Benzene Ring Attached Indirectly To The Sulfur Atom Or Sulfur Chain By Acyclic Nonionic Bonding Patents (Class 508/571)
  • Patent number: 9574149
    Abstract: A fuel composition for a direct fuel injected diesel engine, a method for improving performance of fuel injectors and a method for cleaning fuel injectors for a diesel engine. The fuel composition includes a major amount of fuel and a minor, effective amount of a quaternary ammonium salt having a thermogravimetric analysis (TGA) weight loss of greater than 50 wt. % at 350° C. The amount of quaternary ammonium salt present in the fuel is sufficient to improve performance of the direct fuel injected diesel engine having combusted the composition compared to the performance of such engine having combusted a fuel composition that does not contain the quaternary ammonium salt.
    Type: Grant
    Filed: November 11, 2011
    Date of Patent: February 21, 2017
    Assignee: Afton Chemical Corporation
    Inventors: Xinggao Fang, Julienne M. Galante-Fox
  • Patent number: 8580718
    Abstract: Described are multi-ring antioxidant products comprising at least one sulfur-bridged aromatic hydrocarbon compound substituted on at least one of its aromatic rings by at least one sterically hindered 3,5-dihydrocarbyl-4-hydroxybenzyl moiety. Such products have the formula: R—Sn—R[—S—R]m wherein each R is, independently, an aromatic hydrocarbon group having 6-12 carbon atoms, wherein m is 0-20, wherein n is 1-6 when m is 0, and when n is 1, m is 1-20; and wherein at least one of R, R1, and R2 is substituted by at least one such sterically hindered moiety. The preparation of such products and their use as antioxidants in compositions normally susceptible to oxidative degradation in oxygen or air, e.g., liquid fuel and lubricants, are also described.
    Type: Grant
    Filed: July 13, 2009
    Date of Patent: November 12, 2013
    Assignee: Albermarle Corporation
    Inventor: Mahmood Sabahi
  • Patent number: 8299007
    Abstract: A method of improving air release is disclosed. The method comprises obtaining a lubricant comprising two base stocks. The first base stock comprises a viscosity greater than 100 cSt, Kv100° C. The second base stock comprises a viscosity less than 10 cSt, Kv100° C. In addition, a lubricant formulation and method of blending a lubricant formulation is also disclosed. The lubricant formulation comprises at least two base stocks. At least 5 percent and no more than 90 percent of a first base stock comprising oil with a viscosity greater than 300 cSt, Kv100° C. At least 5 percent and no more than 90 percent of a second base stock comprising oil with a viscosity less than 10 cSt, Kv100° C.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: October 30, 2012
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: James T. Carey, Angela S. Galiano-Roth, Thomas G. Dietz
  • Patent number: 6767872
    Abstract: A lubricant compound for use for both boundary and elastohydrodynamic lubrication utilize a hydrocarbon boundary lubricant linked to one or more fluorocarbon elastohydrodynamic lubricants and may be employed alone or as an additive. The lubricant compound lubricates surfaces on which it is disposed over a range of conditions. The boundary lubricant and the elastohydrodynamic lubricant are substituted such that they react with and/or provide desirable lubrication properties for particular surfaces.
    Type: Grant
    Filed: May 10, 2002
    Date of Patent: July 27, 2004
    Assignee: The Charles Stark Draper Laboratory, Inc.
    Inventor: John R. Williams
  • Patent number: 6689726
    Abstract: Lubricating oil formulations comprising base oil, sulfur-phosphorous anti-wear/extreme pressure agent and hindered phenol antioxidant, which combination of extreme pressure agent and hindered phenol antioxidant produces crystals and containing antioxidants, wherein the base oil is characterized as having a saturates content of 99 wt % or more is stabilized against crystal formation by the addition of a minor amount of high molecular weigh di- or polycarboxylic acid, or anhydride and an ester.
    Type: Grant
    Filed: June 17, 2002
    Date of Patent: February 10, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: David Gary Lawton Holt
  • Publication number: 20030171227
    Abstract: Stabilising compositions for lubricant base stocks and lubricant formulations are composed of a mixture of (a) at least one aromatic aminic amine antioxidant optionally blended with at least one hindered phenolic antioxidant and (b) at least one neutral organo phosphate or phosphite, optionally blended with at least one acid organo phosphate or phosphite. These stabilising composition mixtures are characterised by their stabilising capacity which is considerably higher than that of either the single antioxidants or the single phosphate or phosphite additives. These stabilising compositions can be used in all fields where the single components of the mixtures are generally used and where deterioration due to oxidation processes takes place.
    Type: Application
    Filed: November 5, 2002
    Publication date: September 11, 2003
    Inventors: Alan Holt, Gerard Mulqueen
  • Publication number: 20030158055
    Abstract: The present invention provides a viscosity index improving lubricant additive which comprises an olefinic oligomer of about 2,000 to about 20,000 number average molecular weight having a viscosity of 75 to about 3,000 cSt at 100° C. and a hydrocarbyl aromatic which contains at least about 5% of its weight from aromatic moieties having a viscosity of about 3 to about 50 cSt at 100° C. where the weight ratio of hydrocarbyl aromatic component to olefin oligomer is from about 1:2 to about 50:1. In another aspect, the invention provides for a lubricating oil composition comprising a base oil and the instant viscosity index improving additive.
