Olefinically Unsaturated Compound That Is Not A Carboxylic Acid Ester Is An Additional Monomer Of The Polymer (e.g., Ethylene-ethylacrylate Copolymer, Etc.) Patents (Class 508/472)
  • Patent number: 11732212
    Abstract: This disclosure relates generally to metalworking fluids. This disclosure relates more particularly to water-soluble metalworking fluids that include high viscosity polymers, and that can be used in metal cold rolling operations.
    Type: Grant
    Filed: December 4, 2019
    Date of Patent: August 22, 2023
    Assignee: Castrol Limited
    Inventor: Robert Paul Hudson
  • Patent number: 11453837
    Abstract: The invention relates to random copolymers comprising monomers derived from conjugated dienes and alkyl (meth)acrylates, a method for manufacturing the copolymers, lubricant compositions comprising the copolymers, and the use of the copolymers as additives for lubricant compositions or as a base oil for lubricant compositions. The copolymers are favorably used for driving system lubricating oils, hydraulic oils, engine oils and industrial oil formulations.
    Type: Grant
    Filed: October 23, 2019
    Date of Patent: September 27, 2022
    Assignee: Evonik Operations GmbH
    Inventors: Holger Pletsch, Emily Clare Schweissinger, Hanna Spohr, Sebastian Reimann, Lars Pera, Marius Weiland, Boris Eisenberg, Dmitriy Shakhvorostov
  • Patent number: 10087265
    Abstract: A method for producing poly(dimethyl vinylphosphonate) from a monomer component mainly containing dimethyl vinylphosphonate by anionic polymerization in the presence of an anionic polymerization initiator, the method being characterized in that an aliphatic ether is used as a polymerization solvent, and a method for producing poly(vinylphosphonic acid) characterized in that the poly(dimethyl vinylphosphonate) obtained by the former method is hydrolyzed in the presence of an acid are provided. The methods make it possible to easily produce a poly(dimethyl vinylphosphonate) which has a high molecular weight and in which the molecular weight is controlled, and make it possible to produce a poly(vinylphosphonic acid) which has a high molecular weight and in which the molecular weight is controlled corresponding to the poly(dimethyl vinylphosphonate).
    Type: Grant
    Filed: June 1, 2015
    Date of Patent: October 2, 2018
    Assignee: Maruzen Petrochemical Co., Ltd.
    Inventors: Takashi Takahashi, Keisuke Matsushita, Masaki Sugiyama, Norihiro Yoshida, Eiichi Ikawa, Takahito Mita, Masahiro Endo
  • Publication number: 20150148275
    Abstract: The present invention relates to a lubricating composition containing an oil of lubricating viscosity and a star polymer that has at least two inner blocks, at least one of which is in turn bonded to one or more outer blocks. The invention further relates to methods of lubricating a mechanical device with the lubricating composition.
    Type: Application
    Filed: December 16, 2014
    Publication date: May 28, 2015
    Inventors: Haihu Qin, Marina Baum, John R. Johnson
  • Patent number: 8979951
    Abstract: The invention provides terpolymers of ethylene, at least one ethylenically unsaturated ester and propene, which a) contain from 12.0 to 16.0 mol % of structural units derived from at least one ethylenically unsaturated ester, b) contain from 1.0 to 4.0 methyl groups derived from propene per 100 aliphatic carbon atoms, and c) have fewer than 6.5 methyl groups stemming from chain ends per 100 CH2 groups. and also their use as cold additives for middle distillates.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: March 17, 2015
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bettina Siggelkow, Werner Reimann, Matthias Krull, Markus Kupetz
  • Patent number: 8968428
    Abstract: The invention provides additive mixtures comprising A) at least one terpolymer of ethylene, propene and at least one ethylenically unsaturated ester, which i) contains from 6.0 to 12.0 mol % of structural units derived from at least one ethylenically unsaturated ester having a C1- to C3-alkyl radical, ii) contains from 0.5 to 4.0 methyl groups derived from propene per 100 aliphatic carbon atoms, iii) has fewer than 8.0 methyl groups stemming from chain ends per 100 CH2 groups, and B) from 0.5 to 20 parts by weight, based on A), of at least one further component which is effective as a cold additive for mineral oils and is selected from B1) copolymers of ethylene and ethylenically unsaturated compounds whose content of ethylenically unsaturated compounds is at least 2 mol % higher than the content of ethylenically unsaturated esters in the terpolymer defined under A), B2) comb polymers, and B3) mixtures of B1) and B2), and also their use as a cold additive for middle distillates.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: March 3, 2015
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Bettina Siggelkow, Werner Reimann, Matthias Krull, Ulrike Neuhaus, Markus Kupetz, Andre Graf
  • Publication number: 20150051131
    Abstract: Automotive transmission fluid compositions are provided having improved power transmission properties through the presence therein of certain defined additives, which increase the fuel efficiency of the vehicle during operation. The invention further provides a process for the manufacture of such transmission fluid compositions, a method of improving the energy efficiency of a transmission, and an additive concentrate for a transmission fluid.
