Polycarboxylic Acid Component, Or Salt Thereof Patents (Class 510/229)
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Publication number: 20120178663Abstract: A phosphate-free automatic dishwashing agent is described comprising from 0.05 to 20 wt. % amphoteric polymer and from 2 to 40 wt. % ethylene diamine disuccinic acid. The novel combination of amphoteric polymer with ethylene diamine disuccinic acid (EDDS) results in excellent performance compared to traditional phosphate-free automatic dishwashing agents, especially with regard to good cleaning, clear rinsing, and the overall inhibition of deposits.Type: ApplicationFiled: March 13, 2012Publication date: July 12, 2012Applicant: Henkel AG & Co. KGaAInventors: Dorota Sendor-Müller, Johannes Zipfel, Arnd Kessler, Christian Nitsch, Thorsten Bastigkeit
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Patent number: 8192552Abstract: The invention relates to a detergent composition, suitable for use in dish washing or laundry, comprising at least 15% of a detersive surfactant(s), and a block copolymer, selected from the group consisting of (block A)-(block B) diblock copolymers, (block A)-(block B)-(block A) triblock copolymers, and (block B)-(block A)-(block B) triblock copolymers, wherein block A and block B derive from alpha ethylenically unsaturated monomers, at least one block being water-soluble. The detergent compositions provide an increased cleaning, and/or a decreased redeposition of the fatty substances once they are removed from a substrate.Type: GrantFiled: February 20, 2009Date of Patent: June 5, 2012Assignee: Rhodia ChimieInventor: Jeanne Chang
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Patent number: 8193139Abstract: The invention relates to a phosphate-free cleaning formulation for machine dishwashing, comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 93 mol % acrylic acid and/or of a water-soluble salt of acrylic acid, a2) 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid and a3) 2 to 20 mol % of at least one nonionic monomer of the formula (I), b) 1 to 50% by weight of complexing agents chosen from the group consisting of glycine-N,N-diacetic acid derivatives and glutamic acid-N,N-diacetic acid and salts thereof, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) 0 to 50% by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water, where the sum of componentsType: GrantFiled: August 28, 2006Date of Patent: June 5, 2012Assignee: BASF AktiengesellschaftInventors: Tanja Seebeck, Juergen Tropsch, Lars Kissau
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Patent number: 8188025Abstract: The present invention relates to acidic sanitizing and/or cleaning compositions comprising a specific quaternary antimicrobial system consisting of C1-C4 hydroxyalkyl carboxylic acids, C5-C18 alkyl monocarboxylic acids, unsubstituted or substituted, saturated or unsaturated C4-dicarboxylic acids and additional inorganic or organic acids. The compositions of the present invention can be present in the form of concentrates and in the form of diluted use solutions. They can be used in a process for sanitizing and/or cleaning hard surfaces, preferably in a cleaning-in-place (CIP) and/or sanitize-in-place (SIP) process for cleaning and/or sanitizing plants in the food, dairy, beverage, brewery and soft drink industries.Type: GrantFiled: April 8, 2011Date of Patent: May 29, 2012Assignee: Diversey, Inc.Inventors: Harry Kany, Holger Theyssen, Andreas John, Mario Stanga, Franco Bruschi
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Publication number: 20120128608Abstract: Hybrid copolymer compositions include a hybrid copolymer including at least one ethylenically unsaturated monomer and a naturally derived hydroxyl containing chain transfer agent as an end group; and a hybrid synthetic copolymer including one or more synthetic polymers derived from the at least one ethylenically unsaturated monomer with at least one initiator fragment as an end group. The hybrid copolymer composition may be prepared as a scale inhibiting composition. Methods of preparing a hybrid copolymer are also included.Type: ApplicationFiled: July 30, 2010Publication date: May 24, 2012Applicant: AKZO NOBEL N.V.Inventors: Klin A. Rodrigues, Matthew M. Vanderhoof, Allen M. Carrier, Jannifer Sanders
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Patent number: 8183196Abstract: A neutral automatic dishwashing detergent composition comprising an acidifying particle comprising an aminocarboxylic builder wherein the acidifying particle has a low hygroscopicity, a cake strength of at most 20N and a pH of from about 2 to about 6 as measured in 1% aqueous solution at 20° C.Type: GrantFiled: April 18, 2011Date of Patent: May 22, 2012Assignee: The Procter & Gamble CompanyInventors: Nigel Patrick Somerville Roberts, Chris Hughes, Robert Ian Dyson
