Sulfur-containing, Anionically Substituted Surfactant Patents (Class 510/357)
  • Patent number: 11932828
    Abstract: The need for a liquid hand-dishwashing composition which provides further improved sudsing volume and longevity when washing dishware using diluted liquid hand dishwashing compositions, especially in the presence of greasy soil and particulate soil, while still providing the desired cleaning, is met when the composition is formulated with a surfactant system comprising a specific level of alkyl sulfate surfactant and a co-surfactant, when the alkyl chain of the alkyl sulfate anionic surfactant has a mol fraction of C12 and C13 chains of at least about 50%, and the C13/C12 mol ratio of the alkyl chain is at least about 57/43.
    Type: Grant
    Filed: December 9, 2021
    Date of Patent: March 19, 2024
    Assignee: The Procter & Gamble Company
    Inventors: Jan Julien Marie-Louise Billiauw, Kristof Crets, Phillip Kyle Vinson
  • Patent number: 11851634
    Abstract: A detergent composition includes: A. a co-polymer of diallyldimethylammonium chloride and acrylic acid in an amount of from about 0.05 to about 1 weight percent actives; B. sodium and/or potassium chloride in an amount of greater than about 0.5 up to about 5 weight percent actives; C. a surfactant component in an amount of from about 8 to about 30 weight percent actives and comprising: (1) an alcohol ethoxy sulfate in an amount of from about 0 to about 60 weight percent actives; (2) an alkoxylated alcohol in an amount of from about 0 to about 90 weight percent actives; (3) a linear alkylbenzene sulfonate in an amount of from about 0 to about 90 weight percent actives; wherein at least two of said (1) alcohol ethoxy sulfate, said (2) alkoxylated alcohol, and said (3) linear alkylbenzene sulfonate are present in an amount of greater than zero; and D. water.
    Type: Grant
    Filed: December 15, 2020
    Date of Patent: December 26, 2023
    Assignee: HENKEL IP & HOLDING GMBH
    Inventor: Daniel Thomas Piorkowski
  • Patent number: 11814604
    Abstract: The invention discloses synergistic combinations of surfactant blends and cleaning compositions employing the same. In certain embodiments a surfactant system is disclosed which includes an extended anionic surfactant with novel linker surfactants including one or more of an alkyl glycerol ether, an ethoxylated alkyl glycerol ether, an alcohol ethoxylate and/or a Gemini surfactant. This system forms emulsions with, and can remove greasy and oily stains, even those comprised of non-trans fats. The compositions may be used alone, as a pre-spotter or other pre-treatment or as a part of a soft surface or hard surface cleaning composition.
    Type: Grant
    Filed: March 23, 2022
    Date of Patent: November 14, 2023
    Assignee: ECOLAB USA INC.
    Inventors: Victor Fuk-Pong Man, Derrick Richard Anderson, Yvonne Marie Killeen
  • Patent number: 11708542
    Abstract: The disclosure relates to products including a polysaccharide derivative wherein the polysaccharide derivative includes a polysaccharide substituted with at least one of: a) at least one sulfate group; b) at least one sulfonate group; c) at least one thiosulfate group; or d) a combination thereof; wherein the polysaccharide is poly alpha-1,3-glucan, poly alpha-1,6-glucan, poly alpha-1,3-1,6-glucan, or a mixture thereof; and the polysaccharide derivative has a degree of substitution of about 0.001 to about 3. The products can be useful as anti-deposition and/or anti-graying agents in laundry detergents, and in home care applications.
    Type: Grant
    Filed: June 19, 2019
    Date of Patent: July 25, 2023
    Assignee: The Procter & Gamble Company
    Inventors: Mark Robert Sivik, Zhengzheng Huang, Helen S. M. Lu, Rakesh Nambiar, Jayme L. Paullin
  • Patent number: 11685880
    Abstract: The present disclosure describes a peroxide based cleaning composition comprising a peroxide; a builder; a surfactant; a peroxide stabilizer; and remainder water and optional adjuvant. In various embodiments, the cleaning composition comprises hydrogen peroxide, sodium bicarbonate, a vegetable fatty acid potassium soap, glycerin, water and essential oil. The peroxide based cleaning composition exhibits storage stability for up to about 9-months and provides cleaning efficacy on a wide variety of hard surfaces and fabrics.
