Heterogeneous Arrangement (e.g., Mixture Of Macroscopic Particles Differing In Physical Or Chemical Composition, Etc.; Liquid Component Encapsulated In Or Sorbed On Solid Material, Etc.) Patents (Class 510/438)
  • Patent number: 6417154
    Abstract: A sorbent material is provided comprising a porous substrate, such as a nonwoven web, having a wetting chemistry distributed substantially throughout the substrate. The wetting chemistry can comprise (a) an aliphatic alcohol ethoxylate; (b) one or more of an alkyl sulfosuccinate, an alkyl sulfate and a sulfated fatty acid ester and, optionally, (c) a fatty acid ester ethoxylate. Various formulations are provided having low metal ion concentrations, anti-static properties and/or good absorption characteristics for a broad spectrum of liquids.
    Type: Grant
    Filed: July 17, 2000
    Date of Patent: July 9, 2002
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ali Yahiaoui, Craig Farrell Thomaschefsky, Taiwoo Chiu
  • Patent number: 6410499
    Abstract: A cleaning wipe comprising a nonwoven fabric wherein the nonwoven fabric is impregnated with an antibacterial cleaning composition.
    Type: Grant
    Filed: December 7, 2001
    Date of Patent: June 25, 2002
    Assignee: Colgate-Palmolive Co.
    Inventors: Jean Julemont, Isabelle Leonard, Didier Dormal
  • Patent number: 6403549
    Abstract: The present invention relates to enzyme-containing granules comprising (a) an enzyme and (b) a core which intrinsically is capable of absorbing at least 5% w/w (based on the weight of the core) of water and to processes for the production of such granules comprises (a) contacting absorbent cores, capable of absorbing at least 5% w/w (based on the weight of the core) of water, with a liquid medium, such as an aqueous medium, containing an enzyme in dissolved and/or dispersed form, the amount of the liquid medium employed being such that substantially no attendant agglomeration of the resulting product occurs; and (b) at least partially removing volatile components of the liquid medium from the resulting product.
    Type: Grant
    Filed: April 13, 2000
    Date of Patent: June 11, 2002
    Assignee: Novozymes A/S
    Inventors: Joao F. De Lima, Eder Manzini Bordin, Erik Kjaer Markussen, Kirsten Boegh Levring, Michael Bonde, Erik Marcussen, Grethe Saugmann
  • Patent number: 6380152
    Abstract: A cleaning wipe comprising a nonwoven fabric wherein the nonwoven fabric is impregnated with an antibacterial cleaning composition.
    Type: Grant
    Filed: December 7, 2001
    Date of Patent: April 30, 2002
    Assignee: Colgate-Palmolive Co.
    Inventors: Jean Julemont, Isabelle Leonard, Didier Dormal
  • Patent number: 6380151
    Abstract: A detergent composition for use with a cleaning pad comprising an effective amount of a superabsorbent material, said pad preferably being part of a cleaning implement comprising a handle and said cleaning pad preferably being removable. The detergent composition contains a limited amount of a detergent surfactant, preferably linear in structure and relatively hydrophilic, the level of hydrophobic materials being kept below about 0.5%, and the pH being maintained above about 9, to allow the superabsorbent material to be readily absorbed by the superabsorbent material. The process of using the detergent composition with such a cleaning pad, and the provision of a kit containing both detergent composition and cleaning pad are disclosed.
    Type: Grant
    Filed: September 20, 1999
    Date of Patent: April 30, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Ronald Anthony Masters, Nicola John Policicchio, Alan Edward Sherry
  • Patent number: 6380153
    Abstract: Methods of producing surfactant compositions are disclosed in which processed plant material is used to enhance the saponification process to produce surfactant compositions having enhanced surfactant, mechanical cleaning and emollient characteristics. The plant material provides additional oils and triglycerides for reaction in the saponification process and provides an improved reaction interface, thereby producing surfactant compositions of improved character.
    Type: Grant
    Filed: January 29, 2001
    Date of Patent: April 30, 2002
    Inventor: Chris Carlson
  • Patent number: 6376443
    Abstract: A cleaning wipe comprising a water insoluble substrate being impregnated with a cleaning composition.
