With Hydrocarbon Polymer, Carboxylic Acid, Or Carboxylic Acid Salt Patents (Class 508/473)
  • Patent number: 10077412
    Abstract: Provided are a viscosity modifier for lubricating oils for obtaining an additive composition for lubricating oils having excellent fluidity in a wide temperature range from low temperature to high temperature; and said additive composition for lubricating oils. Further provided are a viscosity modifier for lubricating oils for obtaining a lubricating oil composition capable of reducing viscosity in good balance in a wide temperature range from low temperature to high temperature; and said lubricating oil composition. The viscosity modifier for lubricating oils includes an ethylene ?-olefin copolymer (A) which includes 30 to 50 mole % of structural units derived from at least one ?-olefin selected from ?-olefins having 4 and 5 carbon atoms and 50 to 70 mole % of structural units derived from ethylene (with the proviso that the total of all structural units of said copolymer is 100 mole %) and which satisfies specific requirements (a), (b), and (c).
    Type: Grant
    Filed: March 27, 2015
    Date of Patent: September 18, 2018
    Assignees: MITSUI CHEMICALS, INC., THE LUBRIZOL CORPORATION
    Inventors: Atsushi Yamamoto, Terufumi Suzuki, Kenta Ide, Chor Huang
  • Publication number: 20150018259
    Abstract: A lubricant composition is disclosed. The lubricant composition is made up of (a) an API Group III base stock; (b) one or more semi-crystalline viscosity modifier; and (c) one or more LOFIs having a side-chain distribution which satisfies the following requirements: (1) the distribution contains side chains ranging from C8 to C18 with an average carbon number ranging from 12.4 to 14.4; (2) the side chain distribution is bi-modal with a lower portion of the bi-modal distribution made up primarily of C12 and an upper portion of the distribution made up primarily of C16, C18 or combinations thereof; (3) the total mole % of the upper portion of the distribution must be less than that of the lower portion of the distribution; and (4) the amount of C12 on the side chain must be at least 40 mole % of the total side chain distribution.
    Type: Application
    Filed: July 9, 2013
    Publication date: January 15, 2015
    Inventors: Ricardo A. Bloch, Doyle H. Boese, David J. Martella
  • Publication number: 20140315771
    Abstract: A lubricating oil composition for a transmission includes a base oil in a range of 1 mass % to 80 mass %, the base oil having a kinematic viscosity at 40 degrees C. in a range of 0.5 mm2/s to 20 mm2/s and a viscosity index of 200 or more. Since the composition exhibits a high viscosity index and a high shear stability, the composition is suitable for a continuously variable transmission.
    Type: Application
    Filed: November 16, 2012
    Publication date: October 23, 2014
    Applicant: IDEMITSU KOSAN, CO., LTD.
    Inventor: Toshiaki Iwai
  • Patent number: 8778857
    Abstract: A lubricant composition, additive concentrate, and method for lubricating an engine. The crankcase lubricant has less than 30 weight percent of a relatively low Noack volatility base oil and a viscosity additive. The viscosity additive has a minor effective amount of sacrificial polymeric viscosity index improver having a shear stability index (SSI) of greater than about 45 and a major amount of a viscosity index improver having an SSI of less than about 26. The minor amount of sacrificial viscosity index improver additive is effective to provide a lubricant composition having a ratio of absolute viscosity increase at 40° C. to an absolute viscosity increase at 40° C. of an RL 216 reference oil of less than about 0.8.
    Type: Grant
    Filed: August 6, 2009
    Date of Patent: July 15, 2014
    Assignee: Afton Chemical Corporation
    Inventor: Peter Growcott
  • Publication number: 20140080742
    Abstract: The present invention provides a lubricating oil composition for an internal combustion engine used mainly to drive a generator and to improve the fuel economy thereof. The composition comprises (A) a base oil being a hydrocarbon base oil having a ratio (CA/CB) of the proportion of the component of 24 or fewer carbon atoms (CA) and the proportion of the component of 25 or more carbon atoms (CB) in the carbon number distribution obtained by gas chromatography distillation of 2.0 or higher, the composition having a ratio (Vs/Vk) of the 80° C. high-temperature high-shear (HTHS) viscosity (Vk) and the 150° C. HTHS viscosity (Vs) of 0.4 or higher and a 100° C. kinematic viscosity of 5.2 mm2/s or higher and 8 mm2/s or lower.