    Type: Grant
    Filed: March 17, 2020
    Date of Patent: June 27, 2023
    Assignee: Distinctive Cleaning and Maintenance Services Incorporated
    Inventor: Dori Stolmaker
  • Patent number: 11357718
    Abstract: Provided is a polymer-based antimicrobial composition that is non-toxic, water soluble, and that mitigates the transmission of infectious diseases from surfaces. The composition comprises a cationic polymer, at least one adhesion promoter, optionally organic and/or inorganic particles that are photocatalytically active in visible light, and a carrier, in which the components of the composition are not covalently bound to one another. Also provided is an antimicrobial composition that comprises at least (i) a polyethylenimine-based polymer and a carrier or (ii) an organic and/or inorganic particle that is photocatalytically active in visible light, an adhesion promoter, and a carrier. The antimicrobial compositions can be applied to disinfect a surface and to form residual self-sanitizing films on the surface that are removable.
    Type: Grant
    Filed: September 4, 2018
    Date of Patent: June 14, 2022
    Assignee: eXion labs Inc.
    Inventors: Marion L. Chiattello, Mark Oman
  • Patent number: 11136532
    Abstract: The present invention relates to a hand dishwashing detergent composition including a surfactant system and at least one triblock co-polymer of Formula (I): (EO)x-(PO)y-(EO)x wherein each x is independently on average between about 1 and about 40, and y is on average between about 1 and about 15.
    Type: Grant
    Filed: November 21, 2018
    Date of Patent: October 5, 2021
    Assignee: The Procter & Gamble Company
    Inventors: Patrick Firmin August Delplancke, Robby Renilde Francois Keuleers, Nuray Yaldizkaya
  • Patent number: 10941370
    Abstract: The present disclosure relates to textile care agents and to optically clear and transparent fabric softener formulations which also have a viscous consistency, containing a combination of special ester quats with nonionic emulsifiers and cationic thickeners, to the use of said textile care agents and fabric softener formulations. The present disclosure also relates to a method for washing textiles using said textile care agent and fabric softener formulations. The present disclosure relates to methods for producing the special ester quats, to the thus resulting ester quats and to the use thereof.
    Type: Grant
    Filed: July 15, 2015
    Date of Patent: March 9, 2021
    Assignees: Henkel AG & Co. KGaA, BASF SE
    Inventors: Tatiana Schymitzek, Simon Pluszynski, Ulrich Platzbecker, Peter Schmiedel, Roland Ettl, Silvia Martinez Barrachina, Nuria Bonastre Gilabert, Maria Escoda Margenat
  • Patent number: 10800975
    Abstract: The present invention relates generally to methods for producing renewable detergent compounds. More specifically, the invention relates to methods for producing detergent intermediates, including bio-linear alkylbenzene (LAB), bio-alcohols, and long chain bio-paraffins, from natural oils.
    Type: Grant
    Filed: May 7, 2018
    Date of Patent: October 13, 2020
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey John Scheibel, Scott Leroy Cron, Stephen Anthony Derose, Ryan Michael West, Phillip Kyle Vinson, Thomas Earl Williams, Kevin Lee Garber, Praveen Kumar Depa
  • Patent number: 10113138
    Abstract: A process for scouring textile materials is provided. The process comprising contacting the textile material with scouring textile materials, comprising contacting the textile materials with a composition comprising an alkyl alkoxylate sulfate of formula I, a nonionic alkyl alkoxylate of formula II, and water.
    Type: Grant
    Filed: December 11, 2013
    Date of Patent: October 30, 2018
    Assignee: Dow Global Technologies LLC
    Inventors: Cheng Shen, Jing Ji, Jianhai Mu, Xiaohua Wang
  • Patent number: 10066193
    Abstract: This invention relates to extend the benefits of using hypochlorite compounds such as sodium hypochlorite to clean and disinfect articles while reducing or eliminating the side effects of treating an article with a strong oxidant material. The invention relates to a single step process involving mixing of precursor compositions of a suitable hypohalite or hypohalous acid with a solution of a reducing agent. Optionally a buffer may be present in either or both precursor compositions, such that at time of use such active hypohalous acid concentration in the resulting aqueous mixture remains at a sufficient activity level to effect one or more desired benefits against a target substrate for a desired period of time. The oxidant is substantially consumed by reaction with the reducing agent after the time needed for achieving the desired benefit has passed.
    Type: Grant
    Filed: October 4, 2016
    Date of Patent: September 4, 2018
    Assignee: The Clorox Company
    Inventors: Dewain Garner, William L. Smith, Jared Heymann
  • Patent number: 9719049
    Abstract: A surfactant solution of the present invention includes a component (a): an ?-sulfonated fatty acid ester salt; a component (b): an alkanolamine; a component (c): an aromatic sulfonic acid; and a component (d): water, wherein the content of the component (a) is within a range from 30 to 45 mass %, the molar ratio represented by (b)/(a) is within a range from 0.05 to 0.5, and the molar ratio represented by (b)/(c) is within a range from 0.5 to 2.
