Carbonyl Attached Indirectly To The Ring System By Nonionic Bonding Patents (Class 512/18)
  • Patent number: 10883066
    Abstract: Trans isomers of formula (I) in the form of any of its stereoisomers or a mixture thereof are provided, wherein the bold and hatched lines indicate a relative or absolute configuration. Also provided are their uses as perfuming ingredients to impart vetiver/rooty notes e.g. in perfuming compositions or in consumer products.
    Type: Grant
    Filed: March 29, 2018
    Date of Patent: January 5, 2021
    Assignee: Firmenich SA
    Inventors: Anthony Alexander Birkbeck, Hervé Pamingle
  • Publication number: 20150051133
    Abstract: An aldehyde of formula (I) in the form of any one of its stereoisomers or a mixture thereof, wherein each dotted line, independently from each other, represents a single or double bond; n is 0 or 1; R1 is a hydrogen atom or a methyl group; R2 is a hydrogen atom or a methyl or ethyl group; and R3, which can be present in any of positions 2 to 6 of the cyclic moiety, is a hydrogen atom or a methyl or ethyl group, or a CH2 group bridging positions 3 and 6. Also, the use of the aldehyde as perfuming ingredient to impart odor notes of the aldehyde, lily of the valley type.
    Type: Application
    Filed: January 24, 2013
    Publication date: February 19, 2015
    Applicant: FIRMENICH SA
    Inventor: Robert Moretti
  • Publication number: 20140378360
    Abstract: The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities' options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.
    Type: Application
    Filed: September 12, 2014
    Publication date: December 25, 2014
    Inventors: Hugo Robert Germain DENUTTE, Johan SMETS, An PINTENS, Koen VAN AKEN, Freek Annie Camiel VRIELYNCK
  • Publication number: 20140235520
    Abstract: Perfume ingredients have been investigated and classified for their effectiveness in detaching biofilms from surfaces. Based on this classification, perfume compositions that are effective in assisting biofilm detachment can be formulated, whilst also allowing a degree of freedom in formulation that permits consideration of the hedonic properties of the composition. The compositions can be used in a wide range of perfumed consumer products, such as personal, domestic and industrial products, e.g. hard surface cleaning products, dental care products, and deodorant products.
    Type: Application
    Filed: January 21, 2014
    Publication date: August 21, 2014
    Applicant: Givaudan Nederland Services B.V.
    Inventors: David Jonathan Bradshaw, Alan Forbes Provan, Christopher James Ioannou, John Martin Behan, Keith Douglas Perring
  • Publication number: 20140194338
    Abstract: A fragrance composition and use thereof by inhalation to promote activated, pleasant moods. The fragrance composition comprises at least 75% by weight of perfume materials including at least 10% by weight of at least three specific materials from a group identified as Group IMP and optionally up to 90% of specific materials selected from groups identified as HMR, HMI, HMP, RMP and GEN, the amounts of materials from said Groups falling within specified relationships.
    Type: Application
    Filed: December 3, 2013
    Publication date: July 10, 2014
    Applicant: Givaudan Nederland Services B.V.
    Inventors: John Martin Behan, Briony Care, Anne Churchill, Michael Gordon Evans, Keith Douglas Perring, Alan Forbes Provan
  • Publication number: 20140107220
    Abstract: The present invention is directed to a novel fragrance compound of octahydro-4,7-methano-1H-indene-5-acetaldehyde.
    Type: Application
    Filed: December 13, 2013
    Publication date: April 17, 2014
    Applicant: International Flavors & Fragrances Inc.
    Inventors: Anubhav P.S. Narula, James Anthony Lasome, Richard A. Weiss, Michael G. Monteleone
  • Publication number: 20140107221
    Abstract: The present invention is directed to a novel fragrance compound of octahydro-6-methyl-4,7-methano-1H-indene-5-carboxaldehyde.
