The Single Bonded Chalcogen Is Bonded Directly To An Additional Carbon, Which Carbon May Be Single Bonded To Any Atom But May Be Multiple Bonded Only To Carbon (i.e., Thiocarboxy Esters) Patents (Class 508/444)
  • Patent number: 11634655
    Abstract: A multi-grade lubricating oil including a (meth)acrylate polymer with at least two distinct molecular weight arms and a blend of heavier and lighter base oils with increased amounts of the heavier base oil to achieve SAE grade performance. The compositions herein achieve SAE certifications as lower CCS viscosities at target kinematic viscosities for multi-grade oils.
    Type: Grant
    Filed: March 30, 2021
    Date of Patent: April 25, 2023
    Assignee: AFTON CHEMICAL CORPORATION
    Inventors: Arturo Carranza, Neil Harris
  • Patent number: 9175237
    Abstract: This invention encompasses trunk piston engine lubricating oil compositions, comprising a major amount of one or more Group I base oils; and one or more dispersant additives, wherein the concentration of the one or more dispersant additives within the trunk piston engine lubricating oil composition is about 0.2-0.6 wt. % on an actives basis; and methods for making and using the trunk piston engine lubricating oil compositions.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: November 3, 2015
    Assignee: CHEVRON ORONITE TECHNOLOGY B.V.
    Inventor: Marcel Verlinde
  • Patent number: 8795547
    Abstract: The present invention is directed to a refrigerator oil composition comprising (a) a triester species having the following structure: wherein R1, R2, R3, and R4 are the same or independently selected from hydrocarbon groups having from 2 to 20 carbon atoms and wherein “n” is an integer from 2 to 20; and (b) a refrigerant, wherein the refrigerant is a halohydrocarbon.
    Type: Grant
    Filed: August 25, 2011
    Date of Patent: August 5, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: David C. Kramer, Ravindra Shah, Stephen J. Miller, Saleh Elomari
  • Publication number: 20140045736
    Abstract: The present invention relates to a synergistic combination of an antioxidant and an antiwear additive that results in improved antioxidancy performance in turbine, hydraulic, and other industrial lubricating compositions. The invention further relates to the processes to make the improved lubricating compositions and methods of their use in industrial fluids.
    Type: Application
    Filed: May 14, 2012
    Publication date: February 13, 2014
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Seth L. Crawley, Betsy J. Butke
  • Publication number: 20130252863
    Abstract: Disclosed are compositions of a major amount of alkylated aromatics compounds, in particular alkylated naphthalene and alkylated benzene, optionally combined with API Group II, Group III, Group IV and/or ethylene copolymers, showing improved thermo-oxidation performance when containing an additive combination including an alkylated or non-alkylated diarylamine and a sulfur-containing metal passivator. Particularly, the lubricating compositions include at least 55 wt % of a base oil selected from the group consisting of alkylated naphthalene, alkylated benzene and combinations thereof, and from 0 wt % to 45 wt % of another base oil component. The ratio of amine component to sulfur component in the additive combination is from 1:1 to 20:1. The compositions contain an amount of base oil other than alkylated naphthalene, alkylated benzene and API Group II, Group III, Group IV and/or ethylene copolymers of less than 10 wt % based on the total weight of the components comprising the lubricating composition.
    Type: Application
    Filed: March 8, 2013
    Publication date: September 26, 2013
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Kathleen Kim Cooper, Angela S. Galiano-Roth, David Alan Blain, Eugenio Sanchez, Nilka Yajaira Leon, James T. Carey, Oleg Yurievich Melnichenko
  • Publication number: 20130244917
    Abstract: Lubricant compositions include: (a) one or more polyalkylene glycol base oils obtained by polymerization or copolymerization of alkylene oxides comprising from 3 to 8 carbon atoms, include at least one butylene oxide and (b) at least one detergent chosen from salicylates or phenates. The present disclosure also relates to: 1) use of a lubricant composition as engine oil, preferably as oil for the engines of petrol or diesel motor vehicles; 2) use of a group of additives for an engine lubricant comprising polyalkylene glycol bases obtained by polymerization or copolymerization of alkylene oxides comprising from 3 to 8 carbon atoms; and 3) use of at least one additive chosen from salicylates, phenates, dithiocarbamates, amine-based or phenol-based antioxidants, preferably from salicylates or phenates, for reducing the Noack volatility of the base oils of polyalkylene glycol type, obtained from alkylene oxides comprising from 3 to 8 carbon atoms.
