Aluminum Or Boron Containing Metal Silicate Component (e.g., Aluminosilicate, Zeolite, Etc.) Patents (Class 510/532)
  • Patent number: 11591231
    Abstract: An organotemplate-free synthetic process for the production of a zeolite of TON framework type structure is provided. The process includes the steps of: (1) preparing a mixture comprising: (a) an alumina-coated silica; (b) a source of an alkali metal; (c) an alcohol; (d) a source of hydroxide ions; (e) seed crystals comprising a zeolitic material having a TON framework type structure; and (f) water; and (2) crystallizing the mixture obtained in step (1).
    Type: Grant
    Filed: June 25, 2021
    Date of Patent: February 28, 2023
    Assignee: CHEVRON U.S.A. INC.
    Inventors: Joel Edward Schmidt, Adeola Florence Ojo, Cong-Yan Chen
  • Patent number: 8975056
    Abstract: Alpha-amylases from Bacillus subtilis (AmyE), variants thereof, nucleic acids encoding the same, and host cells comprising the nucleic acids are provided. Methods of using AmyE or variants thereof are disclosed, including liquefaction and/or saccharification of starch. Such methods may yield sugars useful for ethanol production or high fructose corn syrup production. In some cases, the amylases can be used at low pH, in the absence of calcium, and/or in the absence of a glucoamylase.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: March 10, 2015
    Assignee: Danisco US Inc.
    Inventors: Luis G. Cascao-Pereira, William A. Cuevas, David A. Estell, Sang-Kyu Lee, Scott D. Power, Sandra W. Ramer, Amr Toppozada, Louise Wallace
  • Patent number: 8859487
    Abstract: A perfume tester or perfume includes a granule containing a friable peripheral portion incorporating fragrant compounds, which disintegrates as a perfumed powder when the granule is applied onto the skin. A method for making the perfume tester or perfume is by granulation, and the granule can be used in particular for perfume testing.
    Type: Grant
    Filed: July 30, 2007
    Date of Patent: October 14, 2014
    Assignee: Laboratoires Docteur Gaetano Zannini
    Inventors: Jean-Pierre Mathonnet, Gaetano Zannini
  • Patent number: 8729008
    Abstract: The invention relates to solubilizers for metal ions and poorly soluble metal compounds, containing an oxidation product of starch hydrolysate as a solubilizing agent, to a method for solubilizing metal ions and to the use of said solubilizer.
    Type: Grant
    Filed: October 19, 2009
    Date of Patent: May 20, 2014
    Assignee: Suedzucker Aktiengesellschaft Mannheim/Ochsenfurt
    Inventors: Alireza Haji Begli, Markwart Kunz, Christine Kroener, Matthias Moser, Bart Levecke
  • Patent number: 8680031
    Abstract: Exfoliating compositions, such as soaps, scrubs, and muds, for conditioning skin. The compositions include a carrier and particles that are insoluble in the carrier. The carrier may include one of more of a surfactant and an emollient, among other ingredients. The particles preferably include calcium carbonate, one or more phyllosilicates, and a quartz group tectosilicate, preferably have a calcium carbonate equivalent of less than 90%, and preferably embody a schistose texture. The exfoliating compositions with such particles have unexpected moisturizing and skin-conditioning properties.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: March 25, 2014
    Assignee: Roanoke College
    Inventor: DorothyBelle Poli
  • Patent number: 8618039
    Abstract: A granular material for use in the treating of textile materials, comprising (i) a silicone material having at least one nitrogen containing substituent, (ii) an aluminosilicate carrier and (iii) a binder, preferably in conjunction with a surface active material. Also described is a process for preparing such granular materials, which comprises forming a water-in-oil emulsion of component (i) in conjunction with component (iii) by dispersing and agitating said components in water, followed by depositing said emulsion onto a free flowing powder form of component (ii), for example by spraying, and removing sufficient water from the product to obtain a free flowing granular material. The granules are useful in a process of treating textile materials in an aqueous medium, particularly where the textile material is denim. Preferably the granular material is added into the finishing steps of denim such as the desizing, the fading or the softening steps and helps with avoiding backstaining.
