Phosphorus Acid Salt With Metal Or Ammonia (e.g., Overbased Or Carbonated Phosphorus Acids, Etc.) Patents (Class 508/435)
  • Patent number: 11898119
    Abstract: A lubricating oil composition comprising greater than 50 wt. % of a base oil of lubricating viscosity, and an additive composition comprising: an amount of one or more zinc dialkyl dithiophosphates (ZDDP compounds) and an amount of one or more viscosity modifiers, wherein an amount of phosphorus (P) in weight percent provided to the lubricating oil composition by the one or more ZDDP compounds divided by the amount of the one or more viscosity modifiers (VM) in weight percent based on a total weight of the lubricating oil composition is a P/VM quotient of more than about 0.0075. The lubricating oil composition can improve resistance to engine deposits and extend oil drain intervals of an internal combustion engine.
    Type: Grant
    Filed: January 25, 2022
    Date of Patent: February 13, 2024
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Todd Dvorak, Kenneth Garelick, Mark Devlin
  • Patent number: 11884892
    Abstract: An organometallic phosphorus-providing antiwear additive and a lubricating composition including the organometallic phosphorus-providing antiwear additive having improved copper corrosion performance obtained by reacting an organic hydroxy compound with phosphorus pentasulfide to form a reaction product, distilling the reaction product and recovering a condensate, and neutralizing the condensate with a basic or neutral metal compound including one or more of a metal oxide, a metal hydroxide, or a metal carbonate to form the organometallic phosphorus-providing antiwear additive or salt thereof.
    Type: Grant
    Filed: March 31, 2023
    Date of Patent: January 30, 2024
    Assignee: Afton Chemical Corporation
    Inventors: Brandon Knouse, David Edwards, Magdalena Makowska, Keith Hayes, Gregory James
  • Patent number: 11702609
    Abstract: A method for improving lubricating performance of lubricating oils is provided and includes: adding copper phosphate with a porous structure into a base oil, a mass percent of the copper phosphate with the porous structure to the base oil is 0.0001% ˜50%, the porous structure is one of a foam porous structure and a porous nanoflower structure. The copper phosphate with the porous structure is obtained by adding a divalent copper salt solution into an alkaline disodium hydrogen phosphate solution or alkaline phosphoric acid buffer solution and then separating a precipitate. When a ratio of a concentration of a divalent copper ion to that of a phosphate ion is 1:0.1 to 400, the porous structure is porous foam or nanoflower. The porous structure can be well dispersed in the lubricating oil for 1 hour. After adding the lubricating oil, excellent friction reduction and anti-wear is achieved.
    Type: Grant
    Filed: June 21, 2022
    Date of Patent: July 18, 2023
    Assignee: WUHAN RESEARCH INSTITUTE OF MATERIALS PROTECTION
    Inventors: Haitao Duan, Linlin Duan, Dan Jia, Shengpeng Zhan, Tian Yang, Jiesong Tu
  • Patent number: 11485926
    Abstract: The present invention provides a refrigerating machine oil comprising a lubricating base oil and at least one selected from the group consisting of an amine salt of phosphonic acid and an amine salt of phosphonic acid monoester, and a method for producing the same.
    Type: Grant
    Filed: January 21, 2020
    Date of Patent: November 1, 2022
    Assignee: ENEOS CORPORATION
    Inventors: Yohei Shono, Tatsuki Nakajima, Shogo Hashimoto, Yuya Mizutani, Hidetoshi Ogata
  • Patent number: 10036463
    Abstract: A robot includes a first member, a second member that is provided so as to be movable around the first member, and a gear device that transmits driving force from one of the first member and the second member to the other. The gear device includes a contact portion where two surfaces come into contact with each other and a lubricant, which is disposed on the contact portion and of which a change rate of worked penetration caused by a worked stability test is within a range of ?16% to +16% inclusive.
    Type: Grant
    Filed: September 22, 2017
    Date of Patent: July 31, 2018
    Assignee: Seiko Epson Corporation
    Inventor: Masanao Kunugi
  • Patent number: 9587197
    Abstract: A processing fluid that is free of boron and secondary amines includes a petroleum-based or non-petroleum-based oil; water; and an additive composition comprising a long chain primary amine; an tertiary cycloalkylamine; and an amino acid.
