Polycarboxylic Acid Component, Or Acid Anhydride Or Salt Thereof (e.g., Acrylic Acid Polymer, Maleic Anhydride, Sodium Citrate, Etc.) Patents (Class 510/434)
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Patent number: 8569220Abstract: A hard surface cleaning solution having improved cleaning and descaling properties. The cleaning solution includes the following components: a first organic acid, a second organic acid, a surfactant, a solvent and a diluent. The first organic acid is a carboxylic acid, preferably lactic acid, while the second organic acid is also a carboxylic acid, preferably gluconic acid. The surfactant is selected from the group consisting of amine oxides, preferably lauramine oxide. The solvent may be an alkoxylated alcohol, preferably selected from the propylene glycol ether class of compounds.Type: GrantFiled: November 12, 2010Date of Patent: October 29, 2013Assignee: Jelmar, LLCInventor: Rosemary Gaudreault
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Publication number: 20130255729Abstract: A non-Newtonian concentrate composition includes a sensitizer or irritant, a surfactant, an anti-mist component and optionally a stability component. Example sensitizers and irritants include, but are not limited to, acids, quaternary compounds, and amines, and example anti-mist components include, but are not limited to, polyethylene oxide and polyacrylamide.Type: ApplicationFiled: September 19, 2012Publication date: October 3, 2013Applicant: ECOLAB USA INC.Inventors: Charles A. Hodge, Christopher M. McGuirk, Mark D. Levitt, Dale Larson, Elizabeth R. Kiesel, Amanda R. Blattner
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Patent number: 8546317Abstract: The present invention relates to a hard surface cleaning composition comprising a polybetaine polymer, wherein said polybetaine polymer comprises a zwitterionic unit A or a mixture thereof, wherein said unit A comprises a betaine group or a mixture thereof and wherein said betaine group of said unit A is a sulphobetaine group or a mixture thereof, and a vinylpyrrolidone homopolymer or copolymer, wherein said polybetaine polymer and said vinylpyrrolidone homopolymer or copolymer are present in said composition at a weight ratio of polybetaine polymer to vinylpyrrolidone homopolymer or copolymer of at utmost 1.5:1.Type: GrantFiled: July 9, 2010Date of Patent: October 1, 2013Assignee: The Procter & Gamble CompanyInventors: Annick Julia Oscar Mertens, Geert Andre Deleersnyder, Patrick Firmin August Delplancke, Stefano Scialla
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Patent number: 8545635Abstract: A hard floor surface care process comprising a process of identifying, cleaning, polishing, and protecting manmade and natural stone hard floor surfaces having a single surface or multi-surface quality. The hard floor surface care process comprising an acid reactive or nonreactive hard floor surface identifying process; an emulsifying solution, agitating, and toweling cleaning process; a polishing process utilizing a lubricating solution with a polishing chemistry or pad, and a protecting process utilizing a protecting chemistry selected as a function of the identifying process.Type: GrantFiled: June 27, 2012Date of Patent: October 1, 2013Inventor: Steven D. Azevedo
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Publication number: 20130252870Abstract: The present invention is related to a cleaning composition including at least one alkalinity source and a biodegradable terpolymer including maleic acid, vinyl acetate and alkyl acrylate segments or monomers for controlling scale. The diluted use solution has a pH between about 7 and about 11.5.Type: ApplicationFiled: March 23, 2012Publication date: September 26, 2013Applicant: ECOLAB USA INC.Inventor: Carter Silvernail
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Patent number: 8541357Abstract: Cleaning compositions and laundry detergents comprising amphoteric polymers are disclosed. The amphoteric polymers may be comb polymers having polycarboxylate backbones and polyalkoxylate tentacles. In particular, the amphoteric polymer includes: a cationic group structure unit derived from a cationic group-containing monomer; and a carboxyl structure unit derived from a carboxyl group-containing monomer. The cationic group structure unit may be present at a level of 1% to 99% by mass based on 100% by mass of all structure units derived from all monomers in the amphoteric polymer. The carboxyl structure unit may be present at a level of 1% to 99% by mass based on 100% by mass of all the structure units derived from all the monomers in the amphoteric polymer. The cleaning compositions have high anti-soil redeposition ability and solubility with surfactants.Type: GrantFiled: December 16, 2011Date of Patent: September 24, 2013Assignee: The Procter & Gamble CompanyInventors: Koushik Mukherjee, Kenneth Nathan Price, Yoneda Atsuro, Michitaka Daisuke
