Nitrogen Containing Surfactant Devoid Of Covalently Bonded Anionic Substituents Which Is Admixed With A Diverse Non-soap Surfactant Patents (Class 510/350)
  • Patent number: 11390713
    Abstract: Described herein is a process for manufacturing an alkoxylated polyalkylenimine, the process including the following steps: (a) providing a polyalkylenimine (A), (b) reacting the polyalkylenimine (A) with 0.5 to 1.3 moles of propylene oxide or butylene oxide per N—H function at a temperature in the range of 100 to 150° C., (c) reacting the product from step (b) with C2-C4-alkylene oxide wherein the C2-C4-alkylene oxide is different from the alkylene oxide used in step (b).
    Type: Grant
    Filed: February 2, 2018
    Date of Patent: July 19, 2022
    Assignee: BASF SE
    Inventors: Stephan Hueffer, Thomas Wesley Holcombe, Sebastian Mirtschin, Frank Dietsche, Jan Uwe Mueller, Alejandra Garcia Marcos
  • Patent number: 9321985
    Abstract: Laundry detergents useful for cold-water cleaning and boosted bargain detergents are disclosed. The detergents include a surfactant composition derived from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. For fatty alkyl ester sulfonate-containing detergents, the composition is selected from C10 betaines, C12 or C16 amidoamines, C12 ethanolamine amides, C16 amidoamine sulfonates, C18 diamidoamine dioxides, quaternized C18 diamidoamine betaines, sulfonated C18 low-EO fatty ester alkoxylates, C18 amidoamine carboxylates, and amidoamine oxides and sulfobetaines derived from cross-metathesis of palm or soybean oil. The bargain detergents include a performance booster selected from C12 low-EO fatty ester alkoxylate sulfonates, C18 amidoamine oxide esters, C18 amidoamine oxide carboxylates, and amidoamine sulfobetaines made from self metathesized palm or soybean oil.
    Type: Grant
    Filed: December 18, 2015
    Date of Patent: April 26, 2016
    Assignee: Stepan Company
    Inventors: Dave R Allen, Marcos Alonso, Randal J Bernhardt, Dennis S Murphy, Patrick Shane Wolfe, Aaron Brown
  • Patent number: 8940681
    Abstract: The present invention improves dye transfer inhibition in the washing of textiles by the use of SO3M substituted urea derivatives of aromatic amines.
    Type: Grant
    Filed: August 21, 2014
    Date of Patent: January 27, 2015
    Assignee: Henkel AG & Co. KGaA
    Inventors: Mareile Job, Birgit Gluesen, John Taylor, Anthony Lawrence
  • Patent number: 8703689
    Abstract: The present invention provides an aqueous bleaching composition comprising from about 1.0% to 10.0% by weight of alkali metal hypochlorite, from about 0.05% to 5.0% by weight of alkali metal hydroxide to provide the composition with a pH in the range of from about 9 to 14; from about 0.02% to 5.0% by weight of a metal silicate or mixtures of metal silicates; from about 0.0001% to 0.2% by weight of a metal periodate; and water. The compositions reliably protect the fabric against yellowing and weakening while providing protection to stainless steel metal parts of the washing machine and metal garment decors such as buckles, buttons, etc.
    Type: Grant
    Filed: December 29, 2010
    Date of Patent: April 22, 2014
    Assignee: KIK Custom Products Inc.
    Inventor: Hedeliza Malonzo Mercado
  • Publication number: 20130345105
    Abstract: A cleaning system can include a noble gas, and one or more vessels configured to convert the noble gas into a supercritical fluid, and/or receive and clean an article of manufacture with the noble gas in the supercritical fluid state. A cleaning process can include converting a noble gas into a supercritical fluid state; and cleaning an article of manufacture with the noble gas in the supercritical fluid state so as to remove one or more contaminants from the article of manufacture. A cleaning composition can include a noble gas in a supercritical fluid state, and a textile article of manufacture having one or more contaminants located in the supercritical noble gas.
