Phase Inversion Patents (Class 516/925)
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Patent number: 8163838Abstract: A process of producing an artificial latex, comprising the steps: (a) cement formation, wherein a rubber is dissolved in a suitable hydrocarbon solvent; (b) emulsification of the cement formed in step (a), together with an aqueous soap solution, thus forming an oil-in-water emulsion; (c) hydrocarbon solvent removal, resulting in a latex of the rubber having particles of a median particle size in the range of from about 0.5 to 2.0 ?m, and optionally (d) latex concentration, forming an artificial latex with a higher solids content, characterized in that in step (b) a premix is formed first, which is subsequently homogenized into an oil-in-water emulsion, and wherein the premix is formed by mixing the cement with the aqueous soap solution at a volume ratio of 1:1.Type: GrantFiled: December 18, 2007Date of Patent: April 24, 2012Assignee: Kraton Polymers US LLCInventors: Adrie A. Van Der Huizen, Marc S. Sonderman, Arwin W. Van Der Waal, Wouter De Jong, Anton Nicolai
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Patent number: 7511079Abstract: Methods and apparatuses for comminuting and stabilizing small particles are provided. In one embodiment, an apparatus moves an organic compound dissolved in a solvent to form a suspension of particles in a first fluid stream and moves the suspension in a second fluid stream, wherein the second fluid stream is oriented and positioned with respect to the first stream to cause shearing between the streams and mixing of at least some of the particles in the first and second streams.Type: GrantFiled: March 22, 2004Date of Patent: March 31, 2009Assignee: Baxter International Inc.Inventors: James E. Kipp, Joseph Chung Tak Wong, Monte Wisler, Rhonda Garcia
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Patent number: 7317041Abstract: A method for the preparation of a biliquid foam which does not rely upon the initial formation of a gas foam, in which a stirrer having a single or a multiplicity of blades is used, the stirrer being operated in a manner such that at least one part of the stirrer mechanism breaks the interface between the continuous polar phase used to form the biliquid foam and the air, the non-polar phase being added dropwise at least initially whilst stirring the continuous polar phase and the rate of addition of the non-polar phase being controlled so that a biliquid foam composition is formed.Type: GrantFiled: January 31, 2003Date of Patent: January 8, 2008Assignee: Disperse LimitedInventors: Philip Ernest Guffogg, Derek Alfred Wheeler
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Patent number: 6951891Abstract: The present invention relates to the production of dispersions and is particularly suitable for making dispersions with a viscous or solid dispersed phase in a continuous phase with a lower viscosity.Type: GrantFiled: July 31, 2002Date of Patent: October 4, 2005Assignee: Akzo Nobel N.V.Inventors: Jozef Johannes Maria Baltussen, Jan Visser
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Publication number: 20030191195Abstract: A method to invert a water-in-oil emulsion to an oil-in-water emulsion comprises contacting the water-in-oil emulsion with an aqueous colloidal dispersion including hydroxides of elements of Group II and Group III of The Periodic Table of Elements and mixtures thereof and then mixing the water-in-oil emulsion and aqueous colloidal dispersion until the water-in-oil emulsion inverts to an oil-in-water emulsion.Type: ApplicationFiled: March 18, 2003Publication date: October 9, 2003Inventor: Ramesh Varadaraj
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Patent number: 6586479Abstract: The invention relates to fine emulsions comprising at least one W/O emulsifier and at least one hydrophilic component, and to a process for their preparation. The fine emulsions are obtainable by converting a W/O preemulsion comprising at least one W/O emulsifier into an O/W fine emulsion by adding at least one hydrophilic component and, where appropriate, changing the temperature. Suitable W/O emulsifiers are preferably sorbitol esters. The fine emulsions are preferably spray emulsions for cosmetic and pharmaceutical applications.Type: GrantFiled: July 20, 2001Date of Patent: July 1, 2003Assignee: Clariant GmbHInventors: Dennis Miller, Torsten Henning, Wiebke Johannpeter, Eva-Maria Wiener
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Patent number: 6562876Abstract: A process for cold-producing an oil-in-water emulsion having enhanced consistency and tactile properties involving: (a) providing an oil component; (b) providing an aqueous wax dispersion containing: (i) a wax component; and (ii) an emulsifier; (c) providing water; and (d) cold-stirring (a)-(c) to form the emulsion.Type: GrantFiled: April 23, 2001Date of Patent: May 13, 2003Assignee: Cognis Deutschland GmbH & Co. KGInventors: Achim Ansmann, Nicole Mertscheit, Rolf Kawa