    Type: Grant
    Filed: December 11, 2007
    Date of Patent: December 31, 2013
    Assignees: Dow Corning India, Dow Corning Corporation
    Inventors: Ganesh Srinivasan, Anick Colson, Alice Devinat, Jacqueline L'Hostis, Padmadas Nair
  • Patent number: 8323945
    Abstract: Alpha-amylases from Bacillus subtilis (AmyE), variants thereof, nucleic acids encoding the same, and host cells comprising the nucleic acids are provided. Methods of using AmyE or variants thereof are disclosed, including liquefaction and/or saccharification of starch. Such methods may yield sugars useful for ethanol production or high fructose corn syrup production. In some cases, the amylases can be used at low pH, in the absence of calcium, and/or in the absence of a glucoamylase.
    Type: Grant
    Filed: June 5, 2009
    Date of Patent: December 4, 2012
    Assignee: Danisco US Inc.
    Inventors: Luis G. Cascao-Pereira, William A. Cuevas, David A. Estell, Sang-Kyu Lee, Scott D. Power, Sandra W. Ramer, Amr Toppozada, Louise Wallace
  • Patent number: 8318652
    Abstract: This invention relates to non-bleeding and quick color releasing colored speckles for use in granular laundry detergents and other consumer products. The speckles are comprised of a porous carrier, a releasing agent, and a coloring agent.
    Type: Grant
    Filed: August 6, 2010
    Date of Patent: November 27, 2012
    Assignee: Milliken & Company
    Inventors: Gregory Fernandes, Eduardo Torres
  • Publication number: 20100261633
    Abstract: Detergent builder granules containing (component A) a water-soluble inorganic salt containing an inorganic salt having and/or being capable of forming a hydrate crystal and (component B) a clay mineral, wherein the component B is contained in an amount of 60% by weight or less, the component A and the component B are in a weight ratio, i.e. A/B, calculated as an anhydrate, of from 5/95 to 80/20, and a percentage of water loss upon heating to a temperature of 200° C. is from 3 to 30% by weight. According to the present invention, the detergent builder granules for laundry detergents having excellent dispersibility in cold water and a detergent composition containing the detergent builder granules can be obtained.
    Type: Application
    Filed: October 20, 2008
    Publication date: October 14, 2010
    Inventors: Kazuo Oki, Toshima Kume, Motomitsu Hasumi, Tadanobu Asada, Yuya Kozaki, Jun Kozuka
  • Patent number: 7638476
    Abstract: Aqueous washing and cleaning agents that contain capsules in addition to other constituents, the capsules each encompassing an active ingredient in a matrix. The introduction of a combination of aluminum silicate and silicic acid into the matrix improves the solubility characteristics of the capsules in a washing operation.
    Type: Grant
    Filed: February 8, 2008
    Date of Patent: December 29, 2009
    Assignee: Henkel AG & Co. KGaA
    Inventors: Bernhard Orlich, Bernd Richter, Sören Hölsken, Stefan Van Der Burgh
  • Patent number: 7637271
    Abstract: A cleaning composition with a limited number of ingredients contains a polyaluminum compound and surfactant. The cleaning composition optionally has an additional amount of fragrance. The cleaning composition optionally has a small amount of solvent. The cleaning composition optionally comprises a comprises a group selected from the group consisting of a dye, a builder, a fatty acid, a colorant, a preservative, a chelating agent, a colloidal silica and mixtures thereof.
    Type: Grant
    Filed: October 30, 2008
    Date of Patent: December 29, 2009
    Assignee: The Clorox Company
    Inventors: Scott Cumberland, Maria Ochomogo
  • Patent number: 7585825
    Abstract: Particles which comprise a specified inorganic carrier material, perfume and nonionic surfactant(s) in quantities of at least 0.1% by weight, a method for producing the particles, a detergent composition comprising the particles, and a method for washing textiles with the aid of the detergent composition.