    Type: Application
    Filed: August 23, 2013
    Publication date: December 26, 2013
    Applicant: EMPIRE TECHNOLOGY DEVELOPMENT LLC
    Inventors: William B. CARLSON, Gregory D. PHELAN, Philip A. SULLIVAN
  • Publication number: 20130217608
    Abstract: Laundry detergents useful for cold-water cleaning and boosted bargain detergents are disclosed. The detergents include a surfactant composition derived from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. For fatty alkyl ester sulfonate-containing detergents, the composition is selected from C10 betaines, C12 or C16 amidoamines, C12 ethanolamine amides, C16 amidoamine sulfonates, C18 diamidoamine dioxides, quaternized C18 diamidoamine betaines, sulfonated C18 low-EO fatty ester alkoxylates, C18 amidoamine carboxylates, and amidoamine oxides and sulfobetaines derived from cross-metathesis of palm or soybean oil. The bargain detergents include a performance booster selected from C12 low-EO fatty ester alkoxylate sulfonates, C18 amidoamine oxide esters, C18 amidoamine oxide carboxylates, and amidoamine sulfobetaines made from self metathesized palm or soybean oil.
    Type: Application
    Filed: October 25, 2011
    Publication date: August 22, 2013
    Inventors: Dave R. Allen, Marcos Alonso, Randal J. Bernhardt, Dennis S. Murphy, Patrick Shane Wolfe, Aaron Brown
  • Patent number: 8283385
    Abstract: Reversible switchable surfactants are provided. A surfactant is the salt of an amidine or guanidine: having at least one R group that is a hydrophobic moiety selected from the group consisting of higher aliphatic moiety, higher siloxyl moiety, higher aliphatic/siloxyl moiety, aliphatic/aryl moiety, siloxyl/aryl moiety, and aliphatic/siloxyl/aryl moiety. The other R groups are smaller moieties such as H, C1 to C4 aliphatic or the like. The surfactant is turned on by a gas that liberates hydrogen ions, such as, for example, carbon dioxide, which liberates hydrogen ions in the presence of water. The surfactant is turned off by exposure to a flushing gas and/or heating. When “on” the surfactants are useful to stabilize emulsions, and when “off” they are useful to separate immiscible liquids or a liquid and a solid. The surfactants find uses in polymerization and in the oil industry.
    Type: Grant
    Filed: November 15, 2006
    Date of Patent: October 9, 2012
    Assignee: Queen's University at Kingston
    Inventor: Philip G. Jessop
  • Patent number: 8283306
    Abstract: An aqueous laundry detergent composition in the form of a liquid or gel, having a pH of from about 6 to about 11 in a 1% water solution and containing a non-soap anionic surfactant; soap; nonionic surfactant; fabric softening cationic cosurfactant having a molecular weight of less than about 1000; fabric softening quaternized polymer having a molecular weight of at least 100,000; non-quaternized, non polyamine thickener; perfume microcapsules; wherein at least one of the following is true; i) the ratio by weight of nonionic surfactant to anionic surfactant is greater than 1 and the total percentage, by weight of the composition, of the total of anionic surfactant, nonionic surfactant and soap is from 10% to 30%; and/or ii) the aqueous laundry detergent composition further comprises from about 0.5% to about 5% of a hydrotrope. Methods of laundering with such compositions.
    Type: Grant
    Filed: May 28, 2009
    Date of Patent: October 9, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Raphael Emmanuel Guyot, Marc Jennewein, James Charles Theophile Roger Burckett St. Laurent
  • Patent number: 8177857
    Abstract: There is provided a laundry composition comprising i) at least one laundry component selected from the group consisting of surfactants, softening agents, and mixtures thereof and ii) at least one ampholytic polymer comprising, as polymerized units, a) 20% to 90% by weight, based on the solid weight of said ampholytic polymer, at least one cationic monomer, b) 10% to 70% by weight, based on the solid weight of said ampholytic polymer, at least one anionic monomer, and c) 0% to 90% by weight, based on the solid weight of said ampholytic polymer, at least one nonionic monomer; wherein the equivalent ratio of said monomer a) to said monomer b) is from 0.33:1 to 1.2:1; and wherein said ampholytic polymer has weight-average molecular weight of 50,000 or less. Further provided is a method of laundering textiles comprising treating said textiles with such laundry compositions.
