Oxygen Containing Surfactant Devoid Of Covalently Bonded Anionic Substituents (e.g., Polyethoxylated Alcohol, Amine Oxide, Etc.) Patents (Class 510/356)
  • Patent number: 7098179
    Abstract: A method of washing a soiled textile comprising cotton, the method comprising contacting the textile with a wash liquor, the wash liquor containing a soil-release effective amount of one or more soil release polymers obtained by polymerizing one or more polyisocyanates with one or more polymeric polyols having an average molar mass of above 1000 D and a 20° C. water solubility of above 300 g of polymer per liter, one or more polyols having an average molar mass of below 12,000 D and a 20° C. water solubility of below 100 g per liter, and optionally one or more further polyols.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: August 29, 2006
    Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
    Inventors: Josef Penninger, Wolfgang Denuell, Rainer Schoenfeld
  • Patent number: 7098177
    Abstract: A process for preparing detergent particles containing step (I): mixing a base particle for supporting a surfactant ((a) component), and a surfactant composition ((b) component), under mixing conditions wherein the (a) component does not substantially undergo breakdown, to give a mixture; wherein the base particle is obtained by spray-drying an aqueous slurry, wherein the mixing operation is carried out by using a mixer containing agitation impellers, and where the mixer further contains disintegration impellers, the mixing operation step (I) is carried out without substantially rotating the disintegration impellers; and step (II): mixing the mixture obtained in step (I) with 5 to 100 parts by weight of fine powder, while substantially maintaining the shape of the (a) component containing (b) component, to give detergent particles, having a degree of particle growth of 1.3 or less, and a bulk density of 500 g/L or more.
    Type: Grant
    Filed: October 14, 1999
    Date of Patent: August 29, 2006
    Assignee: Kao Corporation
    Inventors: Teruo Kubota, Hitoshi Takaya, Hiroyuki Yamashita
  • Patent number: 7098175
    Abstract: Aqueous laundry detergent compositions comprising a solubilized ethoxylated fatty acid diester as a detergency booster and/or a defoamer. Preferred compositions include a nonionic surfactant, preferably ethoxylated fatty acid monoester, as at least part of the surfactant in the composition, and also functioning as the solibilizer for the ethoxylated fatty acid diester.
    Type: Grant
    Filed: June 8, 2004
    Date of Patent: August 29, 2006
    Assignee: Unilever Home & Personal Care USA Division of Conopco, Inc.
    Inventors: Feng-Lung Gordon Hsu, Shui-Ping Zhu, Yun-Peng Zhu
  • Patent number: 7091168
    Abstract: An aqueous laundry detergent composition containing a hydroxy mixed ether.
    Type: Grant
    Filed: June 29, 2001
    Date of Patent: August 15, 2006
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Manfred Weuthen, Michael Elsner, Ditmar Kischkel
  • Patent number: 7091167
    Abstract: The following dye-transfer-inhibiting dye fixatives are used in laundry detergents which comprise nonionic surfactants: Reaction products of a) amines with epichlorohydrin or b) cyanamide with amines and aldehydes.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: August 15, 2006
    Assignee: Clariant GmbH
    Inventors: Frank-Peter Lang, Helmut Berenbold, Michael Wessling
  • Patent number: 7084100
    Abstract: The present invention is directed to a composition having from about 0.005% to about 5% by weight, preferably, from about 0.01% to about 1% by weight of an antioxidant. The composition is selected from the group consisting of a laundry detergent composition, a fabric softening composition, a dish care composition, a personal cleansing composition, a shampoo composition, a rinsing composition and a conditioner composition.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: August 1, 2006
    Assignee: The Procter & Gamble Company
    Inventor: Randall Alan Watson
  • Patent number: 7078373
    Abstract: The detergent composition of the invention contains a combination of an anionic surfactant, a defined nonionic surfactant of high hydrophilic/lipophilic balance (HLB) value, optionally a cationic surfactant, optionally a detergency builder, optionally an inorganic non-builder salt, an optionally a polycarboxylate polymer. Further optional detergent ingredients may also be present. The amount of the anionic surfactant is from 5 to 40, preferably from 7 to 30 wt % and the amount of the nonionic surfactant is from 1 to 20, preferably from 1 to 10 wt %, based on the weight of the total composition.
