The Single Bonded Chalcogen Is Bonded Directly To An Additional Carbon, Which Carbon May Be Single Bonded To Any Atom But May Be Multiple Bonded Only To Carbon (i.e., Thiocarboxy Esters) Patents (Class 508/444)
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Patent number: 11634655Abstract: A multi-grade lubricating oil including a (meth)acrylate polymer with at least two distinct molecular weight arms and a blend of heavier and lighter base oils with increased amounts of the heavier base oil to achieve SAE grade performance. The compositions herein achieve SAE certifications as lower CCS viscosities at target kinematic viscosities for multi-grade oils.Type: GrantFiled: March 30, 2021Date of Patent: April 25, 2023Assignee: AFTON CHEMICAL CORPORATIONInventors: Arturo Carranza, Neil Harris
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Patent number: 9175237Abstract: This invention encompasses trunk piston engine lubricating oil compositions, comprising a major amount of one or more Group I base oils; and one or more dispersant additives, wherein the concentration of the one or more dispersant additives within the trunk piston engine lubricating oil composition is about 0.2-0.6 wt. % on an actives basis; and methods for making and using the trunk piston engine lubricating oil compositions.Type: GrantFiled: December 12, 2007Date of Patent: November 3, 2015Assignee: CHEVRON ORONITE TECHNOLOGY B.V.Inventor: Marcel Verlinde
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Patent number: 8795547Abstract: The present invention is directed to a refrigerator oil composition comprising (a) a triester species having the following structure: wherein R1, R2, R3, and R4 are the same or independently selected from hydrocarbon groups having from 2 to 20 carbon atoms and wherein “n” is an integer from 2 to 20; and (b) a refrigerant, wherein the refrigerant is a halohydrocarbon.Type: GrantFiled: August 25, 2011Date of Patent: August 5, 2014Assignee: Chevron U.S.A. Inc.Inventors: David C. Kramer, Ravindra Shah, Stephen J. Miller, Saleh Elomari
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Publication number: 20140045736Abstract: The present invention relates to a synergistic combination of an antioxidant and an antiwear additive that results in improved antioxidancy performance in turbine, hydraulic, and other industrial lubricating compositions. The invention further relates to the processes to make the improved lubricating compositions and methods of their use in industrial fluids.Type: ApplicationFiled: May 14, 2012Publication date: February 13, 2014Applicant: THE LUBRIZOL CORPORATIONInventors: Seth L. Crawley, Betsy J. Butke
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Publication number: 20130252863Abstract: Disclosed are compositions of a major amount of alkylated aromatics compounds, in particular alkylated naphthalene and alkylated benzene, optionally combined with API Group II, Group III, Group IV and/or ethylene copolymers, showing improved thermo-oxidation performance when containing an additive combination including an alkylated or non-alkylated diarylamine and a sulfur-containing metal passivator. Particularly, the lubricating compositions include at least 55 wt % of a base oil selected from the group consisting of alkylated naphthalene, alkylated benzene and combinations thereof, and from 0 wt % to 45 wt % of another base oil component. The ratio of amine component to sulfur component in the additive combination is from 1:1 to 20:1. The compositions contain an amount of base oil other than alkylated naphthalene, alkylated benzene and API Group II, Group III, Group IV and/or ethylene copolymers of less than 10 wt % based on the total weight of the components comprising the lubricating composition.Type: ApplicationFiled: March 8, 2013Publication date: September 26, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Kathleen Kim Cooper, Angela S. Galiano-Roth, David Alan Blain, Eugenio Sanchez, Nilka Yajaira Leon, James T. Carey, Oleg Yurievich Melnichenko
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Publication number: 20130244917Abstract: Lubricant compositions include: (a) one or more polyalkylene glycol base oils obtained by polymerization or copolymerization of alkylene oxides comprising from 3 to 8 carbon atoms, include at least one butylene oxide and (b) at least one detergent chosen from salicylates or phenates. The present disclosure also relates to: 1) use of a lubricant composition as engine oil, preferably as oil for the engines of petrol or diesel motor vehicles; 2) use of a group of additives for an engine lubricant comprising polyalkylene glycol bases obtained by polymerization or copolymerization of alkylene oxides comprising from 3 to 8 carbon atoms; and 3) use of at least one additive chosen from salicylates, phenates, dithiocarbamates, amine-based or phenol-based antioxidants, preferably from salicylates or phenates, for reducing the Noack volatility of the base oils of polyalkylene glycol type, obtained from alkylene oxides comprising from 3 to 8 carbon atoms.Type: ApplicationFiled: November 24, 2011Publication date: September 19, 2013Applicants: DOW GLOBAL TECHNOLOGIES LLC, TOTAL RAFFINAGE MARKETINGInventors: Nicholas Obrecht, Julien Guerin, Nadjet Khelidj
