The Compound Contains Silicon Patents (Class 516/144)
  • Patent number: 8809404
    Abstract: The present invention is related to the preparation and use of moderately cross-linked (chin-extended), reverse (or “inverted”) surfactants, wherein the reverse surfactants comprise a polyether backbone with oligomeric or polymeric silicon-containing substitutions along the backbone. The present invention further describes crosslinked versions of the inverted surfactants, reaction products of alkenyl (allyl, vinyl, methallyl) functional copolymers (polyethers), silicone hydrides and cross-linking agents, which may be optionally reacted with water to react the remaining alkoxy groups. The crosslinking agent contains either SiH or Si-alkoxy groups or both. The compounds of the present invention exhibit only moderate cross-linking in order to be soluble or dispersible in appropriate solvents.
    Type: Grant
    Filed: January 30, 2013
    Date of Patent: August 19, 2014
    Assignee: Momentive Performance Materials Inc.
    Inventors: Kalman Koczo, Benjamin Falk, Mark Leatherman, Antonio Palumbo
  • Patent number: 8796433
    Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.
    Type: Grant
    Filed: September 5, 2012
    Date of Patent: August 5, 2014
    Assignees: Kroff Chemical Company, Dow Agrosciences LLC
    Inventors: Paul Rey, David M. Sunderlik, Steven P. Ceplecha
  • Publication number: 20130299390
    Abstract: The present invention provides for a demulsifying composition comprising the reaction product of an oxirane or oxetane compound (I) comprising at least two oxirane or oxetane groups; a compound (II) comprising silicon and one or more amino groups; and optionally a polyamine (III); and a secondary amine (IV).
    Type: Application
    Filed: July 12, 2013
    Publication date: November 14, 2013
    Inventors: Kalman Koczo, Benjamin Falk, Antonio Palumbo, Monjit Phukan
  • Patent number: 8507565
    Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a polyorganosiloxane demulsifier into an emulsion comprising an oil phase and an aqueous phase. The invention also relates to compositions containing polyorganosiloxane demulsifier and the water and oil phases of an emulsion.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: August 13, 2013
    Assignee: Momentive Performance Material Inc.
    Inventors: Anubhav Saxena, Monjit Phukan, Senthilkumar U., Ian Procter, Sigfredo Gonzalez, Kalman Koczo, Sabine Azouani, Vikram Kumar
  • Publication number: 20130197108
    Abstract: The present invention is related to the preparation and use of moderately cross-linked (chin-extended), reverse (or “inverted”) surfactants, wherein the reverse surfactants comprise a polyether backbone with oligomeric or polymeric silicon-containing substitutions along the backbone. The present invention further describes crosslinked versions of the inverted surfactants, reaction products of alkenyl (allyl, vinyl, methallyl) functional copolymers (polyethers), silicone hydrides and cross-linking agents, which may be optionally reacted with water to react the remaining alkoxy groups. The crosslinking agent contains either SiH or Si-alkoxy groups or both. The compounds of the present invention exhibit only moderate cross-linking in order to be soluble or dispersible in appropriate solvents.
    Type: Application
    Filed: January 30, 2013
    Publication date: August 1, 2013
    Applicant: Momentive Performance Materials Inc.
    Inventor: Momentive Performance Materials Inc.
  • Patent number: 8268975
    Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: September 18, 2012
    Assignees: DOW Agrosciences LLC, Kroff Chemical Company
    Inventors: Paul Rey, Steve P. Ceplecha, David M. Sunderlik
  • Patent number: 8198337
    Abstract: The present invention provides for a demulsifying composition comprising a blend of a) an emulsion; and b) a demulsifying-effective amount of a non-crosslinked silicon polyether. The present invention also provides for a method for separating emulsions using the demulsifying composition discussed.
    Type: Grant
    Filed: January 27, 2010
    Date of Patent: June 12, 2012
    Assignee: Momentive Performance Materials Inc.
    Inventors: Benjamin Falk, Kalman Koczo, Monjit Phukan, Antonio Palumbo, Anubhav Saxena
  • Patent number: 8129435
    Abstract: The present invention relates to a perfluoropolyether-modified polysiloxane represented by general formula (1): wherein Rf is a linear or branched perfluoroalkyl group having 1 to 10 carbon atoms; X is a fluorine atom or a trifluoromethyl group; Q is a divalent organic group having 1 to 12 carbon atoms; R1, R2, and R3 are, independently of each other, an alkyl group having 1 to 10 carbon atoms or an aryl group; a, b, c, and d are, independently of each other, an integer of from 0 to 200, provided that a total of a, b, c and d is 1 or larger; e is an integer of 0 or 1; and z is an integer of from 5 to 100; a method for preparing the same; and a defoaming agent comprising the same.
    Type: Grant
    Filed: June 17, 2010
    Date of Patent: March 6, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hiromasa Yamaguchi, Noriyuki Koike, Kazuyuki Takewaki
  • Publication number: 20120024759
    Abstract: The present invention provides for a demulsifying composition comprising a blend of a) an emulsion; and b) a demulsifying-effective amount of a silicon containing co-polymer. The present invention also provides for a method for separating emulsions using the demulsifying composition discussed.