    Type: Application
    Filed: December 13, 2013
    Publication date: April 17, 2014
    Applicant: International Flavors & Fragrances Inc.
    Inventors: Anubhav P.S. Narula, James Anthony Lasome, Richard A. Weiss, Michael G. Monteleone
  • Publication number: 20140030204
    Abstract: A method to confer, enhance, improve or modify the odor properties of a perfuming composition or of a perfumed article by adding to the composition or article an effective amount of at least one compound of formula I: wherein n represents 0, 1 or 2; m represents 0, 1 or 2; the dotted lines represent only single bonds or one double bond and two single bonds; R1 represents a hydrogen atom or a methyl or ethyl group, and R2 represents an OR3 group, R3 representing a C1-C3 alkyl or alkenyl group; a group of formula CR4?C(R4)2, or a group of formula with R4 representing a hydrogen atom or a methyl or ethyl group. These compounds impart a clean and natural fruity, pineapple odor type to the perfuming compositions or perfumed articles to which they are added.
    Type: Application
    Filed: October 1, 2013
    Publication date: January 30, 2014
    Applicant: FIRMENICH SA
    Inventors: Christian CHAPUIS, Anthony BIRKBECK, Maurus MARTY
  • Patent number: 8445424
    Abstract: A method of providing to a fragrance application a musky odor, comprising the addition thereto of at least one compound according to the formula I in which R1 is selected from H and CH3; R2, R3 are selected from the possibilities that (a) both are CH3; and (b) R2 and R3 together form a single bond (as indicated by the broken line); and n is an integer selected from 1, 2, 3, and 4. The compounds are useful in the complete range of fine and functional fragrance applications.
    Type: Grant
    Filed: April 23, 2009
    Date of Patent: May 21, 2013
    Assignee: Givaudan SA
    Inventor: Philip Kraft
  • Patent number: 8445727
    Abstract: A compound and a method to confer, enhance, improve or modify the odor properties of a perfuming composition or of a perfumed article, to confer a green allylic, glycolate and fruity-pineapple odor, by adding the compound thereto. The compound has formula (I): wherein the dotted line represents a carbon-carbon single bond or a carbon-carbon double bond; one R1 represents a hydrogen atom and the other represents a hydrogen atom or a methyl or ethyl group; X representing a C?CH2 or C?CHCH3 group or a CHR2 group, each R2 representing a hydrogen atom or a methyl or ethyl group; and R3 represents a a group of formula CR4?C(R4)2, or a group of formula each R4 representing a hydrogen atom or a methyl or ethyl group. The compound is in the form of a pure enantiomer or a mixture thereof.
    Type: Grant
    Filed: May 12, 2011
    Date of Patent: May 21, 2013
    Assignee: Firmenich SA
    Inventor: Anthony A. Birkbeck
  • Publication number: 20130085204
    Abstract: Unscented and low scented malodor control compositions are provided. The malodor control compositions are suitable for a variety of applications, including use on plastic films or in fabric and air freshening products.
    Type: Application
    Filed: September 30, 2011
    Publication date: April 4, 2013
    Inventors: Judith Ann HOLLINGSHEAD, Steven Anthony Horenziak, Zaiyou Liu, Michael-Vincent Nario Malanyaon, Christine Marie Readnour
  • Publication number: 20130045906
    Abstract: A compound and a method to confer, enhance, improve or modify the odor properties of a perfuming composition or of a perfumed article, to confer a green allylic, glycolate and fruity-pineapple odor, by adding the compound thereto. The compound has formula (I): wherein the dotted line represents a carbon-carbon single bond or a carbon-carbon double bond; one R1 represents a hydrogen atom and the other represents a hydrogen atom or a methyl or ethyl group; X representing a C?CH2 or C?CHCH3 group or a CHR2 group, each R2 representing a hydrogen atom or a methyl or ethyl group; and R3 represents a a group of formula CR4?C(R4)2, or a group of formula each R4 representing a hydrogen atom or a methyl or ethyl group. The compound is in the form of a pure enantiomer or a mixture thereof.