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Publication number: 20130172221Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and a nitrile compound. The invention further relates to a method of the lubricating an internal combustion engine with the lubricating composition.Type: ApplicationFiled: December 10, 2010Publication date: July 4, 2013Applicant: THE LUBRIZOL CORPORATIONInventors: Richard Yodice, Seth L. Crawley, Jody A. Kocsis
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Publication number: 20120108479Abstract: A compressor lubricant composition providing energy savings and exhibiting excellent oxidation stability is provided, as well as a process for preparation of the lubricant composition. The composition comprises: (i) from 68 to 99.999 wt % of an isomerized base oil or blend of isomerized base oils; (ii) 0.001 through 20 wt % of a blend of ashless additives, the ashless additives having a viscosity range at 40° C. of from 50 mm2/s to 60 mm2/s, a density at 20° C. of from 0.95 through 1.05 g/cm3, a flash point of greater than 100° C. (COC), solubility in mineral oil of greater than 5 wt %, sulfur content of from 4.8 wt % through 6.0 wt %, and phosphorus content of from 2.9 through 3.6 wt %; (iii) less than 1.0 wt % of a dithiocarbamate, wherein the Conradson carbon residue is less than or equal to 3.00. The dithiocarbamate is added to the base oil blend as a top treatment.Type: ApplicationFiled: October 28, 2010Publication date: May 3, 2012Applicant: CHEVRON U.S.A. INC.Inventor: Ravindra Shah
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Publication number: 20110168479Abstract: A lubricant composition, which is low in friction, does not have an attacking property against polyamide resin, etc., is excellent in heat resistance, and especially does not undergo deterioration or loss of the respective characteristics in a short term when used under a high temperature environment, is provided along with a speed reduction gear and an electric power steering apparatus that use the lubricant composition. The lubricant composition has blended therein a synthetic hydrocarbon oil, a urea thickener, zinc stearate, and a sulfur-based antioxidant. A speed reduction gear has a portion of engagement of a small gear and a large gear filled with the lubricant composition. In an electric power steering apparatus, an output of a steering assisting electric motor is speed reduced and transmitted to a steering mechanism via the speed reduction gear.Type: ApplicationFiled: October 14, 2009Publication date: July 14, 2011Applicants: JTEKT CORPORATION, KYODO YUSHI CO., LTD.Inventors: Ryuji Nakata, Miwa Hokii, Mitsuhiro Kakizaki, Daisuke Tsutsui
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Publication number: 20110143977Abstract: A lubricating composition containing (a). at least 3 weight percent of an overbased sulphonate detergent with a metal ratio of 12.5:1 to 40:1; (b). at least 1.5 weight percent of a sulphur containing phenate detergent with a metal ratio of not more 2.5; and (c). an oil of lubricating viscosity, wherein the sulphur containing phenate contains oligomers of hydrocarbyl phenol with at least 50 wt % of said oligomers in the form of the tetramer or higher oligomers. The composition is suitable for internal combustion engines, particularly marine diesel applications to provide improved cleanliness decreased cylinder wear and reduced deposits.Type: ApplicationFiled: May 9, 2005Publication date: June 16, 2011Inventors: Stephen J. Cook, Richard Leahy, Alexandra Mayhew
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Patent number: 7772170Abstract: Antimony dithiocarbamate is known to provide extreme pressure (EP) protection in lubricating compositions, such as grease. However, there is a desire to reduce the amount of antimony used in such compositions, while still maintaining acceptable EP performance. It has now been found by using small amounts of either ammonium dithiocarbamate or zinc dithiocarbamate in combination with the antimony dithiocarbamate (SbDTC), a lower amount of SbDTC can be used in the lubricating composition while still maintaining excellent or exceptional EP protection. To counteract the corrosive effects of the SbDTC and ammonium dithiocarbamate composition, it has been found that compounds containing a carboxylic acid group are effective in avoiding copper corrosion.Type: GrantFiled: February 10, 2006Date of Patent: August 10, 2010Assignee: R.T. Vanderbilt Company, Inc.Inventors: Ronald J. Hiza, Gaston A. Aguilar, Steven G. Donnelly, Francis S. Cheng, Ronald J. Tepper