    Type: Grant
    Filed: October 10, 2006
    Date of Patent: September 8, 2009
    Assignee: Henkel AG & Co. KGaA
    Inventors: Rene-Andres Artiga Gonzalez, Stefan Hammelstein, Hubert Harth, Jürgen Hilsmann, Mario Sturm, Andreas Bauer, Wolfgang Lahn
  • Patent number: 7560093
    Abstract: The present invention provides a process for the preparation of detergent builder Zeolite-A from Kimberlite tailing generated as solid waste during diamond mining is disclosed. The process comprises, reacting an acid treated Kimberlite tailing with alkali solution to obtain sodium silicate and reacting it with alkaline aluminum source at room temperature and crystallizing at higher temperature to obtain Zeolite-A. The product is useful as builder in detergent formulation.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: July 14, 2009
    Assignees: Council of Scientific and Industrial Research, National Mineral Development Corporation Limited
    Inventors: Raksh Vir Jasra, Rajesh Shantilal Somani, Haresh Mahipatlal Mody, Hari Chand Bajaj, Jatin Rameshchandra Chunawala, Hemal Ranpara, Dipti Barochiya, Devendra Ghelani, Suresh Chandra, Maharaj Kishen Dhar, Keshav Rao, Kamlesh Kumar
  • Patent number: 7517366
    Abstract: A multiuse laundry cleaning device in a solid state containing a homogeneous quantity of cleaning agent configured to dissolve and release a substantially consistent quantity of cleaning agent over a plurality of laundry wash and rinse cycles. The cleaning agent includes a gas-releasing component, potassium silicate as a solubility control component to limit the solubility of the cleaning agent, an alkalinity agent as a pH regulator, and a water softener to solvate metal ions in a solution of water. Controlled dissolution of the cleaning agent composition releases a desired quantity of cleaning agent in each cleaning cycle over a plurality of cycles. A porous covering of bag may be disposed around the solid cleaning agent.
    Type: Grant
    Filed: February 10, 2005
    Date of Patent: April 14, 2009
    Assignee: Eco-Safe Technologies, LLC
    Inventors: K. Donald Evans, Cory E. Cook, Eddie Caruthers, Jr.
  • Patent number: 7517848
    Abstract: A multiuse cleaning device in a solid state containing a homogeneous quantity of cleaning agent configured to dissolve and release a substantially consistent quantity of cleaning agent over a plurality of wash and rinse cycles. The cleaning agent includes a gas-releasing component and potassium silicate as a solubility control component to limit the solubility of the cleaning agent. The cleaning agent may include other ingredients such as an alkalinity agent as a pH regulator, a water softener to solvate metal ions in a solution of water, an optical brightener, an anti-redeposition agent, fragrances, surfactants, and other ingredients. Controlled dissolution of the cleaning agent composition releases a desired quantity of cleaning agent in each cleaning cycle over a plurality of cycles. A porous enclosure may be disposed around the solid cleaning agent.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: April 14, 2009
    Assignee: Eco-Safe Technologies, LLC
    Inventors: K Donald Evans, Cory E. Cook
  • Patent number: 7470654
    Abstract: The present invention relates to a detergent auxiliary composition comprising: (i) a liquid or liquefiable active component; and (ii) a water-insoluble solid support component and (iii) a water-soluble and/or water dispersible encapsulating material; and (iv) optionally one or more adjunct components, characterised in that the composition further comprises (v) a surface deposition enhancing cationic polymer or oligomer having cationic groups such that fewer than 50% are de-activated when a 1% by weight solution of the polymer or oligomer (prepared in deionised water and then adjusted to pH 7.0 with sodium carbonate or citric acid) is stored at 25° C.
    Type: Grant
    Filed: September 6, 2005
    Date of Patent: December 30, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Fabrizio Meli, Andre Chieffi, Rebecca Louise Selway, Stefan Frenzel
  • Patent number: 7211555
    Abstract: A process for efficiently preparing fine zeolite particles comprising synthesizing zeolite in the presence of an alkaline earth metal-containing compound and/or with controlling the preparation process of zeolite, thereby giving fine zeolite particles being composed of crystalline aluminosilicate, the fine zeolite particles having a fine average primary particle size, being excellent in the cationic exchange properties and the oil-absorbing ability, having a fine average aggregate particle size, and being excellent in the dispersibility; fine zeolite particles obtainable by the above process; and a detergent composition comprising the fine zeolite particles, the detergent composition being excellent in the detergency.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: May 1, 2007
    Assignee: Kao Corporation
    Inventors: Kazuo Oki, Hiroji Hosokawa, Mikio Sakaguchi, Hiroshi Kitagaito, Kazuo Taguchi, Hitoshi Takaya
  • Patent number: 7105477
    Abstract: The liquid detergent composition is provided with a high detergency and ensuring a good dispersion stability of builder particles and comprises a liquid dispersion containing (a) 30 mass % or more of a specific inorganic builder particle and (b) a block or graft polymer having a carboxyl group (i) and a polymer chain (ii), having, as its structural unit, an alkyleneoxy group, the composition having a viscosity (25° C.) of 3000 mPa·s or less and a volumetric separation rate (25° C., allowed to stand for 30 days) of 5% or less.
