Nitrogen Attached Directly Or Indirectly To The Sulfoxy Group By Nonionic Bonding Patents (Class 510/494)
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Patent number: 5866040Abstract: A novel complex containing an ampholytic and/or semi-polar surfactant as well as a higher fatty acid, and if necessary, a clay mineral, and an emulsified composition containing this complex.Type: GrantFiled: July 27, 1994Date of Patent: February 2, 1999Assignee: Shiseido Company, Ltd.Inventors: Yasunari Nakama, Michihiro Yamaguchi, Kiyoshi Miyazawa, Takayuki Ohmura
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Patent number: 5861369Abstract: The present invention relates to compounds of the formula 1 ##STR1## wherein R.sub.1 is selected from hydrogen and -R.sub.4 -R.sub.5 where R.sub.4 is selected from nothing C.sub.1 -C.sub.20 linear or branched alkylene C.sub.3 -C.sub.20 cycloalkylene, C.sub.6 -C.sub.20 arylene, C.sub.7 -C.sub.20 alkarylene and C.sub.7 -C.sub.20 arlkylene; and R.sub.5 is one of hydrogen, hydroxy, --CO.sub.2 Z, phenyl hydroxyphenyl pyridyl, nitrophenyl, furyl, and thienyl; R.sub.2 and R.sub.3 are independently selected from a group of the formula --R.sub.4 --R.sub.6 ; where R.sub.4 is as defined above and R.sub.6 is one of hydrogen, hydroxy --CO.sub.2 Z. --CH(CO.sub.2 Z)--CH.sub.2 --CO.sub.2 Z and NR.sub.7 R.sub.8 ; where R.sub.7 and R.sub.8 are independently selected from a group of the formula: --(CH.sub.2)k--R.sub.g : where k.dbd.0-20 and R.sub.g is one of hydrogen, hydroxy, --CO.sub.2 Z. and --CH(CO.sub.2 Z)--CH.sub.2 --CO.sub.2 Z: wherein Y is selected from --CO.sub.2 Z. --SO.sub.3 Z and --C.dbd.Type: GrantFiled: February 29, 1996Date of Patent: January 19, 1999Assignee: Akzo Nobel nvInventor: Charles Navarro
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Patent number: 5817614Abstract: Bleach boosters comprising quaternary imine zwitterions are disclosed. The bleach boosters increase bleaching effectiveness in lower temperature solutions and demonstrate superior color safety profiles. The bleach boosters are ideally suited for inclusion into bleaching compositions including those with detersive surfactants and enzymes. Also provided is a laundry additive product including quaternary imine zwitterions. A method for laundering a fabric employing the bleach boosters of the present invention is also disclosed.Type: GrantFiled: August 29, 1996Date of Patent: October 6, 1998Assignee: Procter & Gamble CompanyInventors: Gregory Scot Miracle, Robert Richard Dykstra
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Patent number: 5801270Abstract: The present invention relates to an amine derivative represented by the following general formula (1): ##STR1## wherein R.sup.2 and R.sup.3 mean individually an alkyl or alkenyl group which may have --OH and has 1-24 carbon atoms, A denotes an alkylene or alkenylene group which may have at least one --OH, --COOH or --SO.sub.3 H and has 1-6 carbon atoms, Y.sup.1 is --COOH, --SO.sub.3 H or --OSO.sub.3 H, Y.sup.2 means --OH, --OSO.sub.3 H or --OCO--A--COOH, n stands for a number of 0 or 1, and p is an integer of 1-8, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.Type: GrantFiled: June 13, 1996Date of Patent: September 1, 1998Assignee: Kao CorporationInventors: Mitsuru Uno, Tomohito Kitsuki, Katsumi Kita, Yoshiaki Fujikura, Akiko Okutsu
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Patent number: 5783554Abstract: According to the invention, an improved class of surfactants having improved surfactant properties characterized as mild and environmentally safe have been provided comprising compounds of the formula: ##STR1## The anionic surfactants of the invention have at least two hydrophobic chains and at least two hydrophilic groups per molecule and are useful as emulsifiers,detergents, dispersant and solubilizing agents.Type: GrantFiled: June 30, 1997Date of Patent: July 21, 1998Assignee: Rhodia Inc.Inventors: Ji Li, Manilal Dahanayake, Robert Lee Reierson, David James Tracy
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Patent number: 5780421Abstract: A process for making a surfactant product involving the steps of: (1) providing a solid water-free sugar surfactant; (2) providing a co-reactant selected from the group consisting of alpha-olefins, internal olefins, linear alkylbenzene, branched alkylbenzene, fatty alcohol, alkoxylated fatty alcohol, secondary alkanes, N-methylglucamide, tall oil, napthalene, xylene, cumene, toluene, dodecylbenzene and mixtures thereof; (3) dispersing or dissolving the solid water-free sugar surfactant in the co-reactant to form a feed mixture; and (4) sulfating/sulfonating the feed mixture to form a surfactant product.Type: GrantFiled: May 13, 1996Date of Patent: July 14, 1998Assignee: Henkel CorporationInventors: Richard A. Winstanley, Harald P. Wulff