    Type: Grant
    Filed: November 14, 2001
    Date of Patent: April 23, 2002
    Assignee: Colgate-Palmolive Company
    Inventor: Jean Julemont
  • Patent number: 6376453
    Abstract: To provide detergent particles having high-speed dissolution capable of dissolving quickly in water after supplying the detergent particles in water, and a method for preparing the detergent particles, and a detergent composition comprising the detergent particles. Detergent particles having an average particle size of from 150 to 500 &mgr;m and a bulk density of 500 g/liter or more, wherein the detergent particles comprising a detergent particle being capable of releasing a bubble from an inner portion of the detergent particles in a process of dissolving the detergent particle in water, the bubble having a size of one-tenth or more of a particle size of the detergent particle, and wherein the detergent particles have a dissolution rate as calculated by Equation (1) of 90% or more, under conditions where the detergent particles are supplied in water at 5° C.
    Type: Grant
    Filed: July 22, 1999
    Date of Patent: April 23, 2002
    Assignee: Kao Corporation
    Inventors: Teruo Kubota, Hitoshi Takaya, Shu Yamaguchi, Hiroyuki Yamashita, Shuji Takana
  • Publication number: 20020042352
    Abstract: A sorbent material is provided comprising a porous substrate, such as a nonwoven web, having a wetting chemistry distributed substantially throughout the substrate. The wetting chemistry can comprise (a) an aliphatic alcohol ethoxylate; (b) one or more of an alkyl sulfosuccinate, an alkyl sulfate and a sulfated fatty acid ester and, optionally, (c) a fatty acid ester ethoxylate. Various formulations are provided having low metal ion concentrations, anti-static properties and/or good absorption characteristics for a broad spectrum of liquids.
    Type: Application
    Filed: November 5, 2001
    Publication date: April 11, 2002
    Inventors: Ali Yahiaoui, Craig Farrell Thomaschefsky, Taiwoo Chiu
  • Patent number: 6369020
    Abstract: A free-flowing granular detergent component comprises a high level (at least 30 wt %) of a heat-sensitive surfactant, preferably an alkyl ether sulphate; a water-insoluble silica or silicate carrier material of high oil absorption capacity; and a film-forming or crystal-forming structurant. The granular component may be used in conjunction with one or more other granular components containing surfactant and/or detergency builder, to form a particulate laundry detergent composition. The granular component is preferably prepared by mixing and granulation in a high- or moderate-shear mixer and drying in a fluidized bed.
    Type: Grant
    Filed: November 18, 1999
    Date of Patent: April 9, 2002
    Assignee: Unilever Home & Personal Care USA
    Inventors: Reinhard Kohlus, Remy Antal Verburgh, Gilbert Martin Verschelling
  • Patent number: 6362146
    Abstract: A personal washing composition containing a) surfactant selected from anionic, nonionic, zwitterionic and cationic surfactants, soaps and mixes thereof; b) polymeric deposition aid; c) encapsulated sunscreen.
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: March 26, 2002
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventor: Ernest Weatherley Macaulay
  • Patent number: 6355583
    Abstract: A versatile sorbent material is provided comprising a fibrous sheet having applied thereto a wetting chemistry comprising (i) a poly glycoside; (ii) a fatty acid ester ethoxylate; and (iii) one or more surfactants selected from the group consisting of alkyl and aryl alcohol ethoxylates, alkyl sulfonates and sulfates, alcohol ether sulfates, alkyl phosphates and phosphonates, alkyl sulfosuccinates and sulfated fatty acid esters. A sorbent material is provided having excellent electrical resistivity and good absorption properties for a broad range of liquids including paraffin oil, water, sulfuric acid and sodium hydroxide.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: March 12, 2002
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ali Yahiaoui, Gabriel Hamman Adam
  • Patent number: 6340663
    Abstract: The invention provides an improved cleaning wipe which requires no scrubbing, buffing, polishing or rinsing, with the following components: (a) a wipe which comprises at least one layer of absorbent/adsorbent material; (b) a liquid cleaner which comprises (i) a low residue surfactant; (ii) a hydrophilic polymer; and (iii) the remainder, water.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: January 22, 2002
    Assignee: The Clorox Company
    Inventors: Malcolm A. Deleo, Robert L. Blum, Maria G. Ochomogo, Paul A. Pappalardo, Elizabeth N. Swayne
  • Patent number: 6339059
    Abstract: A detergent tablet having at least two discrete regions each compacted from particulate composition, wherein a first said region consists of a compacted particulate composition containing swelling disintegrant such that the region increases in volume on contact with water, and in at least one direction through said region is flanked on both sides by one or more other regions which swell to a lesser extent on contact with water than said first region.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: January 15, 2002
    Assignee: Unilever Home & Personal Care, division of Conopco, Inc.