    Type: Application
    Filed: August 15, 2013
    Publication date: February 19, 2015
    Applicant: INFINEUM INTERNATIONAL LIMITED
    Inventors: Hahn Soo Kim, Joseph R. Noles, JR., Raymond F. Watts
  • Patent number: 8796194
    Abstract: The lubricating oil composition of the invention includes a lubricating base oil with a kinematic viscosity at 100° C. of 1-6 mm2/s, a % Cp of 70 or greater and a % CA of no greater than 2, and a viscosity index improver which, when added to the lubricating base oil, results in an A/B ratio of less than 3.2 and a C/B ratio of less than 1.5. A is the thickening effect on the kinematic viscosity at 100° C., B is the thickening effect on the HTHS viscosity at 150° C., and C is the thickening effect on the HTHS viscosity at 100° C.
    Type: Grant
    Filed: August 30, 2010
    Date of Patent: August 5, 2014
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Akio Mutou, Akira Yaguchi, Shigeki Matsui
  • Patent number: 8785359
    Abstract: A lubricant oil composition comprising: a lubricant base oil whose kinematic viscosity at 100° C. is 1 to 6 mm2/s, % Cp is not less than 70, and % CA is not more than 2; a first viscosity index improver in which the ratio A/B of a viscosity increasing effect A in the equation (1) to a viscosity increasing effect B in the equation (2) when added to the lubricant base oil is a value of not less than 4.5, and a PSSI is not more than 30; and a second viscosity index improver in which the ratio A/B when added to the lubricant base oil is a value less than 4.5: A=X?X0??(1) B=Y?Y0??(2) wherein A represents a viscosity increasing effect of the kinematic viscosity at 100° C., B represents a viscosity increasing effect of the HTHS viscosity at 150° C., X represents a kinematic viscosity at 100° C. of a mixture of the lubricant base oil with 3% by mass of the first or second viscosity index improver, X0 represents a kinematic viscosity at 100° C. of the lubricant base oil, Y represents an HTHS viscosity at 150° C.
    Type: Grant
    Filed: January 25, 2010
    Date of Patent: July 22, 2014
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Akira Yaguchi, Shigeki Matsui, Teppei Tsujimoto
  • Publication number: 20140179578
    Abstract: Provided is an alternating block copolymer. The alternating block copolymer has an olefin polymer block and an poly(alkyl methacrylate) block. The olefin polymer block has monomeric units of one or more alpha olefins of 2 to 12 carbon atoms that make up 90 wt % or more of the total weight of the olefin polymer block. The olefin polymer block exhibits a number average molecular weight of the olefin polymer block is 1000 to 500,000. The poly(alkyl methacrylate) block has monomeric units of one or more alkyl methacrylates with alkyl side chains of 1 to 100 carbon atoms that make up 90 wt % or more of the total weight of the poly(alkyl methacrylate) block. The poly(alkyl methacrylate) block exhibits a number average molecular weight of 1000 to 500,000. There is also provided a lubricant composition containing the alternating block copolymer and a process for making the alternating block copolymer.
    Type: Application
    Filed: December 24, 2012
    Publication date: June 26, 2014
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Andy Haishung Tsou, Yong Yang, Martin N. Webster, Thomas Sun, Johannes Mattieu Soulages, Donna Jean Crowther, C. Rebecca Locker
  • Publication number: 20140113847
    Abstract: A lubricating composition including a first base stock component including: one or more metallocene catalyzed polyalphaolefins (mPAOs), each mPAO having a kinematic viscosity (Kv100) from 40 cSt to 155 cSt and a viscosity index (VI) from 150 to 207; a second base stock including one or more polyalphaolefins (PAOs), each PAO having a kinematic viscosity (Kv100) less than 10 cSt and a VI from 130 to 145; and a viscosity modifier including a copolymer having units derived from monomers of (i) an ?-olefin and (ii) an ethylenically unsaturated carboxylic acid or derivatives thereof esterified with an alcohol. A lubricant including the above lubricating composition. A method for improving fuel efficiency, while maintaining or improving wear control, load carrying capacity and/or traction reduction in a driveline device, e.g., gears and transmissions, lubricated with a lubricating oil, by using as the lubricating oil the above lubricant.
