Liquid Composition (e.g., Slurry, Etc.) Patents (Class 510/321)
  • Patent number: 6046149
    Abstract: There is provided a detergent composition containing an amylase enzyme and a builder system comprising an aluminosilicate zeolite, a crystalline layered silicate and most preferably an organic polymeric compound wherein the weight ratio of said crytalline layered silicate to said amylase enzyme (120 KNU/gram activity basis) is from 7:1 to 20:1. In one preferred aspect the detergent composition contains a bleaching system capable of providing delayed release of an organic peroxyacid to a wash solution.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: April 4, 2000
    Assignee: Procter & Gamble Company
    Inventors: Graham Alexander Sorrie, Alison Lesley Main
  • Patent number: 6034045
    Abstract: A liquid aqueous, laundry detergent composition which has a pH in the range of about 7.0 to about 12.2 and comprises at least one active surfactant; an at least partially neutralized polymer of an .alpha.,.beta.-monoethylenically unsaturated carboxylic acid containing no more than nine carbon atoms which is either (1) a homopolymer of such an unsaturated carboxylic acid, (2) a copolymer of monomers consisting of at least two of such unsaturated carboxylic acids, or (3) a copolymer of monomers consisting of at least 50 mol % of at least one of such unsaturated carboxylic acids with at least one non-carboxylic acid .alpha.,.beta.-monoethylenically unsaturated comonomer containing no more than nine carbon atoms, said polymer having a number average molecular weight of up to about 10,000 and being present in an amount equivalent to at least about 0.025 wt. % of the corresponding unneutralized polymer; and about 30 to about 95 wt. % of water, based on the total weight of the composition.
    Type: Grant
    Filed: February 25, 1997
    Date of Patent: March 7, 2000
    Assignee: Church & Dwight Co., Inc.
    Inventors: Charles D. Carr, John Ip, Anthony J. Falotico
  • Patent number: 6030933
    Abstract: The present invention relates to detergent compositions comprising one or more enzymes which are immobilized by a covalent binding on an activated polymer. Such enzymes are preferably bound to the activated polymer via a spacer molecule. The enzymes are selected from a variety of enzymes including, for example, cellulases, hemicellulases, peroxidases, proteases, glucoamylases, amylases, lipases, cutinases, pectinases, reductases, oxidases, phenoloxidases, lipoxygenases, laccases, ligninases, pullulanases, xylanases, tannases, pentosanases, manlanases, .beta.-glucanases, arabinosidases, and mixtures thereof. The polymer is selected from a variety of polymers. A preferred polymer for use in the present invention is polyethylene glycol.
    Type: Grant
    Filed: June 29, 1998
    Date of Patent: February 29, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Ivan Maurice Alfons Jan Herbots, Madeleine Petronella Jansen, Andre Cesar Baeck, Jean Wevers
  • Patent number: 6025316
    Abstract: Detergent composition are disclosed which are formulated for use in wash water over a wide range of pH in the washing bath. The compositions contain an anionic surfactant, optionally in combination with a nonionic surfactant with optimal builders and enzymes, and also contain at least one water soluble organic polymer, such as polyethylene glycol, which is miscible with or soluble in the surfactant. The presence of the water soluble polymer leads to enhanced fabric cleaning performance.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: February 15, 2000
    Assignee: Colgate-Palmolive Co.