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: September 12, 2006
    Assignee: Kao Corporation
    Inventors: Osamu Takiguchi, Koji Yui, Takashi Oda
  • Patent number: 6964945
    Abstract: The invention relates to solid detergent compositions comprising an aluminosilicate builder and an anionic surfactant and comprising (n) components (i), n being at least 2, whereby the level of aluminosilicate builder in said components together is at least 5% by weight of the composition and the level of the anionic surfactant in said components together is at least 5% by weight of the composition, and whereby the degree of mixture (M) of the anionic surfactant and the aluminosilicate builder is from 0 to 0.7, as defined in the description.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: November 15, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Richard Timothy Hartshorn, Zayeed Alam, Kevin Norwood
  • Patent number: 6908895
    Abstract: A particulate zeolite-built laundry detergent composition having a bulk density of at least 550 g/l comprising at least two different granular components containing both surfactant and builder, preferably one prepared by non-tower granulation and another spray-dried, also contains from 1 to 10 wt % citric acid admixed as a separate particulate component. The admixed citric acid improves dispensing and dissolution properties, whether or not separately admixed sodium carbonate is present.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: June 21, 2005
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Vera Johanna Bakker, Arie Krijgsman, Edwin Leo Lempers, Jasper Mol
  • Patent number: 6894019
    Abstract: Base particles for supporting a surfactant, obtainable by a step of spray-drying a slurry comprising (A) a zeolite having an average aggregate particle diameter of 15 ?m or less and a variation coefficient of a distribution of an aggregate particle diameter of 29% or less, (B) a water-soluble polymer; (C) a water-soluble salt, and (D) a surfactant in an amount of 5% by weight or less of the slurry; detergent particles comprising the base particles; and a zeolite for a laundry detergent, wherein the zeolite has an average aggregate particle diameter of 15 ?m or less and a variation coefficient of a distribution of an aggregate particle diameter of 29% or less; and a process for preparing base particles for supporting a surfactant, comprising a step of spray-drying a slurry comprising a zeolite (A) having an average aggregate particle diameter of 15 ?m or less and a variation coefficient of a distribution of an aggregate particle diameter of 29% or less, a water-soluble polymer (B), a water-soluble salt (C), an
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: May 17, 2005
    Assignee: Kao Corporation
    Inventors: Kazuo Oki, Hiroji Hosokawa, Shu Yamaguchi, Kimihiro Mizusawa
  • Patent number: 6893632
    Abstract: A regimen for hunting includes using a number of zeolite-containing personal items in connection with a hunter's apparel and body to reduce the hunter's scent for improved hunting. The personal items include mouthwash, deodorant/anti-perspirant, body and boot powder, bar and liquid soap for cleansing the body and hair, laundry detergent and dryer sheets. Each of the personal items includes an effective amount of zeolite, so that use of the personal items reduces the available scent to be detected by animals in the wild. The regimen can also include the use of a seat cushion that is covered with an activated carbon-containing fabric for odor control and/or elimination.
    Type: Grant
    Filed: May 9, 2002
    Date of Patent: May 17, 2005
    Inventor: Louis B. Johnson
  • Patent number: 6894016
    Abstract: To present a liquid detergent of a high cleaning power and an excellent storage stability while maintaining the ease of use. A liquid detergent composition comprising, at a specific ratio individually, (a) water, (b) a builder composed of a water-soluble inorganic salt of which solubility in distilled water is 0.5 g/15 g (25° C., distilled water) or more, and (c) a substance liquid at 25° C. containing at least one selected from the group consisting of surfactant (c1) and water-miscible organic solvent (c2) in which part of (b) is present in solid state in the composition, and its electric conductivity measured by a specific method is within a specified range.