    Type: Application
    Filed: September 24, 2013
    Publication date: April 24, 2014
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Willie Allan Givens, Percy Rohinton Kanga, Jared Michael Robillard
  • Publication number: 20140107005
    Abstract: The use is described of polymers which contain, in copolymerized form, an ?-olefin, a vinyl ester and an ester of an ?,?-unsaturated carboxylic acid as an additive for fuel oils and lubricants and in particular as a cold flow improver in fuel oils. En addition, the fuel oils and lubricants additized with these polymers; and also additive packages comprising such polymers are described.
    Type: Application
    Filed: December 20, 2013
    Publication date: April 17, 2014
    Applicant: BASF SE
    Inventors: Wolfgang Ahlers, Andreas Fechtenkoetter, Frank-Olaf Maehling, Irene Troetsch-schaller, Ansgar Eisenbeis
  • Patent number: 8598101
    Abstract: The invention relates to dispersions comprising I) at least one polymer that is effective for mineral oils as a cold extrusion improver and is soluble in oil, II) at least one organic solvent that cannot be mixed with water, III) water, IV) at least one alkanolamine salt of a polycyclic carboxylic acid as a dispersing agent, and V) possibly at least one organic solvent that can be mixed with water.
    Type: Grant
    Filed: September 21, 2012
    Date of Patent: December 3, 2013
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Michael Feustel, Matthias Krull, Christoph Kayser, Mario Loew
  • Patent number: 8524260
    Abstract: The invention consists of a method for manufacturing an aqueous formulation containing at least one oil, and comprising the steps of mixing at least one associative polymer, one oil, and water, encapsulating the oil by increasing the pH to a value greater than 8, potentially precipitating the mixture by reducing the pH to a value less than 6, and potentially isolating the resulting particles by removing the water. The aqueous formulations, as with the aqueous dispersions, and the resulting solid particles constitute other objects of the invention.
    Type: Grant
    Filed: December 3, 2008
    Date of Patent: September 3, 2013
    Assignee: Coatex S.A.S.
    Inventors: Jean Moro, David Platel, Jean-Marc Suau, Olivier Guerret
  • Publication number: 20130196888
    Abstract: A lubricant composition includes: (a) one or more base oils, (b) at least one comb polymer formed by a polyalkyl(meth)acrylate main chain, and hydrocarbon side chains including at least 50 carbon atoms, (c) at least one nitrogen-containing organic friction modifier chosen from the optionally alkoxylated fatty amines, fatty amides or imides obtained by the condensation of fatty amines and carboxylic acids, alone or in a mixture, (d) optionally, one or more organometallic organomolybdenum-type friction modifiers. This is used for the lubrication of 4-stroke gasoline or diesel engines of light vehicles, preferentially of hybrid vehicles.
    Type: Application
    Filed: August 25, 2011
    Publication date: August 1, 2013
    Inventor: Nguyen Truong-Dinh
  • Publication number: 20130040864
    Abstract: The invention relates to a composition comprising at least one microgel and at least one functional additive, to processes for the preparation thereof, to uses of the compositions, and to microgel-containing polymers, rubbers, lubricants, coatings, etc. prepared therefrom.
    Type: Application
    Filed: October 18, 2012
    Publication date: February 14, 2013
    Applicants: RHEIN CHEMIE RHEINAU GMBH, LANXESS DEUTSCHLAND GMBH
    Inventors: LANXESS Deutschland GmbH, Rhein Chemie Rheinau GmbH
  • Publication number: 20120277133
    Abstract: This invention relates to functionalized polymers derived from functionalized monomers. The functionalized polymer may be reacted with an enophilic reagent (e.g., maleic anhydride) to form an enophilic reagent modified functionalized polymer. The functionalized polymer may be further reacted with one or more additional reagents, e.g., an oxygen-containing reagent (e.g., alcohol, polyol), a nitrogen-containing reagent (e.g., amine, polyamine, aminoalcohol), a metal, a metal compound, or a mixture of two or more thereof. The invention relates to lubricants, functional fluids, fuels, dispersants, detergents and polymer compositions.
    Type: Application
    Filed: March 23, 2012
    Publication date: November 1, 2012
    Inventors: Stephen A. DiBiase, Syed Q.A. Rizvi, Georgeta Hategan
  • Patent number: 8293690
    Abstract: The invention relates to dispersions comprising I) at least one polymer that is effective for mineral oils as a cold extrusion improver and is soluble in oil, II) at least one organic solvent that cannot be mixed with water, III) water, IV) at least one alkanolamine salt of a polycyclic carboxylic acid as a dispersing agent, and V) possibly at least one organic solvent that can be mixed with water.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: October 23, 2012
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Michael Feustel, Matthias Krull, Christoph Kayser, Mario Loew
  • Publication number: 20120258899
    Abstract: The present invention relates to the use of comb polymers comprising, in the main chain, repeat units derived from polyolefin-based macromonomers with a molecular weight of at least 500 g/mol, and repeat units derived from low molecular weight monomers with a molecular weight less than 500 g/mol, for improving the load-bearing capacity of hydraulic fluids. Furthermore, the present invention describes new hydraulic fluids.