    Type: Grant
    Filed: October 31, 2014
    Date of Patent: August 1, 2017
    Assignee: Lion Corporation
    Inventors: Atsunori Morigaki, Nobukazu Shogase
  • Patent number: 9446390
    Abstract: The present invention relates to a process for preparing acrylic acid comprising (i) providing a stream comprising a formaldehyde source and acetic acid and (ii) contacting this stream with an aldol condensation catalyst comprising a zeolitic material, wherein the framework structure of the zeolitic material in (ii) includes Si and O, and has a molar Al:Si ratio of 0:1 to 0.001:1, and wherein the framework structure of the zeolitic material in (ii), in addition to Si and any Al, comprises one or more elements selected from the group consisting of tetravalent elements Y other than Si and trivalent elements X other than Al.
    Type: Grant
    Filed: May 28, 2015
    Date of Patent: September 20, 2016
    Assignee: BASF SE
    Inventors: Andrei-Nicolae Parvulescu, Armin Lange De Oliveira, Michael Lejkowski, Nicolai Tonio Woerz, Marco Hartmann, Kazuhiko Amakawa, Michael Goebel, Ulrich Mueller, Mathias Feyen, Yong Liu
  • Patent number: 9371506
    Abstract: An aqueous cleaning composition comprising a surfactant, a polyamine, and propylene glycol. The combination of the polyamine and propylene glycol will provide low residue and increased shine during wet and dry wiping and will provide anti-fog properties to a substrate after cleaning. The use of either the polyamine alone or the propylene glycol alone will not provide results meeting all three tests.
    Type: Grant
    Filed: February 17, 2012
    Date of Patent: June 21, 2016
    Assignee: Colgate-Palmolive Company
    Inventors: Patrick Diet, Marcel Gillis
  • Patent number: 9365811
    Abstract: A process to manufacture large coated detergent particles having perpendicular dimensions x, y and z, wherein x is from 0.2 to 2 mm, y is from 2.5 to 8 mm, and z is from 2.5 to 8 mm the particles being substantially the same shape and size as one another and the uncoated core particles comprising at least 50 wt % of soluble surfactant, the process comprising the steps of suspending uncoated core particles in a fluidized bed and spraying onto the core particles an aqueous slurry of sodium carbonate in admixture with 0.6 to 3 wt % sodium carboxy methyl cellulose and drying to form the coated particles.
    Type: Grant
    Filed: August 10, 2011
    Date of Patent: June 14, 2016
    Assignee: Conopco Inc.
    Inventors: Judith Maria Bonsall, Philip Ronald Moore
  • Patent number: 9309435
    Abstract: The invention relates to compositions and methods of treatment employing compositions comprising polyelectrolyte complexes. The compositions include a water-soluble first polyelectrolyte bearing a net cationic charge or capable of developing a net cationic charge and a water-soluble second polyelectrolyte bearing a net anionic charge or capable of developing a net anionic charge. The total polyelectrolyte concentration of the first solution is at least 110 millimolar. The composition is free of coacervates, precipitates, latex particles, synthetic block copolymers, silicone copolymers, cross-linked poly(acrylic) and cross-linked water-soluble polyelectrolyte. The composition may be a concentrate, to be diluted prior to use to treat a surface.
    Type: Grant
    Filed: February 21, 2013
    Date of Patent: April 12, 2016
    Assignee: The Clorox Company
    Inventors: David R. Scheuing, Thomas F. Fahlen, Jared Heymann, Mike Kinsinger, William Ouellette, William L. Smith
  • Patent number: 9296942
    Abstract: Compositions and methods of synthesis of anionic surfactants by alkoxylation of a Guerbet alcohol (GA) having 12 to 36 carbon atoms using butylene oxide, and optionally propylene oxide and/or ethylene oxide followed by the incorporation of a terminal anionic group are described herein. The GA of the present invention is made by a facile and inexpensive method that involves high temperature base catalyzed dimerization of alcohols with 6 to 18 carbon atoms. The large hydrophobe ether surfactants of the present invention find uses in enhanced oil recovery (EOR) applications where it is used for solubilization and mobilization of oil and for environmental cleanup. Further, the hydrophobe alkoxylated GA without anionic terminal group can be used as an ultra-high molecular weight non-ionic surfactant.
