With Inorganic Phosphorus Containing Component Patents (Class 510/512)
  • Publication number: 20010008877
    Abstract: A cleaning medium for use in cleaning printing forms includes either an acid solution having a pH of from 1 to 4 or a basic solution having a pH of from 10 to 14. A dispersible abrasive agent in a concentration of from 1 to 15 grams per 100 grams of the cleaning composition, a surfactant in a concentration of from 1 to 50 grams per 100 grams of the cleaning composition, an organic solvent in a concentration of from 10 to 50 grams per 100 grams of the cleaning composition, and additional water if needed are added to the acid or basic solution to form the cleaning medium. A cleaning medium in concentrate form is also provided.
    Type: Application
    Filed: December 21, 2000
    Publication date: July 19, 2001
    Applicant: MAN Roland Druckmaschinen AG
    Inventors: Thomas Hartmann, Hans-Christoph Beltle, Andrea Fuchs, Roland Dietrich
  • Patent number: 6258764
    Abstract: A pink colored automatic dishwasher detergent composition is formulated as a gel-like aqueous product of exceptionally good physical stability, low bottle residue, low cup leakage, red color stability and improved cleaning performance.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: July 10, 2001
    Assignee: Colgate Palmolive Company
    Inventor: Philip Gorlin
  • Patent number: 6242403
    Abstract: A detergent tablet of compressed particulate composition, and a process of making such a tablet, wherein the tablet or a region thereof comprises organic detergent and detergency builder and the tablet or region thereof is compacted from a composition which contains: (A) particles containing at least 60% by weight of non-soap anionic detergent (B) particles containing at least 80% of their own weight of one or more water-soluble materials selected from compounds with a water-solubility exceeding 50 grams per 100 grams water at 20° C.; and sodium tripolyphosphate containing at least 50% of its own weight of the phase I anhydrous form.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: June 5, 2001
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Rene Lammers, Seeng Djiang Liem, Alastair Richard Sanderson, Bart Slenderbroek, Harmannus Tammes, Arie Vermaas, Gilbert Martin Verschelling, Ronaldus Wilhelmus Johannes Westerhout
  • Patent number: 6221826
    Abstract: A laundry additive particle having multiple coatings and compositions employing the particle are provided. The laundry additive particle comprises a central core particle with the core particle comprising a porous carrier core material and a glassy encapsulating material intermixed with the carrier material. The glassy encapsulating material is derived from one or more at least partially water-soluble hydroxylic compounds having an anhydrous, nonplasticized, glass transition temperature, Tg, of at least about 0° C. An optional intermediate encapsulating material may be coated on the central core particle. The intermediate encapsulating material may comprise a carbohydrate material having an anhydrous nonplasticized, glass transition temperature, Tg of at least about 130° C. Lastly, an external coating material is coated on the core particle or the intermediate encapsulating material which provides the laundry additive particle with a substantially non-tacky surface.
    Type: Grant
    Filed: September 20, 1999
    Date of Patent: April 24, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Athanasios Surutzidis, Brent Michael Heist, Michael Jude LeBlanc
  • Patent number: 6221835
    Abstract: Novel synthetic zeolite compositions of extremely small particle sizes that have increased loading capability, and process technology for producing such compositions are described. So far as is presently known, it has never been possible to form such compositions heretofore. The process technology involves, inter alia, contacting the zeolite cake formed in its production with a specified type of treating agent and then subjecting the treated zeolite to physical subdivision.
    Type: Grant
    Filed: June 25, 1999
    Date of Patent: April 24, 2001
    Assignee: Albemarle Corporation
    Inventors: Patrick C. Hu, Conrad J. Langlois, Jr., Dixie E. Goins, Joseph E. Coury
  • Patent number: 6211138
    Abstract: A non-tower process for continuously preparing granular detergent compositions having a density of at least of about 600 g/l comprises the steps of (a) dispersing a surfactant, and coating the surfactant with fine powder having a diameter from 0.1 to 500 microns, while wetting the surfactant coated with the fine powder with finely atomized liquid, in a mixer, wherein first agglomerates are formed and (b) granulating the first agglomerates in one or more fluidizing apparatus.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: April 3, 2001
    Assignee: The Procter & Gamble Company
    Inventor: Wayne Edward Beimesch
  • Patent number: 6211137
    Abstract: A non-tower process for continuously preparing granular detergent compositions having a density of at least of about 600 g/l comprises the steps of (a) dispersing a surfactant, and coating the surfactant with fine powder having a diameter from 0.1 to 500 microns, in a mixer, wherein first agglomerates are formed and (b) granulating the first agglomerates in one or more fluidizing apparatus.
