Azeotropic Or Azeotrope-like Composition Patents (Class 510/408)
  • Patent number: 6013194
    Abstract: Compositions disclosed include hexafluoropropane and a hydrocarbon having from 1 to 5 carbon atoms or dimethyl ether. These compositions are useful as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: January 11, 2000
    Assignee: E.I. duPont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 6001273
    Abstract: Refrigerant compositions include mixtures of difluoromethane and isobutane, butane, propylene or cyclopropane; pentafluoroethane and propylene or cyclopropane; 1,1,2,2-tetrafluoroethane and propane; 1,1,1,2-tetrafluoroethane and cyclopropane; 1,1,1-trifluoroethane and DME or propylene; 1,1-difluoroethane and propane, isobutane, butane or cyclopropane; fluoroethane and propane or cyclopropane; 1,1,1,2,2,3,3-heptafluoropropane and butane, cyclopropane, DME, isobutane or propane; or 1,1,1,2,3,3,3-heptafluoropropane and butane, cyclopropane, isobutane or propane.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: December 14, 1999
    Inventors: Barbara Haviland Minor, Donald Bernard Bivens, Brooks Shawn Lunger
  • Patent number: 6001796
    Abstract: Provided are azeotropic and azeotrope-like mixtures of 1,1,1,3,3-pentafluoropropane (HFC-245fa) and hydrogen fluoride. Such are useful as an intermediate in the production of HFC-245fa. The latter is useful as a nontoxic, zero ozone depleting fluorocarbon useful as a solvent, blowing agent, refrigerant, cleaning agent, aerosol propellant, heat transfer medium, dielectric, fire extinguishing composition and power cycle working fluid.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: December 14, 1999
    Assignee: AlliedSignal Inc.
    Inventors: Hang Thanh Pham, Rajiv Ratna Singh, Ian Robert Shankland, Hsueh Sung Tung
  • Patent number: 5985939
    Abstract: The invention relates to the discovery of compositions useful as aerosol propellants that include a first component of butane or isobutane and a second component of 2-fluoropropane (HFC-281 ea) or 1-fluoropropane (HFC-282 fa).
    Type: Grant
    Filed: June 17, 1997
    Date of Patent: November 16, 1999
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 5968406
    Abstract: The azeotropic compositions of 1,1,2,2-tetrafluoroethane and 1,1-difluoroethane and the azeotropic and azeotropic-like composition of 1,1,2,2-tetrafluoroethane and one of, 1-chloro-1,1-difluoroethane, perfluorocyclobutane, n-butane, isobutane and 1,1,1,2,3,3,3-heptafluoropropane, and their use as refrigerants, aerosol propellants and blowing agents for polymer foams, are disclosed. The azeotropic and azeotrope-like compositions of 1,1,1,2-tetrafluoroethane and one of perfluorocyclobutane and 1,1,1,2,3,3,3-heptafluoropropane are also useful as fire extinguishants.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: October 19, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Philip Lee Bartlett, Donald Bernard Bivens, Brooks Shawn Lunger, Akimichi Yokozeki
  • Patent number: 5965511
    Abstract: In order to replace compositions based on CFC or on HCFC in applications for cleaning or drying solid surfaces (in particular defluxing), the invention proposes azeotropic or virtually azeotropic compositions based on 1,1,1,2,3,4,4,5,5,5-decafluoropentane, methylene chloride and optionally methanol.
    Type: Grant
    Filed: January 30, 1998
    Date of Patent: October 12, 1999
    Assignee: Elf Atochem S. A.
    Inventors: Pascal Michaud, Jean-Jacques Martin
  • Patent number: 5888250
    Abstract: A method for dry-cleaning garments which comprises treating them with an azeotropic solvent of propylene glycol tertiary-butyl ether and water.
    Type: Grant
    Filed: April 4, 1997
    Date of Patent: March 30, 1999
    Assignee: Rynex Holdings Ltd.