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Publication number: 20100105581Abstract: The problem to be solved by the present invention is to provide an ionic liquid-containing lubricating oil composition that has extremely low viscosity and does not evaporate during use. This problem is solved through the use of a lubricating oil composition that contains as a base oil an ionic liquid with a kinematic viscosity of 5-20 mm2/s at 40° C., and a polymerization inhibitor with a molecular weight of 200-600.Type: ApplicationFiled: October 26, 2009Publication date: April 29, 2010Inventors: Takanori Shiraishi, Katsushi Hirata
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Patent number: 7598211Abstract: An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.Type: GrantFiled: October 2, 2003Date of Patent: October 6, 2009Assignee: R.T. Vanderbilt Company, Inc.Inventors: Thomas J. Karol, Steven G. Donnelly
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Patent number: 7521401Abstract: Fuels, especially hydrocarbon fuels, and lubricants, especially lubricating oils, contain dithiocarbamyl ?-hydroxy fatty acid esters, a class of anti-corrosion, anti-wear, anti-fatigue, and extreme pressure additives that are derived from epoxidized fatty acid esters. The additives exhibit synergistic anti-wear activity in combination with phosphorus containing additives.Type: GrantFiled: November 14, 2005Date of Patent: April 21, 2009Assignee: ChemTura CorporationInventor: Robert G. Rowland
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Publication number: 20080132435Abstract: Process for hydroconversion of loads of mixtures of waxes from renewable resources that may be made up of waxes of mineral origin or waxes of animal origin, that may be used in their pure form or mixed in any proportion, that may optionally be combined with loads of hydrocarbons of mineral origin, as is the case of waxes obtained from petroleum, by industrial treatment. This mixture flow is submitted to a hydrotreatment and hydroisomerization/hydrofinishing process and the referenced process takes place under the usual hydroconversion conditions, in the presence of a hydrogen stream and hydroconversion catalysts, resulting in obtaining products referred to as biolubricants and bioparaffins, that present characteristics of being biodegradable and less of an environmental pollutant.Type: ApplicationFiled: June 5, 2007Publication date: June 5, 2008Applicant: PETROLEO BRASILEIRO S.A. - PETROBRASInventors: Anita Eleonora Ferreira Fontes, Wlamir Soares Nogueira, Fernando Antonio Duarte Santiago, Jefferson Roberto Gomes
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Patent number: 7183241Abstract: A lubricating oil with very low phosphorus content, and having long life as evidenced by a reduction in viscosity increase, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents, at least a zinc dialkyldithiocarbamate and a zinc dialkyldithiophosphate antiwear additive and at least a dihydrocarbylthiocarbamoyl.Type: GrantFiled: September 19, 2003Date of Patent: February 27, 2007Assignee: ExxonMobil Research and Engineering CompanyInventor: Stanley James Cartwright
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Patent number: 7160845Abstract: Dithiocarbamate derivative compounds, useful as multifunctional additives for lubricating oils and fuels, are provided and are derived from a reaction product obtained from (a) a di(hydrocarbyl)thiocarbamate intermediate derived from the reaction of a dihydrocarbylamine and carbon disulfide; (b) an amide of the general formula R7CONH2 wherein R7 is an alkylene group having 2 to about 30 carbon atoms; and (c) an effective amount of a carbonyl-containing compound.Type: GrantFiled: March 31, 2004Date of Patent: January 9, 2007Assignee: Crompton CorporationInventors: John R. Baranski, Theodore E. Nalesnik
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Patent number: 7112558Abstract: The invention relates to a lubricating composition comprising a base oil of lubricating viscosity, a hydroxy-substituted dithiocarbamate, an organo-molybdenum compound, and optionally a phosphorous source.Type: GrantFiled: February 8, 2002Date of Patent: September 26, 2006Assignee: Afton Chemical Intangibles LLCInventor: Vincent J. Gatto