    Type: Grant
    Filed: November 3, 2003
    Date of Patent: July 18, 2006
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Jacqueline Burrows, Robert John Crawford, Patrick Joseph Norris, David Christopher Thorley
  • Patent number: 7074749
    Abstract: The invention describes detergents and cleaners comprising an effective proportion of one or more surfactants of the formula I in which a is one of the numbers 11, 12, or 13, R1 and R2 are different and are each hydrogen or alkyl radicals R3 is hydrogen, or a sulfato or phosphate radical, x and y are each a number from 0 to 200, and further known auxiliaries and additives customary in detergents and cleaners and optionally in addition further surfactants.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: July 11, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Tropsch, Heiko Maas
  • Patent number: 7056876
    Abstract: Hydrous, paste-like, thixotropic detergent or cleaning agent containing, based on the whole agent, a) an alkalinity support, selected from alkali hydroxide and/or alkali carbonate, in a quantity of 5 to 40 wt. %, preferably 8 to 30 wt. %, b) at least 5 wt. %, preferably 15 to 40 wt. % water, and c) more than 3 wt. %, preferably 5.5 to 30 wt. %, particularly preferably 6 to 15 wt. % non-ionic surfactants, wherein, at 25° C., the agent has a viscosity of 50,000 mPas to 250,000 mPas, measured using a Brookfield rotational viscometer (spindle no. 7) at 5 revolutions per minute and, under otherwise identical conditions, at 50 revolutions per minute has a viscosity of 12,000 mPas to 80,000 mPas.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: June 6, 2006
    Assignee: Ecolab Inc.
    Inventor: Khalil Shamayeli
  • Patent number: 7022662
    Abstract: The invention relates to surfactant mixtures of hydroxy mixed ethers and polymers, optionally together with typical ingredients of dishwashing detergents and cleaners and optionally other nonionic surfactants and anionic surfactants and to the use of such surfactant mixtures for the preparation of cleaning solutions with improved performance against resoiling.
    Type: Grant
    Filed: November 4, 2002
    Date of Patent: April 4, 2006
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Ditmar Kischkel, Manfred Weuthen, Michael Elsner
  • Patent number: 7008917
    Abstract: A cleaning composition, in a concentrated form comprising a water-soluble organic solvent, an ionic surfactant, a nonionic surfactant, a chelating agent, and distilled water.
    Type: Grant
    Filed: June 15, 2004
    Date of Patent: March 7, 2006
    Assignee: The Knockout Group, Inc.
    Inventors: Karl A. Heise, Jerry Moore
  • Patent number: 6989360
    Abstract: Aqueous textile fiber degreasing agents (WE) essentially consisting of (A) at least one amine oxide of the average formula ?as defined in claim 1, (B) at least one hexanediol, (C) at least one secondary, branched or cyclic hexanol, (D) at least one aminosurfactant of the average formula ?as defined in claim 1 and (E) water, and optionally at least one formulation additive (F), their production and use, particularly under alkaline conditions, in textile goods production.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: January 24, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bernard Danner, Francis Palacin
  • Patent number: 6987086
    Abstract: Compositions for removing incidental soils from fabric articles, especially articles of clothing, linen and drapery, provide improved cleaning of incidental soils, either with or without a subsequent wash process. Methods for use of the compositions are also provided. The compositions and methods are safe for use on a wide range of fabric articles, even in the home.