    Type: Application
    Filed: January 20, 2012
    Publication date: March 20, 2014
    Applicant: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Hiroya Miyamoto, Akira Yaguchi
  • Publication number: 20130196888
    Abstract: A lubricant composition includes: (a) one or more base oils, (b) at least one comb polymer formed by a polyalkyl(meth)acrylate main chain, and hydrocarbon side chains including at least 50 carbon atoms, (c) at least one nitrogen-containing organic friction modifier chosen from the optionally alkoxylated fatty amines, fatty amides or imides obtained by the condensation of fatty amines and carboxylic acids, alone or in a mixture, (d) optionally, one or more organometallic organomolybdenum-type friction modifiers. This is used for the lubrication of 4-stroke gasoline or diesel engines of light vehicles, preferentially of hybrid vehicles.
    Type: Application
    Filed: August 25, 2011
    Publication date: August 1, 2013
    Inventor: Nguyen Truong-Dinh
  • Patent number: 8410035
    Abstract: A lubricating oil composition for a power transmission system, which is excellent in both of low-temperature viscosity property and shear stability, is provided. The viscosity modifier of a lubricating oil for a power transmission system according to the present invention comprises an ethylene/?-olefin copolymer (B) having the properties: (B1) an ethylene content in the range of 70 to 85% by mol, (B2) an intrinsic viscosity [?] in the range of 0.2 to 1.0 dl/g, (B3) Mw/Mn not more than 2.4, and (B4) a melting point, as measured by DSC, not higher than 60° C., or no melting point observed.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: April 2, 2013
    Assignees: Mitsui Chemicals, Inc., The Lubrizol Corporation
    Inventors: Ryousuke Kaneshige, Akihiro Matsuda, Satoshi Ikeda, Keiji Okada, Masaaki Kawasaki
  • Publication number: 20120309659
    Abstract: A lubricating oil composition contains (A) a base oil for a lubricating oil in a range of 5 mass % to 70 mass % based on a total amount of the composition, the base oil containing a sulfur content of 0.03 mass % or less and having a kinematic viscosity at 100 degrees C. in a range of 0.5 mm2/s to 1.5 mm2/s, and (B) a poly-alpha-olefin in a range of 15 mass % to 30 mass % based on the total amount of the composition, the poly-alpha-olefin having a kinematic viscosity at 100 degrees C. of 150 mm2/s or more.
    Type: Application
    Filed: November 17, 2010
    Publication date: December 6, 2012
    Applicant: Idemitsu Kosan Co., Ltd.
    Inventor: Hiroshi Fujita
  • Publication number: 20120157318
    Abstract: The present invention relates to the use of a branched addition copolymer in combination with a polymer in a solution or melt formulation to reduce the viscosity of the solution formulation and/or melt formulation compared to the viscosity of a solution and/or melt comprising the polymer alone wherein the branched addition copolymer is obtainable by an addition polymerisation process, methods for the preparation of the formulations, and novel branched addition copolymers for use as same.
    Type: Application
    Filed: September 8, 2010
    Publication date: June 21, 2012
    Applicant: UNILEVER PLC
    Inventors: Paul Hugh Findlay, Brodyck James Lachlan Royles, Roselyne Marie Andree Baudry, Neil John Simpson, Sharon Todd, Steven Paul Rannard
  • Publication number: 20120142568
    Abstract: The present invention provides a lubricating composition comprising a base oil (A) and a hydroxyl group-added poly(meth)acrylate (B).
    Type: Application
    Filed: June 29, 2010
    Publication date: June 7, 2012
    Inventor: Toru Ikai
  • Publication number: 20110077183
    Abstract: A lubricating oil composition which comprises a base oil of lubricating oil having a kinematic viscosity of 3.5 to 10 mm2/s at 100° C. and a viscosity index of 100 or greater and (a) an ethylene-?-olefin copolymer having a number-average molecular weight of 2,500 to 25,000 and/or (b) a polymethacrylate having a number-average molecular weight of 10,000 to 30,000, wherein the kinematic viscosity of the composition is 5.6 to 15.0 mm2/s at 100° C. The lubricating oil exhibits excellent property for decreasing fuel consumption and can suppress generation of noise and vibration.
    Type: Application
    Filed: March 11, 2009
    Publication date: March 31, 2011
    Applicant: IDEMITSU KOSAN CO., LTD
    Inventors: Hideyuki Murata, Moritsugu Kasai
  • Publication number: 20100035778
    Abstract: The present invention provides a composition for a power transmitting fluid that has improved fuel economy, aeration, and cold temperature performance. Additionally, the composition maintains viscosity at higher temperatures that are in line with the viscometrics of current known automatic transmission fluids. The composition preferably comprises an additive and a base stock having a polyalphaolefin blend.
    Type: Application
    Filed: July 20, 2009
    Publication date: February 11, 2010
    Applicant: GM GLOBAL TECHNOLOGY OPERTAIONS, INC.