    Type: Grant
    Filed: February 3, 2014
    Date of Patent: March 7, 2017
    Assignee: FUCHS PETROLUB SE
    Inventors: Michael P. Duncan, D. James Deodhar, Gema del Olmo Tomás, Heinz Gerhard Theis, Paul Roger Littley
  • Publication number: 20140309150
    Abstract: A lubricant composition and a method of lubricating off-road vehicles and/or machinery. The lubricant composition includes (i) a base oil, (ii) at least one ashless component (A) having the structure P(?S)(SR1)(OR2)(OR3), wherein R1, R2 and R3 are independently selected form the group consisting of alkyl, aryl, alkylaryl, cycloalkyl, alcohol, carboxylic acid and ester having 1 to 24 carbon atoms; and (iii) at least one component (B) being a metal dialkyl dithio phosphate salt. The total of ashless components (A) provides to the lubricant composition from 0.010 to 0.080 wt. % phosphorus based on the total weight of the lubricant composition and the total of components (B) provides to the lubricant composition from 0.010 to 0.080 wt. % phosphorus based on the total weight of the lubricant composition.
    Type: Application
    Filed: April 11, 2013
    Publication date: October 16, 2014
    Applicant: Afton Chemical Corporation
    Inventor: Jonathan W. BENDER
  • Publication number: 20140171348
    Abstract: A composition including an ionic liquid alkylammonium salt (e.g., tetraalkylammonium cation and bis(2-ethylhexyl)phosphate anion), or an ionic liquid imidazolium salt (e.g., 1,3-dialkylimidazolium cation and bis(2-ethylhexyl)phosphate anion), that have a structure sufficient to exhibit at least partial solubility in one or more Group I-V base stocks. The disclosure also relates to a lubricating oil base stock and lubricating oil containing the composition, a multifunctional functional fluid containing the composition, and a method for improving solubility of an ionic liquid in a lubricating oil by using as the lubricating oil a formulated oil including a lubricating oil base stock as a major component, and an ionic liquid alkylammonium salt cobase stock, or an ionic liquid imidazolium salt cobase stock, as a minor component.
    Type: Application
    Filed: November 14, 2013
    Publication date: June 19, 2014
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Abhimanyu Onkar Patil, Satish Bodige, Tezcan Guney
  • Patent number: 8673829
    Abstract: It is an object of the present invention to provide a grease composition (7) which can be used for a long term in a wide temperature range from low to high temperatures by using comparatively inexpensive base oil. It is another object of the present invention to provide a rolling bearing and a universal joint in which the grease composition (7) is enclosed. The grease composition (7) is composed of base grease, consisting of base oil and a thickener, to which an additive is added. The base oil contains not less than 50 wt % of highly refined oil having a viscosity index of 120 to 180. The additive contains at least ZnDTP and 0.2 to 6 parts by weight of poly (metha) acrylate having a kinematic viscosity of not less than 100 mm2/s and less than 850 mm2/s at 100° C. for 100 parts by weight of the base grease. The grease composition (7) is enclosed in the circumferences of rolling elements (4) of a rolling bearing (1).
    Type: Grant
    Filed: September 3, 2009
    Date of Patent: March 18, 2014
    Assignee: NTN Corporation
    Inventor: Takayuki Kawamura
  • Patent number: 8586517
    Abstract: A lubricant composition. The lubricant composition includes (a) a phenate, a sulfonate, or both; and (b) a base composition wherein the base composition is (i) a metal carbonate and a metal sulfate, (ii) a metal sulfate and a metal phosphate; (iii) a metal sulfate and a metal carboxylate; (iv) a metal phosphate and a metal carboxylate; or (v) three-way or four-way combination of a metal sulfate, a metal carboxylate, a metal phosphate, and a metal carbonate; and (c) a lubricating oil or a grease.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: November 19, 2013
    Assignee: Southwest Research Institute
    Inventor: John A. Waynick
  • Publication number: 20130252865
    Abstract: A lubricating oil composition comprising a major amount of oil of lubricating viscosity and a minor amount of one or more compounds of formula (I): wherein R1, R2, R3, R4 and R5 independently represent alkyl or substituted alkyl having no aryl substituent.
    Type: Application
    Filed: September 21, 2012
    Publication date: September 26, 2013
    Inventors: Joseph P. Hartley, Gabriele Candido
  • Patent number: 8361941
    Abstract: The present invention relates to an antiwear agent and lubricating compositions thereof. The invention further provides for a method of lubricating a driveline device or a grease application by employing a lubricating composition containing the antiwear agent.
