The Agent Contains Organic Compound Containing Nitrogen, Except If Present Solely As Nh4+ Patents (Class 516/27)
  • Patent number: 11912934
    Abstract: The instant invention friction reducer formulation comprising friction reducer polymers such as PAM within the dispersed phase of an inverse emulsion containing a composition C which comprises a mixture of: —at least an alkanolamide emulsifier; and —a block copolymer comprising: —a hydrophilic block A comprising units deriving from a mono-alpha-ethylenically-unsaturated monomers; and —a hydrophobic block B.
    Type: Grant
    Filed: March 11, 2020
    Date of Patent: February 27, 2024
    Assignee: RHODIA OPERATIONS
    Inventors: Helène Martin, Patrick Moreau, Arnaud Cadix
  • Patent number: 11034878
    Abstract: The invention relates to an emulsion containing or consisting of (A) 40.00 to 97.98 wt. % of at least one hydrocarbon, (B) 2.00 to 59.98 wt. % of water or an aqueous solution of a salt which does not fall under the following definition according to (C) and (C) 0.02 to 8.00 wt. % of a salt of an amino amide of a fatty acid, containing at least one primary, secondary or tertiary amino group, and an acid component of general formula (I) in which R1 is a linear or branched, saturated or mono-unsaturated or poly-unsaturated hydrocarbon radical with 1 to 40 C atoms, R2 is an alkylene radical or arylalkylene radical with 2 to 20 C atoms and X is a radical which contains at least one acid group, m=0 or 1, n=1 to 30, wherein the weight proportions of components (A), (B) and (C) relate to the sum of the masses of these components and this is 100 wt. %.
    Type: Grant
    Filed: June 2, 2017
    Date of Patent: June 15, 2021
    Assignee: BYK-Chemie GmbH
    Inventors: René Nagelsdiek, Sylvia Bühne, Jan von Haaren, Agnetha Klein, Christian Sauerländer
  • Patent number: 10711179
    Abstract: During “fracking” operations, proppants are used to keep open the fissures that are created, and stimulation fluids are often injected into the subterranean hydrocarbon-bearing geological formations to assist in capturing released hydrocarbons. However, because fissure surfaces formed in subterranean hydrocarbon-bearing geological formations from fracking tend to be hydrophobic, both introduced stimulation fluids and the hydrocarbons from the subterranean hydrocarbon-bearing geological formations tend to adhere to the fissure surfaces. The addition of a gemini surfactant appears to reduce the hydrophobic nature of the geological structure's fissure surfaces, thereby wetting surfaces of indigenous rock and/or introduced proppant surfaces. The addition of the gemini surfactant results in an increase of the fluid flow through the subterranean hydrocarbon-bearing geological formations, thereby enhancing of recovery of hydrocarbons and introduced stimulation fluids.
    Type: Grant
    Filed: July 4, 2018
    Date of Patent: July 14, 2020
    Inventors: Deepak Patil, Ambrish Kamdar, Syed Ali, Oscar Portillo, Marek Pakulski
  • Patent number: 10253238
    Abstract: Accretion inhibiting wellbore fluid compositions a ay contain a multiester, a sorbitan ester surfactant, and a base fluid, wherein the composition is in the form of a metastable emulsion. Methods may include emplacing a wellbore fluid into a wellbore, the wellbore fluid containing a multiester, and a sorbitan ester surfactant, wherein the wellbore fluid forms a metastable emulsion.
    Type: Grant
    Filed: November 11, 2016
    Date of Patent: April 9, 2019
    Assignees: M-I L.L.C., SCHLUMBERGER NORGE AS
    Inventors: Stephen Cliffe, Anders Grinrod
  • Publication number: 20150080273
    Abstract: The invention provides a foam control formulation in the form of a microemulsion, the formulation comprising: (a) from S to 70% w/w of primary surfactant, this surfactant having an HLB of from 1 to 12 and/or a cloud point of from 20 to 70° C.; (b) from 2 to 40% w/w of water-insoluble organic carrier liquid; and (c) water. Also provided is the use of this formulation to prevent and/or reduce foam in a fluid system, or as a processing aid to control foam production in a fluid system. The formulation may be used in an aqueous fluid system, such as an oilfield.
    Type: Application
    Filed: May 10, 2013
    Publication date: March 19, 2015
    Inventors: Kevan Hatchman, Gareth Collins, Chris Jones
  • Patent number: 8937102
    Abstract: The invention is drawn to fluid concentrate formulations of fatty acid monoethanolamides comprising (a) about 71-76% by weight of one or more C8-C22 fatty acid monoethanolamides, (b) about 15-17% by weight of water, and (c) about 10-12% by weight of one or more hydrotropes, based on the fluid formulation, wherein the fluid formulation is homogeneous, pumpable and color stable at a temperature of less than 55° C. A preferred embodiment is drawn to fluid concentrate formulations of cocamide monoethanolamide (CMEA) consisting of (a) about 71-76% by weight of CMEA, (b) about 15-17% by weight of water, and (c) about 10-12% by weight of glycerol, based on the fluid formulation. Methods of preparing the fluid concentrate formulations mulations are also disclosed. The fluid concentrate formulations of fatty acid monoethanolamides are useful in the preparation of cosmetic and pharmaceutical compositions.