    Type: Application
    Filed: November 24, 2011
    Publication date: September 19, 2013
    Applicants: DOW GLOBAL TECHNOLOGIES LLC, TOTAL RAFFINAGE MARKETING
    Inventors: Nicholas Obrecht, Julien Guerin, Nadjet Khelidj
  • Publication number: 20130172221
    Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and a nitrile compound. The invention further relates to a method of the lubricating an internal combustion engine with the lubricating composition.
    Type: Application
    Filed: December 10, 2010
    Publication date: July 4, 2013
    Applicant: THE LUBRIZOL CORPORATION
    Inventors: Richard Yodice, Seth L. Crawley, Jody A. Kocsis
  • Publication number: 20120108479
    Abstract: A compressor lubricant composition providing energy savings and exhibiting excellent oxidation stability is provided, as well as a process for preparation of the lubricant composition. The composition comprises: (i) from 68 to 99.999 wt % of an isomerized base oil or blend of isomerized base oils; (ii) 0.001 through 20 wt % of a blend of ashless additives, the ashless additives having a viscosity range at 40° C. of from 50 mm2/s to 60 mm2/s, a density at 20° C. of from 0.95 through 1.05 g/cm3, a flash point of greater than 100° C. (COC), solubility in mineral oil of greater than 5 wt %, sulfur content of from 4.8 wt % through 6.0 wt %, and phosphorus content of from 2.9 through 3.6 wt %; (iii) less than 1.0 wt % of a dithiocarbamate, wherein the Conradson carbon residue is less than or equal to 3.00. The dithiocarbamate is added to the base oil blend as a top treatment.
    Type: Application
    Filed: October 28, 2010
    Publication date: May 3, 2012
    Applicant: CHEVRON U.S.A. INC.
    Inventor: Ravindra Shah
  • Publication number: 20110168479
    Abstract: A lubricant composition, which is low in friction, does not have an attacking property against polyamide resin, etc., is excellent in heat resistance, and especially does not undergo deterioration or loss of the respective characteristics in a short term when used under a high temperature environment, is provided along with a speed reduction gear and an electric power steering apparatus that use the lubricant composition. The lubricant composition has blended therein a synthetic hydrocarbon oil, a urea thickener, zinc stearate, and a sulfur-based antioxidant. A speed reduction gear has a portion of engagement of a small gear and a large gear filled with the lubricant composition. In an electric power steering apparatus, an output of a steering assisting electric motor is speed reduced and transmitted to a steering mechanism via the speed reduction gear.
    Type: Application
    Filed: October 14, 2009
    Publication date: July 14, 2011
    Applicants: JTEKT CORPORATION, KYODO YUSHI CO., LTD.
    Inventors: Ryuji Nakata, Miwa Hokii, Mitsuhiro Kakizaki, Daisuke Tsutsui
  • Publication number: 20110143977
    Abstract: A lubricating composition containing (a). at least 3 weight percent of an overbased sulphonate detergent with a metal ratio of 12.5:1 to 40:1; (b). at least 1.5 weight percent of a sulphur containing phenate detergent with a metal ratio of not more 2.5; and (c). an oil of lubricating viscosity, wherein the sulphur containing phenate contains oligomers of hydrocarbyl phenol with at least 50 wt % of said oligomers in the form of the tetramer or higher oligomers. The composition is suitable for internal combustion engines, particularly marine diesel applications to provide improved cleanliness decreased cylinder wear and reduced deposits.
    Type: Application
    Filed: May 9, 2005
    Publication date: June 16, 2011
    Inventors: Stephen J. Cook, Richard Leahy, Alexandra Mayhew
  • Patent number: 7772170
    Abstract: Antimony dithiocarbamate is known to provide extreme pressure (EP) protection in lubricating compositions, such as grease. However, there is a desire to reduce the amount of antimony used in such compositions, while still maintaining acceptable EP performance. It has now been found by using small amounts of either ammonium dithiocarbamate or zinc dithiocarbamate in combination with the antimony dithiocarbamate (SbDTC), a lower amount of SbDTC can be used in the lubricating composition while still maintaining excellent or exceptional EP protection. To counteract the corrosive effects of the SbDTC and ammonium dithiocarbamate composition, it has been found that compounds containing a carboxylic acid group are effective in avoiding copper corrosion.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: August 10, 2010
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventors: Ronald J. Hiza, Gaston A. Aguilar, Steven G. Donnelly, Francis S. Cheng, Ronald J. Tepper
  • Publication number: 20100105581
    Abstract: The problem to be solved by the present invention is to provide an ionic liquid-containing lubricating oil composition that has extremely low viscosity and does not evaporate during use. This problem is solved through the use of a lubricating oil composition that contains as a base oil an ionic liquid with a kinematic viscosity of 5-20 mm2/s at 40° C., and a polymerization inhibitor with a molecular weight of 200-600.