    Type: Grant
    Filed: June 6, 2011
    Date of Patent: January 29, 2013
    Assignee: The Lubrizol Corporation
    Inventor: Charla A. Ramsey
  • Publication number: 20120329688
    Abstract: The present invention relates to a method of driveline device by supplying to the driveline device a lubricating composition containing an oil of lubricating viscosity and an antiwear package, wherein the antiwear package includes: (a) derivatives of a carboxylic acid (typically a hydroxycarboxylic acid); and (b) a phosphorus compound. The invention further provides lubricating compositions containing an oil of lubricating viscosity and an antiwear package, wherein the antiwear package includes (a) derivatives of a carboxylic acid (typically a hydroxycarboxylic acid); and (b) an amine or metal salt of a phosphorus compound that is either (i) a hydroxy-substituted di-ester of (thio)phosphoric acid, or (ii) a phosphorylated hydroxy-substituted di- or tri-ester of (thio)phosphoric acid.
    Type: Application
    Filed: September 6, 2012
    Publication date: December 27, 2012
    Applicant: THE LUBRIZOL CORPORATION
    Inventor: Morey N. Najman
  • Patent number: 8309500
    Abstract: Novel non-aqueous water soluble food grade lubricant compositions comprising: (a) About 5% to about 50% of a polyalkylene glycol comprised of an ethylene oxide/propylene oxide copolymer, or polymer of propylene oxide, having molecular weight greater than 1,500; and (b) About 50% to about 95% of a polyethylene glycol having molecular weight of from about 200 to about 600; wherein said lubricating compositions have viscosities of about 28 to about 100% at 40° C. The novel non-aqueous water soluble food grade lubricant compositions are particularly useful in food processing and packaging equipment applications where low viscosity food grade lubricants with low pour points are desired, and in applications where there is a need for equipment and spill cleanup. These food grade lubricant compositions are also environmentally friendly due to their water solubility, rapid biodegradability, and low aquatic toxicity.
    Type: Grant
    Filed: July 13, 2005
    Date of Patent: November 13, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Daryl L. Beatty, Martin R. Greaves
  • Publication number: 20120220506
    Abstract: The present invention relates to a lubricating composition containing an oil of lubricating viscosity and a star polymer that has at least two inner blocks, at least one of which is in turn bonded to one or more outer blocks. The invention further relates to methods of lubricating a mechanical device with the lubricating composition.
    Type: Application
    Filed: February 2, 2012
    Publication date: August 30, 2012
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Haihu Qin, Marina Baum, John R. Johnson
  • Publication number: 20120142565
    Abstract: The present invention relates to a lubricating composition containing a sulphur-free metal salt of a hydrocarbyl-substituted phosphorus compound and an organo-sulphide. The composition has a sulphur content of greater than 0.3 weight percent of sulphur. The invention further provides for a method of lubricating a driveline device by using a lubricating composition.
    Type: Application
    Filed: February 9, 2012
    Publication date: June 7, 2012
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: James N. Vinci, Michael E. Huston, Denise R. Vermilya, Charla A. Ramsey, Roger L. Sowerby
  • Publication number: 20100144563
    Abstract: Lubricated surfaces and lubricant compositions for lubricating a surface. The lubricated surface is provided by a lubricant composition including a base oil of lubricating viscosity, at least one metal salt of phosphorothioic acid, and an ashless, sulfur-free organophosphorus compound providing a metal to phosphorus weight ratio ranging from about 0.25:1 to about 1.0:1 by weight. The lubricant composition is substantially devoid of molybdenum.
    Type: Application
    Filed: December 9, 2008
    Publication date: June 10, 2010
    Applicant: AFTON CHEMICAL CORPORATION
    Inventors: Mark T. DEVLIN, John T. LOPER, Roger M. SHEETS, Gregory H. GUINTHER, Jeffrey M. GUEVREMONT
  • Patent number: 7696137
    Abstract: A lubricating oil composition is disclosed which comprises a lubricating base oil, (A) at least one type of compound selected from specific phosphoric acid esters and salts thereof or in combination with (B) at least one type of compound selected from specific metal salts of specific phosphoric acid esters, with excellent oxidation stability, base number retention properties, anti-wear properties, extreme pressure properties and anti-corrosion properties and thus can be suitably used, in particular, as a lubricating oil for an internal combustion engine.