    Type: Grant
    Filed: February 26, 2011
    Date of Patent: January 20, 2015
    Assignee: Cognis IP Management GmbH
    Inventors: John F. Hessel, Stephen F. Gross, Anna Kvecher
  • Patent number: 8900444
    Abstract: A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.
    Type: Grant
    Filed: November 8, 2013
    Date of Patent: December 2, 2014
    Assignees: Queen's University at Kingston, GreenCentre Canada
    Inventors: Philip G. Jessop, Lam N. Phan, Andrew J. Carrier, Rui Resendes, Dominik Wechsler
  • Publication number: 20130085188
    Abstract: Methods of modulating interfacial characteristics in a self-assembled, force-transmitting peptide network at a fluid-fluid interface are disclosed. The methods involve exposing a peptide capable of participating in a self-assembled, force-transmitting peptide network, either before or after it interacts with other peptides to form the peptide network to a stimulus that alters the chemical and/or physical properties of the peptide. Use of such methods in applications such as emulsions and foams are also disclosed.
    Type: Application
    Filed: November 21, 2012
    Publication date: April 4, 2013
    Applicant: THE UNIVERSITY OF QUEENSLAND
    Inventor: THE UNIVERSITY OF QUEENSLAND
  • Patent number: 8357724
    Abstract: The invention concerns a process for controlling the stability or the droplets sized of simple water-in-oil emulsions, wherein a di-block or tri-block copolymer is used. A block is a hydrophilic block, the other block is a hydrophobic block. The invention concerns also a stabilized water-in-oil emulsion.
    Type: Grant
    Filed: May 16, 2006
    Date of Patent: January 22, 2013
    Assignee: Rhodia Chimie
    Inventors: Sophie Deroo, Mikel Morvan
  • Patent number: 8283385
    Abstract: Reversible switchable surfactants are provided. A surfactant is the salt of an amidine or guanidine: having at least one R group that is a hydrophobic moiety selected from the group consisting of higher aliphatic moiety, higher siloxyl moiety, higher aliphatic/siloxyl moiety, aliphatic/aryl moiety, siloxyl/aryl moiety, and aliphatic/siloxyl/aryl moiety. The other R groups are smaller moieties such as H, C1 to C4 aliphatic or the like. The surfactant is turned on by a gas that liberates hydrogen ions, such as, for example, carbon dioxide, which liberates hydrogen ions in the presence of water. The surfactant is turned off by exposure to a flushing gas and/or heating. When “on” the surfactants are useful to stabilize emulsions, and when “off” they are useful to separate immiscible liquids or a liquid and a solid. The surfactants find uses in polymerization and in the oil industry.
    Type: Grant
    Filed: November 15, 2006
    Date of Patent: October 9, 2012
    Assignee: Queen's University at Kingston
    Inventor: Philip G. Jessop
  • Patent number: 8247359
    Abstract: In one aspect, the present invention provides a water-in-oil emulsion comprising from about 5 to about 40 wt % aqueous phase and from about 95 to about 60 wt % non-aqueous phase, said aqueous phase being dispersed in said non-aqueous phase in the form of droplets having an average droplet size no greater than about 0.1 ?m, said emulsion comprising: at least 60 wt % of an oil selected from fuel oils, lubricating oils and mixtures thereof, from about 1 to about 30 wt % of emulsifying agents, and the balance to 100 wt % water, wherein said emulsifying agents include a fatty (C8-C24)-amido-(C1-C6)alkyl betaine, is useful as a fuel, coolant or lubricant.
    Type: Grant
    Filed: January 18, 2007
    Date of Patent: August 21, 2012
    Assignee: Palox Limited
    Inventor: David William Martin
  • Patent number: 8178102
    Abstract: Provided is an emulsified composition for diluting a cancer antigen peptide or a dimer thereof. Also provided is a novel cancer vaccine composition or specific CTL inducer that efficiently induces CTL irrespective of the type of cancer antigen peptide when mixing the emulsified composition for dilution and a water phase comprising a cancer antigen peptide or a dimer thereof. The present invention relates to an emulsified composition for diluting a cancer antigen peptide or a dimer thereof, comprising a particular ester, a particular surfactant, a particular emulsifier, and a water phase. The present invention also relates to a cancer vaccine composition or specific CTL inducer obtained by freshly diluting and mixing a water phase comprising a cancer antigen peptide or a dimer thereof with the emulsified composition for dilution.