    Type: Application
    Filed: May 12, 2011
    Publication date: February 21, 2013
    Applicant: Firmenich SA
    Inventor: Anthony A. Birkbeck
  • Publication number: 20110308555
    Abstract: The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities' options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.
    Type: Application
    Filed: June 22, 2011
    Publication date: December 22, 2011
    Inventors: Johan SMETS, Hugo Robert Germain Denutte, An Pintens, Koen Van Aken, Freek Annie Camiel Vrielynck
  • Patent number: 8071529
    Abstract: The present invention relates to novel compounds and their use in fragrance compositions. Novel 3.2.1-bicyclo-octene and -octane compounds of the present invention are represented by formula: wherein R is selected from the group consisting of hydrogen, acetate, carbonate monomethyl ester, and allyloxy; and wherein the broken line represents a single or double bond.
    Type: Grant
    Filed: October 8, 2010
    Date of Patent: December 6, 2011
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Adam P. Closson, Benjamin Amorelli, Nicole O'Keefe
  • Patent number: 8030524
    Abstract: Described are 2,2,3-trimethylcyclopentane derivatives of formula 1 wherein R1 is methyl or ethyl; and R2 is hydrogen, methyl or ethyl. The invention furthermore relates to a method of their production a to fragrance compositions comprising them.
    Type: Grant
    Filed: November 2, 2007
    Date of Patent: October 4, 2011
    Assignee: Gibaudan SA
    Inventor: Jerzy A. Bajgrowicz
  • Patent number: 8022030
    Abstract: The present invention relates to the field of perfumery. More particularly, it concerns co-polymers, derived from a maleic anhydride derivative and a ethylenic derivative, comprising at least one ?-oxy or ?-thio carbonyl moiety capable of liberating an active molecule such as, for example, an ?,?-unsaturated ketone, aldehyde or carboxylic ester. The present invention concerns also the use of polymers or co-polymers in perfumery as well as the perfuming compositions or perfumed articles comprising the invention's compounds.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: September 20, 2011
    Assignee: Firmenich SA
    Inventors: Damien Berthier, Andreas Herrmann
  • Publication number: 20110039755
    Abstract: A method of providing to a fragrance application a musky odour, comprising the addition thereto of at least one compound according to the formula I in which R1 is selected from H and CH3; R2, R3 are selected from the possibilities that (a) both are CH3; and (b) R2 and R3 together form a single bond (as indicated by the broken line); and n is an integer selected from 1, 2, 3, and 4. The compounds are useful in the complete range of fine and functional fragrance applications.
    Type: Application
    Filed: April 23, 2009
    Publication date: February 17, 2011
    Inventor: Philip KRAFT
  • Patent number: 7648955
    Abstract: A fragrance composition is provided comprising from about 10% wt to about 40% wt of a residual accord, the residual accord comprising perfume raw materials (PRMs) selected from at least three of the five defined classes. In addition, personal care compositions comprising the defined fragrance composition are also provided.
    Type: Grant
    Filed: November 4, 2004
    Date of Patent: January 19, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Zerlina Guzdar Dubois, Lynette Anne Makins Holland
  • Patent number: 7601682
    Abstract: Mixtures are described which comprise or consist of 3-(4-methylcyclohex-3-enyl)butyraldehyde (limonenal) and (4aR,5R,7aS,9R)-octahydro-2,2,5,8,8,9a-hexamethyl-4H-4a,9-methanoazuleno(5,6-d)-1,3-dioxole (Ambrocenide®), the weight ratio of limonenal to Ambrocenide® being in the range from 150:1 to 2500:1.
