Azeotropic Or Azeotrope-like Composition Patents (Class 510/408)
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Patent number: 6013194Abstract: Compositions disclosed include hexafluoropropane and a hydrocarbon having from 1 to 5 carbon atoms or dimethyl ether. These compositions are useful as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.Type: GrantFiled: April 21, 1997Date of Patent: January 11, 2000Assignee: E.I. duPont de Nemours and CompanyInventor: Barbara Haviland Minor
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Patent number: 6001273Abstract: Refrigerant compositions include mixtures of difluoromethane and isobutane, butane, propylene or cyclopropane; pentafluoroethane and propylene or cyclopropane; 1,1,2,2-tetrafluoroethane and propane; 1,1,1,2-tetrafluoroethane and cyclopropane; 1,1,1-trifluoroethane and DME or propylene; 1,1-difluoroethane and propane, isobutane, butane or cyclopropane; fluoroethane and propane or cyclopropane; 1,1,1,2,2,3,3-heptafluoropropane and butane, cyclopropane, DME, isobutane or propane; or 1,1,1,2,3,3,3-heptafluoropropane and butane, cyclopropane, isobutane or propane.Type: GrantFiled: January 28, 1998Date of Patent: December 14, 1999Inventors: Barbara Haviland Minor, Donald Bernard Bivens, Brooks Shawn Lunger
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Patent number: 6001796Abstract: Provided are azeotropic and azeotrope-like mixtures of 1,1,1,3,3-pentafluoropropane (HFC-245fa) and hydrogen fluoride. Such are useful as an intermediate in the production of HFC-245fa. The latter is useful as a nontoxic, zero ozone depleting fluorocarbon useful as a solvent, blowing agent, refrigerant, cleaning agent, aerosol propellant, heat transfer medium, dielectric, fire extinguishing composition and power cycle working fluid.Type: GrantFiled: July 3, 1996Date of Patent: December 14, 1999Assignee: AlliedSignal Inc.Inventors: Hang Thanh Pham, Rajiv Ratna Singh, Ian Robert Shankland, Hsueh Sung Tung
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Patent number: 5985939Abstract: The invention relates to the discovery of compositions useful as aerosol propellants that include a first component of butane or isobutane and a second component of 2-fluoropropane (HFC-281 ea) or 1-fluoropropane (HFC-282 fa).Type: GrantFiled: June 17, 1997Date of Patent: November 16, 1999Assignee: E.I. du Pont de Nemours and CompanyInventor: Barbara Haviland Minor
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Patent number: 5968406Abstract: The azeotropic compositions of 1,1,2,2-tetrafluoroethane and 1,1-difluoroethane and the azeotropic and azeotropic-like composition of 1,1,2,2-tetrafluoroethane and one of, 1-chloro-1,1-difluoroethane, perfluorocyclobutane, n-butane, isobutane and 1,1,1,2,3,3,3-heptafluoropropane, and their use as refrigerants, aerosol propellants and blowing agents for polymer foams, are disclosed. The azeotropic and azeotrope-like compositions of 1,1,1,2-tetrafluoroethane and one of perfluorocyclobutane and 1,1,1,2,3,3,3-heptafluoropropane are also useful as fire extinguishants.Type: GrantFiled: July 31, 1997Date of Patent: October 19, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Philip Lee Bartlett, Donald Bernard Bivens, Brooks Shawn Lunger, Akimichi Yokozeki
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Patent number: 5965511Abstract: In order to replace compositions based on CFC or on HCFC in applications for cleaning or drying solid surfaces (in particular defluxing), the invention proposes azeotropic or virtually azeotropic compositions based on 1,1,1,2,3,4,4,5,5,5-decafluoropentane, methylene chloride and optionally methanol.Type: GrantFiled: January 30, 1998Date of Patent: October 12, 1999Assignee: Elf Atochem S. A.Inventors: Pascal Michaud, Jean-Jacques Martin
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Patent number: 5888250Abstract: A method for dry-cleaning garments which comprises treating them with an azeotropic solvent of propylene glycol tertiary-butyl ether and water.Type: GrantFiled: April 4, 1997Date of Patent: March 30, 1999Assignee: Rynex Holdings Ltd.Inventors: William A. Hayday, Stephen P. Bates