    Inventors: William A. Hayday, Stephen P. Bates
  • Patent number: 5866029
    Abstract: Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and at least one hydrocarbon selected from the group n-pentane, iso-pentane, cyclopentane, n-hexane and iso-hexane are provided. The compositions of the invention are useful in the preparation of polyurethane and polyisocyanurate foams.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: February 2, 1999
    Assignee: AlliedSignal Inc
    Inventors: Earl August Eugene Lund, Robert Christian Parker, Ian Robert Shankland
  • Patent number: 5851436
    Abstract: Compositions of nonafluoromethoxybutane and cyclopentane, nonafluoromethoxybutane and cyclohexane; nonafluoromethoxybutane, cyclopentane and acetone, nonafluoromethoxybutane, cyclohexane and acetone, nonafluoromethoxybutane, trans-1,2-dichloroethylene and cyclopentane; and nonafluoromethoxybutane, trans-1,2-dichloroethylene, cyclopentane and methanol are described. These compositions are useful as cleaning agents, displacement drying agents, refrigerants, heat transfer media, expansion agents for polyolefins and polyurethanes, aerosol propellants, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, and buffing abrasive agents.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: December 22, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Abid Nazarali Merchant, Barbara Haviland Minor, Shoeb Akberali Moiyadi
  • Patent number: 5834416
    Abstract: Binary azeotrope and azeotrope-like compositions contain the alkyl esters n-propyl acetate (NPA) and sec-butyl acetate (SBA) respectively, with hexamethyldisiloxane (MM), and are useful for cleaning, rinsing, or drying.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: November 10, 1998
    Assignee: Dow Corning Corporation
    Inventors: David Lee Morgan, Dwight Edward Williams
  • Patent number: 5827454
    Abstract: A mixed solvent composition, for cleaning electronic components, which consists essentially of dichloropentafluoropropane and 1,1,1,2,3,4,4,5,5,5-decafluoropentane.
    Type: Grant
    Filed: January 18, 1996
    Date of Patent: October 27, 1998
    Assignee: AG Technology Co., Ltd.
    Inventors: Kitamura Kenroh, Ikehata Michino, Tsuzaki Masaaki
  • Patent number: 5792277
    Abstract: Stabilized, n-propyl bromide containing cleaning solvent compositions and a cleaning process are provided. The cleaning solvent compositions include an alcohol selected from 1-propanol and 2-butanol, including mixtures thereof, as a co-solvent so as to form azeotropic or azeotropic-like mixtures which have no fire or flash points.
    Type: Grant
    Filed: July 23, 1997
    Date of Patent: August 11, 1998
    Assignee: Albemarle Corporation
    Inventors: Ronald L. Shubkin, Eric W. Liimatta
  • Patent number: 5788886
    Abstract: The present invention relates to compositions of pentafluoropropane and a fluorinated propane having from 1 to 5 fluorine atoms; a hydrocarbon having from 1 to 5 carbon atoms; 1,1,1,4,4,4-hexafluorobutane, (CF.sub.3).sub.2 CHCH.sub.3, dimethyl ether; or 1,1,1,2,3,4,4,5,5,5-decafluoropentane. The compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: May 5, 1997
    Date of Patent: August 4, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Tuneen E. C. Chisolm
  • Patent number: 5788877
    Abstract: Substantially constant boiling mixtures of difluoromethane and 1,1,1-trifluoroethane or perfluoroethane are useful as refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, and expansion agents for polymers.