    Type: Application
    Filed: October 26, 2009
    Publication date: April 29, 2010
    Inventors: Takanori Shiraishi, Katsushi Hirata
  • Patent number: 7598211
    Abstract: An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: October 6, 2009
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventors: Thomas J. Karol, Steven G. Donnelly
  • Patent number: 7521401
    Abstract: Fuels, especially hydrocarbon fuels, and lubricants, especially lubricating oils, contain dithiocarbamyl ?-hydroxy fatty acid esters, a class of anti-corrosion, anti-wear, anti-fatigue, and extreme pressure additives that are derived from epoxidized fatty acid esters. The additives exhibit synergistic anti-wear activity in combination with phosphorus containing additives.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: April 21, 2009
    Assignee: ChemTura Corporation
    Inventor: Robert G. Rowland
  • Publication number: 20080132435
    Abstract: Process for hydroconversion of loads of mixtures of waxes from renewable resources that may be made up of waxes of mineral origin or waxes of animal origin, that may be used in their pure form or mixed in any proportion, that may optionally be combined with loads of hydrocarbons of mineral origin, as is the case of waxes obtained from petroleum, by industrial treatment. This mixture flow is submitted to a hydrotreatment and hydroisomerization/hydrofinishing process and the referenced process takes place under the usual hydroconversion conditions, in the presence of a hydrogen stream and hydroconversion catalysts, resulting in obtaining products referred to as biolubricants and bioparaffins, that present characteristics of being biodegradable and less of an environmental pollutant.
    Type: Application
    Filed: June 5, 2007
    Publication date: June 5, 2008
    Applicant: PETROLEO BRASILEIRO S.A. - PETROBRAS
    Inventors: Anita Eleonora Ferreira Fontes, Wlamir Soares Nogueira, Fernando Antonio Duarte Santiago, Jefferson Roberto Gomes
  • Patent number: 7183241
    Abstract: A lubricating oil with very low phosphorus content, and having long life as evidenced by a reduction in viscosity increase, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents, at least a zinc dialkyldithiocarbamate and a zinc dialkyldithiophosphate antiwear additive and at least a dihydrocarbylthiocarbamoyl.
    Type: Grant
    Filed: September 19, 2003
    Date of Patent: February 27, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: Stanley James Cartwright
  • Patent number: 7160845
    Abstract: Dithiocarbamate derivative compounds, useful as multifunctional additives for lubricating oils and fuels, are provided and are derived from a reaction product obtained from (a) a di(hydrocarbyl)thiocarbamate intermediate derived from the reaction of a dihydrocarbylamine and carbon disulfide; (b) an amide of the general formula R7CONH2 wherein R7 is an alkylene group having 2 to about 30 carbon atoms; and (c) an effective amount of a carbonyl-containing compound.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: January 9, 2007
    Assignee: Crompton Corporation
    Inventors: John R. Baranski, Theodore E. Nalesnik
  • Patent number: 7112558
    Abstract: The invention relates to a lubricating composition comprising a base oil of lubricating viscosity, a hydroxy-substituted dithiocarbamate, an organo-molybdenum compound, and optionally a phosphorous source.