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: January 17, 2006
    Assignee: Procter & Gamble Company
    Inventors: John Christopher Deak, Robert James Perry
  • Patent number: 6984615
    Abstract: Disclosed is a cleaning article including fibers having at least a surfactant adhered thereto, wherein the surfactant is a mixture that contains from 45 to 76% by weight of a polyoxyethylene (POE) monoester of a fatty acid having from 5 to 15 carbon atoms, and the balance of the mixture is at least one compound selected from the group consisting of a POE monoester of a saturated fatty acid having from 16 to 22 carbon atoms, a POE monoester of an unsaturated fatty acid having from 16 to 22 carbon atoms, a POE diester of an unsaturated fatty acid having from 16 to 22 carbon atoms, and a POE diester of a saturated fatty acid having from 12 to 15 carbon atoms.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: January 10, 2006
    Assignee: Uni-Charm Corporation
    Inventors: Yasuhiko Kenmochi, Masatoshi Fujiwara, Yoshinori Tanaka, Yoshiko Saida, Kodai Furuya
  • Patent number: 6956017
    Abstract: The present invention is directed to laundry detergent compositions comprising a semi-polar nonionic surfactant and a cyclic amine based polymer. Such compositions provide good cleaning performance together with excellent fabric care benefits.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: October 18, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Kemal Vatansever Catalan, Patrick Firmin August Delplancke, Axel Masschelein, Pramod Kakumanu Reddy, Diane Barbara Parry
  • Patent number: 6924259
    Abstract: The present invention relates to a detergent composition having from 3 to 75 percent by weight of at least one surfactant; and from 0.01 to 5 percent by weight percent of a copolymer composed of from 25 to 75 mole percent of at least one amine-functional monomer, and from 75 to 25 mole percent of at least one hydrophobic ethylenically unsaturated monomer, wherein said amine-functional monomer is not a quaternized amine, and wherein said copolymer has been at least partially neutralized. The detergent composition having the copolymers provides color protection and anti-pill properties in laundry applications.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: August 2, 2005
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Klein A. Rodrigues, Martin Crossman
  • Patent number: 6921744
    Abstract: Hydroxy mixed ethers of the general formula (I): R1O[CH2CH2O]xCH2CH(OH)R2??(I) wherein R1 represents a linear or branched, alkyl or alkenyl group having from 4 to 22 carbon atoms; R2 represents a linear or branched, alkyl or alkenyl group having from 2 to 22 carbon atoms; and x represents a number of from 40 to 80, are described along with compositions containing such hydroxy mixed ethers in conjunction with other surfactants. Also described are various anti-foaming uses for such ethers and compositions containing the same.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: July 26, 2005
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Karl Heinz Schmid, Detlev Stanislowski, Hans-Christian Raths
  • Patent number: 6919305
    Abstract: Solid laundry detergents, dishwashing detergents and cleaners which are obtained by mixing gemini surfactants of the formula (I), R1CH(OH)CHR3(OCH2CH2)nOCHR4CH(OH)R2??(I) in which R1 and R2,independently of one another, are linear or branched alkyl and/or alkenyl radicals having 4 to 22 carbon atoms, R3 and R4, independent of one another, each represents a hydrogen or an alk(en)yl radical having from 1 to 22 carbon atoms and n is a number from 5 to 400, with inorganic or organic carriers.
    Type: Grant
    Filed: January 28, 2004
    Date of Patent: July 19, 2005
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Ditmar Kischkel, Manfred Weuthen, Michael Elsner
  • Patent number: 6914041
    Abstract: The present invention relates to laundry detergent compositions which provide enhanced hydrophilic soil cleaning benefits comprising a zwitterionic polyamine, a surfactant system comprising a mid-chain branched surfactant, and carrier and other adjunct ingredients.