    Type: Grant
    Filed: May 8, 2002
    Date of Patent: May 17, 2005
    Assignee: Kao Corporation
    Inventors: Akira Ishikawa, Toshio Miyake, Kazutoshi Ide
  • Patent number: 6831056
    Abstract: A process for efficiently preparing fine zeolite particles comprising synthesizing zeolite in the presence of an alkaline earth metal-containing compound and/or with controlling the preparation process of zeolite, thereby giving fine zeolite particles being composed of crystalline aluminosilicate, the fine zeolite particles having a fine average primary particle size, being excellent in the cationic exchange properties and the oil-absorbing ability, having a fine average aggregate particle size, and being excellent in the dispersibility; fine zeolite particles obtainable by the above process; and a detergent composition comprising the fine zeolite particles, the detergent composition being excellent in the detergency.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: December 14, 2004
    Assignee: Kao Corporation
    Inventors: Kazuo Oki, Hiroji Hosokawa, Mikio Sakaguchi, Hiroshi Kitagaito, Kazuo Taguchi, Hitoshi Takaya
  • Patent number: 6784149
    Abstract: The invention relates to laundry detergents and cleaners comprising microdisperse, hydrophilic silicate-containing particles. The particle diameter of the particles is preferably 1 to 500 nm. The addition of the silicate-containing particles leads to improved soil release with a simultaneous reduction in the tendency for resoiling.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: August 31, 2004
    Assignee: Clariant GmbH
    Inventors: Harald Bauer, Günther Schimmel
  • Patent number: 6773693
    Abstract: A fine A-type zeolite particle having an average primary particle size of 0.1 &mgr;m or less and a variation coefficient of 90% or less, wherein a ratio of a peak area above a background level to all peak are in the range of 2&thgr;=20° to 40° in a powder X-ray diffraction spectrum of said fine A-type zeolite particle is 30% or more; a process for preparing the fine A-type zeolite particle, comprising reacting a silica source with an aluminum source in the presence of an organic compound having an oxygen-containing functional group and a molecular weight of 100 or more; and a detergent composition comprising a surfactant and the fine A-type zeolite particle. The fine zeolite particle is suitably used for detergent builders, water treatment agents, fillers for paper, resin fillers, oxygen-nitrogen separating agents, adsorbents, catalyst carriers, soil improvers for gardening, polishing agents, and the like.
    Type: Grant
    Filed: August 9, 2002
    Date of Patent: August 10, 2004
    Assignee: Kao Corporation
    Inventors: Hiroji Hosokawa, Kazuo Oki
  • Patent number: 6743766
    Abstract: The invention relates to a sparingly soluble alkali metal silicate which comprises alkali metal phyllosilicate in finely divided form in a non-phyllosilicatic alkali metal silicate environment of the formula x MI2O.y SiO2, in which MI is an alkali metal and y/x (1.9 to 500): 1; a process for its preparation and its use in detergents and cleaners.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: June 1, 2004
    Assignee: Clariant GmbH
    Inventors: Harald Bauer, Josef Holz, Guenther Schimmel, Alexander Tapper
  • Patent number: 6699831
    Abstract: The present invention provides a liquid detergent composition being excellent in detergency and dispersion stability and a process for producing the same. The invention provides a liquid detergent composition having a degree of separation by volume of 5% or less after storage for 1 month at 25° C., comprising a liquid phase as the phase (a), a polymeric dispersant as the component (b)] and at least one selected from the group consisting of a crystalline silicate compound and an aluminosilicate compound as the component (c), wherein the component (b) has a cation exchange capacity of not less than 120 CaCO3 mg/g when the water content of the composition is 5% by weight or less and then the aluminosilicate compound only is used as the component (c) or when the water content of the composition is larger than 5% by weight.
    Type: Grant
    Filed: June 7, 2001
    Date of Patent: March 2, 2004
    Assignee: Kao Corporation
    Inventors: Tomoe Takano, Koji Yui, Takashi Oda, Akira Ishikawa, Osamu Takiguchi
  • Patent number: 6693071
    Abstract: Rinse aid materials for coating, coating compositions, methods and articles of manufacture for use in automatic dishwashing appliances comprising a nanoparticle system or employing the same to impart surface modifying benefits for all types of dishware surfaces are disclosed. In some embodiments, dispersement of nanoparticles in a suitable carrier medium allows for the creation of rinse aid surface coating compositions, methods and articles of manufacture that create multi-use benefits to modified dishware surfaces. These surface modifications can produce long lasting or semi-permanent multi-use benefits that include at least one of the following improved surface properties: wetting and sheeting, uniform drying, anti-spotting, anti-staining, anti-filming, self cleaning, and durability benefits, relative to dishware surfaces unmodified with such nanoparticle systems.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: February 17, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Chanchal Kumar Ghosh, William Michael Scheper, Robert Henry Rohrbaugh, Michael Ray McDonald, John David Carter, Eugene Paul Gosselink
  • Patent number: 6673766
    Abstract: The invention relates to detergent compositions comprising from 10-60 wt % of a surfactant system and having a maximum Residues Index of 25 and a maximum Secondary Residues Index of 15. The detergents claim provide good performance in the wash based on the quantities of detergent components in the compositions.