    Type: Grant
    Filed: May 13, 1997
    Date of Patent: August 4, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Mark Brandon Shiflett
  • Patent number: 5785883
    Abstract: Refrigerant compositions include mixtures of difluoromethane and isobutane, butane, propylene or cyclopropane; pentafluoroethane and propylene or cyclopropane; 1,1,2,2-tetrafluoroethane and propane; 1,1,1,2-tetrafluoroethane and cyclopropane; 1,1,1-trifluoroethane and DME or propylene; 1,1-difluoroethane and propane, isobutane, butane or cyclopropane; fluoroethane and propane or cyclopropane; 1,1,1,2,2,3,3-heptafluoropropane and butane, cyclopropane, DME, isobutane or propane; or 1,1,1,2,3,3,3-heptafluoropropane and butane, cyclopropane, isobutane or propane.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: July 28, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Donald Bernard Bivens, Brooks Shawn Lunger
  • Patent number: 5772911
    Abstract: Compositions include compositions of 1,1,2,2,3,3,4,4-octafluorobutane and a hydrocarbon having from 3 to 7 carbon atoms. Specific examples include 1,1,2,2,3,3,4,4-octafluorobutane and butane, cyclopropane, isobutane, propane, cyclopentane, 2,2-dimethylbutane, n-pentane, 2-methylbutane, cyclohexane, 2,3-dimethylpentane, 3-ethylpentane, heptane, hexane or methylcyclopentane. Also included in this invention are compositions of 1,1,2,2,3,3,4,4-octafluorobutane and ethyl formate, propylene oxide, bis(pentafluoroethyl)sulfide, dimethoxyethane or tetrahydrofuran. These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: June 30, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Allen Capron Sievert
  • Patent number: 5766511
    Abstract: Use of near-azeotropic mixtures of hydrofluorocarbons with butane or isobutane selected from:A) 1,1,1,2-tetrafluoroethane (HFC-134a) 5-88% by wt1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) 12-95% by wtB) 1,1,1,2-tetrafluoroethane (HFC-134a) 10-87% by wt1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) 12-81% by wtn-butane 1-30% by wtC) 1,1,1,2-tetrafluoroethane (HFC-134a) 18-69% by wt1,1,1,2,3,3,3-heptafluoropropane (HFC 227ea) 30-81% by wtisobutane 1-30% by wtas propellant fluids for aerosol.Said mixtures have zero ODP, very low GWP, no or low inflammability, insignificant pressure loss during the use and good solubility towards the typical solvents of aerosol formulations.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: June 16, 1998
    Assignee: Ausimont S.P.A.
    Inventors: Ezio Musso, Giampiero Basile
  • Patent number: 5762818
    Abstract: Compositions are disclosed which include 1,1,2,2-tetrafluoroethane and a propane, tris(trifluoromethyl)amine, trifluoromethylsulfur pentafluoride or fluoroethane. The term propane includes compounds of the formula C.sub.3 F.sub.a H.sub.8-a wherein 0.ltoreq.a.ltoreq.8 as well as cyclic compounds of the formula C.sub.3 F.sub.b H.sub.6-b wherein 0.ltoreq.b.ltoreq.6. These compositions are useful as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: June 9, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Donna Marie Patron, Diana Lynn Klug, Brooks Shawn Lunger
  • Patent number: 5736062
    Abstract: Azeotrope-like mixtures, utilizable as refrigerating fluids in substitution of R-12 or R-502, constituted by hydrogen-(chloro)fluorocarbons, optionally in admixture with propane, cyclopropane or dimethylether.
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: April 7, 1998
    Assignee: Ausimont S.p.A.
    Inventors: Giampiero Basile, Ezio Musso
  • Patent number: 5733472
    Abstract: Compositions are disclosed which include 1,1,2,2-tetrafluoroethane and a propane, tris(trifluoromethyl)amine, trifluoromethylsulfur pentafluoride or fluoroethane. The term propane includes compounds of the formula C.sub.3 F.sub.a H.sub.8-a wherein 0.ltoreq.a.ltoreq.8 as well as cyclic compounds of the formula C.sub.3 F.sub.b H.sub.6-b wherein 0.ltoreq.b.ltoreq.6. These compositions are useful as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: March 31, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Donna Marie Patron, Diana Lynn Klug, Brooks Shawn Lunger
  • Patent number: 5730894
    Abstract: Compositions of 1,1,2,2,3,3,4,4-octafluorobutane and a compound of the formula selected from the group consisting of a 4-6 carbon linear or a cyclic hydrofluorocarbon or fluorocarbon, a 3-5 carbon fluoroether, a fluorinated alcohol, perfluoro-n-methylmorpholine; and an ether are disclosed.These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, in small turbine high speed compressors. They may also be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, displacement drying agents or as an anesthetic.
