Liquid Or Paste Composition Patents (Class 510/537)
  • Patent number: 11629311
    Abstract: The present disclosure provides a surfactant blend containing (i) an extended chain anionic surfactant and (ii) an extended chain intermediate surfactant. The surfactant blend may be used in the preparation of cleaning compositions, or compositions for use in oil field treatment applications, water based metal working applications and polyurethane foam applications.
    Type: Grant
    Filed: March 9, 2017
    Date of Patent: April 18, 2023
    Assignee: Indorama Ventures Oxides LLC
    Inventors: George Smith, Gary R. Watkins
  • Patent number: 11396640
    Abstract: The invention relates to a surfactant composition comprising a primary surfactant of sulfonated methyl ester (SME) of a fatty acid having a chain length of 16 to 18 carbon atoms (C16-C18); a secondary surfactant having a carbon chain length shorter than that of the primary surfactant; a non-ionic co-surfactant; a hydrotrope; and a solvent. The secondary surfactant can be a SME of a fatty acid having a chain length of 12 to 14 carbon atoms (C12-C14) or sodium lauryl ether sulfate (SLES). The invention also relates to use of said surfactant composition as a surfactant system in a detergent.
    Type: Grant
    Filed: July 16, 2018
    Date of Patent: July 26, 2022
    Assignee: KL-KEPONG OLEOMAS SDN BHD
    Inventors: Jordan Todorov Petkov, Hui Xu, Yee Seng Lim, Yee Wei Ung
  • Patent number: 8975056
    Abstract: Alpha-amylases from Bacillus subtilis (AmyE), variants thereof, nucleic acids encoding the same, and host cells comprising the nucleic acids are provided. Methods of using AmyE or variants thereof are disclosed, including liquefaction and/or saccharification of starch. Such methods may yield sugars useful for ethanol production or high fructose corn syrup production. In some cases, the amylases can be used at low pH, in the absence of calcium, and/or in the absence of a glucoamylase.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: March 10, 2015
    Assignee: Danisco US Inc.
    Inventors: Luis G. Cascao-Pereira, William A. Cuevas, David A. Estell, Sang-Kyu Lee, Scott D. Power, Sandra W. Ramer, Amr Toppozada, Louise Wallace
  • Publication number: 20140094397
    Abstract: The present invention relates to external structuring system(s) (ESS) comprising crystallized triglycerides including crystallized hydrogenated castor oil (HCO), surfactant and organic non-amino functional alcohols to reduce shear sensitivity. The present invention also relates to laundry detergent compositions in liquid or gel form comprising ESS.
    Type: Application
    Filed: August 12, 2013
    Publication date: April 3, 2014
    Applicant: The Procter & Gamble Company
    Inventors: Vincenzo GUIDA, Joris MEERT
  • Publication number: 20140051622
    Abstract: An oil-in-water emulsion comprising droplets of a molten hydrogenated castor oil, the droplets having a mean diameter of between 0.1 ?m and 4 ?m; and an anionic surfactant; and wherein the mean diameter is measured when the emulsion is at a temperature of between 85° C. and 95° C.
    Type: Application
    Filed: August 13, 2013
    Publication date: February 20, 2014
    Applicant: The Procter & Gamble Company
    Inventors: Niels DE MEIRLEIR, Walter August Maria BROECKX, Linda PELLENS
  • Patent number: 8323945
    Abstract: Alpha-amylases from Bacillus subtilis (AmyE), variants thereof, nucleic acids encoding the same, and host cells comprising the nucleic acids are provided. Methods of using AmyE or variants thereof are disclosed, including liquefaction and/or saccharification of starch. Such methods may yield sugars useful for ethanol production or high fructose corn syrup production. In some cases, the amylases can be used at low pH, in the absence of calcium, and/or in the absence of a glucoamylase.
    Type: Grant
    Filed: June 5, 2009
    Date of Patent: December 4, 2012
    Assignee: Danisco US Inc.