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Patent number: 5866029Abstract: Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and at least one hydrocarbon selected from the group n-pentane, iso-pentane, cyclopentane, n-hexane and iso-hexane are provided. The compositions of the invention are useful in the preparation of polyurethane and polyisocyanurate foams.Type: GrantFiled: June 10, 1997Date of Patent: February 2, 1999Assignee: AlliedSignal IncInventors: Earl August Eugene Lund, Robert Christian Parker, Ian Robert Shankland
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Patent number: 5851436Abstract: Compositions of nonafluoromethoxybutane and cyclopentane, nonafluoromethoxybutane and cyclohexane; nonafluoromethoxybutane, cyclopentane and acetone, nonafluoromethoxybutane, cyclohexane and acetone, nonafluoromethoxybutane, trans-1,2-dichloroethylene and cyclopentane; and nonafluoromethoxybutane, trans-1,2-dichloroethylene, cyclopentane and methanol are described. These compositions are useful as cleaning agents, displacement drying agents, refrigerants, heat transfer media, expansion agents for polyolefins and polyurethanes, aerosol propellants, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, and buffing abrasive agents.Type: GrantFiled: May 19, 1997Date of Patent: December 22, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Abid Nazarali Merchant, Barbara Haviland Minor, Shoeb Akberali Moiyadi
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Patent number: 5834416Abstract: Binary azeotrope and azeotrope-like compositions contain the alkyl esters n-propyl acetate (NPA) and sec-butyl acetate (SBA) respectively, with hexamethyldisiloxane (MM), and are useful for cleaning, rinsing, or drying.Type: GrantFiled: August 19, 1997Date of Patent: November 10, 1998Assignee: Dow Corning CorporationInventors: David Lee Morgan, Dwight Edward Williams
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Patent number: 5827454Abstract: A mixed solvent composition, for cleaning electronic components, which consists essentially of dichloropentafluoropropane and 1,1,1,2,3,4,4,5,5,5-decafluoropentane.Type: GrantFiled: January 18, 1996Date of Patent: October 27, 1998Assignee: AG Technology Co., Ltd.Inventors: Kitamura Kenroh, Ikehata Michino, Tsuzaki Masaaki
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Patent number: 5792277Abstract: Stabilized, n-propyl bromide containing cleaning solvent compositions and a cleaning process are provided. The cleaning solvent compositions include an alcohol selected from 1-propanol and 2-butanol, including mixtures thereof, as a co-solvent so as to form azeotropic or azeotropic-like mixtures which have no fire or flash points.Type: GrantFiled: July 23, 1997Date of Patent: August 11, 1998Assignee: Albemarle CorporationInventors: Ronald L. Shubkin, Eric W. Liimatta
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Patent number: 5788886Abstract: The present invention relates to compositions of pentafluoropropane and a fluorinated propane having from 1 to 5 fluorine atoms; a hydrocarbon having from 1 to 5 carbon atoms; 1,1,1,4,4,4-hexafluorobutane, (CF.sub.3).sub.2 CHCH.sub.3, dimethyl ether; or 1,1,1,2,3,4,4,5,5,5-decafluoropentane. The compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.Type: GrantFiled: May 5, 1997Date of Patent: August 4, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Tuneen E. C. Chisolm
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Patent number: 5788877Abstract: Substantially constant boiling mixtures of difluoromethane and 1,1,1-trifluoroethane or perfluoroethane are useful as refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, and expansion agents for polymers.Type: GrantFiled: May 13, 1997Date of Patent: August 4, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Mark Brandon Shiflett