    Type: Grant
    Filed: February 8, 2002
    Date of Patent: September 26, 2006
    Assignee: Afton Chemical Intangibles LLC
    Inventor: Vincent J. Gatto
  • Patent number: 6887295
    Abstract: The present invention relates to improved metallurgical powder compositions that incorporate solid lubricants, methods for preparing and using the same, and methods of making compacted parts. Ejection properties, such as stripping pressure and sliding pressure, of compacted parts can be improved by using the solid lubricants. The solid lubricants contain functionalized polyalkylene glycol lubricants that contain a phosphate group, phosphite group, hypophosphate group, hypophosphite group, polyphosphate group, thiophosphate group, dithiophosphate group, thiocarbamate group, dithiocarbamate group, borate group, thiosulfate group, sulfate group, a sulfonate group or combinations thereof.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: May 3, 2005
    Assignee: Hoeganaes Corporation
    Inventors: George Poszmik, Sydney Luk
  • Patent number: 6872693
    Abstract: This invention relates to mineral oil based gear oils and transmission fluids which comprise a major amount of a mineral oil having an iodine number of less than 9 and where at least 55% of the saturates are aliphatic, and gear oil or transmission fluid additives. In one embodiment, the invention relates to a gear oil or transmission fluid composition comprising a major amount of lubricant basestock and at least one functional additive wherein a major amount of the lubricant basestock comprises a mineral oil having an iodine number of less than 9 and comprising at least 45% by weight of aliphatic saturates. These gear oils and transmission fluids have good viscosity and oxidation properties.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: March 29, 2005
    Assignee: The Lubrizol Corporation
    Inventor: Robert W. Cain
  • Patent number: 6852680
    Abstract: This invention relates to a low cost, wear inhibitor containing novel dithiocarbamates with alkylthio and hydroxy substituents that can be used to formulate low phosphorus lubricants. In addition to wear inhibition, the dithiocarbamate compositions of the invention provide substantial oxidation protection to lubricating oils and are not detrimental to fuel economy.
    Type: Grant
    Filed: October 26, 2001
    Date of Patent: February 8, 2005
    Assignee: Ethyl Corporation
    Inventor: Vincent James Gatto
  • Publication number: 20040248745
    Abstract: An ashless natural gas engine lubricating composition which has enhanced resistance to oxidation, nitration and viscosity increase employs as additives in a lubricating oil basestock a combination of phenolic and alkylthiocarbamoyl antioxidants and an ashless phosphorous antiwear additive.
    Type: Application
    Filed: April 23, 2004
    Publication date: December 9, 2004
    Inventor: S. James Cartwright
  • Patent number: 6806241
    Abstract: Disclosed are antioxidant compositions comprising of: (1) an organomolybdenum compound; (2) an alkylated diphenylamine; and (3) a sulfur compound selected from the group consisting of: (a) thiadiazole; (b) dithiocarbamate; and (c) mixtures of (a) and (b).
    Type: Grant
    Filed: September 19, 2002
    Date of Patent: October 19, 2004
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventors: Thomas J. Karol, Steven G. Donnelly, Ronald J. Hiza
  • Publication number: 20040138073
    Abstract: An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.
    Type: Application
    Filed: October 2, 2003
    Publication date: July 15, 2004
    Applicant: R.T. Vanderbilt Company, Inc.
    Inventors: Thomas J. Karol, Steven G. Donnelly
  • Publication number: 20040110646
    Abstract: A long life lubricating oil, as evidenced by a reduction in oil thickening, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents and at least one trinuclear molybdenum compound.
    Type: Application
    Filed: October 10, 2003
    Publication date: June 10, 2004
    Inventor: Stanley James Cartwright
  • Patent number: 6743759
    Abstract: This invention relates to improved antioxidant antiwear/extreme pressure compositions consisting of (a) methylenebis(di-n-butyldithiocarbamate) and (b) a diphenylamine derivative of tolutriazole or benzotriazole wherein the (a):(b) mass precent ratio ranges from above about 4:1 to about 50:1 and lubricating compositions containing same.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: June 1, 2004
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventors: Brian W. Stunkel, Thomas J. Karol, Steven G. Donnelly
  • Publication number: 20030158051
    Abstract: Disclosed are antioxidant compositions comprising of:
    Type: Application
    Filed: September 19, 2002
    Publication date: August 21, 2003
    Inventors: Thomas J. Karol, Steven G. Donnelly, Ronald J. Hiza
  • Publication number: 20030139301
    Abstract: This invention relates to a low cost, wear inhibitor containing novel dithiocarbamates with alkylthio and hydroxy substituents that can be used to formulate low phosphorus lubricants. In addition to wear inhibition, the dithiocarbamate compositions of the invention provide substantial oxidation protection to lubricating oils and are not detrimental to fuel economy.
