The Lubrizol CorporationInventor: George A. Malchow, Jr.
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Patent number: 5798322Abstract: A friction-modifying additive composition for a slideway lubricant comprising a mixture of at least one polymeric ester of certain dibasic and monobasic acids with selected organo phosphorus compounds.Type: GrantFiled: August 30, 1996Date of Patent: August 25, 1998Assignee: Gateway Additive CompanyInventors: William Brannen, Aaron Myers, Harish Patel, Philip R. Miller
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Patent number: 5597506Abstract: A method of controlling the friction coefficients and improving the friction durability of an oleaginous compositions, such as an ATF, comprising adding to the composition a combination of competing additives comprising (1) at least one friction modifying chemical additive having a polar head group and a friction reducing substituent group and (2) at least one non-friction reducing additive and/or friction increasing additive having the same polar group as the friction modifying chemical additive, but having a substituent group which has no material friction raising or lowering effect (non-friction reducing additive) or a substituent group which increases the friction coefficients (friction increasing additive) of the composition.Type: GrantFiled: May 30, 1995Date of Patent: January 28, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Ricardo A. Bloch, Roger K. Nibert, Jack Ryer, Raymond F. Watts
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Patent number: 5585030Abstract: A method of controlling the friction coefficients and improving the friction durability of an oleaginous compositions, such as an ATF, comprising adding to the composition a combination of competing additives comprising (a) at least one friction reducing chemical additive having a polar head group other than a dialkoxylated amino group and a friction reducing substituent group, and at least one non-friction reducing additive (b) having a dialkoxylated amino polar head group and having a substituent group which has no material friction raising or lowering effect (non-friction reducing additive) on the composition.Type: GrantFiled: June 7, 1995Date of Patent: December 17, 1996Assignee: Exxon Chemical Patents Inc.Inventors: Roger K. Nibert, Ricardo A. Bloch, Jack Ryer, Raymond F. Watts