    Inventors: Luis G. Cascao-Pereira, William A. Cuevas, David A. Estell, Sang-Kyu Lee, Scott D. Power, Sandra W. Ramer, Amr Toppozada, Louise Wallace
  • Publication number: 20120277140
    Abstract: The present invention relates to aqueous surfactant systems that in diluted or undiluted form may be used for cleaning surfaces or may be used as an active cleaning base in various ready-to-use (or in-use) aqueous cleaning compositions suitable for surface cleaning. The invention also relates to a cleaning system comprising a surfactant system of the invention. According to the invention the cleaning efficacy of the surfactant system or cleaning system is increased by reducing or minimizing the size of the surfactants typically used in surfactant systems and reducing or minimizing the water solubility of the surfactant system.
    Type: Application
    Filed: July 6, 2012
    Publication date: November 1, 2012
    Applicant: NOVOZYMES BIOLOGICALS, INC.
    Inventors: Kenneth Edmund Kellar, Christina Edwards
  • Publication number: 20120213722
    Abstract: Aqueous free-flowing surfactant compositions having non-Newtonian shear thinning properties are disclosed. These stable compositions include both cationic and anionic surfactants and can suspend water-insoluble particles or partially insoluble components.
    Type: Application
    Filed: March 2, 2012
    Publication date: August 23, 2012
    Applicant: Rhodia Operations
    Inventors: Seren FRANTZ, Stewart Warburton
  • Patent number: 8211949
    Abstract: Novel mixtures of long-chain (C10-C20) olefins are functionalized by conversion to aldehydes using an OXO process, or to sulfates, sulfonates, sulfones, sulfides, or sulfoxides by direct sulfonation. The aldehydes may then be hydrogenated to form alcohols, or aminated to form amines or amides. The olefins starting mixture may be acquired as a byproduct of the tetramerization of ethylene in the presence of certain chromium-containing tetramerization catalysts. The functionalized mixtures, and derivatives prepared therefrom such as alkoxylates prepared from the alcohols, may be useful as surfactants that may offer improved performance in many applications, while their preparation based on a byproduct mixture reduces their cost and also reduces waste-handling issues for this non-targeted stream.
    Type: Grant
    Filed: September 16, 2008
    Date of Patent: July 3, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Pierre T. Varineau, Brian W. Kolthammer, Aaron W. Sanders, David A. Wilson, Kara S. Weber, Robert Kirk Thompson, Cynthia L. Rand, Thomas C. Eisenschmid
  • Publication number: 20110230389
    Abstract: The present invention relates to a method for producing an aqueous ?-SF salt solution that maintains fluidity and has superior production adaptability. The method includes dissolving a solid component (a) in the form of an ?-sulfo fatty acid alkyl ester salt and a component (b) in the form of an inorganic sodium salt and/or inorganic potassium salt in water, wherein component (a) is dissolved in water at a temperature of 50° C. or higher while maintaining the following condition (i) or (ii): (i): the concentration of component (a) is 35% by weight or less when the total concentration of sodium and potassium ions derived from component (b) is less than 0.55 mol/kg, or (ii) the concentration of component (a) is 55% by weight or less when the total concentration of sodium and potassium ions derived from component (b) is 0.55 mol/kg to less than 1.8 mol/kg.
    Type: Application
    Filed: November 20, 2009
    Publication date: September 22, 2011
    Applicant: Lion Corporation
    Inventors: Hiroyuki Masui, Kensuke Itakura, Hiroshi Gotou
  • Patent number: 7759301
    Abstract: Surfactant-containing compositions are described which include a protein component that has the effect of improving the surface-active properties of the surfactants contained in the compositions. The surfactant-containing compositions having the protein component demonstrate significantly lower critical micelle concentrations (CMC) than do comparable compositions having no protein component. In addition, the surfactant-containing compositions having the protein component has the effect of converting greasy waste contaminants to surface active materials.
    Type: Grant
    Filed: February 9, 2010
    Date of Patent: July 20, 2010
    Assignee: Advanced BioCatalytics Corp.
    Inventors: John W. Baldridge, Carl W. Podella
  • Patent number: 7737106
    Abstract: A process for making ionic liquids containing ion actives, which provide fabric treating benefits, surface treating benefits and/or air treating benefits. The ionic liquid is made from an ion active feedstock and an ionic liquid forming counterion feedstock, which preferably comprises another ion active.
