Alkaline Earth Metal, Aluminum, Or Heavy Metal Salt Of The Hydroxy Carboxylic Acid Patents (Class 508/523)
  • Patent number: 9023773
    Abstract: Lubrication additives of the current invention require formation of emulsions in base lubricants, created with an aqueous salt solution plus a single-phase compound such that partitioning within the resulting emulsion provides thermodynamically targeted compounds for boundary layer organization thus establishing anti-friction and/or anti-wear. The single-phase compound is termed “boundary layer organizer”, abbreviated BLO. These emulsion-contained compounds energetically favor association with tribologic surfaces in accord with the Second Law of Thermodynamics, and will organize boundary layers on those surfaces in ways specific to the chemistry of the salt and BLO additives. In this way friction modifications may be provided by BLOs targeted to boundary layers via emulsions within lubricating fluids, wherein those lubricating fluids may be water-based or oil-based.
    Type: Grant
    Filed: May 22, 2013
    Date of Patent: May 5, 2015
    Assignee: The United States of America as Represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Robert Chaffee Richmond, Harry F. Schramm, Jr., Francis G. Defalco
  • Publication number: 20140116368
    Abstract: The invention provides a lubricating composition containing a lubricating composition comprising an oil of lubricating viscosity and a polyester. The invention further relates to a method of lubricating a mechanical device (such as an internal combustion engine) with the lubricating composition. The invention further relates to the use of the polyester as a dispersant.
    Type: Application
    Filed: June 18, 2012
    Publication date: May 1, 2014
    Applicant: The Lubrizol Corporation
    Inventor: Matthew D. Gieselman
  • Patent number: 8664170
    Abstract: The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.
    Type: Grant
    Filed: February 15, 2013
    Date of Patent: March 4, 2014
    Assignee: Chevron Oronite Company LLC
    Inventors: Curtis Bay Campbell, Eugene Edward Spala, Willie Horn, Jr.
  • Patent number: 8648020
    Abstract: Overbased MgO dispersions with high magnesium content and acceptably low viscosities are prepared without gel formation by heating to 280-360° C. under high pressure in a sealed reactor a mixture of MgO, selected dispersants, low MW carboxylic acids, water and a hydrocarbon solvent having a boiling point below 280° C. No additional solubilizing or dispersing agents, promoters or reactants such as carbon dioxide, amines, alcohols etc are needed to obtain the desired dispersions. Compositions such as lubricating oils and fuels containing the overbased magnesium dispersions as additives are also disclosed.
    Type: Grant
    Filed: April 26, 2012
    Date of Patent: February 11, 2014
    Assignee: Chemtura Corporation
    Inventors: Qinggao Ma, Mitchel Cohn
  • Patent number: 8618028
    Abstract: Fire resistant lubricating grease compositions resistant to self ignition and/or capable of self extinguishment when contacted with surfaces having temperatures of up to 900° C. are disclosed. The invention provides for grease compositions comprising (1) base oil (which can be mineral, vegetable, synthetic or combinations thereof), (2) at least one grease thickener (selected from calcium sulfonates or lithium-based soaps), and (3) water as major components. The invention also provides a method for the preparation of the grease composition and a method for lubrication of bearings, gears, surfaces and other lubricated components comprising use of the grease composition of the present invention. The grease compositions of this invention display excellent fire resistance properties and still have outstanding physical and performance characteristics for applications where temperatures and loads are high, shock loading is significant and in the presence of significant amounts of water.
    Type: Grant
    Filed: June 1, 2009
    Date of Patent: December 31, 2013
    Assignee: Castrol Limited
    Inventors: Hocine Faci, Robert N. Cisler, Alex M. Medrano
  • Patent number: 8603958
    Abstract: Embodiments of the invention include compositions of calcium/lithium complex greases containing calcium/lithium soaps having a high calcium fraction and complexing agents, encapsulated constant velocity shafts containing such lubricating greases and the use of the lubricating greases in encapsulated shafts of constant velocity shafts.
    Type: Grant
    Filed: July 24, 2009
    Date of Patent: December 10, 2013
    Assignee: Fuchs Petrolub AG
    Inventors: Thomas Litters, Alexander Liebenau
  • Patent number: 8580716
    Abstract: Overbased MgO dispersions with high magnesium content and acceptably low viscosities are reproducibly prepared without gel formation by heating to 280-360° C. a mixture of MgO, selected dispersants, low MW carboxylic acids, water and a combination of high boiling hydrocarbon and organic diluent, wherein water is more than 8%, typically more than 10% of the reaction mixture. No additional solubilizing or dispersing agents, promoters or reactants such as carbon dioxide, amines, alcohols etc are needed to obtain the desired dispersions. Compositions such as lubricating oils and fuels containing the overbased magnesium dispersions as additives are also disclosed.