    Type: Grant
    Filed: January 19, 2006
    Date of Patent: May 15, 2012
    Assignees: Dainippon Sumitomo Pharma Co., Ltd., NOF Corporation
    Inventors: Koichi Saito, Yusuke Okawa
  • Patent number: 7915203
    Abstract: A new class of secondary emulsifying agents for use in inverted mud and other inverted system is disclosed and method for making and using same.
    Type: Grant
    Filed: July 27, 2009
    Date of Patent: March 29, 2011
    Assignee: Clearwater International, LLC
    Inventors: Olusegun Matthew Falana, Arthur T. Gilmer, Edward Marshall
  • Patent number: 7749945
    Abstract: An invert emulsion fluid system and a method of performing petroleum recovery operations using an invert emulsion fluid system.
    Type: Grant
    Filed: September 18, 2007
    Date of Patent: July 6, 2010
    Assignee: Baker Hughes Incorporated
    Inventor: Tao Xiang
  • Patent number: 7709421
    Abstract: Single phase microemulsions improve the removal of filter cakes formed during drilling with oil-based muds (OBMs). The single phase microemulsion removes oil and solids from the deposited filter cake. Optionally, an acid capable of solubilizing the filter cake bridging particles may also be used with the microemulsion. In one non-limiting embodiment the acid may be a polyamino carboxylic acid. Skin damage removal from internal and external filter cake deposition can be reduced. In another optional embodiment, the single phase microemulsion may contain a filtration control additive for delaying the filter cake removal, destruction or conversion.
    Type: Grant
    Filed: October 17, 2007
    Date of Patent: May 4, 2010
    Assignee: Baker Hughes Incorporated
    Inventors: Thomas A. Jones, David E. Clark, Lirio Quintero
  • Publication number: 20100105112
    Abstract: Surfactants (e.g., fluorosurfactants) for stabilizing aqueous or hydrocarbon droplets in a fluorophilic continuous phase are presented. In some embodiments, fluorosurfactants include a fluorophilic tail soluble in a fluorophilic (e.g., fluorocarbon) continuous phase, and a headgroup soluble in either an aqueous phase or a lipophilic (e.g., hydrocarbon) phase. The combination of a fluorophilic tail and a headgroup may be chosen so as to create a surfactant with a suitable geometry for forming stabilized reverse emulsion droplets having a disperse aqueous or lipophilic phase in a continuous, fluorophilic phase. In some embodiments, the headgroup is preferably non-ionic and can prevent or limit the adsorption of molecules at the interface between the surfactant and the discontinuous phase. This configuration can allow the droplet to serve, for example, as a reaction site for certain chemical and/or biological reactions.
    Type: Application
    Filed: August 7, 2007
    Publication date: April 29, 2010
    Inventors: Christian Holtze, Jeremy Jon Agresti, David A. Weitz, Keunho Ahn, John Brian Hutchison, Andrew Gifiths, Abdesiam El Harrak, Olive John Miller, Jean-Christophe Barat, Valorie Taly, Michael Ryckelynck, Christoph Merton
  • Patent number: 7687439
    Abstract: Single phase microemulsions improve the removal of filter cakes formed during drilling with invert emulsions. The single phase microemulsion removes oil and solids from the deposited filter cake. Optionally, an acid capable of solubilizing the filter cake bridging particles may also be used with the microemulsion. In one non-limiting embodiment the acid may be a polyamino carboxylic acid. Skin damage removal from internal and external filter cake deposition can be reduced.
    Type: Grant
    Filed: October 2, 2006
    Date of Patent: March 30, 2010
    Assignee: Baker Hughes Incorporated
    Inventors: Thomas A. Jones, David E. Clark, Lirio Quintero, Bruce Rae Ewen
  • Patent number: 7651984
    Abstract: A lubricant in the form of a water or oil insoluble solvent in oil emulsion is described where a base (soluble or dispersible in said oil-insoluble solvent or water) is present in the dispersed phase. These lubricants are beneficial in various applications such as internal combustion engines where the oil needs enough basicity to neutralize any inorganic acids generated by sulfur present in the fuel.
    Type: Grant
    Filed: June 27, 2002
    Date of Patent: January 26, 2010
    Assignee: The Lubrizol Corporation
    Inventors: Stephen J. Cook, Alexandra Mayhew, Helena M. Cressey
  • Patent number: 7553878
    Abstract: The present invention provides a feedstock composition for increasing the efficiency of atomization in hydrocarbon processing that includes a water-in-hydrocarbon oil emulsion including a non-ionic surfactant capable of stabilizing the emulsion and having a hydrophilic-lipophilic balance of greater than about 12. The emulsion includes water droplets of about 5 to about 10 microns in diameter, the droplets being dispersed substantially uniformly in the hydrocarbon oil phase. These surfactants are capable of stabilizing the water-in-hydrocarbon oil emulsion under relevant temperature and pressure conditions for hydrocarbon processing. The inventive feedstock composition provides a metastable water-in-oil emulsion where expanding water vapor explodes under spray conditions where the system pressure is released, demolishing a larger oil droplet and producing smaller oil droplets.