    Type: Application
    Filed: December 16, 2002
    Publication date: August 21, 2003
    Inventors: Douglas Edward Deckman, William L. Maxwell, William H. Buck, Mark D. Winemiller, David J. Baillargeon
  • Patent number: 6326337
    Abstract: An oxidation-corrosion additive for enhancing the stability of PFPAEs which has the formula: wherein Q is —Rf or —S—Rf, Rf is a perfluoroalkyl or perfluoroalkylether group having 1 to 30 carbon atoms, x and y are integers, each having a value of 0-5, wherein the sum of x and y is in the range of 1 to 10. In the formula above, Rf may be linear or branched. The additive can be a single component or a mixture of components varying in the number and relative positions of x and y. The additive can be used alone or with other suitable additives in PFPAE base fluids.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: December 4, 2001
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Kalathil C. Eapen, Grace J. Chen, Wayne E. Ward, Harvey L. Paige
  • Patent number: 5962380
    Abstract: The use of an effective amount of a compound as an additive improving the compatibility of a lubricating oil formulation having dispersants containing basic nitrogen atoms, with fluorocarbon elastomer seals. That compound has the formula: ##STR1## wherein R and R.sup.1 are independently alkoxycarbonyl, alkenyloxycarbonyl, aryloxycarbonyl, alkylcarbonyl, alkenylcarbonyl, arylcarbonyl, or arylalkyl, or together form a carbocycle, and R.sup.2 and R.sup.3 are independently sulfurized alkyl, alkoxycarbonylalkyl, arylalkyl, or borated hydroxyalkyl, with the proviso that R, R.sup.1, R.sup.2 and R.sup.3 together contain sufficient carbon atoms to render the compound oil soluble in an oil of lubricating viscosity.
    Type: Grant
    Filed: July 16, 1997
    Date of Patent: October 5, 1999
    Assignee: Chevron Chemical Company LLC
    Inventors: Pierre Tequi, Jacques Cazin, Andrew W. Ho
  • Patent number: 5807814
    Abstract: Oil soluble compounds having the formula: ##STR1## wherein R and R.sup.1 are independently cyano, alkoxycarbonyl, aryloxycarbonyl, alkenyloxycarbonyl, alkylcarbonyl, arylcarbonyl, alkenylcarbonyl, alkylsulfonyl, arylsulfonyl, alkenylsulfonyl, substituted aminocarbonyl, alkylphosphoryl, arylphosphoryl, alkenylphosphoryl, aryl, or heterocyclics, or together form a carbocycle or heterocycle, and R.sup.2 and R.sup.3 are independently alkyl, alkenyl, hydroxyalkyl, sulfurized alkyl, alkoxycarbonylalkyl, arylalkyl, or borated hydroxyalkyl, with the proviso that R, R.sup.1, R.sup.2 and R.sup.3 together contain sufficient carbon atoms to render the compound oil soluble in an oil of lubricating viscosity. The compound are useful as wear protectants or extreme pressure agents to enhance wear protection or extreme pressure properties in lubricating oils and greases.
    Type: Grant
    Filed: July 5, 1996
    Date of Patent: September 15, 1998
    Assignee: Chevron Chemical Company
    Inventor: Andrew W. Ho
  • Patent number: 5618778
    Abstract: The present invention relates to a composition containing a lubricant or hydraulic fluid and in an effective amount to improve extreme pressure and anti-wear properties of said lubricant or hydraulic fluid of at least one compound of the formula II ##STR1## R.sup.1, R.sup.2, and R.sup.3 together with the C atom to which they are bound are tert-C.sub.4 -C.sub.14 -alkyl. R.sup.4 is phenyl, --CH.sub.2 --CH.sub.2 --NH.sub.2, --CH.sub.2 CH.sub.2 OH, --CH.sub.2 CH(OH)--CH.sub.2 --OH, tert-C.sub.4 -C.sub.14 alkyl, --(CH.sub.2).sub.2 --S--CH(OH)--CH.sub.2 --S-(tert-C.sub.8 -C.sub.12 alkyl), --CH.sub.2 --COOH, --CH.sub.2 --COO--(i-C.sub.8 H.sub.17), --CH.sub.2 --CO--OH.H.sub.2 N-(tert-C.sub.10 -C.sub.16 -alkyl), --P(S)--[O--(i-C.sub.3 H.sub.7)].sub.2, --P(S)--[O--(i-C.sub.8 H.sub.17)].sub.2, .alpha.-naphthyl, benzothiazolyl, benzimidazolyl, thiazolyl, --CH.sub.2 --CH--(OH)--CH.sub.2 --S--R.sup.10 wherein R.sup.10 is tertiary C.sub.4 -C.sub.14 -alkyl, or R.sup.4 is radical ##STR2## R.sup.1, R.sup.2 and R.sup.
    Type: Grant
    Filed: April 12, 1995
    Date of Patent: April 8, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Hermann O. Wirth, Hans-Helmut Friedrich