    Type: Grant
    Filed: November 14, 2006
    Date of Patent: June 15, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Corey James Kenneally, Stacie Ellen Hecht, Scott Leroy Cron
  • Patent number: 7659237
    Abstract: Surfactant-containing compositions are described which include a protein component that has the effect of improving the surface-active properties of the surfactants contained in the compositions. The surfactant-containing compositions having the protein component demonstrate significantly lower critical micelle concentrations (CMC) than do comparable compositions having no protein component. In addition, the surfactant-containing compositions having the protein component have the effect of converting greasy waste contaminants to surface active materials.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: February 9, 2010
    Assignee: Advanced BioCatalytics Corp.
    Inventors: John W. Baldridge, Carl W. Podella
  • Publication number: 20090221463
    Abstract: The present invention relates to concentrated personal cleansing compositions having desirable lathering and dissolution properties.
    Type: Application
    Filed: January 16, 2009
    Publication date: September 3, 2009
    Inventors: David Johnathan Kitko, Mark William Hamersky, Howard David Hutton, III, David Clayton Brown, Thomas Allen Hutchins, Eric Scott Johnson
  • Publication number: 20080200565
    Abstract: Surfactant systems are provided that, upon contact with an oil, can produce a Windsor Type III middle phase microemulsion at a total surfactant concentration of 1.5% to 1.0% or less based on the weight of water in the surfactant system, without the need for a cosolvent or linking molecule. The microemulsions can have a separation time less than about 2 hours and even less than about 15 minutes.
    Type: Application
    Filed: January 28, 2008
    Publication date: August 21, 2008
    Inventors: Jeffrey H. Harwell, David A. Sabatini, William Shaw, Mrinal Gala, Bor-Jier Shiau, Tzu-Ping Hsu
  • Patent number: 7273840
    Abstract: The invention provides methods for obtaining dilution thickening behavior. Specifically, polydextrose induced biphasic compositions have been unexpectedly found to induce such behavior.
    Type: Grant
    Filed: July 14, 2005
    Date of Patent: September 25, 2007
    Assignee: Conopco, Inc.
    Inventors: Rajesh Patel, Kavssery Parameswaran Ananthapadmanabhan, Lin Yang
  • Patent number: 6730650
    Abstract: A liquid detergent composition includes an anionic surfactant component, a viscosity-enhancing agent, and a liquid carrier. The liquid detergent composition is substantially free of nonionic surfactant. The anionic surfactant component is present in an amount at least as great as about 2% by weight. The anionic surfactant component is also present in an amount no greater than about 7% by weight. The anionic surfactant component includes an alkyl ether sulfate material and a linear alkyl benzene sulfonate material which are present in a ratio in the range of from about 5:1 to about 1:0.5. The viscosity-enhancing agent is present in an amount sufficient so that the liquid detergent composition has a viscosity no less than about 120 centipoise.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: May 4, 2004
    Assignee: The Dial Corporation
    Inventor: Daniel Wood
  • Patent number: 6617303
    Abstract: Anionic surfactant compositions containing alkoxylated amines and having enhanced detergent performance. The compositions may be formulated with anionic surfactants such as alkylbenzene sulfonates having cations that may be exchanged with, for example, ethoxylated amine and/or ethoxylated ether amine to form a salt.
    Type: Grant
    Filed: January 7, 2000
    Date of Patent: September 9, 2003
    Assignee: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Raeda M. Smadi
  • Patent number: 6426326
    Abstract: The invention relates to liquid cleansing compositions in lattellar phase which possess a lotion-like appearance conveying signals of enhanced moisturization. However, these liquids often undergo an irreversible decrease in viscosity under freeze/thaw conditions, losing their moisturization signals. The use of low salt levels in amphoteric and anionic surfactants in a structured liquid product has been found to improve its freeze/thaw stability.
    Type: Grant
    Filed: August 3, 2000
    Date of Patent: July 30, 2002
    Assignee: Unilever Home & Person Care USA, a division of Conopco, Inc.