    Type: Grant
    Filed: February 15, 2005
    Date of Patent: April 13, 2010
    Assignee: Nippon Oil Corporation
    Inventor: Kazuhiro Yagishita
  • Publication number: 20100005829
    Abstract: The present invention provides a lubricating oil for a compression type refrigerator including a polyvinyl ether-based compound which containing an alkylene glycol or polyoxyalkylene glycol unit and a vinyl ether unit in a molecule and having a molecular weight in a range of 300 to 3,000 and one or more kinds of phosphorous compound selected from a phosphate having 25 or more carbon atoms, a phosphite having 10 to 60 carbon atoms, an amine salt of phosphate having 10 to 60 carbon atoms, and a metal salt of phosphate having to 60 carbon atoms. The lubricating oil for a compression type refrigerator of the present invention has high compatibility and high viscosity index, and is excellent in anti-seizure property and also in stability under carbon dioxide atmosphere.
    Type: Application
    Filed: September 21, 2007
    Publication date: January 14, 2010
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventors: Masato Kaneko, Harutomo Ikeda
  • Publication number: 20090042752
    Abstract: A lubricant composition is disclosed. The lubricant composition is made up of (a) ashless dispersant; (b) metal-containing detergent; (c) a phosphorus-containing compound; (d) rust inhibitor; and (e) basestock, wherein the lubricant composition has a concentration of phosphorus less than or equal to 0.08 weight %.
    Type: Application
    Filed: August 9, 2007
    Publication date: February 12, 2009
    Inventors: Malcolm Waddoups, George C. L'Heureux
  • Publication number: 20080103072
    Abstract: The present invention relates to a lubricating composition containing a sulphur-free metal salt of a hydrocarbyl-substituted phosphorus compound and an organo-sulphide. The composition has a sulphur content of greater than 0.3 weight percent of sulphur. The invention further provides for a method of lubricating a driveline device by using a lubricating composition.
    Type: Application
    Filed: November 1, 2006
    Publication date: May 1, 2008
    Applicant: The Lubrizol Corporation
    Inventors: James N. Vinci, Michael E. Huston, Denise R. Vermilya, Charla A. Ramsey, Roger L. Sowerby
  • Publication number: 20040147415
    Abstract: A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of:
    Type: Application
    Filed: September 30, 2003
    Publication date: July 29, 2004
    Inventors: Alisdair J. Brown, Roger W. Glyde, Rebecca Castle, Jane Gilmore, Simon S. M. Chung, Rolfe J. Hartley
  • Patent number: 6764984
    Abstract: Fluorinated dialkyl dithiophosphoric acids according to formula (I) and metallic salts thereof: the compounds are useful, for example, as additives for lubricant compositions.
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: July 20, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Richard P. Beatty
  • Publication number: 20040072702
    Abstract: The invention concerns a method for cold rolling metals using an aqueous lubricant comprising: (1) at least a mixture based on at least an acid selected among saturated or unsaturated mono- or poly-carboxylic acids, comprising 5 to 40 carbon atoms; at least an acid phosphate ester of formula (RO)x—P(═O)(OH)x′, wherein: R is a hydrocarbon radical, optionally polyalkoxylated; x and x′ being equal to 3; the carboxylic acid and/or the acid phosphate ester being optionally neutralised by an organic or mineral base; and (2) at least a natural or synthetic wax exhibiting a melting point not less than 50° C. and having an average particle size ranging between 0.5 and 10 &mgr;m. The use of said lubricant enables to increase the productivity of the method by at least 15% relative to a method using a conventional lubricant.