    Type: Grant
    Filed: April 16, 1996
    Date of Patent: March 24, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 5725791
    Abstract: The azeotropic compositions of 1,1,2,2-tetrafluoroethane and 1,1-difluoroethane and the azeotropic and azeotropic-like composition of 1,1,2,2-tetrafluoroethane and one of, 1-chloro-1,1-difluoroethane, perfluorocyclobutane, n-butane, isobutane and 1,1,1,2,3,3,3-heptafluoropropane, and their use as refrigerants, aerosol propellants and blowing agents for polymer foams, are disclosed. The azeotropic and azeotrope-like compositions of 1,1,1,2-tetrafluoroethane and one of perfluorocyclobutane and 1,1,1,2,3,3,3-heptafluoropropane are also useful as fire extinguishants.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: March 10, 1998
    Assignee: E. I. du pont de Nemours and Company
    Inventors: Donald Bernard Bivens, Brooks Shawn Lunger, Akimichi Yokozeki
  • Patent number: 5723429
    Abstract: The disclosure relates to separating 1,1,2,2 tetrafluoroethane (HFC-134) and 1,1,1,2 tetrafluoroethane (HFC-134a) from each other and/or from fluorocarbon impurities by using extractive distillation with an extractive agent comprising an alcohol. Examples of suitable extractive agents comprise at least one member from the group of methanol, butanol, ethanol, propanol, their isomers and cyclic compounds thereof, among others.
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: March 3, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Barry Asher Mahler, Ralph Newton Miller, Charles Joseph Noelke
  • Patent number: 5723509
    Abstract: Azeotropic compositions made up of from about 68.1 to about 69.1% by weight of dimethoxymethane, from about 29.7 to about 30.7% by weight of cyclopentane and from about 0.7 to about 1.7% by weight in which the sum of the weight percents of the components is 100% by weight. These azeotrope-like compositions are useful as blowing agents in the production of polyurethane foams.
    Type: Grant
    Filed: September 23, 1996
    Date of Patent: March 3, 1998
    Assignee: Bayer Corporation
    Inventors: Joachim Werner, Scott A. Kane, Herman P. Doerge, Eric F. Boonstra, Charles E. Mortimer
  • Patent number: 5705471
    Abstract: Compositions of 1,1,2,2,3,3,4,4-octafluorobutane and a hydrocarbon having from 3 to 7 carbon atoms are described. Specific examples include 1,1,2,2,3,3,4,4-octafluorobutane and butane, cyclopropane, isobutane, propane, cyclopentane, 2,2-dimethylbutane, 2-methylbutane, cyclohexane, 2,3-dimethylpentane, 3-ethylpentane, heptane, hexane, methylcyclopentane, 2-methylpentane or 3-methylpentane. Compositions of 1,1,2,2,3,3,4,4-octafluorobutane and ethyl formate, propylene oxide, bis(pentafluoroethyl)sulfide, dimethoxyethane or tetrahydrofuran are also described. The compositions described above, may be azeotropic or azeotrope-like, and may be used as refrigerants, cleaning agents, expansion agents, for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: January 6, 1998
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Allen Capron Sievert
  • Patent number: 5688431
    Abstract: Compositions of octafluorobutane and a compound of the formula C.sub.a F.sub.b H.sub.2a+2-b, where a=3 or 4 and b=1 to 8 are disclosed. These compositions, may be azeotropic or azeotrope-like, and may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: February 14, 1996
    Date of Patent: November 18, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 5681501
    Abstract: The present invention relates to the discovery of compositions which include a first component of tetrafluoropropane, trifluoropropane, difluoropropane or fluoropropane and a second component of tetrafluoropropane, trifluoropropane, difluoropropane, fluoropropane and 1,1,1-trifluoro-2-trifluoromethylpropane, a hydrocarbon or dimethylether. These compositions are useful as refrigerants, cleaning agents, expansion agents for polyolefin and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: October 28, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 5679631
    Abstract: The present invention is a tetrahydrofurfuryl alcohol and limonene cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: October 21, 1997
    Assignee: AlliedSignal, Inc.
    Inventors: George W. Bohnert, Richard D. Carter, Thomas E. Hand, Michael T. Powers
  • Patent number: 5672293
    Abstract: Refrigerant compositions include mixtures of difluoromethane and isobutane, butane, propylene or cyclopropane; pentafluoroethane and propylene or cyclopropane; 1,1,2,2-tetrafluoroethane and propane; 1,1,1,2-tetrafluoroethane and cyclopropane; 1,1,1-trifluoroethane and DME or propylene; 1,1-difluoroethane and propane, isobutane, butane or cyclopropane; fluoroethane and propane or cyclopropane; 1,1,1,2,2,3,3-heptafluoropropane and butane, cyclopropane, DME, isobutane or propane; or 1,1,1,2,3,3,3-heptafluoropropane and butane, cyclopropane, isobutane or propane.
