Aqueous Coating Agent Patents (Class 510/442)
  • Patent number: 6136777
    Abstract: A non-tower process for continuously preparing granular detergent composition having a density of at least about 600 g/l is provided. The process comprises the overall steps of: (a) dispersing a surfactant, and coating the surfactant with fine powder in a mixer, wherein first agglomerates are formed; (b) spraying finely atomized liquid onto the first agglomerates in a mixer, wherein second agglomerates are formed; and (c) granulating the third agglomerates in one or more fluidizing apparatus. The process is improved by further step (b'), by thoroughly mixing the second agglomerates in a mixer, between step (b) and step (c), wherein, in step (b'), choppers are used to reduce the amount of oversized agglomerates.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: October 24, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Angela Gloria Del Greco, Wayne Edward Beimesch, Manivannan Kandasamy
  • Patent number: 6121229
    Abstract: A non-tower process for continuously preparing granular detergent composition having a density of at least about 600 g/l is provided. The process comprises the overall steps of (a) dispersing a surfactant, and coating the surfactant with fine powder having a diameter from 0.1 to 500 microns, in a mixer, wherein first agglomerates are formed, (b) spraying on finely atomized liquid to the first agglomerates in a mixer, wherein second agglomerates are formed, and (c) the second agglomerates are thoroughly mixed in a mixer to provide rounding and growth.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: September 19, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Angela Gloria Del Greco, Manivannan Kandasamy
  • Patent number: 6087311
    Abstract: Tablets comprise a core and a coating, the core being formed by compressing a particulate material, the particulate material comprising surfactant and detergent builder, and the coating comprising dicarboxylic acid. The tablets are provided with effervescent agents, in the core or water-swellable desintegrant in the coating which aid in their disintegration in wash liquors. The invention also relates to processes for making the tablets.
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: July 11, 2000
    Assignee: The Proctor & Gamble Company
    Inventor: Paul Irma Albertus Van Dijk
  • Patent number: 6054425
    Abstract: Cleansing bars are formed from compositions containing an oil phase, particulate silica and a cleansing agent. The particulate silica is present in an amount to provide sufficient hardness to the composition to facilitate processing into a bar while maintaining good foaming despite a high oil content.
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: April 25, 2000
    Assignee: Imaginative Research Associates, Inc.
    Inventors: Jose E. Ramirez, Mohan Vishnupad
  • Patent number: 5998360
    Abstract: Soluble alkali metal silicates combined with antiredeposition agents can actually have a beneficial effect on bleach stabilisation if said antiredeposition agents are intimately mixed with an alkali metal silicate solution, the resulting product being then dried (spray drying, turbo drying, etc . . . ) into granules.
    Type: Grant
    Filed: April 13, 1998
    Date of Patent: December 7, 1999
    Assignee: Crosfield Limited
    Inventors: Keith R Cockett, Theo J Osinga
  • Patent number: 5958864
    Abstract: A process for producing a particulate amorphous alkali metal silicate having a molar ratio of M.sub.2 O to SiO.sub.2 of 1:1.5 to 1:3.3 bya) spray-drying an aqueous mixture of amorphous alkali metal silicate,b) impregnating the spray-dried amorphous alkali metal silicate with an aqueous dispersion or solution of detergent composition components containing at least one organic component, andc) optionally drying the impregnated amorphous alkali metal silicate.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: September 28, 1999
    Assignee: Henkel Kommandiggesellschaft auf Aktien
    Inventors: Rene-Andres Artiga Gonzalez, Hubert Freese, Manfred Greger, Kathrin Schnepp, Adolf Wiche
  • Patent number: 5898024
    Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled metal surfaces such as food fryers, baking pans, high temperature pasteurizers, and beer kettles, ceramic surfaces such as restaurant grade ceramic china plates and platters, and plastic surfaces. The cleaning composition is noncaustic and includes a peroxygen compound, a chelate, and a metasilicate and/or sesquisilicate. A preferred cleaning composition further includes a surfactant and hydrated builder.
    Type: Grant
    Filed: January 9, 1997
    Date of Patent: April 27, 1999
    Assignee: Charvid Limited Liability
    Inventor: Charles Bullick Talley
  • Patent number: 5891835
    Abstract: A cleaner impregnated towel comprises a flexible, porous substrate and, impregnated into the substrate, a cleaner formulation comprising d-limonene, dibasic acid ester, N-methyl-2-pyrrolidone, secondary alcohol ethoxylate, sodium lauryl sulfate, polysorbate 80, a salt of a coconut oil fatty acid ester of isethionic acid, glycerine, ethyl alcohol, an antimicrobial preservative, and optionally water.
    Type: Grant
    Filed: March 17, 1998
    Date of Patent: April 6, 1999
    Assignee: Dotolo Research Corporation
    Inventor: Jack T. Vlasblom
  • Patent number: 5792738
    Abstract: There is provided a granular, silicate-built, phosphate free laundry detergent composition comprising fine alkali metal percarbonate particles having mean particle diameter below 450 .mu.m, preferably below 400 .mu.m, wherein no more than 20%, preferably no more than 10%, of the particles have a diameter above 710 .mu.m, said particles having a coating comprising one or more soluble inorganic salts. The salts may be selected from alkali or alkaline earth metal carbonates, sulphates, chlorides and nitrates. The coated percarbonate particles have improved stability to storage and are capable of dissolving quickly in wash liquor.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: August 11, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Gerard Marcel Baillely, Anthony Dovey, Graham Alexander Sorrie, David William York
  • Patent number: 5789361
    Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled metal surfaces such as food fryers, baking pans, high temperature pasteurizers, and beer kettles, ceramic surfaces such as restaurant grade ceramic china plates and platters, and plastic surfaces. The cleaning composition is noncaustic and includes a peroxygen compound, a chelate, and a metasilicate and/or sesquisilicate. A preferred cleaning composition further includes a surfactant and hydrated builder.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: August 4, 1998
    Assignee: Charvid Limited Liability Co.