    Inventors: Peter William Appel, Jelles Vincent Boskamp, Anshu Mali Gupta, Christophe Michel Joueux, Marcel van der Kraan, Henning Wagner
  • Patent number: 6335313
    Abstract: In the detergent granules including 10% by weight or more of a nonionic surfactant and 1% by weight or more of a crystalline alkali metal silicate having an average particle size of from 1 to 60 &mgr;m, the detergent granules characterized in that a proportion of the nonionic surfactant to the crystalline alkali metal silicate is in a weight ratio of from 20/1 to 1/20, and that the iron content calculated as Fe in the crystalline alkali metal silicate is 140 ppm or less. The granular detergent composition characterized in that the granular detergent composition includes the detergent granules described above.
    Type: Grant
    Filed: April 28, 1998
    Date of Patent: January 1, 2002
    Assignee: Kao Corporation
    Inventors: Katsuhiko Kasai, Shu Yamaguchi, Hitoshi Takaya, Taiji Nakamae, Itsuro Tsukahara
  • Patent number: 6333301
    Abstract: An environmental protection-type aqueous detergent composition is provided, wherein enzymatic degradation effect is maximized and the use of surfactants is minimized. Said environmental protection-type particulate detergent composition comprises (a) 0.1-10% by weight of one or more detergent components selected from the group consisting of essential oils and essential oil components isolated or synthesized from said essential oils, (b) (i) 0.1-10% by weight of an oily surfactant for solubilizing said detergent components during impregnation and (ii) 0-20% by weight of a particulate surfactant, (c) an enzyme and (d) 10-90% by weight of an expanding agent and/or an enzymatic activity promoter, wherein the weight ratio of said (a) to (b) ranges from 1:0.5 to 1:15 and said (a) is impregnated into said (d).
    Type: Grant
    Filed: July 16, 1999
    Date of Patent: December 25, 2001
    Inventor: Akira Kamiya
  • Patent number: 6329331
    Abstract: An aqueous detergent composition, which is in the form of a thickened, mobile fluid, comprising foaming detergent and a polymer or polymer mixture which is capable of forming a reversible gel, which polymer or mixture is present in the composition as a multiplicity of individual gel particles.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: December 11, 2001
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Michael Paul Aronson, Charles Rupert Brown, Robert James Chatfield, Peter Fairley, Ian Timothy Norton, Jason Richard Williams
  • Patent number: 6303553
    Abstract: The present invention relates to a powdered automatic dishwashing composition disposed in a water soluble package that can be added directly into an automatic dishwasher.
    Type: Grant
    Filed: May 7, 2001
    Date of Patent: October 16, 2001
    Assignee: Colgate-Palmolive Company
    Inventor: Philip Gorlin
  • Patent number: 6294509
    Abstract: The invention relates to disintegrating particles formed by agglomerating primary particles at least part of which are insoluble in water, wherein the agglomeration of the disintegrating particles is disintegrated in an aqueous solution containing a water-soluble salt by lowering the concentration of the water-soluble salt. The invention also relates to a cleanser or detergent composition that includes the disintegrating particles, a water-soluble salt at a concentration lower than its saturated solubility, a surfactant and water. The composition has excellent physical (mechanical) cleanability and stability with time and gives users a pleasant feeling upon use. The composition does not cause damage to and itch on the skin because the disintegrating particles are disintegrated during cleansing and rinsing, and it is extremely good in rinsability.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: September 25, 2001
    Assignee: Kao Corporation
    Inventors: Zenbei Meiwa, Mamoru Nakamura, Tatsuki Matsumoto, Yoshihiro Hasebe, Hideyuki Hanazawa, Ritsuko Yamazaki
  • Patent number: 6294512
    Abstract: Detergent compositions contain sticky particles with at least 45% by weight of a sticky surfactant and non-sticky particles with less than about 1% by weight of sticky surfactant. The particles are further characterized by their size ranges and bulk densities. Compositions containing potassium ions are described. Dissolution of the compositions in aqueous media is optimized.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: September 25, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Paul R Mort, III, Kevin Todd Norwood
  • Patent number: 6291420
    Abstract: A system in the form of an aqueous dispersion or granules containing at least one liquid, waxy or pasty non-ionic surfactant and an alkali metal silicate. The system is prepared using a concentrated aqueous alkali metal silicate solution as the continuous liquid phase optionally containing glycerol, in which is dispersed at least one liquid, pasty or waxy non-ionic surfactant that is non-miscible or poorly compatible with said concentrated alkali metal silicate solution, and at least one non-ionic or anionic surfactant that is compatible with said concentrated alkali metal silicate solution and capable of causing the dispersion of said liquid, pasty or waxy non-ionic surfactant(s) in said concentrated alkali metal silicate solution. The resulting dispersion is optionally dried to produce a rigid alkali metal silicate shell encapsulating droplets or particles of the liquid, pasty or waxy non-ionic surfactant(s).