    Type: Grant
    Filed: October 6, 2003
    Date of Patent: July 5, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Nathan Price, Eugene Paul Gosselink
  • Patent number: 6911423
    Abstract: In order to improve the dispersion of nonionic surfactant into wash water from a granule in which the nonionic surfactant is carried on a water-insoluble granular material, the nonionic surfactant is intimately mixed with a structurant which is a non-soap ionic surfactant in finely divided particulate form. A preferred structurant is an anionic surfactant, for example, primary alcohol sulphate.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: June 28, 2005
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Peter Robert Garrett, John Edley Wilson
  • Patent number: 6903059
    Abstract: The present invention relates to detergent compositions comprising a polyamine with defined end capping units and a mid-chain branched surfactant and also optionally containing a bleach agent, aluminosilicate, silicate, and/or detersive enzyme.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: June 7, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Nathan Price, Eugene Paul Gosselink, Randall Scott Deinhammer
  • Patent number: 6897193
    Abstract: Solid composition useful for the production of dishwashing, laundry or cleaning compositions are comprised of (a) a hydroxy mixed ether of the formula (I) wherein R1 is a linear or branched alkyl group having from 2 to 18 carbon atoms, R2 is hydrogen or a linear or branched alkyl group having from 2 to 18 carbon atoms, R3 is a linear or branched alkyl and/or alkenyl group having from 1 to 22 carbon atoms, each of n1 and n2 independently is a number from 0 to 60 and m is 0 or a number from 0.5 to 5, with the provisos that the total number of carbon atoms in the substituents R1 and R2 is at least 6 and the sum (n1+m+n2) is greater than 0; and (b) a polymer. The compositions according to the invention can optionally contain additional nonionic surfactants, carriers, auxiliaries and additives typically found in laundry detergents, dishwashing detergents and cleaning compositions.
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: May 24, 2005
    Assignee: Cognis Deutschland GmbH & Co., KG
    Inventors: Ditmar Kischkel, Manfred Weuthen, Michael Elsner
  • Patent number: 6894016
    Abstract: To present a liquid detergent of a high cleaning power and an excellent storage stability while maintaining the ease of use. A liquid detergent composition comprising, at a specific ratio individually, (a) water, (b) a builder composed of a water-soluble inorganic salt of which solubility in distilled water is 0.5 g/15 g (25° C., distilled water) or more, and (c) a substance liquid at 25° C. containing at least one selected from the group consisting of surfactant (c1) and water-miscible organic solvent (c2) in which part of (b) is present in solid state in the composition, and its electric conductivity measured by a specific method is within a specified range.
    Type: Grant
    Filed: May 8, 2002
    Date of Patent: May 17, 2005
    Assignee: Kao Corporation
    Inventors: Akira Ishikawa, Toshio Miyake, Kazutoshi Ide
  • Patent number: 6890892
    Abstract: Compositions and methods for removing and/or reducing incidental soils from fabric articles, especially articles of clothing, linen and drapery, wherein the compositions provide improved cleaning of incidental soils, either with or without a subsequent wash process or other entire fabric care process are provided. The compositions and methods are safe for use on a wide range of fabric articles, even in the home.
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: May 10, 2005
    Assignee: Procter & Gamble Company
    Inventors: William Michael Scheper, Michael Stanford Showell, Hiroshi Oh, David Lee Daugherty
  • Patent number: 6878682
    Abstract: The invention relates to a series low foaming capped non-ionic surfactants. These compounds by virtue of reacting the terminal hydroxyl group with methallyl chloride, have increased stability in alkali, lower high cloud points and can be reacted via free radical technology into polymer backbones, resulting in non-water blush surfactants.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: April 12, 2005
    Assignee: Colonial Chemical Inc.
    Inventor: Anthony J. O'Lenick, Jr.
  • Patent number: 6878683
    Abstract: Polymers of a poly(meth)acrylic acid main chain in which, based on the main chain, 0 to 30% by weight of the (meth)acrylic acid basic building blocks may be replaced by maleic acid (anhydride) basic building blocks, fumaric acid basic building blocks or mixtures thereof and 0 to 10% by weight of the (meth)acrylic acid basic building blocks may be replaced by other copolymerizable ethylenic basic building blocks, and C1-30-alkylpoly-C2-4-alkylene glycols, bonded to the main chain via ester groups, having an average molecular weight of from 250 to 10 000 as side chains, where, based on the polymer, 1 to 19% by weight of the main chain and 81 to 99% by weight of the side chains are present and this ratio and the average molecular weight of the side chains are chosen such that free carboxyl groups are present in the polymer, are used as controllable dispersants for detergents or cleaners or constituents thereof.
