Abstract: A method is presented for storage and on-demand release of nanoparticles. Nanoparticles produced by this method can be dried and stored for an extended period of time and subsequently released on-demand in a solvent of choice to form stable suspensions without the need for additional surfactants or stabilizers and without any loss in functionality or material properties. This method can be used to store various categories of nanomaterials including metals, metal oxides, metal chalcogenides, magnetic, polymeric and semiconductor nanoparticles.

Abstract: Compositions containing 2,3,3,3-tetrafluoropropene and to the uses thereof as heat transfer fluid, expansion agents, solvents and aerosol. Compositions essentially containing between 10 and 90 wt. % of 2,3,3,3-tetrafluoropropene, between 5 and 80 wt. % of HFC-134a and between 5 and 10 wt. % of HFC-32. Compositions essentially containing from 10 to 45% by weight of 2,3,3,3-tetrafluoropropene, from 50 to 80% by weight of HFC-134a and from 5 to 10% by weight of HFC-32.

Abstract: Azeotrope-like compositions are disclosed. The azeotrope-like compositions are mixtures of E-1-chloro-2,3,3,3-tetrafluoropropene with E-1,1,1,4,4,4-hexafluoro-2-butene or E-1,1,1,4,4,5,5,5-octafluoro-2-pentene. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotrope-like compositions. Also disclosed is a process of using such azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotrope-like compositions. Also disclosed is a process of using such azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotrope-like compositions. Also disclosed is a process of using such azeotrope-like compositions as dielectrics.

Abstract: A method for treating an inorganic slurry to preserve the slurry against bacterial contamination, including (I) providing a slurry in a substantially homogeneous phase, and then (II) adding to the slurry an effective amount of a composition containing: (a) a tetrakis(hydroxyorgano)phosphonium salt selected from the group consisting of tetrakis(hydroxymethyl)phosphonium sulphate, tetrakis(hydroxymethyl)phosphonium chloride, tetrakis(hydroxymethyl)phosphonium phosphate, tetrakis(hydroxymethyl)phosphonium nitrate and tetrakis(hydroxymethyl)phosphonium oxalate; and (b) a dispersant selected from the group consisting of (i) a phosphonated compound containing at least one tertiary nitrogen atom and (ii) a homopolymer of an unsaturated acid; and (III) preserving the slurry against bacterial contamination, while avoiding instantaneous heterogeneous thickening of the slurry due to the tetrakis(hydroxyorgano)phosphonium salt.

Abstract: A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust. Carbon aerogels can be coated with sol-gel silica and the silica can be converted to silicon carbide, improving the thermal stability of the carbon aerogel.

Abstract: An aerosol for disinsectization comprising a mixture comprising a disinfestant component, a solvent, and a propellant, and a pressure-resistant container provided with an actuator, wherein the mixture is contained in the pressure-resistant container, and wherein the solvent is contained in the mixture in an amount of from 0 to 10% by volume, and the actuator has an orifice diameter of from 0.7 to 2 mm; and an aerosol for disinsectization comprising a mixture comprising a disinfestant component, a solvent, and a propellant, and a pressure-resistant container provided with an actuator, wherein the mixture is contained in the pressure-resistant container, and wherein the solvent is contained in the mixture in an amount of from 0 to 10% by volume, and the actuator has a long nozzle having an orifice diameter of from 0.4 to 2 mm.

Abstract: Some embodiments include methods of forming charge-trapping zones. The methods may include forming nanoparticles, transferring the nanoparticles to a liquid to form a dispersion, forming an aerosol from the dispersion, and then directing the aerosol onto a substrate to form charge-trapping centers comprising the nanoparticles. The charge-trapping zones may be incorporated into flash memory cells.

Abstract: Pressurizing or propellant compositions and products made using the compositions are provided herein. The propellant compositions include ethane as a propellant. The ethane may be the only propellant in the composition or may be mixed with other propellants. The ethane may be the only hydrocarbon or the only saturated hydrocarbon propellant used in the compositions. Sprayable products including the propellants described herein are also provided. Finally methods of removing a contaminate from an article using the sprayable products described herein are also provided.