    Type: Grant
    Filed: September 21, 1998
    Date of Patent: September 18, 2001
    Assignee: Rhodia Chimie
    Inventors: Gilles Guerin, Daniel Joubert, Charles Phan, Kenneth Wong
  • Patent number: 6277809
    Abstract: The resin granule of the present invention for washing comprises a resin granule, a detergent component and, optionally, a third component, wherein the external surface of each particle of the resin granule is coated with the detergent component.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: August 21, 2001
    Inventor: Kenjiro Obama
  • Patent number: 6268322
    Abstract: The invention provides an at least dual compartment container containing at least one surfactant stripe and at least one multiple emulsion stripe. By dispensing a multiple emulsion stripe, greater deposition, particularly deposition of water soluble benefit agent (e.g., glycolic acid) is achieved than believed possible.
    Type: Grant
    Filed: October 22, 1999
    Date of Patent: July 31, 2001
    Assignee: Unilever Home & Personal Care USA, a division of Conopco, Inc.
    Inventors: Dale St. Lewis, Helen Elizabeth Knaggs, Mark Stephen Naser, Philippe Cham
  • Patent number: 6248706
    Abstract: The preparation of an activity-stable and low-dust enzyme granulate for washing and cleaning applications, e.g. for use in granular washing and cleaning agent compositions, is described. Also described are the activity-stable and low-dust enzyme granulates obtained in accordance with the method of preparation as well as their use in washing and cleaning applications. In addition, in a special aspect of the invention, the use of specially selected flours as auxiliary agents for the preparation of enzyme granulates for diverse application purposes is described.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: June 19, 2001
    Assignee: Genencor International, Inc.
    Inventors: Hubert A. Herrmann, Rolf Spannagl
  • Patent number: 6248709
    Abstract: A process for continuously preparing a free flowing agglomerate having a reduced level of resulting undesirable oversized granules is provided. The process comprises the steps of (a) thoroughly mixing a crystalline anionic surfactant paste with a sufficient amount of fine powders of starting detergent materials to form a free flowing agglomerate, then (b) thoroughly mixing a product of the step (a) with a non-crystalline anionic surfactant paste so as to form a free flowing agglomerate.
    Type: Grant
    Filed: August 25, 1999
    Date of Patent: June 19, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Manivannan Kandasamy, Kenji Naemura
  • Patent number: 6245732
    Abstract: A laundry agent delivery particle and granular compositions including the particle are provided. The particle comprises a porous carrier selected from the group consisting of Zeolite X, Zeolite Y and mixtures thereof with the porous carrier including a number of pore openings. The laundry release inhibitor is then incorporated into the porous carrier so that the cross-sectional area of the release inhibitor is larger than the cross-sectional area of the pore openings of the porous carrier. The laundry release inhibitor includes the residue of a deliverable agent such as a perfume component. The deliverable agent is then entrapped in the porous carrier until the release inhibitor is hydrolyzed thereby releasing the deliverable agent and allowing it to escape from the porous carrier.
    Type: Grant
    Filed: September 22, 1998
    Date of Patent: June 12, 2001
    Assignee: The Procter Gamble Co.