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Patent number: 8536106Abstract: The use of ferric hydroxycarboxylate as a chelator and builder for cleaning compositions is disclosed. The cleaning composition may be formulated for warewashing, laundering, and for other means of removing soils and includes a ferric hydroxycarboxylate, an alkalinity source and a surfactant system. The cleaning composition has a pH of between about 9 and about 12.Type: GrantFiled: April 14, 2010Date of Patent: September 17, 2013Assignee: Ecolab USA Inc.Inventor: Altony Miralles
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Patent number: 8524260Abstract: The invention consists of a method for manufacturing an aqueous formulation containing at least one oil, and comprising the steps of mixing at least one associative polymer, one oil, and water, encapsulating the oil by increasing the pH to a value greater than 8, potentially precipitating the mixture by reducing the pH to a value less than 6, and potentially isolating the resulting particles by removing the water. The aqueous formulations, as with the aqueous dispersions, and the resulting solid particles constitute other objects of the invention.Type: GrantFiled: December 3, 2008Date of Patent: September 3, 2013Assignee: Coatex S.A.S.Inventors: Jean Moro, David Platel, Jean-Marc Suau, Olivier Guerret
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Patent number: 8513178Abstract: The invention relates to methods and compositions for treating non-trans fats, fatty acids and sunscreen stains with a chelating agent. The invention also relates to methods for reducing the frequency of laundry fires with a chelating agent.Type: GrantFiled: September 17, 2010Date of Patent: August 20, 2013Assignee: Ecolab USA Inc.Inventors: Victor F. Man, Yvonne M. Killeen
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Patent number: 8496757Abstract: A cleaning solution and method for removing submicron particles from the surface and/or the bevel of an electronic substrate such as a semiconductor wafer. The cleaning solution comprises a polycarboxylate polymer or an ethoxylated polyamine. The method comprises the step of contacting a surface of the substrate with a cleaning solution comprised of a polycarboxylate polymer or an ethoxylated polyamine. Additional optional steps in the method include applying acoustic energy to the cleaning solution and/or rinsing the surface with a rinsing solution with or without the application of acoustic energy to the rinsing solution.Type: GrantFiled: July 22, 2012Date of Patent: July 30, 2013Assignee: Fontana TechnologyInventor: Mark Jonathan Beck
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Patent number: 8486883Abstract: The invention relates to the use of an anionic polymer in a liquid washing or cleaning agent for inhibiting graying when washing and/or cleaning textile web materials, and acrylic acid homopolymers comprising liquid washing and cleaning agents.Type: GrantFiled: January 13, 2012Date of Patent: July 16, 2013Assignee: Henkel AG & Co. KGaAInventors: Marc-Steffen Schiedel, Ulrich Pegelow, Peter Schmiedel, Evelyn Langen, Sabine Schümann, Martina Hutmacher, Heinz-Jürgen Völkel, Matthias Sunder, Birgit Glüsen, Cornelius Bessler, Timothy O'Connell, Stephan Gomolka, Eva-Maria Wikker
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Patent number: 8480808Abstract: A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, a synergistic combination of polyacrylic and polymaleic polymers is used as corrosion inhibitors in traditional alkaline detergent compositions.Type: GrantFiled: July 31, 2012Date of Patent: July 9, 2013Assignee: Ecolab USA Inc.Inventors: Erik Christian Olson, Devon Beau Hammel
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Patent number: 8450262Abstract: [Objective] This invention is to provide a novel copolymer suitably applicable to a detergent composition having an excellent precipitation inhibitory ability and showing a good washing effect even under severe conditions of washing with water used to take Japanese bath. [Solution] A laundry detergent or cleaning composition which comprises a hydrophobic group-containing copolymer characterized by having 1 wt % or more but below 50 wt % of a structural unit (a) derived from at least one kind of monomer (A) selected from ether bond-containing monomers.Type: GrantFiled: September 1, 2009Date of Patent: May 28, 2013Assignee: The Procter & Gamble CompanyInventors: Jeffrey Scott Dupont, Atsuro Yoneda, Akiko Hemmi