    Type: Grant
    Filed: March 7, 2014
    Date of Patent: March 29, 2016
    Assignees: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM, BASF SE
    Inventors: Upali P. Weerasooriya, Gary A. Pope, Christian Bittner, Gunter Oetter, Jack F. Tinsley, Christian Spindler, Gabriela Alvarez Jurgenson, Sophie Vogel
  • Patent number: 9145509
    Abstract: The present invention relates to a process for mineral oil extraction by means of Winsor type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least three ionic surfactants which are different with regard to the alkyl moiety (R1)(R2)—CH—CH2— and are of the general formula (R1)(R2)—CH—CH2—O-(D)n-(B)m-(A)l-XYa?a/bMb+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to surfactant formulations of ionic surfactants of the general formula.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: September 29, 2015
    Assignee: BASF SE
    Inventors: Christian Bittner, Günter Oetter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel, Petra Neumann, Veronika Wloka, Martin Bock
  • Patent number: 9051535
    Abstract: Disclosed herein are compositions containing enzymes, particularly acting at the interface between two immiscible phases where the rate of enzymatic activity is increased by addition of a blend of surfactant(s) and a mixture derived from yeast fermentation, that contain non-enzymatic exo-proteins released by yeast in response to a non-lethal stress. The enzymes include those that work at the interface between an aqueous solution and a water immiscible phase, liquid or solid, such as oil, fat, cellulose, lignin, etc. including, but not limited to the following or combinations thereof: lipases, polysaccharase, lignase, cellulase and the like, in which the substrate of an enzymatic reaction forms a phase, segregated from the aqueous solution in which the enzymes are typically operating.
    Type: Grant
    Filed: March 26, 2013
    Date of Patent: June 9, 2015
    Assignee: ADVANCED BIOCATALYTICS CORPORATION
    Inventors: Michael G. Goldfeld, Andrew H. Michalow, Carl W. Podella, John W. Baldridge
  • Publication number: 20150140311
    Abstract: A method is provided for removing a volatile organic compound (VOC) contained in an artificial leather fabric and odor caused by the volatile organic compound by coating the artificial leather fabric with an adsorbent which reacts with a noxious substance containing the volatile organic compound (VOC); and immersing; washing; and drying the reacted artificial leather fabric. The method includes coating the adsorbent and immobilizing the volatile organic compound through a reaction, to prevent volatilization of the organic compound or reduce an amount thereof. Further, after the reaction between the artificial leather fabric and the adsorbent, the artificial leather fabric is washed, to remove the volatile organic compound immobilized on a surface of the fabric from the artificial leather.
    Type: Application
    Filed: September 3, 2014
    Publication date: May 21, 2015
    Applicants: KOLONGLOTECH. INC., HYUNDAI MOTOR COMPANY
    Inventors: Gun Kang, Hyun Joo Seo, Mi Jung Yun, Dae Seok Choi, Yong Tae Ha, Min Jeong Kim, Ju Ahn Kim, Ki Eop Kim, Yoon Jung Kwon, Shin Hyouk Kang
  • Patent number: 9034811
    Abstract: Concentrated cleaning formulations for removing debris from hard surfaces and textile surfaces. An exemplary formulation includes a mixture of the following chemical components, in specified proportions: glycerin; monopropylene glycol; triethylene glycol methyl ether; a non-ionic surfactant; an emulsifier; soya methyl ester or canola methyl ester, or both; and hydroxypropyl sulfonate; The formulation is free of water other than insignificant amounts present in the chemical components combined to make the mixture. Combining the formulation with water causes a temperature of the combination to increase above the temperatures of the water and the formulation before combining.
    Type: Grant
    Filed: November 8, 2013
    Date of Patent: May 19, 2015
    Inventors: David Edward Molnar, Peter McLean Harrison
  • Publication number: 20150133358
    Abstract: A bleach-free laundry detergent composition containing zero-valent iron nanoparticles. A small amount of nanoparticles with a size range of about 100 nm to about 500 nm replace the bleach and consequently the bleach activator in the laundry detergent composition. These nanoparticles are capable of oxidization which makes them an appropriate alternative for the bleach in a laundry detergent.