    Type: Application
    Filed: November 17, 2003
    Publication date: April 15, 2004
    Inventors: Dominique Raison, Jean-Guy Le Helloco
  • Patent number: 6656887
    Abstract: Lubricating oil compositions comprise a lubricating base oil and (A) at least one compound selected from the group consisting of compounds represented by formula (1) below and compounds represented by formula (2) below: wherein R2, R1, R3 and R4 are each independently hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, X1, X2, X3 and X4 are each independently oxygen or sulfur, but at least one of them is oxygen, and Y1 is a metal atom; and wherein R11 and R12 are each independently hydrogen or a hydrocarbon group having 1 to 30 carbon atoms, X11 and X12are each independently oxygen or sulfur, but at least one of them is oxygen, U is a monovalent metal ion, an ammonium ion or a proton, and k1 is an integer of 1 to 20. Lubricating oil compositions have excellent anti-wear properties and base number maintaining properties.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: December 2, 2003
    Assignee: Nippon Mitsubishi Oil Corporation
    Inventors: Kazuhiro Yagishita, Jinichi Igarashi, Takeo Koizumi
  • Publication number: 20030199400
    Abstract: A water-based household lubricant, free of hydrocarbon oils, comprises a water-soluble ammonium salt of a surfactant, preferably a carboxylate, sulfonate, phosphate or sarcosinate surfactant, preferably having rust preventative activity, most particularly ammonium N-oleol sarcosinate as a main or sole component. The composition also desirably contains an anti-microbial and a surface tension reducer, most preferably N-(N-octal)-2-pyrrolidone. An aqueous solution of the ammonium salt of the fatty acid surfactant, which is non-staining, is applied to a substrate, the water evaporates and ammonia from the ammonium ion is slowly released into the atmosphere leaving the surfactant as a lubricant. The residue provides rust resistance, water repellency and lubrication.
    Type: Application
    Filed: January 7, 2003
    Publication date: October 23, 2003
    Inventor: Robert H. Black
  • Publication number: 20030176299
    Abstract: The multifunctional lubricant according to the invention comprises at least one phosphoric ester (A) of general formula: 1
    Type: Application
    Filed: December 20, 2002
    Publication date: September 18, 2003
    Inventors: Francois Guillemet, Gilles Darvaux-Hubert
  • Publication number: 20030139300
    Abstract: Fluorinated dialkyl dithiophosphoric acids according to formula (I) and metallic salts thereof: 1
    Type: Application
    Filed: December 4, 2002
    Publication date: July 24, 2003
    Inventor: Richard P. Beatty
  • Patent number: 6596672
    Abstract: A low sulfate ash lubricating oil composition comprising an oil of lubricating viscosity, 0.1 to 3.0% of a calcium overbased acidic material, 0.1 to 2.0% of a magnesium overbased acidic material, and at least 0.5% of a combination of an alkylene-coupled hindered phenol antioxidant and an antioxidant other than an alkylene-coupled hindered phenol antioxidant, is particularly useful for lubricating stationary gas engines.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: July 22, 2003
    Assignee: The Lubrizol Corporation
    Inventors: Virginia A. Carrick, Ewa A. Bardasz, David E. Ripple
  • Patent number: 6573223
    Abstract: The invention relates to a lubricating composition comprising: (a) at least one sulfur-free hydrocarbyl phosphoric acid ester or salt, (b) at least one sulfur-containing hydrocarbyl phosphoric acid or salt, (c) an organic polysulfide, (d) at least one dispersant, and (e) at least one triazole metal deactivator. The composition may also include a thiadiazole derivative. This additive combination provides good antiwear and thermal stability properties, even under severe thermal conditions. These compositions also have good demulsibility properties. The above combination of additives provides the antiwear and extreme-pressure protection necessary for automotive and industrial gear applications. These additives additionally provide this protection without adversely effecting demulsibility properties of the lubricant.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: June 3, 2003
    Assignee: The Lubrizol Corporation
    Inventor: James N. Vinci
  • Patent number: 6569821
    Abstract: An overbased metal detergent having friction-modifying properties comprises colloidal inorganic base particles stably dispersed in an oil of lubricating viscosity. The colloidal particles constitute from 15 to 40 mass % of the detergent, and a stabilizing system constitutes from 20 to 45 mass % thereof, the balance being the oil of lubricating viscosity. The stabilizing system is the mixture obtained by combining an oil-soluble detergent component and from 25 to 75 mass % of an aliphatic amide having from 10 to 30 carbon atoms.
    Type: Grant
    Filed: January 3, 2000
    Date of Patent: May 27, 2003
    Assignee: Infineum USA L.P.
    Inventors: Tuncel Ibrahim, John A Cleverley, Phillip Skinner, Jane Rachel Galsworthy, Christopher John Adams, Rudi ter Haar
  • Publication number: 20030069145
    Abstract: A gas engine lubricating oil composition that is substantially free from dispersant. The gas engine lubricating oil composition has a TBN in the range of 3.5 to 20. The gas engine lubricating oil composition comprises an oil of lubricating viscosity and at least one metal detergent.