    Type: Application
    Filed: August 2, 2010
    Publication date: February 2, 2012
    Applicant: Momentive Performance Materials Inc.
    Inventors: Kalman KOCZO, Benjamin FALK, Antonio PALUMBO
  • Publication number: 20110245354
    Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a polyorganosiloxane demulsifier into an emulsion comprising an oil phase and an aqueous phase. The invention also relates to compositions containing polyorganosiloxane demulsifier and the water and oil phases of an emulsion.
    Type: Application
    Filed: June 14, 2011
    Publication date: October 6, 2011
    Applicant: Momentive Performance Materials Inc.
    Inventors: Anubhav Saxena, Monjit Phukan, Senthilkumar U, Ian Procter, Sigfredo Gonzalez, Kalman Koczo, Sabine Azouani, Vikram Kumar
  • Patent number: 8030363
    Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a polyorganosiloxane demulsifier into an emulsion comprising an oil phase and an aqueous phase. The invention also relates to compositions containing polyorganosiloxane demulsifier and the water and oil phases of an emulsion.
    Type: Grant
    Filed: January 25, 2008
    Date of Patent: October 4, 2011
    Assignee: Momentive Performance Materials Inc.
    Inventors: Anubhav Saxena, Monjit Phukan, Umapathy Senthilkumar, Ian Procter, Sigfredo Gonzalez, Kalman Koczo, Sabine Azouani, Vikram Kumar
  • Publication number: 20110184075
    Abstract: The present invention provides for a demulsifying composition comprising a blend of a) an emulsion; and b) a demulsifying-effective amount of a non-crosslinked silicon polyether. The present invention also provides for a method for separating emulsions using the demulsifying composition discussed.
    Type: Application
    Filed: January 27, 2010
    Publication date: July 28, 2011
    Applicant: Momentive Performance Materials Inc.
    Inventors: Benjamin Falk, Kalman Koczo, Monjit Phukan, Antonio Palumbo, Anubhav Saxena
  • Patent number: 7981979
    Abstract: A composition comprising one or more siloxane cross-linked demulsifiers wherein said siloxane cross-linked demulsifiers are prepared by reacting one or more alkylphenol-formaldehyde resin alkoxylates, one or more polyalkylene glycols, or a mixture thereof, with up to about 1.0 molar equivalents of one or more silicon-based cross-linkers of formula R1R2R3R4Si wherein R1, R2, R3, R5, R6 and R7 are independently selected from H, Cl, C1-C4 alkyl and C1-C4 alkoxy; R4. is selected from H, Cl, C1-C4 alkyl, C1-C4 alkoxy and a group of formula L1SiR5R6R7; L1 is absent or is selected from —O—, arylene and C1-C12 alkylene, optionally interrupted by one or more —O— or —N(R8)—; and R8 is H or C1-C4 alkyl and a method of using the demulsifier composition to resolve water-in-oil emulsions.
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: July 19, 2011
    Assignee: Nalco Company
    Inventor: Austen K. Flatt
  • Patent number: 7745501
    Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a silicone demulsifier into an emulsion comprising an oil phase and an aqueous phase, the silicone demulsifier having a molecular structure comprising a polysiloxane backbone of at least two siloxane units covalently bound to (i) one or more alkylene oxide groups comprising one or more alkylene oxide units independently having one to five carbon atoms, and (ii) one or more oxirane-containing and/or oxetane-containing groups, wherein said oxirane or oxetane is optionally ring-opened by reaction with a chemical or group capable of ring-opening an oxirane or oxetane ring, respectively, and wherein a solid filler is substantially excluded from the silicone demulsifier and emulsion. The invention also relates to compositions containing the above-described demulsifier and the water and oil phases of an emulsion.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: June 29, 2010
    Assignee: Momentive Performance Materials Inc.
    Inventors: Kalman Koczo, Sabine Isabelle Azouani, Benjamin Falk
  • Patent number: 7652072
    Abstract: Compositions comprising an asymmetric disiloxane surfactant composition comprising a silicone composition comprising a silicone having the formula: MM? where M or M? comprises an alkylpolyalkyleneoxide bearing substituent selected from the group consisting of: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 and R12SiR5R6(R13(C2H4O)a(C3H6O)b(C4H8O)cR14) that exhibit resistance to hydrolysis over a wide pH range.
    Type: Grant
    Filed: June 30, 2006
    Date of Patent: January 26, 2010
    Assignee: Momentive Performance Materials Inc.