    Inventors: Hoai-Chau Cao, Marie-Christine Houben, Patricia Pagnoul, Patrick Durbut, Guy Broze, Anne-Marie Misselyn
  • Patent number: 6008178
    Abstract: There is provided a detergent composition comprising: a) from 1% to 95% by weight of a surfactant system comprising an anionic surfactant and a cationic ester surfactant, other than N,N-di(2-stearoyloxyethyl)-N-(2-hydroxyethyl)-N-methyl ammonium chloride, present in a weight ratio of said anionic surfactant to said cationic ester surfactant of 2.5:1 to 25:1; and b) from 0.0001% to 5% by weight of a proteolytic enzyme, wherein the % weight of proteolytic enzyme in the formulation is based on an enzyme activity of 4 Knpu/g of the enzyme particle, and wherein the weight ratio of said anionic surfactant to said proteolytic enzyme is at least 1.5:1.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: December 28, 1999
    Assignee: Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Robin Gibson Hall, Christian Leo Marie Vermote
  • Patent number: 6008182
    Abstract: A process for preventing dye redeposition during the washing of a dyed fabric or garment made from natural fibers, which process incorporates as a dye redeposition inhibiting agent, a water-soluble or water-dispersible polyester resin composition comprising a reaction product of 20%-50% by weight of terephthalate polymer or waste terephthalate polymer, 10-40% by weight of at least one glycol and 5-25% by weight of at least one oxyalkylated polyol.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: December 28, 1999
    Assignee: Seydel Research, Inc.
    Inventors: Robert Keith Salsman, Brian J. Clark
  • Patent number: 6001639
    Abstract: The present invention relates to enzyme preparations consisting essentially of an enzyme which has cellulytic activity and comprises a first amino acid sequence consisting of 14 amino acid residues having the following sequenceThr Arg Xaa Xaa Asp Cys Cys Xaa Xaa (SEQ ID NO:79) 1 2 3 4 5 6 7 8 9 - Xaa Cys Xaa Trp Xaa 10 11 12 13 14and a second amino acid sequence consisting of 5 amino acid residues having the following sequenceTrp Cys Cys Xaa Cys (SEQ ID NO:80) 1 2 3 4 5wherein, in position 3 of the first sequence, the amino acid is Trp, Tyr or Phe; in position 4 of the first sequence, the amino acid is Trp, Tyr or Phe; in position 8 of the first sequence, the amino acid is Arg, Lys or His; in position 9, 10, 12 and 14, respectively, of the first sequence, and in position 4 of the second sequence, the amino acid is any of the 20 naturally occurring amino acid residues with the provisos that, in the first amino acid sequence, (i) when the amino residue in position 12 is Ser, then the amino acid residue in posit
    Type: Grant
    Filed: May 21, 1996
    Date of Patent: December 14, 1999
    Assignee: Novo Nordisk A/S
    Inventors: Martin Schulein, Lene Nonboe Andersen, S.o slashed.ren Flensted Lassen, Markus Sakari Kauppinen, Lene Lange, Ruby Iium Nielsen, Michiko Ihara, Shinobu Takagi
  • Patent number: 5998350
    Abstract: The present invention relates to bleaching and detergent compositions comprising conventional detergent ingredients, bleaching systems with one or more bleach activators. Preferred bleaching activators are amido-derived bleach activators and/or N-acyl caprolactam bleach activators. The invention also relates to methods of using the detergent compositions.
    Type: Grant
    Filed: September 6, 1996
    Date of Patent: December 7, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Michael Eugene Burns, Alan David Willey, Jerome Howard Collins, Richard Timothy Hartshorn, Chanchal Kumar Ghosh
  • Patent number: 5998344
    Abstract: Disclosed for cleaning hard surfaces is a detergent gel containing:(a) a detergent composition without thickeners having(i) a first surfactant, wherein the first surfactant is a non-ionic glycolipid, and(ii) a second surfactant, wherein the second surfactant is a charged surfactant, wherein the ratio of the first surfactant and the second surfactant is 1:10-10:1;(b) water, wherein the detergent composition is mixed with a sufficient amount of water to induce a phase change from a liquid phase to a gel phase; and(c) one or more enzymes.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: December 7, 1999
    Assignee: Novo Nordisk A/S
    Inventors: Poul N.o slashed.rgaard Christensen, Bo Kalum, Otto Andresen
  • Patent number: 5994286
    Abstract: An aqueous antimicrobial cleaning composition comprising: (a) a surfactant; (b) triclosan; and (c) a tocopherol and a process for inhibiting the color degradation of an aqueous antimicrobial cleaning composition involving the addition of an effective amount of a tocopherol thereto.