    Type: Application
    Filed: June 20, 2012
    Publication date: October 11, 2012
    Applicant: EVONIK ROHMAX ADDITIVES GMBH
    Inventors: Boris Eisenberg, Roland Schweder, Michael Alibert, Torsten Stöhr
  • Publication number: 20120108679
    Abstract: The present invention relates to a branched copolymer comprising a hydrophilic component obtainable by an addition polymerisation process and compositions and uses thereof said copolymer comprising: i) a residue of at least one monofunctional monomer comprising one polymerisable double bond per molecule and a molecular weight of less than 1000 Daltons; ii) a residue of at least one multifunctional monomer comprising at least two polymerisable double bonds per molecule and a molecular weight of less than 1000 Daltons; and wherein the end termini of the copolymer chains comprise one or more of a residue of a chain transfer agent; an initiator or a terminal group derived from a termination reaction; wherein; the molar ratio of the monofunctional monomer to multifunctional monomer is between 50:1 to 2.
    Type: Application
    Filed: February 9, 2010
    Publication date: May 3, 2012
    Applicant: UNILEVER PLC
    Inventors: Paul Hugh Findlay, Brodyck James Lachlan Royles, Neil John Simpson, Sharon Todd, Steven Paul Rannard, Jonathan Victor Mark Weaver, Roselyne Marie Andree Baudry
  • Publication number: 20120108678
    Abstract: The present invention relates to a branched copolymer obtainable by an addition polymerisation process and uses and compositions thereof comprising: i) a residue of at least one monofunctional monomer comprising one polymerisable double bond per molecule and a molecular weight of less than 1000 Daltons; ii) a residue of at least one multifunctional monomer comprising at least two polymerisable double bonds per molecule and a molecular weight of less than 1000 Daltons; and wherein the end termini of the copolymer chains comprise one or more of a residue of a chain transfer agent; an initiator or a terminal group derived from a termination reaction; wherein; the molar ratio of the monofunctional monomer to multifunctional monomer is between 50:1 to 2.
    Type: Application
    Filed: February 9, 2010
    Publication date: May 3, 2012
    Applicant: UNILEVER PLC
    Inventors: Paul Hugh Findlay, Brodyck James Lachlan Royles, Neil John Simpson, Sharon Todd, Steven Paul Rannard, Jonathan Victor Mark Weaver, Roselyne Marie Andree Baudry
  • Publication number: 20120095111
    Abstract: The present invention relates to the use of a branched addition copolymer as a dispersant in a gaseous, liquid or solid formulation in a range of applications and branched addition copolymers suitable for same wherein the copolymer is obtainable by an addition polymerisation process, wherein said copolymer comprises: at least two chains which are covalently linked by a bridge other than at their ends; and wherein the at least two chains comprise at least one ethyleneically monounsaturated monomer, and wherein the bridge comprises at least one ethyleneically polyunsaturated monomer; and wherein the polymer comprises a residue of a chain transfer agent and wherein the mole ratio of polyunsaturated monomer(s) to monounsaturated monomer(s) is in a range of from 1:100 to 1:4; and wherein the branched copolymer dispersant contains anchoring, solubilising or stabilising moieties and wherein the resulting copolymer comprises at least 10% styrenic monomer, brancher or chain transfer agent.
    Type: Application
    Filed: June 22, 2010
    Publication date: April 19, 2012
    Applicant: UNILEVER PLC
    Inventors: Paul Hugh Findlay, Brodyck James Lachian Royles, Roselyne Marie Andree Baudry, Neil John Simpson, Sharon Todd, Steven Paul Rannard
  • Publication number: 20120095110
    Abstract: The present invention relates to the use of a branched addition copolymer as a dispersant in a gaseous, liquid or solid formulation in a range of applications and to the copolymers per se wherein the copolymer is obtainable by an addition polymerisation process, wherein said copolymer comprises: at least two chains which are covalently linked by a bridge other than at their ends; and wherein the at least two chains comprise at least one ethylenically monounsaturated monomer, and wherein the bridge comprises at least one ethylenically polyunsaturated monomer; and wherein the polymer comprises a residue of a chain transfer agent and wherein the mole ratio of polyunsaturated monomer(s) to monounsaturated monomer(s) is in a range of from 1:100 to 1:4; and wherein the branched copolymer dispersant contains anchoring, solubilising or stabilising moieties and wherein the resulting copolymer has a weight average molecular weight of less than 100,000 Da.