    Inventors: Shuman Mitra, Sudhakar Puvvada
  • Patent number: 6391843
    Abstract: A composition comprising: an organic chemical having a chemical group having a dipole moment of at least about 1.5 Debyes and a chemical linker selected from the group consisting of carboxylic acids having 4 to 6 carbon atoms, an ethoxylated polyhydric alcohol, a polyvinyl pyrrolidone and a polyethylene glycol having a molecular weight of about 600 to about 10,000, wherein the molar ratio of organic chemical to chemical linker is about 4:1 to 1:4.
    Type: Grant
    Filed: September 1, 2000
    Date of Patent: May 21, 2002
    Assignee: Colgate-Palmolive Co.
    Inventors: Michele Davister, Guy Broze, Patrick Durbut, Hoai-Chau Cao, Thomas Connors, John Labows, Anne-Marie Misselyn
  • Patent number: 6387860
    Abstract: A light duty, liquid comprising: a paraffin sulfonate, an alpha olefin sulfonate, an amine oxide, a magnesium containing inorganic compound, and water.
    Type: Grant
    Filed: June 7, 2000
    Date of Patent: May 14, 2002
    Assignee: Colgate-Palmolive Co.
    Inventors: Joan Gambogi, Leonard Zyzyck, Evangelia Arvanitidou
  • Patent number: 6329333
    Abstract: A paste-form detergent and process of making the detergent is presented. The detergent is composed of: 5 to 30 percent by weight of an ethoxylated alcohol of the formula R1—(OC2H4)m—OH where R1 is an alkyl or alkenyl group containing 9 to 15 carbon atoms and the average degree of ethoxylation m is 1 to 8; 1 to 20 percent by weight of an ethoxylated alcohol of the formula R2—(OC2H4)nOH where R2 is an alkyl or alkenyl group containing 12 to 22 carbon atoms and the average degree of ethoxylation n is 3 to 14, and n is greater than m by at least 1.0; 1 to 20 percent by weight of an alcohol or alkyl ether corresponding to the formula R3—O—R4 where R3 is an alkyl or alkenyl group containing 6 to 22 carbon atoms and R4 is hydrogen or an alkyl group containing 1 to 6 carbon atoms; 20 to 80 percent by weight of an alkalizing agent, and 0 to 15 percent by weight of an organic builder.
    Type: Grant
    Filed: October 18, 1999
    Date of Patent: December 11, 2001
    Assignee: Henkel-Ecolab GmbH & Co. OHG
    Inventors: Thomas Merz, Khalil Shamayeli, Edgar Koeppelmann
  • Patent number: 6329331
    Abstract: An aqueous detergent composition, which is in the form of a thickened, mobile fluid, comprising foaming detergent and a polymer or polymer mixture which is capable of forming a reversible gel, which polymer or mixture is present in the composition as a multiplicity of individual gel particles.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: December 11, 2001
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Michael Paul Aronson, Charles Rupert Brown, Robert James Chatfield, Peter Fairley, Ian Timothy Norton, Jason Richard Williams
  • Patent number: 6255267
    Abstract: The present invention is an improved liquid toilet bowl cleanser comprising a fluorosurfactant coating agent, an anionic or non-ionic cleaner and a rheology control agent together with other minor excipients. The flurosurfactant continually adheres to and coats the porcelain surface of the toilet bowl during the active life of the cleanser composition preventing the formation of toilet bowl stains and mineral deposits for a substantial period of time after manual cleaning.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: July 3, 2001
    Assignee: HPD Laboratories, Inc.
    Inventors: Bala C. Nayar, Ronnie A. Carroll, Kenneth J. Ward
  • Patent number: 6248708
    Abstract: A paste-form detergent for use in institutional laundries free from synthetic anionic surfactant of the alkyl benzenesulfonate type containing 5% to 30% by weight of an ethoxylated alcohol corresponding to formula (I): R1—(OC2H2)m—OH   (I) in which R1 is an alkyl or alkenyl group containing 12 to 14 carbon atoms and m has a value of 1 to 8, 1% to 20% by weight of an ethoxylated alcohol corresponding to formula (II): R2—(OC2H2)n—OH   (II) in which R2 is an alkyl or alkenyl group containing 12 to 22 carbon atoms and n has a value of 3 to 14, with proviso that n is greater than m by at least 1.