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Patent number: 6887295Abstract: The present invention relates to improved metallurgical powder compositions that incorporate solid lubricants, methods for preparing and using the same, and methods of making compacted parts. Ejection properties, such as stripping pressure and sliding pressure, of compacted parts can be improved by using the solid lubricants. The solid lubricants contain functionalized polyalkylene glycol lubricants that contain a phosphate group, phosphite group, hypophosphate group, hypophosphite group, polyphosphate group, thiophosphate group, dithiophosphate group, thiocarbamate group, dithiocarbamate group, borate group, thiosulfate group, sulfate group, a sulfonate group or combinations thereof.Type: GrantFiled: October 25, 2002Date of Patent: May 3, 2005Assignee: Hoeganaes CorporationInventors: George Poszmik, Sydney Luk
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Patent number: 6872693Abstract: This invention relates to mineral oil based gear oils and transmission fluids which comprise a major amount of a mineral oil having an iodine number of less than 9 and where at least 55% of the saturates are aliphatic, and gear oil or transmission fluid additives. In one embodiment, the invention relates to a gear oil or transmission fluid composition comprising a major amount of lubricant basestock and at least one functional additive wherein a major amount of the lubricant basestock comprises a mineral oil having an iodine number of less than 9 and comprising at least 45% by weight of aliphatic saturates. These gear oils and transmission fluids have good viscosity and oxidation properties.Type: GrantFiled: May 24, 2000Date of Patent: March 29, 2005Assignee: The Lubrizol CorporationInventor: Robert W. Cain
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Patent number: 6852680Abstract: This invention relates to a low cost, wear inhibitor containing novel dithiocarbamates with alkylthio and hydroxy substituents that can be used to formulate low phosphorus lubricants. In addition to wear inhibition, the dithiocarbamate compositions of the invention provide substantial oxidation protection to lubricating oils and are not detrimental to fuel economy.Type: GrantFiled: October 26, 2001Date of Patent: February 8, 2005Assignee: Ethyl CorporationInventor: Vincent James Gatto
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Publication number: 20040248745Abstract: An ashless natural gas engine lubricating composition which has enhanced resistance to oxidation, nitration and viscosity increase employs as additives in a lubricating oil basestock a combination of phenolic and alkylthiocarbamoyl antioxidants and an ashless phosphorous antiwear additive.Type: ApplicationFiled: April 23, 2004Publication date: December 9, 2004Inventor: S. James Cartwright
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Patent number: 6806241Abstract: Disclosed are antioxidant compositions comprising of: (1) an organomolybdenum compound; (2) an alkylated diphenylamine; and (3) a sulfur compound selected from the group consisting of: (a) thiadiazole; (b) dithiocarbamate; and (c) mixtures of (a) and (b).Type: GrantFiled: September 19, 2002Date of Patent: October 19, 2004Assignee: R.T. Vanderbilt Company, Inc.Inventors: Thomas J. Karol, Steven G. Donnelly, Ronald J. Hiza
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Publication number: 20040138073Abstract: An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur- or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur- or phosphorus-containing compounds are dithiocarbamate, bisdithiocarbamate, 1,3,4-diathiazole, phosphorodithioate, phosphorodithioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more carbon atoms, (b) about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.Type: ApplicationFiled: October 2, 2003Publication date: July 15, 2004Applicant: R.T. Vanderbilt Company, Inc.Inventors: Thomas J. Karol, Steven G. Donnelly
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Publication number: 20040110646Abstract: A long life lubricating oil, as evidenced by a reduction in oil thickening, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents and at least one trinuclear molybdenum compound.Type: ApplicationFiled: October 10, 2003Publication date: June 10, 2004Inventor: Stanley James Cartwright
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Patent number: 6743759Abstract: This invention relates to improved antioxidant antiwear/extreme pressure compositions consisting of (a) methylenebis(di-n-butyldithiocarbamate) and (b) a diphenylamine derivative of tolutriazole or benzotriazole wherein the (a):(b) mass precent ratio ranges from above about 4:1 to about 50:1 and lubricating compositions containing same.Type: GrantFiled: November 19, 2002Date of Patent: June 1, 2004Assignee: R.T. Vanderbilt Company, Inc.Inventors: Brian W. Stunkel, Thomas J. Karol, Steven G. Donnelly