    Type: Grant
    Filed: June 23, 2011
    Date of Patent: November 12, 2013
    Assignee: Chemtura Corporation
    Inventors: Qinggao Ma, Cyril A. Migdal, Kirk A. Schlup, John-Louis DiFlavio, Ronald J. Muir
  • Patent number: 8420582
    Abstract: A wear and/or friction reducing additive for a lubricating fluid in which the additive is a combination of a moderately hydrophilic single-phase compound and an anti-wear and/or anti-friction aqueous salt solution. The aqueous salt solution produces a coating on boundary layer surfaces. The lubricating fluid can be an emulsion-free hydrophobic oil, hydraulic fluid, antifreeze, or water. Preferably, the moderately hydrophilic single-phase compound is sulfonated castor oil and the aqueous salt solution additionally contains boric acid and zinc oxide. The emulsions produced by the aqueous salt solutions, the moderately hydrophilic single-phase compounds, or the combination thereof provide targeted boundary layer organizers that significantly enhance the anti-wear and/or anti-friction properties of the base lubricant by decreasing wear and/or friction of sliding and/or rolling surfaces at boundary layers.
    Type: Grant
    Filed: February 15, 2011
    Date of Patent: April 16, 2013
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Robert Chafee Richmond, Harry F. Schramm, Jr., Francis G. Defalco
  • Patent number: 8399388
    Abstract: The present invention is directed to a method for preparing an unsulfurized, carboxylate-containing additive for lubricating oils and the product produced by said method, wherein said method comprises a) neutralization of a mixture of at least two alkyl phenols using an alkaline earth base in the presence of a promoter, to produce a mixture of alkyl phenates, wherein the mixture of at least two alkyl phenols comprises at least a first alkyl phenol wherein the alkyl group is derived from an isomerized alpha olefin and a second alkyl phenol wherein the alkyl group is derived from a branched chain olefin; (b) carboxylation of the mixture of alkyl phenates obtained in step (a) using carbon dioxide under carboxylation conditions sufficient to convert at least 20 mole % of the starting alkyl phenols to alkyl salicylate; and (c) removal of at least about 10% of the starting mixture of at least two alkyl phenols from the product produced in step (b) to produce said additive.
    Type: Grant
    Filed: July 1, 2009
    Date of Patent: March 19, 2013
    Assignee: Chevron Oronite Company LLC
    Inventors: Curtis Bay Campbell, Eugene Edward Spala, Willie Horn, Jr.
  • Patent number: 7635669
    Abstract: There is provided a fluid composition including at least one hydroxy-substituted carboxylic acid. Also provided are methods of inhibiting at least one of corrosion and rust and of improving at least one of lubricity and lead compatibility. Also provided are lubricating, fuel, anticorrosion, antirust, and additive concentration compositions.
    Type: Grant
    Filed: October 4, 2004
    Date of Patent: December 22, 2009
    Assignee: Afton Chemical Corportation
    Inventor: Scott Anthony Culley
  • Patent number: 6482780
    Abstract: A grease composition for rolling bearing comprising a metal soap-based thickening agent containing a long fiber-like material having a major axis length of at least 3 &mgr;m incorporated in a base oil comprising a lubricant having a polar group in its molecular structure and a non-polar lubricant blended in combination.
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: November 19, 2002
    Assignees: Kyodo Yushi Co., Ltd., NSK Ltd.
    Inventors: Atsushi Yokouchi, Jun Kuraishi, Youichiro Sugimori, Yasunobu Fujita, Michiharu Naka, Atsushi Shibayama, Hiroshi Kimura
  • Patent number: 6159911
    Abstract: Disclosed is a diesel engine oil composition containing a lube oil base and one or more metallic detergent-dispersants selected from among a perbasic alkaline earth metal sulfonate, phenolate, and salicylate. The total phosphorus content of the composition is suppressed to 100 ppm by weight or less, to thereby provide diesel engine oil compositions having excellent oxidation stability and wear resistance.
    Type: Grant
    Filed: April 15, 1998
    Date of Patent: December 12, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Tadashi Katafuchi
  • Patent number: 6008169
    Abstract: Disclosed is a refrigerator oil composition comprising at least one base oil selected from mineral oils and synthetic oils, and at least one hydroxy-fatty acid derivative selected from (A) hydroxy-fatty acids or their condensates, (B) metal salts or amine salts of hydroxy-fatty acids or their condensates, and (C) esters of hydroxy-fatty acids. The composition has an excellent lubricating property, while specifically improving the lubricity between aluminium materials and steel materials. This is effective for preventing such materials from being seized and worn, and is suitable as a lubricating oil in refrigerators using hydrogen-containing Flon refrigerants, such as R134a, that do not cause environmental pollution.
    Type: Grant
    Filed: April 2, 1997
    Date of Patent: December 28, 1999
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Masato Kaneko