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Patent number: 8440601Abstract: A mixed powder or mixed granule for use in detergent formulations for machine dishwashing contains the following components: a) from 10 to 95% by weight of a copolymer of a1) from 50 to 93 mol % of acrylic acid and/or of a water-soluble salt of acrylic acid, a2) from 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid, and a3) from 2 to 20 mol % of at least one nonionic monomer, wherein monomers a1) to a3) are copolymerized in a random or block manner, b) from 5 to 80% by weight of a complexing agent selected from the group consisting of a glycine-N,N-diacetic acid derivative and glutamic acid N,N-diacetic acid and salts thereof, c) from 0 to 20% by weight of a polyethylene glycol, of a nonionic surfactant or of a mixture thereof.Type: GrantFiled: December 14, 2011Date of Patent: May 14, 2013Assignee: BASF SEInventors: Tanja Seebeck, Juergen Tropsch, Lars Kissau
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Patent number: 8420586Abstract: Cleaner compositions, associated cleaners, and associated methods are disclosed. The cleaner compositions are capable for use in making thickened cleaners that are capable of removing from vertical and inverted surfaces fresh, greasy soils and baked-on soils encountered in the food service industry. The cleaner compositions include one or more alkalinity sources, one or more chelants, one or more surfactants, one or more thickening agents, one or more buffers, and as a remainder, water. Cleaner compositions of the invention are substantially free of phosphates and have a low caustic content making them user and environmentally friendly. Yet the cleaners of the invention are surprisingly effective at removing tenacious baked-on soils encountered in the food service industry. Compositions of the invention have a viscosity of about 700 cps and are applied using a foaming or misting dispenser.Type: GrantFiled: September 2, 2010Date of Patent: April 16, 2013Assignee: Ecolab USA Inc.Inventors: Thomas J. Vinson, Karen O. Rigley, Tami J. Tadrowski
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Patent number: 8404626Abstract: One embodiment of the present invention is a method of fabricating an integrated circuit. The method includes providing a substrate having a metal and dielectric damascene metallization layer and depositing substantially on the metal a cap. After deposition of the cap, the substrate is cleaned with a solution comprising an amine to provide a pH for the cleaning solution of 7 to about 13. Another embodiment of the presented invention is a method of cleaning substrates. Still another embodiment of the present invention is a formulation for a cleaning solution.Type: GrantFiled: December 13, 2008Date of Patent: March 26, 2013Assignee: Lam Research CorporationInventors: Artur Kolics, Shijian Li, Tiruchirapalli Arunagiri, William Thie
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Patent number: 8375494Abstract: Cleaning compositions containing a corrosion inhibitor are provided for removing soil from carpets, upholstery and the like without subjecting common metal alloys used in aircraft and other constructions to corrosive attack. Cleaning compositions include at least one dispersing agent, at least one anti-redeposition agent, at least one corrosion inhibitor, at least one pH modifier, at least one chelating agent and at least one stabilizing agent. The compositions also optionally include at least one fragrance and/or at least one preservative agent. Methods for making and using the cleaning compositions are also described.Type: GrantFiled: April 30, 2010Date of Patent: February 19, 2013Assignee: Clean Control CorporationInventor: Cory S. Hammock
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Patent number: 8349783Abstract: The present invention provides compositions which not only effectively kill a broad spectrum of microorganisms present on surfaces on contact but continue to kill microorganisms for a period of time thereafter.Type: GrantFiled: October 5, 2011Date of Patent: January 8, 2013Assignee: Reckitt Benckiser LLCInventors: Timothy Michael Cusack, Karen McCue, Hubert W Ulmer
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Patent number: 8343903Abstract: There is disclosed a cleaning composition comprising (i) 0.1 to 10 percent by weight of the cleaning composition of a biofilm removing detergent solution comprising a combination of an alkyl (C8-18) polysaccharide, a non-ionic surfactant and a nitrogen containing surfactant-biocide (ii) 2 to 80 percent by weight of the cleaning composition of one or more polar solvent (iii) 0.5 to 15 percent by weight of the cleaning composition of one or more primary amine (iv) two or more chelating agents (v) 0.1 to 5.0 percent by weight of the cleaning composition of an alkaline buffer system providing a pH of about 11.5 to 13.3 in aqueous solution (vi) 0.005 to 5.0 percent by weight of the cleaning composition of an alkoxyaminosilane. Also disclosed is a process of cleaning, decontaminating and/or passivating metallic surgical instruments and/or equipment using the composition of the invention.Type: GrantFiled: July 16, 2009Date of Patent: January 1, 2013Assignee: Whiteley Holdings Pty LtdInventor: Reginald Keith Whiteley