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Patent number: 6476168Abstract: Disclosed is an emulsion useful in an inversion process. The emulsion is a water-in-oil emulsion and has an aqueous phase having a water-soluble polymer, an oil phase and an activating agent of the following formula: wherein n=0 to 10 and m=2 to 25 and the oxypropylene and oxyethylene units are of block distribution or intermixed in random or tapered distribution. Further disclosed is a process according to the following: a) providing an water-in-oil emulsion having a water-soluble polymer in the aqueous phase and the activating agent; b) introducing the emulsion into an aqueous medium and c) allowing sufficient time for the emulsion to invert. Further disclosed is another process according to the following: a) providing an water-in-oil emulsion having a water-soluble polymer in the aqueous phase; b) introducing the emulsion into an aqueous medium having the activating agent and c) allowing sufficient time for the emulsion to invert.Type: GrantFiled: September 14, 2001Date of Patent: November 5, 2002Assignee: Rhodia, Inc.Inventors: Manilal S. Dahanayake, Fang Li, Jean-Luc Joye
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Patent number: 6369119Abstract: A cationic rosin-in-water emulsion which has been prepared without intermediate isolation of an anionic rosin-in-water emulsion and in which the dispersed rosin phase is stabilized by a cationic polymer derived from a degraded starch, said polymer having a degree of substitution of at least 0.15 quaternary groups per glucose unit.Type: GrantFiled: April 7, 2000Date of Patent: April 9, 2002Assignee: Rasio Chemcials UK LtdInventors: John C. Roberts, Martin Phillipson
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Patent number: 6316543Abstract: Provided is a low volatile organic content (VOC), isocyanate based curable oil-in-water emulsion of a polyisocyanate crosslinker and a surface active isocyanate reactive material in an aqueous medium, and a process for the preparation thereof. Also provided is a water-in-oil intermediate product to which an aqueous medium can be added to produce the curable oil-in-water emulsions. Such curable emulsions are particularly suited for use in coatings applications.Type: GrantFiled: February 27, 1998Date of Patent: November 13, 2001Assignee: Cytec Technology Corp.Inventor: Denise E. Fiori
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Patent number: 6313218Abstract: Provided is a low volatile organic content (VOC), isocyanate based curable oil-in-water emulsion of a polyisocyanate crosslinker and a surface active isocyanate reactive material in an aqueous medium, and a process for the preparation thereof. Also provided is a water-in-oil intermediate product to which an aqueous medium can be added to produce the curable oil-in-water emulsions. Such curable emulsions are particularly suited for use in coatings applications.Type: GrantFiled: February 27, 1998Date of Patent: November 6, 2001Assignee: Cytec Technology Corp.Inventors: Denise E. Fiori, David Ley, Richard Quinn
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Patent number: 6306915Abstract: The present invention provides a method of making an emulsified composition employing an emulsifier containing a sphingoglycolipid which has a structure represented by the following formula: wherein R1 is a saccharide moiety which consists of three to four hexoses selected from the group consisting of uronic acid, glucosamine, galactose, and mannose, or one uronic acid; R2 is an alkyl group, which may have a cycloalkyl group, an alkenyl group, or an alkynyl group; and R3 is an alkyl group. The alkyl group, the alkenyl group and the alkynyl group may have a normal chain or a branched chain, and may be substituted or unsubstituted. The emulsifier of the present invention has marked moisturizing effect, skin roughening preventing effect, and emulsifying effect.Type: GrantFiled: August 9, 1999Date of Patent: October 23, 2001Assignee: Kibun Food Chemifa Co., LtdInventor: Katsumi Murata
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Patent number: 6207720Abstract: The present invention relates to a process of preparing emulsions of hydrolyzable silanes, such as alkoxysilanes, using an oil concentrate. The emulsifiers are initially stirred with water. An oil concentrate is then prepared by adding a hydrolyzable silane to the stirring mixture of emulsifiers and water. Additional water is then dispersed in the oil concentrate to form the desired emulsion. Emulsions prepared by this process have shelf stability that is 6 months or longer.Type: GrantFiled: June 25, 1999Date of Patent: March 27, 2001Assignee: Crompton CorporationInventors: Toshiko M. Maeda, Antonio Chaves