    Type: Grant
    Filed: December 31, 2007
    Date of Patent: October 13, 2009
    Assignee: SYMRISE GmbH & Co. KG
    Inventors: Fred Naraschkewitz, Marcus Eh
  • Patent number: 7348304
    Abstract: The invention provides a novel fragrance material comprising a compound having the structure (IUPAC name (1R,2S,7R,8R,9S)-2,6,6,9-tetramethyltricyclo-[5.4.0.02,8]undecan-10-one). The novel fragrance material has a strong, pleasant cedar wood fragrance and is useful for imparting, strengthening, or improving the odor of perfumes and perfumed products. Methods for preparing the novel fragrance material are described.
    Type: Grant
    Filed: December 20, 2004
    Date of Patent: March 25, 2008
    Inventor: Laurence G. Cool
  • Patent number: 7312187
    Abstract: Described are polyalkylbicylic chemical derivatives for use a fragrance ingredients having the generic structure: wherein m=0 or 1; wherein X is methyl or hydrogen; wherein R1, R2, R3 and R4 each represents methyl or ethyl with the proviso that when X is methyl, each of R1, R2, R3 and R4 is methyl and when X is hydrogen, one of R1, R2, R3 and R4 is ethyl; and wherein R6 represents hydrogen or methyl. Methods for using and making these compounds are also disclosed.
    Type: Grant
    Filed: September 26, 2003
    Date of Patent: December 25, 2007
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Anubhav P. S. Narula, Edward Mark Arruda
  • Patent number: 7250528
    Abstract: The present invention relates to a process for making indenol esters or ethers from an ?-substituted cinnamic aldehyde derivative such as an acetal or an acylal. Said reaction is promoted by the use of strong mineral acids, sulphonic acids, acidic zeolites or Lewis acids.
    Type: Grant
    Filed: October 12, 2006
    Date of Patent: July 31, 2007
    Assignee: Firmenich SA
    Inventors: Gary Bernard Womack, Roger Leslie Snowden, Hervé Mosimann, Anthony Alexander Birkbeck
  • Publication number: 20040214745
    Abstract: Novel ester compounds and the use of these esters as a fragrance chemicals, suitable for use in creating fragrance, and scents in items such as perfumes, colognes and personal care products are disclosed.
    Type: Application
    Filed: May 14, 2004
    Publication date: October 28, 2004
    Inventors: James O. Bledsoe, Michael Britten-Kelly, Mark A. Sprecker, Robert P. Belko, Manfred Pawlak, Michael G. Monteleone
  • Patent number: 6362141
    Abstract: The present invention is directed to indanyl derivatives and the use of the indanyl derivatives in creating fragrances, and scents in items such as perfumes, colognes and personal care products.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: March 26, 2002
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Richard A. Weiss, Robert P. Belko, Ellen Ann Molner
  • Patent number: 6284929
    Abstract: The invention relates to compounds of the general formula in which R1 to R7 are, independently, H, methyl or ethyl, R8+R9 together form methylene (—CH2—) or a single bond, or R1+R2 together form —(CH2)n—, with n being 3 or 4, or R3+R5 or R5+R7 represent methylene or a single bond; and the presence of at least one cyclopropane ring in the molecule is compulsory and the side chain can be saturated or contains one double bond in position &agr;,&bgr; or &bgr;,&ggr;, a process for the manufacture of these compounds, compounds used to perform the process and the use of these compounds as an odorant or as an ingredient of an odorant composition.
    Type: Grant
    Filed: October 5, 2000
    Date of Patent: September 4, 2001
    Assignee: Givaudan Roure (International) SA
    Inventors: Jerzy A. Baigrowicz, Georg Frater
  • Patent number: 6235943
    Abstract: The invention relates to compounds of the general formula in which R1 to R7 are, independently, H, methyl or ethyl, R8+R9 together form methylene (—CH2—) or a single bond, or R1+R2 together form —(CH2)n—, with n being 3 or 4, or R3+R5 or R5+R7 represent methylene or a single bond; and the presence of at least one cyclopropane ring in the molecule is compulsory and the side chain can be saturated or contains one double bond in position &agr;,&bgr; or &bgr;,&ggr;, a process for the manufacture of these compounds, compounds used to perform the process and the use of these compounds as an odorant or as an ingredient of an odorant composition.