    Type: Grant
    Filed: July 11, 2001
    Date of Patent: January 6, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Richard Timothy Hartshorn, Zayeed Alam, Sylvestre Canceil, Alan Thomas Brooker, Gerard Marcel Baillely, Kevin Norwood, David Scott Bohlen
  • Patent number: 6660713
    Abstract: Cleaning and deodorizing compositions comprising hydrophobic, nanozeolites for odor control on substrates are disclosed. Specifically, cleaning and deodorizing compositions for malodor control comprising nanozeolites and methods for removing odors from substrates using said compositions are disclosed.
    Type: Grant
    Filed: January 30, 2001
    Date of Patent: December 9, 2003
    Assignee: The Procter & Gamble Company
    Inventors: John David Carter, Robert Corkery, Jun Ma, Robert Henry Rohrbaugh
  • Patent number: 6624132
    Abstract: The present invention relates to a liquid enzyme cleaning composition in which the enzyme is stable at alkaline pH and in the presence of water at concentrations of at least about 50 to about 60 weight percent. In one embodiment, the composition of the invention stabilizes the enzyme with potassium borate.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: September 23, 2003
    Assignee: Ecolab Inc.
    Inventors: Victor Fuk-Pong Man, Steven Eugene Lentsch, Yvonne Marie Killeen
  • Patent number: 6620209
    Abstract: A detergent composition comprising: (a) a surfactant selected from the group consisting of an anionic surfactant, a nonionic surfactant, an amphoteric surfactant, a zwitterionic surfactant, and mixtures thereof; (b) a cationic polymer; and (c) a zeolite.
    Type: Grant
    Filed: September 7, 2001
    Date of Patent: September 16, 2003
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Ditmar Kischkel, Manfred Weuthen, Jutta Stute
  • Patent number: 6479455
    Abstract: A process for improving storage stability and solubility of a laundry detergent powder includes the steps of: (a) forming a builder agglomerate which is free of sodium carbonate and (b) adding the builder agglomerate to a laundry detergent powder composition. The builder agglomerate is present in an amount in a range of from about 14% to about 21% by weight of the laundry detergent powder composition. The builder agglomerate has a composition including an aluminosilicate ion exchange and a binder selected from the group consisting of surfactants, polyethylene glycol, polyacrylates, and mixtures thereof. The builder agglomerate also includes sodium diethylenetriaminepentaacetate (DTPA) and balance water but the builder agglomerate is free of sodium carbonate.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: November 12, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Joseph Michael Cruse, Michael Chris Jensen
  • Patent number: 6475982
    Abstract: The present invention relates to a composition containing MAP zeolite, ethoxylated nonionic surfactant and an alkali metal carbonate.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: November 5, 2002
    Assignee: Colgate Palmolive Company
    Inventors: Charles Beagle, Richard Adams, David Beck
  • Patent number: 6468500
    Abstract: An aluminosilicate in an acicular form, a platy form, or a columnar form and having the composition represented by aM2O.bAl2O3.cSiO2.dRmAn.yH2O, wherein M is at least one of Na and K; R is one or more elements selected from the group consisting of Na, K, Ca and Mg; A is one or more members selected from the group consisting of CO3, SO4, NO3, OH and Cl; a is from 1 to 6; b is from 2 to 8; c is from 2 to 12; d is from 0 to 4; m is from 1 to 2; n is from 1 to 3; and y is from 0 to 32; a polishing agent including the aluminosilicate; and a detergent composition including the aluminosilicate.
    Type: Grant
    Filed: April 28, 2000
    Date of Patent: October 22, 2002
    Assignee: Kao Corporation
    Inventors: Mikio Sakaguchi, Takanori Kotera, Masaharu Jyono, Ichiro Sakamoto
  • Patent number: 6465417
    Abstract: The present invention relates to a composition containing a MAP zeolite, ethoxylated nonionic surfactant and an alkali metal carbonate.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: October 15, 2002
    Assignee: Colgate-Palmolive Co.