    Type: Application
    Filed: June 22, 2010
    Publication date: April 19, 2012
    Applicant: Unilever PLC
    Inventors: Paul Hugh Findlay, Brodyck James Lachian Royles, Roselyne Marie Andree Baudry, Neil John Simpson, Sharon Todd, Steven Paul Rannard
  • Patent number: 8067347
    Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one ether compound, with at least one aliphatic compound, and with at least one aromatic compound.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: November 29, 2011
    Assignee: Chevron Oronite Company LLC
    Inventors: William R. Ruhe, Jr., Casey D. Stokes
  • Patent number: 7988748
    Abstract: Mineral oil compositions with trace portions of additives contain as additive a comb polymer containing ester linkages, either based on a) ethylene-vinylester copolymers modified by hydroxy groups or glycidyl groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and b) partially imidated and/or partially esterified maleic anhydride copolymers, wherein in the comb polymer based on a) and b) the modified ethylene-vinylester copolymer component is connected by means of ester linkages to the partially imidated and/or partially esterified maleic anhydride copolymer component, or a comb polymer containing ester linkages based on c) ethylene-vinylester copolymers modified by acid and/or acid anhydride groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and d) polyalcohols partially esterified with C12-C40-monocarboxylic acids wherein in the comb polymer based on c) and d) the ethylene-vinylester copolymer c
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: August 2, 2011
    Assignee: Leuna Polymer GmbH
    Inventors: Hiltrud Täubert, Wolfgang Haubold, Konrad Bühler, Torsten Meyer
  • Patent number: 7928044
    Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one ether compound and with at least one aromatic compound.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: April 19, 2011
    Assignee: Chevron Oronite Company LLC
    Inventors: Casey D. Stokes, William R. Ruhe, Jr.
  • Patent number: 7858566
    Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one polyether aromatic compound, and with at least one polyether aliphatic compound.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: December 28, 2010
    Assignee: Chevron Oronite Company LLC
    Inventors: William R. Ruhe, Jr., Casey D. Stokes
  • Patent number: 7820604
    Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one polyether aliphatic amine compound.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: October 26, 2010
    Assignee: Chevron Oronite Company LLC
    Inventors: William R. Ruhe, Jr., Casey D. Stokes
  • Patent number: 7820605
    Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one polyether aromatic compound.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: October 26, 2010
    Assignee: Chevron Oronite Company LLC
    Inventors: Casey D. Stokes, William R. Ruhe, Jr.
  • Publication number: 20100267564
    Abstract: The invention consists of a method for manufacturing an aqueous formulation containing at least one oil, and comprising the steps of mixing at least one associative polymer, one oil, and water, encapsulating the oil by increasing the pH to a value greater than 8, potentially precipitating the mixture by reducing the pH to a value less than 6, and potentially isolating the resulting particles by removing the water. The aqueous formulations, as with the aqueous dispersions, and the resulting solid particles constitute other objects of the invention.
    Type: Application
    Filed: December 3, 2008
    Publication date: October 21, 2010
    Applicant: COATEX S.A.S.
    Inventors: Jean Moro, David Platel, Jean-Marc Suau, Olivier Guerret
  • Patent number: 7816309
    Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one ether compound and with at least one aliphatic compound capable of reacting with at least one monocarboxylic acid or ester thereof, or dicarboxylic acid, anhydride or ester thereof.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: October 19, 2010
    Assignee: Chevron Oronite Company LLC
    Inventors: Casey D. Stokes, William R. Ruhe, Jr.
  • Patent number: 7776801
    Abstract: An additive mixture as component of a composition of mineral oil as main component and trace portions of an additive mixture containing the additive components a) ethylene-vinylester copolymers modified by polar groups with molecular mass weight averages from 3000 to 50000 and an ethylene component of 50 to 90 mass %, and b) C2-C6-oxyalkyl-bridged C12-C40-monocarboxylic acids, and/or c) partially and/or completely imidated copolymers of unsaturated C4-C20-dicarboxylic acid anhydrides and vinyl aromatics and/or C2-C36-?-olefins, whereby the content of the additive mixture in the mineral is 0.005 to 1 mass %. The compositions are suitable as flowable media to be transported at low temperatures and as mineral oil fuels with high lubricity and flowability.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: August 17, 2010
    Assignee: Leuna Polymer GmbH
    Inventors: Hiltrud Täubert, Wolfgang Haubold, Erhard Brauer, Torsten Meyer, Dietrich von der Wense
  • Patent number: 7741258
    Abstract: A lubricating oil composition comprising base oil, one or more glycerol esters selected from glycerol monooleate and/or glycerol dioleate, optionally in combination with glycerol trioleate, wherein said composition further comprises one or more dispersant-viscosity index improver compounds and an additive amount of one or more additional polyhydric alcohol esters; and a method of lubricating an internal combustion engine comprising applying said lubricating oil composition thereto.