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Publication number: 20030158051Abstract: Disclosed are antioxidant compositions comprising of:Type: ApplicationFiled: September 19, 2002Publication date: August 21, 2003Inventors: Thomas J. Karol, Steven G. Donnelly, Ronald J. Hiza
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Publication number: 20030139301Abstract: This invention relates to a low cost, wear inhibitor containing novel dithiocarbamates with alkylthio and hydroxy substituents that can be used to formulate low phosphorus lubricants. In addition to wear inhibition, the dithiocarbamate compositions of the invention provide substantial oxidation protection to lubricating oils and are not detrimental to fuel economy.Type: ApplicationFiled: October 26, 2001Publication date: July 24, 2003Inventor: Vincent James Gatto
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Publication number: 20030134753Abstract: This invention relates to improved antioxidant antiwear/extreme pressure compositions consisting of (a) methylenebis(di-n-butyldithiocarbamate) and (b) a diphenylamine derivative of tolutriazole or benzotriazole wherein the (a):(b) mass precent ratio ranges from above about 4:1 to about 50:1 and lubricating compositions containing same.Type: ApplicationFiled: November 19, 2002Publication date: July 17, 2003Applicant: R.T. Vanderbilt Company, Inc.Inventors: Brian W. Stunkel, Thomas J. Karol, Steven G. Donnelly
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Publication number: 20020086803Abstract: A premium synthetic lubricant having antiwear properties comprises a synthetic isoparaffinic hydrocarbon base stock and an effective amount of at least one antiwear additive. The antiwear additive is preferably at least one of a metal phosphate, a metal dialkyldithiophosphate, a metal dithiophosphate a metal thiocarbamate, a metal dithiocarbamate, an ethoxylated amine dialkyldithiophosphate and an ethoxylated amine dithiobenzoate. Metal dialkyldithiophosphates are preferred, particularly zincdialkyldithiophosphate (ZDDP). The base stock is derived from a waxy, Fischer-Tropsch synthesized hydrocarbon feed fraction comprising hydrocarbons having an initial boiling point in the range of about 650-750° F., by a process which comprises hydroisomerizing the feed and dewaxing the isomerate. The lubricant may also contain hydrocarbonaceous and synthetic base stock material in admxture with the Fischer-Tropsch derived base stock.Type: ApplicationFiled: November 9, 2001Publication date: July 4, 2002Inventors: Paul J. Berlowitz, Jacob J. Habeeb, Robert J. Wittenbrink
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Patent number: 6258760Abstract: The present invention relates to a grease composition for a constant velocity joint, which has a low coefficient of friction to decrease the vibrations of CVJ, which comprises a base oil, a urea thickening agent, (A) a molybdenum dialkyldithiocarbamate, (B) at least one molybdenum di(alkyl or aryl)dithiophosphate represented by formula (I): wherein R1 represents a primary or secondary alkyl group or an aryl group, and (C) at least one sulfur-containing additive selected from the group consisting of an ashless dithiocarbamate, a polysulfide, zinc dithiocarbamate, sulfurized fat and oil, an olefin sulfide, a sulfur-phosphorus extreme pressure additive, and a thiadiazole extreme pressure additive, wherein each of the components (A), (B) and (C) is in an amount of 10% by weight or less based on the total weight of the grease composition.Type: GrantFiled: April 21, 2000Date of Patent: July 10, 2001Assignees: Showa Shell Sekiyu K.K., NTN CorporationInventors: Takahiro Ozaki, Tsutomu Yoshida, Takao Nishimura, Ryuichi Masumori, Keizo Nagasawa, Yukio Asahara
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Patent number: 6103673Abstract: A composition comprising of an oil of lubricating viscosity; a shear stable viscosity modifier; at least 0.1 percent by weight of an overbased metal salt; at least 0.1 percent by weight of at least one phosphorus compound; and 0.1 to 0.25 percent by weight of a combination of at least two friction modifiers provides an improved fluid for continuously variable transmissions. At least one of the friction modifiers is selected from the group consisting of zinc salts of fatty acids having at least 10 carbon atoms, hydrocarbyl imidazolines containing at least 12 carbon atoms in the hydrocarbyl group, and borated epoxides. The total amount of the friction modifiers is limited to those amounts which provide a metal-to-metal coefficient of friction of at least about 0.120 as measured at 110.degree. C. by ASTM-G-77.Type: GrantFiled: September 14, 1998Date of Patent: August 15, 2000Assignee: The Lubrizol CorporationInventors: James L. Sumiejski, William C. Ward, Jr.