    Type: Grant
    Filed: October 5, 2000
    Date of Patent: May 22, 2001
    Assignee: Givaudan Roure (International) SA
    Inventors: Jerzy A. Bajgrowicz, Georg Frater
  • Patent number: 6184419
    Abstract: The present invention relates to new &agr;,&bgr;-unsaturated ketones of formula I. The new compounds exhibit an intense, very long lasting green galbanum-type odor with fruity undertones. Compositions containing these novel compounds are also provided.
    Type: Grant
    Filed: May 10, 2000
    Date of Patent: February 6, 2001
    Assignee: Givaudan Roure (International) SA
    Inventors: Katja Berg-Schultz, Jerzy A. Bajgrowiecz
  • Patent number: 6126953
    Abstract: The present invention relates to personal care and personal hygiene articles containing a fragrance delivery system which comprises one or more pro-accords, preferably .beta.-ketoester pro-accords, which are capable of releasing mixtures of fragrance raw materials. The pro-accords which comprise the fragrance delivery systems are useful in delivering sustained fragrances to personal care items inter alia deodorants, anti-perspirants, suntan lotions, hair sprays, mousses, shaving creams, body lotions and creams, depilitories, facial masks, athletic rubs and creams.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: October 3, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Jill Bonham Costa, John Cort Severns, Mark Robert Sivik
  • Patent number: 5830835
    Abstract: The present invention relates to dryer-activated fabric softening compositions comprising: (A) fabric softening compounds; (B) a non-allylic perfume alcohol ester; and (C) optionally, (1) a carboxylic acid salt of a tertiary amine and/or a tertiary amine ester; and (2) a nonionic softener; wherein, preferably, the Iodine Value of the total number of fatty acyl groups present in (A), (C)(1), and (C)(2) is from about 3 to about 60. These compositions exhibit good antistatic properties as well as improved delivery from a substrate.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: November 3, 1998
    Assignee: Procter & Gamble Company
    Inventors: John Cort Severns, Mark Robert Sivik, Frederick Anthony Hartman, Hugo Robert Germain Denutte, Jill Bonham Costa, Alex Haejoon Chung, Rafael Ortiz
  • Patent number: 5789374
    Abstract: Described are methyl-substituted 1(2-norbornyl) alkanols and acetate esters thereof defined according to the structures: ##STR1## (wherein Z represents hydrogen or acetyl). The compounds wherein Z is acetyl, the esters, are useful in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles, such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, fabric softener articles, hair sprays, shampoos, bath oils and perfumed polymers. Also described are process intermediates for making such compounds defined according to the structures: ##STR2## wherein M' represents MgX or Li and wherein X represents chloro, bromo or iodo.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: August 4, 1998
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Richard A. Weiss, Marie R. Hanna
  • Patent number: 5698514
    Abstract: Described are allyl esters of 2-norbornane acrylic acids and 2-norbornylidene propionic acids defined according to the generic structure: ##STR1## wherein the wavy line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein one of the dashed lines is carbon-carbon single bond and the other of the dashed lines is a carbon-carbon double bond; and wherein R represents methyl or hydrogen; as well as methods for augmenting or enhancing the aroma of consumable materials including perfumes, colognes and perfumed articles.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: December 16, 1997
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Wilhelmus Johannes Wiegers, Marie R. Hanna
  • Patent number: 5668102