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Publication number: 20120103370Abstract: A dishwasher detergent composition comprising from 0.05 to 7.5 wt % of a surfactant and from 0.1 to 90 wt % of a compound of Formula 1; wherein R is selected from the group consisting of —H, —CH3, —CnH2nCH3, —CnH2nOH, —CnH2nCOOH, —CnH2nSO3H, —CnH2nNH2, —CnH2nNHR?, —CnH2nNRV?2, —NHC(?O)—R? and —CnH2nPO(OR?)2; wherein n?1; and R? is H, alkyl or aryl, and further wherein the composition comprises a bleach selected from inorganic peroxy compounds, organic peracids and salts derived therefrom. The compound of Formula 1 is biodegradable, stable to bleach and yet is an effective builder. The compositions of the invention can be readily formulated as tablet compositions if desired as the compound of Formula 1 is not overly hygroscopic.Type: ApplicationFiled: October 13, 2009Publication date: May 3, 2012Inventors: Steffen Lingler, Judith Preuschen
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Patent number: 8163686Abstract: A dishwasher detergent delivery cartridge comprises a plurality of unit dose elements of a dishwasher detergent composition, the composition being a substantially coherent mass and comprising at least 20 wt % of methyl glycine diacetic acid and/or a salt thereof and/or of glutamic diacetic acid and/or a salt thereof. Such compositions have been found to have excellent stability and/or performance in multi-dose applications.Type: GrantFiled: October 30, 2006Date of Patent: April 24, 2012Assignee: Reckitt Benckiser N.V.Inventors: Karl-Ludwig Gibis, Chris Efstathios Housmekerides
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Patent number: 8123867Abstract: The present invention relates to a phosphate-free machine dishwasher detergent comprising 0.01-20% by weight of at least one alcohol alkoxylate, 0.01-10% by weight of at least one alcohol ethoxylate, 0-15% by weight of at least one sulfonate-containing polymer, 0-15% by weight of at least one hydrophilically modified polycarboxylate, 0-8% by weight of at least one polycarboxylate, 1-50% by weight of at least one complexing agent and 0.1-60% by weight of at least one further additive, where the sum of components (A), (B), (C), (D), (E), (F) and (G) is 100% by weight, to a process for rinsing surfaces of articles by treating these surfaces with the composition, and to the use of the composition for increasing the rinsing performance in the machine washing of articles.Type: GrantFiled: April 24, 2008Date of Patent: February 28, 2012Assignee: BASF SEInventor: Juergen Tropsch
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Patent number: 8101027Abstract: The invention relates to detergent formulations for machine dishwashing which comprise copolymers having sulfonic acid and carboxylic acid functions, and to a method of using of such copolymers in machine dishwashing.Type: GrantFiled: July 31, 2007Date of Patent: January 24, 2012Assignee: BASF AktiengesellschaftInventors: Guido Vandermeulen, Lidcay Herrera Taboada, Tanja Seebeck
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Publication number: 20120006358Abstract: The invention relates to machine dishwashing agents containing specific polycarbonate-, polyurethane-, and/or polyurea-polyorganosiloxane compounds or precursor compounds thereof of the reactive cyclic carbonate and urea type which help to avoid the formation of water spots and filming after the use of the agents and accelerate the drying of dishes.Type: ApplicationFiled: September 20, 2011Publication date: January 12, 2012Applicant: Henkel AG & Co. KGaAInventors: Nadine Warkotsch, Marc-Steffen Schiedel, Johannes Zipfel, Arnd Kessler
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Patent number: 8093196Abstract: A phosphate-free detergent formulation for machine dishwashing is provided. The formulation contains as main components: copolymers of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, and an alkoxylated, monoethylenically unsaturated monomer, wherein the copolymer has a mean molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% by weight aqueous solution at 25° C.; complexing agents; low-foaming nonionic surfactants; bleaches and, optionally, bleach activators; further builders; enzymes; and one or more further additives.Type: GrantFiled: May 20, 2010Date of Patent: January 10, 2012Assignee: BASF SEInventors: Tanja Seebeck, Juergen Tropsch, Lars Kissau