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Patent number: 5759979Abstract: Detergent mixtures containing a) alkyl and/or alkenyl oligoglycosides corresponding to formula (I)R.sup.1 O--?G!.sub.p (I)in which R.sup.1 is an alkyl or alkenyl radical containing 8 to 22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and p is a number of 1 to 10; b) fatty alcohol polyglycol ethers corresponding to formula (II) ##STR1## in which R.sup.2 represents alkyl radicals containing 6 to 14 carbon atoms, n is a number of 0.5 to 2 and m is a number of 2 to 10 and, optionally, c) amphoteric or zwitterionic surfactants and water, have synergistic effects in regard to their washing, dishwashing, foaming and cleaning performance and in regard to their skin-cosmetic compatibility. Accordingly, they are suitable for the production of a number of surface-active preparations, particularly manual dishwashing detergents.Type: GrantFiled: October 4, 1995Date of Patent: June 2, 1998Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Karl Schmid, Brigitte Giesen, Karin Koren
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Patent number: 5749923Abstract: A method for chlorine-free bleaching of denim textile material composed of warp yarn which is dyed with at least one of (a) indigo dye and at least one sulfur dye, and (b) at least one derivative of indigo dye and at least one sulfur dye, and weft yarn which is undyed and substantially white and which continues to be substantially white after bleaching to provide a denim textile material having a stylish gray cast.Type: GrantFiled: May 24, 1996Date of Patent: May 12, 1998Assignee: Degussa AktiengellschaftInventors: Vinzenz Olip, Norbert Steiner
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Patent number: 5733859Abstract: Acidic aqueous cleaning compositions containing a strong acid and maleic acid are disclosed. The maleic acid provides improved surface safety.Type: GrantFiled: September 11, 1996Date of Patent: March 31, 1998Assignee: The Procter & Gamble CompanyInventors: Michel Jean Carrie, Axel Koenig, Eddy Vos
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Patent number: 5719118Abstract: The disclosure is directed to polyalkoxylated amines used as foam stabilizers and a method for cleaning in which foam produced by a detergent composition is maintained for an extended period of time. Detergent compositions including the new foam stabilizers are also disclosed as are methods for detergent foam stabilization. The new foam stabilizers build or enhance foaming and are particularly useful because of their surprisingly mild, non-skin-irritating characteristics. Mildness is a requirement of components to be included in or used in applications such as liquid dish detergents, hand cleaners and car washes.Type: GrantFiled: October 30, 1995Date of Patent: February 17, 1998Assignee: Tomah Products, Inc.Inventors: Terry Crutcher, James A. Krogh
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Patent number: 5710116Abstract: Bleach boosters comprising zwitterionic imines and anionic imine polyions having a net negative charge are disclosed. The bleach boosters increase bleaching effectiveness in lower temperature solutions and demonstrate superior color safety profiles. The bleach boosters are ideally suited for inclusion into bleaching compositions including those with detersive surfactants and enzymes. Also provided is a laundry additive product including zwitterionic imines and anionic imine polyions with a net negative charge as bleach boosters. A method for laundering a fabric employing the bleach boosters of the present invention is also disclosed.Type: GrantFiled: August 29, 1996Date of Patent: January 20, 1998Assignee: The Procter & Gamble CompanyInventors: Gregory Scot Miracle, Michael Eugene Burns, Patti Jean Kellett, James Charles Theophile Roger Burckett-St. Laurent