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: April 12, 2005
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Neumann, Werner Bertleff, Matthias Kroner, Bernard Mohr
  • Patent number: 6861400
    Abstract: The present invention relates to novel hydrophobic soil dispersants having the formula: wherein A units are arylene units, one of which is phenyl, anthryl, or phenanthryl; each R is independently hydrogen, linear or branched C1-C4 alkyl, —O(R3O)mR4, and mixtures thereof; R3 is C2-C4 linear or branched alkylene, R4 is hydrogen, C1-C4 alkyl, phenyl, phenyl sulphonate, —CH2CH(SO3M)CH2OH, —CH2CH(OH)CH2SO3M, —(CH2)eSO3M, —(CH2)fCO2M, —(CH2)eCH(SO3M)-CH2SO3M, —(CH2)eCH(SO2M)-CH2SO3M, —(CH2)fPO3M, —PO3M, or mixtures thereof; M is hydrogen or a water-soluble cation, the index f is an integer from 1 to 6, the index e is an integer from 0 to 6, m is an integer from 0 to 25; R1 is a sulphonate group; R2 is an amino group; [CAP] is a chain capping unit selected from i) hydrogen; ii) an aryl unit having the formula: iii) an aryl unit having the formula: iv) an aryl unit having the formula: v) an aryl unit having the formula: vi) and mixtures thereof; R5 is hydrogen, —CH2OH, —CH2OSO3M, —CH3, and mix
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: March 1, 2005
    Assignee: The Procter & Gamble Co.
    Inventors: Daniel Stedman Connor, Rafael Ortiz
  • Patent number: 6858570
    Abstract: The following dye-transfer-inhibiting dye fixatives are used in laundry detergents: Reaction products of a) polyamines with cyanamides and amidosulfuric acid or b) cyanamides with aldehydes and ammonium salts or c) amines with epichlorohydrin.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: February 22, 2005
    Assignee: Clariant GmbH
    Inventors: Frank-Peter Lang, Helmut Berenbold, Michael Wessling
  • Patent number: 6855680
    Abstract: Structuring systems, specifically thread-like structuring systems and/or disk-like structuring systems wherein structuring agents aggregate together to form disk-like structures that can interact with other disk-like structures to result in a structuring system, and processes for making such structuring systems, stabilized liquid compositions comprising such structuring systems, systems that utilize such structuring systems for stabilizing liquid compositions, and methods for utilizing the stabilized liquid compositions to provide a benefit, are disclosed.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: February 15, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Mark Allen Smerznak, Walter August Maria Broeckx
  • Patent number: 6849587
    Abstract: Liquid and/or gel laundry detergent compositions which snap back at the end of dispensing, thus eliminating or minimizing the dripping from the container. Employing a non-neutralized fatty acid to the total surfactant weight % ratio within a specific range, defined by the Snap Index equation, results in liquids and/or gels with the desired snap-back property.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: February 1, 2005
    Assignee: Unilever Home & Personal Care USA, a division of Conopco, Inc.
    Inventors: Feng-Lung Gordon Hsu, Yun-Peng Zhu, Ronald Frederick Vogel, Agnes Boudou, Charles Ebert
  • Patent number: 6846791
    Abstract: The present invention relates to hydrophobically modified polyamines and laundry detergent compositions comprising such polyamines and a surfactant system. In addition to traditional cleaning benefits, such compositions provide enhanced greasy soil removal capabilities.
    Type: Grant
    Filed: November 7, 2000
    Date of Patent: January 25, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey Scott Dupont, Eugene Paul Gosselink, Kenneth Nathan Price, Robert Henry Rohrbaugh
  • Patent number: 6844309
    Abstract: Ether-capped poly(oxyalkylated) alcohol surfactants having superior grease cleaning abilities and improved spotting/filming benefits are provided.