    Type: Application
    Filed: October 26, 2001
    Publication date: July 24, 2003
    Inventor: Vincent James Gatto
  • Publication number: 20030134753
    Abstract: This invention relates to improved antioxidant antiwear/extreme pressure compositions consisting of (a) methylenebis(di-n-butyldithiocarbamate) and (b) a diphenylamine derivative of tolutriazole or benzotriazole wherein the (a):(b) mass precent ratio ranges from above about 4:1 to about 50:1 and lubricating compositions containing same.
    Type: Application
    Filed: November 19, 2002
    Publication date: July 17, 2003
    Applicant: R.T. Vanderbilt Company, Inc.
    Inventors: Brian W. Stunkel, Thomas J. Karol, Steven G. Donnelly
  • Publication number: 20020086803
    Abstract: A premium synthetic lubricant having antiwear properties comprises a synthetic isoparaffinic hydrocarbon base stock and an effective amount of at least one antiwear additive. The antiwear additive is preferably at least one of a metal phosphate, a metal dialkyldithiophosphate, a metal dithiophosphate a metal thiocarbamate, a metal dithiocarbamate, an ethoxylated amine dialkyldithiophosphate and an ethoxylated amine dithiobenzoate. Metal dialkyldithiophosphates are preferred, particularly zincdialkyldithiophosphate (ZDDP). The base stock is derived from a waxy, Fischer-Tropsch synthesized hydrocarbon feed fraction comprising hydrocarbons having an initial boiling point in the range of about 650-750° F., by a process which comprises hydroisomerizing the feed and dewaxing the isomerate. The lubricant may also contain hydrocarbonaceous and synthetic base stock material in admxture with the Fischer-Tropsch derived base stock.
    Type: Application
    Filed: November 9, 2001
    Publication date: July 4, 2002
    Inventors: Paul J. Berlowitz, Jacob J. Habeeb, Robert J. Wittenbrink
  • Patent number: 6258760
    Abstract: The present invention relates to a grease composition for a constant velocity joint, which has a low coefficient of friction to decrease the vibrations of CVJ, which comprises a base oil, a urea thickening agent, (A) a molybdenum dialkyldithiocarbamate, (B) at least one molybdenum di(alkyl or aryl)dithiophosphate represented by formula (I): wherein R1 represents a primary or secondary alkyl group or an aryl group, and (C) at least one sulfur-containing additive selected from the group consisting of an ashless dithiocarbamate, a polysulfide, zinc dithiocarbamate, sulfurized fat and oil, an olefin sulfide, a sulfur-phosphorus extreme pressure additive, and a thiadiazole extreme pressure additive, wherein each of the components (A), (B) and (C) is in an amount of 10% by weight or less based on the total weight of the grease composition.
    Type: Grant
    Filed: April 21, 2000
    Date of Patent: July 10, 2001
    Assignees: Showa Shell Sekiyu K.K., NTN Corporation
    Inventors: Takahiro Ozaki, Tsutomu Yoshida, Takao Nishimura, Ryuichi Masumori, Keizo Nagasawa, Yukio Asahara
  • Patent number: 6103673
    Abstract: A composition comprising of an oil of lubricating viscosity; a shear stable viscosity modifier; at least 0.1 percent by weight of an overbased metal salt; at least 0.1 percent by weight of at least one phosphorus compound; and 0.1 to 0.25 percent by weight of a combination of at least two friction modifiers provides an improved fluid for continuously variable transmissions. At least one of the friction modifiers is selected from the group consisting of zinc salts of fatty acids having at least 10 carbon atoms, hydrocarbyl imidazolines containing at least 12 carbon atoms in the hydrocarbyl group, and borated epoxides. The total amount of the friction modifiers is limited to those amounts which provide a metal-to-metal coefficient of friction of at least about 0.120 as measured at 110.degree. C. by ASTM-G-77.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: August 15, 2000
    Assignee: The Lubrizol Corporation
    Inventors: James L. Sumiejski, William C. Ward, Jr.
  • Patent number: 6063740
    Abstract: A grease composition for rolling bearing containing a thiocarbamate derivative represented by the formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same or different groups and denote a hydrocarbon group having 1 to 18 carbon atoms, and X denotes S--Cu--S, S--Ni--S, S, S--S, S--S--S--S, S--CH.sub.2 --S, S--(CH.sub.2).sub.2 --S or S--(CH.sub.2).sub.3 --S, in an amount of 0.05 to 10 mass % with respect to the total amount of the composition. The present grease composition exhibits a long flaking life.