    Inventors: Charles Beagle, Richard Adams, David Beck
  • Patent number: 6465418
    Abstract: The present invention relates to a composition containing zeolite, ethoxylated nonionic surfactant and an alkali metal carbonate.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: October 15, 2002
    Assignee: Colgate-Palmolive Co.
    Inventors: Charles Beagle, Richard Adams, David Beck
  • Patent number: 6455490
    Abstract: A non-spray-dried granular component suitable for use in a particulate zero-phosphate laundry detergent composition comprises from 10 to 30 wt % of organic surfactant and from 20 to 50 wt % of zeolite MAP, the component having a bulk density not exceeding 700 g/l. The component may be prepared by a mixing and agglomeration process using a high-speed mixer, a moderate- or low-speed mixer, and a gas fluidization granulator. The component may be used in conjunction with a spray-dried granular component of lower bulk density, for example, a spray-dried detergent base powder containing organic surfactant and zeolite A, or a spray-dried sodium-carbonate-based adjunct.
    Type: Grant
    Filed: June 8, 2000
    Date of Patent: September 24, 2002
    Assignee: Unilever Home & Personal Care USA Division of Conopco, In.c
    Inventors: Daniel Pierre Marie Berthod, Christophe Michel Bruno Joyeux, Johannes Hendrikus Langeveld
  • Patent number: 6440922
    Abstract: A detergent composition comprises a zeolite builder having a particle size, expressed as a d50 value, of less than 1.0 micrometers, an amylase enzyme, and an alkoxylated nonionic surfactant having a hydrophilic lipophilic balance value of less than 9.5 selected from the group consisting of alkoxylated adducts of fatty alcohols containing an average of less than 5 alkylene oxide groups per molecule. The detergent composition has been found to reduce white residue formation on fabrics washed with detergent containing small particle size zeolite.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: August 27, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Carolyn Jayne Garnett, Jonathan Richard Clare, Johan Juliaan Serafin Wauben
  • Patent number: 6387869
    Abstract: A granular surfactant composition comprising sodium silicate and linear alkylbenzenesulfonates, wherein the granular surfactant composition has a mean particle diameter of ≧50 &mgr;m and an ffc value of ≧7; a process for the preparation of this granular surfactant composition, its use, and detergents and cleaners which comprise such granular surfactant composition and a process for the making of the same; and, where appropriate, the granular surfactant composition comprises other active ingredients and auxiliaries.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: May 14, 2002
    Assignee: Clariant GmbH
    Inventors: Harald Bauer, Josef Holz, Gunther Schimmel
  • Patent number: 6387873
    Abstract: This invention relates to detergent compositions having significantly improved calcium sequestration capacity as well as superior builder capacity in comparison to conventional aluminosilicate builder materials, while not redepositing on fabrics. More particularly, this invention relates to detergent compositions comprising microclusters of submicron crystallites of an aluminosilicate ion exchange material.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: May 14, 2002
    Assignee: The Procter & Gamble Company
    Inventors: John David Carter, Eugene Joseph Pancheri, Robert Henry Rohrbaugh
  • Patent number: 6372709
    Abstract: The invention relates to a finely divided crystalline layered sodium disilicate of the formula NaMSixO2x+1.yH2O, where M is sodium or hydrogen, x is a number from 1.9 to 4, and y is a number from 0 to 20, which comprises from 0 to 40% by weight of alpha-disodium disilicate from 0 to 40% by weight of beta-disodium disilicate from 40 to 100% by weight of delta-disodium disilicate from 0 to 40% by weight of amorphous components, to a process for its preparation and to its use.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: April 16, 2002
    Assignee: Clariant GmbH
    Inventors: Harald Bauer, Josef Holz, Günther Schimmel
  • Patent number: 6281180
    Abstract: An automatic dishwashing detergent composition is described which contains an effective amount of a defined water soluble cationic or amphoteric polymer and a phosphate or nonphosphate builder. The polymers are soluble or dispersible to at least 0.01% by weight in distilled water at 25° C. A method of using the polymers to prevent fading or corrosion of dishware is also described.
    Type: Grant
    Filed: September 15, 1999
    Date of Patent: August 28, 2001
    Assignee: Lever Brothers Company, division of Conopco, Inc.
