Inorganic Phosphorus Containing Component Patents (Class 510/534)
  • Patent number: 8809249
    Abstract: A detergent composition for preventing scale on various surfaces includes a threshold system, a caustic and a surfactant system. The threshold system includes a sulfonate/acrylate copolymer, an acrylate homopolymer and a phosphonoalkane carboxylic acid with a sulfonate/acrylate copolymer to acrylate homopolymer weight ratio of between about 2:1 to about 1:2. The pH of the detergent composition is between about 10 and about 13.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: August 19, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Carter M. Silvernail, Erik C. Olson, Elizabeth R. Kiesel
  • Patent number: 8481473
    Abstract: A detergent composition for preventing scale on various surfaces includes a threshold system, a caustic and a surfactant system. The threshold system includes a sulfonate/acrylate copolymer, an acrylate homopolymer and a phosphonoalkane carboxylic acid with a sulfonate/acrylate copolymer to acrylate homopolymer weight ratio of between about 2:1 to about 1:2. The pH of the detergent composition is between about 10 and about 13.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: July 9, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Carter Silvernail, Erik C. Olson, Elizabeth Kiesel
  • Publication number: 20130000370
    Abstract: The invention relates to aminocarboxylates in solid form which have a relatively high storage stability and improved processability, and to the use thereof in household products, in particular detergents, cleaners and care compositions, and in industrial processes.
    Type: Application
    Filed: June 26, 2012
    Publication date: January 3, 2013
    Applicant: BASF SE
    Inventor: Frank-Peter LANG
  • Patent number: 8138138
    Abstract: A solidification matrix includes a polycarboxylic acid polymer, sodium carbonate, and water. Exemplary polycarboxylic acid polymers include a polyacrylic acid polymer having a molecular weight of between about 1,000 and about 100,000, a modified polyacrylic acid polymer having a molecular weight of between about 1,000 and about 100,000, and a polymaleic acid polymer having a molecular weight of between about 500 and about 5,000. The polycarboxylic acid polymer, sodium carbonate, and water interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition.
    Type: Grant
    Filed: July 8, 2010
    Date of Patent: March 20, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Brenda L. Tjelta, Lisa M. Sanders, Michael E. Besse
  • Patent number: 7854770
    Abstract: A detergent composition comprising: from 0.01% to 90% by weight of a surfactant system, one or more detergency builder(s), comprising a phosphate builder, and the phosphate builder containing pyrophosphate, wherein the composition comprises at most 12% by weight of phosphate builder(s) and the phosphate builder(s) comprise(s) at least 40% by weight of pyrophosphate(s).
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: December 21, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Junhua Du, Qing Chen, Li Ran, Ignacio Gallo-Perez, Ming Tang, Kenneth Nathan Price
  • Patent number: 7763576
    Abstract: A solidification matrix includes a polycarboxylic acid polymer, sodium carbonate, and water. Exemplary polycarboxylic acid polymers include a polyacrylic acid polymer having a molecular weight of between about 1,000 and about 100,000, a modified polyacrylic acid polymer having a molecular weight of between about 1,000 and about 100,000, and a polymaleic acid polymer having a molecular weight of between about 500 and about 5,000. The polycarboxylic acid polymer, sodium carbonate, and water interact to form a hydrate solid. The solidification matrix may be used, for example, in a solid detergent composition.
    Type: Grant
    Filed: January 4, 2008
    Date of Patent: July 27, 2010
    Assignee: Ecolab Inc.
    Inventors: Brenda L. Tjelta, Lisa M. Sanders, Michael E. Besse
  • Patent number: 7410938
    Abstract: A solid calcium hypochlorite composition comprising a mixture of: solid calcium hypochlorite; a scale-inhibiting effective amount of a primarily scale-inhibiting alkali metal phosphate; and an effective residue-dispersing amount of primarily residue-dispersing alkali metal phosphate.
    Type: Grant
    Filed: February 22, 2005
    Date of Patent: August 12, 2008
    Assignee: Arch Chemicals, Inc.