    Type: Grant
    Filed: September 12, 2000
    Date of Patent: January 18, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Mark Robert Sivik, Glenn Thomas Jordan, IV, Bernard William Kluesener, William Michael Scheper, Donna Jean Haeggberg, Kristen Lynne McKenzie
  • Patent number: 6831052
    Abstract: Cleaning compositions containing hydroxy mixed ethers of the general formula (I) are described: R1O[CH2CHR4O]x[CH2CHR3O]yCH2CH(OH)R2  (I) wherein R1 represents an alk(en)yl radical having from 4 to 22 carbon atoms; R2 represents an alk(en)yl radical having from 2 to 22 carbon atoms; R3 represents a hydrogen or a methyl radical; R4 represents a hydrogen or a methyl radical; x is from 1 to 40; y is from 1 to 40; and x+y>=1; and wherein the alkylene units —CH2CHR3O— and —CH2CHR4O— are in randomized form, preferably in an ethylene oxide to propylene oxide ratio of from 40:1 to 40:5. Methods of preparing and using the hydroxy mixed ethers are also described.
    Type: Grant
    Filed: January 31, 2002
    Date of Patent: December 14, 2004
    Assignee: Cognis Deutschland GmbH
    Inventors: Manfred Weuthen, Hans-Christian Raths, Michael Elsner
  • Patent number: 6828295
    Abstract: A composition containing a polyoxyalkylene polymer for cleaning fabric articles, especially articles of clothing, linen and drapery, with lipophilic fluid provides improved cleaning of soils while providing excellent garment care, especially for articles sensitive to water.
    Type: Grant
    Filed: September 10, 2002
    Date of Patent: December 7, 2004
    Assignee: Proacter & Gamble Company
    Inventors: John Christopher Deak, Eugene Paul Gosselink, Randall Thomas Reilman, Donna Jean Haeggberg
  • Patent number: 6812198
    Abstract: The present invention relates to hydrophobically modified polyamines and laundry detergent compositions which comprise said polyamines, said compositions comprising: A) from about 0.01%, preferably from about 0.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: November 2, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey Scott Dupont, Eugene Paul Gosselink, Kenneth Nathan Price, Robert Henry Rohrbaugh
  • Patent number: 6812201
    Abstract: Surfactant mixtures comprising (a) a nonionic surfactant mixture present in an amount greater than 60% by weight, based on the weight of the surfactant mixture, the nonionic surfactant mixture comprising: (i) at least one alk(en)yl oligoglycoside of the general formula (I), R1O—[G]p  (I) wherein R1 represents an alk(en)yl radical having from 4 to 22 carbon atoms, G represents a sugar radical having 5 or 6 carbon atoms and p represents a number from 1 to 10; and (ii) at least one nonionic surfactant of the general formula (II) R2O(CH2CHRO)xH  (II) wherein x represents a number of from 1 to 30, each R independently represents a substituent selected from the group consisting of a hydrogen, a methyl group and an ethyl group, and R2 represents a linear alkyl radical having from 16 to 22 carbon atoms; and (b) up to 6% by weight, based on the weight of the surfactant mixture, of one or more anionic surfactants; are described.
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: November 2, 2004
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Manfred Weuthen, Karl Heinz Schmid
  • Patent number: 6812202
    Abstract: The invention relates to a highly alkaline or mildly alkaline detergent composition having enhanced cleaning properties. The detergent combines a source of alkalinity and a blend of nonionic surfactants that enhances cleaning starchy soils. The blend of nonionic surfactants preferably includes an alkyl polyglycoside surfactant and a silicon surfactant having a hydrophobic silicon group and a pendant hydrophilic group. Preferably, the blend of nonionic surfactants includes a surfactant having a hydrophobic group and an ethylene oxide residue containing group and a polymer additive. A method for removing soil from an article is provided.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: November 2, 2004
    Assignee: Ecolab Inc.
    Inventors: Victor F. Man, Terrence P. Everson, Steven E. Lentsch
  • Patent number: 6805135
    Abstract: A cleaning solution is used to remove a byproduct derived from a decomposed substance of a process gas containing C and F. The cleaning solution contains 75 wt % N-methyl-2-pyrrolidone, 15 wt % ethylene glycol monobutyl ether, 0.5 wt % surfactant, and 9.5 wt % water. The content of an alkali metal in the cleaning solution is set to be less than 10 ppb.