    Abstract: The present invention relates to liquid and solid biodegradable fabric softener compositions combined with nonionic or anionic esters of a non-allylic alcohol perfumes. These compositions exhibit improved perfume longevity and reduced environmental impact.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: September 16, 1997
    Assignee: The Procter & Gamble Company
    Inventors: John Cort Severns, Mark Robert Sivik, Frederick Anthony Hartman, Hugo Robert Germain Denutte, Jill Bonham Costa, Alex Haejoon Chung, Rafael Ortiz
  • Patent number: 5559088
    Abstract: The present invention relates to dryer-activated fabric softening compositions comprising: (A) fabric softening compounds; (B) a non-allylic perfume alcohol ester; and (C) optionally, (1) a carboxylic acid salt of a tertiary amine and/or a tertiary amine ester; and (2) a nonionic softener; wherein, preferably, the Iodine Value of the total number of fatty acyl groups present in (A), (C)(1), and (C)(2) is from about 3 to about 60. These compositions exhibit good antistatic properties as well as improved delivery from a substrate.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: September 24, 1996
    Assignee: The Proctor & Gamble Company
    Inventors: John C. Severns, Mark R. Sivik, Frederick A. Hartman, Hugo R. G. Denutte, Jill B. Costa, Alex H. Chung
  • Patent number: 5531910
    Abstract: The present invention relates to liquid and solid biodegradable fabric softener compositions combined with nonionic or anionic esters of a non-allylic alcohol perfumes. These compositions exhibit improved perfume longevity and reduced enviromental impact.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: July 2, 1996
    Assignee: The Procter & Gamble Company
    Inventors: John C. Severns, Mark R. Sivik, Frederick A. Hartman, Hugo R. G. Denutte, Jill B. Costa, Alex H. Chung
  • Patent number: 5512543
    Abstract: The chiral isomers of 3,3-dimethyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol and, more particularly, the (-)-(1'R,2S,E)-3,3-dimethyl-5-(2',2',3'-trimethyl-3'-cyclopenten-1'-yl)-4- penten-2-ol and (+)-(1'S,2S,E)-3,3-dimethyl-5-(2',2',3'-trimethyl-3'-cyclopenten-1'-yl)-4- penten-2-ol, are useful as perfuming ingredients to impart sandalwood type odor notes to the perfuming compositions and perfumed articles into which they are incorporated.
    Type: Grant
    Filed: August 2, 1994
    Date of Patent: April 30, 1996
    Assignee: Firmenich S.A.
    Inventors: Christian Chapuis, Antoine Gautier, Pierre-Alain Blanc
  • Patent number: 5321007
    Abstract: Described are 2,6-dimethylbicyclo[3.3.1]non-6-ene-3-methanol and substituted derivatives thereof defined according to the generic structure: ##STR1## wherein each of the dashed lines represents a carbon-oxygen covalent bond or no bond; N is 0 or 1; R.sub.1 represents hydrogen, C.sub.1 -C.sub.2 lower alkyl, lower alkenyl, lower alkylenyl, C.sub.1 -C.sub.2 acyl, alkoxycarbonyl, magnesium halo or lithium; and R.sub.2 represents methyl or hydrogen as well as uses thereof (wherein R.sub.1 is not magnesium halo or lithium) for augmenting or enhancing the aroma of consumable materials selected from the group consisting of perfume compositions, perfumed articles, colognes, deodorizing articles, deodorizing compositions and malodor maskants.
    Type: Grant
    Filed: October 27, 1993
    Date of Patent: June 14, 1994
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Anubhav P. S. Narula, Matthew J. McGinnis, Leroy P. John, Franc T. Schiet, Charles E. J. Beck
  • Patent number: 5264615
    Abstract: Schiff bases having the formula ##STR1## wherein R.sup.1 signifies CH.sub.3, C.sub.2 H.sub.5R.sup.2 signifies H, CH.sub.3R.sup.3 signifies H, C.sub.1-4 -alkylR.sup.4, R.sup.5, R.sup.6,R.sup.7 signify H, CH.sub.3, C.sub.2 H.sub.5, CH.sub.2 CH.sub.2 CH.sub.3, CH(CH.sub.3).sub.2,X signifies methylene, ethylidene, propylidene, ethylene, propylene, 2,3-butylidene,total number of carbon atoms of R.sup.4, R.sup.5, R.sup.6, R.sup.7, .ltoreq.6 are novel odorants.