    Type: Grant
    Filed: February 21, 2007
    Date of Patent: June 22, 2010
    Assignee: Shell Oil Company
    Inventors: Takashi Fujitsu, Joanna Griffiths
  • Patent number: 7696138
    Abstract: A novel reaction product and method for making the reaction product. The reaction product is a copolymer obtained by reacting together i) an acylated alkylacrylate copolymer having a number average molecular weight ranging from about 5,000 to about 500,000; ii) a hydrocarbyl acylating agent having a number average molecular weight ranging from about 500 to about 5000; and iii) a compound selected from the group consisting of (a) a polyamine; (b) a polyol; and (c) an aminoalcohol to provide a functionalized polyalkylacrylate copolymer. According to the reaction, a mole ratio of component (i) to (ii) ranges from about 1:10 to about 5:1.
    Type: Grant
    Filed: June 18, 2007
    Date of Patent: April 13, 2010
    Assignee: Afton Chemical Corporation
    Inventors: Naresh C. Mathur, John T. Loper, Akhilesh Duggal
  • Publication number: 20080280795
    Abstract: A lubricating oil composition comprising base oil, one or more glycerol esters selected from glycerol monooleate and/or glycerol dioleate, optionally in combination with glycerol trioleate, wherein said composition further comprises one or more dispersant-viscosity index improver compounds and an additive amount of one or more additional polyhydric alcohol esters; and a method of lubricating an internal combustion engine comprising applying said lubricating oil composition thereto.
    Type: Application
    Filed: February 21, 2007
    Publication date: November 13, 2008
    Inventors: Takashi Fujitsu, Joanna Griffiths
  • Patent number: 7244695
    Abstract: According to the invention there is provided a method of reducing wear of one or both of two steel elements having surfaces in sliding or sliding-rolling contact. The method involves applying an HPF friction control composition to one, or more than one contacting surface of one or both of the two steel elements. In a particular example, the HPF friction control composition comprises a rheological control agent, a lubricant, a friction modifier, and one, or more than one of a retentivity agent, an antioxidant, a consistency modifier, and a freezing point depressant.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: July 17, 2007
    Assignee: Kelsan Technologies Corp.
    Inventor: Don T. Eadie
  • Patent number: 7214648
    Abstract: An engine lubricant formulated as a complete crankcase motor oil or additive concentrate composed of a combination of chemical constituents including a base oil selected from a synthetic oil, a mineral oil or semi-synthetic base oil (hydrogenated oil) or combination thereof, an oil soluble molybdenum additive, a dispersant inhibitor containing zinc dithiophosphate, and viscosity index improvers and one or more seal swelling agents to lubricate the engine and recondition the seals of new and/or high mileage engines. Addition of a polyalphaolefin and/or one or more esters such as a diester or polyolester may also be utilized therein. The lubricant may be formulated as a complete engine oil crankcase lubricant, or concentrated into an additive for addition to conventional mineral oil based engine oil, synthetic engine oils, or blends thereof in an effective amount of up to 30 percent volume percent, typically from 20 to 25 percent by volume.
    Type: Grant
    Filed: July 29, 2002
    Date of Patent: May 8, 2007
    Assignee: Ashland Licensing and Intellectual Property, LLC
    Inventors: Mandeep S. Saini, Thomas R. Smith, Michael A. Dituro, Richard J. Baumgart, Frances E. Lockwood
  • Patent number: 7189682
    Abstract: A composition of the following components: an oil of lubricating viscosity; a polymethacrylate viscosity modifier; an ester of a maleic acid/styrene copolymer; and optionally, an additive package that imparts to the fluid the capacity to meet bench and dynamometer tests specified by an equipment manufacturer, is suitable for use as a functional fluid such as a tractor hydraulic fluid, under a wide variety of climatic conditions.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: March 13, 2007
    Assignee: The Lubrizol Corporation
    Inventor: Richard E. Gapinski
  • Patent number: 7091162
    Abstract: Lubricants for containers and for conveyors for transporting containers are provided. The lubricants provide container and conveyor surfaces having low coefficients of friction. In one embodiment, the lubricants comprise a cured coating containing hydrophobic polymers and waxes.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: August 15, 2006
    Assignee: JohnsonDiversey, Inc.