    Type: Grant
    Filed: October 15, 1998
    Date of Patent: May 16, 2000
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Hirotugu Kinoshita, Kiyomi Sakamoto
  • Patent number: 6001782
    Abstract: An antiwear/extreme pressure composition is disclosed that comprises a metal overbased amine of the structureR.sup.1 R.sup.2 NH(MA).sub.xwherein R.sup.1 and R.sup.2 are each independently hydrogen, or a hydrocarbyl group, amino-substituted hydrocarbyl group, hydroxy-substituted hydrocarbyl group, alkoxy-substituted hydrocarbyl group or amino groups wherein the hydrocarbyl group contains from 4 to 50 carbon atoms, provided that R.sup.1 and R.sup.2 are not both hydrogen, M is a metal, A is carbonate, sulfite, sulfate, thiosulfate, phosphite, phosphate, or mixtures thereof, and x has a value of from 1.1 to 40;wherein said metal overbased amine is reacted with carbon disulfide to form a sulfur derivative of a metal overbased amine, an epoxide followed by phosphorus pentoxide to form a phosphorus derivative of a metal overbased amine or wherein the sulfur derivative is further reacted with an epoxide followed by phosphorus pentoxide to form a sulfur and phosphorus derivative of a metal overbased amine.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: December 14, 1999
    Assignee: The Lubrizol Corporation
    Inventor: Nai Z. Huang
  • Patent number: 5912212
    Abstract: A lubricating oil composition comprises (A) a base oil, (B) a 3-methyl-5-tert-butyl-4-hydroxyphenyl substituted fatty acid ester in an amount of 0.1-5 percent by mass and (C) an auxiliary component, said auxiliary component being one member of the group of (a) a nitrogen-containing compound in an amount of 0.001-1 percent by mass, (b) a sulfur and/or phosphorus-containing compound in an amount of 0.1-5.0 percent by mass or (c) a phenolic compound in an amount of 0.1-5.0 percent by mass. This composition features the combination with a base oil of these specified components whereby there is provided synergistic effect conducive to inhibition or prevention of both oxidation and sludge formation while in use under elevated temperature conditions over extended periods of time.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: June 15, 1999
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Jinichi Igarashi, Yoko Matsuyama, Yutaka Shikatani, Toshio Yoshida
  • Patent number: 5902776
    Abstract: This invention relates to a composition, comprising:(A) a metal, amine or ammonium salt of a compound represented by the formula ##STR1## wherein in Formula (A-I), X.sup.1, X.sup.2 and X.sup.3 and X.sup.4 are independently O or S, X.sup.1 and X.sup.2 can be NR.sup.3, a and b are independently zero or 1, and R.sup.1, R.sup.2 and R.sup.3 are independently hydrocarbyl groups and R.sup.3 can be hydrogen; and(B) a thiocarbamate represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (B-I)wherein in Formula (B-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is 1 or 2; and Z is an activating group, a hydrocarbyl group, a hydroxy hydrocarbyl group, a hetero group, or a --SC(X)--NR.sup.1 R.sup.2 group; provided that when a is 2, Z is an activating group.
    Type: Grant
    Filed: May 7, 1998
    Date of Patent: May 11, 1999
    Assignee: The Lubrizol Corporation
    Inventors: Brent R. Dohner, James A. Supp
  • Patent number: 5880073
    Abstract: A lubricating oil composition comprising (A) a base oil containing 3% by weight or less of aromatics, 20% by weight or more of monocyclic naphthenes, 50 ppm by weight or less of N and 50 ppm by weight or less of S, having a viscosity (100.degree. C.) of 2 to 50 mm.sup.2 /s, (B) alkyldiphenylamines and/or phenyl-alpha-naphthylamines in an amount of 0.05 to 2% by weight of the total weight of the composition, and (C) C.sub.8 -C.sub.23 MoDTC and/or C.sub.8 -C.sub.18 MoDTP and/or C.sub.8 -C.sub.18 MoDTX in such an amount that the amount of Mo is 50 to 2000 ppm by weight of the total weight of the composition. The lubricating oil composition has high heat resistance, high oxidation stability and excellent lubricating properties, and is particularly useful for a lubricating oil for internal combustion engines and the like.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: March 9, 1999
    Assignee: Tonen Corporation
    Inventors: Hirotaka Tomizawa, Arai Katsuya
  • Patent number: 5807813
    Abstract: A lubricating oil composition comprising a base oil, (A) at least one compound selected from the group consisting of molybdenum dithiocarbamate and molybdenum dithiophosphate, and (B) an aromatic compound having at least one functional group selected from the group consisting of hydroxyl group, carboxyl group, mercapto group, and thiocarboxyl group on the aromatic ring. The lubricating oil composition maintains the low friction property to achieve sustained low fuel consumption during the use and also enables using the organic molybdenum compound added as the friction modifier in a smaller amount than the amount required in conventional lubricating oil compositions.