    Inventors: Mark D. Leatherman, George A. Policello, Suresh K. Rajaraman
  • Patent number: 7491427
    Abstract: [PROBLEMS] To provide a polyimidesiloxane solution composition that is excellent in defoaming ability and that can maintain the wettability of an outer lead bonded portion on a wiring board at a high level, even when it is applied on the surface of the wiring board and then cured, to form an insulating cured film. [MEANS FOR SOLVING PROBLEMS] A polyimidesiloxane solution composition which comprises an organic solvent, polyimidesiloxane soluble in the organic solvent, a curable components such as an epoxy compound and a polyvalent isocyanate compound, and a silicone defoamer, wherein the silicone defoaming agent comprises dimethylpolysiloxane, a polysiloxane compound having a hydrophilic group in a side chain or a terminal moiety, and a micro-powder silica.
    Type: Grant
    Filed: February 21, 2005
    Date of Patent: February 17, 2009
    Assignee: UBE Industries, Ltd.
    Inventors: Koji Hayashi, Yoshiki Tanaka, Katsutoshi Hirashima, Seiichirou Takabayashi
  • Publication number: 20080076840
    Abstract: A composition comprising one or more siloxane cross-linked demulsifiers wherein said siloxane cross-linked demulsifiers are prepared by reacting one or more alkylphenol-formaldehyde resin alkoxylates, one or more polyalkylene glycols, or a mixture thereof, with up to about 1.0 molar equivalents of one or more cross-linkers of formula R1R2R3R4Si wherein R1, R2, R3 and R4 are independently selected from H, Cl, C1-C4 alkyl and C1-C4 alkoxy and a method of using the demulsifier composition to resolve water-in-oil emulsions.
    Type: Application
    Filed: September 22, 2006
    Publication date: March 27, 2008
    Inventor: Austen K. Flatt
  • Publication number: 20070299143
    Abstract: The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a silicone demulsifier into an emulsion comprising an oil phase and an aqueous phase, the silicone demulsifier having a molecular structure comprising a polysiloxane backbone of at least two siloxane units covalently bound to (i) one or more alkylene oxide groups comprising one or more alkylene oxide units independently having one to five carbon atoms, and (ii) one or more oxirane-containing and/or oxetane-containing groups, wherein said oxirane or oxetane is optionally ring-opened by reaction with a chemical or group capable of ring-opening an oxirane or oxetane ring, respectively, and wherein a solid filler is substantially excluded from the silicone demulsifier and emulsion. The invention also relates to compositions containing the above-described demulsifier and the water and oil phases of an emulsion.
    Type: Application
    Filed: June 22, 2006
    Publication date: December 27, 2007
    Inventors: Kalman Koczo, Sabine Isabelle Azouani, Benjamin Falk
  • Publication number: 20040101859
    Abstract: Antifoam agents improve detection of polynucleotide amplification reactions and improve manipulation of fluids in microfluidic devices.
    Type: Application
    Filed: November 25, 2002
    Publication date: May 27, 2004
    Applicant: Cepheid
    Inventors: Byung Sook Moon, Jose Johnny Valdez
  • Patent number: 6727388
    Abstract: The present invention is a demulsifying and corrosion-inhibiting compound formed from the salt of an amphiphilic amine and an amphiphilic acid. In a preferred embodiment of the invention, the demulsifier may be a salt of an alkyl amine and an alkyl aryl sulfonic acid. Even more preferably, the demulsifier may be a salt of a methyl, di-cocoyl amine and an alkyl aryl sulfonic acid. According to another embodiment of the invention, an organic system may be demulsified by mixing the salt of an alkyl amine and an alkyl sulfonic acid with the system to be demulsified.
    Type: Grant
    Filed: February 4, 2003
    Date of Patent: April 27, 2004
    Assignee: Pilot Chemical Holdings, Inc.
    Inventor: Robert Golden
  • Publication number: 20030130534
    Abstract: The present invention is a demulsifying and corrosion-inhibiting compound formed from the salt of an amphiphilic amine and an amphiphilic acid. In a preferred embodiment of the invention, the demulsifier may be a salt of an alkyl amine and an alkyl aryl sulfonic acid. Even more preferably, the demulsifier may be a salt of a methyl, di-cocoyl amine and an alkyl aryl sulfonic acid. According to another embodiment of the invention, an organic system may be demulsified by mixing the salt of an alkyl amine and an alkyl sulfonic acid with the system to be demulsified.
    Type: Application
    Filed: February 4, 2003
    Publication date: July 10, 2003
    Applicant: Pilot Chemical Holdings, Inc.
    Inventor: Robert Golden
  • Patent number: 6187107
    Abstract: The water-repellent mixture comprises i) a halogenated dispersant chosen from the group constituted by a totally halogenated molecule and a partially halogenated molecule with at least one atom of hydrogen and ii) a copolymeric silicone having a hydrophilic function, for drying solids by the movement of water, the copolymeric silicone preferably being a polyalkylineoxide modified polydimethylsiloxane of formula: with 0≦m≦100, 4≦n≦50 and R being a radical chosen from the group of radicals constituted by a hydrogen atom, an alcohol group, an amine group and a polyalkyl group containing 1 to 5 carbon atoms.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: February 13, 2001
    Assignee: Promosol S.A.
    Inventors: Patrick Duchi, Joseph Micozzi