    Inventor: Roy Fewkes
  • Publication number: 20090312208
    Abstract: A lubricating oil composition for internal combustion engines which comprises a base oil comprising mineral oils and/or synthetic oils and polyisobutylene having a weight-average molecular weight of 500,000 or higher. Consumption of the engine oil can be decreased by using the above composition. In particular, consumption of the engine oil can be decreased even when the above composition is used as the engine oil of the energy saving type using a base oil having a low viscosity.
    Type: Application
    Filed: March 29, 2007
    Publication date: December 17, 2009
    Applicant: IDEMITSU KOSAN CO., LTD.
    Inventors: Motoharu Ishikawa, Masahiko Kido
  • Publication number: 20090023619
    Abstract: A lubricating oil composition for a power transmission system, which is excellent in both of low-temperature viscosity property and shear stability, is provided. The viscosity modifier of a lubricating oil for a power transmission system according to the present invention comprises an ethylene/?-olefin copolymer (B) having the properties: (B1) an ethylene content in the range of 70 to 85% by mol, (B2) an intrinsic viscosity [?] in the range of 0.2 to 1.0 dl/g, (B3) Mw/Mn not more than 2.4, and (B4) a melting point, as measured by DSC, not higher than 60° C., or no melting point observed.
    Type: Application
    Filed: March 24, 2006
    Publication date: January 22, 2009
    Applicants: Mitsui Chemicals, Inc., The Lubrizol Corporation
    Inventors: Ryousuke Kaneshige, Akihiro Matsuda, Satoshi Ikeda, Keiji Okada, Masaaki Kawasaki
  • Patent number: 7189682
    Abstract: A composition of the following components: an oil of lubricating viscosity; a polymethacrylate viscosity modifier; an ester of a maleic acid/styrene copolymer; and optionally, an additive package that imparts to the fluid the capacity to meet bench and dynamometer tests specified by an equipment manufacturer, is suitable for use as a functional fluid such as a tractor hydraulic fluid, under a wide variety of climatic conditions.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: March 13, 2007
    Assignee: The Lubrizol Corporation
    Inventor: Richard E. Gapinski
  • Publication number: 20040132629
    Abstract: A lubricating oil composition comprising an oil of lubricating viscosity and a total of from about 1 to about 50% by weight of copolymers comprising (A) at least one ethylene-aliphatic olefin copolymer wherein the aliphatic olefins contain from 3 to about 24 carbon atoms, said copolymer (A) having {overscore (M)}n ranging from about 600 to about 5000, and (B) at least one copolymer comprising units derived from alkyl acrylate ester monomers containing from 2 to about 25 carbon atoms in the ester group, and optionally, from about 0.1% to about 20% by weight of at least one member of the group consisting of vinyl aromatic monomers and nitrogen-containing vinyl monomers. said copolymer (B) having {overscore (M)}n ranging from about 10,000 to about 350,000, wherein the weight ratio of (A):(B) ranges from about 99:1 to about 1:99.
    Type: Application
    Filed: October 8, 2003
    Publication date: July 8, 2004
    Inventors: James N. Vinci, Craig D. Tipton, Robert W. Cain
  • Patent number: 6734147
    Abstract: A process is disclosed for manufacturing a lubricant composition comprising combining a superabsorbent polymer with a material for decreasing friction between moving surfaces. The superabsorbent polymer absorbs from about 25 to greater than 100 times its weight in water and may comprise a polymer of acrylic acid, an acrylic ester, acrylonitrile or acrylamide, including co-polymers thereof or starch graft co-polymers thereof or mixtures thereof. A product produced by the process includes the material for decreasing friction comprising a petroleum lubricant containing an additive, water containing an additive, synthetic lubricant, grease, solid lubricant or metal working lubricant, wherein the synthetic lubricant, grease, solid lubricant or metal working lubricant optionally contain an additive. A process comprising controlling the delivery of a lubricant to at least one of two moving surfaces in order to decrease friction between said moving surfaces, is also disclosed.
    Type: Grant
    Filed: October 3, 1997
    Date of Patent: May 11, 2004
    Assignee: LCC County Mosquito Control
    Inventor: Richard Levy
  • Patent number: 6402983
    Abstract: Disclosed herein is a flame retardant hydraulic oil excellent in the flame retardancy, unaccompanied by the dangers of pinhole fire at sites of use and giving rise to no environmental contamination. This flame retardant hydraulic oil contain a hydraulic base oil comprising as the essential component an polyol partial ester which is a product formed by reacting (A) a polyol having a total of 6 to 22 carbon atoms and a total of 3 to 6 hydroxyl groups with (B) an acyclic monocarboxylic acid having a total of 6 to 22 carbon atoms. Said polyol partial ester has a hydroxyl value of 35 mg KOH/g or more, a flash point of 290° C. or higher and an average molecular weight of 600 to 1,500.