    Type: Grant
    Filed: April 29, 2003
    Date of Patent: June 30, 2009
    Assignee: General Electric Company
    Inventors: Wiley L. Parker, Collin W. Cross, Alan E. Goliaszewski
  • Patent number: 7521482
    Abstract: An emulsion is optimized in that it is stabilized by the presence of a surfactant specifically selected according to the type of a polymer, or copolymer, also present in the emulsion. The surfactant and the polymer are selected oppositely charged.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: April 21, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Jean-François Argillier, Isabelle Henaut
  • Patent number: 7482310
    Abstract: A method of treating a subterranean formation penetrated by a well bore including: (a) preparing a fracturing fluid containing a mixture resulting from: (I) providing a water-in-oil emulsion composition that includes: (i) 5% to 99% by weight of a water-in-oil emulsion polymer comprising a polymer or copolymer containing repeat units from an acrylamide monomer; (ii) 0.5% to 90% by weight of a carrier solvent; and (iii) 0 to 90% by weight of a fluidizing agent; and adding (iv) 0.1% to 10% by weight of one or more inorganic microparticles, where the total of all components is 100% by weight; and (II) adding the water-in-oil emulsion composition to water; and (b) contacting the subterranean formation with the fracturing fluid.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: January 27, 2009
    Assignees: Kroff Chemical Company, Inc., Superior Well Services, Inc.
    Inventors: Rhys R. Reese, Paul Rey
  • Patent number: 7432230
    Abstract: A superior powder form of a metallic soap for enhancing the properties of an invert emulsion drilling fluid may be prepared by a dry process saponification reaction. The process includes mixing a source of metal cations with the product of a Diels-Alder reaction of dienophiles with fatty acids and/or resin acids and allowing the mixture to react. Heating the mixture increases the rate of reaction. The solid product is ground to form a powder. The properties of the drilling fluid that may be improved by adding the soap include filtration control, fluid loss control, emulsification and emulsion stability, and electrical stability.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: October 7, 2008
    Assignee: Halliburton Energy Service, Inc.
    Inventor: Jeffrey J. Miller
  • Patent number: 7432329
    Abstract: The present invention relates to dispersing agents for pigments or extenders based on acrylic acid alkyl ester polymers, wherein at least part of the ester groups of the polymers is reacted to form acid amides, wherein the dispersing agent is obtainable by the aminolysis of ester groups of the polymers by means of amines, such as amino alkylenyl heterocycles. The invention also relates to the use of the dispersing agents according to the invention for the production of pigment concentrates and coating media, and to a process for producing the dispersing agents.
    Type: Grant
    Filed: July 21, 2003
    Date of Patent: October 7, 2008
    Assignee: BYK-Chemie GmbH
    Inventors: Karlheinz Haubennestel, Wolfgang Pritschins, Ulrich Orth
  • Patent number: 7419938
    Abstract: A method of treating a subterranean formation, the method comprising: (A) injecting down a well bore into the formation an admixture of (a) an emulsion having an internal aqueous phase comprising a water-soluble oil or gas field chemical or an aqueous dispersion of a water-dispersible oil or gas field chemical and an external oil phase comprising a liquid hydrocarbon and an oil-soluble surfactant and (b) a demulsifier comprising a solution of a surfactant having a cloud point temperature of above 40° C.; or (B) separately injecting down a well bore into the formation emulsion (a) and demulsifier (b) and generating an admixture of emulsion (a) and demulsifier (b) within the formation.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: September 2, 2008
    Assignee: BP Exploration Operating Company Limited
    Inventor: Ian Ralph Collins
  • Patent number: 7417010
    Abstract: A method of treating a subterranean formation, the method comprising: (A) injecting down a well bore into the formation an admixture of (a) an emulsion having an internal aqueous phase comprising a water-soluble oil or gas field chemical or an aqueous dispersion of a water-dispersible oil or gas field chemical and an external oil phase comprising a liquid hydrocarbon and an oil-soluble surfactant and (b) a demulsifier comprising a solution of a surfactant having a cloud point temperature of above 40° C.; or (B) separately injecting down a well bore into the formation emulsion (a) and demulsifier (b) and generating an admixture of emulsion (a) and demulsifier (b) within the formation.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: August 26, 2008
    Assignee: BP Exploration Operating Company Limited
    Inventor: Ian Ralph Collins
  • Patent number: 7361692
    Abstract: A dispersant comprising a polyester chain obtainable by polymerising a hydroxy carboxylic acid or lactone thereof such as E-caprolactone with a cyclic alkylene carbonate such as 5,5-dimethyltrimethylene carbonate. The dispersant may be in the form of a phosphate ester where the polyester chain is reacted with a phosphating agent such as polyphosphoric acid or the polyester chain may be attached to a polyamine or polyimine such as polyethyleneimine.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: April 22, 2008
    Assignee: The Lubrizol Corporation
    Inventor: Dean Thetford
  • Patent number: 7276093
    Abstract: A water-in-hydrocarbon emulsion includes a water phase, a hydrocarbon phase and a surfactant, wherein the water phase is present in an amount greater than or equal to about 5% vol. with respect to volume of the emulsion, and the water phase and the surfactant are present at a ratio by volume of the water phase to the surfactant of at least about 1. A method for preparing the emulsion is also provided.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: October 2, 2007
    Assignee: Inievep, S.A.