    Type: Grant
    Filed: March 2, 2006
    Date of Patent: May 15, 2012
    Assignee: Rohm and Haas Company
    Inventors: Marianne Patricia Creamer, Joseph Manna, Jan Edward Shulman
  • Patent number: 8110537
    Abstract: A liquid detergent composition is described. The liquid detergent composition includes an emulsion having a water phase and an oil phase. The liquid detergent composition includes a detersive amount of a nonionic surfactant component, an emulsion stabilizing amount of a cationic surfactant component, about 5 wt. % to about 94 wt. % water, and at least about 5 wt. % of a suspended particulate component. A detergent use solution and methods for using a liquid detergent composition are described.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: February 7, 2012
    Assignee: Ecolab USA Inc.
    Inventors: David W. Gohl, Kim R. Smith, Josh Kassanchuk, Brandon Carlson
  • Patent number: 7939488
    Abstract: A cleaning composition with a limited number of natural ingredients contain a hydrophobic syndetic, a hydrophilic syndetic, and a biguanide or a cationic quaternary ammonium salt. The cleaning composition can be used to clean laundry, soft surfaces, and hard surfaces and cleans as well or better than commercial compositions containing synthetically derived cleaning agents.
    Type: Grant
    Filed: March 4, 2010
    Date of Patent: May 10, 2011
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Rui Zhang
  • Patent number: 7939486
    Abstract: A cleaning composition with a limited number of natural ingredients contains an anionic surfactant, a hydrophobic syndetic, and a hydrophilic syndetic. The cleaning composition can be used to clean laundry, soft surfaces, and hard surfaces and cleans as well or better than commercial compositions containing synthetically derived cleaning agents.
    Type: Grant
    Filed: September 14, 2009
    Date of Patent: May 10, 2011
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Nancy Ann Falk, Sukhvinder Kaur, David Jackson Lestage, Erika Szekeres
  • Patent number: 7939487
    Abstract: A cleaning composition with a limited number of natural ingredients contains an anionic surfactant, a hydrophilic syndetic, nonionic surfactant and a hydrophobic syndetic. The cleaning composition can be used to clean laundry, soft surfaces, and hard surfaces and cleans as well or better than commercial compositions containing synthetically derived cleaning agents.
    Type: Grant
    Filed: September 14, 2009
    Date of Patent: May 10, 2011
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Nancy Ann Falk, David Jackson Lestage, Erika Szekeres, Sukhvinder Kaur
  • Patent number: 7935666
    Abstract: The present invention relates to a detergent composition having from 3 to 75 percent by weight of at least one surfactant; and from 0.01 to 5 percent by weight percent of a copolymer composed of from about 70 to 100 mole percent of at least one amine-functional monomer, and from about 30 to 0 mole percent of at least one hydrophobic ethylenically unsaturated monomer, wherein said amine-functional monomer is not a quaternized amine, and wherein said copolymer has been at least partially neutralized. The detergent composition having the copolymers provides color protection and anti-pill properties in laundry applications.
    Type: Grant
    Filed: February 18, 2005
    Date of Patent: May 3, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Klin A. Rodrigues, Martin Crossman
  • Patent number: 7919451
    Abstract: The invention relates to the use of cationic polycondensation products as additives for fixing colors and/or inhibiting the running of colors, for washing products and washing aftertreatment products. Said cationic polycondensation products can be produced by the condensation of (A1) non-cyclic amines obtained by the reaction of (A1 a) mono(N,N-dialkylaminoalkyl)amines with (A1 b) bifunctional compounds selected from the group containing urea, thiourea, dialkyl carbonates, aliphatic and aromatic dicarboxylic acids, and aliphatic and aromatic diisocyanates, in a molar ratio 1.2:1 to 2.1:1, or (A2) mixtures of non-cyclic amines (A1) and cyclic amines (A3) in a molar ratio 10:1 to 1:10 with (B) bifunctional compounds selected from the group containing alkylene dihalogenides, dihalogen alkyl ethers, halomethyl oxiranes, and bisepoxides, in a molar ratio (B) to (A1) or (B) to (A2) from 0.6:1 to 1.3:1.