    Type: Application
    Filed: November 8, 2014
    Publication date: May 14, 2015
    Applicant: Tolypers Company
    Inventors: Mohammadreza Khanmohammadi Khorrami, Masumeh Rostami arbastan, Fatemeh Abdi
  • Patent number: 8993504
    Abstract: The present invention provides an oxidation catalyst for bleaching containing a component (a) which is an anion caused from a chelating agent having less than or equal to coordination position 5 and/or the chelating agent, and a component (b) which is a copper and/or manganese compound; and a binder compound (c); a hydrogen peroxide-based compound (d) which dissolves in water and generates hydrogen peroxide, the bleaching composition containing a granulated product or a molded product in which at least the component (b) and the component (c) are granulated or molded together. According to the invention, an oxidation catalyst that promotes the oxidation effect of hydrogen peroxide-based compounds with a trace amount of the composition, and has excellent effects of suppressing the decomposition of hydrogen peroxide-based compounds and suppressing coloration of the catalyst itself, and a bleaching composition containing the oxidation catalyst can be utilized.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: March 31, 2015
    Assignee: LION Corporation
    Inventors: Takayasu Kubozono, Tomonari Suekuni, Yosuke Kono, Yukiko Iwasa, Hideyuki Kaneda, Yukihiro Dannoue, Hiroaki Hara, Yasushi Hirata
  • Patent number: 8987179
    Abstract: The invention relates to compositions containing a) 45 to 65 wt. % of one or more secondary paraffin sulfonates with 8 to 22 carbon atoms, b) 1 to 10 wt. % of one or more alcohol alkoxylates which are produced from the reaction of alcohols R—OH, wherein R is an alkyl group with 4 to 8 carbon atoms, with alkoxylating agents selected from ethylene oxide, propylene oxide, or mixtures thereof and which contain on average 1 to 10 mol of structural units derived from the alkoxylating agents per 1 mol of structural units derived from the alcohols, and c) 25 to 52 wt. % water, in relation to the total weight of the composition in each case. The compositions can be used in an advantageous manner for producing washing and cleaning agents.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: March 24, 2015
    Assignee: Weylchem Switzerland AG
    Inventors: Johannes Himmrich, Wolfgang Walther
  • Patent number: 8969280
    Abstract: The present invention is directed to visually contrasting aesthetic particles having increased water solubility, particularly useful for combination with granular laundry detergent composition.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: March 3, 2015
    Assignee: The Procter & Gamble Company
    Inventors: Richard Lock, Michael Pickstock
  • Patent number: 8940681
    Abstract: The present invention improves dye transfer inhibition in the washing of textiles by the use of SO3M substituted urea derivatives of aromatic amines.
    Type: Grant
    Filed: August 21, 2014
    Date of Patent: January 27, 2015
    Assignee: Henkel AG & Co. KGaA
    Inventors: Mareile Job, Birgit Gluesen, John Taylor, Anthony Lawrence
  • Patent number: 8889611
    Abstract: The invention relates to compounds in solid form, containing a) one or more manganese complex compounds of the general formula (1), where M is independently selected from manganese in the III or IV oxidation state, X is independently a co-ordinating or bridging species selected from H2O, O22?, O2?, O2?, OH?, HO2?, SH?, S2?, SO, Cl?, N3?, SCN?, N3?, RCOO?, NH2? and NR3, where R is a radical selected from H, alkyl and aryl, L are independently organic ligands, each of which contains at least two nitrogen atoms co-ordinated on manganese, z is an integer from ?4 to +4, Y is a monovalent or multivalent counter-ion selected from chloride, sulphate, hydrogen sulphate, nitrate and acetate, which leads to charge neutrality of the complex, and q is an integer from 1 to 4, and b) one or more salts of the general formula R?—C6H4—SO3Me, where R? is CH3 or C2H5 and denotes Me, Na, K, Ca or Mg, characterized in that the molar ratio of the manganese complex compound of the general formula (1) to salt of the general formula R
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: November 18, 2014
    Assignee: Clariant International Ltd
    Inventors: Gerd Reinhardt, Michael Best
  • Patent number: 8865638
    Abstract: It has been found that by incorporating a polymer made from vinyl dicarboxylic acid monomers into a liquid laundry detergent composition, the composition can include at least about 30 wt. % water, and be useful in a liquid-containing water-soluble unit dose pouch.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: October 21, 2014
    Assignee: Church & Dwight Co., Inc.
    Inventor: Steven T. Adamy
  • Patent number: 8846596
    Abstract: Liquid cleaning compositions are described herein that include a metal bleach catalyst which is a complex of a transition-metal and a macrocyclic ligand, the ligand having a calculated Octanol/Water Partition Coefficient value of from about ?1.50 to about ?0.10, a formulation enabling fraction comprising at least one formulation enabling ingredient, the formulation enabling fraction having a Hydrophilic Index of from about 4.0 to about 10.0, and a formulation deactivating fraction comprising at least one formulation deactivating ingredient that has a calculated Octanol/Water Partition Coefficient value of from about ?3.5 to about ?0.10.
    Type: Grant
    Filed: February 16, 2012
    Date of Patent: September 30, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Robert Richard Dykstra, Mario Elmen Tremblay, Xiaoru Jenny Wang, James Lee Danziger, Daniel Dale Ditullio, Jr., Consuelo Kong, Ismael Cotte-Rodriguez
  • Patent number: 8841247
    Abstract: This disclosure relates to detergent compositions containing pyridinol-N-oxide compounds and being substantially free of bleach. Methods for treating a stained fabric using such detergent compositions are also disclosed.