    Inventors: Lois Sara Gallon, Janet Sue Littig
  • Patent number: 6228825
    Abstract: The present invention relates to a nonaqueous liquid automatic dishwashing composition disposed in a water soluble package that can be added directly into an automatic dishwasher.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: May 8, 2001
    Assignee: Colgate Palmolive Company
    Inventors: Philip Gorlin, Dennis Calabro, Erinn Martin, Melissa Fiore, Van Canady
  • Patent number: 6225276
    Abstract: A process for washing textiles is presented involving the delayed release of ingredients from a detergent composition. The process involves first dissolving the detergent in water resulting in a pH below pH 8, slowly dissolving the coating on a coated alkalizing agent to raise the pH to above pH to above pH 8.5, and above pH 8.5 the polymeric acid coating on a detergent ingredient dissolves, releasing the ingredient into the wash water. Also presented is a detergent composition for delayed bleaching of 1 to 40 percent by weight of a coated bleaching agent having a coating which dissolves slowly in water irrespective of the pH value, 0.5 to 15 percent by weight of a bleach activator coated with a polymeric acid, and 0.1 to 40 percent by weight of an acidifying agent. The process results in a delayed release of bleaching in the wash cycle.
    Type: Grant
    Filed: August 6, 1999
    Date of Patent: May 1, 2001
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thomas Gassenmeier, Juergen Millhoff, Thomas Mueller-Kirschbaum
  • Patent number: 6221831
    Abstract: A free-flowing built particulate laundry detergent composition comprises: (i) at least 27% by weight of non-soap organic detergent surfactant, (ii) one or more detergency builders, but not more than 7% by weight of alkali metal aluminosilicate, the weight ratio of surfactant to builder being at least 1.2:1.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: April 24, 2001
    Assignee: Lever Brothers Company, division of Conopco, Inc.
    Inventors: William Derek Emery, Andreas Theodorus Groot, Terry Instone, Seeng Djiang Liem, Kenneth Metcalfe, Richard George Smith, Gilbert Martin Verschelling
  • Patent number: 6191095
    Abstract: A particulate detergent composition having a bulk density of 700 g/l or less and containing at least 10 wt % (preferably at least 15 wt %) of organic detergent surfactant comprises a base powder composed of at least two granular components. Less than 80% by weight, preferably less than 66% by weight, of the base powder has a compressibility (measured at 20-25° C. and about 40% relative humidity) of 17% or more. Preferably one of the components of the base powder is a granule containing a high level (at least 60 wt %) of anionic surfactant.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: February 20, 2001
    Assignee: Lever Brothers Company, a division of Conopco, Inc.
    Inventors: William Derek Emery, Terry Instone, Seeng Djiang Liem, Gilbert Martin Verschelling
  • Patent number: 6177397
    Abstract: A free-flowing agglomerated powder detergent process and the resulting composition includes from about 5% to about 80% of an alkali metal carbonate; from about 5% to about 50% of a detergent surfactant, and, up to about 25% of an alkali metal salt of a carboxylic acid, wherein the carboxylic acid is selected from the group of carboxylic acids that, below a first temperature, have a greater water solubility than the water solubility of its corresponding alkali-metal salt. The alkali metal salt is preferably provided solely by the reaction of (a) a premix comprising the alkali metal carbonate coated with the surfactant (b) a carboxylic acid selected from the group consisting of citric acid, malic acid, and mixtures thereof, and (c) water.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: January 23, 2001
    Assignee: Amway Corporation
    Inventor: David Scott Staley
  • Patent number: 6162781
    Abstract: Foam control granules, for use in particulate laundry detergent compositions, comprise a mobile hydrophobic foam control agent, preferably silicone oil in admixture with hydrophobic silica, optionally combined with a mixture of a hydrocarbon such as petroleum jelly and an alkylphosphoric acid salt, sorbed onto a porous absorbent inorganic carrier comprising or consisting of anhydrous sodium carbonate, preferably light soda ash. When such granules are prepared by mixing and granulating in a high shear mixer/granulator, the addition of from 1 to 10 wt % water after mixing and granulation results in granules having improved flow properties.
    Type: Grant
    Filed: August 12, 1999
    Date of Patent: December 19, 2000
    Assignee: Lever Brothers Company, div. of Conopco Inc.
    Inventors: Marinela Buscan, Francois Delwel, Angela Di-Pietro
  • Patent number: 6147048
    Abstract: The use of at least trihydric alcohols and their reaction products with ethylene oxide and/or propylene oxide as additive to particulate detergent formulations, especially compact detergents, to increase their rate of dissolving in water in amounts of from 0.1 to 5% by weight based on the detergent formulations.