    Type: Grant
    Filed: April 1, 1999
    Date of Patent: April 3, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Wayne Edward Beimesch, Jose Francisco Correa Romo, Steven Barrett Rogers
  • Patent number: 6194367
    Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled metal surfaces such as food fryers, baking pans, high temperature pasteurizers, and beer kettles, ceramic surfaces such as restaurant grade ceramic china plates and platters, and plastic surfaces. The cleaning composition is noncaustic and includes a peroxygen compound, a chelate, and a metasilicate and/or sesquisilicate. A preferred cleaning composition further includes a surfactant and hydrated builder.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: February 27, 2001
    Assignee: Charvid Limited Liability Co.
    Inventor: Charles Bullick Talley
  • Patent number: 6191089
    Abstract: An automatic dishwashing composition which is in the form of a tablet generally comprises an alkali metal phosphate detergent builder salt, an alkali metal carbonate, a lubricant, a dialkali metal disilicate, a nonionic surfactant, a polymer containing sulfonic acid groups, a wax coated chlorine bleach compound, and optionally an anionic surfactant.
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: February 20, 2001
    Assignee: Colgate-Palmolive Company
    Inventors: Philip Gorlin, Leonard Zyzyck, Gary Jakubicki
  • Patent number: 6191095
    Abstract: A particulate detergent composition having a bulk density of 700 g/l or less and containing at least 10 wt % (preferably at least 15 wt %) of organic detergent surfactant comprises a base powder composed of at least two granular components. Less than 80% by weight, preferably less than 66% by weight, of the base powder has a compressibility (measured at 20-25° C. and about 40% relative humidity) of 17% or more. Preferably one of the components of the base powder is a granule containing a high level (at least 60 wt %) of anionic surfactant.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: February 20, 2001
    Assignee: Lever Brothers Company, a division of Conopco, Inc.
    Inventors: William Derek Emery, Terry Instone, Seeng Djiang Liem, Gilbert Martin Verschelling
  • Patent number: 6167892
    Abstract: A method of washing pre-expanded particles having a substantially water insoluble inorganic compound attached thereto by contacting the pre-expanded particles with an aqueous washing solution of a water soluble compound. The water soluble compound has a solubility with water of at least 1 g/100 g of water and has 1-500 surface bonding functional groups and 1-500 hydrophilic functional groups. At least one of the surface bonding functional groups of the water soluble compound attaches to the water insoluble inorganic compound.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: January 2, 2001
    Assignee: Kaneka Corporation
    Inventors: Tomonori Iwamoto, Takema Yamaguchi, Minori Yamaguchi
  • Patent number: 6162777
    Abstract: An automatic dishwashing composition which is in the form of a tablet which generally comprises an alkali metal phosphate detergent builder salt, an alkali metal carbonate, a lubricant, a dialkali metal disilicate, a nonionic surfactant, a crosslinked polyacrylic acid polymer, a wax coated chlorine bleach compound, and optionally an anionic surfactant.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: December 19, 2000
    Assignee: Colgate-Palmolive Company
    Inventors: Philip Gorlin, Leonard Zyzyck
  • Patent number: 6156715
    Abstract: The dimensionally stable alkaline solid block warewashing detergent uses an E-form binder forming a solid comprising a sodium carbonate source of alkalinity, a metal corrosion protecting alkali metal silicate composition, a sequestrant, a surfactant package and other optional material. The solid block is dimensionally stable and highly effective in removing soil from the surfaces of dishware in the institutional and industrial environment. The E-form hydrate comprises an organic phosphonate and a hydrated carbonate.