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Patent number: 8093195Abstract: The present invention refers to an aqueous composition comprising one or more amphoteric, organic polynitrogen-compounds having at least 3 nitrogen atoms contained in the molecule in the form of an amine and/or amide and one or more types of inorganic nanoparticles, a concentrate comprising said composition and to a method for treating and/or cleaning a surface which uses said composition.Type: GrantFiled: November 9, 2005Date of Patent: January 10, 2012Assignee: Ecolab USA Inc.Inventors: Stephan Uhl, Jacqueline Thöne
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Patent number: 8048838Abstract: A mixed powder or mixed granule containing at east 80% by weight of a mixture of (a) from 5 to 95% by weight of at least one glycine-N,N-diacetic acid derivative of the general formula (I) MOOC—CHR—N(CH2COOM)2??(I) where R is C1-12-alkyl M is alkali metal, (b) from 5 to 95% by weight of at least one polyethylene glycol or of at least one nonionic surfactant or of a mixture thereof or of a polymer selected from the group consisting of polyvinyl alcohols, polyvinylpyrrolidones (PVP), polyalkylene glycols and derivatives thereof, processes for producing these mixed powders or mixed granules, the use of these mixed powders or mixed granules, and a solid laundry detergent and a solid dishwasher detergent comprising the inventive mixed powder or mixed granule are described.Type: GrantFiled: July 1, 2005Date of Patent: November 1, 2011Assignee: BASF AktiengesellschaftInventors: Helmut Witteler, Michael Schoenherr, Markus Hartmann
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Publication number: 20110263472Abstract: A particle comprising an aminocarboxylic builder obtainable by a process comprising the steps of: a) providing a solution comprising the aminocarboxylic builder; b) optionally adding an acidifying agent; c) adding sulphate or citrate to the solution resulting from of step b) to form a mixture; and d) converting the mixture resulting from step c) into particles.Type: ApplicationFiled: April 18, 2011Publication date: October 27, 2011Inventors: Nigel Patrick Somerville Roberts, Chris Hughes, Robert Ian Dyson
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Publication number: 20110263474Abstract: A neutral automatic dishwashing detergent composition comprising an acidifying particle comprising an aminocarboxylic builder wherein the acidifying particle has a low hygroscopicity, a cake strength of at most 20 N and a pH of from about 2 to about 6 as measured in 1% aqueous solution at 20° C.Type: ApplicationFiled: April 18, 2011Publication date: October 27, 2011Inventors: Nigel Patrick Somerville Roberts, Chris Hughes, Robert Ian Dyson
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Publication number: 20110263473Abstract: A particle comprising an aminocarboxylic builder and sulphate or citrate wherein the aminocarboxylic builder and the sulphate or citrate are present in a weight ratio of from about 6:1 to about 1:1.Type: ApplicationFiled: April 18, 2011Publication date: October 27, 2011Inventors: Nigel Patrick Somerville Roberts, Chris Hughes, Robert Ian Dyson
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Patent number: 8044011Abstract: The invention relates to machine dishwashing agents containing specific polycarbonate-, polyurethane-, and/or polyurea-polyorganosiloxane compounds or precursor compounds thereof of the reactive cyclic carbonate and urea type which help to avoid the formation of water spots and filming after the use of the agents and accelerate the drying of dishes.Type: GrantFiled: September 25, 2009Date of Patent: October 25, 2011Assignee: Henkel AG & Co. KGaAInventors: Nadine Warkotsch, Marc-Steffen Schiedel, Johannes Zipfel, Arnd Kessler
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Publication number: 20110240063Abstract: The invention relates to a phosphate- and bleach-free automatic dishwashing agent containing: a) 5 to 60 wt % citrate, b) (hydrogen) carbonate, c) 2 to 40 wt % ethylenediamine disuccinic acid, wherein the weight ratio of the components b) and c) is between 1:5 and 10:1, and wherein said automatic dishwashing agent is characterized by good cleaning performance, particularly improved cleaning of tea.Type: ApplicationFiled: June 15, 2011Publication date: October 6, 2011Applicant: Henkel AG & Co. KGaAInventors: Dorota Sendor-Müller, Johannes Zipfel, Arnd Kessler, Christian Nitsch, Sven Müller