    Inventor: James P. Brennan
  • Patent number: 7375072
    Abstract: A builder-containing laundry detergent or cleaning composition is comprised of: (1) alkali metal percarbonate; (2) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 10% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (3) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise alkali metal percarbonates and contain only water-soluble builders.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: May 20, 2008
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Josef Penninger
  • Patent number: 7354888
    Abstract: Provided is an antibacterial aqueous solution comprising a phosphate, a citrate, and a silicate; a method of controlling bacterial contamination and/or growth in food substance; a method of prohibiting the formation of, and/or facilitating the removing of, silicate aggregation on metal article; and a method of reducing phosphate usage in industrial antibacterial process.
    Type: Grant
    Filed: November 10, 2004
    Date of Patent: April 8, 2008
    Assignee: Danisco A/S
    Inventor: Charles R. Mostoller
  • Patent number: 7316995
    Abstract: A builder-containing laundry detergent or cleaning composition comprising: (1) a water-soluble builder block which comprised of: a) from 5% by weight to 35% by weight of citric acid, an alkali metal citrate, an alkali metal carbonate, and/or an alkali metal hydrogen carbonate, b) up to 5% by weight of alkali metal silicate having a modulus in the range from 1.8 to 2.5, c) up to 2% by weight of phosphonic acid and/or alkali metal phosphate, d) up to 50% by weight of alkali metal phosphate, and e) up to 10% by weight of polymeric polycarboxylate, wherein at least two of components b), c), d) and e) are present in amounts greater than 0% by weight, and (2) a soil release-capable alkyl or hydroxyalkyl cellulose derivative. The soil release-capable action of cellulose derivatives is particularly marked when they are used in laundry detergents or cleaning compositions which comprise only water-soluble builders.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: January 8, 2008
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Josef Penninger
  • Patent number: 7018975
    Abstract: A cleaning formulation comprising a cleaning agent, a particulate clay material and an aqueous carrier. The formulation has a pH less than about 4.0 and is characterized by at least a 90% reduction in viscosity at 25° C. at a shear rate of up to about 0.10 s?1. The cleaning formulation is thixotropic and has a highly desirable combination of acid stability, temperature stability, electrolyte stability and ultraviolet radiation stability.
    Type: Grant
    Filed: September 11, 2003
    Date of Patent: March 28, 2006
    Assignee: Trojan Technologies Inc.
    Inventor: Howard A. Ketelson
  • Patent number: 6982242
    Abstract: An aqueous detergent composition is provided containing phosphoric acid or salt thereof, an organic phosphate surfactant, a nonionic surfactant, and water. The aqueous detergent composition may be employed to improved the adhesion of a coating to a substrate. Also provided is a method of improving the adhesion of a coating to a substrate.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: January 3, 2006
    Assignee: Rohm and Haas Company
    Inventors: Audrey Brenda Liss, Joseph Martin Rokowski, Thomas James Ennis
  • Patent number: 6635613
    Abstract: A cleaning formulation comprising a cleaning agent, a particulate clay material and an aqueous carrier. The formulation has a pH less than about 4.0 and is characterized by at least a 90% reduction in viscosity at 25° C. at a shear rate of up to about 0.10 s−1. The cleaning formulation is thixotropic and has a highly desirable combination of acid stability, temperature stability, electrolyte stability and ultraviolet radiation stability.
    Type: Grant
    Filed: September 19, 2000
    Date of Patent: October 21, 2003
    Assignee: Trojan Technologies, Inc.
    Inventor: Howard A. Ketelson
  • Patent number: 6528474
    Abstract: The invention relates to a process for the production of substantially alumosilicate-free detergents containing a soluble builder system which provides free-flowing and storage-stable granules. In this process for the production of a particulate, substantially alumosilicate-free detergent, an anionic surfactant acid is sprayed onto a detergent component containing anionic surfactant and builders in order to increase the anionic surfactant content.