    Type: Grant
    Filed: March 5, 1999
    Date of Patent: June 19, 2001
    Assignee: Henkel-Ecolab GmbH & Co. OHG
    Inventors: Thomas Merz, Khalil Shamayeli
  • Patent number: 6234183
    Abstract: A method and composition for removing deposits of heavy hydrocarbonaceous materials and finely divided inorganic particulate matter from wellbore and flowline surfaces using a composition containing an alkyl polyglycoside, an ethoxylated alcohol, a caustic and an alkyl alcohol.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: May 22, 2001
    Assignee: Atlantic Richfield Company
    Inventors: Albert F. Chan, William Mark Bohon, David J. Blumer, Kieu T. Ly
  • Patent number: 6159927
    Abstract: The present invention relates to structured surfactant compositions comprising a detergent surfactant and hydrophilic silica particulates to be used in granular detergent compositions. The preferred silica particulate is hydrophilic precipitated silica. The process for making a structured surfactant composition comprising a detergent surfactant and hydrophilic silica particulates is also included. The present invention encompasses a structured surfactant composition consisting essentially of: (a) from about 35% to about 60% of a detergent surfactant; (b) from about 1% to about 20% of hydrophylic, finely-divided silica particulate; and (c) from about 15% to about 25% moisture.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: December 12, 2000
    Assignee: The Procter & Gamble Company
    Inventor: Manivannan Kandasamy
  • Patent number: 6147044
    Abstract: A light duty, liquid comprising: a paraffin sulfonate, an alpha olefin sulfonate, an amine oxide, a magnesium containing inorganic compound, and water.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: November 14, 2000
    Assignee: Colgate Palmolive Company
    Inventors: Joan Gambogi, Leonard Zyzyck, Evangelia Arvanitidou
  • Patent number: 6099589
    Abstract: In fabric laundry procedures, commercial and household laundry detergent compositions commonly contain an optical brightener composition. Brighteners adjust the optical properties of the fabric in such a way that the fabric appears to be white even after repeated washings. Often white fabrics can yellow during use. Fluorescent optical brighteners having an optical blue aspect, mask the yellowing of the fabric. Common laundry detergents fail to have sufficient brightening capacity to brighten heavily soiled white cotton items used in household, commercial, institutional or fast-food food surface. A process for improving the whiteness of soiled white cotton, preferably terry cloth, items involves contacting the soiled white fabric item with a presoak containing an effective proportion of a fluorescent optical brightener composition, removing the item from the presoak and separating the presoak composition from the fabric item producing an extracted item.
    Type: Grant
    Filed: December 30, 1997
    Date of Patent: August 8, 2000
    Assignee: Kay Chemical Company
    Inventors: Eddie D. Sowle, Carleton J. Parker, III
  • Patent number: 6087320
    Abstract: A stable, pumpable, flowable and pourable surfactant concentrate, and a method of preparation thereof, said concentrate consisting essentially of (a) at least one anionic or amphoteric surfactant, (b) at least one alkylpolyglycoside surfactant, (c) a viscosity-adjusting agent selected from the group consisting of inorganic and organic electrolytes and (d) water. The concentrate is economically shippable and easily handleable by the formulator for dilution with water, without gelation difficulties, for a variety of end-use applications with adjuvants usually associated with the desired end-use.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: July 11, 2000
    Assignee: Henkel Corp.
    Inventors: Allen D. Urfer, Virginia Lazarowitz, Patricia E. Bator, Barry A. Salka, Robert A. Aleksejczyk
  • Patent number: 6048831
    Abstract: A low-viscosity surfactant composition which contains an anionic surfactant and which is excellent in handleability even in a high surfactant concentration range and is easily handleable at room temperature is provided, which comprises (a) a nonionic surfactant represented by the general formula (I) and (b) an anionic surfactant at an (a)/(b) weight ratio ranging from 99/1 to 10/90:RO--(EO).sub.x --(PO).sub.y --(EO).sub.x',--H (I)wherein R represents C.sub.8 -C.sub.20 alkyl or the like; EO represents oxyethylene; PO represents oxypropylene; x and x' are each 1 or above; and y is more than 0 but below the sum of x and x', provided (EO).sub.x, (PO).sub.y and (EO).sub.x', are bonded to each other in block in this order.