    Inventors: Alla Tartakovsky, Joseph Oreste Carnali, Richard Gerald Gary
  • Patent number: 6265371
    Abstract: A powdery detergent composition having a high detergency and an excellent storage stability (caking resistance), and comprising (a) a chelating agent composed of a compound having an average degree of neutralization in a molecule of 20 to 70%, a molecular weight of 600 or less, the number of carboxyl groups contained in one molecule of 3 to 5, and a constant of a chelating stability with Ca2+ of 6 to 13, (b) an alkali agent composed of a compound a 0.1% by weight aqueous solution or dispersion of which has the maximum pH of 10 or more at 20° C., at least 5 ml of 0.1 N HCl aqueous solution being required to adjust 1 liter of the aqueous solution or the dispersion to pH 9, and (c) a surfactant at specific ratios, respectively.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: July 24, 2001
    Assignee: Kao Corporation
    Inventors: Genjiro Hagino, Shuji Tagata, Sachiko Noguchi
  • Patent number: 6258768
    Abstract: P-type zeolite having the oxide formula M2/nAl2O3 (1.8-2.66) SiO2 y H2O and having a Calcium Binding Capacity of between 100 and 145 mg/g, preferably between 110 and 140 and a Calcium uptake rate of between 12 and 100 seconds, preferably below 50 seconds can be prepared from metakaolin.
    Type: Grant
    Filed: August 20, 1998
    Date of Patent: July 10, 2001
    Assignee: Imperial Chemical Industries PLC
    Inventor: Abraham Araya
  • Patent number: 6239096
    Abstract: A powdered abrasive cleanser that exhibits superior soil removal properties and surface safety is provided. The cleanser includes a surfactant, an optional source of active chlorine, a borax pentahydrate compound that is preferably sodium tetraborate pentahydrate, and optionally an alkaline detergent builder and/or calcium carbonate.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: May 29, 2001
    Assignee: The Clorox Company
    Inventors: Robert L. Blum, Denise A. Garner, Carl M. Kling
  • Patent number: 6235704
    Abstract: A solid textile detergent formulation comprises (A) from 1 to 30% by weight of inorganic builders based on carbonates, (B) from 0 to 12% by weight of inorganic builders based on crystalline or amorphous alumosilicates and/or crystalline or amorphous silicates, (C) from 0 to 5% by weight of inorganic builders based on phosphates, (D) from 1 to 40% by weight of one or more glycine-N,N-diacetic acid derivatives I where R is an organic radical and M is hydrogen or a cation, as organic builder component, (E) from 0 to 40% by weight of anionic surfactants and (F) from 0.5 to 50% by weight of nonionic surfactants.
    Type: Grant
    Filed: January 28, 2000
    Date of Patent: May 22, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Jürgen Detering, Richard Baur, Werner Bertleff, Rainer Rahm, Günter Oetter
  • Patent number: 6225278
    Abstract: The invention relates to a solid textile detergent formulation containing (A) 1-60 wt. % inorganic builders based on crystalline or amorphous aluminosilicates, crystalline or amorphous silicates, carbonates and/or phosphates, (B) 1-40 wt. % of one or several glycin-N, N-diacetic acid derivatives of formula (I), wherein R stands for an organic radical and M means hydrogen or a cation, (C) 0-6 wt. % anionic surfactants with one or several sulphate groups, one or several sulphate groups or one or two carboxylate groups and (D) 0.5-50 wt. % non ionic surfactants.
    Type: Grant
    Filed: January 28, 2000
    Date of Patent: May 1, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Jürgen Detering, Richard Baur, Werner Bertleff, Rainer Rahm, Günter Oetter, Beate Ehle
  • Patent number: RE38411
    Abstract: A washing method is described which has excellent washing power and a low surfactant concentration. The described clothes washing method comprises the use of a phosphorus-free clothes detergent composition comprising (a) one or more surfactants, (b) one or more alkali metal silicates, and (c) one or more metal ion capturing agents other than the alkali metal silicate (b). The above detergent composition is added to water in an amount sufficient to produce a washing liquid having the following washing conditions (1) a pH of not less than 10.60; (2) containing a material having an ion capturing capacity in an amount sufficient for theoretically changing the water hardness of said water to be not more than 0.5° DH; and (3) having a surfactant concentration of from 0.07 to 0.17 g/L.
    Type: Grant
    Filed: October 5, 2001
    Date of Patent: February 3, 2004
    Assignee: Kao Corporation
    Inventors: Shu Yamaguchi, Noriaki Ushio, Akiko Ishikura, Katsuhiko Kasai, Masaki Tsumadori, Hiroyuki Yamashita