    Inventors: Hercilio Rivas, Xiomara Gutiérrez, Manuel A. González, Geoffrey McGrath, Migdalia Carrasquero, Francisco López-Linares, Roberto Galiasso
  • Patent number: 7262152
    Abstract: The invention concerns modified hydrophobic polyelectrolytes by amide formation of a hydrophilic skeleton by n-alkylamines whereof the alkyl chain comprises 6 to 22 carbon atoms. Preferably, the amide formation is obtained by di-n-dodecylamine. The hydrophilic skeleton is preferably a sodium polyacrylate or polyacrylic acid corresponding to a statistical acrylate-AMPS copolymer. Said polymers can be used for stabilizing direct or invert emulsions likely to be destabilized or inverted by a modification in the degree of salinity of the aqueous phase or a pH modification. The invention is particularly useful for stabilizing oil drilling fluids or the like in particular drilling, fracturation, acidification or completion fluids.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: August 28, 2007
    Assignee: M-I L.L.C.
    Inventors: Nathalie Monfreux-Gaillard, Patrick Perrin, Françoise LaFuma, Christopher Sawdon
  • Patent number: 7256159
    Abstract: The present invention concerns a water-based drilling mud for utilization in the drilling of oil wells comprising an aqueous phase wherein the aqueous phase contains an oil soluble polymer in the form of a gel as a fluid loss reducer. The subject invention further reveals a method of lubricating a drilling bit during the drilling of a well which comprises circulating a water-based drilling mud in the vicinity of the drilling bit wherein the water-based drilling mud is comprised of an aqueous phase, and wherein the aqueous phase contains an oil soluble polymer in the form of a gel as a fluid loss reducer.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: August 14, 2007
    Assignee: Eliokem S.A.S.
    Inventors: Bertrand Guichard, Barry Wood, Patrick Vongphouthone
  • Patent number: 7238646
    Abstract: A method for using an invert emulsion fluid in a well bore, comprising placing an invert emulsion fluid in a well bore, wherein the invert emulsion fluid comprises an oleaginous fluid, a non-oleaginous fluid and an emulsifier comprising one or more amines generally represented by the formula: wherein R is a radical selected from the group consisting of abietyl, hydroabietyl, dihydroabietyl, tetrahydroabietyl, and dehydroabietyl, each R? may be the same or different and is an alkyl having from about 1 to about 3 carbons, each A may be the same or different and is NH or O, and the sum of x and y ranges from about 1 to about 20, and contacting the invert emulsion fluid with an acid solution to reversibly convert the invert emulsion to an oil-in-water emulsion.
    Type: Grant
    Filed: November 18, 2005
    Date of Patent: July 3, 2007
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Carl J. Thaemlitz, Robert S. Taylor, Ryan M. Foster
  • Patent number: 7101829
    Abstract: The present invention concerns a water-based drilling mud for utilization in the drilling of oil wells comprising an aqueous phase wherein the aqueous phase contains an oil soluble polymer in the form of a gel as fluid loss reducer. The subject invention further reveals a process for preparing an oil soluble polymer fluid loss control agent comprising the steps of dissolving at least one polymer in a hydrocarbon oil to form a clear solution or a gel, adding an emulsifier to the solution or the gel, and keeping the mixture under conditions of agitation until a clear creamy mixture is obtained.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: September 5, 2006
    Assignee: Eliokem S.A.S.