    Type: Grant
    Filed: November 19, 1998
    Date of Patent: November 14, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Jurgen Huff, Hans-Ulrich Jager, Martin aus dem Kahmen, Matthias Kroner, Jurgen Alfred Lux, Gunter Oetter
  • Patent number: 6136772
    Abstract: The present invention relates to enzyme-containing granules comprising (a) an enzyme and (b) a core which intrinsically is capable of absorbing at least 5% w/w (based on the weight of the core) of water and to processes for the production of such granules comprises (a) contacting absorbent cores, capable of absorbing at least 5% w/w (based on the weight of the core) of water, with a liquid medium, such as an aqueous medium, containing an enzyme in dissolved and/or dispersed form, the amount of the liquid medium employed being such that substantially no attendant agglomeration of the resulting product occurs; and (b) at least partially removing volatile components of the liquid medium from the resulting product.
    Type: Grant
    Filed: May 14, 1997
    Date of Patent: October 24, 2000
    Assignees: Novo Nordisk A/S, Novo Nordisk Bio Industrial
    Inventors: Joao F. De Lima, Eder Manzini Bordin, Erik Kjaer Markussen, Kirsten Boegh Levring, Michael Bonde, Erik Marcussen, Grethe Saugmann
  • Patent number: 6130193
    Abstract: A laundry sheet is disclosed which is a substrate having a detergent composition applied thereto. The detergent composition contains a water insoluble silica gel to produce a laundry sheet having a dry hand. The laundry sheet provides a total laundering process that cleans and softens.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: October 10, 2000
    Assignee: Precision Fabrics Group, Inc.
    Inventor: Samuel Mark Gillette
  • Patent number: 6117830
    Abstract: A liquid detergent composition for cleaning hard surfaces comprising, a liquid washing medium, and globular particles having a mean particle diameter of 0.01 to 15 .mu.m which are insoluable in the liquid washing medium, with the provisos that the content of the globular particles in the composition is 0.1 to 30% by wt. and that the viscosity of the composition is 2 to 500 cps determined at 20.degree. C.
    Type: Grant
    Filed: January 7, 1998
    Date of Patent: September 12, 2000
    Assignee: Kao Corporation
    Inventors: Michio Yokosuka, Masashi Yoshikawa, Junichiro Nishiwaki, Masaki Tosaka, Yoshiyuki Watanabe
  • Patent number: 6114297
    Abstract: The detergent composition for clothes washing includes (I) surfactant components including:A) one or more sulfonate-type anionic surfactants; and B) at least one of nonionic surfactants and sulfate-type anionic surfactants, wherein a weight ratio of Component B to Component A is B/A=1/10 to 2/1; and(II) components including:C) one or more alkali metal silicates; and D) one or more metal ion capturing agents other than component C), wherein a weight ratio of Component C to Component D is C/D=1/15 to 5/1. Here, a total amount of the components (I) is from 20 to 50% by weight, and a total amount of the components (II) is from 30 to 80% by weight, and the detergent composition has a bulk density of 0.6 g/cc or more.
    Type: Grant
    Filed: September 9, 1998
    Date of Patent: September 5, 2000
    Assignee: Kao Corporation
    Inventors: Shu Yamaguchi, Hitoshi Tanimoto, Masaki Tsumadori
  • Patent number: 6107268
    Abstract: A sorbent material is provided comprising a porous substrate, such as a nonwoven web, having a wetting chemistry distributed substantially throughout the substrate. The wetting chemistry can comprise (a) an aliphatic alcohol ethoxylate; (b) one or more of an alkyl sulfosuccinate, an alkyl sulfate and a sulfated fatty acid ester and, optionally, (c) a fatty acid ester ethoxylate. Various formulations are provided having low metal ion concentrations, anti-static properties and/or good absorption characteristics for a broad spectrum of liquids.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: August 22, 2000
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ali Yahiaoui, Craig Farrell Thomaschefsky, Taiwoo Chiu
  • Patent number: 6100231
    Abstract: Aqueous concentrated liquid hard surface cleaning compositions which include: a pine oil constituent; organic solvent constituent; binary co-solvent system comprising alkyl biphenyl solvent and a co-solvent; and amine oxide surfactant constituent, and optionally but desirably at least one optional constituent.The liquid hard surface cleaning compositions feature excellent initial blooming characteristics, as well as good long term blooming retention.