Abstract: Disclosed are compositions comprising HFC-245eb and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-245fa, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-143a, HFC-134, HFC-134a, FC-1216, HFO-1234yf, HFC-254eb, HFO-1243zf, and HFC-254fb. Compositions comprising HFC-245eb are useful in processes to make HFO-1234yf. Also disclosed are compositions comprising HFO-1234yf and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-254eb, HFC-254fb, HFO-1243zf, HFCHFC-245eb, HFC-245fa, HFC-245cb, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-134, HFC-134a, HFO-1132a and FC-1216. Compositions comprising HFO-1234yf are useful as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

Abstract: A process for the salt-free coagulation of polymer dispersions in a rotor/stator assembly is disclosed. The rotor/stator assembly includes a casing, a rotor shaft rotatably mounted within the casing, a rotor having a conical surface affixed to the rotor shaft, and a stator affixed to the casing and concentrically associated with the rotor. The conical surface faces a surface of the stator to form an adjustable shear gap, which is surrounded by an annular space. A polymer dispersion is fed into the assembly and conveyed through the shear gap. During this conveyance, the polymer dispersion is precipitated at a predetermined shear rate and a predetermined shear deformation. The polymer dispersion is discharged from the assembly through an outlet neck, and the assembly is flushed with water using one or more ports formed in at least one of a pipeline coupled to the axial feed neck, the stator, and the casing.

Abstract: The present disclosure relates to compositions comprising 2,3,3,3-tetrafluoropropene that may be useful as heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, extinguishing agents, and fire suppression agents in liquid or gaseous form. Additionally, the present disclosure relates to compositions comprising 1,1,2,3-tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane, which may be useful in processes to produce 2,3,3,3-tetrafluoropropene.

Abstract: Various uses of monochlorotrifluoropropenes, in combination with one or more other components, including other fluoroalkenes, hydrocarbons; hydrofluorocarbons (HFCs), ethers, alcohols, aldehydes, ketones, methyl formate, formic acid, water, trans-1,2-dichloroethylene, carbon dioxide and combinations of any two or more of these, in a variety of applications, including as blowing agents, are disclosed.

Abstract: A photocatalytic coating composition comprising photocatalytic titanium oxide, silver, copper and a quaternary ammonium hydroxide. The photocatalytic coating composition may include a photocatalytic titanium oxide sol dispersed in a binder. Furthermore, a photocatalytic member includes a substrate having a surface coated with the photocatalytic coating composition. The photocatalyst coating composition can contain highly antibacterial silver by skillfully utilizing copper and a quaternary ammonium hydroxide, and accordingly can show an antibacterial effect not only in a dark place simply due to silver, but also a higher antibacterial effect in a conventional application of employing ultraviolet sterilization by concomitantly using the photocatalyst titanium oxide sol according to the present invention and an ultraviolet sterilizer.

Abstract: The present invention relates to compositions containing hydrofluoroolefins and to the uses thereof as heat transfer fluids, blowing agents, solvents and aerosols. More particularly, the invention relates to compositions having: 10 to 55% by weight, of 2,3,3,3-tetrafluoropropene, 5 to 50% by weight of HFC-152a and 30 to 55% by weight of HFC-32.

Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of Z-1,1,1,4,4,4-hexafluoro-2-butene with ethanol, 2-chloro-3,3,3-trifluoropropene, methanol, E-1,1,1,4,4,5,5,5-octafluoro-2-pentene, 2-bromo-3,3,3-trifluoropropene, methyl acetate, acetone, chloroform, n-hexane or 1-chloro-3,3,3-trifluoropropene. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media.

Abstract: The present invention relates to compositions containing hydrofluoroolefins and to the uses thereof as heat transfer fluids, blowing agents, solvents and aerosols. More particularly, the invention relates to compositions having from 5 to 65% by weight, preferably from 5 to 15% by weight, of 2,3,3,3-tetrafluoropropene, 5 to 70% by weight, preferably 40 to 60% by weight, of HFC-134a and 25 to 42% by weight of HFC-32.

Abstract: Provided are azeotrope or azeotrope-like compositions comprised of E-1-chloro-3,3,3-trifluoropropene (HCFO-E-1233zd) and isopropanol, and uses thereof.

Abstract: A photocatalytic titanium oxide sol presents antibacterial properties in a dark place, and, in particular, relates to a photocatalytic titanium oxide sol which is stable and causes no discoloration by light even though containing silver, and relates to a coating composition and a member using the same. The photocatalytic titanium oxide sol includes silver, copper and a quaternary ammonium hydroxide, may be dispersed in a binder, and may be coated on the surface of a substrate.

Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises 2,3,3,3-tetrafluoropropene (HFC-1234yf) and at least one hydrocarbon. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, and aerosol propellants.

Abstract: A set of nanoparticles is disclosed. Each nanoparticle of the set of nanoparticles is comprised of a set of Group IV atoms arranged in a substantially spherical configuration. Each nanoparticle of the set of nanoparticles further having a sphericity of between about 1.0 and about 2.0; a diameter of between about 4 nm and about 100 nm; and a sintering temperature less than a melting temperature of the set of Group IV atoms.

Abstract: A cannister-based, high solids, low and non-VOC aerosol adhesive and canister based system. The aerosol adhesive typically includes a high solids polymeric base, a hexane or cyclohexane and acetone solvent mixture and a compressed gas dissolved within the solvent. The compressed gas typically includes carbon dioxide, nitrogen, nitrous oxide and air. The aerosol adhesive is adapted to be filled into a cannister including a hose connected to the canister and a spray gun connected to the hose. The system typically includes high solids with a high viscosity. Thus the canister typically maintains high pressures up to 350 psi, but typically at 260 psi while maintaining 325 psi at 130° F., to deliver effective spray patterns.

Abstract: An improved process for the production of ultralow density, high specific surface area gel products is provided which comprises providing, in an enclosed chamber, a mixture made up of small particles of material suspended in gas; the particles are then caused to aggregate in the chamber to form ramified fractal aggregate gels. The particles should have a radius (a) of up to about 50 nm and the aerosol should have a volume fraction (fv) of at least 10?4. In preferred practice, the mixture is created by a spark-induced explosion of a precursor material (e.g., a hydrocarbon) and oxygen within the chamber. New compositions of matter are disclosed having densities below 3.0 mg/cc.

Abstract: The invention provides a method of producing a personal care product comprising combining a fragrance, a propellant and porous carrier particles, to produce a composition substantially free of pre-encapsulated fragrance particles, and containing the composition in a pressurized container. Also provided is a personal care product comprising a pressurized container and a composition contained therein, which includes a fragrance, a propellant and porous carrier particles, wherein the composition is substantially free pre-encapsulated fragrance particles. When the composition is released from the container, the propellant evaporates rapidly to produce a matrix, which incorporates the fragrance into the pores of the carrier, to produce a sustained-release fragrance delivery system.

Abstract: Disclosed are the use of fluorine substituted olefins, including tetra- and penta-fluoropropenes, in a variety of applications, including connection with blowing agents, foams, foamable compositions, foaming methods, heat transfer compositions and methods, propellants, and solvating methods.

Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

Abstract: Provided are azeotrope-like compositions comprising tetrafluoropropene and hydrofluorocarbons and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.

Abstract: A curable silicone composition is provided that includes a silanol functional silicone fluid. A crosslinker reactive with the silanol functional silicone fluid is combined with the silanol fluid to yield a capped reactive silanol fluid. The composition is provided with a propellant in an aerosol container under pressure so as to expel the capped reactive silanol fluid along with a diluent such as a nonvolatile unreactive silicone, an organic plasticizer, a volatile organic solvent, or a combination thereof. A film produced from this composition provides a plastic or rubber substrate with a high gloss finish with desirable wear properties. The inclusion of the optional diluent and the optional propellant facilitates aerosol application of the curable silicone composition as a thin film coating.

Abstract: A process for preparing 5,5?-bi-1H-tetrazolediammonium salts (BHT.2NH3) maintaining a high yield through oxaldiimidic acid dihydrazide (OAH) from the starting materials which are cheaply available and are easy to handle. The 5,5?-bi-1H-tetrazolediammonium salts (BHT.2NH3) are prepared by dissolving the oxaldiimidic acid dihydrazide (OAH) obtained by the reaction of hydrated hydrazide with dicyan in an aqueous solution of a weakly acidic compound such as acetic acid, dropwisely adding an aqueous solution of sodium nitrite thereto to form an azide thereof and to effect the cyclization reaction by heating, adding an aqueous solution of sodium hydroxide to the reaction product to convert it into a 5,5?-bi-1H-tetrazoledisodium salt (BHT.2Na), reacting it with an aqueous solution of ammonium chloride, and recovering the formed ammonium salt as sparingly soluble crystals.