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Patent number: 5785883Abstract: Refrigerant compositions include mixtures of difluoromethane and isobutane, butane, propylene or cyclopropane; pentafluoroethane and propylene or cyclopropane; 1,1,2,2-tetrafluoroethane and propane; 1,1,1,2-tetrafluoroethane and cyclopropane; 1,1,1-trifluoroethane and DME or propylene; 1,1-difluoroethane and propane, isobutane, butane or cyclopropane; fluoroethane and propane or cyclopropane; 1,1,1,2,2,3,3-heptafluoropropane and butane, cyclopropane, DME, isobutane or propane; or 1,1,1,2,3,3,3-heptafluoropropane and butane, cyclopropane, isobutane or propane.Type: GrantFiled: April 23, 1997Date of Patent: July 28, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Donald Bernard Bivens, Brooks Shawn Lunger
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Patent number: 5772911Abstract: Compositions include compositions of 1,1,2,2,3,3,4,4-octafluorobutane and a hydrocarbon having from 3 to 7 carbon atoms. Specific examples include 1,1,2,2,3,3,4,4-octafluorobutane and butane, cyclopropane, isobutane, propane, cyclopentane, 2,2-dimethylbutane, n-pentane, 2-methylbutane, cyclohexane, 2,3-dimethylpentane, 3-ethylpentane, heptane, hexane or methylcyclopentane. Also included in this invention are compositions of 1,1,2,2,3,3,4,4-octafluorobutane and ethyl formate, propylene oxide, bis(pentafluoroethyl)sulfide, dimethoxyethane or tetrahydrofuran. These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.Type: GrantFiled: May 7, 1997Date of Patent: June 30, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Allen Capron Sievert
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Patent number: 5766511Abstract: Use of near-azeotropic mixtures of hydrofluorocarbons with butane or isobutane selected from:A) 1,1,1,2-tetrafluoroethane (HFC-134a) 5-88% by wt1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) 12-95% by wtB) 1,1,1,2-tetrafluoroethane (HFC-134a) 10-87% by wt1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) 12-81% by wtn-butane 1-30% by wtC) 1,1,1,2-tetrafluoroethane (HFC-134a) 18-69% by wt1,1,1,2,3,3,3-heptafluoropropane (HFC 227ea) 30-81% by wtisobutane 1-30% by wtas propellant fluids for aerosol.Said mixtures have zero ODP, very low GWP, no or low inflammability, insignificant pressure loss during the use and good solubility towards the typical solvents of aerosol formulations.Type: GrantFiled: December 17, 1996Date of Patent: June 16, 1998Assignee: Ausimont S.P.A.Inventors: Ezio Musso, Giampiero Basile
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Patent number: 5762818Abstract: Compositions are disclosed which include 1,1,2,2-tetrafluoroethane and a propane, tris(trifluoromethyl)amine, trifluoromethylsulfur pentafluoride or fluoroethane. The term propane includes compounds of the formula C.sub.3 F.sub.a H.sub.8-a wherein 0.ltoreq.a.ltoreq.8 as well as cyclic compounds of the formula C.sub.3 F.sub.b H.sub.6-b wherein 0.ltoreq.b.ltoreq.6. These compositions are useful as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.Type: GrantFiled: April 23, 1997Date of Patent: June 9, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Donna Marie Patron, Diana Lynn Klug, Brooks Shawn Lunger
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Patent number: 5736062Abstract: Azeotrope-like mixtures, utilizable as refrigerating fluids in substitution of R-12 or R-502, constituted by hydrogen-(chloro)fluorocarbons, optionally in admixture with propane, cyclopropane or dimethylether.Type: GrantFiled: February 12, 1996Date of Patent: April 7, 1998Assignee: Ausimont S.p.A.Inventors: Giampiero Basile, Ezio Musso
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Patent number: 5733472Abstract: Compositions are disclosed which include 1,1,2,2-tetrafluoroethane and a propane, tris(trifluoromethyl)amine, trifluoromethylsulfur pentafluoride or fluoroethane. The term propane includes compounds of the formula C.sub.3 F.sub.a H.sub.8-a wherein 0.ltoreq.a.ltoreq.8 as well as cyclic compounds of the formula C.sub.3 F.sub.b H.sub.6-b wherein 0.ltoreq.b.ltoreq.6. These compositions are useful as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.Type: GrantFiled: November 12, 1996Date of Patent: March 31, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Donna Marie Patron, Diana Lynn Klug, Brooks Shawn Lunger