    Inventors: Paul F. Lewis, Jim J. Hilarides
  • Patent number: 7045489
    Abstract: According to the invention there is provided a liquid friction control composition characterized as either having a high and positive friction characteristic or a low and neutral friction characteristic, comprising a retentivity agent. The liquid friction control composition may also comprise other components such as a solid lubricant, a wetting agent, a consistency modifier, and a preservative. The liquid friction control compositions may be used to modify the interfacial friction characteristics in sliding and rolling-sliding contact such as steel wheel-rail systems including mass transit and freight systems.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: May 16, 2006
    Assignee: Kelsan Technologies Corp.
    Inventors: John Cotter, Donald T. Eadie, Kelvin Spencer Chiddick
  • Publication number: 20040254080
    Abstract: A grease composition containing a polymer with (a) monomers (i) at least one unsaturated &agr;,&bgr;-carboxylic acid ester containing an alkyl group with about 10 to about 20 carbon atoms; and (ii) at least one unsaturated &agr;,&bgr;-carboxylic acid ester containing an alkyl group with about 4 to about 11 carbon atoms different from monomer (i); and (iii) at least one unsaturated dicarboxylic acid anhydride or derivatives thereof; and (iv) optionally at least one unsaturated &agr;,&bgr;-carboxylic acid ester containing an alkyl group with about 1 to about 3 carbon atoms; and optionally (b) at least one non-monomeric amine with primary functionality, secondary functionality or mixtures thereof; and optionally (c) other performance additives; and (d) at least one thickening agent, and (e) an oil of lubricating viscosity. The invention further relates to the process to make the composition and its use in greases.
    Type: Application
    Filed: June 10, 2003
    Publication date: December 16, 2004
    Applicant: The Lubrizol Corporation, a corporation of the State of Ohio
    Inventors: Matthew R. Sivik, Mohamed G. Fahmy
  • Patent number: 6821933
    Abstract: The invention relates to additives for improving the flowability of mineral oils, containing: A) 1-40 wt. % of at least one copolymer, which is oil-soluble and improves the cold flow properties of mineral oil, selected from A1) copolymers consisting of 80 to 96.5 mol % ethylene and 3.5-20 mol % vinyl esters of carboxylic acids with 1-20 C atoms and/or (meth)acrylic acid esters of alcohols with 1-8 C atoms, and A2) homopolymers or copolymers of esters, containing C10-C30 alkyl radicals, of ethylenically unsaturated carboxylic acids with up to 20 mol % of other olefinically unsaturated compounds, B) 20-80 wt. % of at least one poly-alpha-olefin with a molecular weight of 250-5000, derived from monoolefins with 3-5 C atoms, and C) 5-70 wt.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: November 23, 2004
    Assignee: Clariant International Ltd.
    Inventors: Michael Feustel, Matthias Krull, Hans-Jörg Oschmann
  • Publication number: 20040038836
    Abstract: The lubricating oil of the present invention has a viscosity suitable for use in a diesel engine and includes at least one functionalized olefin polymer, and at least one zinc dialkyl dithiophosphate (ZDDP). The ZDDP is made from a mixture of primary alcohols or a mixture of primary and secondary alcohols, wherein the lubricant has a high boundary film value greater than or equal to 15, and preferably greater than 60, as measured by using a High Frequency Reciprocating Rig (HFRR).
    Type: Application
    Filed: August 21, 2002
    Publication date: February 26, 2004
    Inventors: Mark Thomas Devlin, Charles A. Passut, Carl K. Esche, John T. Loper
  • Publication number: 20030139303
    Abstract: This invention relates to a lubricating composition comprising at least about 30% by weight at least one mineral oil, having a kinematic viscosity of less than about 8 cSt at 100° C., (A) from about 15% to about 40% by weight of at least one polymer, and (B) up to about 30% by weight of at least one fluidizing agent, provided that when the fluidizing agent is a poly&agr;-olefin is present in an amount up about 2 to about 30 cSt at 100° C., then the poly&agr;-olefin is present in an amount up to about 12% by weight, wherein the lubricating composition has a shear loss of less than about 15% in the 20 hour taper bearing shear test. The invention also relates to concentrates used in preparing lubricating compositions. The present combination of components provides good low and high temperature properties especially when used in combination with one or more mineral oils. In one aspect, the compositions provide improved oxidation resistance.
    Type: Application
    Filed: July 7, 1997
    Publication date: July 24, 2003
    Inventors: CURTIS R. SCHARF, ROBERT C. RICHARDSON, BERNARD C. ROELL
  • Publication number: 20030036488
    Abstract: A viscosity index improver, which comprises a polymer (A) having a solubility parameter of 8.6-9.4, a crystallizing initiation temperature of equal to or less than −15° C.