    Inventor: Charles Bullick Talley
  • Patent number: 5756445
    Abstract: A granular detergent component having a bulk density of less than 400 g/l comprises from 20% to 50%, by weight, of aluminosilicate, optionally up to 50%, by weight, of a co-filler, and 0.05% to 2%, by weight, of anionic surfactant, preferably C14-C20 alkyl sulphate. The low bulk density component is preferably mixed with other components such as percarbonate, silicate, layered silicate, carbonate, bicarbonate, sesquicarbonate, sulphate, citrate and mixtures thereof to provide a granular detergent composition.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: May 26, 1998
    Assignee: The Proctor & Gamble Company
    Inventors: Andrew Dorset, Robin Gibson Hall
  • Patent number: 5756447
    Abstract: A cleaning composition contains (a) a detersive surfactant and (b) a poly(amino acid) compound or a precursor thereof, the said component (b) being protected from contact with a level of alkalinity as would cause degradation thereof. The component (b) may be stabilized by, for example, coating it with an organic acid compound or with a film-forming polymer; by agglomerating it with a controlled level of alkaline or alkaline-reacting compound (e.g. sodium carbonate); by spray-granulating it in admixture with a nonionic surfactant; by encapsulating it with a silicone-based resin; or by incorporating it in a composition that is non-alkaline. The storage stability of the compositions is thereby improved.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: May 26, 1998
    Assignee: The Procter & Gamble Company
    Inventor: Robin Gibson Hall
  • Patent number: 5700294
    Abstract: Unique detergent compositions include a calcium precipitate-scavenging amount of an amorphous alkali metal silicoaluminate, advantageously are devoid of phosphate and zeolite values, and typically comprise at least one amorphous alkali metal silicoaluminate, an alkali metal carbonate, and at least one inhibitor of the crystal growth of calcium carbonate, such alkali metal carbonate being present in ionic calcium-removing amounts.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: December 23, 1997
    Assignee: Rhone-Poulenc Chimie
    Inventors: Patrick Boittiaux, Virginie Couvret, Daniel Joubert
  • Patent number: 5691294
    Abstract: Detergent components or compositions having a bulk density of at least 700 g/l comprise a nonionic surfactant system including at least one nonionic surfactant which is a liquid at temperatures below 40.degree. C., and from about 0.5% to 15% by weight of the component or compositions of a flow aid which is a premixed powder comprising sodium aluminosilicate and hydrophobic silica in a weight ratio of from 100:1 to 5:1. The detergent components or compositions are made by free dispersion mixing or granulation.
    Type: Grant
    Filed: December 11, 1995
    Date of Patent: November 25, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Paul Amaat Raymond Gerard France, Paul Irma Albertus Van Dijk
  • Patent number: 5665427
    Abstract: The invention relates to a process for stabilizing particulate alkali metal percarbonate by coating by coating it with an aqueous solution, preferably concentrated, of a complex formed from a boric acid or borate and an organic diol, polyol or hydroxycarboxylic acid, to the resulting coated product, and to compositions including the product. The coating can additionally contain an alkali metal neutral salt such as sodium chloride or sodium sulphate.
    Type: Grant
    Filed: May 30, 1996
    Date of Patent: September 9, 1997
    Assignee: Solvay Interox Limited
    Inventors: Graham Robert Horne, Alun Pryce James
  • Patent number: 5658873
    Abstract: Sodium percarbonate is often used in the form of coated particles to increase its storage stability in detergents.Sodium percarbonate particles coated in accordance with the invention have a coating containing reaction products from the reaction of a dialkali metal tetraborate or alkali metal pentaborate with aqueous hydrogen peroxide. Preferred coating components are: perborax with the formula Na.sub.2 B.sub.4 O.sub.7 .multidot.H.sub.2 O.sub.2, where n =2 or 4.The coated sodium percarbonate particles are produced by coating the percarbonate particles using a solution containing the reaction products mentioned above.Detergent, bleaching and cleaning compositions containing sodium percarbonate particles coated in accordance with the invention are distinguished by very high stability in storage.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: August 19, 1997
    Assignee: Degussa Aktiengesellschaft
    Inventors: Birgit Bertsch-Frank, Claas-Juergen Klasen, Thomas Lieser, Klaus Mueller, Martin Bewersdorf
  • Patent number: 5556834
    Abstract: A process for stabilizing percarbonate by coating by means of a coating agent according to which the percarbonate particles are treated with a concentrated aqueous solution containing at least one boron compound selected from meta and ortho boric acids and at least one silicate, following by removal of water to provide coated percarbonate particles. The solution is prepared by adding the boron compound to a solution of the silicate. The coated particles are useful in washing and bleaching compositions.
    Type: Grant
    Filed: June 21, 1995
    Date of Patent: September 17, 1996
    Assignee: Solvay Interox Limited
    Inventors: Alun P. James, Graham R. Horne