    Type: Grant
    Filed: December 9, 1991
    Date of Patent: November 23, 1993
    Assignee: Givaudan Corporation
    Inventor: Josianne Baudin
  • Patent number: 5206217
    Abstract: The present invention relates to novel indane compounds, such as, for example, 5-formyl-1,1,2,3,3,4,6-heptamethylindane, a compound of the formula ##STR1## and to compositions including the same, as well as to methods for their preparation. Compounds and compositions of the invention possess a fragrant musk-like aroma and have utility in the perfumery and/or other industries.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: April 27, 1993
    Assignee: Union Camp Corporation
    Inventor: Walter C. Frank
  • Patent number: 5039659
    Abstract: Described are 2,2,3-trimethylcyclopentenyl acetone derivatives defined according to one or a mixture of compounds having the structures: ##STR1## organoleptic uses thereof, processes for preparing same using as a starting material the compound having the structure: ##STR2## which is reacted to form the compound having the structure: ##STR3## which is further reacted to form the novel intermediate: ##STR4## which is then converted to the 2,2,3-trimethylcyclopentenyl acetone derivatives or our invention using the allylic alcohol having the structure: ##STR5## wherein R.sub.3, R.sub.4, and R.sub.5 are the same or different hydrogen or methyl; R.sub.6 represents hydrogen, methyl, ethyl, or propyl or isopropyl; x is 0, 1 or 2; R.sub.7 is methyl or ethyl; R.sub.7 ' and R.sub.7 " represent methyl or ethyl or R.sub.7 ', (CH.sub.2).sub.x and R.sub.7 " taken together represents C.sub.2 -C.sub.6 alkylene; M represents Li, Mg, X or MgX; and X represents chloro or bromo.
    Type: Grant
    Filed: August 7, 1990
    Date of Patent: August 13, 1991
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Anubhav P. S. Narula, John J. De Virgilio, Vincent F. Kuczinski, Anton V. Ouwerkerk, Charles E. J. Beck, Kathleen E. Boardwick, Marie R. Hanna
  • Patent number: 5002929
    Abstract: Certain trimethylbicylo-[4.3.0]-nonane derivatives, particularly those having a single acetyl substituent on the six membered ring, are novel compounds useful as perfumes to give highly persistent iris butter, methyl ionone, tobacco, and wood odor notes.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: March 26, 1991
    Assignee: Henkel Kommadnitgesellschaft auf Aktien
    Inventors: Klaus Bruns, Thomas Gerke, Ursula Schmitz
  • Patent number: 4959349
    Abstract: Indane derivatives useful as fragrance-imparting components are disclosed. The represented indane derivatives by the formula (I), ##STR1## wherein ring A is a benzene or cyclohexane ring and R.sup.1 is a hydrogen atom, an alkyl group having 1-4 carbon atoms, or an alkanoyl group having 1-6 carbon atoms, provided that when ring A is benzene, R.sup.1 is a group other than hydrogen atom.
    Type: Grant
    Filed: February 23, 1990
    Date of Patent: September 25, 1990
    Assignee: KAO Corporation
    Inventors: Hiroaki Ohnuma, Yoshiaki Fujikura, Manabu Fujita, Nao Toi
  • Patent number: 4933319
    Abstract: Described are substituted tetrahydroindanes defined according to the generic structure: ##STR1## wherein Z is a moiety selected from the group consisting of: ##STR2## wherein X represents chloro or bromo; wherein R.sub.1 represents:--OR.sub.3 or --O.sup..crclbar. M.sup..sym. ;wherein R.sub.3 represents hydrogen, methyl or ethyl; wherein M represents alkali metal, sodium potassium or lithium; wherein R.sub.2 represents hydrogen or the moiety: ##STR3## as well as uses of substituted tetrahydroindanes defined according to the structure: ##STR4## wherein Z' represents a moiety selected from the group consisting of: ##STR5## wherein R.sub.2 is hydrogen and wherein R.sub.1 is the moiety:--OR.sub.3 'wherein R.sub.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: June 12, 1990
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Robert P. Belko, Charles E. J. Beck
  • Patent number: 4929599
    Abstract: The bicyclic ester represented by the formula ##STR1## or 2-(2,3,4,5,6,7-hexahydro-1,1,4,4-tetramethyl-2(1H)-indenyl)-ethyl acetate, develops odor characters of the woody, slightly amber and musky type, and can therefore be advantageously used for the preparation of perfuming compositions or perfumes, and for perfuming products such as soaps, cosmetic preparations, detergents, fabric softeners or air deodorizers.