    Type: Grant
    Filed: July 30, 1998
    Date of Patent: April 11, 2000
    Assignee: Kao Corporation
    Inventors: Atsuhito Mori, Yasuo Ishii, Hiroki Sawada
  • Patent number: 6025318
    Abstract: An improvement is described in all purpose liquid cleaning composition and microemulsion composition which are especially effective in the removal of oily and greasy soil and contains an anionic detergent, a nonionic surfactant, a short chain amphiphile, a hydrocarbon ingredient, and water.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: February 15, 2000
    Assignee: Colgate Palmolive Company
    Inventor: Baudouin Mertens
  • Patent number: 6004919
    Abstract: An improvement is described in all purpose liquid cleaning composition and microemulsion composition which are especially effective in the removal of oily and greasy soil and contains an anionic detergent, a nonionic surfactant, a short chain amphiphile, a hydrocarbon ingredient, and water.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: December 21, 1999
    Assignee: Colgate-Palmolive Co.
    Inventor: Baudouin Mertens
  • Patent number: 5981450
    Abstract: A surfactant mixture containing(a) monoglyceride sulfates or monoglyceride ether sulfates, and(b) amino acid derivatives selected from(b1) acyl glutamates,(b2) vegetable protein hydrolyzates, and(b3) vegetable protein fatty acid condensates.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: November 9, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernd Fabry, Ansgar Behler
  • Patent number: 5908582
    Abstract: A liquid composition comprisingA) at least one sulosuccinic acid diester of the formula: ##STR1## in which M is an inorganic or organic cation, R and R' independently of one another represent aliphatic or cycloaliphatic C.sub.3-22 alkyl, C.sub.2-22 alkenyl or optionally C.sub.1-8 alkyl-substituted C.sub.6-22 aryl;B) water as a solvent; andC) a cosolvent consisting essentially of at least one polymer containing alkylene oxide units which is liquid at 10.degree. C.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: June 1, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Dieter Feustel, Uwe Held, Joachim Meyer
  • Patent number: 5885952
    Abstract: A detergent base which is obtainable from the reaction of an ethylenically unsaturated sulfonic acid or carboxylic acid or anhydride thereof with a nonionic surfactant of the formulaR.sub.1 --O-(alkylene-O).sub.n.sbsb.1 --R.sub.2 (1)in whichR.sub.1 is C.sub.8 -C.sub.22 alkyl or C.sub.8 -C.sub.18 alkenyl;R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, a cycloaliphatic radical having at least 6 C atoms or benzyl; andn.sub.1 is a number from 1 to 60;and if appropriate with sugar derivatives.The detergent base has a good calcium-dispersing power, is very stable to electrolytes and heat and has an excellent washing action and anti-redeposition properties. It is therefore suitable for the preparation of powder and liquid detergents.
    Type: Grant
    Filed: May 15, 1996
    Date of Patent: March 23, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rolf Kuratli, Claude Eckhardt, Frank Bachmann, Werner Schreiber
  • Patent number: 5872093
    Abstract: A detergent composition with excellent color care properties. The detergent composition comprises a dendritic macromolecule.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: February 16, 1999
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Daniel Convents, Rudolf Willem Pieter van Drunen, Jean Hypolites Koek
  • Patent number: 5858961
    Abstract: The invention relates to a process for the production of light-colored surfactants in which the surfactants are stabilized before bleaching by addition of antioxidants.
    Type: Grant
    Filed: February 6, 1996
    Date of Patent: January 12, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Manfred Weuthen
  • Patent number: 5814596
    Abstract: The present invention provides a structured paste which is substantially free of LAS and which is suitable for processing into a high bulk density, high active granular detergent. Surfactant pastes of the present invention have a viscosity of at least 10 Pa.s (measured at 70.degree. C. and 25 sec.sup.-1) and comprise: from 30% to 90% by weight of anionic surfactant; from 0% to 50% by weight of nonionic surfactant; from 0.5% to 20% by weight of either a polymeric cationic material or a polar amino acid; and from 1% to 40% by weight of water.