    Type: Grant
    Filed: July 22, 1997
    Date of Patent: November 30, 1999
    Assignee: Henkel Corporation
    Inventors: Sureshchandra G. Desai, deceased, Arturo Valdes
  • Patent number: 5990069
    Abstract: The present invention concerns lipolytic enzymes naturally produced by a fungus of the species Fusarium solanii. The lipolytic enzymes include two lipases and a cutinase. The present invention concerns a biologically pure culture of Fusarium solanii producing these lipolytic enzymes and in particular a biologically pure culture of Fusarium solanii var. minus T.92.637/1. The present invention concerns also a detergent composition containing these lipolytic enzymes.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: November 23, 1999
    Assignee: Genencor International, Inc.
    Inventors: Christophe Andre, Lucien Charmoille
  • Patent number: 5981466
    Abstract: The present invention relates to detergent compositions containing amine surfactants. More particularly, the invention is directed to detergent compositions containing anionic surfactants selected from the group consisting of alkyl alkoxylated sulfates and alkyl sulfates, said composition further containing specific primary and/or tertiary amines.
    Type: Grant
    Filed: August 21, 1997
    Date of Patent: November 9, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Joseph Paul Morelli, Dimitris Lappas, Sherri Lynn Randall, Rajan Keshav Panandiker, Jean-Pol Boutique, Chris Efstathios Housmekerides
  • Patent number: 5972873
    Abstract: The present invention relates to a liquid composition comprising an enzyme and a phenyl boronic acid derivative enzyme stabilizer of the following formula: ##STR1## wherein R is selected from the group consisting of hydrogen, hydroxy, C.sub.1 -C.sub.6 alkyl, substituted C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkenyl and substituted C.sub.1 -C.sub.6 alkenyl.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: October 26, 1999
    Assignee: Novo Nordisk A/S
    Inventors: Lone Kierstein Nielsen, Allison Deane-Wray
  • Patent number: 5972872
    Abstract: The present invention relates to detergent compositions comprising an enzyme preparation with substantial cellulytic activity, especially endoglucanase activity, at alkaline conditions which is enzyme composition is derived from or producible by a fungus selected from the Basidiomycetous families Coprinaceae and Bolbitiaceae, preferably from the group of strains belonging to the genera Psathyrella, Podaxis, Panaeolus, Coprinus and Bolbitius, more preferably from the group of strains belonging to the species Coprinus micaceus, Coprinus domesticus, Coprinus ephemerus, Coprinus disseminatus, Coprinus radians, Coprinus picaceus, Coprinus frisei, Coprinus subimpatiens, Psathyrella candolleana, Psathyrella prona, Panaeolus semiovatus, Podaxis pistillaris and Bolbitius aleuriatus; and a method for providing a stone-washed look to textiles, especially to cellulosic fabric such as denim, using the mentioned enzyme preparation; and a method for improving the drainage of paper pulp or the de-inking of recycled paper usi
    Type: Grant
    Filed: June 6, 1997
    Date of Patent: October 26, 1999
    Assignee: Novo Nordisk A/S
    Inventors: Lene Lange, Jack Bech Nielsen, Martin Schulein
  • Patent number: 5968887
    Abstract: The invention relates to a liquid composition which comprises an enzyme and a enzyme stabilizing component. The enzyme stabilizing component is a boronic acid derivative.