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: September 15, 1998
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Ryou Yamada
  • Patent number: 5789357
    Abstract: Dithiocarbamyl carboxylic acids, useful as multifunctional additives for lubricating oils, possess the general formula: ##STR1## wherein R.sup.1 and R.sup.2 each independently is a hydrocarbyl group of from 1 to about 60 carbon atoms and R.sup.3 is a divalent alkylene group of from 1 to about 20 carbon atoms.
    Type: Grant
    Filed: January 10, 1997
    Date of Patent: August 4, 1998
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: John R. Baranski, Cyril A. Migdal, Robert G. Rowland
  • Patent number: 5783735
    Abstract: A process for preparing polymeric amides is disclosed. The process comprises sequentially reacting a hydrocarbon polymer functionalized (e.g., via the Koch reaction) to contain acid, ester, thioacid and/or thioester groups with a heavy polyamine to form a partially derivatized product in which at least about 85% of the functional groups are converted to heavy (thio)amide groups, and then reacting the partially derivatized product with an excess of light amine to complete the derivatization by converting substantially all of the remaining functional groups to light (thio)amide groups. Products of the foregoing process are also disclosed, which products are useful as additives in fuels and in lubricants.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: July 21, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob I. Emert, Joseph V. Cusumano, David C. Dankworth, William D. Diana, William B. Eckstrom, Keith R. Gorda, Antonio Gutierrez, Jon E. Stanat, Warren A. Thaler, Stephen Zushma
  • Patent number: 5767046
    Abstract: A hydrocarbon composition functionalized via the Koch reaction which is the reaction product of at least one hydrocarbon having a number average molecular weight of less than 500 and at least one ethylenic double bond per molecule, with carbon monoxide and a nucleophilic trapping agent. The hydrocarbon is usefully functionalized and derivatized, producing, in particular, lubricants suitable for use in two-cycle engines.
    Type: Grant
    Filed: May 15, 1997
    Date of Patent: June 16, 1998
    Assignee: Exxon Chemical Company
    Inventors: Joseph V. Cusumano, William D. Diana, William B. Eckstrom, Jacob I. Emert, Keith R. Gorda, Michael J. Keenan, Richard H. Schlosberg
  • Patent number: 5759965
    Abstract: This invention relates to a composition, comprising: (A) a boron-containing overbased material; (B) a phosphorus acid, ester or derivative thereof; and (C) a borated epoxide or borated fatty acid ester of glycerol. In one embodiment the inventive composition further comprises (D) a thiocarbamate. These compositions are useful in providing lubricants and functional fluids, particularly automatic transmission fluids, with enhanced antiwear properties. In one embodiment these compositions also provide such lubricants and functional fluids with enhanced extreme-pressure and/or friction-modifying.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: June 2, 1998
    Assignee: The Lubrizol Corporation
    Inventor: James L. Sumiejski
  • Patent number: 5726135
    Abstract: Phosphorus-free and ashless high-temperature aircraft and turbo engine lubricant that contains no halogens or hazardous substances is disclosed. The phosphorus-free lubricating oil may be prepared from pentaerythritol tetraester, methylolpropane triester, or their combinations, ashless dithiocarbamate additives, a dialkydiphenylamine, an alkylphenylnaphthylamine, a triazole derivative, a rest inhibitor or metal deactivator, and an anti-foam. The use of this lubricating oil in addition to its superior wear and friction performance over the standard lubricating oil provides a safe and an environmentally benign gas turbine engine oil for aircraft and turbo engines.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: March 10, 1998
    Inventor: Behrooz A. Khorramian
  • Patent number: 5726132
    Abstract: This invention relates to compositions for improving fuel efficiency in internal combustion engines. The composition comprises a lubricant having an oil of lubricating viscosity and (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: March 10, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Stephen H. Roby, James A. Supp, John S. Manka, William D. Abraham
