Abstract: A process for preparing an oligomeric phenolic detergent composition comprising contacting an oil soluble alkylphenol with an alkaline earth metal base, an alpha amino acid, and a C1 to C6 aldehyde, in the in the presence of a C2 to C6 alkylene glycol and a C2 to C4 carboxylic acid; and reacting under reactive conditions at a temperature of from 150° C. to 225° C. The oligomeric phenolic detergent product can be employed in a lubricating oil.
Abstract: Hydrocarbyl substituted carboxylic compositions and derivatives thereof useful as additives for lubricating oil and fuel compositions. Carboxylic composition are derived from (A) an olefinically unsaturated hydrocarbon, said hydrocarbon having at least one allylic hydrogen atom, and (B) an ?,?-unsaturated carboxylic compound prepared by reacting (1) an active methylene compound of the formula ?and (2) a carbonyl compound of the general formula ?wherein Ra is H or hydrocarbyl and Rb is a member of the group consisting of H, hydrocarbyl and ?wherein each R? is independently R or OR and each R is, independently, H or a hydrocarbyl group; and lower alkyl acetals, ketals, hemiacetals and hemiketals of the carbonyl compound (2).
Type:
Grant
Filed:
June 21, 2001
Date of Patent:
January 25, 2005
Assignee:
The Lubrizol Corporation
Inventors:
Stuart L. Bartley, James D. Burrington, Richard Yodice
Abstract: The present invention relates to polymeric acetals containing the recurring structural unit (I) ##STR1## where the substituents and numbers are as defined in the description. These polymeric acetals are suitable as base components for water-soluble cooling lubricants.
Abstract: The reaction product of a hydroxyaromatic compound, at least some of the units of which are hydrocarbyl-substituted, a carboxy-substituted aldehyde, and an aldehyde other than a carboxy-substituted aldehyde, provides an additive for lubricants as well as an intermediate for further reaction with amines, alcohols, or neutralization to form a salt.
Abstract: The present invention is directed to lubricating oil and fuel dispersants comprising hydroxy aromatic succinimide Mannich Base condensates of heavy polyamine. A heavy polyamine is a mixture of polyalkylenepolyamines comprising small amounts of lower polyamine oligomers such as tetraethylene pentamine and pentahexamine but primarily oligomers with 7 or more nitrogens, 2 or more primary amines per molecule, and more extensive branching than conventional polyamine mixtures.