    Type: Grant
    Filed: July 9, 1998
    Date of Patent: October 19, 1999
    Assignee: Novo Nordisk A/S
    Inventors: Lone Kierstein Nielsen, Allison Deane-Wray
  • Patent number: 5965507
    Abstract: This invention concerns cleaning compositions like laundry compositions containing a chondroitinase enzyme. More in particular, the invention relates to compact detergent compositions, granular and liquids as well containing said chondroitinase enzyme.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: October 12, 1999
    Assignee: Procter & Gamble Company
    Inventors: Christiaan Arthur Jacques Thoen, Anju Deepali Massey Brooker, Youssef Oubrahim, Ian Martin Dodd
  • Patent number: 5955416
    Abstract: The present invention relates to detergent compositions comprising lipases, a lipase compatible anionic surfactant system, and a gemini polyhydroxy fatty acid amide. The anionic surfactant system comprises alkyl alkoxylated sulphates having specific ratios of mono-, di- and tri-alkoxylated sulphates. The detergent compositions provide improved greasy soil removal over a wide range of temperatures.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: September 21, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Barry Thomas Ingram, Christian Leo Marie Vermote
  • Patent number: 5955415
    Abstract: Detergent compositions, essentially free of chlorine bleach compounds, containing a surfactant, builder, enzyme, peroxygen bleach and from about 0.001% to about 5% by weight polyethyleneimine (PEI) or salts thereof are disclosed. These compositions exhibit controlled and improved bleaching action on stains as well as improved storage stability, fabric safety and whitening/brightening characteristics.
    Type: Grant
    Filed: August 4, 1997
    Date of Patent: September 21, 1999
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Eddie Gutierrez, Shang-Ren Wu, Uday Racherla, Robert Vermeer
  • Patent number: 5948745
    Abstract: Detergent compositions are disclosed which are formulated for use in wash water over a wide range of pH in the washing bath. The compositions contain a surfactant mixture comprised of an anionic surfactant and an amphoteric surfactant optionally further including a nonionic surfactant with optional builders and enzymes, and also contain at least one water soluble organic polymer, such as polyethylene glycol, which is miscible with or soluble in the surfactant mixture. The presence of the water soluble polymer leads to enhanced fabric cleaning performance.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: September 7, 1999
    Assignee: Colgate-Palmolive Co.
    Inventors: Hoai-Chau Cao, Marie-Christine Houben, Patricia Pagnoul, Patrick Durbut, Guy Broze, Anne-Marie Misselyn
  • Patent number: 5935271
    Abstract: The present invention relates to laundry detergent compositions containing a lipolytic enzyme (lipase) and specially selected primary and/or tertiary amines. The compositions provide enhanced cleaning of grease/oil soils and stains, particularly when used in a pre-treat laundering process for cleaning fabrics stained with grease/oil soils.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: August 10, 1999
    Assignee: Procter & Gamble Company
    Inventors: Dimitris Lappas, Rajan Keshav Panandiker, Thomas Wilhelm Horner, Robert Walter Boswell
  • Patent number: 5932532
    Abstract: Bleaching and cleaning compositions comprising a bleaching compound, one or more bleach activators, and protease enzymes are provided. Thus, laundry detergent compositions which comprise protease, perborate or percarbonate and activators such as benzoyl caprolactain exhibit improved dingy clean-up performance.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: August 3, 1999
    Assignee: Procter & Gamble Company
    Inventors: Chanchal Kumar Ghosh, Gayle Marie Frankenbach, Catherine Michelle Quinn
  • Patent number: 5925609
    Abstract: A non-phosphate builder-containing detergent composition comprising a surfactant, and a) at least 0.5% by weight of a source of hydrogen peroxide; b) from 0.01% to 10% by weight of an organic peroxyacid bleach precursor; c) from 0.001% to 5% by weight of a proteolytic enzyme; d) an alkalinity source having the capacity to deliver alkalinity to a wash solution as measured by the alkalinity release test described herein, such that the % weight of NaOH equivalent of the composition is greater than 10.6% by weight of the composition, and wherein the detergent composition has a Hydrogen peroxide Precursor Proteolytic enzyme (HPP) Index of at least 0.35 as defined by the formula: ##EQU1## wherein the % weight of proteolytic enzyme in the formulation is based on an enzyme activity of 13 knpu/g of the enzyme particle, and wherein the % AvO.sub.2 is the total amount of available oxygen present in the composition is provided.