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Publication number: 20110237482Abstract: Phosphate-free, bleach-free automatic dishwashing agents comprising 10 to 60 wt % citrate and from 1 to 30 wt % maleic acid are described, wherein the automatic dishwashing agents are characterized by good cleaning performance, particularly in the improved cleaning of tea stains.Type: ApplicationFiled: June 13, 2011Publication date: September 29, 2011Applicant: Henkel AG & Co. KGaAInventors: Dorota Sendor-Müller, Johannes Zipfel, Arnd Kessler, Christian Nitsch, Sven Müller, Wolfgang Wick
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Patent number: 7935668Abstract: A detergent composition comprises an MGDA containing particulate material. The MGDA particulate is at least partially coated with a coating of a water soluble/dispersible material having a melting point of less than 100° C. The coating material exhibits a pH of greater than or equal to 7 in an aqueous medium.Type: GrantFiled: July 4, 2005Date of Patent: May 3, 2011Assignee: Reckitt Benckiser N.V.Inventors: Thomas Enkel, Mladen Nedic, Judith Preuschen
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Publication number: 20100311634Abstract: A solidification matrix includes a straight chain saturated carboxylic acid salt, sodium carbonate, and water. The straight chain saturated carboxylic acid salt is selected from a salt of a mono-, di-, or tri-carboxylic acid. The solidification matrix may be used, for example, in a solid detergent composition.Type: ApplicationFiled: July 19, 2010Publication date: December 9, 2010Inventors: Michael E. Besse, Brenda L. Tjelta, Lisa M. Sanders
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Publication number: 20100234264Abstract: A phosphorus-free automatic dishwashing detergent composition containing a polymer of acrylic acid, maleic acid and 2-acrylamido-2-methylpropanesulfonic acid (AMPS); a carbonate; and a silicate. The composition contains carbonate and silicate in a weight ratio from 2.5:1 to 1:4, respectively; from 10 to 90 wt % total carbonate and silicate.Type: ApplicationFiled: March 8, 2010Publication date: September 16, 2010Inventors: Marianne Patricia Creamer, Joseph Manna, Jan Edward Shulman
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Publication number: 20100227787Abstract: A phosphate-free detergent formulation for machine dishwashing is provided. The formulation contains as main components: copolymers of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, and an alkoxylated, monoethylenically unsaturated monomer, wherein the copolymer has a mean molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% by weight aqueous solution at 25° C.; complexing agents; low-foaming nonionic surfactants; bleaches and, optionally, bleach activators; further builders; enzymes; and one or more further additives.Type: ApplicationFiled: May 20, 2010Publication date: September 9, 2010Applicant: BASF AkiengesellschaftInventors: Tanja Seebeck, Jürgen Tropsch, Lars Kissau
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Patent number: 7781387Abstract: A phosphate free automatic dishwashing detergent provides improved spotting and filming performance by including a spot reduction system that contains a combination of a polyacrylate and a carboxymethyl inulin. The detergent also includes an enzyme system that contains a combination of Esperase® 6.0T and an alkaline stable protease.Type: GrantFiled: January 22, 2008Date of Patent: August 24, 2010Assignee: Access Business Group International, LLC.Inventors: Douglas K. Feenstra, Ronald C. Jackson
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Patent number: 7674761Abstract: This invention is directed to a water soluble sachet comprising a detergent composition having a discrete particle that enhances cleaning in a dishwashing machine. The water soluble sachet unexpectedly results in excellent cleaning properties and minimizes spot and film formation on items being cleaned in a dishwasher.Type: GrantFiled: October 8, 2002Date of Patent: March 9, 2010Assignee: Unilever Home & Personal Care, Division of Conopco, Inc.Inventors: Natasha Pfeiffer, Naresh Dhirajlal Ghatlia, Isaac Israel Secemski