    Type: Grant
    Filed: August 15, 2012
    Date of Patent: September 23, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Gregory Scot Miracle, Bruce Prentiss Murch, Patrick Christopher Stenger, Charles Allen Pettigrew, Jr., Justin Angelo Caserta, Casey Patrick Kelly
  • Patent number: 8835374
    Abstract: The present invention relates to a process to prepare external structuring system(s) (ESS) comprising crystallized triglycerides including crystallized hydrogenated castor oil (HCO) and packing parameter adjusting agent to provide higher structuring ability. The present invention also relates to laundry detergent compositions in liquid or gel form comprising ESS.
    Type: Grant
    Filed: August 12, 2013
    Date of Patent: September 16, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Vincenzo Guida, Joris Meert
  • Patent number: 8802613
    Abstract: The present invention is directed to a stabilized hydrogen peroxide solution containing stabilizers that maintain relatively high hydrogen peroxide stability in both concentrated form and when formulated into a cleaning solution that has a pH above 6 and contains components that normally would have a destabilizing effect on the hydrogen peroxide. The stabilizers include a first cyclic amino methane diphosphonic acid compound stabilizer in combination with a second phosphonic acid based stabilizer (different from the cyclic amino methane diphosphonic acid compound), wherein the weight ratio of the first stabilizer to the second stabilizer is at least about 2:1.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: August 12, 2014
    Assignee: Akzo Nobel N.V.
    Inventors: David J. Bonislawski, David C. Lovetro
  • Patent number: 8785363
    Abstract: The invention discloses synergistic combinations of surfactants blends and cleaning composition. In certain embodiments a surfactant system is disclosed which includes extended anionic surfactants, linker surfactants, and a multiply charged cation component. This system forms emulsions with, and can remove greasy and oily stains, even those comprised of non-trans fats. In another embodiment anionic surfactants are combined with a solvent, and amine oxide to remove sunscreen stains. The compositions may be used alone, as a pre-spotter or other pre-treatment or as a part of a soft surface or hard surface cleaning composition.
    Type: Grant
    Filed: October 23, 2013
    Date of Patent: July 22, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Victor Fuk-Pong Man, Michael Charles DeNoma, Yvonne Marie Killeen, Steven E. Lentsch
  • Patent number: 8785364
    Abstract: Dual-usage aqueous liquid detergent compositions having suds compatability and improved cleaning, said composition containing from about 1% to about 60%, by weight of the composition, of a surfactant system wherein said surfactant system contains at least 35%, by weight of the surfactant system, of alkylethoxysulfate; from 0% to about 10%, by weight of the surfactant system, of nonionic surfactant; from 0% to about 10%, by weight of the surfactant system, of soap; further contains from about 0.001% to about 4.0%, by weight of the composition, of an anti-foam selected from organomodified silicone polymers with aryl or alkylaryl substituents combined with silicone resin and the primary filler is modified silica; and mixtures thereof; and contains from about 0.01% to about 2.5%, by weight of the composition, of a structurant. Methods of using such detergent compositions for laundering textiles.
    Type: Grant
    Filed: June 21, 2013
    Date of Patent: July 22, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Eugene Steven Sadlowski, Shari Joy Soper
  • Patent number: 8729007
    Abstract: An acidic laundry detergent composition comprising less than about 20% of a surfactant system comprising surfactants selected from the group consisting of anionic surfactants, nonionic surfactants, cationic surfactants and mixtures thereof, wherein the surfactant system has a Hydrophilic Index of greater than or equal to about 9.00 and an organic acidulant at a level such that the ratio of surfactant system to organic acidulant is less or equal to about 3.0 and an alkaline neutralizer added in an amount necessary to raise the neat pH of the detergent composition above or equal to about 2.5 but no higher than or equal to about 3.0.
    Type: Grant
    Filed: January 17, 2013
    Date of Patent: May 20, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Eugene Steven Sadlowski, Cheyne Thomas, Peter De Nies, Nilgun Esin Aksoy
  • Patent number: 8722610
    Abstract: An auto-emulsifying cleaning composition capable of emulsifying upon contact with water, the composition in one typical embodiment comprising, based on the total weight of the composition, (a) from about 1% to about 99% by weight a blend of dibasic esters; (b) from about 1% to about 40% by weight of a blend of surfactants consisting of an organic anion neutralized with an organic cation, where either or both of the anion and the cation have surfactant properties, and the complex of which is soluble in the dibasic ester solvent blend. The blend of surfactants is typically a cationic surfactant and an anionic surfactant, which may or may not be used in conjunction with non-ionic surfactants. The dibasic esters are be derived from a blend of adipic, glutaric, and succinic diacids, and, in one particular embodiment, the blend comprises dialkyl adipate, dialkyl methylglutarate and dialkyl ethylsuccinate, wherein the alkyl groups individually comprise a C1-C12 hydrocarbon group.