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Patent number: 6063740Abstract: A grease composition for rolling bearing containing a thiocarbamate derivative represented by the formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same or different groups and denote a hydrocarbon group having 1 to 18 carbon atoms, and X denotes S--Cu--S, S--Ni--S, S, S--S, S--S--S--S, S--CH.sub.2 --S, S--(CH.sub.2).sub.2 --S or S--(CH.sub.2).sub.3 --S, in an amount of 0.05 to 10 mass % with respect to the total amount of the composition. The present grease composition exhibits a long flaking life.Type: GrantFiled: October 15, 1998Date of Patent: May 16, 2000Assignee: Nippon Oil Co., Ltd.Inventors: Hirotugu Kinoshita, Kiyomi Sakamoto
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Patent number: 6001782Abstract: An antiwear/extreme pressure composition is disclosed that comprises a metal overbased amine of the structureR.sup.1 R.sup.2 NH(MA).sub.xwherein R.sup.1 and R.sup.2 are each independently hydrogen, or a hydrocarbyl group, amino-substituted hydrocarbyl group, hydroxy-substituted hydrocarbyl group, alkoxy-substituted hydrocarbyl group or amino groups wherein the hydrocarbyl group contains from 4 to 50 carbon atoms, provided that R.sup.1 and R.sup.2 are not both hydrogen, M is a metal, A is carbonate, sulfite, sulfate, thiosulfate, phosphite, phosphate, or mixtures thereof, and x has a value of from 1.1 to 40;wherein said metal overbased amine is reacted with carbon disulfide to form a sulfur derivative of a metal overbased amine, an epoxide followed by phosphorus pentoxide to form a phosphorus derivative of a metal overbased amine or wherein the sulfur derivative is further reacted with an epoxide followed by phosphorus pentoxide to form a sulfur and phosphorus derivative of a metal overbased amine.Type: GrantFiled: December 17, 1998Date of Patent: December 14, 1999Assignee: The Lubrizol CorporationInventor: Nai Z. Huang
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Patent number: 5912212Abstract: A lubricating oil composition comprises (A) a base oil, (B) a 3-methyl-5-tert-butyl-4-hydroxyphenyl substituted fatty acid ester in an amount of 0.1-5 percent by mass and (C) an auxiliary component, said auxiliary component being one member of the group of (a) a nitrogen-containing compound in an amount of 0.001-1 percent by mass, (b) a sulfur and/or phosphorus-containing compound in an amount of 0.1-5.0 percent by mass or (c) a phenolic compound in an amount of 0.1-5.0 percent by mass. This composition features the combination with a base oil of these specified components whereby there is provided synergistic effect conducive to inhibition or prevention of both oxidation and sludge formation while in use under elevated temperature conditions over extended periods of time.Type: GrantFiled: December 18, 1996Date of Patent: June 15, 1999Assignee: Nippon Oil Co., Ltd.Inventors: Jinichi Igarashi, Yoko Matsuyama, Yutaka Shikatani, Toshio Yoshida
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Patent number: 5902776Abstract: This invention relates to a composition, comprising:(A) a metal, amine or ammonium salt of a compound represented by the formula ##STR1## wherein in Formula (A-I), X.sup.1, X.sup.2 and X.sup.3 and X.sup.4 are independently O or S, X.sup.1 and X.sup.2 can be NR.sup.3, a and b are independently zero or 1, and R.sup.1, R.sup.2 and R.sup.3 are independently hydrocarbyl groups and R.sup.3 can be hydrogen; and(B) a thiocarbamate represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (B-I)wherein in Formula (B-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is 1 or 2; and Z is an activating group, a hydrocarbyl group, a hydroxy hydrocarbyl group, a hetero group, or a --SC(X)--NR.sup.1 R.sup.2 group; provided that when a is 2, Z is an activating group.Type: GrantFiled: May 7, 1998Date of Patent: May 11, 1999Assignee: The Lubrizol CorporationInventors: Brent R. Dohner, James A. Supp
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Patent number: 5880073Abstract: A lubricating oil composition comprising (A) a base oil containing 3% by weight or less of aromatics, 20% by weight or more of monocyclic naphthenes, 50 ppm by weight or less of N and 50 ppm by weight or less of S, having a viscosity (100.degree. C.) of 2 to 50 mm.sup.2 /s, (B) alkyldiphenylamines and/or phenyl-alpha-naphthylamines in an amount of 0.05 to 2% by weight of the total weight of the composition, and (C) C.sub.8 -C.sub.23 MoDTC and/or C.sub.8 -C.sub.18 MoDTP and/or C.sub.8 -C.sub.18 MoDTX in such an amount that the amount of Mo is 50 to 2000 ppm by weight of the total weight of the composition. The lubricating oil composition has high heat resistance, high oxidation stability and excellent lubricating properties, and is particularly useful for a lubricating oil for internal combustion engines and the like.Type: GrantFiled: February 6, 1998Date of Patent: March 9, 1999Assignee: Tonen CorporationInventors: Hirotaka Tomizawa, Arai Katsuya