    Type: Grant
    Filed: September 10, 1997
    Date of Patent: July 20, 1999
    Assignee: Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Richard Timothy Hartshorn, Christian Leo Marie Vermote
  • Patent number: 5919271
    Abstract: The invention relates to a detergent composition which comprises a nonionic polysaccharide ether, a surfactant, a dye transfer inhibition agent, a cellulase enzyme and a chelating agents. In addition the invention further relates to a method of treating fabrics with the detergent composition.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: July 6, 1999
    Assignee: Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Robin Gibson Hall, Nour-Eddine Guedira
  • Patent number: 5919746
    Abstract: The present invention relates to an alkaline lipolytic enzyme derivable from a strain of Botryosphaeria or Guignardia, to a lipolytic enzyme-producing microbial strain, to methods for the production of lipolytic enzyme and to a detergent composition comprising the lipolytic enzyme.
    Type: Grant
    Filed: August 28, 1997
    Date of Patent: July 6, 1999
    Assignee: Novo Nordisk A/S
    Inventors: Satoshi Hirayama, Torben Halkier
  • Patent number: 5916862
    Abstract: A liquid detergent composition comprising anionic surfactants selected from the group of alkyl alkoxy sulfates and alkyl sulfates, characterized in that said detergent composition further comprises a tertiary amine having formula (1), wherein R.sub.1 is C.sub.4 -C.sub.10, preferably C.sub.8 -C.sub.10 alkyl; n is 2-4, preferably n is 3; R.sub.2 is C.sub.1 -C.sub.4 or formula (2), whereby x is 1-5, R.sub.3 is H or C.sub.1 -C.sub.2 alkyl.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: June 29, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Joseph Paul Morelli, Dimitris Lappas, Sherri Lynn Randall, Rajan Keshev Panandiker, Jean-Pol Boutique, Chris Efstathios Housmekerides
  • Patent number: 5904736
    Abstract: In washing agents containing tensides and cellulase, the properties of the cellulase which are relevant to the application were to be improved. This was essentially achieved in that use was made of a cellulase mixture in which the first component, with a CMCase activity of 1 U per liter and a protein concentration of a most 3 mg per liter, gives an increase in remission of at least 5 units in the secondary washing test and the second component, with a CMCase activity of 20 U per liter gives an increase in absorption in the cellulose decomposition test of at least 0.075.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: May 18, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl-Heinz Maurer, Albrecht Weiss
  • Patent number: 5904735
    Abstract: Detergent compositions, essentially free of peroxygen or chlorine bleach compounds, containing a surfactant, builder, enzyme and from about 0.001% to about 5% by weight polyethyleneimine (PEI) or salts thereof are disclosed. These compositions provide enhanced removal of organic stains, particularly on polyphenolic stains such as morello juice (cherry juice), blueberry juice, red wine, tea and coffee. Improvement was also demonstrated on certain non-polyphenolic stains such as grass.
    Type: Grant
    Filed: August 4, 1997
    Date of Patent: May 18, 1999
    Assignee: Lever Brothers Company
    Inventors: Eddie Gutierrez, Shang-Ren Wu, Uday Racherla, Robert Vermeer
  • Patent number: 5883065
    Abstract: An emulsified detergent composition is provided. The detergent composition comprises from about 0.1% to about 70%, by weight of the detergent composition, of a detersive surfactant wherein at least from about 70% to about 90%, by weight of the detersive surfactant, is a nonionic surfactant. The detergent composition also includes an electrolyte, in an amount sufficient to render the cloud point of the detergent composition to be less than about 20.degree. C., and water. The detersive surfactant and the water are in two phases in a weight ratio of about 1:10 to about 10:1 in the detergent composition. Superior cleaning and stain removal results because the emulsified detergent composition provides separation of the water and surfactant phases in a low water wash system over a broad temperature range and allows for cleaning below the cloud point of the surfactant system.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: March 16, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Ronald A. Swift, II, Stephen W. Morrall
  • Patent number: 5880080
    Abstract: The use of alkaline bacillus proteases in commercial laundry methods and compositions containing these proteases for commercial laundering are described.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: March 9, 1999
    Assignee: Solvay Enzymes GmbH & Co. KG
    Inventors: Antoine Amory, Andre Clippe, Gerhard Konieczny-Janda
  • Patent number: 5877139
    Abstract: There is provided an enzymatic detergent composition comprising one or more surfactants and an endoglucanase which is not a Family 7 cellulase, which contains no cellulose binding domain and wherein the catalytic domain contains at least two disulphide bridges. Preferably, the endoglucanase is producible from Thermomonospora fusca, or mutants or variants thereof.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: March 2, 1999
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Eric Casteleijn, Willem R. van Dijk, Jan Klugkist, Pieter Dirk van Wassenaar
  • Patent number: 5877141
    Abstract: Glycolic acid or its salts is effective in stabilizing enzymes in liquid laundry detergent compositions.