    Type: Grant
    Filed: May 4, 1995
    Date of Patent: September 30, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Barbara Haviland Minor, Donald Bernard Bivens, Brooks Shawn Lunger
  • Patent number: 5670079
    Abstract: This invention relates to compositions that include at least one hydrocarbon and at least one fluorinated species. Such compositions may be used as refrigerants, cleaning agents, expansion agents for foams such as polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, displacement drying agents, among others.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: September 23, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Brooks Shawn Lunger, Glenn Scott Shealy
  • Patent number: 5667594
    Abstract: A cleaning solvent composition that is made by either blending aliphatic fluorohydrocarbon as expressed by the general formulaC.sub.n F.sub.m H.sub.2n+2-m(wherein, n and m are a positive integral numbers, being 4.ltoreq.n.ltoreq.6, 2n-3.ltoreq.m<2n+2 respectively) or blending a mixture of this aliphatic fluorohydrocarbon and alcohol having a carbon number of 1 to 4 with lactam and/or carboxylic acid amide, tertiary amines, or alcohol having ether linkage and/or amino linkage within its molecules. A cleaning process wherein an object is dipped into the said composition to remove dirty component, then rinsed with a mixture of the said aliphatic fluorohydrocarbon and the said alcohol having a carbon number of 1 to 4, and thereafter the object is steam cleaned with the said mixture when necessity arises.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: September 16, 1997
    Assignee: Daikin Industries Ltd.
    Inventors: Yukio Omure, Hirokazu Aoyama, Satoshi Ide, Takahiro Matsuda
  • Patent number: 5654264
    Abstract: The present invention includes compositions of octafluorobutane and a compound of the formula C.sub.a F.sub.b H.sub.2a+2-b, where a=3 or 4 and b=1 to 8 are disclosed. These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 5, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 5653908
    Abstract: The invention includes compositions of 1,2,2,3,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy-1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy-1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran, or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,2,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane or 2,2,3,3-tetrafluorooxetane; or 1,1,2,2,3,3,4,4-octafluorobutane and methyl tert-butyl ether, bis(fluoromethyl) ether or 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2,2-tetrafluoroethoxy)propane.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 5, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barbara Haviland Minor
  • Patent number: 5648017
    Abstract: The azeotropic compositions of 1,1,2,2-tetrafluoroethane and 1,1-difluoroethane and the azeotropic and azeotropic-like composition of 1,1,2,2-tetrafluoroethane and one of, 1-chloro-1,1-difluoroethane, perfluorocyclobutane, n-butane, isobutane and 1,1,1,2,3,3,3-heptafluoropropane, and their use as refrigerants, aerosol propellants and blowing agents for polymer foams, are disclosed. The azeotropic and azeotrope-like compositions of 1,1,1,2-tetrafluoroethane and one of perfluorocyclobutane and 1,1,1,2,3,3,3-heptafluoropropane are also useful as fire extinguishants.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 15, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Philip Lee Bartlett, Donald Bernard Bivens, Brooks Shawn Lunger, Akimichi Yokozeki
  • Patent number: 5635098
    Abstract: This invention relates to compositions that include at least one hydrocarbon and at least one fluorinated species. Such compositions may be used as refrigerants, cleaning agents, expansion agents for foams such as polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, displacement drying agents, among others.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: June 3, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Brooks S. Lunger, Glenn S. Shealy
  • Patent number: 5632928