    Type: Grant
    Filed: March 21, 2006
    Date of Patent: April 5, 2011
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Detering, Lidcay Herrera Taboada, Christian Hubert Weidl
  • Publication number: 20100330004
    Abstract: The invention includes a method of increasing the substantivity of a personal care composition to hair, skin or nails by preparing a composition of an aqueous phase, a non-aqueous phase and a neutralized amino acid ester that is a reaction product of a neutral amino acid having a non-polar side chain with a long chain fatty alcohol and is represented by formula (I): wherein R1 is an alkyl group; R2 is a linear or branched carbon chain; and the amine group of the amino acid is neutralized with an acid. The composition is substantially free of petrochemicals and/or derivatives of petrochemical materials. The aqueous phase and the non-aqueous phase are emulsified by the neutralized amino acid ester. Other methods and an emulsifiers that is the neutralized amino acid ester are included. Because the neutralized amino acid ester and the compositions do not contain petrochemical-derived ingredient, the products are natural.
    Type: Application
    Filed: June 29, 2010
    Publication date: December 30, 2010
    Applicant: Inolex Investment Corporation
    Inventor: Rocco Burgo
  • Publication number: 20100313360
    Abstract: The present invention provides a process for the preparation of a non-aqueous liquid fabric treatment composition wherein the process comprises a) provision of a pre-mix comprising cationic cellulosic polymer, water and optional solvent; b) admixture of the pre-mix with at least one anionic surfactant; and, c) subsequent addition of non-ionic surfactant, wherein the steps a) to c) are performed sequentially. The invention further relates to a process to produce a unit dose fabric treatment product, a product produced according to said process, the use of said product as a fabric softener, and a method of fabric treatment.
    Type: Application
    Filed: February 13, 2007
    Publication date: December 16, 2010
    Inventors: Rob Menting, Vidyadhar Sudhir Ranade
  • Patent number: 7820610
    Abstract: An alkaline laundry detergent for hand washing a fabric contains a sudsing surfactant, a polyethyleneimine suds collapser having the empirical formula (PEI)a(EO)b(PO)c where a is about 100-100,000, b is about 0-60, and c is about from 0-60, and a pH control system When diluted to form a laundry liquor and during washing the pH control system maintains the pH of the laundry liquor above about 8.
    Type: Grant
    Filed: April 1, 2009
    Date of Patent: October 26, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Michael Stanford Showell, Ming Tang, Frank Hulskotter, Haiyan Song, James Lee Danziger, Christofer Arisandy
  • Patent number: 7807614
    Abstract: Quaternary surfactants of the formula (I), wherein R1CO is a linear or branched, saturated or unsaturated, optionally hydroxy-functionalized acyl radical having 6 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, R2 is a CH2COOH radical, an alkyl radical having 1 to 4 carbon atoms, a CH2CH2OH or a CH2CH2OCH2CH2OH group, and X is halide, alkyl sulfate, alkyl carbonate or alkyl phosphate, are useful as surfactants in cosmetic and pharmaceutical preparations. Aqueous solutions above 50% by weight of the surfactants are flowable and pumpable.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: October 5, 2010
    Assignee: Cognis IP Management GmbH
    Inventors: Joaquin Bigorra Llosas, Karl Heinz Schmid, Rafael Pi Subirana, Nuria Bonastre Gilabert
  • Patent number: 7786068
    Abstract: Cleaning compositions are described comprising an aqueous component: an organic solvent; an anionic surfactant; an amine co-surfactant containing either (a) an N-oxide group or (b) a zwitterionic group; and a nonionic surfactant; in a form of a microemulsion or microemulsion preconcentrate. Methods of cleaning a hard surface using such compositions are also described.
    Type: Grant
    Filed: October 12, 2009
    Date of Patent: August 31, 2010
    Assignee: Colgate-Palmolive Company
    Inventors: Alexandrine Tuzi, Guy Broze
  • Patent number: 7786064
    Abstract: A novel class of ionic liquids and methods for their preparation are disclosed. Specifically, these novel ionic liquids can be derived from anionic surfactants, such as alkyl aryl sulfonates, and mid-chain branched derivatives of alkyl sulfates, alkyl alkoxy sulfates, and alkyl aryl sulfonates. In addition, novel ionic liquids can be derived from other anionic surfactants, such as methyl ester sulfonates (MES), alkyl glycerol ether sulfonates, and alpha olefin sulfonates. Anions may be paired with a variety of cations to achieve various advantageous properties. The present invention also relates to compositions containing these novel ionic liquids and method of using the same.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: August 31, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Stacie Ellen Hecht, Scott Leroy Cron, Jeffrey John Scheibel, Gregory Scot Miracle, Kenneth Richard Seddon, Martyn Earle, Harambage Quintus Nimal Gunaratne
  • Patent number: 7786065
    Abstract: A novel class of ionic liquids and methods for their preparation are disclosed. Specifically, these novel ionic liquids can be derived from peracid anions. The present invention also relates to compositions containing these novel ionic liquids and method of using the same.