    Inventors: Bertrand Guichard, Barry Wood, Patrick Vongphouthone
  • Patent number: 7041145
    Abstract: Fuel made from an emulsion between water and a liquid hydrocarbon and polymeric surfactant, used to stabilize the emulsion, obtainable by (a) reacting (i) at least one polyolefin oligomer functionalized with at least one group deriving from a dicarboxylic acid, or a derivative thereof; and (ii) at least one polyoxylalkylene having linear oxyalkylene units, the polyoxyalkylene being linked to a long-chain alkyl group optionally containing at least one ethylenic unsaturation; and (b) reacting the product of step (a) with (ii) at least one nitrogen compound selected from monoamines, polyamines and quaternary ammonium hydroxides. The fuel has high stability over time, without forming carbonaceous deposits adhering to metal surfaces.
    Type: Grant
    Filed: July 9, 2001
    Date of Patent: May 9, 2006
    Assignee: CAM Technologie S.p.A.
    Inventors: Tiziano Ambrosini, Attilio Citterio, Alberto De Amicis, Guido Rivolta
  • Patent number: 6989354
    Abstract: An invert emulsion fluid, method for making same, and method for using same as a servicing fluid in a well bore. The invert emulsion fluid contains an oleaginous fluid, a non-oleaginous fluid, and an emulsifier comprising one or more amines generally represented by the formula: wherein R is a cycloaliphatic hydrocarbon, each R? may be the same or different and is H or an alkyl having from about 1 to about 3 carbon atoms, each A may be the same or different and is NH or O, and the sum of x and y ranges from about 1 to about 20. In a preferred embodiment, R is a radical selected from the group consisting of abietyl, dihydroabietyl, tetrahydroabietyl, and dehydroabietyl, R? is H, and A is O.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: January 24, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Carl J. Thaemlitz, Robert S. Taylor, Ryan M. Foster
  • Patent number: 6780209
    Abstract: The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second interme
    Type: Grant
    Filed: January 24, 2000
    Date of Patent: August 24, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Brian B. Filippini, Richard M. Lange, Bryan A. Grisso, Bryn Hird
  • Publication number: 20040123513
    Abstract: Aqueous diesel oils are disclosed which may be stored over several days without separating out as a result of the added emulsifier mixture.
    Type: Application
    Filed: February 18, 2004
    Publication date: July 1, 2004
    Inventors: Frank Bongardt, Juergen Roeder
  • Patent number: 6653355
    Abstract: An oil treating agent of W/O emulsion, wherein an aqueous dispersed phase is dispersed in an oily continuous phase, and wherein the dispersed phase is an alkaline mixture solution obtained by mixing water, a solution comprising water and an alcohol, or a water-free alcohol solution with an alkali hydroxide e.g. sodium hydroxide or with a metal alkoxide e.g. sodium alkoxide and the continuous phase comprises a liquid incompatible with the dispersed phase.
    Type: Grant
    Filed: September 5, 2000
    Date of Patent: November 25, 2003
    Assignees: Hakugen Co., Ltd., Prest Corporation
    Inventors: Tatsuo Kasahara, Tomohiro Shiiya, Kunimitsu Tamura
  • Patent number: 6620770
    Abstract: A method and product is disclosed which provides emulsion stability and filtration control to invert emulsion drilling fluids. The product comprises a blend of a carboxylic acid terminated polyamide and a mixture produced by the Diels-Alder reaction of dienophiles, preferably carboxylic acids, polycarboxylic acids, acid anhydrides, or combinations or mixes thereof, with a mixture of fatty acids and resin acids. The product is extremely effective, decreasing by about two-thirds the amount of emulsifier generally required to formulate an effective drilling fluid. The product also greatly reduces and in many cases eliminates the need for conventional fluid loss additives, and additionally provides electrical stability. Moreover, the product has a pour point as low as about 20 degrees Fahrenheit with minimal solvents, thereby eliminating the need to ship large amounts of inert material for use, and may be transported in a highly active state.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: September 16, 2003
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jeff Kirsner, Jeff Miller, Jon Bracken
  • Patent number: 6596816
    Abstract: The present invention relates to dispersing agents for pigments or extenders based on acrylic acid alkyl ester polymers, wherein at least part of the ester groups of the polymers is reacted to form acid amides, wherein the dispersing agent is obtainable by the aminolysis of ester groups of the polymers by means of amines, wherein, for the aminolysis, at least one amine is used from the group comprising a) amines of general formula NH2—R1—NR2R3, wherein R1 is a divalent alkylene radical comprising 2-4 carbon atoms and R2 and R3 are aliphatic and/or alicyclic alkyl radicals which comprise 1-12, preferably 1-6 carbon atoms and which can be the same or different. The invention also relates to the use of the dispersing agents according to the invention for the production of pigment concentrates and coating media, and to a process for producing the dispersing agents.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: July 22, 2003
    Assignee: BYK-Chemie GmbH
    Inventors: Karlheinz Haubennestel, Wolfgang Pritschins, Ulrich Orth
  • Patent number: 6586479
    Abstract: The invention relates to fine emulsions comprising at least one W/O emulsifier and at least one hydrophilic component, and to a process for their preparation. The fine emulsions are obtainable by converting a W/O preemulsion comprising at least one W/O emulsifier into an O/W fine emulsion by adding at least one hydrophilic component and, where appropriate, changing the temperature. Suitable W/O emulsifiers are preferably sorbitol esters. The fine emulsions are preferably spray emulsions for cosmetic and pharmaceutical applications.