    Type: Grant
    Filed: February 3, 1997
    Date of Patent: March 2, 1999
    Assignee: Rhodia Inc.
    Inventors: Gladys Saliba Gabriel, Ronald B. Bell
  • Patent number: 5872091
    Abstract: This invention relates to a laundry detergent composition as well as a method of laundrying fabric or soiled garments in which the composition requires a surfactant, a pectinase enzyme, a specific hemicellulase enzyme or enzymes, a cellulase enzyme, and additional component which includes bleaching agents, builders, an amylase enzyme and/or a protease enzyme.
    Type: Grant
    Filed: January 30, 1997
    Date of Patent: February 16, 1999
    Assignee: Genencor International Inc.
    Inventors: Roelck A. Cuperus, Margareta A. Herweijer, Albert J.J. Van Ooijen, Dick J. Van Schouwen
  • Patent number: 5858948
    Abstract: Liquid laundry detergent compositions comprising water soluble and/or dispersible, modified polyamines having functionalized backbone moieties which provide cotton soil release benefits (optionally in combination with non-cotton soil release agents) and protease enzymes.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: January 12, 1999
    Assignee: Procter & Gamble Company
    Inventors: Chanchal Kumar Ghosh, Sanjeev Krishnadas Manohar, Eugene Paul Gosselink, Randall Alan Watson
  • Patent number: 5858946
    Abstract: There is provided a detergent composition comprising conventional detergent components characterized in that it contains a lactase enzyme. The lactase enzyme is preferably incorporated into the compositions at a level of from 0,0001% to 2% active enzyme by weight of the composition.
    Type: Grant
    Filed: February 4, 1997
    Date of Patent: January 12, 1999
    Assignee: Procter & Gamble Company
    Inventors: Peter Robert Foley, Lynda Anne Jones
  • Patent number: 5855621
    Abstract: The transfer of a textile dye from a dyed fabric to another fabric during washing or rinsing is inhibited by adding an enzyme exhibiting peroxidase activity or an enzyme exhibiting a suitable oxidase activity to the wash liquor in which said fabrics are washed and/or rinsed. Peroxidase is produced extracellularly by some strains of Bacillus pumilus. The novel peroxidase preparation from B. pumilus is a microperoxidase, i.e. it contains hemopeptide as an active component. The preparation has improved stability at high temperature, at high pH and at high concentrations of hydrogen peroxide. It can be produced without undesired catalase activity.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: January 5, 1999
    Assignee: Novo Nordisk A/S
    Inventors: Ture Damhus, Ole Kirk, Gitte Pedersen, Manuel Garcia Venegas
  • Patent number: 5851973
    Abstract: This invention is a manual dishwashing composition which comprises surfactant, calcium or magnesium ions, amylase enzymes, lipase enzymes, and polycarboyxlic polymer thickeners. An additional agent includes a calcium stabilizing agent such as malic acid or malic acid salt, maleic acid or maleic acid salt.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: December 22, 1998
    Assignee: The Procter & Gamble Company
    Inventor: Peter Robert Foley
  • Patent number: 5840678
    Abstract: Aqueous liquid detergent compositions are described which comprise a proteolytic enzyme wherein the proteolytic activity is reversibly inhibited by a peptide trifluoromethyl ketone.