    Type: Grant
    Filed: November 24, 2000
    Date of Patent: October 19, 2004
    Assignees: Nittou Chemical Industries, Ltd., Tokyo Electron Limited
    Inventors: Kenichi Hirota, Hitoshi Yamada, Kiyoshi Yuasa, Eiji Yamaguchi, Shinichi Kawaguchi, Takahiro Shimoda, Nobuyuki Nagayama
  • Patent number: 6805141
    Abstract: A rinse agent composition containing: (a) a gemini surfactant corresponding to formula I: R—CHOH—CH2—[OCH2CH2]x—O—CH2—CHOH—R  (I) wherein R is a linear or branched alkyl and/or alkenyl radical having from about 4 to 22 carbon atoms, and x is a number from about 5 to 90; and (b) a fatty alcohol alkoxylate corresponding to formula II: R1O[CH2(CH3)CHO]q(CH2CH2O)rH  (II) wherein R1 is a linear or branched alkyl and/or alkenyl group having from about 4 to 22 carbon atoms, and q is a number up to about 10, and r is a number from about 1 to 50, and wherein (a) and (b) are present in the composition in a ratio by weight of from about 1:1 to 4:1.
    Type: Grant
    Filed: December 12, 2002
    Date of Patent: October 19, 2004
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Michael Elsner, Ditmar Kischke, Manfred Weuthen
  • Patent number: 6802870
    Abstract: A solventless cleaning and treating composition for carpet is described. The composition comprises an aqueous solution of a stainblocking polymer, a silsesquioxane anti-soiling polymer, a surfactant and optionally a sequesting agent or salt.
    Type: Grant
    Filed: December 3, 2003
    Date of Patent: October 12, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: John C. Chang, Robert F. Deutsch
  • Patent number: 6797687
    Abstract: Mixtures comprising: (a) a gemini surfactant of the formula (I) R1—CHOH—CH2—[OCH2CH2]x—O—CH2—CHOH—R  (I) wherein each of R and R1 is a linear or branched alkyl and/or alkenyl group having from 4 to 22 carbon atoms and x is a number from about 5 to about 400; (b) polyethylene glycol are useful as components in laundry detergents, dishwashing detergents and cleaners and for improving the wetting behavior on various surfaces.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: September 28, 2004
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Ditmar Kischkel, Hans-Christian Raths, Manfred Weuthen, Michael Elsner
  • Patent number: 6797011
    Abstract: Compositions which are used directly in the conventional home laundry machine to clean and renourish articles made from leather, textile and synthetic leather. Specifically, two separate compositions are used during a typical washing cycle in the home washing machine. First, the leather laundry solution is added during the “wash cycle.” Subsequently a laundry rinse and dressing composition is added to the finishing rinse cycle of the washing machine. The composition may also be used as a wipe-on application after laundering.
    Type: Grant
    Filed: December 5, 2002
    Date of Patent: September 28, 2004
    Inventor: Anna Carner Blangiforti
  • Patent number: 6794349
    Abstract: A built particulate laundry detergent composition containing anionic sulphonate or sulphate surfactant and conventional ethoxylated alcohol nonionic surfactant also contains a low level of a highly ethoxylated alcohol nonionic surfactant having an average degree of ethoxylation of from 15 to 40. The composition exhibits increased mildness to the skin without loss of detergency performance.
    Type: Grant
    Filed: October 10, 2002
    Date of Patent: September 21, 2004
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Rudolfus Johannes Hafkamp, Rob Menting
  • Patent number: 6794345
    Abstract: The invention relates to gemini surfactants, optionally in combination with ingredients customary in dishwashing detergents and cleaners, optionally with further nonionic surfactants and anionic surfactants, and to the use of such gemini surfactants for improving the wetting behavior and the compatibility with plastics, for the simplified preparation of solid cleaners and as foam-suppressing surfactant in rinse aid formulations.