    Type: Grant
    Filed: February 24, 1997
    Date of Patent: September 29, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Yousef Georges Aquad, Brian Joseph Pangrle, Johan Gerwijn L. Pluyter
  • Patent number: 5811386
    Abstract: A surface active mixture comprising: (A) from about 1 to about 50% by weight of an anionic surfactant having one or two lipophilic groups and having from 1 to 22 carbon atoms and a polar group selected from the group consisting of carboxylate, sulfate and sulfonate groups; (B) from about 0.5 to about 15% by weight of an alkyl glycoside of the formula R(G).sub.x, wherein R is a linear saturated alkyl radical having from 8 to 22 carbon atoms and (G).sub.x is a glycoside or oligoglycoside unit with a degree of oligomerization x of 1 to 10; (C) from about 0.1 to about 7% by weight of a nitrogen-containing copolymer having a molecular weight of from about 15,000 to about 1,500,000 wherein said copolymer is comprised of: (i) from about 99.5 to about 45 mole-% of units derived from vinyl pyrrolidone, (ii) from at 0.5 to about 50 mole-% of units derived from a monomer corresponding to formula (I):CH.sub.2 .dbd.CHR.sup.1 --COOR.sup.2 --NR.sup.3 R.sup.4 (I)R.sup.1 is hydrogen or methyl, R.sup.2 is a C.sub.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: September 22, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Reinhard Mueller, Kurt Seidel, Detlef Hollenberg, Manuela Ehlert
  • Patent number: 5759979
    Abstract: Detergent mixtures containing a) alkyl and/or alkenyl oligoglycosides corresponding to formula (I)R.sup.1 O--?G!.sub.p (I)in which R.sup.1 is an alkyl or alkenyl radical containing 8 to 22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and p is a number of 1 to 10; b) fatty alcohol polyglycol ethers corresponding to formula (II) ##STR1## in which R.sup.2 represents alkyl radicals containing 6 to 14 carbon atoms, n is a number of 0.5 to 2 and m is a number of 2 to 10 and, optionally, c) amphoteric or zwitterionic surfactants and water, have synergistic effects in regard to their washing, dishwashing, foaming and cleaning performance and in regard to their skin-cosmetic compatibility. Accordingly, they are suitable for the production of a number of surface-active preparations, particularly manual dishwashing detergents.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: June 2, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl Schmid, Brigitte Giesen, Karin Koren
  • Patent number: 5688759
    Abstract: Nitrogen-free anionic conditioning formulations containing sulfated polyol fatty acid esters corresponding to formula (I): ##STR1## in which R.sup.1 CO is a linear or branched, saturated or unsaturated acyl radical containing 6 to 22 carbon atoms, R.sup.2 represents hydrogen, an OCR.sup.1 group or an SO.sub.3 X group, R.sup.3 is hydrogen or an (OCH.sub.2 CH.sub.2).sub.m OR.sup.2 group, n is 0 or a number of 1 to 5, m is 0 or a number of 1 to 10, and X is an alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium ion.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: November 18, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ansgar Behler, Gunther Uphues, Bernd Wahle
  • Patent number: 5686400
    Abstract: Liquid manual dishwashing detergent compositions which exhibit superior foaming and detergency properties in laboratory tests are comprised of alkyl sulfates, .alpha.-olefin sulfonates alkyl betaines, and alkyl polyglycosides.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: November 11, 1997
    Assignee: Henkel Corporation
    Inventors: Allen D. Urfer, Virginia L. Lazarowitz
  • Patent number: 5646106
    Abstract: Novel cold pearlizing concentrates provide pearlescent personal hair and skin compositions such as shampoos and beauty soaps with added luster and sheen.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: July 8, 1997
    Assignee: Rhone-Poulenc Specialty Chemicals Asia Pacific PTE LTD
    Inventors: Pu Chen, Siew Fang Yoong
  • Patent number: 5599787
    Abstract: Aqueous solutions of anionic surfactants having improved low-temperature stability are obtained by addition to the solutions of mixtures of nonionic surfactants containinga) alkyl and/or alkenyl oligoglycosides corresponding to formula (I)R.sup.1 -O-[G].sub.p (I)in which R.sup.1 is an alkyl and/or alkenyl radical containing 6 to 22 carbon atoms, G is a sugar unit containing 5 or 6 carbon atoms and p is a number of 1 to 10,b) fatty alcohol polyglycol ethers corresponding to formula (II) ##STR1## in which R.sup.2 is an alkyl radical containing 8 to 11 carbon atoms, n is a number of 4 to 9 and m=0 or is a number of 1 to 3, and optionallyc) fatty alcohol polyglycol ethers corresponding to formula (III) ##STR2## in which R.sup.3 is an alkyl radical containing 12 to 15 carbon atoms, n is an integer of 4 to 9 and m=0 or is a number of 1 to 3.The products are particularly suitable for the production of manual dishwashing detergents.