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: December 5, 2000
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Victor F. Man, Keith E. Olson
  • Patent number: 6083895
    Abstract: A tabletted detergent composition comprises from 45% to 80% by weight of a builder system which is not fully hydrated and from 5% to 30% total water content, wherein the total water content comprises water derived from the builder system, optional ingredients and from added water, wherein the ratio of the total water content to added water content is from 100:1 to 5:4. The tablet exhibits improved hardness and strength.
    Type: Grant
    Filed: February 5, 1998
    Date of Patent: July 4, 2000
    Assignee: The Procter & Gamble Company
    Inventor: Jane Margaret Warwick
  • Patent number: 6025315
    Abstract: An automatic dishwashing composition which is in the form of a tablet generally comprises an alkali metal phosphate detergent builder salt, an alkali metal carbonate, a lubricant, a dialkali metal disilicate, a nonionic surfactant, optional a polymer containing sulfonic acid groups, a wax coated chlorine bleach compound, and optionally a solubilizing agent.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: February 15, 2000
    Assignee: Colgate Palmolive Company
    Inventors: Philip A. Gorlin, Steve Phillips
  • Patent number: 6017873
    Abstract: Two processes for producing agglomerated high density detergent compositions are provided. On process comprises blending secondary (2,3) alkyl sulfate with a detergency builder to form a homogeneous powder mixture which is agglomerated with a surfactant paste mixture comprising C.sub.10-20 linear alkylbenzene sulfonates, C.sub.10-20 alkyl sulfates, C.sub.10-18 alkyl ethoxy sulfates having from about 1 to about 7 ethoxy groups, alcohol ethoxylates and polyethylene glycol and drying the agglomerates. Another process comprises blending secondary (2,3) alkyl sulfate with a detergency builder to form a homogeneous powder mixture which is agglomerated with a liquid acid precursor of C.sub.10-20 linear alkylbenzene sulfonate so as to form an agglomerated detergent composition which has a density of at least about 650 g/l.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: January 25, 2000
    Assignee: The Procter & Gamble Compnay
    Inventors: Stephen William Sikra, James Bert Royston
  • Patent number: 5998345
    Abstract: An automatic dishwashing composition which is in the form of a tablet generally comprises an alkali metal phosphate detergent builder salt, an alkali metal carbonate, a dialkali metal disilicate, a nonionic surfactant, optional a polymer containing sulfonic acid groups, a wax coated chlorine bleach compound, and a hydrotrope.
    Type: Grant
    Filed: March 25, 1999
    Date of Patent: December 7, 1999
    Assignee: Colgate Palmolive Company
    Inventors: Philip Gorlin, Steve Phillips, Divaker Kenkare
  • Patent number: 5998358
    Abstract: The invention relates to compositions and methods for cleaning typically organic beverage and food soils. The cleaning composition is formulated to remove carbohydrate and proteinaceous soils from hard surfaces. The formulations of the invention are directed to remove carbohydrate and proteinaceous soils from beverage manufacturing locations such as soils arising in the manufacture of malt beverages, fruit juices, dairy products, etc.
    Type: Grant
    Filed: March 23, 1999
    Date of Patent: December 7, 1999
    Assignee: Ecolab Inc.
    Inventors: Brandon L. Herdt, David A. Halsrud
  • Patent number: 5981456
    Abstract: An automatic dishwashing detergent composition is described which contains an effective amount of a defined water soluble cationic or amphoteric polymer and a phosphate or nonphosphate builder. The polymers are soluble or dispersible to at least 0.01% by weight in distilled water at 25.degree. C. A method of using the polymers to prevent fading or corrosion of dishware is also described.
    Type: Grant
    Filed: July 23, 1997
    Date of Patent: November 9, 1999
    Assignee: Lever Brothers Company
    Inventors: Alla Tartakovsky, Joseph Oreste Carnali, Richard Gerald Gary
  • Patent number: 5962387
    Abstract: An automatic dishwashing composition which is in the form of a multilayer table comprises an alkali metal phosphate detergent builder salt, an alkali metal carbonate, a dialkali metal disilicate, a nonionic surfactant, an alkali metal metasilicate, optionally a polymer containing sulfonic acid groups, a wax coated chlorine bleach compound, and a hydrotrope.