    Type: Grant
    Filed: September 25, 1996
    Date of Patent: November 24, 1998
    Assignee: Procter & Gamble Company
    Inventors: Regine Labeque, John McMillan McIver, Christiaan Arthur J.K. Thoen
  • Patent number: 5837010
    Abstract: The invention concerns detergent compositions comprising lipase variant D96L of the native lipase derived from Humicola lanuginosa present at a level of from 50 LU to 8500 LU per liter wash solution.Using these levels of lipase delivers an improved whiteness maintenance on fabrics.
    Type: Grant
    Filed: October 11, 1996
    Date of Patent: November 17, 1998
    Assignee: Procter & Gamble Company
    Inventors: Andre Baeck, Chandrika Kasturi
  • Patent number: 5834415
    Abstract: A liquid detergent composition comprising a surfactant, an enzyme and a naphthalene boronic acid derivative enzyme stabilizer.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: November 10, 1998
    Assignee: Novo Nordisk A/S
    Inventors: Lone Kierstein Nielsen, Allison Deane-Wray
  • Patent number: 5804543
    Abstract: Disclosed are detergent compositions and methods which are suitable for washing colored fabrics in aqueous washing solution with little or no transfer of dye between fabrics. The compositions utilized comprise certain nil-LAS detersive surfactants, detergent builder and certain selected polymeric dye transfer inhibiting agents. The detersive surfactants used must comprise alkyl ether sulfates and certain types of nonionic surfactants (polyhydroxy fatty acid amides and/or alcohol ethoxylates). The polymeric dye transfer inhibiting agents are polyamine N-oxides such as poly(4-vinylpyridine-N-oxide), i.e., PVNO and/or copolymers of N-vinylpyrrolidone and N-vinylimidazole, i.e., PVPVI.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: September 8, 1998
    Assignee: The Procter & Gamble Company
    Inventors: William C. Wertz, Rajan K. Panandiker
  • Patent number: 5801039
    Abstract: This invention relates to proteases with improved application properties in cleaners and detergents. The improvement's achieved by substituting positively charged or uncharged amino acids in the substrate binding region of the wild type subtilisin protease.
    Type: Grant
    Filed: December 1, 1995
    Date of Patent: September 1, 1998
    Assignee: Cognis Gesellschaft fuer Bio und Umwelttechnologie mbH
    Inventors: Karl-Heinz Maurer, Albrecht Weiss, Christian G. Paech, Dean W. Goddette, Teresa M. Christianson, Maria R. Tang, Charles Ronald Wilson
  • Patent number: 5798327
    Abstract: There is provided an enzymatic detergent composition comprising a surfactant and an endoglucanase producible from Thermomonospora fusca, preferably E5, or mutants or variants thereof.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: August 25, 1998
    Assignee: Lever Brothers Company
    Inventors: Eric Casteleijn, Willem R. van Dijk, Jan Klugkist, Pieter Dirk van Wassenaar
  • Patent number: 5786316
    Abstract: The invention concerns compositions comprising xylanolytic activity. Specfically, the invention relates to detergent compositions havin xylanase activity. Specific compositions show an excellent boost on cleaning performanc on fruit, vegetables and/or mud and clay compounds containing said soil.
    Type: Grant
    Filed: April 16, 1997
    Date of Patent: July 28, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Andre Cesar Baeck, Alfred Busch, Ann Katrien Marie Agnes Verschuere
  • Patent number: 5783542
    Abstract: A two-part enzyme-based cleaning system useful in clean-in-place operations to remove proteinaceous soils from dairy equipment is described. The system comprises two liquid concentrates stored in separate containers, the concentrates being diluted and mixed for use.A. The first concentrate consists of:i) 1.5 to 7.5 percent by weight of a source of alkalinity selected from the sources of hydroxide based alkaline compositions;ii) 1 to 16 percent by weight of a water conditioner selected from the group consisting of polyacrylic acids and polyphosphates; andiii) balance water.B. The second concentrate consists of:i) 5 to 45 percent by weight of an enzyme stabilizing blend of an alkali salt of a (C.sub.6 to C.sub.12) fatty acid and a linear (C.sub.8 -C.sub.