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Patent number: 8343906Abstract: An alkaline liquid hand dish washing detergent composition to provide superior stain removal and superior stability during storage and use.Type: GrantFiled: December 13, 2010Date of Patent: January 1, 2013Assignee: The Procter & Gamble CompanyInventors: Jean-Luc Philippe Bettiol, Salua Morabet, Stefano Scialla
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Patent number: 8337608Abstract: A multi-purpose solvent includes a soy ester material and includes less than 25 Grams Per Liter (GPL) of Volatile Organic Compound (VOC) rating which permits the multi-purpose solvent to be used for cleaning in government regulated areas. The desire to reduce VOCs is well recognized. The multi-purpose solvent of the present invention performs as well as known cleaning products (for example, xylene or MEK) having greater than 25 grams per liter VOC products. Further, the multi-purpose solvent according to the present invention has less than one tenth of the hazardous ingredients present in the other multi-purpose solvents. The multi-purpose solvent is suitable for reducing water and oil based coatings and material and may be used as a cleaner or thinner.Type: GrantFiled: April 8, 2011Date of Patent: December 25, 2012Inventor: Steven H. Bortz
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Patent number: 8329634Abstract: A paint thinner and cleaner includes a methyl soy ester and dibasic ester and satisfies a less than 25 grams per liter Volatile Organic Compound (VOC) rating which permits the thinner and cleaner to be used for cleaning and thinning in government regulated areas. Requirements for reducing VOCs are well recognized. The paint thinner and cleaner of the present invention performs as well as products (for example, hydrocarbon based thinners) having greater than 25 grams per liter VOC products. Further, the paint thinner and cleaner according to the present invention has less than one tenth of the hazardous ingredients present in the other paint thinners. The paint thinner and cleaner is suitable for reducing water and oil based coatings and material.Type: GrantFiled: July 16, 2010Date of Patent: December 11, 2012Inventor: Steven H. Bortz
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Patent number: 8329631Abstract: An aqueous cleaning agent for hard surfaces which contains a surfactant combination of fatty alcohol ether sulfate and at least one further surfactant together with 10 to 40 wt. % of a water-soluble salt, may be used for manual dishwashing and is above all suitable for removing stubborn, burnt-on or dried-on soiling while being gentle on the skin.Type: GrantFiled: August 24, 2011Date of Patent: December 11, 2012Assignee: Henkel AG & Co. KGaAInventors: Detlef Buisker, Heinz-Dieter Soldanski
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Patent number: 8323416Abstract: One exemplary embodiment can be a process for removing one or more scale deposits formed on a surface. The process can include contacting the surface with a composition for a period of time sufficient to remove the scale deposits that comprise coke or metal sulfides or mixtures thereof. Generally, the composition includes an effective amount of an organic acid and/or a salt thereof, and an effective amount of an oxidizing agent.Type: GrantFiled: July 28, 2009Date of Patent: December 4, 2012Assignee: UOP LLCInventors: Steven A. Bradley, Walter Zamechek
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Patent number: 8303721Abstract: A phosphate-free dishwasher detergent which contains a builder, bleaching agents, and also a) a copolymer comprising i) monomers from the group of mono- or polyunsaturated carboxylic acids; ii) monomers of general formula R1(R2)C?C(R3)—X—R4; and iii) optionally further monomers, and b) a nonionic surfactant of general formula R1—CH(OH)CH2O-(AO)w-(A?O)x-(A?O)y-(A??O)z—R2. The detergent has good cleaning and rinsing results which are comparable to those of phosphate-containing dishwasher detergents or even outdo them.Type: GrantFiled: August 5, 2009Date of Patent: November 6, 2012Assignee: Henkel AG & Co. KGaAInventors: Nadine Warkotsch, Johannes Zipfel, Arnd Kessler, Christian Nitsch, Arno Dueffels, Thomas Holderbaum
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Patent number: 8293696Abstract: Compositions, such as alkali builder compositions for the laundry industry, are provided and include water, an alkali metal hydroxide component, a chelating component and a hydroxyethyliminodiacetic acid (HEIDA) component. Methods for producing such compositions are also disclosed.Type: GrantFiled: February 6, 2009Date of Patent: October 23, 2012Assignee: Ecolab, Inc.Inventors: Kevin P. McLaren, Joseph C. Drozd, Gordon Renn