    Type: Grant
    Filed: July 20, 2001
    Date of Patent: July 1, 2003
    Assignee: Clariant GmbH
    Inventors: Dennis Miller, Torsten Henning, Wiebke Johannpeter, Eva-Maria Wiener
  • Patent number: 6509024
    Abstract: The first embodiment of the present invention provides a composition, which includes: an aqueous phase dispersed in an oily phase; wherein the oily phase includes at least one particle of a crosslinked solid organopolysiloxane elastomer having at least one oxyalkylene group, and wherein the aqueous phase includes at least one crosslinked and at least partially neutralized poly(2-acrylamido-2-methylpropanesulphonic acid) polymer. Other embodiments of the present invention provide methods of using the above-identified composition, compositions containing same, and a method of preparing water-in-oil emulsions.
    Type: Grant
    Filed: March 21, 2001
    Date of Patent: January 21, 2003
    Assignee: L'Oreal
    Inventor: Raluca Lorant
  • Patent number: 6492430
    Abstract: A process for preparing a composition comprising a mixture with ester and amine function in the form of ester-amines, amines, salts of amines, monoglycerides and diglycerides all derived from monomeric, dimeric, trimeric, and/or tetrameric fatty acids contained in polymerized polyunsaturated oil comprising: (a) polymerizing a polyunsaturated vegetable or animal oil to form a polymerized oil, (b) treating the polymerized oil with water vapor, and (c) reacting the polymerized oil with an excess of at least one compound containing at least one hydroxyl function and at least one tertiary amine function, optionally in the presence of a catalyst. Said methods further comprise adding the compositions to an oil effluent as dispersing agents for hydrates.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: December 10, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Gérard Hillion, Isabelle Durand, Anne Sinquin, Marie Velly
  • Patent number: 6476081
    Abstract: In order to manufacture a composition mainly containing compounds with ester and amide functions, in particular in the form of ester-amides, as well as compounds with amine functions, such as ester-amines, the salts of amines, monoglycerides and diglycerides, formed from monomeric, dimeric, trimeric and/or tetrameric fatty acids contained in a polymerized polyunsaturated oil, a process is implemented which comprises the following stages: a) use (or preparation) of a polymerized oil by polymerization of a polyunsaturated vegetable or animal oil; b) treatment of said polymerized oil by entrainment with water vapor; and c) reaction of the polymerized oil thus treated with an excess of at least one aminoalcohol, in the presence or not of a catalyst. This composition can be used as an emulsifying and dispersing surfactant, in particular as an additive for dispersing hydrates in oil effluents.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: November 5, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Gérard Hillion, Isabelle Durand, Anne Sinquin, Marie Velly
  • Patent number: 6387961
    Abstract: Alkyl 2-acetamido-2-deoxy-D-glucopyranoside uronic acids, and their pharmaceutically or cosmetically acceptable salts, and their use as surface-active and/or interfacially active active compounds, in particular as detergent surfactants or emulsifiers.
    Type: Grant
    Filed: September 12, 2000
    Date of Patent: May 14, 2002
    Assignee: Beiersdorf AG
    Inventors: Günther Schneider, Hartmut Schmidt-Lewerkühne, Joachim Thiem, Oliver Scheel
  • Patent number: 6342553
    Abstract: A dispersion of an ester polymer in at least one liquid wherein the ester polymer is a polymer consisting essentially of a first monomer with structural units derived from at least one ester (1) of an aliphatic carboxylic acid with an aliphatic alcohol, wherein one of the acid and alcohol is ethylenically unsaturated and the other of the acid and alcohol has a long chain group of 14-40 carbons. A second monomer is optionally present which is a monomer derived from a different ester (2) within the same definition as ester (1), such that the mole average carbon content of the long chain group is 15-35, and a third monomer with structural units derived from a corresponding ester (3) of an aliphatic carboxylic acid and an aliphatic alcohol. One of the acid and alcohol is ethylenically unsaturated and the other has an aliphatic group of 1-13 carbons, such that at least 30% of the said aliphatic groups have 15-35 carbons.