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: September 21, 2004
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Michael Elsner, Manfred Weuthen, Hans-Christian Raths
  • Patent number: 6784146
    Abstract: The present invention is a deinking method and composition that uses at least 50% by weight based on the total weight of surfactants of non-ionic, C16 to C25 aliphatic, monohydric alcohol alkoxylates having 14 to 40 moles of ethylene oxide per mole of alcohol and 0 to 10 moles of propylene oxide per mole of alcohol. Using deinking compositions to deink wastepaper pulp wherein the surfactants primarily include the C16 to C18 aliphatic alcohol alkoxylates of the invention produces paper having excellent brightness and low effective residual ink concentrations. In addition, a low amount of sizing agents is used to produce paper having acceptable levels of water repellency.
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: August 31, 2004
    Assignee: Kemira Chemicals, Inc.
    Inventors: Jing Luo, David D. Dreisbach, Michael Lease Hemenway
  • Patent number: 6777384
    Abstract: The invention relates to gemini surfactants, optionally in combination with ingredients customary in laundry detergents, dishwashing detergents and cleaners, optionally with further nonionic surfactants and anionic surfactants, and to the use of such gemini surfactants for improving the wetting behavior and the compatibility with plastics, for the simplified preparation of solid cleaners and as foam-suppressing surfactant in rinse aid formulations.
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: August 17, 2004
    Assignee: Cognis Deutschland GmbH & Co., KG
    Inventors: Hans-Christian Raths, Manfred Weuthen, Michael Elsner
  • Patent number: 6759380
    Abstract: A built laundry detergent composition contains a combination of anionic, nonionic and cationic surfactants which includes a highly ethoxylated nonionic surfactant which is a C8-C16 alcohol ethoxylated with an average of from 20 to 50 ethylene oxide groups. The cationic surfactant may advantageously be an ethoxylated quaternary ammonium compound. The composition exhibits improved oily soil detergency.
    Type: Grant
    Filed: September 12, 2003
    Date of Patent: July 6, 2004
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Amrat Paul Singh, David Christopher Thorley
  • Patent number: 6756351
    Abstract: Cleaning packets containing laundry detergents are comprised of a water-soluble container or a water-insoluble container comprising a compound of the formula (I) wherein R1 is a linear or branched alkyl radical having from 2 to 18 carbon atoms, R2 is hydrogen or a linear or branched alkyl radical having from 2 to 18 carbon atoms, R3 is hydrogen or methyl, R4 is a linear or branched, alkyl and/or alkenyl radical having from 1 to 22 carbon atoms and n is a number from 1 to 50, with the proviso that the sum of the carbon atoms in the radicals R1 and R2 is at least 6. The cleaning packets exhibit improved washing performance.
    Type: Grant
    Filed: October 17, 2002
    Date of Patent: June 29, 2004
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventor: Manfred Weuthen
  • Patent number: 6753306
    Abstract: A germicide and disinfectant composition contains detergent and at least two enzymes adapted to cause lysis in glycoprotein in infectious agents. These germicidal and disinfectant compositions are used in conjunction with prepackaged wipes and kits that allows the user to remove liquid or dried contaminated material without coming into direct contact with the contaminated material.
    Type: Grant
    Filed: June 3, 2002
    Date of Patent: June 22, 2004
    Inventor: Joseph J. Simpson
  • Patent number: 6746997
    Abstract: A process for the preparation of mixed ethoxylated alkyl phenol/alkyl phenol ethoxy sulfate surfactants, such surfactants, and detergent formulations incorporating the same. The mixed surfactants are more tolerant of sodium carbonate, allowing greater amounts of sodium carbonate to be used so that the amount of surfactant can be reduced resulting in overall cost savings in the resultant laundry product.
    Type: Grant
    Filed: September 3, 2002
    Date of Patent: June 8, 2004
    Assignee: Church & Dwight Co., Inc.
    Inventors: Charles D. Carr, Archana Gupta