    Type: Grant
    Filed: October 16, 1998
    Date of Patent: October 5, 1999
    Assignee: Colgate Palmolive Company
    Inventors: Philip Gorlin, Divaker Kenkare
  • Patent number: 5916868
    Abstract: A process for preparing a free-flowing high bulk density granular laundry detergent product comprises pre-blending a powder admixture comprising (1) between about 40-90 weight percent of a water soluble detergent builder wherein at least 70 weight percent of the detergent builder is sodium carbonate, and (b) between about 0.5-10 weight percent of alkali metal chloride salt, (2) forming a builder-surfactant powder by blending the step (1) admixture with between about 5-40 weight percent of a detergent active ingredient which is a blend of sulfated ethoxylated alcohols and nonionic ethoxylated alcohols, (3) subjecting the builder-surfactant powder to treatment with water under agglomerating conditions, and (4) drying the detergent composition to provide a free-flowing granular laundry detergent product having a bulk density of at least 650 grams per liter, and in which the detergent granule surfaces are coated with a glossy shell of alkali metal salt crystallites.
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: June 29, 1999
    Assignee: Church & Dwight Co., Inc
    Inventors: Louis R. Mazzola, Anthony J. Falotico
  • Patent number: 5914307
    Abstract: A process for preparing a high density detergent-composition is provided. The process comprises the steps of:a) drying detergent agglomerates to a free moisture content of less than about 7% by weight thereby forming substantially dry detergent agglomerates; andb) charging the substantially dry detergent agglomerates into a moderate speed mixer/densifier to densify the substantially dry detergent agglomerates to form a high density detergent having a density of at least about 900 g/l. In preferred embodiments, the process also comprises forming hydrated detergent agglomerates via the steps of hydrating an anhydrous hydratable detergent salt to a degree of hydration of at least about 60% and agglomerating the hydrated detergent salt by charging the hydrated detergent salt and additional detergent ingredients into a high speed mixer/densifier and agglomerating the hydrated detergent salt and additional detergent ingredients to form hydrated detergent agglomerates.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: June 22, 1999
    Assignee: The Procter & Gamble Company
    Inventors: Frank William DeNome, John Frederick Lange
  • Patent number: 5888313
    Abstract: A filter pouch cleaner, for cleaning coffee and tea makers, has a top and bottom filter layer made from tea bag paper. The top and bottom filter layers are joined together along and adjacent to their outer edges to form a sealed pouch therebetween. The pouch is filled with a powdered cleaner compound that includes trisodium phosphate, sodium metasillicate and sodium perborate, along with soda ash as a filler. To facilitate the biodegradability and the safety of the cleaner compound, tripolyphosphate and a trace of blue dye powder are included in the cleaner compound. To clean a brewbasket and dispenser of a coffee or tea maker, the filter pouch cleaner is placed in the brewbasket. The brewbasket is then placed above the dispenser and filled with hot water. The hot water soaks through the filter and dissolves the cleaner compound. The hot water and dissolved cleaner flows out of the brewbasket and fills the dispenser.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: March 30, 1999
    Assignee: Coffee Dispenser Cleaner Company, LLC
    Inventor: Steve F. West
  • Patent number: 5767061
    Abstract: The present invention pertains to a crystalline hydrated layered sodium silicate/amorphous sodium silicate composite material with predetermined hardness ion sequestration properties achieved by control of the process for forming the material, and a process for making the material. The process for producing the crystalline hydrated layered sodium silicate/amorphous sodium silicate composite consists of producing a crystalline sodium disilicate by heating a sodium silicate at a specified time and temperature. The resulting material may include amorphous material, and the crystalline sodium disilicate can be either alpha-phase or delta-phase disilicate. This crystalline sodium disilicate is then hydrolyzed with up to 50.0 milliequivalents per gram of either H.sub.3 O.sup.+0 ions or OH.sup.- ions. The resulting material can sequester Ca.sup.2+ ions, Mg.sup.2+ ions, or both, depending on the results desired, processing conditions, and starting materials used.