    Type: Grant
    Filed: April 12, 1989
    Date of Patent: May 29, 1990
    Assignee: Firmenich SA
    Inventors: Wolfgang K. Giersch, Karl-Heinrich Schulte-Elte
  • Patent number: 4762819
    Abstract: The invention relates to 2,6-exo-configured tricyclo-5.2.1.0.sup.2,6 decane derivatives that correspond to general formula A wherein ##STR1## R.sup.a, R.sup.b, R.sup.c, R.sup.d are hydrogen or R.sup.d is a methyl group and R.sup.a, R.sup.b, R.sup.c are hydrogen or methyl groups, one of the substituents being a methyl group and both the others being hydrogen,the broken line represents a C-C double bond optionally at (-3) or (-4),the wavy line represents geometric isomers,R.sup.1 and R.sup.2 are hydrogen, or lower alkyl groups with a total of 1-6 carbon atoms, andX represents a carbonyl or hydroxyl function, as well as a process for their synthesis and their use as scents.
    Type: Grant
    Filed: May 5, 1987
    Date of Patent: August 9, 1988
    Assignee: Dragoco Gerberding & Co. GmbH
    Inventor: Ernst-Joachim Brunke
  • Patent number: 4731356
    Abstract: 2,3-Epoxy-1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1-butanone, an epoxy ketone of formula ##STR1## possess useful fragrance characters and, consequently, it can be used advantageously in the manufacture of perfume, perfume bases and perfumed products. It develops a flowery and fruity odor.
    Type: Grant
    Filed: June 4, 1987
    Date of Patent: March 15, 1988
    Assignee: Firmenich SA
    Inventors: Karl-Heinrich Schulte-Elte, Dietrich Kastner
  • Patent number: 4728747
    Abstract: Novel disubstituted bicyclo[2.2.1]heptanes of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.3 -alkyl, R.sup.2 is C.sub.1 -C.sub.8 -alkyl or-alkenyl, R.sup.3 and R.sup.4 together are .dbd.O, .dbd.CH--CN, .dbd.CH--CO--OCH.sub.3 or .dbd.CH--CO--OC.sub.2 H.sup.5, or R.sup.3 is hydrogen, --CH.sub.3, --CH.dbd.CH.sub.2 or --C.tbd.CH when R.sup.4 is --OH or --O--CO--CH.sub.3, or R.sup.3 is H when R.sup.4 is --CH.sub.2 --CO--OCH.sub.3, --CH.sub.2 --CO--OC.sub.2 H.sub.5 or --CH.sub.2 --C.tbd.N and one or both of the dashed lines may be a further bond, are obtained by subjecting cyclopentadiene to a Diels-Alder reaction with an unsaturated ketone, this reaction being catalyzed by a Lewis acid, and then subjecting the compound of the formula Ia ##STR2## initially formed to a reduction, a Grignard reaction or a reaction with diethylphosphonoacetonitrile or ethyl phosphonoacetate and NaH.They can be used as scents and/or aromas or as intermediates for scents.
    Type: Grant
    Filed: December 30, 1985
    Date of Patent: March 1, 1988
    Assignee: Basf Aktiengesellschaft
    Inventors: Werner Hoffmann, Lothar Janitschke