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Patent number: 5730894Abstract: Compositions of 1,1,2,2,3,3,4,4-octafluorobutane and a compound of the formula selected from the group consisting of a 4-6 carbon linear or a cyclic hydrofluorocarbon or fluorocarbon, a 3-5 carbon fluoroether, a fluorinated alcohol, perfluoro-n-methylmorpholine; and an ether are disclosed.These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, in small turbine high speed compressors. They may also be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, displacement drying agents or as an anesthetic.Type: GrantFiled: April 16, 1996Date of Patent: March 24, 1998Assignee: E. I. du Pont de Nemours and CompanyInventor: Barbara Haviland Minor
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Patent number: 5725791Abstract: The azeotropic compositions of 1,1,2,2-tetrafluoroethane and 1,1-difluoroethane and the azeotropic and azeotropic-like composition of 1,1,2,2-tetrafluoroethane and one of, 1-chloro-1,1-difluoroethane, perfluorocyclobutane, n-butane, isobutane and 1,1,1,2,3,3,3-heptafluoropropane, and their use as refrigerants, aerosol propellants and blowing agents for polymer foams, are disclosed. The azeotropic and azeotrope-like compositions of 1,1,1,2-tetrafluoroethane and one of perfluorocyclobutane and 1,1,1,2,3,3,3-heptafluoropropane are also useful as fire extinguishants.Type: GrantFiled: August 9, 1993Date of Patent: March 10, 1998Assignee: E. I. du pont de Nemours and CompanyInventors: Donald Bernard Bivens, Brooks Shawn Lunger, Akimichi Yokozeki
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Patent number: 5723429Abstract: The disclosure relates to separating 1,1,2,2 tetrafluoroethane (HFC-134) and 1,1,1,2 tetrafluoroethane (HFC-134a) from each other and/or from fluorocarbon impurities by using extractive distillation with an extractive agent comprising an alcohol. Examples of suitable extractive agents comprise at least one member from the group of methanol, butanol, ethanol, propanol, their isomers and cyclic compounds thereof, among others.Type: GrantFiled: April 24, 1996Date of Patent: March 3, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Barry Asher Mahler, Ralph Newton Miller, Charles Joseph Noelke
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Patent number: 5723509Abstract: Azeotropic compositions made up of from about 68.1 to about 69.1% by weight of dimethoxymethane, from about 29.7 to about 30.7% by weight of cyclopentane and from about 0.7 to about 1.7% by weight in which the sum of the weight percents of the components is 100% by weight. These azeotrope-like compositions are useful as blowing agents in the production of polyurethane foams.Type: GrantFiled: September 23, 1996Date of Patent: March 3, 1998Assignee: Bayer CorporationInventors: Joachim Werner, Scott A. Kane, Herman P. Doerge, Eric F. Boonstra, Charles E. Mortimer
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Patent number: 5705471Abstract: Compositions of 1,1,2,2,3,3,4,4-octafluorobutane and a hydrocarbon having from 3 to 7 carbon atoms are described. Specific examples include 1,1,2,2,3,3,4,4-octafluorobutane and butane, cyclopropane, isobutane, propane, cyclopentane, 2,2-dimethylbutane, 2-methylbutane, cyclohexane, 2,3-dimethylpentane, 3-ethylpentane, heptane, hexane, methylcyclopentane, 2-methylpentane or 3-methylpentane. Compositions of 1,1,2,2,3,3,4,4-octafluorobutane and ethyl formate, propylene oxide, bis(pentafluoroethyl)sulfide, dimethoxyethane or tetrahydrofuran are also described. The compositions described above, may be azeotropic or azeotrope-like, and may be used as refrigerants, cleaning agents, expansion agents, for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.Type: GrantFiled: February 23, 1996Date of Patent: January 6, 1998Assignee: E. I. Du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Allen Capron Sievert