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Patent number: 7645345Abstract: Use of copolymers containing sulfonic acid groups which comprise (a) 30 to 95 mol % of at least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic ester or one water-soluble salt of a monoethylenically unsaturated carboxylic acid, (b) 3 to 35 mol % of at least one monomer containing sulfonic acid groups of the formula I in which the variables have the following meanings: R is hydrogen or methyl; X is a chemical bond or —COO—R1—; R1 is unbranched or branched C1-C4-alkylene; M is hydrogen, alkali metal or ammonium, and (c) 2 to 35 mol % of at least one nonionic monomer of the formula II in which the variables have the following meanings: R2 is hydrogen or methyl; R3 is a chemical bond or unbranched or branched C1-C6-alkylene; R4 are identical or different unbranched or branched C2-C4-alkylene radicals; R5 is unbranched or branched C1-C6-alkyl, C5-C8-cycloalkyl or aryl; n is 3 to 50, in random or block copolymerized form, as additive for detergentsType: GrantFiled: July 29, 2008Date of Patent: January 12, 2010Assignee: BASF AktiengesellschaftInventors: Pia Baum, Kathrin Michl, Franz Weingart, Stephan Nied, Gregor Brodt
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Publication number: 20090275492Abstract: A method of reducing rust in an automatic dishwasher comprises providing a rust-combating composition in the cleaning cycle of the dishwasher. The rust-combating composition be an organic acid. Preferred organic acids are oxalic acid and ascorbic acid. A passivating agent may be present, for example a phosphoric acid, a phosphate or a silicate.Type: ApplicationFiled: April 18, 2007Publication date: November 5, 2009Applicant: Reckitt Benckiser N.V.Inventors: Karlheinz Ulrich Hahn, Karl Ludwig Gibis, Karin Werner
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Patent number: 7530360Abstract: Use of copolymers comprising alkylene oxide units and comprising, in randomly or blockwise copolymerized form, (a) 50 to 93 mol % of acrylic acid and/or a water-soluble salt of acrylic acid, (b) 5 to 30 mol % of methacrylic acid and/or a water-soluble salt of methacrylic acid and (c) 2 to 20 mol % of at least one nonionic monomer of the formula I in which the variables have the following meanings: R1 is hydrogen or methyl; R2 is a chemical bond or unbranched or branched C1-C6-alkylene; R3 is identical or different unbranched or branched C2-C4-alkylene radicals; R4 is unbranched or branched C1-C6-alkyl; n is 3 to 50, as deposit-inhibiting additives in the rinsing cycle of a dishwasher.Type: GrantFiled: October 23, 2004Date of Patent: May 12, 2009Assignee: BASF AktiengesellschaftInventors: Marcus Guzmann, Heike Becker
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Patent number: 7468346Abstract: A low-foaming, liquid composition is disclosed. Methods of making and using the low-foaming, liquid composition are also disclosed.Type: GrantFiled: June 17, 2004Date of Patent: December 23, 2008Assignee: Ecolab Inc.Inventors: Joseph Thekkekandam, Anna Starobin, Frank Lama
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Patent number: 7332466Abstract: A low-foaming surfactant composition comprising: (a) a hydroxy mixed ether corresponding to formula I: R1O[CH2CH(CH3)O]x(CH2CHR2O)y[CH2CH(OH)R3]z??(I) wherein R1 is an alkyl and/or alkylene group containing from 4 to 18 carbon atoms, R2 is hydrogen, R3 is an alkyl group having from 2 to 22 carbon atoms, x is 0, y is a number from 1 to 30, and z is a number from 1 to 3; and (b) a low-foaming nonionic surfactant selected from the group consisting of an optionally end-capped fatty alcohol polyethylene glycol/polypropylene glycol ether corresponding to formula II: R4O(CH2CH2O)n[CH2(CH3)CHO]mR5 ??(II) wherein R4 is an alkyl and/or alkylene group containing from 8 to 22 carbon atoms, R5 is hydrogen or an alkyl group containing from 1 to 8 carbon atoms, n is a number from 1 to 15 and m is a number up to 10, an optionally end-capped fatty alcohol polypropylene glycol/polyethylene glycol ether corresponding to formula II: R6O[CH2(CH3)CHO]p(CH2CH2O)qR7 ??(III) wherein R6 is an alkyl and/or alkylene group having fType: GrantFiled: November 17, 2004Date of Patent: February 19, 2008Assignee: Cognis Deutschland GmbH & Co. KGInventors: Karl-Heinz Schmid, Rita Koester
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Household cleaning composition in self-sustaining body form and essentially free of zeolite and clay
Patent number: 7326674Abstract: New cleaning compositions and methods of forming and using those compositions are provided. In a preferred embodiment, the compositions are in tablet form, with the tablets being dissolvable in water at the point-of-use for ease of storing and shipping. The compositions comprise sodium bicarbonate, citric acid, an alkali metal alkylbenzene sulfonate, an ingredient selected from the group consisting of a trialkyl glycol monoalkyl ether, limonene, and mixtures thereof, and other ingredients depending upon the embodiment. The diluted cleaner has a very low impact on the environment due to the low levels of surfactants in the diluted solution. Furthermore, the cleaning solution performs well on protein stains due to the production of CO2 and the presence of sodium perborate. The inventive composition can be used on a wide range of substrates, from hard surfaces to fabrics.Type: GrantFiled: February 8, 2007Date of Patent: February 5, 2008Assignee: Kegel, LLCInventors: Dennis Sheirs, Brandy Padilla, Donald Wall -