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Patent number: 8293845Abstract: A method for increasing the efficacy of hydrophobically modified (meth)acrylic based polymers to increase the critical micelle concentration of a surfactant composition by attenuating the degree of neutralization (DN) of the polymer is disclosed.Type: GrantFiled: November 9, 2007Date of Patent: October 23, 2012Inventors: Krishnan Tamareselvy, William F. Masler, III, Deborah S. Filla, Gary Gray
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Publication number: 20120264673Abstract: A solvent blend cleaner useful for reflux cleaning of chemical manufacturing equipment, including that used in manufacturing pharmaceuticals, comprises a blend of environmentally friendly and safe solvents selected on the basis of specific criteria, such as vapor pressure, vapor density, boiling point, specific heat, and heat of vaporization, among other things; achieves excellent cleaning even upon further dilution with water; and avoids the disadvantages associated with the use of conventional commodity solvents in reflux cleaning methods. Desired solvency, cleaning and wetting properties of the inventive formulations in use can be achieved through blending of solvents having the selected criteria. Additives, such as surfactants, can be added to enhance cleaning and lower solvent requirements.Type: ApplicationFiled: April 13, 2011Publication date: October 18, 2012Applicant: AMERICAN STERILIZER COMPANYInventors: Shahin Keller, Nancy E. Kaiser
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Patent number: 8287657Abstract: A cleaning composition for hard surfaces containing a polymeric compound comprising a main backbone derived from at least the following monomeric components: (I) 20 to 99.9% by weight of at least one cationic monomer according to formula (I) wherein R1 and R2 are, independently of one another, hydrogen or C1-C4 alkyl; R3 and R4 are, independently of one another, hydrogen or alkyl, hydroxyalkyl, carboxyl alkyl, carboxyamide alkyl or alkoxyalkyl having from 1 to 18 carbon atoms; and Y represents an anion, and (II) 0.1 to 80% by weight of a hydrophobic unsaturated nonionic monomer that polymerizes in the presence of an initiator; optionally up to 60% by weight of a water-soluble monomer (III) which is different from either monomer (I) or monomer (II); and optionally reactant (IV), a crosslinking agent in an amount between 0 to 10% by weight, gives improved soil removal properties, antimicrobial and biofilm suppression properties as well as resistance to resoiling and staining.Type: GrantFiled: November 28, 2005Date of Patent: October 16, 2012Assignee: BASF SEInventors: Zhiqiang Song, Bingham Scott Jaynes, Jianwen Mao, Andrea Preuss
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Patent number: 8283306Abstract: An aqueous laundry detergent composition in the form of a liquid or gel, having a pH of from about 6 to about 11 in a 1% water solution and containing a non-soap anionic surfactant; soap; nonionic surfactant; fabric softening cationic cosurfactant having a molecular weight of less than about 1000; fabric softening quaternized polymer having a molecular weight of at least 100,000; non-quaternized, non polyamine thickener; perfume microcapsules; wherein at least one of the following is true; i) the ratio by weight of nonionic surfactant to anionic surfactant is greater than 1 and the total percentage, by weight of the composition, of the total of anionic surfactant, nonionic surfactant and soap is from 10% to 30%; and/or ii) the aqueous laundry detergent composition further comprises from about 0.5% to about 5% of a hydrotrope. Methods of laundering with such compositions.Type: GrantFiled: May 28, 2009Date of Patent: October 9, 2012Assignee: The Procter & Gamble CompanyInventors: Raphael Emmanuel Guyot, Marc Jennewein, James Charles Theophile Roger Burckett St. Laurent
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Publication number: 20120234359Abstract: A liquid hard surface detergent composition comprising a liquid mixed alkoxylate fatty alcohol non-ionic surfactant comprising a greater number of the lower higher alkoxylate group than the higher alkoxylate group in the molecule and a builder. The compositions provide good shine/anti-spotting characteristics on hard surfaces and are especially suitable for use as automatic dishwashing compositions.Type: ApplicationFiled: October 6, 2010Publication date: September 20, 2012Applicant: Reckitt Benckiser N.V.Inventors: Lucia Krubasik, Judith Preuschen, Andrea Stein, Pavlinka Roy
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Patent number: 8263540Abstract: A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, a synergistic combination of polyacrylic and polymaleic polymers are used as corrosion inhibitors in traditional alkaline detergent compositions.Type: GrantFiled: August 27, 2010Date of Patent: September 11, 2012Assignee: Ecolab USA Inc.Inventors: Erik Christian Olson, Devon Beau Hammel