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Patent number: 5688431Abstract: Compositions of octafluorobutane and a compound of the formula C.sub.a F.sub.b H.sub.2a+2-b, where a=3 or 4 and b=1 to 8 are disclosed. These compositions, may be azeotropic or azeotrope-like, and may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.Type: GrantFiled: February 14, 1996Date of Patent: November 18, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barbara Haviland Minor
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Patent number: 5681501Abstract: The present invention relates to the discovery of compositions which include a first component of tetrafluoropropane, trifluoropropane, difluoropropane or fluoropropane and a second component of tetrafluoropropane, trifluoropropane, difluoropropane, fluoropropane and 1,1,1-trifluoro-2-trifluoromethylpropane, a hydrocarbon or dimethylether. These compositions are useful as refrigerants, cleaning agents, expansion agents for polyolefin and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.Type: GrantFiled: October 11, 1995Date of Patent: October 28, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barbara Haviland Minor
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Patent number: 5679631Abstract: The present invention is a tetrahydrofurfuryl alcohol and limonene cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.Type: GrantFiled: December 22, 1995Date of Patent: October 21, 1997Assignee: AlliedSignal, Inc.Inventors: George W. Bohnert, Richard D. Carter, Thomas E. Hand, Michael T. Powers
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Patent number: 5672293Abstract: Refrigerant compositions include mixtures of difluoromethane and isobutane, butane, propylene or cyclopropane; pentafluoroethane and propylene or cyclopropane; 1,1,2,2-tetrafluoroethane and propane; 1,1,1,2-tetrafluoroethane and cyclopropane; 1,1,1-trifluoroethane and DME or propylene; 1,1-difluoroethane and propane, isobutane, butane or cyclopropane; fluoroethane and propane or cyclopropane; 1,1,1,2,2,3,3-heptafluoropropane and butane, cyclopropane, DME, isobutane or propane; or 1,1,1,2,3,3,3-heptafluoropropane and butane, cyclopropane, isobutane or propane.Type: GrantFiled: May 4, 1995Date of Patent: September 30, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Barbara Haviland Minor, Donald Bernard Bivens, Brooks Shawn Lunger
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Patent number: 5670079Abstract: This invention relates to compositions that include at least one hydrocarbon and at least one fluorinated species. Such compositions may be used as refrigerants, cleaning agents, expansion agents for foams such as polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, displacement drying agents, among others.Type: GrantFiled: May 8, 1995Date of Patent: September 23, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Brooks Shawn Lunger, Glenn Scott Shealy
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Patent number: 5667594Abstract: A cleaning solvent composition that is made by either blending aliphatic fluorohydrocarbon as expressed by the general formulaC.sub.n F.sub.m H.sub.2n+2-m(wherein, n and m are a positive integral numbers, being 4.ltoreq.n.ltoreq.6, 2n-3.ltoreq.m<2n+2 respectively) or blending a mixture of this aliphatic fluorohydrocarbon and alcohol having a carbon number of 1 to 4 with lactam and/or carboxylic acid amide, tertiary amines, or alcohol having ether linkage and/or amino linkage within its molecules. A cleaning process wherein an object is dipped into the said composition to remove dirty component, then rinsed with a mixture of the said aliphatic fluorohydrocarbon and the said alcohol having a carbon number of 1 to 4, and thereafter the object is steam cleaned with the said mixture when necessity arises.Type: GrantFiled: March 14, 1994Date of Patent: September 16, 1997Assignee: Daikin Industries Ltd.Inventors: Yukio Omure, Hirokazu Aoyama, Satoshi Ide, Takahiro Matsuda
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Patent number: 5654264Abstract: The present invention includes compositions of octafluorobutane and a compound of the formula C.sub.a F.sub.b H.sub.2a+2-b, where a=3 or 4 and b=1 to 8 are disclosed. These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.Type: GrantFiled: June 7, 1995Date of Patent: August 5, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barbara Haviland Minor