    Type: Grant
    Filed: July 5, 2000
    Date of Patent: March 4, 2003
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rene-Andres Artiga Gonzalez, Andreas Lietzmann, Maria Liphard, Wilfried Roehl
  • Patent number: 6465413
    Abstract: This invention discloses laundering and dishwashing products which can be incorporated in a single compartment water soluble film sachet, the formulation comprising a granulated percarbonate compound mixed with and encapsulated in an encapsulating blend comprising sulfate, carboxy methyl cellulose and nonionic surfactant, wherein the detergent composition does not include zeolites or perborates.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: October 15, 2002
    Inventor: Gerald Thomas Hinton
  • Patent number: 6372710
    Abstract: The invention of this application aims to offer the detergent composition that does not destroy natural ecosystem or pollute air, as the detergent contains neither organic synthetic surfactant that pollutes environment, rivers and lakes nor petroleum volatile solvent that is the source of air pollution. The invention of this application concerns the detergent composition and manufacturing methods of said detergent. The detergent composition contains at least one or more species of sodium (III) phosphate, sodium metasilicate, sodium sulfate, sodium tripolyphosphate, sodium chloride, sodium carbonate, potassium chloride, trisodium citrate and sodium hydroxide.
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: April 16, 2002
    Inventor: Yasuo Sadoyama
  • Patent number: 6281180
    Abstract: An automatic dishwashing detergent composition is described which contains an effective amount of a defined water soluble cationic or amphoteric polymer and a phosphate or nonphosphate builder. The polymers are soluble or dispersible to at least 0.01% by weight in distilled water at 25° C. A method of using the polymers to prevent fading or corrosion of dishware is also described.
    Type: Grant
    Filed: September 15, 1999
    Date of Patent: August 28, 2001
    Assignee: Lever Brothers Company, division of Conopco, Inc.
    Inventors: Alla Tartakovsky, Joseph Oreste Carnali, Richard Gerald Gary
  • Patent number: 6265371
    Abstract: A powdery detergent composition having a high detergency and an excellent storage stability (caking resistance), and comprising (a) a chelating agent composed of a compound having an average degree of neutralization in a molecule of 20 to 70%, a molecular weight of 600 or less, the number of carboxyl groups contained in one molecule of 3 to 5, and a constant of a chelating stability with Ca2+ of 6 to 13, (b) an alkali agent composed of a compound a 0.1% by weight aqueous solution or dispersion of which has the maximum pH of 10 or more at 20° C., at least 5 ml of 0.1 N HCl aqueous solution being required to adjust 1 liter of the aqueous solution or the dispersion to pH 9, and (c) a surfactant at specific ratios, respectively.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: July 24, 2001
    Assignee: Kao Corporation
    Inventors: Genjiro Hagino, Shuji Tagata, Sachiko Noguchi
  • Patent number: 6235704
    Abstract: A solid textile detergent formulation comprises (A) from 1 to 30% by weight of inorganic builders based on carbonates, (B) from 0 to 12% by weight of inorganic builders based on crystalline or amorphous alumosilicates and/or crystalline or amorphous silicates, (C) from 0 to 5% by weight of inorganic builders based on phosphates, (D) from 1 to 40% by weight of one or more glycine-N,N-diacetic acid derivatives I where R is an organic radical and M is hydrogen or a cation, as organic builder component, (E) from 0 to 40% by weight of anionic surfactants and (F) from 0.5 to 50% by weight of nonionic surfactants.
    Type: Grant
    Filed: January 28, 2000
    Date of Patent: May 22, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Jürgen Detering, Richard Baur, Werner Bertleff, Rainer Rahm, Günter Oetter
  • Patent number: 6225278
    Abstract: The invention relates to a solid textile detergent formulation containing (A) 1-60 wt. % inorganic builders based on crystalline or amorphous aluminosilicates, crystalline or amorphous silicates, carbonates and/or phosphates, (B) 1-40 wt. % of one or several glycin-N, N-diacetic acid derivatives of formula (I), wherein R stands for an organic radical and M means hydrogen or a cation, (C) 0-6 wt. % anionic surfactants with one or several sulphate groups, one or several sulphate groups or one or two carboxylate groups and (D) 0.5-50 wt. % non ionic surfactants.