Patent number: 7153816Abstract: A dishwasher detergent containing a builder and one or more magnesium and/or zinc salt(s) of at least one monomeric and/or polymeric organic acid, excluding zinc ricinoleate, zinc abietate, and zinc oxalate. A method of inhibiting glass corrosion by treatment with one or more salts of magnesium and/or zinc with organic acids, excluding formic acid, acetic acid, gluconic acid, and oxalic acid.Type: GrantFiled: February 17, 2004Date of Patent: December 26, 2006Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)Inventors: Arnd Kessler, Rainer Sorg, Melanie Baumann, Wolfgang Wick
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Patent number: 7132390Abstract: The invention provides an adsorbate which comprises a soluble zinc compound of a polycarboxylic acid adsorbed on crystalline alkali metal phyllosilicate, and the use thereof.Type: GrantFiled: July 21, 2004Date of Patent: November 7, 2006Assignee: Clariant GmbHInventors: Harald Bauer, Günther Schimmel
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Patent number: 7091166Abstract: An aqueous liquid composition comprising water; at least one acid selected from the group consisting of carboxylic acids, hydroxycarboxylic acids, and inorganic acids other than phosphoric acid wherein the at least one acid is present in an amount from about 1.0 to about 30 milliequivalents per kilogram of total composition (“mEq/kg”); and an amphoteric surfactant wherein the amphoteric surfactant is present in an amount from about 0.01 to about 20 grams per kilogram of total composition (“g/kg”), the aqueous liquid composition having a pH from about 2.0 to about 6.1 and having a reduced etch attack on metal as compared to an aqueous composition comprising from about 1.0 to about 30 milliequivalents per kilogram of total composition (“mEq/kg”) of acids selected from the group consisting of carboxylic, hydroxycarboxylic, and inorganic acids, and not containing the amphoteric surfactant.Type: GrantFiled: March 20, 2002Date of Patent: August 15, 2006Assignee: Henkel Kommanditgesellschaft auf AktienInventor: Theodore D. Held, III
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Patent number: 6962898Abstract: Detergents for dishwashing contain 1% up to 98.8% by weight of builders, 0.1% to 70% by weight of copolymers of unsaturated carboxylic acids and monomers containing sulfonic acid groups, and one or both of 5% to 30% by weight of nonionic surfactants and 0.1% to 30% by weight of homo- or copolymeric polycarboxylic acids or salts thereof.Type: GrantFiled: June 28, 2001Date of Patent: November 8, 2005Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Arnd Kessler, Rolf Bayersdoerfer, Rainer Sorg, Christian Nitsch, Melanie Baumann
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Patent number: 6956016Abstract: An automatic laundry or dishwashing product in unit dose form comprising at least three distinct zones for delivering into at least three different stages in the washing cycle. The product provides improved cleaning, care and finishing benefits.Type: GrantFiled: May 14, 2002Date of Patent: October 18, 2005Assignee: The Procter & Gamble CompanyInventors: Lynda Anne Speed, Glenn Steven Ward
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Patent number: 6903058Abstract: Machine dishwashing agents containing a) 1 to 99.9% by weight of builder(s), and b) 0.1 to 70% by weight of copolymers of i) unsaturated carboxylic acids ii) monomers containing sulfonic acid groups, and iii) optionally further ionic or nonionogenic monomers, wherein the copolymer containing sulfonic acid groups is in particulate form, as well as methods of preparing the dishwashing agents.Type: GrantFiled: August 29, 2003Date of Patent: June 7, 2005Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Christian Nitsch, Bernd Richter, Rolf Bayersdoerfer