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Patent number: 5653908Abstract: The invention includes compositions of 1,2,2,3,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy-1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy-1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran, or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,2,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane or 2,2,3,3-tetrafluorooxetane; or 1,1,2,2,3,3,4,4-octafluorobutane and methyl tert-butyl ether, bis(fluoromethyl) ether or 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2,2-tetrafluoroethoxy)propane.Type: GrantFiled: June 7, 1995Date of Patent: August 5, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barbara Haviland Minor
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Patent number: 5648017Abstract: The azeotropic compositions of 1,1,2,2-tetrafluoroethane and 1,1-difluoroethane and the azeotropic and azeotropic-like composition of 1,1,2,2-tetrafluoroethane and one of, 1-chloro-1,1-difluoroethane, perfluorocyclobutane, n-butane, isobutane and 1,1,1,2,3,3,3-heptafluoropropane, and their use as refrigerants, aerosol propellants and blowing agents for polymer foams, are disclosed. The azeotropic and azeotrope-like compositions of 1,1,1,2-tetrafluoroethane and one of perfluorocyclobutane and 1,1,1,2,3,3,3-heptafluoropropane are also useful as fire extinguishants.Type: GrantFiled: June 7, 1995Date of Patent: July 15, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Philip Lee Bartlett, Donald Bernard Bivens, Brooks Shawn Lunger, Akimichi Yokozeki
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Patent number: 5635098Abstract: This invention relates to compositions that include at least one hydrocarbon and at least one fluorinated species. Such compositions may be used as refrigerants, cleaning agents, expansion agents for foams such as polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, displacement drying agents, among others.Type: GrantFiled: May 8, 1995Date of Patent: June 3, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Brooks S. Lunger, Glenn S. Shealy
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Patent number: 5632928Abstract: Azeotrope and azeotropic-like compositions of the following are provided:(a) Chlorotetrafluorethane with an effective amount of polybutene;(b) Chlorohexafluoropane with an effective amount of perfluoro(alkane or alkene), wherein the alkane and alkene contains 5 carbon atoms; and(c) Octafluorobutane, optionally mono-chloro substituted, with an effective amount of perfluoro(alkane or alkene), wherein the alkane and alkene contains 5 carbon atoms,the effective amount in each case being sufficient to form said azeotropic or azeotrope-like composition.Type: GrantFiled: May 31, 1995Date of Patent: May 27, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Scott C. Jackson
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Patent number: 5626790Abstract: Refrigerant compositions include mixtures of 1,1,2-trifluoroethane and a second component wherein the second component is (CF.sub.3).sub.2 NF, (CF.sub.3).sub.3 N, N(CHF.sub.2).sub.2 (CF.sub.3), N(CH.sub.2 F)(CF.sub.3).sub.2, SF.sub.5 CF.sub.2 H.sub.5, SF.sub.5 C.sub.2 F.sub.5, HFC-236ca, HFC-236cb, HFC-236ea, HFC-254cb, HFC-254eb, HFC-263fb, HFC-272ca, HFC-281ea, HFC-281fa, HFC-338mf, HFC-4310mee, butane, cyclopropane, isobutane or propane.Except for FIG. 7, the invention also relates to azeotropic or azeotrope-like compositions which comprise admixtures of effective amounts of 1,1,2-trifluoroethane and (CF.sub.3).sub.2 NF, (CF.sub.3).sub.3 N, N(CHF.sub.2).sub.2 (CF.sub.3), N(CH.sub.2 F)(CF.sub.3).sub.2, SF.sub.5 CF.sub.2 H, SF.sub.5 C.sub.2 F.sub.5, HFC-236ca, HFC-236cb, HFC-236ea, HFC-254cb, HFC-254eb, HFC-263fb, HFC-272ca, HFC-281ea, HFC-281fa, HFC-338mf, HFC-4310mee, butane, cyclopropane, isobutane or propane to form an azeotropic or azeotrope-like composition.Type: GrantFiled: March 14, 1994Date of Patent: May 6, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barbara H. Minor