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Patent number: 8262804Abstract: A phosphate-free detergent formulation for machine dishwashing, having from 1 to 20% by weight of a mixture of from 5 to 95% by weight of hydrophobically modified polycarboxylates I formed from 20 to 80 mol % of at least one monoethylenically unsaturated C3-C10-mono- or -dicarboxylic acid or anhydrides thereof, from 0 to 80 mol % of at least one monomer of the general formula (I) in which R1, R2 and R3 are each independently H, CH3 or C2H5, and R4 is a linear, branched or cyclic radical having from 1 to 6 carbon atoms or an aromatic radical having from 6 to 12 carbon atoms, and from 0 to 20 mol % of at least one further monomer, from 5 to 95% by weight of hydrophilically modified polycarboxylates II, where the sum of a1) and a2) adds up to 100% by weight.Type: GrantFiled: October 10, 2008Date of Patent: September 11, 2012Assignee: BASF SEInventors: Heike Weber, Roland Ettl, Juergen Tropsch
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Publication number: 20120208739Abstract: Liquid cleaning compositions are described herein that include a metal bleach catalyst which is a complex of a transition-metal and a macrocyclic ligand, the ligand having a calculated Octanol/Water Partition Coefficient value of from about ?1.50 to about ?0.10, a formulation enabling fraction comprising at least one formulation enabling ingredient, the formulation enabling fraction having a Hydrophilic Index of from about 4.0 to about 10.0, and a formulation deactivating fraction comprising at least one formulation deactivating ingredient that has a calculated Octanol/Water Partition Coefficient value of from about ?3.5 to about ?0.10.Type: ApplicationFiled: February 16, 2012Publication date: August 16, 2012Inventors: Robert Richard Dykstra, Mario Elmen Tremblay, Xiaoru Jenny Wang, James Lee Danziger, Daniel Dale Ditullio, JR., Consuelo Kong, Ismael Cotte-Rodriguez
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Patent number: 8227394Abstract: The embodiments of the present invention provide improved materials for cleaning patterned substrates with fine features. The cleaning materials have advantages in cleaning patterned substrates with fine features without substantially damaging the features. The cleaning materials are fluid, either in liquid phase, or in liquid/gas phase, and deform around device features; therefore, the cleaning materials do not substantially damage the device features or reduce damage all together. To assist removing of particles from the wafer (or substrate) surfaces, the polymeric compound of the polymers can contain a polar functional group, which can establish polar-polar molecular interaction and hydrogen bonds with hydrolyzed particles on the wafer surface. The polymers of a polymeric compound(s) with a large molecular weight form long polymer chains and network.Type: GrantFiled: November 7, 2008Date of Patent: July 24, 2012Assignee: Lam Research CorporationInventors: Ji Zhu, Arjun Mendiratta, David Mui
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Patent number: 8227381Abstract: Low molecular weight graft copolymer comprising a synthetic component formed from at least one or more olefinically unsaturated carboxylic acid monomers or salts thereof, and a natural component formed from a hydroxyl-containing natural moiety. The number average molecular weight of the graft copolymer is about 100,000 or less, and the weight percent of the natural component in the graft copolymer is about 50 wt % or greater based on total weight of the graft copolymer. Processes for preparing such graft copolymers are also disclosed.Type: GrantFiled: September 23, 2010Date of Patent: July 24, 2012Assignee: Akzo Nobel N.V.Inventors: Klin A. Rodrigues, Jannifer Sanders
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Patent number: 8202372Abstract: The invention relates to the use of polycarbonate-, polyurethane-, and/or polyurea-polyorganosiloxane compounds, or precursor compounds thereof containing specific reactive groups, in the treatment of hard surfaces. The treated surface is protected from soiling and/or the removal of soil from the surface is facilitated.Type: GrantFiled: October 2, 2009Date of Patent: June 19, 2012Assignee: Henkel AG & Co. KGaAInventors: Nadine Warkotsch, Birgit Middelhauve, Marc-Steffen Schiedel, Matthias Lueken
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Patent number: 8193139Abstract: The invention relates to a phosphate-free cleaning formulation for machine dishwashing, comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 93 mol % acrylic acid and/or of a water-soluble salt of acrylic acid, a2) 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid and a3) 2 to 20 mol % of at least one nonionic monomer of the formula (I), b) 1 to 50% by weight of complexing agents chosen from the group consisting of glycine-N,N-diacetic acid derivatives and glutamic acid-N,N-diacetic acid and salts thereof, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) 0 to 50% by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water, where the sum of componentsType: GrantFiled: August 28, 2006Date of Patent: June 5, 2012Assignee: BASF AktiengesellschaftInventors: Tanja Seebeck, Juergen Tropsch, Lars Kissau