    Type: Application
    Filed: September 9, 2002
    Publication date: April 10, 2003
    Inventors: Laurent Chambard, Yolanda Owen
  • Patent number: 6528457
    Abstract: A composition that can be used as lubricant for high electric field including spark plug boots is disclosed. The composition comprises, or is produced by combining, a halogenated oil such as a perfluoropolyether, a polytrichlorofluoroethylene, a fluorosilicone, or combinations of two or more thereof; a basic thickener; and optionally an additional thickener in which the basic thickener is a metal hydroxide, a metal salt, an ammonium salt, or combinations of two or more thereof. The optional additional thickener is polytetrafluoroethylene, talc, silica, clay, boron nitride, metal soaps, titanium dioxide, polydimethylsiloxane, polyurea, polyurethane, or combinations of two or more thereof. Also provided is a spark plug boot that comprises the composition applied thereto.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: March 4, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Jon L. Howell, H. Carl Walther, Gregory A. Bell
  • Publication number: 20030013617
    Abstract: A composition that can be used as lubricant for high electric field including spark plug boots is disclosed. The composition comprises, or is produced by combining, a halogenated oil such as a perfluoropolyether, a polytrichlorofluoroethylene, a fluorosilicone, or combinations of two or more thereof; a basic thickener; and optionally an additional thickener in which the basic thickener is a metal hydroxide, a metal salt, an ammonium salt, or combinations of two or more thereof. The optional additional thickener is polytetrafluoroethylene, talc, silica, clay, boron nitride, metal soaps, titanium dioxide, polydimethylsiloxane, polyurea, polyurethane, or combinations of two or more thereof. Also provided is a spark plug boot that comprises the composition applied thereto.
    Type: Application
    Filed: June 28, 2001
    Publication date: January 16, 2003
    Inventors: Jon L. Howell, H. Carl Walther, Gregory A. Bell
  • Patent number: 6489271
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (a) a extreme pressure improving amount of at least one sulfur compound, and an antiwear or an extreme pressure improving amount of the combination of (b) at least one ammonium salt of a phosphoric acid ester, (c) at least one phosphite, and (d) at least one thiophosphate or at least one reaction product of a phosphite and sulfur or a source of sulfur. The invention also relates to concentrates and greases containing the combination of the sulfur is compound and the specific phosphorus compounds.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: December 3, 2002
    Assignee: The Lubrizol Corporation
    Inventor: Robert C. Richardson
  • Patent number: 6482777
    Abstract: This invention relates to a lubricating composition comprising a blend of a major amount of an oil of lubricating viscosity, gear or transmission oil package and a top treatment which comprises at least one saturated fatty phosphate ester or salt, wherein the lubricating composition is free of saturated fatty phosphites. Tin another embodiment, the invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, at least one saturated fatty phosphate ester or salt, at least one polysulfide and at least one phosphorus antiwear or extreme pressure agent, wherein the lubricating composition is free of saturated fatty phosphites. The invention relates to additive combinations which when added to a lubricant can provide and improve frictional and, optionally, thermal stability properties. The additives include a phosphate ester or salt wherein the hydrocarbyl group of the phosphate is a fatty-saturated group.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: November 19, 2002
    Assignee: The Lubrizol Corporation
    Inventor: Robert W. Cain
  • Patent number: 6468946
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) a di or trihydrocarbyl phosphite, (B) at least one reaction product of a di or trihydrocarbyl phosphite and sulfur or a source of sulfur; at least one di or trihydrocarbyl monothiophosphate; or salt thereof, and (C) a salt of a hydrocarbyl phosphoric acid ester. In one embodiment, the lubricant composition contains less than 0.1% phosphorus or less than about 0.75% borated dispersant. This combination of phosphorus compounds provides antiwear and thermal stability to lubricants, even at low phosphorus levels. The lubricating compositions containing the combination of the phosphorus compounds has low corrosivity to copper and low odor as well.
    Type: Grant
    Filed: July 6, 1999
    Date of Patent: October 22, 2002
    Assignee: The Lubrizol Corporation
    Inventor: James N. Vinci
  • Publication number: 20020086802
    Abstract: This invention relates to a lubricating composition comprising a blend of a major amount of an oil of lubricating viscosity, gear or transmission oil package and a top treatment which comprises at least one saturated fatty phosphate ester or salt, wherein the lubricating composition is free of saturated fatty phosphites. Tin another embodiment, the invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, at least one saturated fatty phosphate ester or salt, at least one polysulfide and at least one phosphorus antiwear or extreme pressure agent, wherein the lubricating composition is free of saturated fatty phosphites. The invention relates to additive combinations which when added to a lubricant can provide and improve frictional and, optionally, thermal stability properties. The additives include a phosphate ester or salt wherein the hydrocarbyl group of the phosphate is a fatty-saturated group.