    Type: Grant
    Filed: February 1, 2006
    Date of Patent: August 31, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Stacie Ellen Hecht, Gregory Scot Miracle, Scott Leroy Cron, Michael Stanford Showell
  • Patent number: 7737102
    Abstract: A novel class of ionic liquids and methods for their preparation are disclosed. Specifically, these novel ionic liquids can be derived from anionic surfactants, such as alkyl aryl sulfonates, and mid-chain branched derivatives of alkyl sulfates, alkyl alkoxy sulfates, and alkyl aryl sulfonates. In addition, novel ionic liquids can be derived from other anionic surfactants, such as methyl ester sulfonates (MES), alkyl glycerol ether sulfonates, and alpha olefin sulfonates. Anions may be paired with a variety of cations to achieve various advantageous properties. The present invention also relates to compositions containing these novel ionic liquids and method of using the same.
    Type: Grant
    Filed: October 31, 2005
    Date of Patent: June 15, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Stacie Ellen Hecht, Scott Leroy Cron, Jeffrey John Scheibel, Gregory Scot Miracle, Kenneth Richard Seddon, Martyn Earle, Harambage Quintus Nimal Gunaratne
  • Patent number: 7700539
    Abstract: The present invention relates to a solid free-flowing particulate laundry detergent composition comprising a detersive surfactant, carbonate and a cellulosic polymer.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: April 20, 2010
    Assignee: The Procter & Gamble Company
    Inventors: John Peter Eric Muller, Alan Thomas Brooker, Doris Appleby
  • Patent number: 7678752
    Abstract: Systems, compositions and methods for fabric laundering comprising selected organosilicones which are formulated into microemulsions for improved deposition onto fabrics to provide fabric care benefits.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: March 16, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Rajan Keshav Panandiker, Kerry Andrew Vetter, Mary Jane Combs, David Gladney, Jr., Connie Lynn Sheets
  • Patent number: 7678755
    Abstract: A modified polyol compound having alkoxylation and having at least one anionic capping unit, uses of the modified polyol compound having alkoxylation and having at least one anionic capping unit and cleaning compositions comprising the same.
    Type: Grant
    Filed: April 15, 2009
    Date of Patent: March 16, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey John Scheibel, Julie Ann Menkhaus, Xinbei Song, Eva Schneiderman
  • Patent number: 7670389
    Abstract: The use of water-soluble or water-dispersible polymers obtainable by reaction of (a) polyalkylenepolyamines, polyamidoamines or ethyleneimine-grafted polyamidoamines or mixtures thereof, (b) if desired at least bifunctional crosslinkers and (c) monoethylenically unsaturated carboxylic acids, salts, esters, amides or nitriles of monoethylenically unsaturated carboxylic acids, chlorocarboxylic acids and/or glycidyl compounds, said component (a) having an average molecular weight Mw in the range from 20 000 to 2 000 000 and the molar ratio of the hydrogen atoms on the nitrogen in said component (a) to said component (b) being in the range from 1:0.7 to 1:0.9, as a laundry detergent additive.
    Type: Grant
    Filed: January 24, 2006
    Date of Patent: March 2, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Heike Becker, Volker Braig, Lidcay Herrera Taboada
  • Publication number: 20100035790
    Abstract: The invention relates to fragrance-modified branched polyorganosiloxanes, methods for producing them and their use.
    Type: Application
    Filed: March 19, 2008
    Publication date: February 11, 2010
    Applicant: MOMENTIVE PERFORMANCE MATERIALS GMBH
    Inventors: Horst Lange, Christopher Roos, Roland Wagner, Martin Kropfgans
  • Publication number: 20100011519
    Abstract: The invention provides improvements in the color protection properties of detergents and cleaning agents during their utilization for washing or cleaning colored textile fabrics. Specific polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compounds or a precursor compound thereof containing specific reactive groups, which can be used for the production of the polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compounds, are utilized.