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Patent number: 8192552Abstract: The invention relates to a detergent composition, suitable for use in dish washing or laundry, comprising at least 15% of a detersive surfactant(s), and a block copolymer, selected from the group consisting of (block A)-(block B) diblock copolymers, (block A)-(block B)-(block A) triblock copolymers, and (block B)-(block A)-(block B) triblock copolymers, wherein block A and block B derive from alpha ethylenically unsaturated monomers, at least one block being water-soluble. The detergent compositions provide an increased cleaning, and/or a decreased redeposition of the fatty substances once they are removed from a substrate.Type: GrantFiled: February 20, 2009Date of Patent: June 5, 2012Assignee: Rhodia ChimieInventor: Jeanne Chang
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Patent number: 8183196Abstract: A neutral automatic dishwashing detergent composition comprising an acidifying particle comprising an aminocarboxylic builder wherein the acidifying particle has a low hygroscopicity, a cake strength of at most 20N and a pH of from about 2 to about 6 as measured in 1% aqueous solution at 20° C.Type: GrantFiled: April 18, 2011Date of Patent: May 22, 2012Assignee: The Procter & Gamble CompanyInventors: Nigel Patrick Somerville Roberts, Chris Hughes, Robert Ian Dyson
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Publication number: 20120121523Abstract: A monomer compound that contains at least one polymerizable functional group per molecule, and at least one bicycloheptyl-, bicycloheptenyl-, or branched (C5-C42)alkyl-polyether radical per molecule, wherein the bicycloheptyl- or bicycloheptenyl-polyether radical may optionally be substituted on one or more of the ring carbon atoms by one or two (C1-C6)alkyl groups per ring carbon atom is useful in making polymers, particularly pH responsive polymers.Type: ApplicationFiled: November 7, 2011Publication date: May 17, 2012Applicant: RHODIA OPERATIONSInventors: Hui Shirley Yang, Derek Pakenham, Herve Adam, Pierre Hennaux, Brian Chung, Subramanian Kesavan, Seren Frantz
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Patent number: 8173585Abstract: The present invention relates to liquid acidic hard surface cleaning composition which are effective against common stains encountered on hard surfaces, methods for cleaning such hard surfaces as well as methods for the manufacture of said liquid acidic hard surface cleaning compositions.Type: GrantFiled: December 6, 2007Date of Patent: May 8, 2012Assignee: Reckitt Benckiser (UK) LimitedInventors: Victoria Heather Cobb, James Young
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Patent number: 8168578Abstract: A water-based composition for enhancing shine or gloss in an elastomeric surface is in the form of a stable aqueous dispersion having a pH of from about 6 to about 7 and containing by weight: (a) less than 10% of at least one polydiorganosiloxane fluid; (b) from about 0.02% to about 2.0% of an alkali-swellable acrylic homopolymer or copolymer crosslinked with a polyalkenyl polyether; and (c) water. In one embodiment, the composition contains less than 1% by weight of a wetting agent and has no additional surfactants, hydrotropes and emulsifying agents. The composition can be used to enhance shine or gloss in elastomeric surfaces such as rubber or vinyl, preferably automotive tires, by applying an effective amount of the composition to the surface and distributing the composition with an application implement. The composition contains less organopolysiloxane than commercial formulations but exhibits gloss-enhancing performance that is comparable or even higher than that exhibited by commercial compositions.Type: GrantFiled: July 17, 2007Date of Patent: May 1, 2012Assignee: The Armor AII/STP Products CompanyInventor: Ashot K. Serobian
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Patent number: 8163687Abstract: The present invention relates to a liquid composition, having a pH between 3 and 7, comprising a non ionic surfactant or a mixture thereof, an amine oxide or a mixture thereof, a glycol ether solvent, a chelant and a cationic polymer. The composition of the present invention does not contain any anionic surfactant. The present invention also encompasses a process of treating hard-surfaces, including delicate hard-surfaces located in bathrooms, wherein a liquid composition according to the present invention is applied onto said surfaces.Type: GrantFiled: November 14, 2007Date of Patent: April 24, 2012Assignee: The Procter & Gamble CompanyInventors: Fabienne Riou, Marina Jozefa Hermie