    Type: Grant
    Filed: October 19, 2010
    Date of Patent: May 13, 2014
    Assignee: Rhodia Operations
    Inventors: Amit Sehgal, Cecile Lara, Ashwin Rao, Charles Aymes
  • Patent number: 8691741
    Abstract: The present invention provides a liquid detergent composition containing the following components (a) to (c), wherein the total content of components (a) to (c), (a)+(b)+(c), is 40 to 90% by mass; a mass ratio of components (a) to (b), (a)/(b), is 25/75 to 90/10; and a mass ratio [(a)+(b)]/(c), is 95/5 to 70/30: component (a): 15 to 75% by mass of a nonionic surfactant produced by adding p1 mol of ethylene oxide to a compound represented by R—OH (wherein, R represents a hydrocarbon group having 8 to 18 carbon atoms), then adding q1 mol of an alkylene oxide having 3 to 5 carbon atoms, and then adding p2 mol of ethylene oxide, wherein p1 is the number of 3 to 30, q1 is the number of 1 to 5, and p1+p2 is 14 to 50, component (b): anionic surfactant, component (c): cationic surfactant, component (d): 5 to 40% by mass of water-miscible organic solvent.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: April 8, 2014
    Assignee: Kao Corporation
    Inventors: Hitoshi Ishizuka, Kyoko Okada, Yoshiyuki Komatsu, Toshio Miyake
  • Patent number: 8685913
    Abstract: The invention provides improvements in the primary detergency of detergents for washing textiles, particularly against oily stains and/or stains containing fat. These improvements are realized through the use of certain polycarbonate-, polyurethane-, and/or polyurea-polyorganosiloxane compounds or precursor compounds usable in the production thereof having certain reactive groups.
    Type: Grant
    Filed: September 29, 2009
    Date of Patent: April 1, 2014
    Assignee: Henkel AG & Co. KGAA
    Inventors: Nadine Warkotsch, Birgit Middelhauve, Marc-Steffen Schiedel, Konstantin Benda
  • Patent number: 8658590
    Abstract: Coated sodium percarbonate particles comprising a core of sodium percarbonate obtainable by fluidized bed buildup granulation, and a coating layer comprising sodium sulfate and sodium carbonate in a weight ratio of from 95:5 to 75:25 and in which the proportion of sodium sulfate and sodium carbonate is at least 80% by weight, effect as a detergent component an improved washing power of the detergent and exhibit a high storage stability in detergent formulations.
    Type: Grant
    Filed: July 4, 2007
    Date of Patent: February 25, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Stefan Leininger, Harald Jakob, Ulrike Kottke
  • Publication number: 20140033448
    Abstract: The present application relates to organosilicones and compositions such as consumer products comprising such organosilicones, as well as processes for making and using such organosilicones and such compositions. Such compositions comprising such organosilicones are easier to formulate, and provide more economical and superior care benefits when compared to current silicone containing compositions.
    Type: Application
    Filed: October 10, 2013
    Publication date: February 6, 2014
    Applicant: The Procter & Gamble Company
    Inventors: Rajan Keshav Panandiker, Steven Daryl Smith, Bernard William Kluesener, Mark Gregory Solinsky, Matthew Scott Wagner
  • Publication number: 20130345108
    Abstract: The present invention is directed to visually contrasting aesthetic particles having increased water solubility, particularly useful for combination with granular laundry detergent composition.
    Type: Application
    Filed: June 7, 2013
    Publication date: December 26, 2013
    Inventors: Richard Lock, Michael Pickstock
  • Publication number: 20130326824
    Abstract: A laundry detergent comprising a granulated foam control composition and an anionic detersive surfactant.
    Type: Application
    Filed: June 5, 2013
    Publication date: December 12, 2013
    Inventors: Nigel Patrick SOMERVILLE ROBERTS, Haiyan SONG, Jerome Macaisa CASTRO, Jacqueline L'HOSTIS, Stephanie LECOMTE
  • Patent number: 8580727
    Abstract: The invention discloses synergistic combinations of surfactants blends and cleaning composition. In certain embodiments a surfactant system is disclosed which includes extended anionic surfactants, linker surfactants, and a multiply charged cation component. This system forms emulsions with, and can remove greasy and oily stains, even those comprised of non-trans fats. In another embodiment anionic surfactants are combined with a solvent, and amine oxide to remove sunscreen stains. The compositions may be used alone, as a pre-spotter or other pre-treatment or as a part of a soft surface or hard surface cleaning composition.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: November 12, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Victor Fuk-Pong Man, Michael Charles DeNoma, Yvonne Marie Killeen, Steven Eugene Lentsch
  • Publication number: 20130288943
    Abstract: The present invention provides a coated lenticular or disc detergent particle having perpendicular dimensions x, y and z, wherein x is from 1 to 2 mm, y is from 2 to 8 mm and z is from 2 to 8 mm, wherein the particle comprises: (i) from 40 to 90 wt % surfactant selected from anionic surfactant and non-ionic surfactant; (ii) from 1 to 40 wt % water soluble inorganic salts; and (iii) from 0.0001 to 0.1 wt % pigment, wherein the pigment is selected from organic and inorganic pigments, wherein the inorganic salts are present on the detergent particle as a coating and the surfactant and the pigment are present as a core.