    Type: Application
    Filed: April 3, 2002
    Publication date: February 20, 2003
    Applicant: Sanyo Chemical Industries, Ltd.
    Inventors: Tsuyoshi Yuki, Yoshihisa Ota
  • Patent number: 6500789
    Abstract: An economical lubricant blended from refined bleached deodorized soybean oil, a food grade. additive that confers “tack” or stringiness, and a food grade anti-oxidant. The preferred food grade additive that confers “tack” is FUNCTIONAL V-584 and the preferred food grade anti-oxidant is TENOX 20A.
    Type: Grant
    Filed: October 11, 2001
    Date of Patent: December 31, 2002
    Assignee: Ventura Foods, LLC
    Inventors: Jerald David Wiltz, Rayphael James Aucion
  • Patent number: 6475964
    Abstract: Motor oils and transmission oils of the usual commercial SAE single- and multiple viscosity classes, which oils contain polymeric additives and which have high dispersivity and good wear protection characteristics, said oils containing the following additives: (i) at least one heavy-duty (HD) additive, which contains phosphorus compounds; and (ii) as dispersive polymeric components PC, cooligomers copolymers, or combinations thereof comprised of: (a) units of C6-24 alkyl (meth)acrylates, (b) units of at least one functionalized alkyl (meth)acrylate, (c) units of one or more C1-5-alkyl (meth)acrylate monomers, and (d) units of 1-alkenes, with the following provisions: (1) the units of formulas I and II together comprise 100 wt. %, (2) the content of polymer components) PC in the additive-containing mineral oils is in the range 0.5-50 wt. %, and (3) the content of phosphorus in the additive-containing mineral oils is less than or equal to 0.08 wt. %.
    Type: Grant
    Filed: August 2, 1995
    Date of Patent: November 5, 2002
    Assignee: Roehm GmbH & Co. KG
    Inventors: Peter Neudoerfl, Horst Pennewiss, Gerhard Renner
  • Patent number: 6461999
    Abstract: Lubricating additives for drilling fluids are prepared from semi-solid highly viscous and/or high molecular weight lubricants, such as polyalkylenes (e.g., polybutene), by steam jet cooking a mixture of starch, water, and the lubricant in order to uniformly suspend micrometer-sized lubricant droplets in an aqueous starch matrix. These additives avoid the need for toxic emulsifiers, surfactants, or short-chain hydrocarbon solvents for dispersing the lubricants. They impart lubricity to drilling fluids (muds) and also inhibit fluid loss in geological formations by enhancing the filtration control properties of the fluid.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: October 8, 2002
    Assignees: The United States of America as represented by the Secretary of Agriculture, Shrieve Chemical Products
    Inventors: George F. Fanta, Herman M. Muijs, Kenneth Eskins, Frederick C. Felker, Selim M. Erhan
  • Patent number: 6350723
    Abstract: Block copolymers having a molecular weight distribution of between 1.0 and 5.0 comprising at least one block of polymerized alkyl methacrylate monomer(s), wherein from 50 to 100% by weight of the monomers for forming the alkyl methacrylate block are C12-C30 alkyl methacrylates, and a block of a polymerized conjugated alkadiene. The block copolymers of the present invention are useful as viscosity index improvers in lubricating oil compositions as well as compatibilizers for compositions containing both polymethacrylates and olefin copolymers or hydrogenated block polymers.
    Type: Grant
    Filed: November 29, 1999
    Date of Patent: February 26, 2002
    Assignee: Ethyl Corporation
    Inventors: Munmaya K. Mishra, Roderic P. Quirk, Robert S. Porzio
  • Patent number: 6258761
    Abstract: A composition prepared by reacting (A) an esterified carboxy-containing interpolymer, said interpolymer being derived from at least two monomers, (i) one of said monomers being at least one vinyl aromatic monomer and (ii) the other of said monomers being at least one alpha, beta-unsaturated acylating agent, and having, before esterification, {overscore (M)}n determined by gel permeation chromatography ranging from about 8,000 to about 350,000, wherein from about 80% to about 99% of the carboxylic groups of said interpolymer are esterified, wherein from about 80 to about 100% of the ester groups contain from 8 to about 23 carbon atoms and from 0 to about 20% of the ester groups contain from 2 to 7 carbon atoms, with (B) a hydrocarbyl substituted carboxylic acid or functional derivative thereof wherein the hydrocarbyl group comprises from about 10 to about 400 carbon atoms, and (C) an amine having an average of more than 1 condensable N—H group, in any order or simultaneously, or with the preformed reac
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: July 10, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Richard M. Lange, James R. Shanklin, Jr., Jeffry G. Dietz, Richard Yodice, Naresh C. Mathur