    Type: Grant
    Filed: January 28, 2000
    Date of Patent: May 1, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Jürgen Detering, Richard Baur, Werner Bertleff, Rainer Rahm, Günter Oetter, Beate Ehle
  • Patent number: 6221824
    Abstract: The storage stability of bleach-activating acetonitrile derivatives in solid detergent compositions was to be improved. This was essentially achieved by the use of compounded compounds corresponding to formula R1R2R3NxCH2CN X−, in which R1, R2 and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, in addition to which the groups R2 and R3 may even be part of a heterocycle including the N atom and optionally other hetero atoms, and X is a charge-equalizing anion. “Compounds” of this type are produced by drying in vacuo, for which purpose a suspension of the acetonitrile derivative and a solid carrier material is introduced into a mixer and the resulting mixture is dried with superheated vapor. Dishwashing detergents, more particularly machine dishwashing detergents, contain about 1% by weight to 10% by weight of this bleach boosting compound.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: April 24, 2001
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Andreas Lietzmann, Artiga Gonzalez, Stefan Hammelstein, Christian Nitsch, Horst-Dieter Speckmann
  • Patent number: 6204231
    Abstract: An aqueous alkaline composition for cleaning equipment used in the food industry wherein the composition contains potassium hydroxide or a mixture of potassium hydroxide and sodium hydroxide and wherein the potassium hydroxide is present in an amount of at least 20% by weight, based on the weight of hydroxide present in the composition. A process for regenerating the cleaning solution is also disclosed.
    Type: Grant
    Filed: September 1, 1998
    Date of Patent: March 20, 2001
    Assignee: Henkel Kommandigesellschaft Auf Aktien
    Inventors: Anja Patten, Ralf Krack, Dietmar Rossner
  • Patent number: 6194367
    Abstract: The present invention discloses an alkaline cleaning composition for cleaning heavily soiled metal surfaces such as food fryers, baking pans, high temperature pasteurizers, and beer kettles, ceramic surfaces such as restaurant grade ceramic china plates and platters, and plastic surfaces. The cleaning composition is noncaustic and includes a peroxygen compound, a chelate, and a metasilicate and/or sesquisilicate. A preferred cleaning composition further includes a surfactant and hydrated builder.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: February 27, 2001
    Assignee: Charvid Limited Liability Co.
    Inventor: Charles Bullick Talley
  • Patent number: 6147042
    Abstract: The cleaner of the present invention contains, as an active ingredient, a polyphosphoric-acid-urea condensate or phosphoric-acid-urea polymer which is a reaction product from orthophosphoric acid and urea and is used for cleaning a metal surface and/or a glass surface in at least one process of a semiconductor device production process and a liquid crystal device production process. According to the present invention, an etching residue and impurities on metal (including semimetal) and glass surfaces can be cleaned off with high environmental and working safety and effectively without causing the problem of metal corrosion.
    Type: Grant
    Filed: July 2, 1999
    Date of Patent: November 14, 2000
    Assignees: Kishimoto Sangyo Co., Ltd., Otsuka Chemical Co., Ltd.
    Inventors: Takashi Yata, Yutaka Koinuma, Kazunori Fukumura, Yoshihito Fukumura
  • Patent number: 6121219
    Abstract: The invention relates to compositions and methods for cleaning typically organic beverage and food soils. The cleaning composition is formulated to remove carbohydrate and proteinaceous soils from hard surfaces. The formulations of the invention are directed to remove carbohydrate and proteinaceous soils from beverage manufacturing locations such as soils arising in the manufacture of malt beverages, fruit juices, dairy products, etc.
    Type: Grant
    Filed: August 10, 1999
    Date of Patent: September 19, 2000
    Assignee: Ecolab Inc.