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Patent number: 5807813Abstract: A lubricating oil composition comprising a base oil, (A) at least one compound selected from the group consisting of molybdenum dithiocarbamate and molybdenum dithiophosphate, and (B) an aromatic compound having at least one functional group selected from the group consisting of hydroxyl group, carboxyl group, mercapto group, and thiocarboxyl group on the aromatic ring. The lubricating oil composition maintains the low friction property to achieve sustained low fuel consumption during the use and also enables using the organic molybdenum compound added as the friction modifier in a smaller amount than the amount required in conventional lubricating oil compositions.Type: GrantFiled: March 14, 1997Date of Patent: September 15, 1998Assignee: Idemitsu Kosan Co., Ltd.Inventor: Ryou Yamada
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Patent number: 5789357Abstract: Dithiocarbamyl carboxylic acids, useful as multifunctional additives for lubricating oils, possess the general formula: ##STR1## wherein R.sup.1 and R.sup.2 each independently is a hydrocarbyl group of from 1 to about 60 carbon atoms and R.sup.3 is a divalent alkylene group of from 1 to about 20 carbon atoms.Type: GrantFiled: January 10, 1997Date of Patent: August 4, 1998Assignee: Uniroyal Chemical Company, Inc.Inventors: John R. Baranski, Cyril A. Migdal, Robert G. Rowland
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Patent number: 5783735Abstract: A process for preparing polymeric amides is disclosed. The process comprises sequentially reacting a hydrocarbon polymer functionalized (e.g., via the Koch reaction) to contain acid, ester, thioacid and/or thioester groups with a heavy polyamine to form a partially derivatized product in which at least about 85% of the functional groups are converted to heavy (thio)amide groups, and then reacting the partially derivatized product with an excess of light amine to complete the derivatization by converting substantially all of the remaining functional groups to light (thio)amide groups. Products of the foregoing process are also disclosed, which products are useful as additives in fuels and in lubricants.Type: GrantFiled: May 25, 1995Date of Patent: July 21, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Jacob I. Emert, Joseph V. Cusumano, David C. Dankworth, William D. Diana, William B. Eckstrom, Keith R. Gorda, Antonio Gutierrez, Jon E. Stanat, Warren A. Thaler, Stephen Zushma
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Patent number: 5767046Abstract: A hydrocarbon composition functionalized via the Koch reaction which is the reaction product of at least one hydrocarbon having a number average molecular weight of less than 500 and at least one ethylenic double bond per molecule, with carbon monoxide and a nucleophilic trapping agent. The hydrocarbon is usefully functionalized and derivatized, producing, in particular, lubricants suitable for use in two-cycle engines.Type: GrantFiled: May 15, 1997Date of Patent: June 16, 1998Assignee: Exxon Chemical CompanyInventors: Joseph V. Cusumano, William D. Diana, William B. Eckstrom, Jacob I. Emert, Keith R. Gorda, Michael J. Keenan, Richard H. Schlosberg
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Patent number: 5759965Abstract: This invention relates to a composition, comprising: (A) a boron-containing overbased material; (B) a phosphorus acid, ester or derivative thereof; and (C) a borated epoxide or borated fatty acid ester of glycerol. In one embodiment the inventive composition further comprises (D) a thiocarbamate. These compositions are useful in providing lubricants and functional fluids, particularly automatic transmission fluids, with enhanced antiwear properties. In one embodiment these compositions also provide such lubricants and functional fluids with enhanced extreme-pressure and/or friction-modifying.Type: GrantFiled: October 17, 1996Date of Patent: June 2, 1998Assignee: The Lubrizol CorporationInventor: James L. Sumiejski
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Patent number: 5726135Abstract: Phosphorus-free and ashless high-temperature aircraft and turbo engine lubricant that contains no halogens or hazardous substances is disclosed. The phosphorus-free lubricating oil may be prepared from pentaerythritol tetraester, methylolpropane triester, or their combinations, ashless dithiocarbamate additives, a dialkydiphenylamine, an alkylphenylnaphthylamine, a triazole derivative, a rest inhibitor or metal deactivator, and an anti-foam. The use of this lubricating oil in addition to its superior wear and friction performance over the standard lubricating oil provides a safe and an environmentally benign gas turbine engine oil for aircraft and turbo engines.Type: GrantFiled: December 11, 1996Date of Patent: March 10, 1998Inventor: Behrooz A. Khorramian