  • Patent number: 5712230
    Abstract: This invention relates to a composition, comprising: (AT) reaction products of compounds represented by the formula (A)and compounds selected to reduce the polysulfide components of (A); and ##STR1## wherein in Formula (A), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3 (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: January 27, 1998
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, John S. Manka, Stephen H. Roby, James A. Supp
  • Patent number: 5698498
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) a minor amount of at least one hydroxyalkyl dithiocarbamate or at least one borate thereof, wherein the dithiocarbamate is derived from an amine other than an alkyl or alkenylsuccinimide. In another aspect the invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, a hydroxyalkyl dithiocarbamate or a borate thereof, and (B) at least one sulfur compound or (C) at least one phosphorus or boron antiwear or extreme pressure agent. The invention also relates to greases, functional fluids and aqueous fluids containing the hydroxyalkyl dithiocarbamates and borates thereof. The lubricants and fluids have improved antiwear and extreme pressure properties including providing improved antiscuff protection.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: December 16, 1997
    Assignee: The Lubrizol Corporation
    Inventors: Carmen V. Luciani, Syed Q. A. Rizvi, Bernard C. Roell, Jr.
  • Patent number: 5693598
    Abstract: This invention relates to a low-viscosity lubricating oil and functional fluid compositions, comprising: a major amount of an oil having a kinematic viscosity of up to about 4 cST at 100.degree. C.; and a minor antiwear amount of(A) a compound represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (A-I)wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is zero, 1 or 2; and Z is a hydrocarbyl group, a hetero group, a hydroxy hydrocarbyl group, an activating group, or a --(S).sub.b C(X)--NR.sup.1 R.sup.2 group wherein b is zero, 1 or 2; provide that when a is 2, Z is an activating group; and when a is zero, Z can be an ammonium, amine or metal cation. In one embodiment this composition further comprises (B) a phosphorus compound.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: December 2, 1997
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, Brent R. Dohner, John S. Manka, Stephen H. Roby, James A. Supp
  • Patent number: 5674820
    Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms, In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof, In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxytic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: October 7, 1997
    Assignee: The Lubrizol Corporation
    Inventors: John S. Manka, William D. Abraham, Stephen H. Roby, James A. Supp, Craig D. Tipton
  • Patent number: 5604187
    Abstract: A grease composition for constant velocity joints which consists essentially of: (a) a base oil; (b) a diurea compound represented by the following general formula:R.sup.1 NH--CO--NH--p--C.sub.6 H.sub.4 --CH.sub.2 --p--C.sub.6 H.sub.4 --NH--CO--NHR.sup.2(wherein R.sup.1 and R.sup.3 may be the same or different and each represents an aryl group or a cyclohexyl group); (c) melamine cyanurate; (d) molybdenum disulfide; and (e) a phosphorus-free sulfur extreme pressure agent, and optionally (f) molybdenum dithiocarbamate.The grease composition exhibits excellent pitting-inhibitory effect and heat resistance.
    Type: Grant
    Filed: April 16, 1996
    Date of Patent: February 18, 1997
    Assignees: Kyodo Yushi Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Kiyoshi Takeuchi, Tsuyoshi Sasaki, Tomio Hanawa, Yoshimi Usui, Takahiro Ogura
  • Patent number: 5589444
    Abstract: A grease composition for constant velocity joints consists essentially of: (a) a base oil; (b) an urea thickener; (c) molybdenum disulfide; (d) a calcium salt or an overbasic calcium salt selected from the group consisting of calcium salts or overbasic calcium salts of oxidized waxes, petroleum sulfonates, alkyl aryl sulfonates, salicylate, and phenates; (e) a metal-free sulfur-phosphorus extreme pressure agent; and (f) molybdenum dithiocarbamate. The grease composition exhibits excellent wear-resistance and pitting-inhibitory effect.
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: December 31, 1996
    Assignee: Kyodo Yushi Co., Ltd.
    Inventor: Ko Hatakeyama