    Type: Grant
    Filed: March 19, 1998
    Date of Patent: August 8, 2000
    Assignee: Reckitt & Colman Inc.
    Inventors: Tak Wai Cheung, Dennis Smialowicz
  • Patent number: 6083893
    Abstract: The present invention provides a firm, mild, good performing, low-smear semi-solid or solid dishwashing product. The rheology of the dishwashing product is such that structural elements have been separated from functional elements to obtain best structure properties and in-use properties. By using an interlocking mesh of carboxylic acid and/or neutralized carboxylic acid fibers and/or platelets to provide a support structure, the semi-solid or solid dishwashing product can be loaded with superior performing dishcare materials (e.g., mild surfactants) and appearance enhancers without dependence on surfactant-water phase behavior to provide the support structure. As a result, the present dishwashing product is milder than semi-solid dishwashing products currently on the market. The support structure of the present product, and preferably the use of hygroscopic surfactants, provide a product with lower smear than current gel dishwashing products.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: July 4, 2000
    Assignee: The Proctor and Gamble Co.
    Inventors: David Robert Zint, Mark Leslie Kacher, Tony Pace, Robert Owens
  • Patent number: 6077360
    Abstract: A cleaning composition for a mold for molding a semiconductor device comprising an unvulcanized rubber, a cleaning agent, and water in an amount of from 1 to 30% by weight based on the total amount of the cleaning composition.The cleaning composition is preferably used as a sheet form comprising the cleaning composition itself, wherein a plurality of straight cuts are formed on the surface of the sheet in a definite direction in parallel at an definite interval for enabling folding of the sheet and at least one cutting cut may be formed on the surface such that the cutting cut crosses perpendicularly to the plural cuts.The cleaning sheet is very effective to remove soiled material on the inside surfaces of a mold formed by repeatedly molding semiconductor devices using a thermosetting resin composition.
    Type: Grant
    Filed: March 26, 1999
    Date of Patent: June 20, 2000
    Assignee: Nitto Denko Corporation
    Inventor: Kouichi Takashima
  • Patent number: 6071429
    Abstract: Amide compositions useful for softening textile materials, such as fabrics. A concentrate composed of the amide softener and an alkylpolyglycoside is diluted to provide a softening solution of low viscosity stable over extended periods, which on application to a fabric provide improved hand (softeners) and scorch resistance.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: June 6, 2000
    Assignee: Henkel Corporation
    Inventors: James A. Wofford, Steve C. James
  • Patent number: 6069124
    Abstract: A detergent composition having a bulk density of at least 550 kg/m.sup.3 comprises a mixture of:(a) a granulate, preferably a mechanically mixed granulate, of bulk density 450 kg/m.sup.3 to 1300 kg/m.sup.3, comprising surfactant and inorganic material, and(b) a spray-dried adjunct comprising inorganic material, preferably sodium sesquicarbonate or Burkeite,component (a) being present in an amount of from 35% to 85% by weight of the total granular product.The adjunct allows the bulk density of the final composition to be adjusted to any chosen value without detriment to other properties, thus providing flexibility to formulate at a range of bulk densities.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: May 30, 2000
    Assignee: Lever Brothers Company Division of Conopco, Inc.
    Inventors: Peter Willem Appel, Marcel van der Kraan
  • Patent number: 6066613
    Abstract: The invention relates to hydrogel dispersions/particles capable of trapping water insoluble beneficial agent, yet capable of disintegrating smoothly to impart desirable in use characteristics.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: May 23, 2000
    Assignee: Lever Brothers Company
    Inventors: Liang Sheng Tsaur, Shiji Shen, Margaret Jobling, Michael Paul Aronson
  • Patent number: 6048830
    Abstract: A laundry agent delivery particle is provided. The particle comprises: a) a porous carrier selected from the group consisting of Zeolite X, Zeolite Y and mixtures thereof, the porous carrier including a number of pore openings; and b) a release barrier having at least one deliverable agent residue and at least one size enlarging agent residue, the deliverable agent residue being incorporated into the porous carrier, the size enlarging agent residue having a hydrophilic portion and a hydrophobic portion, the hydrophilic portion incorporated into the porous carrier and in conjunction with the deliverable agent residue forming the release barrier wherein the cross-sectional area of the release barrier within the porous carrier is larger than the cross-sectional area of the pore openings of the porous carrier. Preferred size enlarging agents include those having a fatty chain or alcohol chain in the hydrophobic portion, such as nonionic surfactants.