    Type: Application
    Filed: September 1, 2011
    Publication date: October 31, 2013
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley
  • Patent number: 8568490
    Abstract: The invention provides a liquid detergent composition containing (a) a nonionic surfactant obtained by adding ethylene oxide and an alkylene oxide with from 3 to 5 carbon atoms to a compound represented by R—OH (wherein R represents an alkyl group or an alkenyl group with from 8 to 18 carbon atoms) under a specified condition, (b) an anionic surfactant and (c) a water-miscible organic solvent in specified ratios, respectively.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: October 29, 2013
    Assignee: Kao Corporation
    Inventors: Toshio Miyake, Hitoshi Ishizuka, Kohei Nishida, Ayako Kita
  • Publication number: 20130281349
    Abstract: The present invention provides a coated lenticular or disc detergent particle having perpendicular dimensions x, y and z, wherein x is from 1 to 2 mm, y is from 2 to 8 mm and z is from 2 to 8 mm, wherein the particle comprises: (i) from 40 to 90 wt % surfactant selected from anionic surfactant and non-ionic surfactant; (ii) from 1 to 40 wt % water soluble inorganic salts; and (iii) from 0.0001 to 0.1 wt % dye, wherein the dye is covalently bound to from 1 to 4 sulphonate groups, wherein the inorganic salts and the dye are present on the detergent particle as a coating and the surfactant is present as a core.
    Type: Application
    Filed: September 1, 2011
    Publication date: October 24, 2013
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley
  • Publication number: 20130281351
    Abstract: The present invention provides a lenticular or disc coated detergent particle having perpendicular dimensions x, y and z, wherein x is from 1 to 2 mm, y is from 2 to 8 mm and z is from 2 to 8 mm, wherein the particle comprises: (i) from 40 to 90 wt % surfactant selected from anionic surfactant and non-ionic surfactant; (ii) from 1 to 40 wt % water soluble inorganic salts; and (iii) from 0.0001 to 0.5 wt % pigment, wherein the pigment is selected from organic and inorganic pigments, wherein the inorganic salts and the pigment are present on the detergent particle as a coating and the surfactant is present as a core.
    Type: Application
    Filed: September 1, 2011
    Publication date: October 24, 2013
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley
  • Publication number: 20130281348
    Abstract: The present invention provides a coated lenticular or disc detergent particle having perpendicular dimensions x, y and z, the particle comprises: (i) from 40 to 90 wt % surfactant selected from: anionic surfactant; and, non-ionic surfactant; (ii) from 1 to 40 wt % water soluble inorganic salts; (iii) from 0.0001 to 0.1 wt % dye, wherein the dye is selected: from anionic dyes; and, non-ionic dyes; and, (iv) from 0 to 3 wt % of perfume, wherein the inorganic salts and the dye are present on the detergent particle as a coating and the surfactant is present as a core.
    Type: Application
    Filed: September 1, 2011
    Publication date: October 24, 2013
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley, Jennifer Sian Roseblade
  • Publication number: 20130281350
    Abstract: The present invention provides a coated lenticular or disc detergent particle having maximum perpendicular dimensions x, y and z, wherein x is from 1 to 2 mm, y is from 2 to 8 mm, and z is from 2 to 8 mm, wherein the particle comprises: (i) from 40 to 90 wt % surfactant selected from: anionic surfactant; and, non-ionic surfactant; (ii) from 1 to 40 wt % water soluble inorganic salts; and, (iii) from 0.0001 to 0.1 wt % dye, wherein the dye is selected from: anionic dyes; and non-ionic dyes, wherein the inorganic salts are present on the detergent particle as a coating and the surfactant and the dye are present as a core.
    Type: Application
    Filed: September 1, 2011
    Publication date: October 24, 2013
    Inventors: Stephen Norman Batchelor, Andrew Paul Chapple, Stephen Thomas Keningley, Jennifer Sian Roseblade
  • Patent number: 8524648
    Abstract: The invention provides improvements in the color protection properties of detergents and cleaning agents during their utilization for washing or cleaning colored textile fabrics. Specific polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compounds or a precursor compound thereof containing specific reactive groups, which can be used for the production of the polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compounds, are utilized.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: September 3, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Nadine Warkotsch, Birgit Middelhauve, Marc-Steffen Schiedel, Thomas Eiting