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Patent number: 6180117Abstract: Microemulsion compositions comprising MQ resins and microemulsifiable amino silicone fluids or gums and a surfactant having a high phase inversion temperature, the microemulsions formed therewith, a means for preparing said microemulsions, and personal care products comprising said microemulsions.Type: GrantFiled: February 10, 1995Date of Patent: January 30, 2001Assignee: General Electric CompanyInventors: Marianne D. Berthiaume, James H. Merrifield, Donna A. Riccio
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Patent number: 6153657Abstract: An organic solvent-less O/W type emulsion having an excellent stability for storage and water-dilution is produced by a specific process in which (1) a mixture of (a) water with (b) an oily substance selected from oily effective materials and oily liquid materials, the oily substance and water being capable of forming an interface therebetween, (c) a high molecular weight surfactant and (d) a low molecular weight surfactant is stirred at a temperature of 40.degree. C. or less, to provide an O/W type emulsion; (2) the emulsion is heated to gel the emulsion; (3) the gel is heated to phase invert from O/W to W/O; (4) the W/O emulsion is cooled to a temperature below the gelling temperature; and (5) the resultant O/W emulsion is further stirred, and optionally in or after the cooling step (4), a particulate solid substance or an aqueous suspension thereof is mixed with the emulsion.Type: GrantFiled: June 1, 1998Date of Patent: November 28, 2000Assignee: Hodogaya Chemical Co., Ltd.Inventors: Atsushi Kisuno, Tatsuo Ansai, Shihoko Aizawa
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Patent number: 6103786Abstract: Stable polymer dispersions with polymer particle sizes of 0.1 to 10 .mu.m are prepared by dissolving a water-in-oil emulsion, comprising a polymer dissolved in an organic solvent which is immiscible with water (organic phase) and an aqueous phase, wherein the viscosity of the organic phase is 1.0 to 20,000 mPas (measured at 25.degree. C.), the surface tension between organic and aqueous phase is 0.01 to 30 mN/m, the particle size of the water emulsified in the organic phase is 0.2 to 50 .mu.m and the ratio by volume of organic phase to aqueous phase is in the range 80:20 to 20:80, subjecting this emulsion to a shear process at a shear power of 1.times.10.sup.3 to 1.times.10.sup.8 Watts per cm.sup.3, wherein the water-in-oil emulsion is converted into an oil-in-water emulsion.Type: GrantFiled: February 24, 1998Date of Patent: August 15, 2000Assignee: Bayer AktiengesellschaftInventors: Martin Hoch, Rainer Elbert, Bernd Klinksiek
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Patent number: 6087403Abstract: This composition based on polyglycosides comprises 30 to 65% by weight of at least one fatty alcohol of formula ROH, where R is a staturated or unsaturated, straight-chained or branched aliphatic radical having 1 to 4 ethylenically unsaturated bonds and having 12 to 22 carbon atoms, the remainder being a mixture of polyglycosides containing 35 to 75% by weight, based on the polyglycosides, of polyhexosides.Type: GrantFiled: August 7, 1998Date of Patent: July 11, 2000Assignee: Agro Industrie Recherches et Developments (A.R.D.)Inventors: Jean-Noel Bertho, Philippe Mathaly, Regis de Baynast, Veronique Dubois
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Patent number: 6077322Abstract: Methods and additive compounds for retarding the dispersion in water of bitumen-in-water emulsions, and in particular ORIMULSION, are disclosed. Methods include applied mixing at high speed and changing the pH of the emulsion. Additives include salts and flocculants.Type: GrantFiled: August 12, 1997Date of Patent: June 20, 2000Assignee: The Babcock & Wilcox CompanyInventor: Shih-Yung Shiao
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Patent number: 5912390Abstract: A method for the work-up of a nonionic surfactant-containing microemulsion reaction mixture formed in the o-alkylation of phenols by an alkyl halide in the presence of sodium hydroxide. Said mixture has one reaction product present as an aqueous phase and a further reaction product present as a water immiscible phase and which the reaction mixture is obtained in microemulsion form. Said reaction mixture is worked up by:a) subjecting this microemulsion to a temperature decreased by 20 to 50K thereby forming an aqueous phase having a high surfactant content and a substantially surfactant-free organic phase,b) separating off the substantially surfactant-free organic phase formed and replacing said surfactant-free organic phase with an organic solution of the alkyl halide.Type: GrantFiled: December 6, 1995Date of Patent: June 15, 1999Assignee: Bayer AktiengesellschaftInventors: Ortwin Wagner, Reinhard Schomacker