    Type: Grant
    Filed: June 7, 1996
    Date of Patent: July 21, 1998
    Assignee: Diversey Lever, Inc.
    Inventor: Carol A. Rouillard
  • Patent number: 5783547
    Abstract: The present invention is concerned with granular components comprising an enzyme, specified polymeric binding material, and a mixture of coating components. The granular components are particularly suitable for use in detergent compositions.
    Type: Grant
    Filed: September 24, 1996
    Date of Patent: July 21, 1998
    Assignee: The Procter & Gamble Company
    Inventor: Carole Patricia Denise Wilkinson
  • Patent number: 5780283
    Abstract: A method for stabilizing an enzyme against decomposition at elevated temperatures or by water is described which comprises combining the enzyme with stabilizing amounts of a non-ionic polyether-polyol block-copolymer surfactant. Stabilized compositions based on the enzyme and surfactant are also described.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: July 14, 1998
    Assignee: Buckman Laboratories International, Inc.
    Inventor: James C. Lee
  • Patent number: 5759984
    Abstract: Methods for stabilizing enzymes in liquid compositions, including those liquid compositions having a high water content and those stabilized enzyme liquid compositions formed thereby. The method involves forming the enzyme, so that it is in an insoluble form thereof and then adding thereto an agent for maintaining the enzyme in the insoluble form thereof. Examples of such insoluble forms are crystal forms of the enzyme. Enzymes which are stabilized in this manner are useful for combining with liquid compositions, including liquid compositions having a high water content. The method is particularly useful for the preparation of stable enzyme-containing liquid detergent compositions.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: June 2, 1998
    Inventors: Jayarama K. Shetty, Chimanbhai P. Patel
  • Patent number: 5731278
    Abstract: Low cost, highly aqueous, thickened heavy duty liquid laundry detergent compositions are provided. Such compositions contain relatively low levels of surfactant materials, a formate-based viscosity-enhancing agent, a selected type of thickening perfume and relatively large amounts of water. Only minimal amounts of other detergent composition adjuvants are permitted in such compositions.
    Type: Grant
    Filed: October 29, 1996
    Date of Patent: March 24, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Hari A. Nair, Gary G. Staud, Jose M. Velazquez
  • Patent number: 5728670
    Abstract: Mixed chain alkyl (alkyl glycosid) uronates as nonionic surfactants are disclosed.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: March 17, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Bijan Harichian, Robert Vermeer, Robert William Riley Humphreys
  • Patent number: 5723655
    Abstract: The present invention relates to an amine compound represented by the following general formula (1): ##STR1## wherein R.sup.1 and R.sup.2 represent individually a linear or branched C.sub.1 -C.sub.24 alkyl or alkenyl group which may be substituted by a hydroxyl group, X.sup.1 represents a C.sub.1 -C.sub.6 alkylene or alkenylene group which may be substituted by a hydroxyl, sulfonic or carboxyl group, Y.sup.1 represents a carboxyl or sulfonic group, or a sulfuric acid residue, Y.sup.2 represents a hydroxyl group, a sulfuric acid residue or a group --OCO--X.sup.1 --COOH, Z represents a sulfoalkyl group or a group obtained by removing an amino group from an amino acid or a salt thereof, and n represents a number of 0 or 1, or a salt or quaternized product thereof, an intermediate useful for the preparation thereof, and detergent compositions containing such an amine compound.
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: March 3, 1998
    Assignee: Kao Corporation
    Inventors: Mitsuru Uno, Tomohito Kitsuki, Katsumi Kita