    Type: Application
    Filed: October 19, 1999
    Publication date: July 4, 2002
    Inventor: ROBERT W. CAIN
  • Patent number: 6265360
    Abstract: The present invention relates to a wax-containing liquid hydrocarbon fuel composition comprising (a) at least one wax-containing liquid hydrocarbon; and b) a transesterified acrylate polymer obtained by transesterifying a starting acrylate polymer with at least one higher alcohol, the transesterified acrylate polymer being present in an amount sufficient to modify the cold flow properties of the wax containing liquid hydrocarbon fuel.
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: July 24, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Marvin B. DeTar, Richard M. Lange, John S. Manka
  • Patent number: 6153565
    Abstract: Phenate overbased detergents and salicylate overbased detergents with TBN: % surfactant ratios of 11 or more are useful marine diesel lubricant additives.
    Type: Grant
    Filed: November 9, 1998
    Date of Patent: November 28, 2000
    Assignee: Exxon Chemical Patents INC
    Inventors: Philip Skinner, Alain Louis Pierre Lenack
  • Patent number: 6103675
    Abstract: The invention relates to the use of mixtures of one or more phosphoric esters of the formula (I) with one or more amines of the formula (II) as extreme pressure additives in water-immiscible cooling lubricants ##STR1## in which the substituents have the meaning defined in the description.
    Type: Grant
    Filed: March 11, 1998
    Date of Patent: August 15, 2000
    Assignee: Clariant GmbH
    Inventors: Peter Pyka, Barbara Vollnhals, Bernd Pomrehn
  • Patent number: 6100226
    Abstract: Improved grease compositions comprise a major amount of an oil based metal soap thickened base grease selected from the group consisting of simple metal soap thickened base grease, complex grease and failed complex grease, at least one sulfur and phosphorus containing composition, an overbased metal salt of an organic acid, a hydrocarbyl phosphite, and an aliphatic group substituted carboxylic acid or anhydride thereof, wherein the aliphatic group contains at least about 12 carbon atoms in amounts sufficient to increase the dropping point of the base grease, as measured by ASTM Procedure D-2265 by at least 15.degree. C., the phosphorus and sulfur compound being described in detail herein.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: August 8, 2000
    Assignee: The Lubrizol Corporation
    Inventors: Edward J. Konzman, Gary W. Wiggins
  • Patent number: 6063742
    Abstract: Improved grease compositions comprise a major amount of an oil based metal soap thickened base grease selected from the group consisting of simple metal soap thickened base grease, complex grease and failed complex grease, at least one metal salt of a sulfur and phosphorus containing acid, an overbased metal salt of an organic acid, a hydrocarbyl phosphite, and optionally, an aliphatic group substituted carboxylic acid, anhydride thereof and aliphatic group substituted lactone, wherein the aliphatic group contains at least about 8 carbon atoms in amounts sufficient to increase the dropping point of the base grease, as measured by ASTM Procedure D-2265 by at least 15.degree. C.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: May 16, 2000
    Assignee: The Lubrizol Corporation
    Inventor: Edward J. Konzman
  • Patent number: 6004910
    Abstract: A lubricating oil having an ashless nitrogenous TBN source together with ash containing detergent having a TBN in excess of 100, a source of magnesium, and metal dihydrocarbyl dithiophosphate with predominantly or exclusively secondary hydrocarbyl groups is described. It comprises a major amount of an oil of lubricating viscosity having a sulfated ash content between 0.35 and 2 mass percent and A) a nitrogenous TBN source selected from the group consisting of ashless nitrogen containing dispersants, ashless nitrogen containing dispersant viscosity modifiers, oil soluble aliphatic, oxyalkyl, or arylalkyl amines and mixtures thereof; B) a metal salt of an oil soluble acid having a TBN in excess of 100; C) at least 500 ppm (mass) magnesium; and D) at least one metal dihydrocarbyl dithiophosphate. The nitrogenous TBN source provides at least about 1.5 TBN to the finished lubricant. The metal salt of an oil soluble acid provides at least about 40% of the total TBN of the composition.