    Inventors: Brandon L. Herdt, David A. Halsrud
  • Patent number: 6071434
    Abstract: The reaction of compounds of the formula:X.sub.2 O.sub.3 P CHY CZ.sub.2where Y and each Z are each H, PO.sub.3 X.sub.2, SO.sub.3 X or CO.sub.2 X (e.g. vinyl phosphonic acid or vinylidene diphosphonic acid) with hypophosphorous acid in the presence of free radicals provides novel compounds X.sub.2 O.sub.3 PCHYCZ.sub.2 PO.sub.2 XH which react with monomers such as vinyl sulphonate, vinyl phosphonate, vinylidene diphosphonate and acrylic acid to form telomers useful for scale inhibition, especially barium scale in oil wells. The polymers show better absorption to rock than PVSA and better thermal stability than random copolymers containing equivalent phosphorus.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: June 6, 2000
    Assignee: Albright & Wilson UK Limited
    Inventors: Keith Philip Davis, Alan Craig Smith, David Robert Edward Walker, Gary Woodward
  • Patent number: 5935708
    Abstract: In order to increase active oxygen stability, sodium percarbonate is coated with single or multiple layers of various substances. Sodium percarbonate particles consist of a core of sodium percarbonate fluidized bed spray granulate and sodium sulphate, which may be partially hydrated, as the sole constituent of a single coating layer. The particles exhibit both elevated active oxygen stability and very good ensilability. The coating layer is applied by spraying an aqueous Na.sub.2 SO.sub.4 solution onto the particles to be coated, which were themselves produced by fluidized bed spray granulation, in a fluidized bed and vaporizing water at a fluidized bed temperature of 35 to 100.degree. C.
    Type: Grant
    Filed: November 25, 1996
    Date of Patent: August 10, 1999
    Assignee: Degussa Aktiengesellschaft
    Inventors: Ruediger Schuette, Martin Bewersdorf, Claas-Juergen Klasen
  • Patent number: 5900399
    Abstract: A tablet composition containing 2% to 100% by weight of amorphous crystalline or partly crystalline layer-form sodium silicates corresponding to the formula Na.sub.2 Si.sub.x --O.sub.2x+1.yH.sub.2 O wherein x is a number of 1.9 to 4 and y is a number of 0 to 20, with the proviso that the tablet composition only contains water in a quantity such that the maximum theoretical water-binding capacity of the components of the composition is not exceeded.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: May 4, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Seiter, Dieter Jung, Otto Koch, Birgit Stevermann
  • Patent number: 5759976
    Abstract: Tableted detergents are formed from a hydrated phosphate sequestrant, caustic, free water and, optionally, fillers by combining the products and tableting the components without permitting the tablets or detergent to exceed 50.degree. C. In a preferred embodiment where fillers are incorporated, all free water is combined with the phosphate sequestrants, both anhydrous and hydrated. After the water has been absorbed by the sequestrants, the filler and caustic can be added and the detergent tableted. The free water is bound sufficiently tightly to the phosphate sequestrant that it does not rapidly react with the anhydrous caustic, maintaining the temperature at less than 50.degree. C., which in turn prevents the water of hydration in the phosphates from reacting and thereby weakening the formed tablets. The tablets can also be formed by combining the filler with the phosphate sequestrants and water and subsequently adding caustic if the detergent is cooled and its temperature maintained below 50.degree. C.
    Type: Grant
    Filed: July 22, 1997
    Date of Patent: June 2, 1998
    Assignee: Diversey Lever, Inc.
    Inventors: Kenneth James Roach, Patricia Anderson
  • Patent number: 5541316
    Abstract: A process for the production of polycarboxylic acids or salts thereof from polysaccharides by oxidation with nitrogen dioxide/dinitrogen tetroxide with at least partial conversion of the primary alcohol groups of the polysaccharides into carboxyl groups and optionally at least partial neutralization of the carboxylic acid groups formed is provided. The oxidation reaction is carried out in a closed reaction system in the presence of oxygen under pressures of 2 bar to 10 bar and at a temperature above room temperature. Nitrogen dioxide/dinitrogen tetroxide is used in such quantities that, in the event of a theoretically complete shift of the equilibrium onto the nitrogen dioxide side, the nitrogen dioxide is present in quantities of at most 2 mole equivalents, based on the content of monomer unit of the polysaccharide containing one primary alcohol group.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: July 30, 1996
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Konrad Engelskirchen, Herbert Fischer, Hans-Wilhelm Verholt