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Patent number: 5705469Abstract: A process is disclosed for the manufacture of a liquid detergent composition comprising a sulphiting agent and an enzyme system. Said enzyme system and said sulphiting agent interact together so as to generate odors which result in an odor deviation in said detergent composition. In the process of the invention, said enzyme system and said sulphiting agent are intimately mixed together separately from the remainder of the detergent composition so as to generate said odors outside the remainder of said detergent composition. Also disclosed is an enzyme premix consisting essentially of said enzyme system and said sulphiting agent.Type: GrantFiled: April 20, 1995Date of Patent: January 6, 1998Assignee: The Procter & Gamble CompanyInventors: Alan David Blake, Jozef Philemona R. Geudens, Paul Andrew Hardy, Fabrice Francois J. Questel
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Patent number: 5696069Abstract: A detergent, personal cleansing or cosmetic composition comprising: a) one or more surfactants selected from anionic, nonionic, amphoteric, zwitterionic, and mixtures thereof, and which comprises at least one surfactant having a structure incorporating acyl taurate, b) quaternium cation, c) low HLB nonionic surfactants; and d) water, and wherein low HLB nonionic surfactants are in the form of a solution or dispersion.Type: GrantFiled: November 21, 1995Date of Patent: December 9, 1997Assignee: The Andrew Jergens CompanyInventors: Tsukasa Ito, David Story, Tomohiko Sano
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Patent number: 5693603Abstract: Novel bleaches, a method for bleaching substrates using these materials and detergent compositions containing same are reported. The bleaches are sulfanimines. Substrates such as fabrics may be bleached in an aqueous solution containing the sulfanimine and a peroxygen compound.Type: GrantFiled: April 30, 1996Date of Patent: December 2, 1997Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventor: Naresh Dhirajlal Ghatlia
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Patent number: 5599483Abstract: A N-alkylcarbamylalkanol sulfate or a salt thereof represented by the following general formula (1-1), a process for producing the same, and a detergent composition containing the same, which is useful as a detergent for hair, body or tableware and has not only excellent foaming power and detergency but also high safety: ##STR1## wherein R.sup.1 represents a linear or branched alkyl or alkenyl group having 6 to 22 carbon atoms; R.sup.2 represents an alkyl or alkenyl group having 1 to 22 carbon atoms or a hydrogen atom: R.sup.3 represents a linear or branched alkylene group having 1 to 5 carbon atoms; R.sup.4 O represents an oxyalkylene group having 2 or 3 carbon atoms; Ma represents a hydrogen atom, an alkali metal atom, an ammonium group, etc.; and n represents a number between 0 and 20.Type: GrantFiled: October 11, 1995Date of Patent: February 4, 1997Assignee: Kao CorporationInventors: Hiromoto Mizushima, Masakatsu Takahashi, Akira Yamamuro, Takashi Matsuo, Kazuyuki Yahagi
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Patent number: 5580847Abstract: An aqueous ammonia composition having low surface tension is disclosed, which comprises ammonia water and a fluoroalkylsulfonamide compound having the following general formula:R.sup.1 SO.sub.2 NR.sup.2 --X--H (I)wherein R.sup.1 represents a fluoroalkyl group, R.sup.2 represents a hydrogen atom or a lower alkyl group, X represents a grouping selected from CH.sub.2 COO and (CH.sub.2 CH.sub.2 O).sub.n, wherein n is a positive integer from 1 to 20. This aqueous ammonia composition may be mixed with an aqueous hydrogen peroxide solution and water so that it can be used for cleaning a semiconductor substrate. The cleaning solution has outstanding stability, and exhibits improved efficacy in removing microparticles of impurities and excellent surface-protecting effect on the semiconductor substrate that is useful in the manufacture of high density integrated circuit elements.Type: GrantFiled: June 7, 1995Date of Patent: December 3, 1996Assignees: Nissan Chemical Industries, Ltd., Kanto Kagaku Kabushiki KaishaInventors: Fumihiro Morikawa, Akihisa Yoshikawa, Norio Ishikawa, Takao Shihoya