    Abstract: Azeotrope and azeotropic-like compositions of the following are provided:(a) Chlorotetrafluorethane with an effective amount of polybutene;(b) Chlorohexafluoropane with an effective amount of perfluoro(alkane or alkene), wherein the alkane and alkene contains 5 carbon atoms; and(c) Octafluorobutane, optionally mono-chloro substituted, with an effective amount of perfluoro(alkane or alkene), wherein the alkane and alkene contains 5 carbon atoms,the effective amount in each case being sufficient to form said azeotropic or azeotrope-like composition.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: May 27, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Scott C. Jackson
  • Patent number: 5626790
    Abstract: Refrigerant compositions include mixtures of 1,1,2-trifluoroethane and a second component wherein the second component is (CF.sub.3).sub.2 NF, (CF.sub.3).sub.3 N, N(CHF.sub.2).sub.2 (CF.sub.3), N(CH.sub.2 F)(CF.sub.3).sub.2, SF.sub.5 CF.sub.2 H.sub.5, SF.sub.5 C.sub.2 F.sub.5, HFC-236ca, HFC-236cb, HFC-236ea, HFC-254cb, HFC-254eb, HFC-263fb, HFC-272ca, HFC-281ea, HFC-281fa, HFC-338mf, HFC-4310mee, butane, cyclopropane, isobutane or propane.Except for FIG. 7, the invention also relates to azeotropic or azeotrope-like compositions which comprise admixtures of effective amounts of 1,1,2-trifluoroethane and (CF.sub.3).sub.2 NF, (CF.sub.3).sub.3 N, N(CHF.sub.2).sub.2 (CF.sub.3), N(CH.sub.2 F)(CF.sub.3).sub.2, SF.sub.5 CF.sub.2 H, SF.sub.5 C.sub.2 F.sub.5, HFC-236ca, HFC-236cb, HFC-236ea, HFC-254cb, HFC-254eb, HFC-263fb, HFC-272ca, HFC-281ea, HFC-281fa, HFC-338mf, HFC-4310mee, butane, cyclopropane, isobutane or propane to form an azeotropic or azeotrope-like composition.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: May 6, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barbara H. Minor
  • Patent number: 5618781
    Abstract: Stable azeotrope-like compositions consisting essentially of dichloropentafluoropropane and a hydrocarbon containing six carbon atoms which are useful in a variety of industrial cleaning applications including cold cleaning and defluxing of printed circuit boards.
    Type: Grant
    Filed: February 11, 1992
    Date of Patent: April 8, 1997
    Assignee: AlliedSignal Inc.
    Inventors: Hillel Magid, David P. Wilson, Dennis M. Lavery, Richard M. Hollister, Richard E. Eibeck, Michael Vanderpuy
  • Patent number: 5616275
    Abstract: This invention relates to compositions of a hexafluoropropane and a hydrofluorocarbon, with the hydrofluorocarbon being hexafluoropropane, pentafluoropropane, tetrafluoropropane, trifluoropropane, difluoropropane, fluoropropane, or (CF.sub.3).sub.2 CHCH.sub.3. The compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 1, 1997
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Tuneen E. C. Chisolm, Barbara H. Minor
  • Patent number: 5614565
    Abstract: Azeotropic compositions made up of (a) from about 73 to about 88% by weight perfluorohexane and (b) one compound selected from (1) about 14 to about 27% by weight 2-methyl pentane or (2) about 13 to about 25% by weight 3-methyl pentane or (3) about 12 to about 23% by weight, provided that the sum of the weight percent (a) plus weight percent (b) is 100 percent are suitable blowing agents for the production of foams.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: March 25, 1997
    Assignee: Bayer Corporation
    Inventors: Joachim Werner, Scott A. Kane, Herman P. Doerge, Eric F. Boonstra
  • Patent number: 5607912
    Abstract: A hydrochlorofluorocarbon azeotropic or azeotropic-like mixture comprising at least one member selected from the group consisting of hydrogen-containing fluoropropanes of the formula I:CH.sub.a Cl.sub.b F.sub.c CF.sub.2 CH.sub.x Cl.sub.y F.sub.z (I)wherein a+b+c=3, x+y+z=3, a+x.gtoreq.1, b+y.gtoreq.1, and 0.ltoreq.a,b,c,x,y,z.ltoreq.3, and at least one member selected from the group of compounds II consisting of halogenated hydrocarbons having a boiling point of from 20.degree. to 85.degree. C. other than said hydrochlorofluoropropanes, hydrocarbons having a boiling point of from 20.degree. to 85.degree. C. and alcohols having from 1 to 4 carbon atoms.
    Type: Grant
    Filed: September 9, 1992
    Date of Patent: March 4, 1997
    Assignee: Asahi Glass Company Ltd.