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Patent number: 8123867Abstract: The present invention relates to a phosphate-free machine dishwasher detergent comprising 0.01-20% by weight of at least one alcohol alkoxylate, 0.01-10% by weight of at least one alcohol ethoxylate, 0-15% by weight of at least one sulfonate-containing polymer, 0-15% by weight of at least one hydrophilically modified polycarboxylate, 0-8% by weight of at least one polycarboxylate, 1-50% by weight of at least one complexing agent and 0.1-60% by weight of at least one further additive, where the sum of components (A), (B), (C), (D), (E), (F) and (G) is 100% by weight, to a process for rinsing surfaces of articles by treating these surfaces with the composition, and to the use of the composition for increasing the rinsing performance in the machine washing of articles.Type: GrantFiled: April 24, 2008Date of Patent: February 28, 2012Assignee: BASF SEInventor: Juergen Tropsch
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Patent number: 8105999Abstract: The present invention provides compositions which not only effectively kill a broad spectrum of microorganisms present on surfaces on contact but continue to kill microorganisms for a period of time thereafter.Type: GrantFiled: August 26, 2009Date of Patent: January 31, 2012Assignee: Reckitt Benckiser Inc.Inventors: Timothy Michael Cusack, Karen Ann McCue, Herbert W. Ulmer
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Patent number: 8101027Abstract: The invention relates to detergent formulations for machine dishwashing which comprise copolymers having sulfonic acid and carboxylic acid functions, and to a method of using of such copolymers in machine dishwashing.Type: GrantFiled: July 31, 2007Date of Patent: January 24, 2012Assignee: BASF AktiengesellschaftInventors: Guido Vandermeulen, Lidcay Herrera Taboada, Tanja Seebeck
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Patent number: 8093196Abstract: A phosphate-free detergent formulation for machine dishwashing is provided. The formulation contains as main components: copolymers of a monoethylenically unsaturated monocarboxylic acid and/or of a salt thereof, and an alkoxylated, monoethylenically unsaturated monomer, wherein the copolymer has a mean molecular weight Mw of from 30 000 to 500 000 g/mol and a K value of from 40 to 150, measured at pH 7 in 1% by weight aqueous solution at 25° C.; complexing agents; low-foaming nonionic surfactants; bleaches and, optionally, bleach activators; further builders; enzymes; and one or more further additives.Type: GrantFiled: May 20, 2010Date of Patent: January 10, 2012Assignee: BASF SEInventors: Tanja Seebeck, Juergen Tropsch, Lars Kissau
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Patent number: 8080508Abstract: A chelating composition suitable for low-temperature use or storage is disclosed. The chelating compositions include 20 to 70 wt. percent of a polar solvent and 30 to 80 wt. percent of a first component of the formula: wherein R is a hydroxyalkyl group and each R? is individually selected from the group consisting of hydrogen, unsubstituted or inertly substituted alkyl groups, carbonyl-containing alkyl groups, carboxylate-containing alkyl groups, hydroxyalkyl groups and alkoxy groups; R? is selected from the group consisting of hydrogen, unsubstituted or inertly substituted alkyl groups; carbonyl-substituted alkyl groups, carboxylate-containing alkyl groups, hydroxyalkyl groups and alkoxy groups; M1 and M2 are alkali metal ions, wherein the M1 has a higher atomic weight than M2; wherein x+y=n and the mole fraction of M1 is greater than 0.70 to 1. Methods of suppressing crystallization and methods of cleaning surfaces employing the compositions described herein are also disclosed.Type: GrantFiled: July 26, 2011Date of Patent: December 20, 2011Assignee: Dow Global Technologies LLCInventors: Druce K. Crump, David A. Wilson
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Publication number: 20110256085Abstract: A composition for enhancing fluid viscosity including a mixture of at least one cationic or cationizable polymer and at least one anionic or anionizable (hydrolysable) polymer. The composition has a zeta potential at 25° C. in the range of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV, or is a precursor convertible at a temperature of 100 to 250° C. to the composition having a zeta potential at 25° C. of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV. Typically the compositions exhibit salt tolerance and interaction of both polymers at very high temperatures (>300° F.) such that the system exhibits an increase of viscosity at extreme temperatures. The compositions are useful for hydraulic fracturing, enhanced oil recovery, subterranean acidization, personal care as well as home and industrial cleaners.Type: ApplicationFiled: February 14, 2011Publication date: October 20, 2011Applicant: RHODIA OPERATIONSInventors: Ruela TALINGTING PABALAN, Nemesio Martinez-Castro, Subramanian Kesavan, Marie Pierre Labeau, Bruno Langlois