    Type: Grant
    Filed: July 11, 1995
    Date of Patent: June 11, 2002
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Kazuaki Abe, Hiromichi Seiki, Mitsuhiro Iwata
  • Patent number: 6361711
    Abstract: Disclosed herein is a flame retardant hydraulic oil excellent in the flame retardancy, heat stability and oxidative stability, unaccompanied by the dangers of pinhole fire and giving rise to no environmental contamination. This flame retardant hydraulic oil contains a hydraulic base oil including as the essential component a synthetic ester, which is a product formed by reacting (A) at least one polyol selected from the group consisting of neopentyl glycol, 2,2-dimethyl-3-hydroxypropyl-2′,2′-dimethyl-3′-hydroxypropionate, glycerin and trimethylolpropane with (B) a carboxylic acid including 15 to 85% by mole of oleic acid based on the total carboxylic acid and 15 to 85% by mole of isostearic acid based on the total carboxylic acid or a carboxylic acid obtained by incorporating into the carboxylic acid 85% by mole or less of monocarboxylic acid having 6 to 22 carbon atoms (excluding oleic acids and isostearic acids) based on the total carboxylic acid.
    Type: Grant
    Filed: June 13, 1995
    Date of Patent: March 26, 2002
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Kazuaki Abe, Hiromichi Seiki, Mitsuhiro Iwata
  • Patent number: 6034041
    Abstract: Disclosed is a solid or aqueous lubricant concentrate used for the cold forming of metals, which, with reference to the solids content, including a) 20 to 50 parts by weight polyethylene with a softening point above 120.degree. C. and a particle size int he range between 0.1 and 50 .mu.m; b) 20 to 8 parts by weight polyacrylate with a molecular weight of 4,500 to 10,000 and c) 2 to 8 parts by weight styrene/acrylic acid copolymer with a molecular weight of 150,000 to 250,000 and a glass transition temperature of 45 to 55.degree. C., where, under the conditions of use, the acrylic acid component of the polymers in accordance with items b) and c) is predominantly present as salt of one or more inorganic cations, and the softening points of the individuals polymers are distributed over the temperature range defined by the limiting values of ambient temperature and 200.degree. C.
    Type: Grant
    Filed: August 20, 1998
    Date of Patent: March 7, 2000
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Klaus-Dieter Nittel, Norbert Schwinke-Kruse, Gunter Hesse
  • Patent number: 5939365
    Abstract: A lubricant which comprises: a mineral oil basestock which has been dewaxed via catalytic cracking and/or catalytic isomerization; an alkylene-alkylene copolymer; and a lubricating oil flow improver formed from the reaction product of: (a) an unsaturated carboxy ester formed via the esterification of an unsaturated carboxylic acid or its corresponding anhydride with a monohydric aliphatic alcohol having an average carbon number of between about 10 to 18, the unsaturated carboxy ester having the formula: ##STR1## wherein R' is selected from the group consisting of hydrogen and COOR and wherein R is a C.sub.6 to C.sub.22 alkyl group; and (b) a monomer selected from the group consisting of(i) a vinyl ester having the formula: ##STR2## wherein R.sub.1 comprises an alkyl group containing from 1 to 18 carbon atoms;(ii) an olefin having the formula ##STR3## wherein R.sub.1 and R.sub.2 can independently be hydrogen, an alkyl having from 1 to 28 carbon atoms, or a substituted aryl group, provided both R.sub.1 and R.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: August 17, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: John V. Redpath, Arunas T. Lapinas, David J. Martella, Albert Rossi, William M. Davis
  • Patent number: 5538651
    Abstract: A composition comprising (A) an ethylene-alpha olefin-bicyclic non-conjugated diene copolymer, wherein the alpha olefin contains from 3 to about 24 carbon atoms; (B) at least one organic sulfur containing compound selected from the group consisting of mercaptans and disulfides; and (C) a major amount of diluent; wherein the sulfur-containing compound (B) is present in amounts ranging from about 0.1% to about 15% by weight relative to the weight of the copolymer (A). This invention also relates to a method of shearing a composition comprising (A) an ethylene-alpha olefin-bicyclic non-conjugated diene copolymer and (C) a diluent, the improvement which comprises reducing or preventing the formation of gel-like particles on shearing by intimately mixing with said copolymer prior to shearing an amount of (B) an organic sulfur containing compound selected from the group consisting of mercaptans and disulfides in an amount sufficient to inhibit formation of said gel-like particles.
    Type: Grant
    Filed: June 19, 1995
    Date of Patent: July 23, 1996
    Assignee: The Lubrizol Corporation
    Inventors: Bryan A. Grisso, Richard M. Lange