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Patent number: 5618781Abstract: Stable azeotrope-like compositions consisting essentially of dichloropentafluoropropane and a hydrocarbon containing six carbon atoms which are useful in a variety of industrial cleaning applications including cold cleaning and defluxing of printed circuit boards.Type: GrantFiled: February 11, 1992Date of Patent: April 8, 1997Assignee: AlliedSignal Inc.Inventors: Hillel Magid, David P. Wilson, Dennis M. Lavery, Richard M. Hollister, Richard E. Eibeck, Michael Vanderpuy
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Patent number: 5616275Abstract: This invention relates to compositions of a hexafluoropropane and a hydrofluorocarbon, with the hydrofluorocarbon being hexafluoropropane, pentafluoropropane, tetrafluoropropane, trifluoropropane, difluoropropane, fluoropropane, or (CF.sub.3).sub.2 CHCH.sub.3. The compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.Type: GrantFiled: June 7, 1995Date of Patent: April 1, 1997Assignee: E. I. du Pont de Nemours and CompanyInventors: Tuneen E. C. Chisolm, Barbara H. Minor
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Patent number: 5614565Abstract: Azeotropic compositions made up of (a) from about 73 to about 88% by weight perfluorohexane and (b) one compound selected from (1) about 14 to about 27% by weight 2-methyl pentane or (2) about 13 to about 25% by weight 3-methyl pentane or (3) about 12 to about 23% by weight, provided that the sum of the weight percent (a) plus weight percent (b) is 100 percent are suitable blowing agents for the production of foams.Type: GrantFiled: March 24, 1995Date of Patent: March 25, 1997Assignee: Bayer CorporationInventors: Joachim Werner, Scott A. Kane, Herman P. Doerge, Eric F. Boonstra
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Patent number: 5607912Abstract: A hydrochlorofluorocarbon azeotropic or azeotropic-like mixture comprising at least one member selected from the group consisting of hydrogen-containing fluoropropanes of the formula I:CH.sub.a Cl.sub.b F.sub.c CF.sub.2 CH.sub.x Cl.sub.y F.sub.z (I)wherein a+b+c=3, x+y+z=3, a+x.gtoreq.1, b+y.gtoreq.1, and 0.ltoreq.a,b,c,x,y,z.ltoreq.3, and at least one member selected from the group of compounds II consisting of halogenated hydrocarbons having a boiling point of from 20.degree. to 85.degree. C. other than said hydrochlorofluoropropanes, hydrocarbons having a boiling point of from 20.degree. to 85.degree. C. and alcohols having from 1 to 4 carbon atoms.Type: GrantFiled: September 9, 1992Date of Patent: March 4, 1997Assignee: Asahi Glass Company Ltd.Inventors: Shunichi Samejima, Kenroh Kitamura, Naohiro Watanabe, Teruo Asano, Toru Kamimura, Yoko Usami
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Patent number: 5605882Abstract: This invention relates to compositions that include at least one fluoroether and at least one hydrofluorocarbon. Included in this invention are compositions of a cyclic or acyclic hydrofluoroether of the formula C.sub.a F.sub.b H.sub.2a+2-b O.sub.c wherein a=2 or 3 and 3.ltoreq.b.ltoreq.8 and c=1 or 2 and a hydrofluorocarbon of the formula C.sub.n F.sub.m H.sub.2n+2-m wherein 1.ltoreq.n.ltoreq.4 and 1.ltoreq.m.ltoreq.8. Such compositions may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.Type: GrantFiled: March 5, 1993Date of Patent: February 25, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Diana L. Klug, Barbara H. Minor, Donna M. Patron, Tuneen E. C. Chisolm, Allen C. Sievert
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Patent number: 5578137Abstract: Compositions of 1,1,1,2,3,4,4,5,5,5-decafluoropentane, bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1,1,1,2-tetrafluoro-2-(fluoromethoxy)ethane, 1-(difluoromethoxy)-1,2,2-trifluoroethane, 1-(difluoromethoxy)-1,1,2-trifluoroethane, acetone, cyclopentane, ethyl acetate, ethyl formate, methyl tert-butyl ether, methyl acetate, methyl formate, propylene oxide, 2,2-dimethylbutane, n-pentane or n-propanol are useful as cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.Type: GrantFiled: May 19, 1994Date of Patent: November 26, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Glenn S. Shealy