    Type: Grant
    Filed: January 22, 1997
    Date of Patent: June 16, 1998
    Assignee: PQ Corporation
    Inventors: Petra M. Gill, Eric von Rehren Borgstedt, Raymond P. Denkewicz, Jr.
  • Patent number: 5712232
    Abstract: An aqueous liquid cleansing composition, packaged in a foamer container, said composition comprising:(A) from 5 to 50% by weight of an anionic carboxylate surfactant; and(B) from 0.1 to 5% by weight of a salt.The aqueous liquid cleansing composition of the present invention shows an extremely low viscosity increase at a low temperature and can be easily pushed out from the foamer container even at a low temperature thus giving uniform foam. It is particularly suitable for a skin cleanser.
    Type: Grant
    Filed: September 14, 1995
    Date of Patent: January 27, 1998
    Assignee: Kao Corporation
    Inventors: Masaaki Moriyama, Hisateru Tanabe, Hideyuki Hanazawa, Yasushi Kajihara
  • Patent number: 5712236
    Abstract: A metal cleaning composition useful in an aqueous solution comprises an alkali metal salt and a corrosion inhibitor. The corrosion inhibitor is provided in the form of zinc phosphate compounds such as zinc orthophosphate.
    Type: Grant
    Filed: August 2, 1995
    Date of Patent: January 27, 1998
    Assignee: Church & Dwight Co., Inc.
    Inventors: Steven A. Bolkan, Steve Dunn, Gale Byrnes
  • Patent number: 5681808
    Abstract: The present invention relates to a detergent composition comprising at least 1 surfactant, at least 1 detergency builder, and a foam suppressor composition comprising an organosilicon compound as the base oil and silica. The detergent compositions of this invention do not require the use of a large amount of water during the rinsing stage and allow continuous suppression of foam at the rinsing stage after washing without impairing the detergency effect of the composition.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: October 28, 1997
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hideki Kobayashi, Hidetoshi Kondo
  • Patent number: 5670473
    Abstract: A method for forming solid cleaning agents starts with hydrated forms of salts that generally have considerably lower melting points in their hydrated forms. The hydrated salt cleaning agents are heated to form a melted cleaning suspension. Additional ingredients can be mixed into the melted cleaning suspension. These additional ingredients can be selected from the group consisting of nonionic surfactants, anionic surfactants, alkaline builders, multivalent metal sequestering agents, active enzymes, soil suspending agents, defoamers, oxygenated solvents, fragrances, optical brighteners and colorants. An alternative method involves the formation of a mixture of powder or granular cleaning composition components. These components include at least 15 percent by weight of a moderate melting point cleaning additive. A receptacle with the cleaning components is heated to a temperature above the melting point of the moderate melting point cleaning additive.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 23, 1997
    Assignee: Sunburst Chemicals, Inc.
    Inventor: William H. Scepanski
  • Patent number: 5663136
    Abstract: A process for the continuous preparation of a granular detergent composition or component having a bulk density greater than 650 g/l which comprises the steps of: i) dispersing a detergent active paste throughout a powder stream in a high speed mixer with a residence time of from 2 seconds to 30 seconds, ii) forming an agglomerate in a moderate speed mixer/agglomerator with a residence time of less than 2 minutes, in which, optionally, a finely divided powder may be added, iii) drying and/or cooling. Granular detergent compositions which are made by this process, and which have excellent solubility properties especially with respect to dispensing and rate of dissolution are also described.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: September 2, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Paul Van Dijk, Jose Luis Vega, Haydn Guy William Dickenson
  • Patent number: 5656583
    Abstract: A filter pouch cleaner for cleaning coffee and tea makers, has a top and bottom filter layer made from tea bag paper. The top and bottom filter layers are joined together along and adjacent to their outer edges to form a sealed pouch therebetween. The pouch is filled with a powdered cleaner compound that includes trisodium phosphate, sodium metasillicate and sodium perborate, along with soda ash as a filler. To facilitate the biodegradability and the safety of the cleaner compound, tripolyphosphate and a trace of blue dye powder are included in the cleaner compound.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: August 12, 1997
    Assignee: Coffee Dispenser Cleaner Company, LLC
    Inventor: Steve F. West