    Type: Grant
    Filed: September 22, 1998
    Date of Patent: April 11, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Lois Sara Gallon, William Richard Mueller, Robert Ya-Lin Pan
  • Patent number: 6025319
    Abstract: A laundry additive particle having multiple coatings and compositions employing the particle are provided. The laundry additive particle comprises a porous carrier core material; a first encapsulating material coated on the core material to form an intermediate layer, the first encapsulating material comprising a glassy material derived from one or more at least partially water-soluble hydroxylic compounds having an anhydrous, nonplasticized, glass transition temperature, T.sub.g, of at least about 0.degree. C.; and a second encapsulating material coated on the intermediate layer to form an outer layer, the second encapsulating material comprising a carbohydrate material having an anhydrous, nonplasticized, glass transition temperature, T.sub.g, of at least about 130.degree.0 C.; and the laundry additive particle has a hygroscopicity value of less than about 80%. Preferably, a laundry or cleaning agent such as a perfume is supported on or contained in the porous carrier.
    Type: Grant
    Filed: September 18, 1998
    Date of Patent: February 15, 2000
    Assignee: Procter & Gamble Company
    Inventors: Athanasios Surutzidis, Michael J. LeBlanc
  • Patent number: 6013614
    Abstract: A portable stain removal kit containing single use packets of various spotting agents and a stain guide directing use of the various spotting agents to effectively and professionally remove any type of known or unknown stain. The spotting agents include wet side spotting agents and a dry side spotting agent. Rinse solutions are provided to remove the wet side spotting agents. Non-woven, embossed, synthetic webs are impregnated with the various solutions and sealed within vapor-impervious packets. The stain guide features one side with stains removable by a single spotting agent and a second side with combination stains removable by two or more recommended spotting agents.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: January 11, 2000
    Inventor: John Mahdessian
  • Patent number: 5998360
    Abstract: Soluble alkali metal silicates combined with antiredeposition agents can actually have a beneficial effect on bleach stabilisation if said antiredeposition agents are intimately mixed with an alkali metal silicate solution, the resulting product being then dried (spray drying, turbo drying, etc . . . ) into granules.
    Type: Grant
    Filed: April 13, 1998
    Date of Patent: December 7, 1999
    Assignee: Crosfield Limited
    Inventors: Keith R Cockett, Theo J Osinga
  • Patent number: 5980580
    Abstract: A washing method characterized in that washing is carried out under conditions that a pH of a washing liquid starts increasing after a water hardness of the washing liquid starts decreasing; a detergent composition characterized by containing particles capable of delayed-exerting an alkalizing effect of a washing liquid, wherein a pH of a washing liquid starts increasing after a water hardness of the washing liquid starts decreasing; and a detergent composition comprising an alkalizing agent coated with an organic material, or organic and inorganic materials, the alkalizing agent occupying an amount of 70% by weight or more of the entire alkalizing agents in the detergent composition.
    Type: Grant
    Filed: May 1, 1997
    Date of Patent: November 9, 1999
    Assignee: KAO Corporation
    Inventors: Shu Yamaguchi, Katsuhiko Kasai, Yoko Yamaguchi, Shigeru Tamura, Masaki Tsumadori, Hiroyuki Yamashita
  • Patent number: 5955412
    Abstract: A powder blend of 95% Sodium metasilicate anhydrous and 5% sodium lauroyl sarcosinate which is hygroscopic. The mixture is formulated for effective use when 11.25 ounces are dissolved in one gallon of water or diluted up to six gallons of water. The constituent powders are added to the drum at their mixture ratio of 95% sodium metasilicate and 5% sodium lauroyl sarcosinate which will form the blend. The drum is resealed with the processing lid trapping only low moisture air inside. The drum is relocated to the blending machine which rolls and tilts the drum for blending for 30 minutes at 16 rpm, which ensures complete and uniform blending of the 2 constituent powders. Next, the drum is removed from the blending machine, and the processing drum lid is removed in the process room ensuring low moisture exposure. A filling lid is installed which includes an auger feed, and the drum is rotated and placed in the filling stand. An air motor is attached to the auger.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: September 21, 1999
    Inventors: Sarah E. Post, Donald J. Ashby, Benny Surratt