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Patent number: 5576282Abstract: Bleach boosters comprising zwitterionic imines and anionic imine polyions having a net negative charge are disclosed. The bleach boosters increase bleaching effectiveness in lower temperature solutions and demonstrate superior color safety profiles. The bleach boosters are ideally suited for inclusion into bleaching compositions including those with detersive surfactants and enzymes. Also provided is a laundry additive product including zwitterionic imines and anionic imine polyions with a net negative charge as bleach boosters. A method for laundering a fabric employing the bleach boosters of the present invention is also disclosed.Type: GrantFiled: September 11, 1995Date of Patent: November 19, 1996Assignee: The Procter & Gamble CompanyInventors: Gregory S. Miracle, Michael E. Burns, Patti J. Kellett, James C. T. R. Burckett-St. Laurent
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Patent number: 5549715Abstract: A method for bleaching textile material, including preparing an aqueous alkaline solution of a bleaching agent composed of formamidine sulfinic acid and at least one carbohydrate having a general total formula C.sub.n H.sub.2n O.sub.n, the formamidine sulfinic acid and the at least one carbohydrate having a weight ratio with respect to one another which ranges from 80:20 to 99:1; and bleaching textile material composed at least in part of cellulose materials by contacting the textile material with the bleaching agent at a temperature above 50.degree. C. therefor.Type: GrantFiled: November 22, 1994Date of Patent: August 27, 1996Assignee: Degussa Austria GmbHInventor: Vinzenz Olip
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Patent number: 5540864Abstract: Aqueous, liquid hard surface detergent compositions contain zwitterionic detergent surfactant and monoethanolamine and/or other specific beta-aminoalkanols as solvents and/or buffers for improved spotting/filming and good cleaning. Some formulas do not contain large amounts of builders and are suitable for general purpose cleaning including cleaning of glass.Type: GrantFiled: June 2, 1995Date of Patent: July 30, 1996Assignee: The Procter & Gamble CompanyInventor: Daniel W. Michael
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Patent number: 5536451Abstract: Aqueous, liquid hard surface detergent compositions having good filming/streaking characteristics contain short chain amphocarboxylate detergent surfactant; hydrophobic, volatile cleaning solvent; and, optionally, zwitterionic detergent surfactant and/or monoethanolamine and/or other specific beta-aminoalkanols for improved filming/streaking and good cleaning. Preferred formulas do not contain large amounts of builders and/or other materials that contribute to bad spotting and filming and said formulas are suitable for general purpose cleaning including cleaning of glass.Type: GrantFiled: January 18, 1994Date of Patent: July 16, 1996Assignee: The Procter & Gamble CompanyInventors: Ronald A. Masters, Michael S. Maile, Martha R. Macy-Ruhe
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Patent number: 5531939Abstract: Concentrated liquid glass and window cleaning compositions are disclosed containing high levels of solvents and exhibiting improved cleaning performance and homogeneity in solution. A preferred formulation includes sodium methyl oleoyl taurate, dioctyl sodium sulfosuccinate, a glycol ether solvent mixture and water and other optional ingredients to provide a concentrated cleaning composition which can be diluted by the end user to desired strength. Another preferred embodiment discloses a method of using a concentrated liquid glass and window cleaning composition.Type: GrantFiled: March 23, 1994Date of Patent: July 2, 1996Assignee: Amway CorporationInventors: Kalliopi S. Haley, Jeffrey J. Fisher
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Patent number: 5531933Abstract: Aqueous, liquid hard surface detergent compositions having improved cleaning and good filming/streaking characteristics contain specific polycarboxylate detergent builders at critical levels. Preferred formulas contain a zwitterionic/anionic detergent surfactant mixture at levels (e.g., from about 0.02 to about 15%); hydrophobic solvent; alkaline material, especially volatile alkaline materials comprising monoethanolamine or certain beta-amino-alkanol compounds; and salt of ethylenediaminetetraacetic acid as the detergent builder in levels (e.g., from about 0.05% to about 0.5%, by weight of the composition).Type: GrantFiled: August 23, 1994Date of Patent: July 2, 1996Assignee: The Procter & Gamble CompanyInventors: Ronald A. Masters, Michael S. Maile, David C. Underwood, Michael J. Kupneski, Timothy C. Roetker