    Type: Application
    Filed: September 25, 2009
    Publication date: January 21, 2010
    Applicant: Henkel AG & Co. KGaA
    Inventors: Nadine Warkotsch, Brigit Middelhauve, Marc-Steffen Schiedel, Thomas Eiting
  • Patent number: 7629305
    Abstract: A cleaning composition with a limited number of natural ingredients contains a nonionic surfactant, a solvent and a short chain syndetic. The cleaning composition can be used to clean laundry, soft surfaces, and hard surfaces and cleans as well or better than commercial compositions containing synthetically derived cleaning agents.
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: December 8, 2009
    Assignee: The Clorox Company
    Inventors: Erika Szekeres, David Jackson Lestage, Joe McShane, David R. Scheuing, Laura Shimmin
  • Patent number: 7622436
    Abstract: Cleaning compositions are described comprising an aqueous component; an organic solvent; an anionic surfactant; an amine co-surfactant containing either (a) an N-oxide group or (b) a zwitterionic group; and a nonionic surfactant; in a form of a microemulsion or microemulsion preconcentrate. Methods of cleaning a hard surface using such compositions are also described.
    Type: Grant
    Filed: February 2, 2009
    Date of Patent: November 24, 2009
    Assignee: Colgate-Palmolove Company
    Inventors: Alexandrine Tuzi, Guy Broze
  • Patent number: 7618931
    Abstract: A cleaning composition with a limited number of natural ingredients contains an anionic surfactant, a hydrophobic syndetic, a hydrophilic syndetic and a solvent. The cleaning composition can be used to clean laundry, soft surfaces, and hard surfaces and cleans as well or better than commercial compositions containing synthetically derived cleaning agents.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: November 17, 2009
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Nancy Ann Falk, Sukhvinder Kaur, David Jackson Lestage, Erika Szekeres
  • Patent number: 7608573
    Abstract: A cleaning composition with a limited number of natural ingredients contains an anionic surfactant, a nonionic surfactant, a solvent and a short chain syndetic. The cleaning composition can be used to clean laundry, soft surfaces, and hard surfaces and cleans as well or better than commercial compositions containing synthetically derived cleaning agents.
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: October 27, 2009
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Nancy Ann Falk, David Jackson Lestage, Erika Szekeres
  • Publication number: 20090264328
    Abstract: A surfactant composition comprising: (a) a surfactant material; (c) a polyethylene imine of the general formula —(CH2CH2NH)n—; and (d) an aromatic, monoethylenically-unsaturated carboxylic acid ester of the formula (I) where R1 is selected from the group consisting of hydrogen, C1-C16 alkyl, C1-C16 alkoxy, aryl and substituted aryl, and R2 is selected from the group consisting of aryl, substituted aryl and C6-C16 alkyl; the materials (b)-(d) each having an odour value of 10,000 maximum. The problem of rancidity, commonly encountered when low-grade surfactant materials are used, especially in soaps, is considerably reduced.
    Type: Application
    Filed: July 25, 2005
    Publication date: October 22, 2009
    Applicant: GIVAUDAN SA
    Inventors: Venkateswara Kumar Vedantam, Janardhanan Mahalingam, Jee Ting Nicholas Wong, Markus Gautschi
  • Patent number: 7550631
    Abstract: Uses of a modified polyol compound having alkoxylation and having at least one anionic capping unit.
    Type: Grant
    Filed: September 24, 2007
    Date of Patent: June 23, 2009
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey John Scheibel, Julie Ann Menkhaus, Xinbei Song, Eva Schneiderman
  • Patent number: 7538080
    Abstract: A modified polyol compound having alkoxylation and having at least one anionic capping unit, uses of the modified polyol compound having alkoxylation and having at least one anionic capping unit and cleaning compositions comprising the same.
    Type: Grant
    Filed: September 24, 2007
    Date of Patent: May 26, 2009
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey John Scheibel, Julie Ann Menkhaus, Xinbei Song, Eva Schneiderman
  • Publication number: 20090124531
    Abstract: Laundry detergent and cleaning compositions comprising amphiphilic water-soluble alkoxylated polyalkylenimine polymer having an inner polyethylene oxide block comprising 20 to 50 polyethylene oxide units and an outer polypropylene oxide block comprising 10 to 50 polyethylene oxide units and especially to such alkoxylated polyalkylenimines wherein the ratio of polyethylene oxide units and polypropylene oxide units is proportionally related to the square root of the number of polyalkylenimine units present in the backbone.