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Patent number: 6887836Abstract: Disclosed are home care compositions comprising a dicarboxy functionalized polyorganosiloxane and methods for treating and modifying surfaces and for enhancing delivery of active agents to surfaces treated with the compositions. Said home care compositions can be used particularly for cleaning, rinsing, care or treatment of industrial, domestic or communal hard surfaces, as well as textile article surfaces; they are targeted at conferring on the surfaces treated therewith benefits such as water repellency, soil release, stain resistance, anti-fogging, surface repair, anti-wrinkling, shine, lubrication and/or at improving the residuality, impact and or efficacy of active materials comprised in said compositions. The dicarboxy functionalized polyorganosiloxane can be present in the home care compositions at a concentration of from about 0.005% to 10% by weight, preferably from about 0.05% to 5% by weight.Type: GrantFiled: May 6, 2003Date of Patent: May 3, 2005Assignee: The Procter & Gamble CompanyInventors: Satyanarayana Majeti, Elizabeth Ann Brown Reno, Stephen Andras Kovacs, Philippe Olier
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Patent number: 6867173Abstract: An automatic dishwashing composition is presented having 0.01 to 90 percent by weight of a detergency builder and 0.1 to 20 percent by weight of at least one polymer, wherein said polymer or polymers comprises carboxylate groups and sulfonate groups. The composition is useful in liquid, tablet and granular compositions. The composition reduces filming and spotting of glass and plastics.Type: GrantFiled: March 27, 2001Date of Patent: March 15, 2005Assignee: National Starch and Chemical Investment Holding CorporationInventor: Klein A. Rodrigues
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Patent number: 6864221Abstract: The present invention relates to particles for supporting a surfactant and a process for preparing the same. Further, the present invention relates to high-density detergent particles using the particles for supporting a surfactant, and a process for preparing the same.Type: GrantFiled: June 14, 2000Date of Patent: March 8, 2005Assignee: Kao CorporationInventors: Shuji Takana, Hitoshi Takaya, Hiroki Yamaboshi, Yoichi Sugiyama, Hiroshi Kitagaito, Shu Yamaguchi, Hiroyuki Yamashita
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Patent number: 6835703Abstract: The invention provides liquid automatic dishwashing detergents (LADDs) that contain a detergent enzyme and have a pH value less than 7.0. Such LADDs can lack phosphate builders, chlorine bleaches, and alkali, each of which is undesirable from the perspective of human and environmental safety. In addition, the invention provides methods for cleaning tableware.Type: GrantFiled: December 29, 2000Date of Patent: December 28, 2004Assignee: Melaleuca, Inc.Inventors: Suk H. Cho, Kathy Dillon, James L. Kurtz
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Patent number: 6835702Abstract: The present invention relates to compositions and methods for mitigating corrosion of applied color designs on a bottle, or on another glass or ceramic item. More specifically the composition or method of the present invention can mitigate corrosion even in the presence of a known corrosive agent. The composition and methods of the invention employ one or more phosphates and one or more phosphonates at a ratio that reduces or minimizes corrosion of an applied color design.Type: GrantFiled: November 7, 2001Date of Patent: December 28, 2004Assignee: Ecolab Inc.Inventors: Brandon Leon Herdt, Gerald Kurt Wichmann, David Arnold Halsrud, Michel Marie Lawrence, Richard Eugene Steindorf
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Patent number: 6812195Abstract: The present invention is directed to a grease-cutting detergent composition that exhibits a stable foaming profile when used with non-enclosed automatic dishwashers. The composition can be sold in a concentrated form or in ready-to-use (RTU) diluted form. The concentrated compositions are formulated to be diluted with water before use. The RTU formulas are intended for as-is usage. In one embodiment the concentrated compositions comprises a) from about 0.25% to about 10% of a surfactant, b) from about 4% to about 8% of an alkalinity source, c) from about 0.1% to about 4.0% of a hydrotrope, d) from about 0.001% to about 2.0% of a builder, and e) from about 0.01% to about 3.0% of a thickener. In another embodiment an RTU formulation comprises a) from about 50 ppm to about 80 ppm of a surfactant, b) from about 45 ppm to about 75 ppm of an alkalinity source, c) from about 20 ppm to about 45 ppm of a hydrotrope, d) from about 0.Type: GrantFiled: September 16, 2002Date of Patent: November 2, 2004Assignee: The Procter & Gamble Co.Inventors: Thomas James Wierenga, James August Weikel