    Type: Grant
    Filed: August 4, 1999
    Date of Patent: January 29, 2002
    Assignee: BP Chemicals Limited
    Inventors: Philip Kenneth Gordon Hodgson, Spencer Edwin Taylor
  • Patent number: 6339165
    Abstract: Disclosed are a fatty acid esters composition of a polyglycerine containing more than 70% of a fatty acid monoester which is defined by a specified analysis method, a process for the preparation thereof, a process for the preparation of a highly-purified fatty acid esters composition of a polyglycerine, and a highly-purified fatty acid esters composition of a polyglycerine having an oxirane oxygen concentration of below 100 ppm which is defined by a specified analysis method. The fatty acid esters compositions of a polyglycerine are useful as additives for a variety of food-stuffs, additives for a variety of thermoplastic resins, and as additives for a variety of cosmetics or detergents.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: January 15, 2002
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Toshio Endo, Terumasa Daito
  • Patent number: 6323246
    Abstract: A fatty acid amphoteric surfactant complex obtained by mixing a) at least one imidazolinium ampholytic surfactant of the formula: wherein R1 represents an alkyl or alkenyl group having 9 to 17 carbon atoms on average; and Z is 1 or 2; with b) a higher fatty acid selected from the group consisting of oleic acid, isostearic acid and a mixture of oleic acid and isostearic acid; wherein the ratio of said higher fatty acid to the total amount of said imidazolinium ampholytic surfactant(s) in said complex ranges from about 25:75 to 90:10. The complex containing an ampholytic and/or semipolar surfactant and higher fatty acid may optionally contain a clay mineral. Said complex may be employed in making emulsions.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: November 27, 2001
    Assignee: Shiseido Company, Ltd.
    Inventors: Yasunari Nakama, Michihiro Yamaguchi, Kiyoshi Miyazawa, Takayuki Ohmura
  • Patent number: 6221920
    Abstract: The following are described herein: a composition that consists of a mixture that comprises at least amides, amines, ester-amides, ester-amines, amine salts and monoglycerides, that are all derived from monomeric, dimeric, trimeric and/or tetrameric fatty acids; a process for the production of said composition which comprises the transamidification reaction of a polyunsaturated vegetable oil that is polymerized thermally, with an excess of at least one amino alcohol, which may or may not be in the presence of a catalyst; and the uses of this composition particularly as an emulsifying agent that allow it, depending on the nature of the oil, to form an oil-in-water or water-in-oil emulsion, as a solid-dispersing agent, or as an agent for the stabilization of foams in a liquid or an emulsion.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: April 24, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Gérard Hillion, Isabelle Durand, Robert Stern, Marie Velly
  • Patent number: 6176893
    Abstract: Non-explosive water in oil emulsion fertilizer compositions comprise a discontinuous aqueous phase comprising at least one fertilizer component, a continuous organic phase, an emulsifying amount of an emulsifier composition comprising: the reaction product of an amine (C) characterized by the presence within its structure of at least one H—N group and an intermediate formed in the reaction of (A) at least one olefinic compound containing at least one group of the formula and (B) at least one carboxylic reactant selected from the group consisting of compounds of the formula R3C(O)(R4)nC(O)OR5   (III) wherein each of R3 and R5 is independently H or a hydrocarbyl group, R4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof and optionally, from about 0.5 to about 2 moles, per mole of (B), of (D) at least one aldehyde or ketone. The fertilizer compositions provide for controlled release of the fertilizer components.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: January 23, 2001
    Assignee: The Lubrizol Corporation
    Inventor: James H. Bush
  • Patent number: 6156326
    Abstract: Alkyl 2-acetamido-2-deoxy-D-glucopyranoside uronic acids, and their pharmaceutically or cosmetically acceptable salts, and their use as surface-active and/or interfacially active active compounds, in particular as detergent surfactants or emulsifiers.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: December 5, 2000
    Assignee: Beiersdorf AG
    Inventors: Gunther Schneider, Hartmut Schmidt-Lewerkuhne, Joachim Thiem, Oliver Scheel
  • Patent number: 6153657
    Abstract: An organic solvent-less O/W type emulsion having an excellent stability for storage and water-dilution is produced by a specific process in which (1) a mixture of (a) water with (b) an oily substance selected from oily effective materials and oily liquid materials, the oily substance and water being capable of forming an interface therebetween, (c) a high molecular weight surfactant and (d) a low molecular weight surfactant is stirred at a temperature of 40.degree. C. or less, to provide an O/W type emulsion; (2) the emulsion is heated to gel the emulsion; (3) the gel is heated to phase invert from O/W to W/O; (4) the W/O emulsion is cooled to a temperature below the gelling temperature; and (5) the resultant O/W emulsion is further stirred, and optionally in or after the cooling step (4), a particulate solid substance or an aqueous suspension thereof is mixed with the emulsion.
    Type: Grant
    Filed: June 1, 1998
    Date of Patent: November 28, 2000
    Assignee: Hodogaya Chemical Co., Ltd.
    Inventors: Atsushi Kisuno, Tatsuo Ansai, Shihoko Aizawa