    Type: Grant
    Filed: June 19, 1995
    Date of Patent: February 4, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl Schmid, Brigitte Giesen, Andreas Syldath
  • Patent number: 5589447
    Abstract: A liquid dishwashing-detergent composition containing an anionic surfactant, at least two types of amphoteric compounds, and a nonionic surface active compound. The amphoteric compounds are characterized by general formula (I) and (III) or (IV): ##STR1## wherein R is a hydrocarbon group having 7-22 carbon atoms, n is 0 or 1, A is a carbonyl group (C(O)), a group (OCH.sub.2 CH.sub.2).sub.z or a group (OCH.sub.2 CH.sub.2 CH.sub.2).sub.z in which z is an integer from 1 to 5, R.sub.1 is hydrogen or a lower alkyl group, x is 2 or 3, y is an integer from 0 to 4, Q is the group --R.sub.2 COOM in which R.sub.2 is an alkylene group having 1-6 carbon atoms and M is hydrogen or an ion from the groups alkali metals, alkaline earth metals, ammonium and substituted ammonium, and B is hydrogen or a group Q as defined above; ##STR2## wherein R is a longer hydrophobic hydrocarbon group having at least 7 carbon atoms, R' is an alkyl or hydroxyalkyl group having 1-4 carbon atoms, n is 1 or 2, and M is hydrogen or a sodium ion.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: December 31, 1996
    Assignee: Berol Nobel AB
    Inventor: Jadwiga Palicka
  • Patent number: 5562866
    Abstract: Certain double-tailed alcohol ether sulfates of specified chemical structures are formulated with a hydrotrope or a co-surfactant. The formulations are useful for various surfactant utilities including use in hard water systems.
    Type: Grant
    Filed: June 20, 1995
    Date of Patent: October 8, 1996
    Assignee: Albemarle Corporation
    Inventors: Patrick C. Hu, Raynold J. Corona
  • Patent number: 5556577
    Abstract: A high foaming, light duty liquid detergent with desirable cleansing properties and mildness to the human skin composing: a water soluble nonionic surfactant; a ethoxylated alkyl ether sulfate anionic surfactant, a zwitterionic betaine surfactant and the balance being water.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: September 17, 1996
    Assignee: Colgate-Palmolive Co.
    Inventors: Gilbert S. Gomes, Rita Erilli, Ronald Kern
  • Patent number: 5554313
    Abstract: The present invention relates to shampoo compositions and more particularly shampoo compositions containing non-volatile silicone materials and methods of making the same. Specifically, this invention is directed to aqueous shampoo compositions comprising sorbitan stearate, sorbitan distearate or mixtures thereof; stearyl alcohol ethoxylates, insoluble non-volatile silicone, and combinations of surfactants selected from anionic, nonionic and amphoteric surfactants. This invention also relates to a method of forming a aqueous shampoo composition comprising insoluble, non-volatile silicone by the method of forming a preformed aqueous silicone emulsion and combining with a combination of surfactants.
    Type: Grant
    Filed: June 28, 1994
    Date of Patent: September 10, 1996
    Assignee: ICI Americas Inc.
    Inventor: John M. Chandler
  • Patent number: H1632
    Abstract: The present invention provides a clear, flowable liquid laundry detergent formulation comprising one or more of certain alcohol ethoxylate compounds, one or more alcohol ethoxysulfate compounds, one or more alkylaryl sulfonate compounds, water and, optionally, one or more organic water-soluble builders.
    Type: Grant
    Filed: August 15, 1994
    Date of Patent: February 4, 1997
    Assignee: Shell Oil Company
    Inventors: Anne M. Brun, Kirk H. Raney