    Inventors: Shunichi Samejima, Kenroh Kitamura, Naohiro Watanabe, Teruo Asano, Toru Kamimura, Yoko Usami
  • Patent number: 5605882
    Abstract: This invention relates to compositions that include at least one fluoroether and at least one hydrofluorocarbon. Included in this invention are compositions of a cyclic or acyclic hydrofluoroether of the formula C.sub.a F.sub.b H.sub.2a+2-b O.sub.c wherein a=2 or 3 and 3.ltoreq.b.ltoreq.8 and c=1 or 2 and a hydrofluorocarbon of the formula C.sub.n F.sub.m H.sub.2n+2-m wherein 1.ltoreq.n.ltoreq.4 and 1.ltoreq.m.ltoreq.8. Such compositions may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: February 25, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Diana L. Klug, Barbara H. Minor, Donna M. Patron, Tuneen E. C. Chisolm, Allen C. Sievert
  • Patent number: 5578137
    Abstract: Compositions of 1,1,1,2,3,4,4,5,5,5-decafluoropentane, bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1,1,1,2-tetrafluoro-2-(fluoromethoxy)ethane, 1-(difluoromethoxy)-1,2,2-trifluoroethane, 1-(difluoromethoxy)-1,1,2-trifluoroethane, acetone, cyclopentane, ethyl acetate, ethyl formate, methyl tert-butyl ether, methyl acetate, methyl formate, propylene oxide, 2,2-dimethylbutane, n-pentane or n-propanol are useful as cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
    Type: Grant
    Filed: May 19, 1994
    Date of Patent: November 26, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Glenn S. Shealy
  • Patent number: 5562854
    Abstract: The invention includes compositions of 1,2,2,3,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy-1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy- 1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran, or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,2,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane or 2,2,3,3-tetrafluorooxetane; or 1,1,2,2,3,3,4,4-octafluorobutane and methyl tert-butyl ether, bis(fluoromethyl) ether or 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2,2-tetrafluoroethoxy)propane.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: October 8, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barbara H. Minor
  • Patent number: 5562853
    Abstract: Compositions include compositions of 1,1,2,2,3,3,4,4-octafluorobutane and a hydrocarbon having from 3 to 7 carbon atoms. Specific examples include 1,1,2,2,3,3,4,4-octafluorobutane and butane, cyclopropane, isobutane, propane, cyclopentane, 2,2-dimethylbutane, n-pentane, 2-methylbutane, cyclohexane, 2,3-dimethylpentane, 3-ethylpentane, heptane, hexane or methylcyclopentane. Also included in this invention are compositions of 1,1,2,2,3,3,4,4-octafluorobutane and ethyl formate, propylene oxide, bis(pentafluoroethyl)sulfide, dimethoxyethane or tetrahydrofuran. These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: October 8, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Barbara H. Minor, Allen C. Sievert
  • Patent number: 5562855
    Abstract: The present invention includes compositions of octafluorobutane and a compound of the formula C.sub.a F.sub.b H.sub.2a+2-b, where a=3 or 4 and b=1 to 8 are disclosed. These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: September 29, 1994
    Date of Patent: October 8, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Barbara H. Minor
  • Patent number: 5560861
    Abstract: Azeotropic compositions include a perfluorinated alkane or alkene and an organic solvent.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: October 1, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard M. Flynn, Mark W. Grenfell, Frank W. Klink, Daniel R. Vitcak
  • Patent number: 5538659
    Abstract: This invention relates to compositions of a hexafluoropropane and a hydrofluorocarbon, with the hydrofluorocarbon being hexafluoropropane, pentafluoropropane, tetrafluoropropane, trifluoropropane, difluoropropane, fluoropropane, or (CF.sub.3).sub.2 CHCH.sub.3. The compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: July 23, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Tuneen E. C. Chisolm, Barbara H. Minor
  • Patent number: 5532283
    Abstract: Azeotropic compositions made up of from about 64 to about 80% by weight of 1,1,1,4,4,4-hexafluorobutane and from about 20 to about 36% by weight of 2-methyl butane have been found to be particularly useful as blowing agents for the production of polyurethane foams.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: July 2, 1996
    Assignee: Bayer Corporation
    Inventors: Joachim Werner, Scott A. Kane, Eric F. Boonstra, Herman P. Doerge