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Patent number: 5562854Abstract: The invention includes compositions of 1,2,2,3,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy-1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,3,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane, 2,2,3,3-tetrafluorooxetane, 1-difluoromethoxy-1,1,2,2-tetrafluoroethane, 1-difluoromethoxy- 1,2,2,2-tetrafluoroethane, 2,2,3,3,4,5,5-heptafluorotetrahydrofuran, or 2,2,3,3,4,4,5-heptafluorotetrahydrofuran; 1,1,1,2,2,4,4,4-octafluorobutane and bis(fluoromethyl) ether, 2,2,4,4-tetrafluorooxetane or 2,2,3,3-tetrafluorooxetane; or 1,1,2,2,3,3,4,4-octafluorobutane and methyl tert-butyl ether, bis(fluoromethyl) ether or 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2,2-tetrafluoroethoxy)propane.Type: GrantFiled: September 29, 1994Date of Patent: October 8, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barbara H. Minor
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Patent number: 5562853Abstract: Compositions include compositions of 1,1,2,2,3,3,4,4-octafluorobutane and a hydrocarbon having from 3 to 7 carbon atoms. Specific examples include 1,1,2,2,3,3,4,4-octafluorobutane and butane, cyclopropane, isobutane, propane, cyclopentane, 2,2-dimethylbutane, n-pentane, 2-methylbutane, cyclohexane, 2,3-dimethylpentane, 3-ethylpentane, heptane, hexane or methylcyclopentane. Also included in this invention are compositions of 1,1,2,2,3,3,4,4-octafluorobutane and ethyl formate, propylene oxide, bis(pentafluoroethyl)sulfide, dimethoxyethane or tetrahydrofuran. These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.Type: GrantFiled: September 29, 1994Date of Patent: October 8, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Barbara H. Minor, Allen C. Sievert
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Patent number: 5562855Abstract: The present invention includes compositions of octafluorobutane and a compound of the formula C.sub.a F.sub.b H.sub.2a+2-b, where a=3 or 4 and b=1 to 8 are disclosed. These compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.Type: GrantFiled: September 29, 1994Date of Patent: October 8, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Barbara H. Minor
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Patent number: 5560861Abstract: Azeotropic compositions include a perfluorinated alkane or alkene and an organic solvent.Type: GrantFiled: December 2, 1994Date of Patent: October 1, 1996Assignee: Minnesota Mining and Manufacturing CompanyInventors: Richard M. Flynn, Mark W. Grenfell, Frank W. Klink, Daniel R. Vitcak
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Patent number: 5538659Abstract: This invention relates to compositions of a hexafluoropropane and a hydrofluorocarbon, with the hydrofluorocarbon being hexafluoropropane, pentafluoropropane, tetrafluoropropane, trifluoropropane, difluoropropane, fluoropropane, or (CF.sub.3).sub.2 CHCH.sub.3. The compositions, which may be azeotropic or azeotrope-like, may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, refrigerants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents or displacement drying agents.Type: GrantFiled: March 21, 1994Date of Patent: July 23, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Tuneen E. C. Chisolm, Barbara H. Minor
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Patent number: 5532283Abstract: Azeotropic compositions made up of from about 64 to about 80% by weight of 1,1,1,4,4,4-hexafluorobutane and from about 20 to about 36% by weight of 2-methyl butane have been found to be particularly useful as blowing agents for the production of polyurethane foams.Type: GrantFiled: March 24, 1995Date of Patent: July 2, 1996Assignee: Bayer CorporationInventors: Joachim Werner, Scott A. Kane, Eric F. Boonstra, Herman P. Doerge