    Type: Grant
    Filed: March 7, 1995
    Date of Patent: December 21, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Ricardo Alfredo Bloch, Arunas T. Lapinas, Edward F. Outten, Andrew James Dalziel Ritchie, Malcolm Waddoups
  • Patent number: 5997761
    Abstract: A refrigerating machine oil composition which comprises, in the form of a blend, a base oil comprising a mineral oil or a synthetic oil and at least one species of an amine salt of an organic phosphoric acid, e.g. monooctylamine dioleyl phosphate.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: December 7, 1999
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Masato Kaneko
  • Patent number: 5958850
    Abstract: A rust preventive composition which is obtained by blending at least one base oil selected from the group consisting of a hydrocarbon solvent, a mineral oil and a synthetic oil with, as essential components,(A) an organophosphoric ester calcium salt represented by the following general formula (1) in an amount of 0.1 to 5.0% by mass based on the total mass of the composition ##STR1## wherein R.sup.1 and R.sup.2 are each an alkyl group having 6 to 18 carbon atoms; and a and b are each an integer of 1 to 6,(B) water in an amount of 0.1 to 3.0 parts by weight based on 1 part by weight of the component (A), and(C) a rust inhibitor in an amount of 2.0 to 30% by mass based on the total mass of the composition.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: September 28, 1999
    Assignee: Nippon Oil., Ltd.
    Inventors: Yukio Matsuzaki, Yoshihiro Iwamura, Yoshitaka Natsume
  • Patent number: 5919740
    Abstract: There are disclosed antioxidant additives for lubricating oils which exhibit reduced phosphorus volatility, the additives being sodium, potassium, lithium or oil soluble amine salts of a dialkyldithiophosphoric acid prepared by reacting P.sub.2 S.sub.5 with a mixture of alcohols consisting of (a) a polyol of the formula R(OH).sub.n where R is a C.sub.2 -C.sub.20 hydrocarbyl group and n is 2-10 and (b) an aliphatic monohydric alcohol having 3-18 carbon atoms, the mixture containing relative amounts of polyol and monohydric alcohol such that 50 mole % of the total OH groups are OH groups of the polyol.
    Type: Grant
    Filed: May 29, 1998
    Date of Patent: July 6, 1999
    Assignee: Exxon Chemical Patents Inc
    Inventors: Ricardo A. Bloch, Alexander B. Boffa
  • Patent number: 5865884
    Abstract: A glass forming lubricant comprising an organic titanate or an organic phospherous ester calcium salt as a lubricant agent.
    Type: Grant
    Filed: May 1, 1997
    Date of Patent: February 2, 1999
    Assignees: Asahi Glass Company Ltd., Chukyo Kasei Kogyo Co., Ltd.
    Inventors: Yutaka Segawa, Yukio Morisawa, Ryoji Nishizawa, Norio Doi
  • Patent number: 5858266
    Abstract: A refrigerating machine oil composition which comprises, in the form of a blend, a base oil comprising a mineral oil or a synthetic oil and at least one species selected from the group consisting of a metallic salt of an inorganic phosphoric acid, e.g. potassium phosphate, an amine salt of an inorganic phosphoric acid, e.g. octylamine phosphate, a metallic salt of an organic phosphoric acid, e.g. dipotassium lauryl phosphate, an amine salt of an organic phosphoric acid, e.g. monooctylamine dioleyl phosphate, a metallic salt of an organic phosphonic acid, e.g. dipotassium oleyl phosphonate, an amine salt of an organic phosphonic acid, e.g. octylamine dilauryl phosphonate, a metallic salt of an organic phosphorous acid, e.g. sodium dioleyl phoshite, and an amine salt of an organic phosphorous acid, e.g. octylamene dioleyl phosphate.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: January 12, 1999
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Masato Kaneko
  • Patent number: 5595964
    Abstract: A composition of an oil of lubricating viscosity, an antioxidant, an anti-nitration agent, and optionally a borated product of an epoxide or the reactive equivalent of an epoxide, provides a desirable lubricant for diesel or natural gas-fueled engines. The composition is substantially free from metals and preferably substantially free from phosphorus. The amount of the antioxidant the anti-initration agent are sufficient to reduce the amount of varnish formation in a natural gas engine.
    Type: Grant
    Filed: September 1, 1995
    Date of Patent: January 21, 1997
    Assignee: The Lubrizol Corporation
    Inventor: Ewa A. Bardasz