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Patent number: 6780832Abstract: The present invention provides: a specific water-soluble polymer exhibiting a high calcium-ion-scavenging function and further exhibiting a high clay-dispersing function even in high-hardness water; a detergent composition comprising the water-soluble polymer; and uses, other than the detergent composition, by making the best use of the characteristics of the water-soluble polymer. The specific water-soluble polymer, according to the present invention, has a calcium ion scavengeability of not less than 0.40 and further has a clay dispersibility of not less than 0.50 in high-hardness water and, preferably, includes polymers A and B as essential components wherein the polymer A has a calcium ion scavengeability of not less than 0.45 and wherein the polymer B has a clay dispersibility of not less than 0.65 in high-hardness water. The detergent composition comprising this water-soluble polymer has a good detergency even in high-hardness water.Type: GrantFiled: November 1, 2000Date of Patent: August 24, 2004Assignee: Nippon Shokubai Co., Ltd.Inventors: Yoshihiro Maeda, Akiko Hemmi, Shigeru Yamaguchi
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Patent number: 6750186Abstract: A tablet or pellet for cleaning mineral deposits from the interior of a dishwasher machine is placed within the machine, and the machine is run through its normal dishwashing cycle. The pellet or tablet is formed of a mixture of a binder matrix and a chelating agent capable of carrying out chelation solubilization on the mineral deposits. The pellet or tablet withstands substantial dissolving during the initial rinse cycle or cycles, and then dissolves to provide a pH no greater than 6 during the wash cycle.Type: GrantFiled: January 31, 2003Date of Patent: June 15, 2004Inventor: Robert Black
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Patent number: 6734156Abstract: The present invention relates to particles for supporting a surfactant and a process for preparing the same. Further, the present invention relates to high-density detergent particles using the particles for supporting a surfactant, and a process for preparing the same.Type: GrantFiled: February 14, 2001Date of Patent: May 11, 2004Assignee: Kao CorporationInventors: Shuji Takana, Hitoshi Takaya, Hiroki Yamaboshi, Yoichi Sugiyama, Hiroshi Kitagaito, Shu Yamaguchi, Hiroyuki Yamashita
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Patent number: 6730645Abstract: A method for improving stability of a dye used in a colored aqueous acidic rinse aid composition to ambient and ultra-violet light radiation is disclosed. The method includes the step of adding a chelant to an acidic rinse aid composition. The chelant is present in an amount of at least 1 ppm by weight of the rinse aid composition.Type: GrantFiled: July 11, 2001Date of Patent: May 4, 2004Assignee: The Procter & Gamble CompanyInventors: Peter Robert Foley, Xiaoqing Song, Lucio Pieroni
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Patent number: 6727213Abstract: A composition for use in a dishwasher is characterized by a base composition in the form of a tablet which becomes active substantially during the main wash cycle of the dishwasher. At least one separate zone in or on the tablet is provided with a substance that becomes active substantially during the rinse cycle of the dishwasher and with at least one substance that prevents lime scale build-up in the dishwasher and/or on the washed articles. The composition further includes agents that guarantee that at least the substance that becomes active substantially during the rinse cycle of the dishwasher is at least mainly released at the beginning of the rinse cycle at the earliest.Type: GrantFiled: June 28, 2002Date of Patent: April 27, 2004Assignee: Reckitt Benckiser N.V.Inventors: Guido Wäschenbach, Harald Magg, Richard Neergaard, Enric Carbonell, Ralf Wiedemann
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Patent number: 6703358Abstract: This invention relates to a cleaning composition for hard surfaces, comprising at least one surfactant and a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units: (a) at least one monomeric compound of general formula I; (b) at least one hydrophilic monomer chosen from C3-C8 carboxylic acids containing monoethylenic unsaturation, anhydrides thereof and water-soluble salts thereof; (c) optionally, at least one hydrophilic monomeric compound containing ethylenic unsaturation, of neutral charge, bearing one or more hydrophilic groups, which is copolymerizable with (a) and (b).Type: GrantFiled: July 13, 2000Date of Patent: March 9, 2004Assignee: Rhodia ChimieInventors: Eric Aubay, Gladys Saliba Gabriel, Dominic Yeung