    Type: Application
    Filed: November 7, 2008
    Publication date: May 14, 2009
    Inventors: James Lee Danziger, Frank Hulskotter, Dieter Boeckh, Sophia Ebert, Andrea Misske, Stefan Frenzel
  • Patent number: 7439219
    Abstract: A modified polyol having alkoxylation and amine capping units, uses of the modified polyol having alkoxylation and amine capping units, and leaning compositions having the modified polyol having alkoxylation and amine capping units.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: October 21, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey John Scheibel, Julie Ann Menkhaus
  • Publication number: 20080131393
    Abstract: The present invention relates to a block polymeric material. Typically the block polymer comprises units capable of having an average cationic charge density of about 15 or less, preferably 5 or less, more preferably from about 0.05 to about 5, even more preferably from about 0.05 to about 2.77, even more preferably from about 0.1 to about 2.75, most preferably from about 0.75 to about 2.25 units per 100 daltons molecular weight at a pH of from about 4 to about 12. The polymeric material is a suds enhancer and a suds volume extender for personal care products such as soaps and shampoos. The compositions have increased effectiveness for preventing re-deposition of grease during hand and body washing. The polymers are also effective as a soil release agent in fabric cleaning compositions.
    Type: Application
    Filed: December 28, 2007
    Publication date: June 5, 2008
    Applicant: Rhodia Inc.
    Inventors: Dominic Wai-Kwing YEUNG, Vance Bergeron, Jean-Francois Bodet, Mark Robert Sivik, Bernard William Kluesener, William Michael Scheper
  • Patent number: 7335629
    Abstract: The present invention relates to support-fixed bleaching catalyst(s)suitable or the catalysis of peroxide compounds, characterized in that the support-fixed bleaching catalyst(s) is/are covalently bonded to a support by means of at least one organic ligand of the bleaching catalyst. The bleaching catalyst(s) form(s) a complex with at least on transition metal. The invention further relates to support-fixed bleaching catalysts for the catalysis of peroxide compounds, where at least one ligand, covalently bonded to a support, is a transition-metal-free ligand, which chelates with transition metal, derived from another source, preferably from the bleaching composition and/or added water and thus forms the complex with a transition metal.
    Type: Grant
    Filed: June 21, 2004
    Date of Patent: February 26, 2008
    Assignee: Henkel Kommanditgesellschaft Auf Aktien
    Inventors: Pavel Gentschev, Steve Döring, Jacques Breyer, Antonio Machin
  • Patent number: 7297675
    Abstract: The invention relates to a process for preparing highly concentrated flowable and pumpable aqueous solutions of betaines by quaternization of compounds containing tertiary amine nitrogen with ?-halocarboxylic acids by known processes, wherein 0.1 to less than 3% by weight, preferably 0.1 to 1% by weight, based on the end product, of one or more micellar thickeners are added to the reaction mixture before or during the quaternization reaction.
    Type: Grant
    Filed: September 19, 2006
    Date of Patent: November 20, 2007
    Assignee: Goldschmidt GmbH
    Inventors: Petra Allef, Uwe Begoihn, Burghard Grüning, Ralf Klein, Jörg Peggau
  • Patent number: 7189685
    Abstract: The present invention relates to methods and compositions for removing hydrophobic soils from textiles. The methods include contacting a soiled textile with a penetrant composition and then washing the textile. The present compositions include penetrant compositions that can also include wetting agent and hydrotrope.
    Type: Grant
    Filed: July 23, 2004
    Date of Patent: March 13, 2007
    Assignee: Ecclab Inc.
    Inventors: Stephan Maria Hubig, Robert D. P. Hei, Terry J. Klos
  • Patent number: 7163916
    Abstract: The invention relates to a process for preparing highly concentrated flowable and pumpable aqueous solutions of betaines by quaternization of compounds containing tertiary amine nitrogen with ?-halocarboxylic acids by known processes, wherein 0.1 to less than 3% by weight, preferably 0.1 to 1% by weight, based on the end product, of one or more micellar thickeners are added to the reaction mixture before or during the quaternization reaction.