Abstract: A self-shining aerosol-type shoe polish composition consisting essentially of 0.5 to 25% by volume of a silicone compound, optionally 3 to 25% by volume of a drying retardant and/or 0.1 to 1% by volume of an anti-static agent component, and the remainder of liquefied gas as a solvent as well as a propellant gas, exhibits excellent drying properties and self-shining effect when sprayed on the surface of shoes.

Abstract: The present invention provides a coating composition for producing difficult-to-wet surfaces, comprising i) at least one finely divided powder whose particles have a hydrophobic surface and a porous structure characterized by a BET surface area (determined in accordance with DIN 66131) of at least 1 m2/g, and ii) at least one film-forming binder characterized by a surface tension <50 mN/m, the weight ratio of powder to binder being at least 1:4. It also provides a process for producing difficult-to-wet surfaces, and provides for the use of the coating compositions for producing surfaces having a self-cleaning effect and for reducing the flow resistance for liquids in pipes.

Abstract: For the preparation of pulverulent particle-reduced formulations with the aid of compressed gases, the solid compound to be formulated, a poorly soluble and usually bioactive active compound, is homogeneously ground together with 10-99% by weight (based on the formulation) of a carrier material which is essentially soluble in the compressed gas mixture, in the presence of compressed gas or mixtures thereof in a stirred autoclave having a mechanical grinding device at process temperatures between 10 and 200° C. and at process pressures between 5 and 500 bar, and in a second process stage the compressed gas mixture, usually dimethyl ether, pure propane and/or carbon dioxide, is expanded by lowering the pressure and separated off from the homogenate, which can also be present as a melt.

Abstract: The invention relates to a new propellant composition for use with aerosols such as may be used in medical devices such as a metered dose inhaler (or MDI) or a nasal spray device. The propellant features helium as its primary ingredient, preferably at least about 70% and most preferably at or around 100% by weight of the propellant composition, and this propellant can be used in a variety of applications since it is both inert and environmentally safe. The propellant of the invention can thus be utilized advantageously as a safe and environmentally friendly alternative to many current propellants including those based on hydrofluorocarbons (e.g., HFA), fluorocarbons (e.g., CFC), or hydrocarbons such as butane and propane.

Abstract: An electrically neutral composition in the form of a water-in-oil or an oil-in-water emulsion is imparted with a unipolar electrostatic charge on spraying from an aerosol spray device by incorporating into the composition a non-ionic surfactant and at least one polar or ionic or aromatic or linearly conjugated compound. The amount of the polar or ionic or aromatic or linearly conjugated compound included in the composition is about 0.01 to about 80% w/w based on the non-ionic surfactant, but is such that the theoretical conductivity of the emulsion is less than the bulk conductivity of the emulsion.

Abstract: In general, a cannister-based low and non-VOC aerosol adhesive is disclosed. The aerosol adhesive typically includes a high solids polymeric base, a hexane acetone solvent mixture and a compressed gas dissolved within the solvent. The compressed gas typically includes carbon dioxide, nitrogen, nitrous oxide and air. The aerosol adhesive is adapted to be filled into a cannister including a hose connected to the canister and a spray gun connected to the hose.

Abstract: The invention relates to an internal liquid composition contained in a releasing container such as an aerosol container, and a releasing container product containing such composition. The following three types are proposed as the composition. The first type is a blending of inorganic porous fine particles carrying a chemical, disperse solution, acrylic acid polymer, and alkali. The second type is a blending of inorganic porous fine particles carrying a chemical, disperse solution, and synthetic resin fine particles. The third type is a blending of inorganic porous fine particles carrying a chemical, disperse solution, acrylic acid polymer, alkali, and synthetic resin fine particles. As inorganic porous fine particles, for example, silicic anhydride porous fine particles may be used.

Abstract: A method is disclosed for the preparation of optically pure isomers of formoterol by the reaction of an optically pure 4-benzyloxy-3-formamidostyrene oxide with an optically pure 4-methoxy-.alpha.-methyl-N-(phenylmethyl)benzeneethanamine followed by debenzylation. Useful intermediates in the process are also disclosed, as are the novel L-tartrate salt of R,R-formoterol and pharmaceutical compositions thereof.