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Patent number: 5726132Abstract: This invention relates to compositions for improving fuel efficiency in internal combustion engines. The composition comprises a lubricant having an oil of lubricating viscosity and (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate.Type: GrantFiled: February 28, 1997Date of Patent: March 10, 1998Assignee: The Lubrizol CorporationInventors: Stephen H. Roby, James A. Supp, John S. Manka, William D. Abraham
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Patent number: 5712230Abstract: This invention relates to a composition, comprising: (AT) reaction products of compounds represented by the formula (A)and compounds selected to reduce the polysulfide components of (A); and ##STR1## wherein in Formula (A), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3 (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol.Type: GrantFiled: March 10, 1997Date of Patent: January 27, 1998Assignee: The Lubrizol CorporationInventors: William D. Abraham, John S. Manka, Stephen H. Roby, James A. Supp
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Patent number: 5698498Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) a minor amount of at least one hydroxyalkyl dithiocarbamate or at least one borate thereof, wherein the dithiocarbamate is derived from an amine other than an alkyl or alkenylsuccinimide. In another aspect the invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, a hydroxyalkyl dithiocarbamate or a borate thereof, and (B) at least one sulfur compound or (C) at least one phosphorus or boron antiwear or extreme pressure agent. The invention also relates to greases, functional fluids and aqueous fluids containing the hydroxyalkyl dithiocarbamates and borates thereof. The lubricants and fluids have improved antiwear and extreme pressure properties including providing improved antiscuff protection.Type: GrantFiled: August 23, 1996Date of Patent: December 16, 1997Assignee: The Lubrizol CorporationInventors: Carmen V. Luciani, Syed Q. A. Rizvi, Bernard C. Roell, Jr.
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Patent number: 5693598Abstract: This invention relates to a low-viscosity lubricating oil and functional fluid compositions, comprising: a major amount of an oil having a kinematic viscosity of up to about 4 cST at 100.degree. C.; and a minor antiwear amount of(A) a compound represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (A-I)wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is zero, 1 or 2; and Z is a hydrocarbyl group, a hetero group, a hydroxy hydrocarbyl group, an activating group, or a --(S).sub.b C(X)--NR.sup.1 R.sup.2 group wherein b is zero, 1 or 2; provide that when a is 2, Z is an activating group; and when a is zero, Z can be an ammonium, amine or metal cation. In one embodiment this composition further comprises (B) a phosphorus compound.Type: GrantFiled: September 3, 1996Date of Patent: December 2, 1997Assignee: The Lubrizol CorporationInventors: William D. Abraham, Brent R. Dohner, John S. Manka, Stephen H. Roby, James A. Supp
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Patent number: 5674820Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms, In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof, In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxytic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.Type: GrantFiled: September 5, 1996Date of Patent: October 7, 1997Assignee: The Lubrizol CorporationInventors: John S. Manka, William D. Abraham, Stephen H. Roby, James A. Supp, Craig D. Tipton
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Patent number: 5604187Abstract: A grease composition for constant velocity joints which consists essentially of: (a) a base oil; (b) a diurea compound represented by the following general formula:R.sup.1 NH--CO--NH--p--C.sub.6 H.sub.4 --CH.sub.2 --p--C.sub.6 H.sub.4 --NH--CO--NHR.sup.2(wherein R.sup.1 and R.sup.3 may be the same or different and each represents an aryl group or a cyclohexyl group); (c) melamine cyanurate; (d) molybdenum disulfide; and (e) a phosphorus-free sulfur extreme pressure agent, and optionally (f) molybdenum dithiocarbamate.The grease composition exhibits excellent pitting-inhibitory effect and heat resistance.Type: GrantFiled: April 16, 1996Date of Patent: February 18, 1997Assignees: Kyodo Yushi Co., Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Kiyoshi Takeuchi, Tsuyoshi Sasaki, Tomio Hanawa, Yoshimi Usui, Takahiro Ogura
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Patent number: 5589444Abstract: A grease composition for constant velocity joints consists essentially of: (a) a base oil; (b) an urea thickener; (c) molybdenum disulfide; (d) a calcium salt or an overbasic calcium salt selected from the group consisting of calcium salts or overbasic calcium salts of oxidized waxes, petroleum sulfonates, alkyl aryl sulfonates, salicylate, and phenates; (e) a metal-free sulfur-phosphorus extreme pressure agent; and (f) molybdenum dithiocarbamate. The grease composition exhibits excellent wear-resistance and pitting-inhibitory effect.Type: GrantFiled: June 6, 1996Date of Patent: December 31, 1996Assignee: Kyodo Yushi Co., Ltd.Inventor: Ko Hatakeyama