    Type: Grant
    Filed: November 17, 2005
    Date of Patent: January 16, 2007
    Assignee: Goldschmidt GmbH
    Inventors: Petra Allef, Uwe Begoihn, Burghard Grüning, Ralf Klein, Jörg Peggau
  • Patent number: 7141076
    Abstract: A hydrolizable polymer-containing textile article and method for producing the same is provided that has been chemically modified by treating the article with certain branched chain amines to reduce the strength of the fibers contained therein, thus rendering the article less prone to the formation of objectionable pill balls, thereby increasing wearer comfort and retaining the desired appearance of the article, and thereby extending the useful life of the article.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: November 28, 2006
    Assignee: Milliken & Company
    Inventor: William C. Kimbrell
  • Patent number: 7137999
    Abstract: A hydrolizable polymer-containing textile article and method for producing the same is provided that has been chemically modified by treating the article with certain branched chain amines to reduce the strength of the fibers contained therein, thus rendering the article less prone to the formation of objectionable pill balls, thereby increasing wearer comfort and retaining the desired appearance of the article, and thereby extending the useful life of the article.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: November 21, 2006
    Assignee: Milliken & Company
    Inventor: William C. Kimbrell
  • Patent number: 7125831
    Abstract: The invention can provide a detergent composition for dry cleaning which comprises a nonionic surfactant as the component (a), a cyclic polysiloxane as the component (b) and a polyether modified silicone having a HLB value of at most 6 as the component (c), wherein the content of the component (a) is 5 to 70% by weight based on the total weight of the components (a), (b) and (c), the content of the total of the components (b) and (c) is 30 to 95% by weight based on the same, and the ratio by weight of the component (b) to the component (c) {b/c} is 1/10 to 20/1 and a detergent liquid for dry cleaning using the above detergent composition.
    Type: Grant
    Filed: May 29, 2002
    Date of Patent: October 24, 2006
    Assignee: NOF Corporation
    Inventors: Takaya Azuma, Susumu Shirouzu
  • Patent number: 7098179
    Abstract: A method of washing a soiled textile comprising cotton, the method comprising contacting the textile with a wash liquor, the wash liquor containing a soil-release effective amount of one or more soil release polymers obtained by polymerizing one or more polyisocyanates with one or more polymeric polyols having an average molar mass of above 1000 D and a 20° C. water solubility of above 300 g of polymer per liter, one or more polyols having an average molar mass of below 12,000 D and a 20° C. water solubility of below 100 g per liter, and optionally one or more further polyols.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: August 29, 2006
    Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
    Inventors: Josef Penninger, Wolfgang Denuell, Rainer Schoenfeld
  • Patent number: 7041648
    Abstract: The PTX3 gene or equivalent PTX3 activity is required for female fertility. Manipulation of PTX3 activity will regulate female fertility. The effects of female sterility may be ameliorated, reproductive ability may be increased or decreased as desired, female fertility may be enhanced, or combinations thereof. The need for therapies that affect female fertility is thereby addressed.
    Type: Grant
    Filed: February 25, 2004
    Date of Patent: May 9, 2006
    Assignee: Sigma-Tau Industrie Farmaceutiche Riunite S.p.A.
    Inventor: Alberto Mantovani
  • Patent number: 6989360
    Abstract: Aqueous textile fiber degreasing agents (WE) essentially consisting of (A) at least one amine oxide of the average formula ?as defined in claim 1, (B) at least one hexanediol, (C) at least one secondary, branched or cyclic hexanol, (D) at least one aminosurfactant of the average formula ?as defined in claim 1 and (E) water, and optionally at least one formulation additive (F), their production and use, particularly under alkaline conditions, in textile goods production.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: January 24, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bernard Danner, Francis Palacin
  • Patent number: 6956017
    Abstract: The present invention is directed to laundry detergent compositions comprising a semi-polar nonionic surfactant and a cyclic amine based polymer. Such compositions provide good cleaning performance together with excellent fabric care benefits.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: October 18, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Kemal Vatansever Catalan, Patrick Firmin August Delplancke, Axel Masschelein, Pramod Kakumanu Reddy, Diane Barbara Parry